Standout Papers
Citation Impact
Citing Papers
Anti-Markovnikov alkene oxidation by metal-oxo–mediated enzyme catalysis
2017 StandoutScienceNobel
A Highly Regio‐ and Diastereoselective Phosphane‐Catalyzed [3+2] Annulation of Morita–Baylis–Hillman Carbonates with Cyclic N‐Acyl Ketimines
2013
Theoretical investigation toward organophosphine‐catalyzed [3 + 3] annulation of Morita–Baylis–Hillman carbonates with azomethine imines: Mechanism, origin of stereoselectivity, and role of catalyst
2017
Nucleophilic phosphine-catalyzed [3+2] cycloaddition of allenes with N-(thio)phosphoryl imines and acidic methanolysis of adducts N-(thio)phosphoryl 3-pyrrolines: a facile synthesis of free amine 3-pyrrolines
2008
Phosphine‐Catalyzed Asymmetric Umpolung Addition of Trifluoromethyl Ketimines to Morita–Baylis–Hillman Carbonates
2016
Highly Substituted Cyclohexenes via Phosphine‐Catalyzed [4+2] Annulation of Electron‐deficient Dienes and Vinyl Ketones
2017
Phosphine‐Catalyzed Asymmetric Formal [4+2] Tandem Cyclization of Activated Dienes with Isatylidenemalononitriles: Enantioselective Synthesis of Multistereogenic Spirocyclic Oxindoles
2014
Enantioselective [3 + 2] annulation of α-substituted allenoates with β,γ-unsaturated N-sulfonylimines catalyzed by a bifunctional dipeptide phosphine
2016
Highly enantioselective [4 + 2] cycloadditions of allenoates and dual activated olefins catalyzed by N-acyl aminophosphines
2012
Synthesis of Chiral Spirocyclopentenyl‐β‐lactams through Phosphane‐Catalyzed [3+2] Annulation of Allenoates with 6‐Alkylidenepenicillanates
2013
Sequential Catalyst Phosphine/Secondary Amine Promoted [1+4]/Rearrangement Domino Reaction for the Construction of (2H)‐Pyrans and 2‐Oxabicyclo[2.2.2]oct‐5‐ene Skeletons
2014
A Phosphine‐Catalyzed Novel Asymmetric [3+2] Cycloaddition of C,N‐Cyclic Azomethine Imines with δ‐Substituted Allenoates
2014
Stereoselective syntheses of functionalized spirocyclopenteneoxindoles via triphenylphosphine-catalyzed [3+2] cycloaddition reactions
2013
Asymmetric Synthesis of Spiropyrazolones through Phosphine‐Catalyzed [4+1] Annulation
2014
PPh3-catalyzed [2 + 2 + 2] and [4 + 2] annulations: synthesis of highly substituted 1,2-dihydropyridines (DHPs)
2009
Catalytic Markovnikov and anti‐Markovnikov Functionalization of Alkenes and Alkynes: Recent Developments and Trends
2004
Direct Asymmetric α‐Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts
2011 StandoutNobel
Gold(I)‐Catalyzed Intermolecular Hydroarylation of Alkenes with Indoles under Thermal and Microwave‐Assisted Conditions
2008
Development of asymmetric phosphine-promoted annulations of allenes with electron-deficient olefins and imines
2011
Phosphine‐Initiated Domino Reaction: A Convenient Method for the Preparation of Spirocyclopentanones
2014
Nucleophilic conjugate 1,3-addition of phosphines to oligoynoates
2014
Elucidation of the reaction mechanisms and diastereoselectivities of phosphine-catalyzed [4 + 2] annulations between allenoates and ketones or aldimines
2012
Phosphine-catalyzed highly diastereoselective [3+2] cyclization of isatin derived electron-deficient alkenes with α-allenic esters
2010
Phosphine‐Catalyzed Intramolecular Formal [3+2] Cycloaddition for Highly Diastereoselective Synthesis of Bicyclo[n.3.0] Compounds
2007
Dynamic Covalent Chemistry
2002 StandoutNobel
Diversity Through a Branched Reaction Pathway: Generation of Multicyclic Scaffolds and Identification of Antimigratory Agents
2010
Asymmetric [3 + 2] annulation of N-protected isatins with but-3-yn-2-one catalyzed by DIOP: facile creation of enantioenriched spiro[furan-2,3′-indoline]-2′,4(5H)-dione
2012
Indoles from Simple Anilines and Alkynes: Palladium‐Catalyzed CH Activation Using Dioxygen as the Oxidant
2009
Asymmetric Synthesis of Natural Product Inspired Tricyclic Benzopyrones by an Organocatalyzed Annulation Reaction
2008
Rhodium(III)‐Catalyzed Amidation of Unactivated C(sp3)H Bonds
2015
Catalytic Asymmetric CN Bond Formation: Phosphine‐Catalyzed Intra‐ and Intermolecular γ‐Addition of Nitrogen Nucleophiles to Allenoates and Alkynoates
2013
DABCO and Bu3P catalyzed [4 + 2] and [3 + 2] cycloadditions of 3-acyl-2H-chromen-ones and ethyl 2,3-butadienoate
2012
Multifunctional chiral phosphines-catalyzed highly diastereoselective and enantioselective substitution of Morita–Baylis–Hillman adducts with oxazolones
2011
Organocatalytic asymmetric allylic alkylation of oxindoles with Morita–Baylis–Hillman carbonates
2009
Versatile Enantioselective [3+2] Cyclization between Imines and Allenoates Catalyzed by Dipeptide‐Based Phosphines
2011
Lewis Base Catalyzed [4+2] Annulation of Electron‐Deficient Chromone‐Derived Heterodienes and Acetylenes
2011
Chiral phosphines in nucleophilic organocatalysis
2014
Recent advances in organocatalytic methods for the synthesis of disubstituted 2- and 3-indolinones
2012 Standout
An Unexpected Phosphine‐Catalyzed Regio‐ and Diastereoselective [4+1] Annulation Reaction of Modified Allylic Compounds with Activated Enones
2010
Asymmetric [3+2] annulation of allenes with maleimides catalyzed by dipeptide-derived phosphines: facile creation of functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers
2011
Phosphine-catalyzed [3 + 2] cycloaddition of allenoates with trifluoromethylketones: synthesis of dihydrofurans and tetrahydrofurans
2011
Chiral multifunctional thiourea-phosphine catalyzed asymmetric [3 + 2] annulation of Morita–Baylis–Hillman carbonates with maleimides
2012
Phosphine-catalyzed [3+2] annulation of α-substituted allenoates with ester-activated α,β-unsaturated imines: a novel variation of the Lu [3+2] cycloaddition reaction
2013
Phosphine‐Catalyzed [3 + 2] Annulation: Synthesis of Ethyl 5‐(tert‐Butyl)‐2‐Phenyl‐1‐Tosyl‐3‐Pyrroline‐3‐Carboxylate
2011
Phosphine‐Catalyzed Domino Reaction for the Synthesis of Conjugated 2,3‐Dihydrofurans from Allenoates and Nazarov Reagents
2012
Catalysis for fluorination and trifluoromethylation
2011 StandoutNature
Synthesis of Indoles Using Visible Light: Photoredox Catalysis for Palladium‐Catalyzed CH Activation
2014
Construction of adjacent spiro-quaternary and tertiary stereocenters through phosphine-catalyzed asymmetric [3+2] annulation of allenoates with alkylidene azlactones
2012
Palladium‐Catalyzed Oxidative Wacker Cyclizations in Nonpolar Organic Solvents with Molecular Oxygen: A Stepping Stone to Asymmetric Aerobic Cyclizations
2003
If CH Bonds Could Talk: Selective CH Bond Oxidation
2011
PPh3-catalyzed unexpected α-addition reaction of 1-(o-hydroxyaryl)-1,3-diketones to terminal alkynoates: a straightforward synthesis of multifunctional vinylesters
2009
Amino Acid Derived Phosphine‐Catalyzed Enantioselective 1,4‐Dipolar Spiroannulation of Cyclobutenones and Isatylidenemalononitrile
2015
Catalytic Asymmetric [4+2] Annulation Initiated by an Aza‐Rauhut–Currier Reaction: Facile Entry to Highly Functionalized Tetrahydropyridines
2012
Stereoselective syntheses of α,β-unsaturated γ-amino esters through phosphine-catalyzed γ-umpolung additions of sulfonamides to γ-substituted allenoates
2015
Phosphine-catalyzed domino reaction: an efficient method for the synthesis of highly functionalized spirooxazolines
2012
Chiral phosphine-catalyzed asymmetric allylic alkylation of 3-substituted benzofuran-2(3H)-ones or oxindoles with Morita–Baylis–Hillman carbonates
2012
Recent extensions of the Morita–Baylis–Hillman reaction
2009
Phosphine-catalyzed intramolecular γ-umpolung addition of α-aminoalkylallenic esters: facile synthesis of 3-carbethoxy-2-alkyl-3-pyrrolines
2012
Phosphahelicenes in Asymmetric Organocatalysis: [3+2] Cyclizations of γ‐Substituted Allenes and Electron‐Poor Olefins
2015
Recent advances in the stereoselective synthesis of tetrahydrofurans
2006
Organocatalytic enantioselective desymmetrization of cyclic enonesviaphosphine promoted [3+2] annulations
2010
Phosphine‐Catalyzed [3+2] Cycloaddition Reactions of Azomethine Imines with Electron‐Deficient Alkenes: A Facile Access to Dinitrogen‐Fused Heterocycles
2014
Phosphine-containing Lewis base catalyzed cyclization of benzofuranone type electron-deficient alkenes with allenoates: a facile synthesis of spirocyclic benzofuranones
2013
The Mechanism of the Wacker Reaction: A Tale of Two Hydroxypalladations
2009
Highly Enantioselective [3+2] Annulation of Morita–Baylis–Hillman Adducts Mediated by L ‐Threonine‐Derived Phosphines: Synthesis of 3‐Spirocyclopentene‐2‐oxindoles having Two Contiguous Quaternary Centers
2011
Combining Rhodium and Photoredox Catalysis for CH Functionalizations of Arenes: Oxidative Heck Reactions with Visible Light
2014
Phosphine-catalyzed asymmetric [4+1] annulation of activated α,β-unsaturated ketones with Morita–Baylis–Hillman carbonates: enantioselective synthesis of spirooxindoles containing two adjacent quaternary stereocenters
2014
A computational study of the activation of allenoates by Lewis bases and the reactivity of intermediate adducts
2014
Phosphine-catalyzed domino reaction: a novel sequential [2+3] and [3+2] annulation reaction of γ-substituent allenoates to construct bicyclic[3, 3, 0]octene derivatives
2013
Catalytic Functionalization of Indoles in a New Dimension
2009 Standout
Magical Power of Transition Metals: Past, Present, and Future (Nobel Lecture)
2011 Nobel
Chiral Phosphine Catalyzed Asymmetric Michael Addition of Oxindoles
2012
Carbon–Nitrogen Bond‐Forming Reactions of Dialkyl Azodicarboxylate: A Promising Synthetic Strategy
2008
Molecular Assembly of an Achiral Phosphine and a Chiral Primary Amine: A Highly Efficient Supramolecular Catalyst for the EnantioselectiveMichael Reaction of Aldehydes with Maleimides
2013
The reaction of acyl cyanides with “Huisgen zwitterion”: an interesting rearrangement involving ester group migration between oxygen and nitrogen atoms
2009
Phosphine‐Catalyzed Domino Reactions: A Route to Functionalized Bicyclic Skeletons
2014
Phosphine-catalyzed [4 + 2] annulation and vinylogous addition reactions between 1,4-dien-3-ones and 1,1-dicyanoalkenes
2011
