Citation Impact
Citing Papers
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2009
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2008
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2013
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2006 Nobel
A General, Practical Triethylborane‐Catalyzed Reduction of Carbonyl Functions to Alcohols
2015
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2008
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2012
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2010
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2011
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Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems
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2011
Structure and Dynamic Features of an Intramolecular Frustrated Lewis Pair
2010
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2010
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2011
Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes
2015
Frustrated Lewis Pair Inspired Carbon Dioxide Reduction by a Ruthenium Tris(aminophosphine) Complex
2012
Noncoordinating Anions—Fact or Fiction? A Survey of Likely Candidates
2004 Standout
Chiral Organoborane Lewis Pairs Derived from Pyridylferrocene
2014
Formylborane Formation with Frustrated Lewis Pair Templates
2013
Metal‐free Catalytic Olefin Hydrogenation: Low‐Temperature H2 Activation by Frustrated Lewis Pairs
2012
Interactions with Aromatic Rings in Chemical and Biological Recognition
2003 Standout
B(C6F5)3‐Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa‐1,4‐dienes as a Dihydrogen Source
2014
Frustrated Lewis Pair Chemistry of Chiral (+)‐Camphor‐Based Aminoboranes
2013
Discovery of Frustrated Lewis Pairs: Intermolecular FLPs for Activation of Small Molecules
2012
Fluorescent boron(iii) iminocoumarins (Boricos)
2013
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2005
Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl
2012
Heterolytic Cleavage of Dihydrogen by “Frustrated Lewis Pairs” Comprising Bis(2,4,6‐tris(trifluoromethyl)phenyl)borane and Amines: Stepwise versus Concerted Mechanism
2011
Homogeneous Catalytic Hydroamination of Alkynes and Allenes with Ammonia
2008
1,5,9‐Triazacoronenes: A Family of Polycyclic Heteroarenes Synthesized by a Threefold Pictet–Spengler Reaction
2010
Synthesis and Reactions of N‐Heterocyclic Carbene Boranes
2011
Regiospecific N‐Heteroarylation of Amidines for Full‐Color‐Tunable Boron Difluoride Dyes with Mechanochromic Luminescence
2013
Turning Frustration into Bond Activation: A Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis Pairs
2008
Functional Porous Coordination Polymers
2004 StandoutNobel
Tetrachlorinated Tetraazaperopyrenes (TAPPs): Highly Fluorescent Dyes and Semiconductors for Air‐Stable Organic n‐Channel Transistors and Complementary Circuits
2012
Cyclometalative C–H bond activation in rare earth and actinide metal complexes
2012
Agostic Interactions in d0Metal Alkyl Complexes
2004
Brønsted Acid Catalyzed Addition of Phenols, Carboxylic Acids, and Tosylamides to Simple Olefins
2006
Dispersion‐Oriented Soft Interaction in a Frustrated Lewis Pair and the Entropic Encouragement Effect in its Formation
2009
Solvents for ring-closing metathesis reactions
2008
Reactivity of a Frustrated Lewis Pair and Small‐Molecule Activation by an Isolable Arduengo CarbeneB{3,5‐(CF3)2C6H3}3 Complex
2012
Metal‐Free Hydrogenation of Electron‐Poor Allenes and Alkenes
2012
One hundred years of helicene chemistry. Part 1: non-stereoselective syntheses of carbohelicenes
2012
Ruthenium–Olefin Complexes: Effect of Ligand Variation upon Geometry
2008 Nobel
Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H2 Addition and Kinetic Analysis
2014
Frustrated Lewis Pair Chemistry: Development and Perspectives
2015 Standout
Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism
2012
Activation of CO2 by phosphinoamide hafnium complexes
2013
N‐Methylacridinium Salts: Carbon Lewis Acids in Frustrated Lewis Pairs for σ‐Bond Activation and Catalytic Reductions
2014
Reaction of Frustrated Lewis Pairs with Conjugated Ynones‐Selective Hydrogenation of the Carbon–Carbon Triple Bond
2011
Four-coordinate organoboron compounds for organic light-emitting diodes (OLEDs)
2013
Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls
2010
Boron-pyridyl-imino-isoindoline dyes: facile synthesis and photophysical properties
2013
Alkene metathesis: the search for better catalysts
2007
1,1-Carboboration
2011
Synthesis, Structural Investigation, and Reactivity of Neutral and Cationic Bis(guanidinato)zirconium(IV) Complexes
2001
Fixation of carbon dioxide and related small molecules by a bifunctional frustrated pyrazolylborane Lewis pair
2012
A Standard System of Characterization for Olefin Metathesis Catalysts
2006 Nobel
Observing a Homogeneous Ziegler Catalyst Precursor at Work: Insertion Reactions into the Zirconium – Carbon Bond of the (Butadiene)ZrCp2/B(C6F5)3 Addition Product
1996
Nonmetal Catalyzed Hydrogenation of Carbonyl Compounds
2014
Internal Fluorocarbon Coordination as a Tool for the Protection of Active Catalytic Sites: Experimental Characterization of the Zr···F−C Interaction in the Group 4 Metallocene(butadiene)/B(C6F5)3 Betaine Ziegler Catalyst Systems
1997
Ligand Influence on Metathesis Activity of Ruthenium Carbene Catalysts: A DFT Study
2007
Stoichiometric Reduction of CO2 to CO by Phosphine/AlX3-Based Frustrated Lewis Pairs
2013
3d Transition Metals for C–H Activation
2018 Standout
Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs
2009
Metallfreie katalytische Hydrierung von Enaminen, Iminen und konjugierten Phosphinoalkenylboranen
2008
B(C6F5)3‐Catalyzed Reduction of Ketones and Imines Using Silicon‐Stereogenic Silanes: Stereoinduction by Single‐Point Binding
2009
Frustrated Lewis Pairs: From Concept to Catalysis
2014 Standout
The propensity for covalent organic frameworks to template polymer entanglement
2024 StandoutScienceNobel
Developing Phospha‐Stork Chemistry Induced by a Borane Lewis Acid
2014
Stabilization of a Cationic Ti Center by a Ferrocene Moiety: A Remarkably Short Ti−Fe Interaction in the Diamide {[(η5-C5H4NSiMe3)2Fe]TiCl}22+
2001
Bio-Organometallic Chemistry, ansa-Metallocenes, and Frustrated Lewis Pairs: Functional Group Chemistry at the Group 4 Bent Metallocenes
2011
Ancillary Metal Centers in Frustrated Lewis Pair Chemistry: Ruthenium Acetylide as a Lewis Base in the Activation of CO2, Aldehyde, and Alkyne
2013
Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
2012
Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair
2010
Frustrated Lewis Pair Modification by 1,1-Carboboration: Disclosure of a Phosphine Oxide Triggered Nitrogen Monoxide Addition to an Intramolecular P/B Frustrated Lewis Pair
2014
Heterolytic Activation of H2 Using a Mechanically Interlocked Molecule as a Frustrated Lewis Base
2012
Die Reaktionen eines P/Al‐basierten frustrierten Lewis‐Paars mit Ammoniak, Boran und Aminboranen: Adduktbildung und katalytische Wasserstoffeliminierung
2013
Ab initiodynamics trajectory study of the heterolytic cleavage of H2 by a Lewis acid [B(C6F5)3] and a Lewis base [P(tBu)3]
2013
Frustrated Lewis Pair Inspired Carbon Dioxide Reduction by a Ruthenium Tris(aminophosphine) Complex
