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1999
Photochemical Phase Transition Behavior of Polymer Azobenzene Liquid Crystals with Electron-Donating and -Accepting Substituents at the 4,4‘-Positions
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The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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2004
Tandem Catalysis: Three Mechanistically Distinct Reactions from a Single Ruthenium Complex
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Metallkomplexe funktioneller Isocyanide, XI. Homoleptische Carbenkomplexe, II. Tetrakis(oxazolidin‐2‐yliden)‐ und Tetrakis(perhydrooxazin‐2‐yliden)nickel, ‐palladium und ‐platin
1985
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2001 StandoutNobel
Early Transition-Metal Perfluoroalkyl Complexes
2003
A novel double insertion of the difluoromethylene unit from trifluoromethylcopper into the carbon–copper bond of perfluoroaryl- and perfluorovinylcopper reagents: preparation, mechanism and applications of new fluorinated copper reagents
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C−H Activation for the Construction of C−B Bonds
2009 Standout
Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis Reactions
2004 StandoutNobel
Chiroptical Molecular Switches
2000 StandoutNobel
Activation of small molecules by osmium(II) and ruthenium(II) complexes
1974
Reaction between Ruthenium(0) Complexes and Dihalo Compounds. A New Method for the Synthesis of Ruthenium Olefin Metathesis Catalysts
1997 StandoutNobel
Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated with Phosphine and N-Heterocyclic Carbene Ligands
2003 StandoutNobel
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1997
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1993
Well-Defined Ruthenium Olefin Metathesis Catalysts: Mechanism and Activity
1997 StandoutNobel
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1988
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N-Heterocyclic Carbene, Silylene, and Germylene Complexes of MCl (M = Cu, Ag, Au). A Theoretical Study1
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2007
Metal-Catalyzed Reactions of Organoboronic Acids and Esters
2008
Preparation and Properties of Trifluoromethylated Aryl Derivatives of Germanium, Tin, and Lead. High-Yield Syntheses of Trifluoromethylbenzene
2000
New Entries to and New Reactions of Fluorocarbon Ligands
1997
The chemistry of the carbon–transition metal double and triple bond: annual survey covering the year 1998
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Homogeneous Catalysis in Supercritical Fluids
1999 StandoutNobel
Two Principles of Reticular Chemistry Uncovered in a Metal–Organic Framework of Heterotritopic Linkers and Infinite Secondary Building Units
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Homogeneous catalytic hydrogenation of supercritical carbon dioxide
1994 StandoutNatureNobel
(Alkylidyne)tungsten Complexes Anchored to a Planar Tetraoxo Surface: Exhaustive Alkylation of a (Calixarene)tungsten Complex
1996
A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density
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Tandem Catalysis: The Sequential Mediation of Olefin Metathesis, Hydrogenation, and Hydrogen Transfer with Single-Component Ru Complexes
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Construction of multicomponent systems by utilizing functionalized transition metal complexes as building blocks
1996 StandoutNobel
Benzothiazolin-2-ylidene Complexes of Iridium(I)
2006
Reductive elimination of hydrogen chloride from chloro hydrido transition metal complexes: an efficient and simple method for generation of electron-rich, coordinatively unsaturated, reactive intermediates
1993
Direct Synthesis of Soluble, End-Functionalized Polyenes and Polyacetylene Block Copolymers
2003 StandoutNobel
Thermal, Catalytic, Regiospecific Functionalization of Alkanes
2000 Science
Long-Range Electronic Coupling in Bis(cyclometalated) Ruthenium Complexes
1998 StandoutNobel
The coordination chemistry of bivalent group IV donors;
1975
A Stable Four-Membered N-Heterocyclic Carbene
2004 StandoutNobel
Unexpected H2O-Induced Ar−X Activation with Trifluoromethylpalladium(II) Aryls
2006
Oxidative addition to bis(trifluoromethyl)platinum(II) complexes with N-donor ligands
1988
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
Tandem Ring Opening−Ring Closing Metathesis of Cyclic Olefins
1996 StandoutNobel
Aromaticity as a Cornerstone of Heterocyclic Chemistry
2004 Standout
Synthesis and Structure of the Novel μ2‐Carbido Complex [(TPP)FeCRe(CO)4 Re(CO)5]
1990
Synthesis, Structure, and Activity of Enhanced Initiators for Olefin Metathesis
2003 StandoutNobel
Fluxionality of [(Ph3P)3M(X)] (M = Rh, Ir). The Red and Orange Forms of [(Ph3P)3Ir(Cl)]. Which Phosphine Dissociates Faster from Wilkinson’s Catalyst?