Applications of Chiral Phosphine‐Based Organocatalysts in Catalytic Asymmetric Reactions
2014
Asymmetric [3+2] Cycloadditions of Allenoates and Dual Activated Olefins Catalyzed by Simple Bifunctional N‐Acyl Aminophosphines
2010
Mechanism, Regioselectivity, and the Kinetics of Phosphine‐Catalyzed [3+2] Cycloaddition Reactions of Allenoates and Electron‐Deficient Alkenes
2008
Phosphine-catalyzed [3 + 2] cycloaddition of Morita–Baylis–Hillman carbonates with sulfamate-derived cyclic imines
2013
Discovery of Neuritogenic Compound Classes Inspired by Natural Products
2013
Catalytic [2+2] and [3+2] cycloaddition reactions of allenoates with cyclic ketimines
2011
Palladium‐Catalyzed ortho‐Acylation of Acetanilides with Aldehydes through Direct CH Bond Activation
2011
Expanding the Scope of Enantioselective FerroPHANE‐Promoted [3+2] Annulations with α,β‐Unsaturated Ketones
2009
One step synthesis of benzoxazepine derivatives via a PPh3 catalyzed aza-MBH domino reaction between salicyl N-tosylimines and allenoates
2013
Photoredox‐Initiated α‐Alkylation of Imines through a Three‐Component Radical/Cationic Reaction
2011
Phosphine‐Catalyzed [4+2] Annulations of 2‐Alkylallenoates and Olefins: Synthesis of Multisubstituted Cyclohexenes
2011
Direct use of allylic alcohols in the allylation of sulfonylimidates
2010
Biphenyl‐Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes
2014
Organocatalytic umpolung: N-heterocyclic carbenes and beyond
2012 Standout
Direct transition metal-catalyzed functionalization of heteroaromatic compounds
2007 Standout
Phosphine‐Catalyzed Enantioselective γ‐Addition of 3‐Substituted Oxindoles to 2,3‐Butadienoates and 2‐Butynoates: Use of Prochiral Nucleophiles
2014
Phosphane‐Catalyzed [3+2] Annulation of Allenoates with Aldehydes: A Simple and Efficient Synthesis of 2‐Alkylidenetetrahydrofurans
2009
Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons
2014
Phosphine-catalyzed enantioselective [3 + 2] cycloadditions of γ-substituted allenoates with β-perfluoroalkyl enones
2017
Direct Catalytic Intermolecular α‐Allylic Alkylation of Aldehydes by Combination of Transition‐Metal and Organocatalysis
2006
Enantioselective catalysis and complexity generation from allenoates
2009
Enantioselective One‐Pot Synthesis of α‐Amino Esters by a Phosphine‐Catalyzed [3+2]‐Cycloaddition Reaction
2011
A phosphine-mediated reaction of cyclic 1,2-diones and 3-alkyl allenoates: an efficient protocol for benzannulation applicable to the synthesis of polycyclic aromatic hydrocarbons
2014
Phosphine‐Catalyzed Annulations of 4,4‐Dicyano‐2‐Methylenebut‐3‐enoates with Maleimides and Maleic Anhydride
2014
Phosphine-Catalyzed α-P-Addition on Activated Alkynes: A New Route to P−C−P Backbones
2006
Organopalladium(iv) chemistry
2009
Silicon as a directing group in the phosphine-catalyzed [2 + 3]-cycloaddition of aryl allenones with electron-deficient olefins
2009
Synthesis of Functionalized Cyclopentenes through Catalytic Asymmetric [3+2] Cycloadditions of Allenes with Enones
2006
Stereoselective Phosphine‐Catalyzed Synthesis of Highly Functionalized Diquinanes
2009
The Baylis–Hillman reaction: a novel concept for creativity in chemistry
2011
Tuning Catalysts to Tune the Products: Phosphine‐Catalyzed Aza‐Michael Addition Reaction of Hydrazones with Allenoates
2013
PPh3‐Catalyzed Reactions of Alkyl Propiolates with N‐Tosylimines: A Facile Synthesis of Alkyl 2‐[aryl(tosylimino)methyl]acrylate and an Insight into the Reaction Mechanism
2009
Phosphine-triggered synthesis of functionalized cyclic compounds
2008 Standout
Phosphine-boronates: efficient bifunctional organocatalysts for Michael addition
2012
Advances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs
2013
One-pot formation of fluorescent γ-lactams having an α-phosphorus ylide moiety through three-component α(δ′)-Michael reactions of phosphines with an enyne and N-tosyl aldimines
2013
Bystanding F+ Oxidants Enable Selective Reductive Elimination from High‐Valent Metal Centers in Catalysis
2011
An efficient stereoselective synthesis of 3-spirocyclopentene- and 3-spiropyrazole-2-oxindoles via 1,3-dipolar cycloaddition reaction
2010
Theory-guided design of Brønsted acid-assisted phosphine catalysis: synthesis of dihydropyrones from aldehydes and allenoates
2008
[4+2] Annulation of Vinyl Ketones Initiated by a Phosphine‐Catalyzed Aza‐Rauhut–Currier Reaction: A Practical Access to Densely Functionalized Tetrahydropyridines
2012
Highly Diastereoselective Synthesis of Bicyclo[3.2.1]octenones through Phosphine‐Mediated Condensations of 1,4‐Dien‐3‐ones
2006
Morita–Baylis–Hillman adduct derivatives (MBHADs): versatile reactivity in Lewis base-promoted annulation
2015
An overview of N-heterocyclic carbenes
2014 StandoutNature
Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)‐Catalyzed CH Bond Activation
2013
Recent Advances in the Synthesis of Indole and Quinoline Derivatives through Cascade Reactions
2009
N-heterocyclic carbene-catalyzed reactions of C–C unsaturated bonds
2013
An Organocatalytic [3+2] Cyclisation Strategy for the Highly Enantioselective Synthesis of Spirooxindoles
2010
Bifunctional N‐Acyl‐Aminophosphine‐Catalyzed Asymmetric [4+2] Cycloadditions of Allenoates and Imines
2011
PPh3‐Catalyzed Ring‐Expansion Reactions of Sulfamate‐Derived Cyclic Imines with Acetylenedicarboxylates
2013
Chemoselective phosphine-catalyzed cascade annulations between two different activated alkenes: highly diastereoselective syntheses of polysubstituted cyclohexanes and cyclopentenes
2010
Allenes as Three‐Carbon Units in Catalytic Cycloadditions: New Opportunities with Transition‐Metal Catalysts
2010
Phosphine‐Mediated Domino Benzannulation Strategy for the Construction of Highly Functionalized Multiaryl Skeletons
2012
Phosphine‐Catalyzed [3+2] and [4+3] Annulation Reactions of C,N‐Cyclic Azomethine Imines with Allenoates
2012
Phosphine‐Catalyzed Rauhut–Currier Domino Reaction: A Facile Strategy for the Construction of Highly Functionalized Cyclopentene
2012
PPh3-catalyzed synthesis of dicyano-2-methylenebut-3-enoates as efficient dienes in catalytic asymmetric inverse-electron-demand Diels–Alder reaction
2011
Equilibrium between a vinylogous ylide and a phosphonium dienolate zwitterion: vinylogous Wittig olefination versus vinylogous aldol-type reaction
2010
Phosphine-catalyzed asymmetric [4+1] annulation of Morita–Baylis–Hillman carbonates with dicyano-2-methylenebut-3-enoates
2012
Metal‐Free Intramolecular Carbocyanation of Activated Alkenes: Functionalized Nitriles Bearing β‐Quaternary Carbon Centers
2013
Baylis–Hillman reactions of N-tosyl aldimines and aryl aldehydes with 3-methylpenta-3,4-dien-2-one
2005
Phosphine‐Initiated General‐Base‐Catalyzed Quinolone Synthesis
2014
Intramolecular Organocatalytic [3+2] Dipolar Cycloaddition: Stereospecific Cycloaddition and the Total Synthesis of (±)‐Hirsutene
2003
Abnormal Behaviour of Allenylsulfones under Lu’s Reaction Conditions: Synthesis of Enantiopure Polyfunctionalised Cyclopentenes
2010
Lewis Base Catalysis in Organic Synthesis
2008
Phosphine-Catalyzed Addition/Cycloaddition Domino Reactions of β′-Acetoxy Allenoate: Highly Stereoselective Access to 2-Oxabicyclo[3.3.1]nonane and Cyclopenta[a]pyrrolizine
2015
Selective palladium-mediated synthesis of racemic 4,5-disubstituted 5H-furan-2-ones from 3-ynoic acids and organic halides
1998
Enantioselective allylic substitution of Morita–Baylis–Hillman adducts catalyzed by planar chiral [2.2]paracyclophane monophosphines
2007
Two-directional carbon chain elongation via the consecutive 1,4-addition of allyl malononitrile and the Cope rearrangement on an alkynoate platform
2015
Nucleophilic‐Bisphosphine‐Catalysed One‐Pot Sequential [4+2]/[4+2] Annulation of an Allenoate with Benzylidenepyrazolones
2015
Palladium-Catalyzed, Carboxylic Acid-Assisted Allylic Substitution of Carbon Nucleophiles with Allyl Alcohols as Allylating Agents in Water
2003
A Phosphine‐Catalyzed Regioselective [3+2] Cycloaddition of Ethyl 5,5‐Diarylpenta‐2,3,4‐trienoate with Aromatic Aldehydes and α,β‐Unsaturated Carbonyl Compounds
2014
Ultrasound in Baylis–Hillman reactions with aliphatic and aromatic aldehydes: scope and limitations
2002
Fluoride Ion and Phosphines as Nucleophilic Catalysts: Synthesis of 1,4-Benzothiazepines from Cyclic Sulfenamides
2009
C–H bond functionalization based on metal carbene migratory insertion
2015
Bisphosphine-Catalyzed Mixed Double-Michael Reactions: Asymmetric Synthesis of Oxazolidines, Thiazolidines, and Pyrrolidines
2007
Organocatalytic Reactions of α-Trifluoromethylated Esters with Terminal Alkenes at Room Temperature
2013
α‐Addition of 1,3‐Dicarbonyl Compounds to Acetylenic Ketones Catalyzed by Triphenylphosphine
2005
Highly Enantioselective Regiodivergent Allylic Alkylations of MBH Carbonates with Phthalides
2012
Atom Economy—A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way
1995 Standout
Phosphine-Catalyzed [4 + 2] Annulation of Allenoate with Sulfamate-Derived Cyclic Imines: A Reaction Mode Involving γ′-Carbon of α-Substituted Allenoate
2017
Highly enantioselective synthesis of dihydrocoumarin-fused dihydropyrans via the phosphine-catalyzed [4 + 2] annulation of allenones with 3-aroylcoumarins
2016
Diastereo- and Enantioselective [3 + 2] Cycloaddition Reaction of Morita–Baylis–Hillman Carbonates of Isatins with N-Phenylmaleimide Catalyzed by Me-DuPhos
2012
A promising new catalyst family for enantioselective cycloadditions involving allenes and imines: chiral phosphines with transition metal–CH2–P: linkages
2006
Divergence in the Reactivity between Amine- and Phosphine-Catalyzed Cycloaddition Reactions of Allenoates with Enynals: One-Pot Gold-Catalyzed Synthesis of Trisubstituted Benzofurans from the [3 + 2] Cycloadduct via 1,2-Alkyl Migration and Dehydrogenation
2015
Phosphine catalyzed δ-carbon addition and isomerization of alkynones to ketimines: the preparation of 1,3-diene substituted dihydroquinazolinones and 3-aminooxindoles
2017
Cooperative, Highly Enantioselective Phosphinothiourea Catalysis of Imine−Allene [3 + 2] Cycloadditions