2012
Frustrated Lewis Pair Behavior of Intermolecular Amine/B(C6F5)3 Pairs
2012
Turning Frustration into Bond Activation: A Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis Pairs
2008
The chemistry of the carbon–transition metal double and triple bond: annual survey covering the year 1999
2001
Lewis Acid Properties of Tris(pentafluorophenyl)borane. Structure and Bonding in L−B(C6F5)3 Complexes
1999
Polycyclic π-Electron System with Boron at Its Center
2012
Auf der Suche nach einer neuen Generation von Katalysatoren zur Olefinpolymerisation: „Leben” jenseits der Metallocene
1999
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals
2007 Standout
Hydrogen Activation by an Aromatic Triphosphabenzene
2014
Reactions of Boron Amidinates with CO2 and CO and Other Small Molecules
2010
Four-Coordinate Organoboron Compounds with a π-Conjugated Chelate Ligand for Optoelectronic Applications
2011
Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N‐Heterocyclic Carbene and B(C6F5)3
2008
Geminal Phosphorus/Aluminum‐Based Frustrated Lewis Pairs: CH versus CC Activation and CO2 Fixation
2011
Coupling of Carbon Monoxide with Nitrogen Monoxide at a Frustrated Lewis Pair Template
2016
Molecular Tweezers for Hydrogen: Synthesis, Characterization, and Reactivity
2008
Syntheses and properties of the novel co-catalysts N,N-dimethylanilinium- and trityl{tetrakis[4-(trifluoromethyl)-2,3,5,6-tetrafluorophenyl]borate}
2001
Noninteracting, Vicinal Frustrated P/B-Lewis Pair at the Norbornane Framework: Synthesis, Characterization, and Reactions
2013
Rare-Earth-Catalyzed C–H Bond Addition of Pyridines to Olefins
2011
Cationic Zirconium Complexes that Contain Mesityl-Substituted Diamido/Donor Ligands. Decomposition via CH Activation and Its Influence on 1-Hexene Polymerization
2001 StandoutNobel
Preparation and crystal structures of the complexes (η5-C5H4CPh2-η5-C13H8) MCl2 (M Zr, Hf) and the catalytic formation of high molecular weight high tacticity syndiotactic polypropylene
1993
Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H2 Addition and Kinetic Analysis
2014
Neutral Ti Catalysts for the Intramolecular Hydroamination of Alkenes
2006
Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2 Activation and the Role of Acid−Base Properties
2009
Carbonylation Reactions of Intramolecular Vicinal Frustrated Phosphane/Borane Lewis Pairs
2013
Syntheses and Reactivity of Analogues of Grubbs’ Second Generation Metathesis Catalyst with Fluorous Phosphines: A New Phase‐Transfer Strategy for Catalyst Activation
2007
Olefin Metathesis Reactions with Vinyl Halides: Formation, Observation, Interception, and Fate of the Ruthenium−Monohalomethylidene Moiety
2007
Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation
2014
Non‐Metal‐Mediated Homogeneous Hydrogenation of CO2 to CH3OH
2009
A Highly Active Palladium Catalyst for Intermolecular Hydroamination. Factors that Control Reactivity and Additions of Functionalized Anilines to Dienes and Vinylarenes
2006
Formylborane Formation with Frustrated Lewis Pair Templates
2013
Synthesis and self-assembly of dibenzo[jk,mn]naphtho[2,1,8-fgh]thebenidinium derivates
2008
Remarkable Behavior of a Bifunctional Alkynylborane Zirconocene Complex toward Donor Ligands and Acetylenes
2013
Group 3 metal complexes based on a chiral tetradentate diamine-diamide ligand: Synthesis and use in polymerization of (d,l)-lactide and intramolecular alkene hydroamination catalysis
2006
Chelating Diamide Based Rate Enhancement of Intramolecular Alkene Hydroaminations Catalyzed by a Neutral Sc(III) Complex
2005
Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
2008 Standout
Diverging Pathways in the Activation of Allenes with Lewis Acids and Bases: Addition, 1,2-Carboboration, and Cyclization
2015
Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
1995 Standout
A Highly Active Phosphine–Borane Organocatalyst for the Reduction of CO2 to Methanol Using Hydroboranes
2013
Zr−Alkyl Isomerization in ansa-Zirconocene-Catalyzed Olefin Polymerizations. Contributions to Stereoerror Formation and Chain Termination1
1996
Dihydrogen Activation by B(p-C6F4H)3 and Phosphines
2010
The Hitchhiker’s Guide to Flow Chemistry
2017 Standout
Chiral-at-metal organolanthanides: enantioselective aminoalkene hydroamination/cyclisation with non-cyclopentadienylsElectronic supplementary information (ESI) available: complete experimental procedures and characterising data for all ligands and complexes, crystal data for [YL2{N(SiMe2H)2}(THF)] and [SmL4{N(SiMe2H)}]. See http://www.rsc.org/suppdata/cc/b3/b305105f/
2003
Chiral Architectures from Macromolecular Building Blocks
2001
New NMR Spectroscopic Probe of the Absolute Stereoselectivity for Metal-Hydride and Metal-Alkyl Additions to the Carbon−Carbon Double Bond. Demonstration with a Single-Component, Isospecific Ziegler−Natta α-Olefin Polymerization Catalyst
1996
The (Ph)2nacnac Ligand in Organochromium Chemistry
2002
Oxygen-Bridged Borate Anions from Tris(pentafluorophenyl)borane: Synthesis, NMR Characterization, and Reactivity
2005
Heterolytic Cleavage of Dihydrogen by “Frustrated Lewis Pairs” Comprising Bis(2,4,6‐tris(trifluoromethyl)phenyl)borane and Amines: Stepwise versus Concerted Mechanism
2011
Electrophile-Functionalized Metallocene Intermediates. Application in the Diastereoselective Synthesis of a Tetramethyldisiloxane-Bridged C2-Symmetric ansa-Zirconocene Dibromide
1999
Pathways to Functionalized Heterocycles: Propargyl Rearrangement using B(C6F5)3
2015
Synthesis and Structure of the Hafnium Alkylidene Complex [P2Cp]HfCHPh(Cl) ([P2Cp] = (η5-C5H3-1,3-(SiMe2CH2PPri2)2))
2001
New Yttrium Complexes Bearing Diamidoamine Ligands as Efficient and Diastereoselective Catalysts for the Intramolecular Hydroamination of Alkenes and Alkynes
2004
Two BN Isosteres of Anthracene: Synthesis and Characterization
2014
Evidence for the Existence of Terminal Scandium Imidos: Mechanistic Studies Involving Imido–Scandium Bond Formation and C–H Activation Reactions
2012
Enantioselective Hydrogenation with Chiral Frustrated Lewis Pairs
2010
C−H Activation for the Construction of C−B Bonds
2009 Standout
Unexpected Results of a Turnover Number (TON) Study Utilising Ruthenium‐Based Olefin Metathesis Catalysts
2005
Metallocene catalysts for olefin polymerization
1999
Gold catalyzed hydrogenations of small imines and nitriles: enhanced reactivity of Au surface toward H2via collaboration with a Lewis base
2013
Ring-Opening Reactions of Aromatic N-Heterocycles by Scandium and Yttrium Alkyl Complexes
2008
Organoyttrium-Catalyzed Sequential Cyclization/Silylation Reactions of Nitrogen-Heteroaromatic Dienes Demonstrating “Aryl-Directed” Regioselectivity
2000
Carbon−Carbon Bond Forming Reactions Mediated by Silicon Lewis Acids
2003 Standout
Electronic Effects in the Reactions of Olefin-Coordinated Gold Carbene Complexes
2009
Addition of N−H and O−H Bonds of Amines and Alcohols to Electron-Deficient Olefins Catalyzed by Monomeric Copper(I) Systems: Reaction Scope, Mechanistic Details, and Comparison of Catalyst Efficiency
2007
A Phosphorus/Aluminum‐Based Frustrated Lewis Pair as an Ion Pair Receptor: Alkali Metal Hydride Adducts and Phase‐Transfer Catalysis
2012
Phosphorus Lewis acids: emerging reactivity and applications in catalysis