2010
C−H and C−S Bond Cleavage in Uranium(III) Thiolato Complexes
2001
Complexes of the platinum metals. 7. Homogeneous ruthenium and osmium catalysts for the dehydrogenation of primary and secondary alcohols
1977
Conversion of Carbon–Fluorine Bonds α to Transition Metal Centers to Carbon–Hydrogen, Carbon–Carbon, and Carbon–Heteroatom Bonds
2009
Aromatic Trifluoromethylation with Metal Complexes
2011 Standout
DFT Studies of β-Boryl Elimination Processes: Potential Role in Catalyzed Borylation Reactions of Alkenes
2007
Amphiphilie kationischer η2-phosphinocarbenkomplexe des wolframs
1995
Synthesis of Cyclic Diamino-Substituted Metal Carbene Complexes
1996
π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
1999 Standout
Isocyanidsynthesen am Komplex
1991
Aminocarbene complexes derived from nucleophilic addition to isocyanide ligands
2001
The quest for terminal phosphinidene complexes
1988
The Nature of the Bonding in Transition-Metal Compounds
2000
Nucleophilic Reactivity of the Multiply Bonded Carbon Center in Group 4−Pincer Bis(iminophosphorano)methanediide Complexes
2000
Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination
1980 Standout
Water-Soluble Ruthenium Alkylidenes: Synthesis, Characterization, and Application to Olefin Metathesis in Protic Solvents
2000 StandoutNobel
Group 9 and 11 Metal(I) Gallyl Complexes Stabilized by N-Heterocyclic Carbene Coordination: First Structural Characterization of Ga−M (M = Cu or Ag) Bonds
2007
New Zirconium Hydrocarbyl Bis(phosphoranimino) “Pincer” Carbene Complexes
1999
Polarity reversal in η2-phosphinocarbene and η2-arsinocarbene complexes of tungsten
1999
New Insights into the Mechanism of Ruthenium-Catalyzed Olefin Metathesis Reactions
2001 StandoutNobel
Rhodium Boryl Complexes in the Catalytic, Terminal Functionalization of Alkanes
2005
Übergangsmetall-carbin-komplexe XCVII. Carbonylhaltige und carbonylfreie diethylaminocarbin-komplexe von wolfram in einer höheren oxidationszahl mit trimethylphosphit- und isonitril-liganden
1990 Nobel
Transition metal complexes of boron — synthesis, structure and reactivity
2001
Novel Reactivity of Ruthenium Alkylidenes in Protic Solvents: Degenerate Alkylidene Proton Exchange
2001 StandoutNobel
Metallkomplexe funktioneller Isocyanide, XVI1) 1,3‐Dipolare Cycloadditionen von Heteroallenen an die metallorganischen Nitrilylide [(OC)5MCNCHR]− (M = Cr, W; R = CO2Et)
1987
Cu-Catalyzed Azide−Alkyne Cycloaddition
2008 StandoutNobel
Triamidoamine Complexes of Molybdenum and Tungsten That Contain Metal−E (E = N, P, and As) Single, Double, or Triple Bonds
1997 StandoutNobel
Syngas reactions
1987
N-heterocyclic carbenes from transition metal coordinated functional isocyanides of the type o-(CH2Y)C6H4N C (Y = OSiMe3, OH; N3; AsR 3 +
2005
A catalytic fluoride-rebound mechanism for C(sp 3 )-CF 3 bond formation
2017 Science
Transition metal boryl and borylene complexes: substitution and abstraction chemistry
2004
Synthesis of Stable MultifunctionalC-Phosphonio Phosphorus Vinyl Ylides
1996