2008
Phosphine-Catalyzed β′-Umpolung Addition of Nucleophiles to Activated α-Alkyl Allenes
2011
PPh3-KOBut–Mediated Cyclization Reaction of β-Ketoesters with Alkynyl Ketones: Synthesis of Functionalized 2-Pyrones
2011
Synthesis of Chiral 2‐Phospha[3]ferrocenophanes and their Behaviour as Organocatalysts in [3+2] Cyclization Reactions
2009
Tandem Three-Component Reactions of Aldehyde, Alkyl Acrylate, and Dialkylmalonate Catalyzed by Ethyl Diphenylphosphine
2012
Novel Phosphine-Catalyzed Zipper Cyclization of Aliphatic Diyne−Dione and Yne−Dione Systems
2002
Phosphite-mediated annulation: an efficient protocol for the synthesis of multi-substituted cyclopropanes and aziridines
2009
Phosphine-Catalyzed [3 + 2] Cycloaddition of Sulfamate-Derived Cyclic Imines with Allenoate: Synthesis of Sulfamate-Fused Dihydropyrroles
2013
Phosphine‐Catalyzed Domino Reactions of Allenoates with N ‐Hydroxyphthalimides: Direct Method to 3 a‐Hydroxyisoxazolo[3,2‐ a ]isoindol‐8(3 a H )‐one Derivatives
2017
Polymer-supported tertiaryphosphine (JJ–TPP) as a green and recyclable organocatalyst for α-addition of carbon nucleophiles to α,β-unsaturated compounds
2007
The tert-Butylsulfinamide Lynchpin in Transition-Metal-Mediated Multiscaffold Library Synthesis
2010
Phosphine-Mediated [4 + 2] Annulation of Bis(enones): A Lewis Base Catalyzed “Mock Diels−Alder” Reaction
2004
Bifunctional‐Phosphine‐Catalyzed Sequential Annulations of Allenoates and Ketimines: Construction of Functionalized Poly‐heterocycle Rings
2016
Chiral Phosphine‐Catalyzed Enantioselective [3+2] Annulation of Morita–Baylis–Hillman Carbonates with Cyclic 1‐Azadienes: Synthesis of Functionalized Cyclopentenes
2016
Enantioselective [4+2] cycloaddition reaction of α,β-unsaturated imine and methyl vinyl ketone catalyzed by chiral phosphine
2015
Phosphine-Catalyzed Enantioselective [4 + 2] Annulation of o-Quinone Methides with Allene Ketones
2017
Cyclizations via Palladium‐Catalyzed Allylic Alkylations [New Synthetic Methods (79)]
1989
Catalytic Enantioselective Cycloaddition with Chiral Lewis Bases
2011
Stereoselective synthesis of planar chiral 2,2′-diarylsubstituted ferrocene derivatives as precursors for new 2-phospha[3]ferrocenophanes
2012
Phosphine-catalyzed [3 + 2] cycloaddition of phthalazinium dicyanomethanides with allenoates: highly efficient synthesis of 1,2,3,10b-tetrahydropyrrolo[2,1-a]phthalazine derivatives
2016
β-Olefination of 2-Alkynoates Leading to Trisubstituted 1,3-Dienes
2011
Lewis Base Effects in the Baylis−Hillman Reaction of Imines with Methyl Vinyl Ketone
2002
Synthesis of 2-azaspiro[4.4]nonan-1-ones via phosphine-catalysed [3+2]-cycloadditions
2005
Phosphine-catalyzed [4+2] annulations of α-aminonitriles with allenoates: Synthesis of functionalized tetrahydropyridines
2016
Phosphine-Catalyzed (4 + 1) Annulation of o-Hydroxyphenyl and o-Aminophenyl Ketones with Allylic Carbonates: Syntheses and Transformations of 3-Hydroxy-2,3-Disubstituted Dihydrobenzofurans and Indolines
2016
Phosphine- and Nitrogen-Containing Lewis Base Catalyzed Highly Regioselective and Geometric Selective Cyclization of Isatin Derived Electron-Deficient Alkenes with Ethyl 2,3-Butadienoate
2011
Wittig Olefination between Phosphine, Aldehyde, and Allylic Carbonate: A General Method for Stereoselective Synthesis of Trisubstituted 1,3-Dienes with Highly Variable Substituents
2010
Phosphine-catalyzed addition of P(O)–H compounds to ethyl phenylpropiolate
2015
Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation
2010
A theoretical study of DABCO and PPh3 catalyzed annulations of allenoates with azodicarboxylate
2016
Activation of Allyl Alcohols as Allyl Cations, Allyl Anions, and Amphiphilic Allylic Species by Palladium
2005
Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations
2015 Standout
Copper-Catalyzed Regio- and Enantioselective Synthesis of Chiral Enol Acetates and β-Substituted Aldehydes
2010 StandoutNobel
Phosphine-catalyzed [3 + 2] and [3 + 3] Annulations of Azomethine Imines with Ethyl 2-Butynoate
2012
Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands
2016
Recent Contributions from the Baylis−Hillman Reaction to Organic Chemistry
2010
Nucleophilic Lewis Base Dependent Addition Reactions of Allenoates with Trifluoromethylated Cyclic Ketimines
2014
Synthesis of α-Methylene-β-Lactams via PPh3-Catalyzed Umpolung Cyclization of Propiolamides
2014
Phosphine-catalyzed [4 + 2] cycloaddition of unsaturated pyrazolones with allenoates: a concise approach toward spiropyrazolones
2015
Nucleophilic polymer-supported tertiaryphosphine organocatalysis: [3+2] annulation reaction of alkyl 2-butynoates with activated alkenes
2014
Dual-reagent organocatalysis with a phosphine and electron-deficient alkene: application to the Henry reaction
2008
Phosphine-catalyzed asymmetric [3 + 2] annulation of chalcones with allenoates for enantioselective synthesis of functionalized cyclopentenes
2015
Highly Enantioselective Synthesis of 3,4-Dihydropyrans through a Phosphine-Catalyzed [4+2] Annulation of Allenones and β,γ-Unsaturated α-Keto Esters
2014
Reactions of Arylaldehydes and N-Sulfonated Imines with Dimethyl Acetylenedicarboxylate Catalyzed by Nitrogen and Phosphine Lewis Bases
2003
Direct allylic substitution of allyl alcohols by carbon pronucleophiles in the presence of a palladium/carboxylic acid catalyst under neat conditions
2004
Assembly of Dimethyl Acetylenedicarboxylate and Phosphanes with Aldehydes Leading to γ‐Lactones Bearing α‐Phosphorus Ylides as Wittig Reagents
2012
An Unexpected Phosphine-Mediated Olefination of Salicylaldehydes with α-Methyl Allenoate
2008
Efficient Ring-Opening Reaction of Epoxides and Aziridines Promoted by Tributylphosphine in Water
2002
Palladium-catalyzed direct cross-coupling reaction between indenes and electron-deficient alkenes
2010
Palladium-Catalyzed Hydrophosphorylation of Allenes Leading to Regio- and Stereoselective Formation of Allylphosphonates
2000
Triphenylphosphine catalyzed formation of functionalized 2‐aminothiophenes
2007
Tunable Phosphine‐Triggered Cascade Reactions of MBH Derivatives and 3‐Acyl‐2H‐chromen‐2‐ones: Highly Selective Synthesis of Diverse Chromenones
2013
Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (−)-Pyrrolines
2014
Catalytic Asymmetric Intramolecular Cascade Reaction for the Construction of Functionalized Benzobicyclo[4.3.0] Skeletons. Remote Control of Enantioselectivity
2010
Screening of chiral phosphines as catalysts for the enantioselective [3+2] annulations of N-tosylimines with allenic esters
2007
Efficient Activation of Aromatic C-H Bonds for Addition to C-C Multiple Bonds
2000 Science
Phosphine-Catalyzed [3 + 2] Cycloaddition of 4,4-Dicyano-2-methylenebut-3-enoates with Benzyl Buta-2,3-dienoate and Penta-3,4-dien-2-one
2013
Phosphine-Catalyzed Sequential [4 + 3] Domino Annulation/Allylic Alkylation Reaction of MBH Carbonates: Efficient Construction of Seven-Membered Heterocycles
2017
Three-Component and Nonclassical Reaction of Phosphines with Enynes and Aldehydes: Formation of γ-Lactones Featuring α-Phosphorus Ylides
2011
Enantioselective Organocatalyzed Formal [4+2] Cycloaddition of Ketimines with Allenoates: Easy Access to a Tetrahydropyridine Framework with a Chiral Tetrasubstituted Stereogenic Carbon Center
2014
Enantioselective [4 + 1]-Annulation of α,β-Unsaturated Imines with Allylic Carbonates Catalyzed by a Hybrid P-Chiral Phosphine Oxide–Phosphine
2017
Phosphine Organocatalysis in the Synthesis of Natural Products and Bioactive Compounds
2012
P-Acylphosphonium salts and their vinyloges — application in synthesis
2010
Enantioselective Synthesis of Spirobarbiturate-Cyclohexenes through Phosphine-Catalyzed Asymmetric [4 + 2] Annulation of Barbiturate-Derived Alkenes with Allenoates
2016
Organocatalytic umpolung annulative dimerization of ynones for the synthesis of 5-alkylidene-2-cyclopentenones
2017
Formation of P-Ylide under Neutral and Metal-Free Conditions: Transformation of Aziridines and Epoxides to Conjugated Dienes In the Presence of Phosphine
2004
Phosphine-catalyzed [4+1] annulation of 2-tosylaminochalcones with allenoates: synthesis of trans-2,3-disubstitued indolines
2015
Understanding and exploiting C–H bond activation
2002 StandoutNature
[3+2] Cycloaddition of Dialkyl (E)‐Hex‐2‐en‐4‐ynedioates to [60]Fullerene by Phosphane‐Promoted Tandem α(δ′)‐Michael Additions
2012
Lewis‐Base‐Catalyzed Annulations of Nitroallylic Acetates as C3 Synthons with Electron‐Deficient Alkenes
2014
Phosphine-catalyzed regioselective Michael addition to allenoates
2015
Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron‐Deficient η5‐Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions
2014
Phosphine-Catalyzed Asymmetric (3+2) Annulations of δ-Acetoxy Allenoates with 2-Naphthols
2017
Intermolecular Additions and Cycloisomerizations by a Pd‐Catalyzed Sequence of an Intramolecular Redox Reaction and an Addition
1992
Mild metal-catalyzed C–H activation: examples and concepts
2016 Standout
Enantioselective Synthesis of Tetrahydropyridines/Piperidines via Stepwise [4 + 2]/[2 + 2] Cyclizations
2017
Phosphine-Catalyzed [4 + 2] Annulation: Synthesis of Cyclohexenes
2007
Nitrogen-containing Heterocycles via Palladium-catalyzed Reaction of Alkynes with Organic Halides or Triflates
2002
Phosphine-Catalyzed [3 + 2] Annulations of γ-Functionalized Butynoates and 1C,3O-Bisnucleophiles: Highly Selective Reagent-Controlled Pathways to Polysubstituted Furans
2011
Catalytic Synthesis of Indoles from Alkynes
2008
Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform
2012
Palladium-Catalyzed Anti-Markovnikov Oxidation of Allylic Amides to Protected β-Amino Aldehydes
2014 StandoutNobel
Phosphine-mediated diverse reactivity of γ-substituted allenoates with aldehydes: syntheses of highly functionalized chromans and (E,E)-1,3-dienes
2010
Iron‐Catalyzed Cross Dehydrogenative Coupling (CDC) of Indoles and Benzylic CH Bonds
2015