2015
Al-, Nb-, and Ta-Based Perfluoroaryloxide Anions as Cocatalysts for Metallocene-Mediated Ziegler−Natta Olefin Polymerization
2000
Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts
2000
Bis(amidate) titanium precatalyst for the intermolecular hydroamination of allenes
2006
Complexes of tris(pentafluorophenyl)boron with nitrogen-containing compounds: Synthesis, reactivity and metallocene activation
2005
Electronic Control of Frustrated Lewis Pair Behavior: Chemistry of a Geminal Alkylidene-Bridged Per-pentafluorophenylated P/B Pair
2011
Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis
2005
Structural modification strategies for the rational design of red/NIR region BODIPYs
2014 Standout
Expeditive Syntheses of Functionalized Pentahelicenes and NC-AFM on Ag(001)
2009
Probing the Association of Frustrated Phosphine–Borane Lewis Pairs in Solution by NMR Spectroscopy
2013
Identification and Characterization of a New Family of Catalytically Highly Active Imidazolin-2-ylidenes
2008
Cationic rare earth metal alkyls as novel catalysts for olefin polymerization and copolymerization
2006
Internal Adduct Formation of Active Intramolecular C4-bridged Frustrated Phosphane/Borane Lewis Pairs
2014
Substitutent Effects in the Periphery of 2,9-Bisaryl-tetraazaperopyrene Dyes
2010
Cationic NHC–Pd (NHC=N-heterocyclic carbene) complex-catalyzed cycloisomerization of dienes
2007
Organo-Lewis Acid Cocatalysts in Single-Site Olefin Polymerization—A Highly Acidic Perfluorodiboraanthracene
2000
Chelate Complexes of Cyclopentadienyl Ligands Bearing Pendant O-Donors
2000
N,N-Addition of Frustrated Lewis Pairs to Nitric Oxide: An Easy Entry to a Unique Family of Aminoxyl Radicals
2012
Stoichiometric Reduction of CO2 to CO by Aluminum‐Based Frustrated Lewis Pairs
2011
New advances in nanographene chemistry
2015 Standout
Structural features and reactions of a geminal frustrated phosphane/borane Lewis pair
2013
α-Agostic Interactions and Olefin Insertion in Metallocene Polymerization Catalysts
1996 StandoutNobel
Influence of π-Ligand Substitutions on the Regiospecificity and Stereospecificity in Isospecific Zirconocenes for Propene Polymerization. A Molecular Mechanics Analysis
1998
Carbon−Carbon Bond Activation by 1,1-Carboboration of Internal Alkynes
2010
3,12-Dimethoxy-7,8-dicyano-[5]helicene as a novel emissive material for organic light-emitting diode
2010
Bis(Pentafluorophenyl)(2-perfluorobiphenylyl)borane. A New Perfluoroarylborane Cocatalyst for Single-Site Olefin Polymerization
2000
An Electronic Rationale for Observed Initiation Rates in Ruthenium-Mediated Olefin Metathesis: Charge Donation in Phosphine and N-Heterocyclic Carbene Ligands
2007
P−C Bond Activation Chemistry: Evidence for 1,1-Carboboration Reactions Proceeding with Phosphorus−Carbon Bond Cleavage
2011
Tetrakis(pentafluorophenyl)gallates (I)
2000
Fused polycyclic aromatics incorporating boron in the core: fundamentals and applications
2015
Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs
2011
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
The formation and structures of the methyl-bridged complexes Cp∗TiMe2(μ-Me)B(C6F5)3 and [Cp∗TiMe2(μ-Me)TiMe2Cp∗][MeB(C6F5)3]
1997
Synthesis and activity for ROMP of bidentate Schiff base substituted second generation Grubbs catalysts
2006
The search for new hydrogenation catalyst motifs based on N-heterocyclic carbene ligands
2006
Reversible, nicht metallunterstützte Bindung von Kohlendioxid durch frustrierte Lewis‐Paare
2009
Frustrated Lewis Pairs: Metal‐free Hydrogen Activation and More
2009 Standout
Addition of Enamines or Pyrroles and B(C6F5)3 “Frustrated Lewis Pairs” to Alkynes
2010
Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation
2012
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
2009 Standout
Metal‐Free HB(C6F5)2‐Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane‐Mediated σ‐Bond Metathesis
2013
Preorganized Frustrated Lewis Pairs
2011
Boron–nitrogen substituted perylene obtained through photocyclisation
2014
C–H Bond Activations by Monoanionic, PNP-Supported Scandium Dialkyl Complexes
2015
Synthesis of Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligand, [((t-Bu-d6)N-o-C6H4)2O]2- ([NON]2-) and the Living Polymerization of 1-Hexene by Activated [NON]ZrMe2
1997 StandoutNobel
Metallfreie Hydrierung von ungesättigten Kohlenwasserstoffen mit molekularem Wasserstoff
2014
Bifunctional Cyclopentadienyl Ligands in Organotransition Metal Chemistry
1994
Ten Years of N‐Heteropentacenes as Semiconductors for Organic Thin‐Film Transistors
2014
[(acridine)BCl2]+: A Borenium Cation That Is a Strong Boron- and Carbon-Based Lewis Acid
2013
Synthesis and Characterization of Alkyllanthanum Biphenolate Complexes as Catalysts for Hydroamination/Cyclization and Hydrosilylation
2004
New Family of Weakly Coordinating Anions
2000
Synthesis and Structural Characterization of {[Me2Si(C5Me4)2]Zr(η2-C2H4)H}2Mg: An ansa-Zirconocene Ethylene−Hydride Complex
1998
Cationic Alkyl Complexes of the Rare‐Earth Metals: Synthesis, Structure, and Reactivity
2005
Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids
2016
Ethylene Polymerization Using β-Diketimine Complexes of Zirconium
2000
Hydroboration of Carbon Dioxide Using Ambiphilic Phosphine–Borane Catalysts: On the Role of the Formaldehyde Adduct
2015
Highly Active Chiral Ruthenium Catalysts for Asymmetric Ring-Closing Olefin Metathesis
2006 Nobel
Formation of Unsaturated Vicinal Zr+/P Frustrated Lewis Pairs by the Unique 1,1-Carbozirconation Reactions
2014
One-Electron Oxidation of an Organic Molecule by B(C6F5)3; Isolation and Structures of Stable Non-para-substituted Triarylamine Cation Radical and Bis(triarylamine) Dication Diradicaloid
2013
Supramolecular Polymers
2001 Standout
Gas-Phase Lewis Acidity of Perfluoroaryl Derivatives of Group 13 Elements
2008
Cyclodextrin-Based Catenanes and Rotaxanes
1998 StandoutNobel
Frustrated Lewis Pairs beyond the Main Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene–Phosphinoaryloxide Complexes
2011
Highly selective catalytic trans-hydroboration of alkynes mediated by borenium cations and B(C6F5)3
2016
Functionalization of the C−H Bond of N‐Heteroaromatics Assisted by Early Transition‐Metal Complexes
2018
Homogeneous catalytic hydrogenation of supercritical carbon dioxide
1994 StandoutNatureNobel
Nickel Indenyl Complexes as Catalysts for the Dimerization and Polymerization of Ethylene
2001
Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides
2014
Catalytic Intramolecular Hydroamination of Substituted Aminoallenes by Chiral Titanium Amino-Alcohol Complexes
2004
Cationic Group 4 metallocene complexes and their role in polymerisation catalysis: the chemistry of well defined Ziegler catalysts
1996
Transition-Metal Oxos as the Lewis Basic Component of Frustrated Lewis Pairs
2016
Doubly Bridgedansa-Zirconocenes Based on the Norbornadiene Skeleton: A Quantum Mechanical and Molecular Mechanics Study
1996
Thermal Cyclodehydrogenations To Form 6-Membered Rings: Cyclizations of [5]Helicenes
2007
Intramolecular Hydroamination of Unactived Olefins with Ti(NMe2)4 as a Precatalyst
2005
Helicenes: Synthesis and Applications
2011 Standout
Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field?
