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Citing Papers
Potassium t -Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes
2008
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2010 StandoutNobel
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2009
Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant
2012
Regioselective copper-catalyzed chlorination and bromination of arenes with O2 as the oxidant
2009
Selective Rhodium(III)‐Catalyzed Cross‐Dehydrogenative Coupling of Furan and Thiophene Derivatives
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Stereospecific Copper‐Catalyzed CH Allylation of Electron‐Deficient Arenes with Allyl Phosphates
2011
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Copper‐Catalyzed Direct Carboxylation of CH Bonds with Carbon Dioxide
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Selective Synthesis of [12]Cycloparaphenylene
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Fluorescent Diarylindoles by Palladium‐Catalyzed Direct and Decarboxylative Arylations of Carboxyindoles
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Charge and Spin Transport in an Organic Molecular Square
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2014
Palladium‐ and Nickel‐Catalyzed Direct Alkylation of Azoles with Unactivated Alkyl Bromides and Chlorides
2010
Palladium‐Catalyzed β‐Selective Direct Arylation of Porphyrins
2011
Direct Arylation of Thiazoles on Water
2007
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
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2011
Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds
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Direct arylations on water: synthesis of 2,5-disubstituted oxazoles balsoxin and texaline
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Iron‐Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides
2010
Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality
2009 Standout
An Efficient Bimetallic Rhodium Catalyst for the Direct Arylation of Unactivated Arenes
2007
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2014 Standout
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2012
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2009
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2008
Direct C–H bond arylation of arenes with aryltin reagents catalysed by palladium complexes
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Recent advances in aryl–aryl bond formation by direct arylation
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Phosphine‐Free, Palladium‐Catalyzed Arylation of Heterocycles through CH Bond Activation with Pivalic Acid as a Cocatalyst
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Relativistic effects in homogeneous gold catalysis
2007 StandoutNature
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2012
Oxidative Cross‐Coupling of Arenes Induced by Single‐Electron Transfer Leading to Biaryls by Use of Organoiodine(III) Oxidants
2007
Enzymatic functionalization of carbon–hydrogen bonds
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Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
2010 StandoutNobel
Direct transition metal-catalyzed functionalization of heteroaromatic compounds
2007 Standout
Tris(pentafluorophenyl)borane: a special boron Lewis acid for special reactions
2005
Fe‐Catalyzed Oxidative Coupling of Heteroarenes and Methylamines
2009
Airway Mucus Function and Dysfunction
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2012
Ruthenium‐Catalyzed Oxidative Cross‐Coupling of Chelating Arenes and Cycloalkanes
2008
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2010
Recent Progress in Coupling of Two Heteroarenes
2011
Catalytic Asymmetric Synthesis of Phosphine Boronates
2015 StandoutNobel
Copper(ii)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides
2011
Importance of palladium–carbon bond energies in direct arylation of polyfluorinated benzenes
2010
Oxidative Biaryl Coupling of Thiophenes and Thiazoles with Arylboronic Acids through Palladium Catalysis: Otherwise Difficult C4‐Selective CH Arylation Enabled by Boronic Acids
2011
Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents
2010
Ligand-free copper(i)-catalysed intramolecular direct C–H functionalization of azoles
2009
TRPA1 Mediates the Inflammatory Actions of Environmental Irritants and Proalgesic Agents
2006 StandoutNobel
Transition‐Metal‐Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage
2009 Standout
Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages
2009
CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems
2010
Iron‐Mediated Direct Arylation of Unactivated Arenes
2008
Copper‐Catalyzed Oxidative Arylation of Heteroarenes under Mild Conditions Using Dioxygen as the Sole Oxidant
2011
Beyond Directing Groups: Transition‐Metal‐Catalyzed CH Activation of Simple Arenes
2012 Standout
Engineering the third wave of biocatalysis
2012 StandoutNature
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2016 StandoutNobel
Cationic Rh(I)/Modified-BINAP-Catalyzed Reactions of Carbonyl Compounds with 1,6-Diynes Leading to Dienones and Ortho-Functionalized Aryl Ketones
2007
Establishment of Broadly Applicable Reaction Conditions for the Palladium-Catalyzed Direct Arylation of Heteroatom-Containing Aromatic Compounds
2009
Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates
2008 Standout
Direct Arylation of Simple Azoles Catalyzed by 1,10-Phenanthroline Containing Palladium Complexes: An Investigation of C4 Arylation of Azoles and the Synthesis of Triarylated Azoles by Sequential Arylation
2011
Copper‐Catalyzed Direct Carboxylation of CH Bonds with Carbon Dioxide
2010
Pd-Catalyzed β-Selective Direct C–H Bond Arylation of Thiophenes with Aryltrimethylsilanes
2012
Ruthenium‐Catalyzed Oxidative Homo‐Coupling of 2‐Arylpyridines
2009
Copper-Mediated Direct Arylation of 1,3,4-Oxadiazoles and 1,2,4-Triazoles with Aryl Iodides
2009
3d Transition Metals for C–H Activation
2018 Standout
Fluorine in medicinal chemistry
2007 Standout
Modulating Reactivity and Diverting Selectivity in Palladium-Catalyzed Heteroaromatic Direct Arylation Through the Use of a Chloride Activating/Blocking Group
2010
Palladiumkatalysierte oxidative Kupplung von Thiophenen und Thiazolen mit Arylboronsäuren: ungewöhnliche C4‐selektive C‐H‐Arylierung durch den Einsatz von Boronsäuren
2011
Neue und selektive Übergangsmetall-katalysierte Reaktionen von Allenen
2000
Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis
2016 Standout
Copper-Catalyzed Selective Benzylic C–O Cyclization ofN-o-Tolylbenzamides: Synthesis of 4H-3,1-Benzoxazines
2012
Cu(II)-Mediated Methylthiolation of Aryl C−H Bonds with DMSO
2010
Iron‐Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides
2010
Emergence of Copper‐Mediated Formation of C–C Bonds
2016
Direct arylation of imidazo[2,1‐b]thiazoles and thiazoles with aryl iodides via CuCl2/PPh3‐catalyzed C–H bond functionalization
2015
Palladium‐Catalyzed β‐Selective Direct Arylation of Porphyrins
2011
Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates
2009
C4‐Selective Oxidative Coupling of Thiophenes with Arylboron Compounds: Influence of Solvent Acidity and Boron Substitution
2013
Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction
2009
Organic Photoredox Catalysis
2016 Standout
Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology
2005 Standout
Anatomy and Neurophysiology of the Cough Reflex
2006
Efficient and highly regioselective direct C-2 arylation of azoles, including free (NH)-imidazole, -benzimidazole and -indole, with aryl halides
2006
Recent Advances in Copper-mediated Direct Biaryl Coupling
2015
C–H Arylation Reaction: Atom Efficient and Greener Syntheses of π-Conjugated Small Molecules and Macromolecules for Organic Electronic Materials
2013
Site-Selective Azaindole Arylation at the Azine and Azole Rings via N-Oxide Activation
2009
Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
2008 Standout
Straightforward access to aryl-substituted tetrathiafulvalenes by palladium-catalysed direct C–H arylation and their photophysical and electrochemical properties
2011
Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A
2012
C−C Bond Formation via C−H Bond Activation Under Protic Conditions: On the Role of Phosphane Ligand and Cosolvent