Enantioselective Phosphine‐Catalyzed Formal [4+4] Annulation of α,β‐Unsaturated Imines and Allene Ketones: Construction of Eight‐Membered Rings
2017
Diphosphine-Catalyzed Mixed Double-Michael Reaction: A Unified Synthesis of Indolines, Dihydropyrrolopyridines, Benzimidazolines, Tetrahydroquinolines, Tetrahydroisoquinolines, Dihydrobenzo-1,4-oxazines, and Dihydrobenzo-3,1-oxazines
2010
Rh(III)- and Ir(III)-Catalyzed C–H Alkynylation of Arenes under Chelation Assistance
2014
Totally Regio- and Stereoselective Behavior of Mono- and Diactivated Cyclic Alkenes in the Lu Reaction: Synthesis of Enantiopure Functionalized Cyclopentanes
2008
Synthesis and Functionalization of Indoles Through Palladium-catalyzed Reactions
2005 Standout
Phosphine‐Catalyzed [3+2] Annulation of Electron‐Deficient Alkynes with N‐Hydroxyphthalimide: Synthesis of 3a‐Hydroxyisoxazolo[3,2‐a]isoindol‐8(3aH)‐ones
2013
cis-Dihydroxylation and Epoxidation of Alkenes by [Mn2O(RCO2)2(tmtacn)2]: Tailoring the Selectivity of a Highly H2O2-Efficient Catalyst
2005 StandoutNobel
Michael Reaction of Stabilized Carbon Nucleophiles Catalyzed by [RuH2(PPh3)4]
1996
Phosphine-Catalyzed Synthesis of 1,3-Dioxan-4-ylidenes
2005
Phosphine Organocatalysis
2018 Standout
Divergent Phosphine‐Catalyzed [2+4] or [3+2] Cycloaddition Reactions of γ‐Substituted Allenoates with Oxadienes
2014
A Highly Nucleophilic Multifunctional Chiral Phosphane‐Catalyzed Asymmetric Intramolecular Rauhut–Currier Reaction
2012
Phosphine-Catalyzed Domino Benzannulation: An Efficient Method to Construct Biaryl Skeletons
2013
Catalytic Diastereoselective Synthesis of Diquinanes from Acyclic Precursors
2003
Total Synthesis of α-Pyrone Meroterpenoids, Novel Bioactive Microbial Metabolites
2005 StandoutNobel
Cyclopenta[b]annulation of Heteroarenes by Organocatalytic γ′[C(sp3)−H] Functionalization of Ynones
2016
Theoretical mechanistic study of TangPhos-catalyzed asymmetric γ addition of thiols to allenoates
2011
PPh3-Catalyzed Domino Reaction: A Facile Method for the Synthesis of Chroman Derivatives
2009
A convenient synthesis of γ-(Z)-alkylidene butenolides
1993
An Easy, Stereoselective Synthesis of Hexahydroisoindol‐4‐ones under Phosphine Catalysis
2011
Phosphine-Catalyzed Highly Enantioselective [3 + 3] Cycloaddition of Morita–Baylis–Hillman Carbonates with C,N-Cyclic Azomethine Imines
2015
Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones
2001 StandoutNobel
Palladium-Catalyzed Allylic Amination of Allylic Alcohols with Tin(II) Chloride and Triethylamine
1995
Amine-Catalyzed Coupling of Allenic Esters to α,β-Unsaturated Carbonyls
2003
The Contribution Made by Triphenylphosphane in the Putative Catalysis by Ruthenium Species in Conjugate Additions of β-Dicarbonyl Compounds
2001
Facile Synthesis of Spirooxindole‐Cyclohexenes via Phosphine‐Catalyzed [4 + 2] Annulation of α‐Substituted Allenoates
2017
Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts
2012
Chiral phosphine-mediated intramolecular [3 + 2] annulation: enhanced enantioselectivity by achiral Brønsted acid
2017
Stereoselective synthesis of cyclopentanone-fused benzosultams through Tomita zipper cyclization
2016
Chiral Phosphine-Catalyzed Enantioselective Construction of γ-Butenolides Through Substitution of Morita−Baylis−Hillman Acetates with 2-Trimethylsilyloxy Furan
2008
Tricyclohexylphosphine-Catalyzed Cycloaddition of Enynoates with [60]Fullerene and the Application of Cyclopentenofullerenes as n-Type Materials in Organic Photovoltaics
2015
Stereo- and Chemoselective Cross-Coupling between Two Electron-Deficient Acrylates: An Efficient Route to (Z,E)-Muconate Derivatives
2015
Highly Chemoselective Rauhut–Currier Reaction between Maleimides and Enones and Dual Phosphine-Mediated One-Pot Synthesis of Bicyclic and Polycyclic Skeletons
2013
Halide-Free Dehydrative Allylation Using Allylic Alcohols Promoted by a Palladium−Triphenyl Phosphite Catalyst
2004
Nucleophilic Phosphine Organocatalysis
2004 Standout
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
nBu3P-Catalyzed Desulfonylative [3 + 2] Cycloadditions of Allylic Carbonates with Arylazosulfones to Pyrazole Derivatives
2015
Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups
2014
Synthesis of novel conformationally restricted L-glutamate analogues
1997
The Atom Economy—A Search for Synthetic Efficiency
1991 StandoutScience
PPh3-catalyzed synthesis of multifunctional vinylesters from terminal alkynoates and aromatic aldehydes
2008
Synthesis of Highly Functionalized γ-Butyrolactones from Activated Carbonyl Compounds and Dimethyl Acetylenedicarboxylate
1996
Heterocyclic Spiranes and Dispiranes via Enantioselective Phosphine‐Catalyzed [3+2] Annulations
2012
Novel Pd(II)- and Pt(II)-Catalyzed Regio- and Stereoselective trans-Hydroarylation of Alkynes by Simple Arenes
2000
Synthesis and characterization of a cyclic vinylpalladium(ii) complex: vinylpalladium species as the possible intermediate in the catalytic direct olefination reaction of enamide
2011
Michael additions catalyzed by phosphines. An overlooked synthetic method
2005
Phosphine-mediated annulation of N-protected imines with DEAD
2011
Highly Efficient Epoxidation of Olefins Using Aqueous H2O2 and Catalytic Methyltrioxorhenium/Pyridine: Pyridine-Mediated Ligand Acceleration
1997 StandoutNobel
Synthesis of 3,3′-Spirocyclic Oxindoles via Phosphine Catalyzed [4 + 2] Cyclizations
2013
Catalytic Asymmetric Synthesis of Oxindoles Bearing a Tetrasubstituted Stereocenter at the C‐3 Position
2010
Mild and Efficient Synthesis of (Z)-α-Chloroalkylidene-β-lactones via the PdCl2-Catalyzed Cyclocarbonylation of 2-Alkynols
2003
Palladium-Catalyzed Alkynylation
2003
Enantioselective Allylic Amination of Morita‐Baylis‐Hillman Acetates Catalyzed by Chiral Thiourea‐Phosphine
2015
Facile synthesis of highly functionalized six-membered heterocycles via PPh3-catalyzed [4+2] annulations of activated terminal alkynes and hetero-dienes: scope, mechanism, and application
2010
A Formal [3 + 3] Cycloaddition Approach to Natural‐Product Synthesis
2004
Recent developments in the asymmetric organocatalytic Morita−Baylis−Hillman reaction
2017
A DFT study on PBu3-catalyzed intramolecular cyclizations of N-allylic substituted α-amino nitriles for the formation of functionalized pyrrolidines: mechanisms, selectivities, and the role of catalysts
2016
Chiral Counteranions in Asymmetric Transition-Metal Catalysis: Highly Enantioselective Pd/Brønsted Acid-Catalyzed Direct α-Allylation of Aldehydes
2007 StandoutNobel
Construction of Complex 1,3-Cyclohexadienes via Phosphine-Catalyzed (4 + 2) Annulations of δ-Acetoxy Allenoates and Ketones
2017
PPh3-Catalyzed (3 + 3) Annulations of 5-Acetoxypenta-2,3-dienoate with 1C,3O-Bisnucleophiles: Facile Entry to Stable Monocyclic 2H-Pyrans
2012
PPh3-Catalyzed [3 + 2] Spiroannulation of 1C,3N-Bisnucleophiles Derived from Secondary β-Ketoamides with δ-Acetoxy Allenoate: A Route to Functionalized Spiro N-Heterocyclic Derivatives
2017
Transition Metal-Mediated Cycloaddition Reactions
1996 Standout
Ph3P promoted one-pot synthesis of dialkyl 2-(2-oxopyridin-1(2H)-yl)but-2-enedioates from a reaction of 2-hydroxypyridine and dialkyl acetylenedicarboxylates
2007
Reduction of Activated Carbonyl Groups Using Alkylphosphanes as Reducing Agents: A Mechanistic Study
2012
Multifunctional Chiral Phosphine Organocatalysts in Catalytic Asymmetric Morita−Baylis−Hillman and Related Reactions
2010
Highly Enantioselective Syntheses of Functionalized α-Methylene-γ-butyrolactones via Rh(I)-catalyzed Intramolecular Alder Ene Reaction: Application to Formal Synthesis of (+)-Pilocarpine
2002
Quantum chemical investigation on the reaction mechanism of tertiary phosphines with unsaturated carboxylic acids: An insight into kinetic data
2012
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N‐Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center
2014
2-Phospha[3]ferrocenophanes with Planar Chirality: Synthesis and Use in Enantioselective Organocatalytic [3 + 2] Cyclizations
2008
Catalyst‐Controlled Switch in Chemo‐ and Diastereoselectivities: Annulations of Morita–Baylis–Hillman Carbonates from Isatins
2016
Recent Advances in Organocatalytic Asymmetric Morita–Baylis–Hillman/aza-Morita–Baylis–Hillman Reactions
2013
Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes
2014
Bifunctional Phosphine-Catalyzed Domino Reaction: Highly Stereoselective Synthesis of cis-2,3-Dihydrobenzofurans from Salicyl N-Thiophosphinyl Imines and Allenes
2008
Quantum Mechanical Investigations of Organocatalysis: Mechanisms, Reactivities, and Selectivities
2011
Reaction Mechanism of Phosphane‐Catalyzed [4+2] Annulations between α‐Alkylallenoates and Activated Alkenes: A Computational Study
2012
Highly Chemo- and Regioselective Thiocarbonylation of Conjugated Enynes with Thiols and Carbon Monoxide Catalyzed by Palladium Complexes: An Efficient and Atom-Economical Access to 2-(Phenylthiocarbonyl)-1,3-dienes
1999
Phosphine-catalyzed domino reactions of alkynyl ketones with sulfonylhydrazones: construction of diverse pyrazoloquinazoline derivatives
2016
Powerful Amino Acid Derived Bifunctional Phosphine Catalysts Bearing a Hydrogen Bond Donor in Asymmetric Synthesis
2013
Phosphine triggered [3+2] allenoate–acrylate annulation: a mechanistic enlightenment
2007
Highly Regio- and Stereoselective Acylboration, Acylsilation, and Acylstannation of Allenes Catalyzed by Phosphine-Free Palladium Complexes: An Efficient Route to a New Class of 2-Acylallylmetal Reagents
2003
Synthesis of Functionalized Chromans by PnBu3-Catalyzed Reactions of Salicylaldimines and Salicylaldehydes with Allenic Ester
2010
Palladium-Catalyzed Oxidation of Unsaturated Hydrocarbons Using Molecular Oxygen
2012
Regiodivergent Enantioselective γ-Additions of Oxazolones to 2,3-Butadienoates Catalyzed by Phosphines: Synthesis of α,α-Disubstituted α-Amino Acids and N,O-Acetal Derivatives
2015
Synthesis of quaternary carbon centered chromans from the reactions of ethyl 2-(2-hydroxyaryl)-2-oxoacetates with allenic ester or allenic sulfone catalyzed by tertiary phosphine and SPTS