2013
Interlocked Macromolecules
1999 StandoutNobel
The First Imidazolium-Substituted Metal Alkylidene
2007
[RhH] and [Rh][O2CH] Complexes as Models for the Catalytically Active Intermediates in the Rh‐Catalyzed Hydrogenation of CO2 to HCOOH
1993
Scandium Terminal Imido Chemistry
2018
Direct Experimental Observation of the Stereochemistry of the First Propene Insertion Step at an Active Homogeneous Single-Component Metallocene Ziegler Catalyst
1999
Catalytic Hydroamination of Alkynes and Norbornene with Neutral and Cationic Tantalum Imido Complexes
2004
Conformations of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis
2009 Nobel
Toleranz gegenüber funktionellen Gruppen bei frustrierten Lewis‐Paaren: Hydrierung von Nitroolefinen und Acrylaten
2013
Parent and trisubstituted triazacoronenes: synthesis, crystal structure and physicochemical properties
2015
Homogeneous Catalysis with Methane. A Strategy for the Hydromethylation of Olefins Based on the Nondegenerate Exchange of Alkyl Groups and σ-Bond Metathesis at Scandium
2003
Reaktionen frustrierter Lewis‐Paare mit konjugierten Inonen – selektive Hydrierung der Kohlenstoff‐Kohlenstoff‐Dreifachbindung
2011
Metal‐Free Catalytic Hydrogenation
2007
Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C–H Bond Activation, Cycloaddition, and Dehydrofluorination
2014
Back-Skip of the Growing Chain at Model Complexes for the Metallocene Polymerization Catalysis
1996
Copper-Catalyzed Direct Alkynylation of Electron-Deficient Polyfluoroarenes with Terminal Alkynes Using O2 as an Oxidant
2010
Investigations of the magnitude of steric and α deuterium kinetic isotope effects in a carboncarbon bond-forming reaction of a permethylscandocene complex
1991
Ladder-Type BN-Embedded Heteroacenes with Blue Emission
2013
The frustrated Lewis pair pathway to methylene phosphonium systems
2013
Advances in Non-Metallocene Olefin Polymerization Catalysis
2002 Standout
Alkene Carbon−Hydrogen Bond Activation at a Heterobimetallic Center: [RuCo(CO)3(μ-CO)(η-C5Me5){μ-η2:η2-C(CF3)C(CF3)}]
2004
Simple, Chemoselective, Catalytic Olefin Isomerization
2014
Neutral Group‐IV Metal Catalysts for the Intramolecular Hydroamination of Alkenes
2008
Olefin Isomerization and Hydrosilylation Catalysis by Lewis Acidic Organofluorophosphonium Salts
2013
A New Class of Zirconocene Catalysts for the Syndiospecific Polymerization of Propylene and Its Modification for Varying Polypropylene from Isotactic to Syndiotactic
1996
Reactivity of Organogold Compounds with B(C6F5)3: Gold–Boron Transmetalation via σ-B/π-Au Species
2014
Alkyl Complexes of Group 4 Metals Containing a Tridentate-Linked Amido−Cyclopentadienyl Ligand: Synthesis, Structure, and Reactivity Including Ethylene Polymerization Catalysis
1998
Mechanistic comparison of ruthenium olefin metathesis catalysts: DFT insight into relative reactivity and decomposition behavior
2006
The Thioether–Methyleneborane (PhSCH2B(C6F5)2)2: Synthesis and Reactivity with Donors and Alkynes
2011
The broadening reach of frustrated Lewis pair chemistry
2016 StandoutScience
Titanium-catalyzed iminohydrazination of alkynes
2005
Metallfreie Hydrierung von elektronenarmen Allenen und Alkenen
2012
Pressure Modulates Stereoregularities in the Polymerization of Propylene Promoted by rac-Octahedral Heteroallylic Complexes
1998
Neutral Yttrium Tris(amide) and Ate Complexes Coordinated by an (R)‐N,N′‐Diisopropyl‐1,1′‐binaphthyl‐2,2′‐diamido Ligand as Enantioselective Catalysts for Intramolecular Hydroamination
2007
Activation of H2 by Phosphinoboranes R2PB(C6F5)2
2008
Activation of Alkynes with B(C6F5)3 – Boron Allylation Reagents Derived from Propargyl Esters
2013
Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis
2008
An Enamine/HB(C6F5)2 Adduct as a Dormant State in Frustrated Lewis Pair Chemistry
2013
Lanthanides and actinides: Annual survey of their organometallic chemistry covering the years 2003 and 2004
2006
Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts: A Further Step toward an Optimum Balance between Antinomic Properties
2006
Agostic interactions in transition metal compounds
2007 Standout
Single-Component Polymerization Catalysts for Ethylene and Styrene: Synthesis, Characterization, and Reactivity of Alkyl and Hydrido Yttrium Complexes Containing a Linked Amido−Cyclopentadienyl Ligand
1999
Frustrierte Lewis‐Paare: metallfreie Wasserstoffaktivierung und mehr
2009
Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes
2007 Standout
Arene–perfluoroarene interactions in crystal engineering 8: structures of 1∶1 complexes of hexafluorobenzene with fused-ring polyaromatic hydrocarbons
2002
Homogeneous group 4 metallocene ziegler-natta catalysts: The influence of cyclopentadienyl-ring substituents
1994
Synthesis of BN-Fused Polycyclic Aromatics via Tandem Intramolecular Electrophilic Arene Borylation
2011
Selectivity in Propene Polymerization with Metallocene Catalysts
2000 Standout
Reactions of an Intramolecular Frustrated Lewis Pair with Unsaturated Substrates: Evidence for a Concerted Olefin Addition Reaction
2009
Zirconium-Catalyzed Enantioselective Alkylalumination of Monosubstituted Alkenes Proceeding via Noncyclic Mechanism
1996 StandoutNobel
Reversible Optical Transcription of Supramolecular Chirality into Molecular Chirality
2004 StandoutScienceNobel
Bimetallic Effects in Homopolymerization of Styrene and Copolymerization of Ethylene and Styrenic Comonomers: Scope, Kinetics, and Mechanism
2008
Construction of a Borole Ligand from Coordinated Diene and B(C6F5)3via Successive C−H Activation Steps: A Case of Catalyst Self-Activation
1998
Mechanism ofUnlikeStereoselectivity in 1-Alkene Primary Insertions: Syndiospecific Propene Polymerization by Brookhart-Type Nickel(II) Catalysts
2000
A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis
2015
Bioinspired Metal–Organic Framework for Trace CO2 Capture
2018
The synthesis and X-ray structure of trans-NiCl2(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)2; attempts to polymerize olefins utilizing a nickel(II) complex of a sterically demanding N-heterocyclic carbene
2003
Phosphine catalyzed reduction of CO2 with boranes
2014
Titanium Complexes Having Chelating Diaryloxo Ligands Bridged by Tellurium and Their Catalytic Behavior in the Polymerization of Ethylene
2000
Fluoride Ion Chelation By a Bidentate Phosphonium/Borane Lewis Acid
2008
Stoichiometric reductions of alkyl-substituted ketones and aldehydes to borinic esters
2014
Expanding the Scope of Metal‐Free Catalytic Hydrogenation through Frustrated Lewis Pair Design
2010
Stereoselective synthesis of enantiopure β, γ-disubstituted α-alkylideneγ-butyrolactones via A palladium(II) catalyzed cyclization
1995
Contrasting the Reactivity of Ethylene and Propylene with P/Al and P/B Frustrated Lewis Pairs
2013
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
Anomalous Stereoselectivity in the Wittig Reaction: The Role of Steric Interactions
2013
Silylium Ion/Phosphane Lewis Pairs
2013
Scandium-catalyzed C(sp3)–H alkylation of N,N-dimethyl anilines with alkenes
2017