Cyclic [2]Pseudorotaxane Tetramers Consisting of Two Rigid Rods Threaded through Two Bis-Macrocycles: Copper(I)-Templated Synthesis and X-ray Structure Studies
2008 StandoutNobel
Reactions of β-functional phenyl isocyanides
1999
Facile Two-Step Construction of a Novel Tetrathiamacrotricycle
2005
Preparation of Metal−Imidazolidin-2-ylidene Complexes by Oxidative Addition
2003
The Metal−Ligand Bifunctional Catalysis: A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds
2000 StandoutNobel
Oxidative Addition of Imidazolium Salts to Ni0 and Pd0: Synthesis and Structural Characterization of Unusually Stable Metal–Hydride Complexes
2004
The First Example of an Equilibrium between a Carbene and an Isomeric Carbyne Transition Metal Complex
2000
Synthesis and Applications of RuCl2(CHR‘)(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity
1996 StandoutNobel
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
1999 Standout
A Metal−Organic Framework with Covalently Bound Organometallic Complexes
2010 StandoutNobel
Homogeneous Catalysis in Supercritical Fluids: Hydrogenation of Supercritical Carbon Dioxide to Formic Acid, Alkyl Formates, and Formamides
1996 StandoutNobel
Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations
2003 StandoutNobel
Works of W.R. Roper being referenced
Synthesis and Structures of cis- and trans-[Os(Bcat)(aryl)(CO)2(PPh3)2]: Compounds of Relevance to the Metal-Catalyzed Hydroboration Reaction and the Metal-Mediated Borylation of Arenes
1999
680. Bipyridyl and terpyridyl complexes from halides of Group IVB elements
1965
The tris(triphenylphosphine)osmium zerovalent complexes Os(CO)2(PPh3)3, .Os(CO)(CNR)(PPh3)3, Os(CO)(CS)(PPh3)3, Os(CS)(cNR)(PPh3)3 and derived compounds
1982
Carbonyl, thiocarbonyl, selenocarbonyl, and tellurocarbonyl complexes derived from a dichlorocarbene complex of osmium
1980
Syntheses and structures of the chalcocarbonyl complexes OsCl2(CO)(CE)(PPh3)2 (E = S, Se, Te)
1988
Direct nitration of aryl groups σ-bound to ruthenium(II)
1994
A Base-Stabilized Terminal Borylene Complex of Osmium Derived from Reaction between a Dichloroboryl Complex and 8-Aminoquinoline
2000
Five-Coordinate Ruthenium(II) and Osmium(II) Boryl Complexes
1997
Transition Metal−Boryl Compounds: Synthesis, Reactivity, and Structure
1998
Co-ordinated thioformaldehyde monomer. Synthesis and Reactions of [Os(η2-CH2S)(CO)2(PPh3)2]
1977
A fluorochlorocarbene complex of osmium, OsCl2(CFCI)(CO)(PPh3)2 and the structure of a fluoroalkoxycarbene complex of ruthenium, RuCl2(CFOCH2CMe3)(CO)(PPh3)2
1984
Tethered Osmium Boryl Complexes from the Reaction of Os(BCl2)Cl(CO)(PPh3)2 with 2-Hydroxypyridine
2002
Reactions of the dichloroboryl complex of osmium, Os(BCl2)Cl(CO)(PPh3)2, with water, alcohols, and amines
2003
Transition-metal dihalocarbene complexes
1988
Exchange of boryl ligand substituents in Os[B(OEt)2]Cl(CO)(PPh3)2
2004
[Os(η2‐PHS)(CO)2(PPh3)2], a Stable η2‐Thioxophosphane(HPS)‐Metal Complex
1988
Oxidation of alcohol to co-ordinated carboxylate with a dioxygen complex of ruthenium. Examples of reversible hydrogen transfer to an isocyanide ligand