2012
Stable Tetravalent Phosphonium Enolate Zwitterions
2007
PBu3-Mediated Vinylogous Wittig Reaction of α-Methyl Allenoates with Aldehydes and Mechanistic Investigations
2011
Phosphine-Catalyzed [4 + 2] Annulation of γ-Substituent Allenoates: Facile Access to Functionalized Spirocyclic Skeletons
2013
Tertiary Amine-Catalyzed Chemoselective and Asymmetric [3 + 2] Annulation of Morita–Baylis–Hillman Carbonates of Isatins with Propargyl Sulfones
2011
Triphenylphosphine-Catalyzed Nucleophilic α-Addition to Alkyl Propiolates Synthesis of α-Substituted Alkyl Acrylates
2002
Diversity through phosphine catalysis identifies octahydro-1,6-naphthyridin-4-ones as activators of endothelium-driven immunity
2011
The Oxidative Annulation of Tertiary Benzyl Alcohols with Internal Alkynes using an (Electron‐Deficient η5‐Cyclopenta‐ dienyl)Rhodium(III) Catalyst under Ambient Conditions
2014
Phosphine-Catalyzed Sequential [2 +3] and [3 + 2] Annulation Domino Reaction of γ-Benzyl-Substituted Allenoates with α,β-Unsaturated Ketimines To Construct aza-Bicyclo[3,3,0]octane Derivatives
2014
Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups
2015
Core-Structure-Motivated Design of a Phosphine-Catalyzed [3 + 2] Cycloaddition Reaction: Enantioselective Syntheses of Spirocyclopenteneoxindoles
2011
Catalytic Intramolecular Formal [3 + 2] Cycloaddition for the Synthesis of Benzobicyclo[4.3.0] Compounds
2009
Efficient Palladium‐Catalyzed Oxidative Indolation of Allylic Compounds with DDQ via sp3 CH Bond Activation and Carbon‐Carbon Bond Formation Under Mild Conditions
2009
Phosphine-Catalyzed Enantioselective Intramolecular [3+2] Annulations To Generate Fused Ring Systems
2015
Use of a New Spirophosphine To Achieve Catalytic Enantioselective [4 + 1] Annulations of Amines with Allenes To Generate Dihydropyrroles
2015
Highly regio- and stereoselective PdCl2(MeCN)2-catalyzed cross coupling of 1,2-allenylic sulfoxides with allyl bromide
2004
Phosphine‐Catalyzed Diastereoselective [3 + 3] Annulation of Morita–Baylis–Hillman Carbonates with C,N‐Cyclic Azomethine Imines
2017
Phosphine-Mediated Stereoselective Reductive Cyclopropanation of α-Substituted Allenoates with Aromatic Aldehydes
2010
Studies on the asymmetric, phosphine-promoted [3+2] annulations of allenic esters with 2-aryl-1,1-dicyanoalkenes
2010
Efficient organocatalysts derived from simple chiral acyclic amino acids in asymmetric catalysis
2011
N-Heterocyclic Carbene-Catalyzed Reaction of Chalcones and Enals via Homoenolate: an Efficient Synthesis of 1,3,4-Trisubstituted Cyclopentenes
2006
Phosphine‐Catalyzed Asymmetric [4+2] Annulation of Vinyl Ketones with Oxindole‐Derived α,β‐Unsaturated Imines: Enantioselective Syntheses of 2′,3′‐Dihydro‐1′H‐spiro[indoline‐3,4′‐pyridin]‐2‐ones
2013
An Unexpected Phosphine-Catalyzed [3 + 2] Annulation. Synthesis of Highly Functionalized Cyclopentenes
2008
New synthesis of a selective estrogen receptor modulator using an enatioselective phosphine-mediated 2+3 cycloaddition
2013
Phosphine catalysed (5 + 1) annulation of ynone/cinnamates with primary amines
2017
Phosphine-Catalyzed Asymmetric (3 + 2) Annulations of δ-Acetoxy Allenoates with β-Carbonyl Amides: Enantioselective Synthesis of Spirocyclic β-Keto γ-Lactams
2017
New Access to Trisubstituted 3-Pyrrolines under Phosphine Catalysis
2009
Diastereoselective synthesis of cyclopentene spiro-rhodanines containing three contiguous stereocenters via phosphine-catalyzed [3 + 2] cycloaddition or one-pot sequential [3 + 2]/[3 + 2] cycloaddition
2016
Asymmetric Formation of Quaternary Carbon Centers Catalyzed by Novel Chiral 2,5-Dialkyl-7-phenyl-7-phosphabicyclo[2.2.1]heptanes
1998
Phosphine-Catalyzed Enantioselective [4 + 3] Annulation of Allenoates with C,N-Cyclic Azomethine Imines: Synthesis of Quinazoline-Based Tricyclic Heterocycles
2016
Phosphine/Palladium-Catalyzed Syntheses of Alkylidene Phthalans, 3-Deoxyisoochracinic Acid, Isoochracinic Acid, and Isoochracinol
2012
Organocatalytic and Electrophilic Approach to Oxindoles with C3-Quaternary Stereocenters
2010
Preparation of Chiral Multifunctional Thiourea–Phosphanes and Synthesis of Chiral Allylic Phosphites and Phosphane Oxides through Asymmetric Allylic Substitution Reactions of Morita–Baylis–Hillman Carbonates
2011
Asymmetric Construction of Functionalized Bicyclic Imides via [3 + 2] Annulation of MBH Carbonates Catalyzed by Dipeptide-Based Phosphines
2012
Regio- and diastereoselective construction of 1′,2′-(dihydrospiro[indoline-3,3′-pyrrol]-2′-yl)acrylates through phosphine-catalyzed [4 + 1] annulation of Morita–Baylis–Hillman carbonates with oxindole-derived α,β-unsaturated imines
2015
Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones
2015
Mechanistic Aspects of the Phosphine-Catalyzed Isomerization of Allenic Sulfones to 2-Arylsulfonyl 1,3-Dienes
2015
Ruthenium-Catalyzed Reactions for Organic Synthesis
1998
Highly Stereoselective α-Hydroxyalkylation/Chlorination of α,β-Acetylenic Ketones—An Efficient Approach to β-Halogeno Baylis–Hillman Adducts
2000
Chiral bifunctional ferrocenylphosphine catalyzed highly enantioselective [3 + 2] cycloaddition reaction
2015
Enantioselective Phosphine-Catalyzed Allylic Alkylations of mix-Indene with MBH Carbonates
2017
Phosphine‐Catalyzed [4+2] Annulation: Synthesis of Ethyl 6‐Phenyl‐1‐Tosyl‐1,2,5,6‐Tetrahydropyridine‐3‐Carboxylate
2009
N‐Heterocyclic Carbene‐Catalyzed Reaction of Chalcones and Enals via Homoenolate: An Efficient Synthesis of 1,3,4‐Trisubstituted Cyclopentenes.
2006
Polymeric tertiaryphosphine as a green and recyclable organocatalyst for stereoselective isomerization reaction
2005
An Unexpected Role of a Trace Amount of Water in Catalyzing Proton Transfer in Phosphine-Catalyzed (3 + 2) Cycloaddition of Allenoates and Alkenes
2007
A Ru-Catalyzed Three-Component Addition To Form 1,5-Diketones
1997
Phosphine-catalyzed [4 + 3] cycloaddition reaction of aromatic azomethine imines with allenoates
2015
Recent advances in stoichiometric phosphine-mediated organic synthetic reactions
2013
Phosphine-Catalyzed [4 + 1] Annulation between α,β-Unsaturated Imines and Allylic Carbonates: Synthesis of 2-Pyrrolines
2011
Lu's [3 + 2] cycloaddition of allenes with electrophiles: discovery, development and synthetic application
2017
Phosphine-Catalyzed Synthesis of 3,3-Spirocyclopenteneoxindoles from γ-Substituted Allenoates: Systematic Studies and Targeted Applications
2013
Tributylphosphine-catalyzed ring-opening reaction of epoxides and aziridines with acetic anhydride
2003
Highly regio- and diastereoselective construction of spirocyclopenteneoxindole phosphonates through a phosphine-catalyzed [3 + 2] annulation reaction
2014
Discovery of a Phosphine-Mediated Cycloisomerization of Alkynyl Hemiketals: Access to Spiroketals and Dihydropyrazoles via Tandem Reactions
2012
Phosphine Catalyst-Controlled Cycloaddition or Dienylation Reactions of Trifluoromethyl Aryl Ketones with Bis-Substituted Allenoates
2013
Phosphine-Mediated Reaction of 3-Alkyl Allenoates and Diaryl 1,2-Diones: Efficient Diastereoselective Synthesis of Fully Substituted Cyclopentenones
2013
Stereoselective Synthesis of 1,2,3,4-Tetrasubstituted Dienes from Allenoates and Aldehydes: An Observation of Phosphine-Induced Chemoselectivity
2010
Methyltrioxorhenium as Catalyst of a Novel Aldehyde Olefination
1991
Engaging Allene‐Derived Zwitterions in an Unprecedented Mode of Asymmetric [3+2]‐Annulation Reaction
2016
Probing Phosphane‐Mediated [2+1] Annulation Reactions
2010
Phosphine-Catalyzed Annulation Reactions of 2-Butynoate and α-Keto Esters: Synthesis of Cyclopentene Derivatives
2014
Triphenylphosphine‐Catalyzed Michael Addition of Alcohols to Acrylic Compounds
2007
Lewis base-catalyzed diastereoselective [3 + 2] cycloaddition reaction of nitrones with electron-deficient alkenes: an access to isoxazolidine derivatives
2017
Phosphine-catalyzed enantioselective [3+2] annulations of 2,3-butadienoates with imines
2006
Phosphine-catalyzed formal vinylogous aldol reaction of γ-methyl allenoates with aldehydes: easy access to 1,3-dioxanes and dienols
2013
Phosphine-Catalyzed Synthesis of Highly Functionalized Coumarins
2007
Tunable Phosphine‐Mediated Domino Reaction: Selective Synthesis of 2,3‐Dihydrofurans and Biaryls
2012
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
Convenient Synthesis of Triphenylphosphanylidene Spiro[cyclopentane-1,3′-indolines] and Spiro[cyclopent[2]ene-1,3′-indolines] via Three-Component Reactions
2014
Phosphane‐Catalyzed [3+3] Annulation of C,N‐Cyclic Azomethine Imines with Ynones: A Practical Method for Tricyclic Dinitrogen‐Fused Heterocycles
2016
Lewis base-catalyzed divergent isomerizations of 5-hydroxyl-2,3-dienoate
2013
Palladium-Catalyzed Etherification of Allyl Alcohols Using Phenols in the Presence of Titanium(IV) Isopropoxide
1997
Phosphine-Catalyzed Tandem Reaction of Allenoates with Nitroalkenes
2010
Phosphine-Catalyzed Formation of Carbon−Sulfur Bonds: Catalytic Asymmetric Synthesis of γ-Thioesters
2010
Allenes as building blocks in heterocyclic chemistry
2011
Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings
2015
Mild and Efficient Ir(III)-Catalyzed Direct C–H Alkynylation of N-Phenoxyacetamides with Terminal Alkyne
2015
Alkyne Elementometalation−Pd-Catalyzed Cross-Coupling. Toward Synthesis of All Conceivable Types of Acyclic Alkenes in High Yields, Efficiently, Selectively, Economically, and Safely: “Green” Way
2010 StandoutNobel
Phosphine‐Catalyzed Direct δ‐Carbon Addition of Alkynones to Electron‐Deficient Carbonyl‐Group‐Containing Compounds: Preparation of Conjugated Dienes
2016
Enantioselective Construction of All‐Carbon Quaternary Stereogenic Centers by Using Phosphine Catalysis
2017
Enantioselective [3 + 2] Cycloaddition of Allenes to Acrylates Catalyzed by Dipeptide-Derived Phosphines: Facile Creation of Functionalized Cyclopentenes Containing Quaternary Stereogenic Centers
2011
aza-Baylis−Hillman Reaction
2009
Catalytic Diastereoselective Synthesis of Diquinanes from Acyclic Precursors.