Electronic effects of triarylphosphines in metal-free hydrogen activation: a kinetic and computational study
2013
Synthesis of Pyridine−Borane Complexes via Electrophilic Aromatic Borylation
2010
Stabilization of (Trialkylphosphine)ruthenium Alkylidene Metathesis Catalysts using Phosphine Exchange
2007
Reactions of (Diphenylphosphinomethyl)zirconocene Chloride with B(C6F5)3: Competition between P/B and P/Zr+ Frustrated Lewis Pair Reactions
2013
Metal-free transfer hydrogenation of olefins via dehydrocoupling catalysis
2014
Facile Carbon Monoxide Reduction at Intramolecular Frustrated Phosphane/Borane Lewis Pair Templates
2013
Die Ladungsumpolungs‐Analogie als Inspiration für die Synthese mehrzähniger Lewis‐saurer Borane
2003
Development of Mono- and Di-AcO Substituted BODIPYs on the Boron Center
2011
Reactivity of Scandium Terminal Imido Complex toward Boranes: C(sp3)–H Bond Borylation and B–O Bond Cleavage
2017
Synthesis, Structures, and Reactivity of Weakly Coordinating Anions with Delocalized Borate Structure: The Assessment of Anion Effects in Metallocene Polymerization Catalysts
2000
Stoichiometric Metal-Free Reduction of CO in Syn-Gas
2013
Lanthanocene Catalysts in Selective Organic Synthesis
2002
Synthesis and Catalytic Properties of Phenylene-Bridged Binuclear Organolanthanide Complexes
2008
Highly Active Metal‐Free Catalysts for Hydrogenation of Unsaturated Nitrogen‐Containing Compounds
2011
Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent N‐Oxyl Radical
2011
Single-Boron Complexes of N-Confused and N-Fused Porphyrins
2007
Perfluoroalkyl borates: congeners of perfluoroalkanes
2001
Synthesis and Structural Chemistry of Non-Cyclopentadienyl Organolanthanide Complexes
2002
Hydrogen Activation by an Intramolecular Boron Lewis Acid/Zirconocene Pair
2012
Interaction of benzene and 1,2-bis(chloromercurio)tetrafluorobenzene. Supramolecular frameworks based on Hg · · · Cl, Hg · · · F, Hg · · · π and π–π interactions
2000
Chiral Lanthanocene Derivatives Containing Two Linked Amido−Cyclopentadienyl Ligands: Heterobimetallic Structure and Lactone Polymerization Activity
1997
Experimental Evidence for γ-Agostic Assistance in β-Methyl Elimination, the Microscopic Reverse of α-Agostic Assistance in the Chain Propagation Step of Olefin Polymerization
2005
Supramolecular potentials and embraces for fluorous aromatic molecules
2000
Studies of Weakly Coordinating Anions Paired with Iodonium Cations
2002
Chiral Dienes as “Ligands” for Borane-Catalyzed Metal-Free Asymmetric Hydrogenation of Imines
2013
Chiral Molecular Tweezers: Synthesis and Reactivity in Asymmetric Hydrogenation
2015
Cationic Organometallic Complexes of Scandium, Yttrium, and the Lanthanoids
2006
Combinations of Ethers and B(C6F5)3 Function as Hydrogenation Catalysts
2013
Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts
2009 StandoutNobel
Reactions of Modified Intermolecular Frustrated P/B Lewis Pairs with Dihydrogen, Ethene, and Carbon Dioxide
2012
Taking the F out of FLP: Simple Lewis Acid–Base Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis
2012
Cationic Tricoordinate Boron Intermediates: Borenium Chemistry from the Organic Perspective
2012
Preparation of NHC–ruthenium complexes and their catalytic activity in metathesis reaction
2006
ansa‐Zirconocenium catalysis of syndiospecific polymerization of propylene: Theory and experiment
1995
Synthesis, Characterization, Physical Properties, and OLED Application of Single BN-Fused Perylene Diimide
2014
Alkene Metathesis: The Search for Better Catalysts
2007
Chelating Bis(thiophosphinic amidate)s as Versatile Supporting Ligands for the Group 3 Metals. An Application to the Synthesis of Highly Active Catalysts for Intramolecular Alkene Hydroamination
2003
New Scandium Borylimido Chemistry: Synthesis, Bonding, and Reactivity
2017
B(C6F5)3 promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds
2014
Indolocarbazole-Based Ligands for Ladder-Type Four-Coordinate Boron Complexes
2012
Proline-modified poly(propyleneimine) dendrimers as catalysts for asymmetric aldol reactions
2005
Planarized Triarylboranes: Stabilization by Structural Constraint and Their Plane-to-Bowl Conversion
2012
Advances in the Synthesis of Organoborane Polymers for Optical, Electronic, and Sensory Applications
2010 Standout
Efficient intramolecular hydroamination of aminoalkynes catalyzed by a zirconium(IV) complex
2008
Iron-Catalyzed ortho-Selective C–H Borylation of 2-Phenylpyridines and Their Analogs
2017
Frustrated Lewis Pairs
2015 Standout
Activation of olefins via asymmetric Brønsted acid catalysis
2018 StandoutScienceNobel
α-CH acidity of alkyl–B(C6F5)2 compounds – the role of stabilized borata-alkene formation in frustrated Lewis pair chemistry
2014
Nitrene Radical Intermediates in Catalytic Synthesis
2017
Selectivity Control By Temperature Variation in the Formation of Isotactic vs. Syndiotactic Polypropylene with a Titanocene/Alumoxane Catalyst
1992
Intramolecular frustrated N/B lewis pairs by enamine hydroboration
2011
Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs
2014
Calcium-Mediated Intramolecular Hydroamination Catalysis
2005
B(C6F5)3‐Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond
2014
Kinetic Investigation of the Polymerization of 1-Hexene by the {[t-BuNON]ZrMe}[B(C6F5)4] Initiator
2001 StandoutNobel
Metal‐free Catalytic Olefin Hydrogenation: Low‐Temperature H2 Activation by Frustrated Lewis Pairs
2012
Ruthenium Alkylidenes: Fast Initiators for Olefin Metathesis
2005
Reaction of a Bridged Frustrated Lewis Pair with Nitric Oxide: A Kinetics Study
2013
Iridium Complexes withN-Allyl-Substituted Benzimidazol-2-ylidene Ligands and Their Application in Catalytic Transfer Hydrogenation
2005
Facile Activation of H–H and Si–H Bonds by Boranes
2012
Frustrated Lewis pair olefin addition reactions: P-, N-, C- and H-based nucleophilic additions to an olefin-tethered borane
2012
Expanding the Scope of Metal‐Free Catalytic Hydrogenation through Frustrated Lewis Pair Design
2010
Modeling Metal-Catalyzed Olefin Polymerization
2000
Polymerization of α-Olefins by Chelating Diamide Complexes of Titanium
1996
Ruthenium Metallacycles Derived from 14-Electron Complexes. New Insights into Olefin Metathesis Intermediates
2006 Nobel
Dehydrofluorination of Hydrofluorocarbons by Titanium Alkylidynes via Sequential C−H/C−F Bond Activation Reactions. A Synthetic, Structural, and Mechanistic Study of 1,2-CH Bond Addition and β-Fluoride Elimination
2008
Synthesis, structure and properties of C3-symmetric heterosuperbenzene with three BN units
2015
CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ‐Allyl Complexes
2012
Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes
2010
Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications
2016 Standout
Revisiting the optical signatures of BODIPY with ab initio tools
2013
On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration
2009
Internal Alkene Hydroaminations Catalyzed by Zirconium(IV ) Complexes and Asymmetric Alkene Hydroaminations Catalyzed by Yttrium(III ) Complexes
2006