1972
Synthesis of an osmium(II) complex with the PIPh ligand and a possible terminal phenylphosphinidene complex intermediate from iodide abstraction
1984
The interaction of an osmium-carbon triple bond with copper(I), silver(I) and gold(I) to give mixed dimetallocyclopropene species and the structures of R) Cl(CO) (PPh3)2
1980
O-bonded and S-bonded sulphinate complexes of iridium(I) and iridium(III). Ligand isomerisation accompanying change in co-ordination number
1971
Migration of a hydride ligand to a difluorocarbene ligand bound to rhodium. The synthesis and crystal structure of RhCl2(CF2H)(PPh3)2
1990
Synthesis of transition metal—heterocyclic carbene complexes. Oxazol-2-ylidene and oxazolidin-2-ylidene complexes of osmium(II) derived from coordinated tosylmethylisocyanide
1975
Crystal Structure of Os(Bcat)Cl(CO)(PPh3)2 and the Syntheses and Structural Studies of Derived Cationic and Neutral Osmium Boryl Complexes
1998
Reactions of cis and trans Bcat, Aryl Osmium Complexes (cat = 1,2-O2C6H4). Bis(Bcat) Complexes of Osmium and Ruthenium and a Structural Comparison of cis and trans Isomers of Os(Bcat)I(CO)2(PPh3)2
2000
Synthesis and structure of a P-metallated phospha-alkene, [Os(PC[O]CF3)(CO)2(PPh3)2]
1985
Seven-coordinate dioxygen complexes from dioxygen addition to five-coordinate σ-phenyl, isocyanide-containing derivatives of ruthenium(II) and osmium(II). Crystal structures of OS(η2-O2)(η2-CPh = Np-chlorophenyl)Cl(PPh3)2 and Os(η2-SO4)(η2-CPh = Np-chlorophenyl)Cl(PPh3)2
1996
Selenocarbonyl complexes of iridium(I) and iridium(III). Synthesis and reactions of IrCl(CSe)(PPh3)2
1983
Stepwise reduction of the thiocarbonyl ligand: hydride transfer to CS: thioformyl, thioformaldehyde, methylthiolato, secondary carbene, formyl and iminoformyl complexes of osmium
1978
Vinylidene complexes of osmium(0) derived from 1-naphthyl- or 2-naphthyl-carbyne complexes by hydride addition to the naphthyl substituents. The crystal structure of Os(CC10H8)(CO)2(PPh3)2
1998
Oxidation state control of the reactivity of a transition metal–carbon double bond. Synthesis, X-ray crystal structure, and reactions of the zerovalent difluorocarbene complex [Ru(CF2)(CO)2(PPh3)2]
1983
Tethered Boryl and Base-Stabilized Borylene Osmium Complexes from the Reaction of Os(BCl2)Cl(CO)(PPh3)2 with 2-Aminopyridine
2002
Ru(CO)2(PPh3)3 and Os(CO)2(PPh3)3. An ethylene complex of ruthenium and a dioxygen complex of osmium
1972
Trifluoromethyl and mixed hydrido trifluoromethyl complexes of iridium(III) as potential precursors of an iridium(I) trifluoromethyl complex
1986
Combined decarboxylation of the formato ligand and reductive elimination of hydrido and aryl groups in the synthesis of ruthenium(0) complexes. Methylation of ruthenium(0) with formaldehyde
1982
Synthesis and some reactions of a terminal carbyne complex of osmium. Crystal structures of Os(CR)Cl(CO)(PPh3)2 and gCl]R)Cl(CO)(PPh3)2
1986
Iridium(III) S-Sulfinates. Preparation of an Iridium(III) Aryl
1966