2003
Tunable regiodivergent phosphine-catalyzed [3 + 2] cycloaddition of alkynones and trifluoroacetyl phenylamides
2017
Phosphine-Catalyzed Domino Reaction: Highly Stereoselective Synthesis of trans-2,3-Dihydrobenzofurans from Salicyl N-Thiophosphinyl Imines and Allylic Carbonates
2010
Tributylphosphine: A Remarkable Promoting Reagent for the Ring-Opening Reaction of Aziridines
2002
Recent Advances in Efficient and Selective Synthesis of Di-, Tri-, and Tetrasubstituted Alkenes via Pd-Catalyzed Alkenylation−Carbonyl Olefination Synergy
2008 StandoutNobel
Phosphine-Catalyzed Cascade [3 + 2] Cyclization−Allylic Alkylation, [2 + 2 + 1] Annulation, and [3 + 2] Cyclization Reactions between Allylic Carbonates and Enones
2011
1,3,5‐Triaza‐7‐phosphaadamantane (PTA): A Practical and Versatile Nucleophilic Phosphine Organocatalyst
2007
A convenient method for the preparation of α-vinylfurans by phosphine-initiated reactions of various substituted enynes bearing a carbonyl group with aldehydes
2004
Use of Allenylphosphonates as New Substrates for Phosphane‐Catalyzed [3+2] and [4+2] Annulations
2008
The Cinchona Primary Amine-Catalyzed Asymmetric Epoxidation and Hydroperoxidation of α,β-Unsaturated Carbonyl Compounds with Hydrogen Peroxide
2013 StandoutNobel
Enantioselective Synthesis of Highly Functionalized Trifluoromethyl‐Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita–Baylis–Hillman Carbonates with Trifluoroethylidenemalonates Catalyzed by Multifunctional Thiourea‐Phosphines
2012
Phosphane‐Catalyzed [4+2] Annulation of Allenoates with Ketimines: Synthesis of Sultam‐Fused Tetrahydropyridines
2012
Phosphine-mediated enantioselective synthesis of carbocycles and heterocycles
2016
Three-Component Coupling Catalyzed by Phosphine: Preparation of α-Amino γ-Oxo Acid Derivatives
2012
Phosphane‐Catalyzed Umpolung Addition Reaction of Nucleophiles to Ethyl 2‐Methyl‐2,3‐butadienoate
2011
Chemoselective Reduction of Isatin‐Derived Electron‐Deficient Alkenes Using Alkylphosphanes as Reduction Reagents
2011
Intermolecular Dehydrogenative Heck Reactions
2011
Palladium-Catalyzed Direct Cross-Coupling Reaction of Glycals with Activated Alkenes
2011
Palladium/Brønsted Acid‐Catalyzed α‐Allylation of Aldehydes with Allylic Alcohols
2011 StandoutNobel
Intermolecular Coupling Reaction of Cyclic Amines and Alkenes Catalyzed by a Ruthenium-Hydride Complex (PCy3)2(CO)RuHCl
2004
Allylation of Carbon Pronucleophiles with Alkynes in the Presence of Palladium/Acetic Acid Catalyst
2004
A Stereoselective Synthesis of α-(1-Hydroxyalkyl)-β-Substituted Acrylic Acid Esters
2000
Phosphine catalyzed aldol reaction between ketene silyl acetals and aldehydes: nucleophilic O–Si and C–Si bond cleavage by phosphines
2000
Phosphine-catalyzed [3 + 2] and [4 + 2] annulation reactions of ynones with barbiturate-derived alkenes
2017
Phosphine-Catalyzed Annulation of Thioamides and 2-Alkynoates: A New Synthesis of Thiazolines
2002
Stereoselective formation of tertiary and quaternary carbon centers via inverse conjugate addition of carbonucleophiles to allenic esters
2010
C−C, C−O, C−N Bond Formation on sp2 Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents
2007
Synthesis of fluorinated 3-pyrrolines and pyrroles via [3+2] annulation of N-aryl fluorinated imines with allenoates catalyzed by phosphine
2016
Catalytic Coupling of Haloolefins with Anilides
2005
Synthesis of Isocoumarins and α-Pyrones via Palladium-Catalyzed Annulation of Internal Alkynes
1999
Tributylphosphine as a superior catalyst for the α-C-addition of 1,3-dicarbonyl compounds to electron-deficient alkynes
2005
Divergent Reactivity in Amine- and Phosphine-Catalyzed C–C Bond-Forming Reactions of Allenoates with 2,2,2-Trifluoroacetophenones
2011
Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis
2015
Catalytic Asymmetric Total Synthesis of (−)-Actinophyllic Acid
2016
An efficient approach to H-pyrazolo[5,1-a]isoquinolines via a silver triflate-catalyzed reaction of N′-(2-alkynylbenzylidene)hydrazide with allenoate
2012
PPh3-catalyzed ylide cyclization for the controllable synthesis of benzobicyclo[4.3.0] compounds: base effects and scope
2007
PPh2Me-Mediated Tandem Reaction of 2-Alkyl-2,3-butadienoates with Isothiocyanates: Formation of 2-Aminothiophenes
2011
Alcohol-Assisted Phosphine Catalysis: One-Step Syntheses of Dihydropyrones from Aldehydes and Allenoates
2008
Highly Efficient and Regioselective Allylation with Allylic Alcohols Catalyzed by [Mo3S4Pd(η3-allyl)] Clusters
2010
Palladium catalyzed cyclization reactions of acetylenic lactams
2001
Transition metal-catalyzed C–H functionalization of N-oxyenamine internal oxidants
2014
A facile synthesis of 4-methylene-1,3-oxazolidines from γ-hydroxybutynoate and N-tosylimines
2009
Enantioselective synthesis of spirocyclic cyclopentenes: asymmetric [3+2] annulation of 2-arylideneindane-1,3-diones with MBH carbonates derivatives catalyzed by multifunctional thiourea–phosphines
2012
Direct Ortho-Acetoxylation of Anilides via Palladium-Catalyzed sp2 C−H Bond Oxidative Activation
2008
Regioselective and diastereoselective phosphine-catalysed [3+2] cycloadditions to 5-methylenehydantoins: reversal of regioselectivity using chiral N-2-butynoyl-(4S)-benzyloxazolidinone
2002
Advances in the Baylis–Hillman reaction-assisted synthesis of cyclic frameworks
2008 Standout
Application of a New Chiral Phosphepine to the Catalytic Asymmetric Synthesis of Highly Functionalized Cyclopentenes That Bear an Array of Heteroatom-Substituted Quaternary Stereocenters
2011
Lewis Base Promoted Intramolecular Acylcyanation of α-Substituted Activated Alkenes: Construction of Ketones Bearing β-Quaternary Carbon Centers
2012
Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis
2004 Standout
Annulation Reactions of Allene-Derived 1,3-Dipole with 3-Substituted-Chromones: Unusual Recognition of 4π-Component in 3-(N-Aryliminomethyl)chromones through [4 + 3] Annulation
2000
Enantioselective [3 + 2]-Cycloadditions Catalyzed by a Protected, Multifunctional Phosphine-Containing α-Amino Acid
2007
Asymmetric Catalysis via Cyclic, Aliphatic Oxocarbenium Ions
2017 StandoutNobel
Enantioselective synthesis of α-methylene-γ-butyrolactones using chiral Pd(II)-SPRIX catalyst
2003
A multi-pronged mechanistic study of the phosphine-mediated conjugate addition of an alcohol to an acetylenic ester
2014
Redox Cycloisomerization Approach to 1,2-Dihydropyridines
2015
Phosphine-Catalyzed Annulations of Azomethine Imines: Allene-Dependent [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] Pathways
2011
Enantioselective Binaphthophosphepine‐Promoted [3+2] Annulations of N‐Ts‐ and N‐DPP‐Imines with Allenoates and 2‐Butynoates
2008
Palladium-Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air
2008
Advances in Annulation Reactions Initiated by Phosphorus Ylides Generated in situ
2016
Synthesis of cyclopentenyl and cyclohexenyl ketones via [3+2] and [4+2] annulations of 1,2-allenic ketones
2013
Phosphine-catalyzed regioselective heteroaromatization between activated alkynes and isocyanides leading to pyrroles
2005
Phosphine‐Mediated Dimerization of Conjugated Ene‐Yne Ketones: Stereoselective Construction of Dihydrobenzofurans
2017
Phosphine‐Catalyzed Regioselective and Stereoselective Hydrohalogenation Reaction of 2‐(1‐Alkynyl)‐2‐alken‐1‐ones: Synthesis of 2‐Halo‐1,3‐dienes
2015
[4 + 3] Cycloadditions with Bromo-Substituted Morita–Baylis–Hillman Adducts of Isatins and N-(ortho-Chloromethyl)aryl Amides
2015
Catalytic and selective conversion of (Z)-2-en-4-ynoic acids to either 2H-pyran-2-ones in the presence of ZnBr2 or (Z)-5-alkylidenefuran-2(5H)-ones in the presence of Ag2CO3
2002
Rhodium(III)‐Catalyzed Amidation of Unactivated C(sp3)H Bonds
2015
Phosphine-Catalyzed [2 + 4] Annulation of Allenoates with Thiazolone-Derived Alkenes: Synthesis of Functionalized 6,7-Dihydro-5H-pyrano[2,3-d]thiazoles
2016
Phosphorus‐Containing Lewis Base Catalyzed Cascade Reactions of Isatin‐Derived Oximes with Allenic Esters and Further Transformations
2012
Rh(III)-Catalyzed Cyclopropanation Initiated by C–H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes
2014
Catalyst-controlled regioselectivity in phosphine catalysis: the synthesis of spirocyclic benzofuranones via regiodivergent [3 + 2] annulations of aurones and an allenoate
2017
Enantioselective synthesis of 3-fluoro-3-allyl-oxindoles via phosphine-catalyzed asymmetric γ-addition of 3-fluoro-oxindoles to 2,3-butadienoates
2015
Pd(II)-Catalyzed ortho-Trifluoromethylation of Arenes Using TFA as a Promoter
2010
Intra/Intermolecular Direct Allylic Alkylation via Pd(II)-Catalyzed Allylic C−H Activation
2008
Aza‐Baylis–Hillman Reactions and Their Synthetic Applications
2007
Phosphine-catalyzed [4+2] cycloaddition of sulfamate-derived cyclic imines with allenoates: synthesis of sulfamate-fused tetrahydropyridines
2013
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Asymmetric Carbon−Carbon Bond Formation γ to a Carbonyl Group: Phosphine-Catalyzed Addition of Nitromethane to Allenes
2009
Highly enantioselective [4 + 2] annulations catalyzed by amino acid-based phosphines: Synthesis of functionalized cyclohexenes and 3-spirocyclohexene-2-oxindoles
2012
Access to 2′,3′-dihydro-1′H-spiro[indoline-3,4′-pyridin]-2-ones via amino acid derived phosphine-catalyzed asymmetric [4+2] annulation with easily available oxindole-derived α,β-unsaturated imines
2014
Phosphines catalyzed nucleophilic addition of azoles to allenes: synthesis of allylazoles and indolizines
2006
Activation of olefins via asymmetric Brønsted acid catalysis
2018 StandoutScienceNobel
Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes
2004 Standout
Phosphine-Catalyzed [3 + 3]-Domino Cycloaddition of Ynones and Azomethine Imines To Construct Functionalized Hydropyridazine Derivatives
2016
Pd(II)-Catalyzed Coupling Cyclization of 2,3-Allenoic Acids with Allylic Halides. An Efficient Methodology for the Synthesis of β-Allylic Butenolides
2003
Synthesis of β-iodo-α-(hydroxyalkyl)acrylates: a convenient and stereoselective reaction
2002
Phosphine-Catalyzed Domino Reaction: An Efficient Method for the Synthesis of Bicyclo[3.2.0]heptenes Skeleton
2013
Applications of Chiral Thiourea‐Amine/Phosphine Organocatalysts in Catalytic Asymmetric Reactions
2016
Phosphine-Catalyzed Asymmetric Synthesis of α-Quaternary Amine via Umpolung γ-Addition of Ketimines to Allenoates
2017
Phosphine catalysis of allenes with electrophiles
2014
Construction of pyrazolo[5,1-a]isoindol-8(3aH)-one derivatives via phosphine-catalyzed cyclization of electron-deficient alkynes and N-amino substituted phthalimide
2015
Phosphine‐mediated Highly Enantioselective Spirocyclization with Ketimines as Substrates
2016
Asymmetric Construction of Highly Functionalized Spirobarbiturate‐Cyclopentenes through Chiral Phosphine‐Catalyzed [3+2] Annulation of Morita–Baylis–Hillman Carbonates with Barbiturate‐Derived Alkenes
2016