C−H Bond Activation Processes in Cationic and Neutral Titanium Benzyl Compounds with Cyclopentadienyl−Arene Ligands
2002
Asymmetric Enamine Catalysis
2007 StandoutNobel
Large Stokes Shift Induced by Intramolcular Charge Transfer in N,O-Chelated Naphthyridine–BF2 Complexes
2012
Constrained Geometry Organolanthanide Catalysts. Synthesis, Structural Characterization, and Enhanced Aminoalkene Hydroamination/Cyclization Activity
1999
Chelating diamide complexes of titanium: new catalyst precursors for the highly active and living polymerization of α-olefins
1998
Group-4 Dipyrrolylmethane Complexes in Intramolecular Olefin Hydroamination
2008
Intramolecular B/N frustrated Lewis pairs and the hydrogenation of carbon dioxide
2015
Complexation of Nitrous Oxide by Frustrated Lewis Pairs
2009
Decomposition of Ruthenium Olefin Metathesis Catalysts
2007 Nobel
C−H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their Reactivities
2009
The Coordination Chemistry of the CF Unit in Fluorocarbons
1997
C−F Bond Activation in Organic Synthesis
2009
Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds
2016
Palladium‐Catalyzed Double Cross‐Coupling Reactions of Organodimetallic Reagents Leading to Polycyclic Aromatic Hydrocarbons
2013
Catalytic metal-free Si–N cross-dehydrocoupling
2014
Transition Metal Complexation of σ Bonds
1993
Metal-Free Borane-Catalyzed Highly Stereoselective Hydrogenation of Pyridines
2013
Reducing CO2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism of Phosphine–Borane-Mediated Hydroboration of CO2
2014
Stereospezifische Olefinpolymerisation mit chiralen Metallocenkatalysatoren
1995
Synthesis and fluorescence properties of isoindoline–benzazole-based boron difluoride complexes
2013
Ruthenium‐Based NHC‐Arene Systems as Ring‐Opening Metathesis Polymerisation Catalysts
2007
1,1‐Carbozirconation: Unusual Reaction of an Alkyne with a Methyl Zirconocene Cation and Subsequent Frustrated Lewis Pair Like Reactivity
2013
Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds
1996 StandoutNobel
Redox-active, near-infrared dyes based on ‘Nindigo’ (indigo-N,N′-diarylimine) boron chelate complexes
2012
A Highly Enantioselective Hydrogenation of Silyl Enol Ethers Catalyzed by Chiral Frustrated Lewis Pairs
2014
Ruthenium aryloxide catalysts: Synthesis and applications in ring-closing metathesis
2006
Non-metallocene rare earth metal catalysts for the diastereoselective and enantioselective hydroamination of aminoalkenes
2005
A Straightforward Strategy toward Large BN-Embedded π-Systems: Synthesis, Structure, and Optoelectronic Properties of Extended BN Heterosuperbenzenes
2014
A Zwitterionic Zirconocene Alkyl Complex as a Single-Component α-Olefin Dimerization Catalyst
1998
A Unique Frustrated Lewis Pair Pathway to Remarkably Stable Borata–Alkene Systems
2013
Molecular mechanics study of zirconocenium catalyzed isospecific polymerization of propylene
1995
Weakly Coordinating Al-, Nb-, Ta-, Y-, and La-Based Perfluoroaryloxymetalate Anions as Cocatalyst Components for Single-Site Olefin Polymerization
2002
Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships
2000 Standout
Rhodium N-heterocyclic carbene complexes: Synthesis, structure, NMR studies and catalytic activity
2005
Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions
2006
Reactions of Zinc Dialkyls with (Perfluorophenyl)boron Compounds: Alkylzinc Cation Formation vs C6F5 Transfer
2001
Phosphorus as a Lewis Acid: CO2 Sequestration with Amidophosphoranes
2012
β-Diketiminate complexes of the first row transition metals: applications in catalysis
2017
On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o-R2P(Ph)BR‘2
2006
Catalytic CO2 Activation Assisted by Rhenium Hydride/B(C6F5)3 Frustrated Lewis Pairs—Metal Hydrides Functioning as FLP Bases
2013
Effects of NHC-Backbone Substitution on Efficiency in Ruthenium-Based Olefin Metathesis
2009 Nobel
The role of agostic H Zr interactions in the insertion of olefins with metallocene catalysts. An MO study
1993
CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ‐Allyl Complexes
2012
Enantioselective Hydrogenation with Chiral Frustrated Lewis Pairs
2010
Reversible, Metal-Free Hydrogen Activation
2006 StandoutScience
Model Compounds of Ruthenium−Alkene Intermediates in Olefin Metathesis Reactions
2006 Nobel
Influence of alkyl chain length on the solid-state properties and transistor performance of BN-substituted tetrathienonaphthalenes
2014
Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid
2002 StandoutScienceNobel
Cationic Aluminum Alkyl Complexes Incorporating Aminotroponiminate Ligands
2001
Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes
2008 Nobel
Titanium Dichloro, Bis(carbyl), Aryne, and Alkylidene Complexes Stabilized by Linked Cyclopentadienyl−Amido Auxiliary Ligands
1997
Chemistry on Boranils: An Entry to Functionalized Fluorescent Dyes
2012
Understanding Ni(II)-Mediated C(sp3)–H Activation: Tertiary Ureas as Model Substrates
2018
Lanthanides and actinides: Annual survey of their organometallic chemistry covering the years 2001 and 2002
2006
Olefin–Borane “van der Waals Complexes”: Intermediates in Frustrated Lewis Pair Addition Reactions
2011
From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids
2001 Standout
Works of Warren E. Piers being referenced
9‐Boraanthracene Derivatives Stabilized by N‐Heterocyclic Carbenes
2009
5b,7b-Diaza-3b,9b-diborabenzo[ ghi ]perylenes
2010
BN‐Dibenzo[a,o]picenes: Analogues of an Unknown Polycyclic Aromatic Hydrocarbon
2013
2,2′-Disubstituted F12binaphthyl derivatives: stannanes, boranes, and (R)-F12BINOL
2006
10a‐Aza‐10b‐borapyrenes: Heterocyclic Analogues of Pyrene with Internalized BN Moieties
2007
Photochemical Synthesis of a Ladder Diborole: A New Boron‐Containing Conjugate Material
2012
Cyclic boronium and borenium cations derived from borabenzene–pyridine complexes
2005
Enforced Planarity: A Strategy for Stable Boron‐Containing π‐Conjugated Materials
2012
Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations
2014
Bimolecular Extrusion of TeR2 from -Diketiminato Supported Scandium Bis-tellurolates
2000
Borenium cations derived from BODIPY dyes
2008
Synthesis and Comparative Characterization of 9‐Boraanthracene, 5‐Boranaphthacene, and 6‐Borapentacene Stabilized by the H2IMes Carbene
2010
Arene Complexes of β‐Diketiminato Supported Organoscandium Cations: Mechanism of Arene Exchange and Alkyne Insertion in Solvent Separated Ion Pairs
2006
Reversible insertion of carbon dioxide into Pt(ii)–hydroxo bonds
2013
Benzo‐ and Naphthoborepins: Blue‐Emitting Boron Analogues of Higher Acenes
2009
Perfluoropentaphenylborole
2009
High Stokes Shift Anilido‐Pyridine Boron Difluoride Dyes
2011
Heterolytic H2 Activation by Nonmetals
2007
Thermal Decomposition Modes for Four‐Coordinate Ruthenium Phosphonium Alkylidene Olefin Metathesis Catalysts
2008
Rapidly Initiating Ruthenium Olefin‐Metathesis Catalysts
2004
Borinium, Borenium, and Boronium Ions: Synthesis, Reactivity, and Applications
2005
2,2′‐Diborabiphenyl: A Lewis Acid Analogue of 2,2′‐Bipyridine
2003