2009
Direct Arylation as a Synthetic Tool for the Synthesis of Thiophene-Based Organic Electronic Materials
2011
Strained Dehydrobenzoannulenes
2006
Iron‐Mediated Direct Arylation of Unactivated Arenes
2008
Tandem Catalysis: Alcohol Oxidation and CC Bond Formation via CH Bond Activation
2011
Mild and efficient palladium-catalyzed intramolecular direct arylation reactions
2008
Catalysis for the Valorization of Exhaust Carbon: from CO2to Chemicals, Materials, and Fuels. Technological Use of CO2
2013 Standout
Palladium-Catalyzed Direct Arylation of Azine and Azole N-Oxides: Reaction Development, Scope and Applications in Synthesis
2009
Palladium-Catalyzed C–H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation
2012
Aromatic C–H coupling with hindered arylboronic acids by Pd/Fe dual catalysts
2013
C−H Activation for the Construction of C−B Bonds
2009 Standout
Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective
2008 Standout
Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts
2007
Cp2Ni-KOt-Bu-BEt3 (or PPh3) Catalyst System for Direct C−H Arylation of Benzene, Naphthalene, and Pyridine
2009
Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene
2010
Ruthenium‐Catalyzed Oxidative Cross‐Coupling of Chelating Arenes and Cycloalkanes
2008
The Sonogashira Reaction: A Booming Methodology in Synthetic Organic Chemistry
2007 Standout
C–H arylation and alkenylation of imidazoles by nickel catalysis: solvent-accelerated imidazole C–H activation
2015
Mechanistic Study on Cu(II)-Catalyzed Oxidative Cross-Coupling Reaction between Arenes and Boronic Acids under Aerobic Conditions
2018
Programmed Synthesis of Tetraarylthiophenes through Sequential C−H Arylation
2009
Copper-Mediated Direct C(sp3)–H and C(sp2)–H Acetoxylation
2014
Development and Applications of Disulfonimides in Enantioselective Organocatalysis
2015 StandoutNobel
Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope
2011 Standout
Ligand Effects in Homogeneous Au Catalysis
2008 Standout
Ruthenium‐Catalyzed CH Bond Activation of Michael Acceptors: An Unusual Reactivity Leading to Allylsilanes
2009
Organometallic Chemistry on Silicon and Germanium Surfaces
2002
Copper‐Catalyzed Direct C Arylation of Heterocycles with Aryl Bromides: Discovery of Fluorescent Core Frameworks
2009
Palladium-Catalyzed Direct Arylation of Nitro-Substituted Aromatics with Aryl Halides
2008
Frustrated Lewis Pairs: Metal‐free Hydrogen Activation and More
2009 Standout
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
2009 Standout
The conjugate addition of enantiomerically pure lithium amides as homochiral ammonia equivalents: scope, limitations and synthetic applications
2005
Gold‐Catalyzed 5‐ and 6‐exo‐dig Selective Cyclizations of Alkynyl Silyl Enol Ethers: Efficient Method for [3+2] and [4+2] Annulations onto α,β‐Enones
2007
Nickel-catalyzed direct C–H arylation of unactivated arenes with aryl halides
2011
Ein effizienter Dirhodiumkatalysator für die nichtdirigierte Direktarylierung nichtaktivierter Arene
2007
Ru(II)- and Pt(II)-Catalyzed Cycloisomerization of ω-Aryl-1-alkynes. Generation of Carbocationic Species from Alkynes and Transition Metal Halides and Its Interception by an Aromatic Ring
2000
Direct Arylation of Imidazo[1,2‐b]pyridazines: Microwave‐Assisted One‐Pot Suzuki Coupling/Pd‐Catalysed Arylation
2010
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Highly selective catalytic trans-hydroboration of alkynes mediated by borenium cations and B(C6F5)3
2016
Rhodium complexes of PCNHCP: Oxidative addition of dichloromethane and catalytic hydrosilylation of alkynes affording (E)-alkenylsilanes
2005
Phosphonium Coupling in the Direct Bond Formations of Tautomerizable Heterocycles via C–OH Bond Activation
2008
Copper‐catalyzed/mediated aromatic CH bond functionalization
2010
Cu(II)-Mediated C–H Amidation and Amination of Arenes: Exceptional Compatibility with Heterocycles
2014
RuCl3-Catalyzed Alkenylation of Aromatic C−H Bonds with Terminal Alkynes
2008
Cu(II) Catalyzed Imine C–H Functionalization Leading to Synthesis of 2,5-Substituted 1,3,4-Oxadiazoles
2011
Transition Metal Salts-Catalyzed Aza-Michael Reactions of Enones with Carbamates