Microwave-assisted organocatalysis: phosphine-mediated Tomita Zipper cyclization affording functionalized spirooxindole
2016
Ruthenium-Catalyzed Cycloaddition of Alkynes and Organic Azides
2005 StandoutNobel
Palladium-catalyzed synthesis of stereodefined 3-[(1,1-unsymmetrically disubstituted)methylidene]isobenzofuran-1(3H)-ones and stereodefined 5-[(1,1-unsymmetrically disubstituted)methylidene]furan-2(5H)-ones
2000
Natural Product Biosynthesis Inspired Concise and Stereoselective Synthesis of Benzopyrones and Related Scaffolds
2011
Phosphine-catalyzed cage carbon functionalization of o-carborane: facile synthesis of alkenylcarboranes
2016
Chiral phosphine-catalyzed regio- and enantioselective allylic amination of Morita–Baylis–Hillman acetates
2009
Phosphine-Catalyzed Intramolecular Cyclizations of α-Nitroethylallenoates Forming (Z)-Furanone Oximes
2016
Highly selective synthesis of 1‐phenylpentane‐1, 4‐diones, and (E)‐5‐hydroxy‐5‐phenylpent‐3‐en‐2‐ones catalyzed by organophosphorus compounds
2009
Enantioselective Intramolecular Formal [2 + 4] Annulation of Acrylates and α,β-Unsaturated Imines Catalyzed by Amino Acid Derived Phosphines
2012
Synthesis of Functionalized Alkylidene Indanes and Indanones through Tandem Phosphine–Palladium Catalysis
2015
Stereoselective Synthesis of 5-(1-Hydroxyalkyl)-2-pyrrolidinones Utilizing Oxidation of 5-Alkylidene-2-pyrrolidinones to Acyliminium Ion Precursors
2000
Domino Cyclization Initiated by Cross‐Rauhut–Currier Reactions
2013
Phosphine-Mediated Olefination between Aldehydes and Allenes: An Efficient Synthesis of Trisubstituted 1,3-Dienes with High E-Selectivity
2009
Cycloaddition of Alkynyl Ketones with N-Tosylimines Catalyzed by Bu3P and DMAP: Synthesis of Highly Functionalized Pyrrolidines and Azetidines
2008
Alternate Heme Ligation Steers Activity and Selectivity in Engineered Cytochrome P450-Catalyzed Carbene-Transfer Reactions
2018 StandoutNobel
The Catalytic Asymmetric Fischer Indolization
2011 StandoutNobel
Unusual Regioselectivity of Pd(0)-Catalyzed Coupling Reaction of Electron-Deficient Alkenyl Halides with Allenic/Propargylic Zinc Reagents. Highly Selective Synthesis of 6-Phenylhex-5-yn-2(or 3)-enoates/Enitrile and 4-Phenyl-6-substituted-hexa-2,4,5-trienoates
2000
Phosphine-Catalyzed Synthesis of 6-Substituted 2-Pyrones: Manifestation of E/Z-Isomerism in the Zwitterionic Intermediate
2005
Highly Regio- and Diastereoselective Construction of Spirocyclopenteneoxindoles through Phosphine-Catalyzed [3 + 2] Annulation of Morita–Baylis–Hillman Carbonates with Isatylidene Malononitriles
2011
Geminal Dicarboxylates as Carbonyl Surrogates for Asymmetric Synthesis. Part I. Asymmetric Addition of Malonate Nucleophiles
2001
Highly enantio-, regio- and diastereo-selective one-pot [2 + 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates,
2010
A sidearm-assisted phosphine for catalytic ylide intramolecular cyclopropanation
2014
Allenylphosphonates ― Useful Precursors of Pyrazoles and 1,2,3‐Triazoles
2008
Enantioselective Fujiwara–Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)–NicOx Complexes
2009
Phosphine-catalyzed one-pot isomerization of 3-alkynoates and [2 + 3]-cycloaddition with imines: formal synthesis of Securinega alkaloid (±)-allosecurinine
2011
Solar Synthesis: Prospects in Visible Light Photocatalysis
2014 StandoutScience
A Phosphine-Catalyzed Preparation of 4-Arylidene-5-imidazolones
2014
Phosphane‐Catalyzed [3+2] Cycloaddition Reaction of Allenoate and Cyclic Imines: A Simple and Efficient Method for Synthesis of Benzo‐Fused Cyclic Sulfamidate Heterocycles
2013
Asymmetric Enamine Catalysis
2007 StandoutNobel
Phosphine-Mediated Regio- and Stereoselective Hydrocarboxylation of Enynes
2013
Some Typical Advances in the Synthetic Applications of Allenes
2005 Standout
A highly diastereoselective synthesis of 3-carbethoxy-2,5-disubstituted-3-pyrrolines by phosphine catalysis
2005
Phosphine-Catalyzed Domino β/γ-Additions of Benzofuranones with Allenoates: A Method for Unsymmetrical 3,3-Disubstituted Benzofuranones
2017
P(n‐Bu)3Catalyzed Reactions of Salicyl N‐Thiophosphinyl Imines with Allenylphosphonates: Synthesis of Phosphono‐Chromans
2013
Iridium-Catalyzed, Asymmetric Amination of Allylic Alcohols Activated by Lewis Acids
2007
The Rauhut–Currier reaction: a history and its synthetic application
2009
(π-Allyl)palladium Complexes Bearing Diphosphinidenecyclobutene Ligands (DPCB): Highly Active Catalysts for Direct Conversion of Allylic Alcohols
2002
One-Pot Phosphine-Catalyzed Syntheses of Quinolines
2012
Phosphine-catalyzed [3 + 2] annulation reaction: highly regio- and diastereoselective synthesis of 2-azaspiro[4.4]nonene-1,3-diones
2017
Nitrogen‐ and Phosphorus‐Containing Lewis Base Catalyzed [4+2] and [3+2] Annulation Reactions of Isatins with But‐3‐yn‐2‐one
2011
Atomökonomische Synthesen – eine Herausforderung in der Organischen Chemie: die Homogenkatalyse als wegweisende Methode
1995
Novel Brønsted Acid Catalyzed Three-Component Alkylations of Indoles withN-Phenylselenophthalimide and Styrenes
2007
Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents
2012 StandoutNobel
Redox induced radical and radical ionic carbon-carbon bond forming reactions
1995
A Computational Study: Reactivity Difference between Phosphine- and Amine-Catalyzed Cycloadditions of Allenoates and Enones
2014
Reactivity of Allenylphosphonates toward Salicylaldehydes and Activated Phenols: Facile Synthesis of Chromenes and Substituted Butadienes
2009
Abnormal Aza-Baylis−Hillman Reaction of N-Tosylated Imines with Ethyl 2,3-Butadienoate and Penta-3,4-dien-2-one
2003
Enantioselective Synthesis of Chromanones via a Peptidic Phosphane Catalyzed Rauhut–Currier Reaction
2015
2-(Acetoxymethyl)buta-2,3-dienoate, a Versatile 1,4-Biselectrophile for Phosphine-Catalyzed (4 + n) Annulations with 1,n-Bisnucleophiles (n = 1, 2)
2010
Tributylphosphine-catalyzed reaction of ethanethiol with alkynyl ketones
2011
Regiodivergent Synthesis of 1- and 2-Arylsulfonyl 1,3-Dienes
2014
Room-Temperature Regioselective C−H/Olefin Coupling of Aromatic Ketones Using an Activated Ruthenium Catalyst with a Carbonyl Ligand and Structural Elucidation of Key Intermediates
2010
Phosphine‐Catalyzed Annulations between Modified Allylic Derivatives and Polar Dienes and Substituent Effect on the Annulation Mode
2013
Phosphine-Initiated General Base Catalysis: Facile Access to Benzannulated 1,3-Diheteroatom Five-Membered Rings via Double-Michael Reactions of Allenes
2011
Approach to thiazole-containing tetrahydropyridines via Aza–Rauhut–Currier reaction and their potent fungicidal and insecticidal activity
2016
Recent Advances in the Baylis−Hillman Reaction and Applications
2003 Standout
Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds
1996 StandoutNobel
Multifunctional chiral phosphine-catalyzed [3+2] annulation of Morita–Baylis–Hillman carbonates with cyclopentenones: asymmetric synthesis of 4-oxo-hexahydropentalenes
2017
Hydroxy-Assisted Regio- and Stereoselective Synthesis of Functionalized 4-Methylenepyrrolidine Derivatives via Phosphine-Catalyzed [3 + 2] Cycloaddition of Allenoates with o-Hydroxyaryl Azomethine Ylides
2017
Chiral Bifunctional Thiourea–Phosphane Organocatalysts in Asymmetric Allylic Amination of Morita–Baylis–Hillman Acetates
2011
Phosphine-Catalyzed Regiospecific Allylic Amination and Dynamic Kinetic Resolution of Morita−Baylis−Hillman Acetates
2004
Importance of Intermolecular Hydrogen Bonding for the Stereochemical Control of Allene–Enone (3+2) Annulations Catalyzed by a Bifunctional, Amino Acid Derived Phosphine Catalyst
2016
Chemoselective Synthesis of Trifluoromethylated γ-Butenolide Derivatives via Phosphine-Promoted Tandem Reaction of Allylic Carbonates and Trifluoromethyl Ketones
2014
Ruthenium‐Catalyzed Alkenylation of Arenes with Alkynes or Alkenes by 1,2,3‐Triazole‐Directed C–H Activation
2014
Water Enables Direct Use of Allyl Alcohol for Tsuji−Trost Reaction without Activators
2004
Palladium-Catalyzed Bisolefination of C−C Triple Bonds: A Facile Method for the Synthesis of Naphthalene Derivatives
2010
Enantioselective [4 + 2]-Annulation of Oxadienes and Allenones Catalyzed by an Amino Acid Derived Phosphine: Synthesis of Functionalized Dihydropyrans
2016
Phosphine-promoted [3+2] cycloaddition between nonsubstituted MBH carbonates and trifluoromethyl ketones
2015
Bisphosphine-Triggered One-Pot Sequential [3 + 2]/[3 + 2] Annulation of Allenoates with Cyclic Ketimines
2013
Regio- and stereoselective synthesis of γ-alkylidenebutenolides and related compounds
1997 StandoutNobel
Nucleophilic Phosphine-Catalyzed Intramolecular Michael Reactions of N-Allylic Substituted α-Amino Nitriles: Construction of Functionalized Pyrrolidine Rings via 5-endo-trig Cyclizations
2014
Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes
1996 StandoutNobel
Unusual [8 + 2] Annelation in the Reactions of Allenic Ester/Ketone-Derived 1,3-Dipoles with Tropone
2000
Catalytic Asymmetric Vinylogous Prins Cyclization: A Highly Diastereo- and Enantioselective Entry to Tetrahydrofurans
2016 StandoutNobel
Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds
2014
Diastereoselective Synthesis of 6-Trifluoromethyl-5,6-dihydropyrans via Phosphine-Catalyzed [4 + 2] Annulation of α-Benzylallenoates with Ketones
2010
Diastereo‐ and Enantioselective Construction of γ‐Butenolides through Chiral Phosphane‐Catalyzed Allylic Alkylation of Morita–Baylis–Hillman Acetates
2011
Metal-Free Multicomponent Syntheses of Pyridines
2014 Standout
Practical Pd(II)-Catalyzed C–H Alkylation with Epoxides: One-Step Syntheses of 3,4-Dihydroisocoumarins
2015
Allenoate-derived 1,5-, 1,7-, and 1,9-zwitterions as highly versatile coupling-partners for phosphine-triggered cycloaddition reactions
2012
Stereoselective addition of carboxylic acids to electron deficient acetylenes catalyzed by the PdMo3S4 cubane-type cluster
1995
Palladium-catalyzed functionalization of indoles with 2-acetoxymethyl substituted electron-deficient alkenes
2004
Pd-Catalyzed cyclization reactions of acetylene-containing α-amino acids
1998
Asymmetric Total Synthesis of the Iridoid β-Glucoside (+)-Geniposide via Phosphine Organocatalysis
2009
Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules
2015
Enantioselective total synthesis of (+)-ibophyllidine via an asymmetric phosphine-catalyzed [3 + 2] annulation
2012
Phosphine-Mediated [3+2] Cycloaddition Reactions of Ethyl 5,5-Diarylpenta-2,3,4-trienoates with Arylmethylidenemalononitriles and N-Tosylimines
2009
Ferrocene Derived Bifunctional Phosphine‐Catalyzed Asymmetric Oxa‐[4+2] Cycloaddition of α‐Substituted Allenones with Enones
2017
Generation of Anti-trypanosomal Agents through Concise Synthesis and Structural Diversification of Sesquiterpene Analogues
2011 StandoutNobel
Phosphine-Catalyzed Cycloadditions of Allenic Ketones: New Substrates for Nucleophilic Catalysis
2007
Phosphine-Triggered Tandem Annulation between Morita–Baylis–Hillman Carbonates and Dinucleophiles: Facile Syntheses of Oxazepanes, Thiazepanes, and Diazepanes