Methane Loss from Cationic μ-Methyl Dimers Formed via Trityl Borate Activation of Monocyclopentadienyl Ketimide Complexes Cp[(tBu)2CN]Ti(CH3)2 (Cp = C5H5, C5Me5, C5Me4SiMe3)
2001
Reactions of Bis(pentafluorophenyl)borane with Cp2Ta(CH2)CH3: Generation and Trapping of Tantalocene Borataalkene Complexes
2001
9‐Boraanthracene Derivatives Stabilized by N‐Heterocyclic Carbenes
2009
Permethyltitanocene Tellurides and Ditellurides. X-ray Structures of [(C5Me5)2Ti]2(.mu.-Te) and (C5Me5)2Ti(.eta.2-Te2)
1995
B(C6F5)3-Catalyzed Silation of Alcohols: A Mild, General Method for Synthesis of Silyl Ethers
1999
Synthesis, Characterization, and Fluorescence Behavior of Twisted and Planar B2N2-Quaterphenyl Analogues
2007
Hydroboration of vinyl silanes with bis-(pentafluorophenyl)borane: Ground state β-silicon effects
1998
Coordinatively unsaturated binuclear clusters of rhodium. The reactivity of [{Pri2P(CH2)nPPri2}Rh]2(μ-H)2 (n = 2, 3, and 4) with dihydrogen, and their use in the catalytic hydrogenation of olefins
1989
Spirocyclic boronium ions: precursors to persistent neutral radicals
2009
Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4
2003
Competing Pathways in the Reaction of Bis(pentafluorophenyl)borane with Bis(η5‐cyclopentadienyl)dimethylzirconium: Methane Elimination versus Methyl–Hydride Exchange and an Example of Pentacoordinate Carbon
1995
Crystal Structure of (Pentamethylcyclopentadienyl)- (π-η5:σ-η1-tetramethylfulvene)titanium(III)
1996
Mechanistic Aspects of the Reactions of Bis(pentafluorophenyl)borane with the Dialkyl Zirconocenes Cp2ZrR2(R = CH3, CH2SiMe3, and CH2C6H5)
1998
β-Diketiminato Scandium Chemistry: Attempted Deprotonation of Cationic Amido Complexes
2006
Heterolytische H2‐Aktivierung durch Nichtmetalle
2007
BN‐Dibenzo[a,o]picenes: Analogues of an Unknown Polycyclic Aromatic Hydrocarbon
2013
Bifunctional Perfluoroaryl Boranes: Synthesis and Coordination Chemistry with Neutral Lewis Base Donors
2005
Comparative Lewis Acidity in Fluoroarylboranes: B(o-HC6F4)3, B(p-HC6F4)3, and B(C6F5)3
2012
High Stokes Shift Anilido‐Pyridine Boron Difluoride Dyes
2011
Intramolecular Ion−Ion Interactions in Zwitterionic Metallocene Olefin Polymerization Catalysts Derived from “Tucked-In” Catalyst Precursors and the Highly Electrophilic Boranes XB(C6F5)2(X = H, C6F5)
1997
Anion Stability in Stannylium, Oxonium, and Silylium Salts of the Weakly Coordinating Anion [C6F4-1,2-{B(C6F5)2}2(μ-OCH3)]-
2001
Mechanistic insights into perfluoroaryl borane-catalyzed allylstannations: Toward asymmetric induction with chiral boranes
2004
Generation and Spectroscopic Characterization of Ruthenacyclobutane and Ruthenium Olefin Carbene Intermediates Relevant to Ring Closing Metathesis Catalysis
2008
Attachment of C5Me4HSi(Me2)NH-t-C4H9 to yttrium via amine elimination. X-ray structure of [(η5-C5Me4)Si(Me2)-η1-N-t-C4H9]YN(SiMe3)2
1995
Studies on the Mechanism of B(C6F5)3-Catalyzed Hydrosilation of Carbonyl Functions
2000
Ketone coordination chemistry of the diborane t-BuCH=C[B(C6F5)2]2
1998
Scandium-Catalyzed Intramolecular Hydroamination. Development of a Highly Active Cationic Catalyst
2004
Reactions of Bis(pentafluorophenyl)borane with Phosphine Olefin Complexes of Zirconocene
1996
Carbon Monoxide Activation via O-Bound CO Using Decamethylscandocinium–Hydridoborate Ion Pairs
2012
Selective Hydrosilation of CO2 to a Bis(silylacetal) Using an Anilido Bipyridyl‐Ligated Organoscandium Catalyst
2013
Synthesis, characterization and olefin metathesis studies of a family of ruthenium phosphonium alkylidene complexes
2005
Bronsted acid-catalyzed skeletal rearrangements in polycyclic conjugated boracycles: a thermal route to a ladder diborole
2014
A New Chelating Anilido-Imine Donor Related to β-Diketiminato Ligands for Stabilization of Organoyttrium Cations
2003
Cationic Organoscandium β-Diketiminato Chemistry: Arene Exchange Kinetics in Solvent Separated Ion Pairs
2003
B(C 6 F 5 ) 3 catalyzed hydrosilation of enones and silyl enol ethers
2002
Design, Synthesis, and Characterization of Functionalized Silepins: High Quantum Yield Blue Emitters
2011
ChemInform Abstract: B(C6F5)3‐Catalyzed Hydrosilation of Imines via Silyliminium Intermediates.
2001
Synthesis of the diborylated ferrocene 1,1'-bis-(bis-pentafluorophenylboryl)ferrocene and the X-ray structure of its trimethylphosphine adduct
2001
Coping With Extreme Lewis Acidity: Strategies for the Synthesis of Stable, Mononuclear Organometallic Derivatives of Scandium
1990
Tris(pentafluorophenyl)boron-Catalyzed Hydrosilation of Aromatic Aldehydes, Ketones, and Esters
1996
Organometallic Complexes of Scandium and Yttrium Supported by a Bulky Salicylaldimine Ligand
2002
Triphenylene Analogues with B2N2C2 Cores: Synthesis, Structure, Redox Behavior, and Photophysical Properties
2006
Cationic Scandium Methyl Complexes Supported by a β-Diketiminato (“Nacnac”) Ligand Framework
2002
Mechanistic Studies on the B(C6F5)3 Catalyzed Allylstannation of Aromatic Aldehydes with Ortho Donor Substituents
2002
Solution and Solid-State Characteristics of Imine Adducts with Tris(pentafluorophenyl)borane
2002
Activation of [Cp2ZrMe2] with New Perfluoroaryl Diboranes: Solution Chemistry and Ethylene Polymerization Behavior in the Presence of MeAl(BHT)2
1999
Mechanistic Aspects of Bond Activation with Perfluoroarylboranes
2011
Decamethylscandocinium-hydrido-(perfluorophenyl)borate: fixation and tandem tris(perfluorophenyl)borane catalysed deoxygenative hydrosilation of carbon dioxide
2013
Reactions of Bis(pentafluorophenyl)borane with Cp2Ta(CH2)CH3
1999
Synthesis and thermal behavior of dimethyl scandium complexes featuring anilido-phosphinimine ancillary ligands
2007
Blue Fluorescent 4a-Aza-4b-boraphenanthrenes
2007
Synthesis and Reactivity of a Terminal Scandium Imido Complex
2012
Synthesis, Structure, and Ion Pair Dynamics of β-Diketiminato-Supported Organoscandium Contact Ion Pairs
2005
Activation of Si–H bonds across the nickel carbene bond in electron rich nickel PCcarbeneP pincer complexes
2015
Facile hydrogen atom transfer to iron(iii ) imido radical complexes supported by a dianionic pentadentate ligand
2016
Benzo[b]thiophene-Fused Boron and Silicon Ladder Acenes
2013
Bis(pentafluorophenyl)borane: Synthesis, Properties, and Hydroboration Chemistry of a Highly Electrophilic Borane Reagent
1995
(R)-1,1′-Binaphthyl-2-bis(pentafluorophenyl)borane Lewis Acids
2004
Isomeric Dipyrrinato and Dipyrromethanato Boranes
2011
Competitive ArC−H and ArC−X (X = Cl, Br) Activation in Halobenzenes at Cationic Titanium Centers
2006
Trimethylphosphine–tris(pentafluorophenyl)borane
2006
Isobutene Polymerization Using a Chelating Diborane Co-Initiator
2003
The solid-state structure of bis(pentafluorophenyl)zinc
1998
Bis(pentafluorphenyl)boran: Synthese, Eigenschaften und Hydroborierungschemie eines sehr elektrophilen Borans
1995
Synthesis, characterization and chemistry of bis-(pentafluorophenyl)boryl ferrocene
2001
Reaction of olefins and dienes with binuclear rhodium hydride complexes to generate bridging alkenyl, dienyl and diene units
1988
New Bifunctional Perfluoroaryl Boranes. Synthesis and Reactivity of the ortho-Phenylene-Bridged Diboranes 1,2-[B(C6F5)2]2C6X4 (X = H, F)‘