A Base-Stabilized Terminal Borylene Complex of Osmium Derived from Reaction between a Dichloroboryl Complex and 8-Aminoquinoline
2000
A Base-Stabilized Terminal Borylene Complex of Osmium Derived from Reaction between a Dichloroboryl Complex and 8-Aminoquinoline
2000
Isocyanide complexes of zerovalent ruthenium. Proton addition to a transition-metal base offering alternative base sites
1971
Metallacyclobutadiene complexes from ligand combination of cs and acetylene on osmium
1983
Synthesen und Strukturen voncis- undtrans-[Os(Bcat)(aryl)(CO)2(PPh3)2]: bedeutende Verbindungen für metallkatalysierte Hydroborierungen und metallvermittelte Borylierungen von Arenen
1999
Preparation and Oxidative Addition Reactions of a Monomeric Ruthenium(0) Complex
1965
Platinum group metals in the formation of metal–carbon multiple bonds
1986
Cationic cyclic carbene complexes of iridium(III), nickel(II), palladium(II), and platinum(II)
1974
Cationic cyclic carbene or carbon-bonded ylide complexes of iridium(III) and platinum(II)
1973
Insertion of Ethyne into the Ru−B Bond of a Coordinatively Unsaturated Ruthenium Boryl Complex. X-ray Crystal Structure of Ru(CHCH[BOC6H4O])Cl(CO)(PPh3)2
1997
An osmium-carbyne complex
1980
Synthesis, structure, and reactions of IrCl3(CCl2)(PPh3)2, A compound with an iridium-carbon double bond (LnIrCCl2)
1982
Tetrafluoroethyl complexes of iridium(III) derived from a tetrafluoroethylene complex of iridium(I). A study of α-fluoride abstraction and determination of the structure of IrCl2(CF2CF2Cl)(CO)(PPh3)2
1994
Reactions of a dichlorocarbene-ruthenium complex, RuCl2(CCl2)(CO)(PPh3)2
1982
Thioxophosphine (HP:S) and selenoxophosphine (HP:Se) complexes of Os(0): synthesis, structure, reactivity, and theoretical studies of Os(.eta.2-PR:E)(CO)2(PPh3)2 (E = S, R = H, Me; E = Se, R = H)
1990
2,2'-Dipyridyl Adducts of the Group VB Trihalides and Their Ionization
1964
Electrophilic Aromatic Substitution Reactions of a Metallabenzene: Nitration and Halogenation of the Osmabenzene [Os{C(SMe)CHCHCHCH}I(CO)(PPh3)2]
2000
Hydrogen transfer from HCl to the nitrosyl ligand. Examples of co-ordinated HNO, NHOH-, and NH2OH
1970
Trifluoromethyl, difluorocarbene and tetrafluoroethylene complexes of iridium and the crystal structures of IrI(CH3)(CF3)(CO)(PPh3)2, Ir(CF3)(C2F4)(CO)(PPh3)2 and Ir(CF3)(CF2)(CO)(PPh3)2
1990
Syntheses and reactions of the carbyne complexes, M(CR)Cl(CO)(PPh3)2 (M=Ru, Os; R=1-naphthyl, 2-naphthyl). The crystal structures of [Os(C-1-naphthyl)(CO)2(PPh3)2]ClO4, Os(CH-2-naphthyl)Cl2(CO)(PPh3)2, and Os(2-naphthyl)Cl(CO)2(PPh3)2
1998
Carbene complexes of iridium, rhodium, manganese, chromium, and iron containing thiazolidinylidene and pyridinylidene ligands
1974
Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2]
1982
A mononuclear, low-valent, electron-rich osmium methylene complex
1983
Difluorocarbene complexes of ruthenium derived from trifluoromethyl compounds. RuCl2(CF2)(CO)(PPh3)2, RuCl2(CFNMe2)(CO)(PPh3)2, RuCl2(CFOMe)(CO)(PPh3)2 and the structure of Ru(CF3)(HgCF3)(CO)2(PPh3)2
1982