2012
Fluorescence Resonance Energy Transfer Between Quantum Dot Donors and Dye-Labeled Protein Acceptors
2003 StandoutNobel
Works of Xiyan Lu being referenced
PdII-Catalyzed Cyclization of Alkynes Containing Aldehyde, Ketone, or Nitrile Groups Initiated by the Acetoxypalladation of Alkynes
2002
A Catalytic Carbon–Phosphorus Ylide Reaction: Phosphane‐Catalyzed Annulation of Allylic Compounds with Electron‐Deficient Alkenes
2003
Rhodium(III)‐Catalyzed Redox‐Neutral Coupling of N‐Phenoxyacetamides and Alkynes with Tunable Selectivity
2013
Control of Chemoselectivity by Counteranions of Cationic Palladium Complexes: A Convenient Enantioselective Synthesis of Dihydrocoumarins
2009
Palladium and arsenic(III) oxide-catalyzed allylic alkylation by allylic alcohols under neutral conditions
1987
A Phosphine-Catalyzed [3+6] Annulation Reaction of Modified Allylic Compounds and Tropone
2005
Observations on the unusual stereochemistry of the oxidative cleavage of palladium–carbon bonds
1995
Palladium(II)-Catalyzed Three-Component Coupling Reaction Initiated by Acetoxypalladation of Alkynes: An Efficient Route to γ,δ-Unsaturated Carbonyls
2002
Cationic Palladium Complex Catalyzed Diastereo- and Enantioselective Tandem Annulation of 2-Formylarylboronic Acids with Allenoates
2009
Palladium(II)-Catalyzed Tandem Intramolecular Aminopalladation of Alkynes and Conjugate Addition. Synthesis of Oxazolidinones, Imidazolidinones, and Lactams
2000
Reactions of Electron-Deficient Alkynes and Allenes under Phosphine Catalysis
2001 Standout
Novel palladium catalayzed synthesis of pyran derivatives
1987
A convenient stereoselective synthesis of fluorinated α-alkylidene-γ-butyrolactone derivatives
1994
Synthetic methodology using tertiary phosphines as nucleophilic catalysts
2005
Synthesis of indoles via palladium-catalyzed C–H activation of N-aryl amides followed by coupling with alkynes
2011
Reinvestigation on the catalytic isomerisation of carbon–carbon triple bonds
1993
Palladium-catalyzed allylic alkylation of carbonucleophiles witl allylic borates or allylic alcohols and boron oxide under neutral conditions
1988
Phosphine-Catalyzed [4 + 3] Annulation for the Synthesis of Highly Functionalized Bicyclo[3.2.2]nonadienes
2009
Cationic Palladium(II)-Catalyzed Highly Enantioselective Tandem Reactions of ortho-Boronate-Substituted Cinnamic Ketones and Internal Alkynes: A Convenient Synthesis of Optically Active Indenes
2009
Palladium(II)-Catalyzed Synthesis of α-Alkylidene-γ-butyrolactams from N-Allylic 2-Alkynamides. Total Synthesis of (±)-Isocynodine and (±)-Isocynometrine
2001
Palladium(II)-Catalyzed Asymmetric Cyclization of (Z)-4‘-Acetoxy-2‘-butenyl 2-Alkynoates. Role of Nitrogen-Containing Ligands in Palladium(II)-Mediated Reactions
2001
Rhodium(III)‐Catalyzed Redox‐Neutral Coupling of N‐Phenoxyacetamides and Alkynes with Tunable Selectivity
2013
Diastereoselective Synthesis of Arylglycine Derivatives by Cationic Palladium(II)-Catalyzed Addition of Arylboronic Acids to N-tert-Butanesulfinyl Imino Esters
2007
Palladium(II)-catalyzed tandem intramolecular aminopalladation of alkynylanilines and conjugate addition for synthesis of 2,3-disubstituted indole derivatives
2006
Cationic Pd(II)/Bipyridine-Catalyzed Conjugate Addition of Arylboronic Acids to β,β-Disubstituted Enones: Construction of Quaternary Carbon Centers
2010
Effect of Halide Ligands on the Reactivity of Carbon−Palladium Bonds: Implications for Designing Catalytic Reactions
2000
Studies on [PdH]- and [PdCl]-Catalyzed Intramolecular Cyclization: The Search for a Better Solution to Selective Enyne Coupling
1996
Cationic Palladium Complex Catalyzed Highly Enantioselective Intramolecular Addition of Arylboronic Acids to Ketones. A Convenient Synthesis of Optically Active Cycloalkanols
2006
Iridium pentahydride complex catalyzed formation of CC bond by CH bond activation followed by olefin insertion
1987
Tandem Reactions to Construct Heterocycles via Phosphine-Catalyzed Umpolung Addition and Intramolecular Conjugate Addition
2002
Palladium catalyzed cyclization-carbonylation of allylic 2-alkynoates: Facile synthesis of α-alkylidene-γ-butyrolactone β-acetic acid derivatives
1994
Palladium(II)-Catalyzed Enyne Coupling Reaction Initiated by Acetoxypalladation of Alkynes and Quenched by Protonolysis of the Carbon−Palladium Bond
2005
A novel deoxygenation–isomerization reaction of 4-hydroxy-2-ynoic esters and γ-hydroxy-α,β-ynones
1993
A Phosphine-Catalyzed [3+2] Cycloaddition Strategy Leading to the First Total Synthesis of (−)-Hinesol
2003
Palladium-Templated Regio- and Stereoselective Cyclization of 2'-Alkenyl 2-Alkynoates and Its Synthetic Applications
1995
Phosphine-catalyzed [3+3] annulation reaction of modified tert-butyl allylic carbonates and substituted alkylidenemalononitriles
2009
Palladium catalyzed annulation reaction using a bifunctional allylic alkylating agent
1988
Stereospecific hydrohalogenation reactions of electron‐deficient alkynes
1998
A convenient stereoselective synthesis of conjugated (2Z)-EN-4-ynoic and (2Z,4Z)- and (2Z,4E)-dienoic acid derivatives from propiolic acid derivatives
1992
Samarium diiodide initiated addition reaction of fluoroalkyl iodides to olefins
1988
A novel stereospecific hydrohalogenation reaction of propiolates and propiolic acid
1990
Highly stereoselective isomerization of ynones to conjugated dienones catalyzed by transition-metal complexes
1989
A convenient stereoselective synthesis of conjugated dienoic esters and amides
1990
Efficient Preparation of Functionalized (E,Z) Dienes Using Acetylene as the Building Block
1998
Studies on PdII-catalyzed cyclization of 4′-hydroxy-2′-alkenyl 2-alkynoates
1993
Role of Halide Ions in Divalent Palladium-Mediated Reactions: Competition between β-Heteroatom Elimination and β-Hydride Elimination of a Carbon−Palladium Bond
2001
A highly regio- and stereo-selective [3+2] annulation of allylic compounds and 2-substituted 1,1-dicyanoalkenes through a catalytic carbon–phosphorus ylide reaction
2007
Stereoselective synthesis of conjugated polyenones from diynones
1991
A Novel [3+2] Cycloaddition Approach to Nitrogen Heterocycles via Phosphine-Catalyzed Reactions of 2,3-Butadienoates or 2-Butynoates and Dimethyl Acetylenedicarboxylate with Imines: A Convenient Synthesis of Pentabromopseudilin
1998
Selective cconversion of pinane into β-pinene catalyzed by an iridium pentahydride complex
1987
Highly Enantioselective Palladium(II)-Catalyzed Cyclization of (Z)-4‘-Acetoxy-2‘-butenyl 2-Alkynoates: An Efficient Synthesis of Optically Active γ-Butyrolactones
2000
Phosphine-catalyzed [3+2] cycloaddition reaction of methyl 2,3-butadienoate and N-tosylimines. A novel approach to nitrogen heterocycles
1997
A Phosphine-Catalyzed [3 + 2] Annulation Reaction of Modified Allylic Compounds and N-Tosylimines
2008
One-pot synthesis of tetrahydrofuran derivatives via a divalent palladium-catalyzed three-component coupling
2003
Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of ortho-Alkenyl Phenols Using an Oxidizing Directing Group
2013
Stereoselective synthesis of enantiopure β, γ-disubstituted α-alkylideneγ-butyrolactones via A palladium(II) catalyzed cyclization
1995
A novel highly regio- and diastereoselective haloamination of alkenes catalyzed by divalent palladium
2004
A novel regio‐ and stereo‐specific hydrohalogenation reaction of 2‐alkynoic acids and their derivatives
1993
Differentiation of the reactivities of carbon-carbon multiple bonds in one molecule. Highly chemo- and stereo-selective hydrohalogenation of allyl or propargyl propiolates
1990
Synthesis of benzofurans via ruthenium-catalyzed redox-neutral C–H functionalization and reaction with alkynes under mild conditions
2014
A novel stereoselective synthesis of conjugated dienones
1988
Novel Palladium-Catalyzed Acyloxylation/Cyclization of 2-(3′-Alkenyl)indoles
2009
Highly Regioselective Construction of Spirocycles via Phosphine-Catalyzed [3 + 2]-Cycloaddition
2002
Isomerization of propargylic alcohols catalyzed by an iridium complex
1989
Palladium dihalide catalysed stereoselective synthesis of α-(Z)-halomethylene-γ-butyrolactone derivatives
1990
Cycloisomerization of 1,6-Enynes Using Acetate as a Nucleophile under Palladium(II) Catalysis
2005
Unexpected results in the reaction of active methylene compounds with phenylsulfonyl-1,2-propadiene triggered by triphenylphosphine
2004
Nickel chlorides catalyzed rearrangement of allylic phosphites
1986
Total synthesis of both enantiomers of melodorinol. Redetermination of their absolute configurations
1997
Palladium-catalyzed reaction of nucleophiles with diacetates of allylic 1,1-diols
1984
The use of iminopyridines as efficient ligands in the palladium(II)-catalyzed cyclization of (Z)-4′-acetoxy-2′-butenyl 2-alkynoates
2007
Palladium-Catalyzed Nucleophile−Alkyne−α,β-Unsaturated Carbonyl Coupling through Tandem Nucleopalladation and Conjugate Addition
1996
Highly Efficient Construction of Benzene Ring in Carbazoles by Palladium-Catalyzedendo-Mode Oxidative Cyclization of 3-(3‘-Alkenyl)indoles
2006
A palladium-catalyzed construction of enantiomerically pure α-methylene-γ-butyrolactones. Enantiospecific synthesis of both enantiomers of methylenolactocin
1995
A novel regio- and stereo-specific hydroacetoxylation reaction of 2-alkynoic acid derivatives
1992
Control of the β-Hydride Elimination Making Palladium-Catalyzed Coupling Reactions more Diversified
2005
Alkaloids-catalyzed regio- and enantioselective allylic nucleophilic substitution of tert-butyl carbonate of the Morita–Baylis–Hillman products
2004
An organometallic analogue of the Wittig reaction. A one-pot reaction for CC bond formation catalyzed by a molybdenum complex
1989
Cationic Palladium(II)-Catalyzed Addition of Arylboronic Acids to Nitriles. One-Step Synthesis of Benzofurans from Phenoxyacetonitriles
2006
Phosphine-catalyzed [3+2] cycloaddition reactions of substituted 2-alkynoates or 2,3-allenoates with electron-deficient olefins and imines
1999
Phosphine-catalyzed one-pot synthesis of cyclopentenes from electron-deficient allene, malononitrile and aromatic aldehydes
2005
A Palladium(II)-Catalyzed Construction of .alpha.-Methylene-.gamma.-butyrolactones in Optically Active Form. Total Synthesis of (-)-Methylenolactocin
1995
Stereoselective Synthesis of Methyl (Z)-3-Iodo-2-(1-hydroxyalkyl)prop-2-enoates and Their Further Transformation to α-(Z)-Iodomethylene-β-lactones
1996
Cationic Palladium(II)-Catalyzed Highly Enantioselective [3 + 2] Annulation of 2-Acylarylboronic Acids with Substituted Alkynes
2007
Facile synthesis of (2E,4E)-dienoic esters via stereoselective isomerization of 2-ynoic esters
1989
ChemInform Abstract: A Novel [3 + 2] Cycloaddition Approach to Nitrogen Heterocycles via Phosphine‐Catalyzed Reactions of 2,3‐Butadienoates or 2‐Butynoates and Dimethyl Acetylenedicarboxylate with Imines: A Convenient Synthesis of Pentabromopseudilin (VII).
1998