1999
Divergent Reactivity of Perfluoropentaphenylborole with Alkynes
2010
Aqueous Suspension Polymerization of Isobutene Initiated by 1,2-C6F4[B(C6F5)2]2
2004
Weaker Lewis Acid, Better Catalytic Activity: Dual Mechanisms in Perfluoroarylborane-Catalyzed Allylstannation Reactions
2003
Reactions of Neutral Cobalt(II) Complexes of a Dianionic Tetrapodal Pentadentate Ligand: Cobalt(III) Amides from Imido Radicals
2017
7:8,9:10-Dibenzo-1,2,3,4-tetrafluoro- triphenylene: Synthesis, Structure, and Photophysical Properties of a Novel [5]Helicene
2005
Borinium‐, Borenium‐ und Boroniumionen: Synthese, Reaktivität, Anwendung
2005
Reaction of pentaarylboroles with carbon monoxide: an isolable organoboron carbonyl complex
2012
Future Trends in Organometallic Chemistry: Organometallic Approaches to Water Splitting
2011
Mechanistic Studies on 14-Electron Ruthenacyclobutanes: Degenerate Exchange with Free Ethylene
2007
Synthesis and thermal reactivity of organoscandium and yttrium complexes of sterically less bulky salicylaldiminato ligandsElectronic supplementary information (ESI) available: Further experimental details. See http://www.rsc.org/suppdata/dt/b3/b303097k/
2003
Accelerated Ligand Metalation in a β-Diketiminato Scandium Dimethyl Complex Activated with Bis(pentafluorophenyl)borane
2007
Zwitterionic Metallocenes
1998
Erzwungene Planarität: eine Strategie für stabile, borhaltige π‐konjugierte Materialien
2012
Nucleophilic Degradation of a β-Diketiminato Ancillary by a Transient Scandium Hydride Intermediate
2009
Dihydrogen Activation with tBu3P/B(C6F5)3: A Chemically Competent Indirect Mechanism via in Situ-Generated p-tBu2P–C6F4–B(C6F5)2
2011
Bifunctional Lewis Acids. Synthesis and Olefin Polymerization Chemistry of the 1,1-Di[bis(perfluorophenyl)boryl]alkenes RCHC[B(C6F5)2]2 (R = t-Bu, C6H5, C6F5)
1998
Reactivity of Scandium β-Diketiminate Alkyl Complexes with Carbon Dioxide
2012
.alpha. Agostic assistance in Ziegler-Natta polymerization of olefins. Deuterium isotopic perturbation of stereochemistry indicating coordination of an .alpha. carbon-hydrogen bond in chain propagation
1990
Synthesis and Solution and Solid-State Structures of Tris(pentafluorophenyl)borane Adducts of PhC(O)X (X = H, Me, OEt, NPri2)
1998
B-N as a C-C substitute in aromatic systems
2008
Reactions of binuclear rhodium hydrides with imines: factors influencing the insertion of carbon-nitrogen double bonds into rhodium-hydride bonds
1990
Zwitterionic alkene polymerization catalyst derived from Cp2Zr(η2-C2H4)PPh2Me and B(C6F5)3
1998
Activation of Water, Ammonia, and Other Small Molecules by PCcarbeneP Nickel Pincer Complexes
2013
One-Component Group 4 Homogeneous Ziegler-Natta Olefin Polymerization Catalysts: Hydroboration of Zirconium Bisalkyls with Pendant 2-Propenyl Groups Using [(C6F5)2BH]2
1995
Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide
2010
Use of Alkane Elimination in the One-Step Synthesis of Organoscandium Complexes Containing a New Multidentate Cyclopentadienyl Ligand
1996
A Photo Lewis Acid Generator (PhLAG): Controlled Photorelease of B(C6F5)3
2012
Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand
2002
Highly Lewis Acidic Bifunctional Organoboranes
2000
A new family of monocyclopentadienyl organoscandium bis-alkyls supported by a bulky trialkylphosphine oxide ancillary
2004
B(C6F5)3-Catalyzed Hydrosilation of Imines via Silyliminium Intermediates
2000
Aktivierung von [Cp2ZrMe2] mit neuartigen Perfluoraryl-substituierten Diboranen: Chemie in Lösung und Verhalten bei der Polymerisation von Ethen in Gegenwart von MeAl(BHT)2
1999
Synthesis and Characterization of (Perfluoroaryl)borane-Functionalized Carbosilane Dendrimers and Their Use as Lewis Acid Catalysts for the Hydrosilation of Acetophenone
2002
Zirconium complexes of a cyclopentadienyl-amido ligand with a pendant amine donor via amine and alkane elimination
1996
Mechanistic Studies on Selectivity in the B(C6F5)3-Catalyzed Allylstannation of Aldehydes: Is Hypercoordination at Boron Responsible?
2000
Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design
2002
Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene
2013
Low-Coordinate Organoyttrium Complexes Supported by β-Diketiminato Ligands
2009
Synthesis, Properties, and Hydroboration Activity of the Highly Electrophilic Borane Bis(pentafluorophenyl)borane, HB(C6F5)21
1998
Pentafluorophenylboranes: from obscurity to applications
1997
β-Diketiminato Scandium Chemistry: Synthesis, Characterization, and Thermal Behavior of Primary Amido Alkyl Derivatives
2004
10a‐Aza‐10b‐borapyrenes: Heterocyclic Analogues of Pyrene with Internalized BN Moieties
2007
Novel Trityl Activators with New Weakly Coordinating Anions Derived from C6F4-1,2-[B(C6F5)2]2: Synthesis, Structures, and Olefin Polymerization Behavior
2000
Dihydrogen Activation by Antiaromatic Pentaarylboroles
2010
Dialkylscandium Complexes Supported by β-Diketiminato Ligands: Synthesis, Characterization, and Thermal Stability of a New Family of Organoscandium Complexes
2001
Mechanistic Studies on the Metal-Free Activation of Dihydrogen by Antiaromatic Pentarylboroles
2012
η1 versus η5 Bonding Modes in Cp*Al(I) Adducts of 9-Borafluorenes
2003
Konkurrierende Reaktionswege bei der Reaktion von Bis(pentafluorphenyl)boran mit Bis(η5‐cyclopentadienyl)dimethylzirconium: Methan‐Eliminierung oder Methyl‐Hydrid‐Austausch und ein Beispiel für fünffach koordinierten Kohlenstoff
1995
Isobutene Polymerization Using Chelating Diboranes: Polymerization in Aqueous Suspension and Hydrocarbon Solution
2008
Synthesis and characterization of mono-(pentamethylcyclopentadienyl)alkoxyscandium alkyl derivatives, (η5-C5Me5)(OR)ScR′
1991
Sterically Enforced Linearity in a Bridging Telluride Ligand. X-ray Structure of{(CH3)2Si[(tert-C4H9)C5H3]2Sc(PMe3)}2(.mu.-Te).cntdot.C6H6
1994
Rapidly Initiating Ruthenium Olefin‐Metathesis Catalysts
2004
Synthesis and Chemistry of Zwitterionic Tantala-3-boratacyclopentenes: Olefin-like Reactivity of a Borataalkene Ligand
2002
B−H Bond Activations in the Alkane Analogues H3B⋅PR3
2000
Perfluoroaryl-Substituted Boron Dipyrrinato Complexes
2009
Zwitterionic metallocenes via reactions of organozirconocenes with highly electrophilic perfluorophenyl substituted boranes
1999
2,2′‐Diborabiphenyl: A Lewis Acid Analogue of 2,2′‐Bipyridine
2003
New ligand environments for soluble Zieglernatta olefin polymerization catalyst precursors. X-ray structures of
1995
Synthesis of Dialkylscandium Complexes Supported by β-Diketiminato Ligands and Activation with Tris(pentafluorophenyl)borane
1999
Efficient synthetic methods for the installation of boron–nitrogen bonds in conjugated organic molecules
2015
New Fluorinated 9-Borafluorene Lewis Acids
2000
Titanium-Mediated Heterodehydrocoupling of Tributylstannane and Tellurium. X-ray Structure of (C5Me5)2TiTeSn(C6H5)3
1996
Bimolecular Extrusion of TeR2 from β-Diketiminato Supported Scandium Bis-tellurolates
2000
Direct Observation of a 14-Electron Ruthenacyclobutane Relevant to Olefin Metathesis
2005