2002
Evaluation of Electron‐Deficient Phosphine Ligands for Direct Arylation of Heterocycles
2010
Copper-Catalyzed Synthesis of Phenanthridine Derivatives under an Oxygen Atmosphere Starting from Biaryl-2-carbonitriles and Grignard Reagents
2010
Oxidative Coupling of Arylboronic Acids with Arenes via Rh-Catalyzed Direct C−H Arylation
2007
Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit
2009
Synthesis of 2,5-diaryloxazoles through van Leusen reaction and copper-mediated direct arylation
2009
A Pictet-Spengler ligation for protein chemical modification
2012 StandoutNobel
Benzofuran synthesis via copper-mediated oxidative annulation of phenols and unactivated internal alkynes
2013
Transition Metal‐Catalysed, Direct and Site‐Selective N1‐, C2‐ or C3‐Arylation of the Indole Nucleus: 20 Years of Improvements
2009
Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates
2009
Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate
2010
The broadening reach of frustrated Lewis pair chemistry
2016 StandoutScience
Tishchenko reactions of aldehydes promoted by diisobutylaluminum hydride and its application to the macrocyclic lactone formation
2007
Synthesis of Fused 1-Aminoindole Polycycles by a Sequence of Palladium-Catalyzed N–H and C(sp2)–H Arylations
2014
Catalaytic Isomerization of 1,5-Enynes to Bicyclo[3.1.0]hexenes
2004
Selective Synthesis of [12]Cycloparaphenylene
2009
Copper-catalyzed direct cross-coupling of 1,3,4-oxadiazoles with N-tosylhydrazones: efficient synthesis of benzylated 1,3,4-oxadiazoles
2013
Aerobic Copper-Catalyzed Organic Reactions
2013 Standout
Frustrierte Lewis‐Paare: metallfreie Wasserstoffaktivierung und mehr
2009
1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-promoted efficient and versatile aza-Michael addition
2006
Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization
2012 Standout
Confined acids catalyze asymmetric single aldolizations of acetaldehyde enolates
2018 StandoutScienceNobel
Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C–H hydroxylation and amination
2016
Copper-Catalyzed Dehydrogenative Cross-Coupling of Benzothiazoles with Thiazoles and Polyfluoroarene
2012
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
Oxidative C–H/C–H Coupling of Azine and Indole/Pyrrole Nuclei: Palladium Catalysis and Synthesis of Eudistomin U
2011
Oxidative Nickel–Air Catalysis in CH Arylation: Direct Cross‐Coupling of Azoles with Arylboronic Acids using Air as Sole Oxidant
2010
“On Water” Direct and Site‐Selective Pd‐Catalysed CH Arylation of (NH)‐Indoles
2010
Übergangsmetallkatalysierte direkte Arylierungen von (Hetero)Arenen durch C‐H‐Bindungsbruch
2009
Ruthenium-catalyzed direct arylations with aryl chlorides
2016
Direct Amination of Azoles via Catalytic C−H, N−H Coupling
2009
Organocatalytic Asymmetric Transferhydrogenation of β-Nitroacrylates: Accessing β2-Amino Acids
2008 StandoutNobel
Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
2016 Standout
A General Catalyst for the β‐Selective C–H Bond Arylation of Thiophenes with Iodoarenes
2010
C−C Bond Formation via C−H Bond Activation Using an in Situ-Generated Ruthenium Catalyst
2009
Functionalization of a Simple Dithienylethene via Palladium-Catalyzed Regioselective Direct Arylation
2011
Advanced Carbon Electrode Materials for Molecular Electrochemistry
2008 Standout
Palladium-Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air
2008
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation
2008
Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents
2010
Functionalization of Azacalixaromatics by Cu(II)-Catalyzed Oxidative Cross-Coupling Reaction between the Arene C–H Bond and Boronic Acids
2016
Direct C−H Transformation via Iron Catalysis
2010 Standout
Ruthenium Chloride as an Efficient Catalytic Precursor for Hydroarylation Reactions via C−H bond Activation
2010
Hindered biaryls by C–H coupling: bisoxazoline-Pd catalysis leading to enantioselective C–H coupling
2012
Gold-Catalyzed Organic Reactions
2007 Standout
Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents
2008
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
2009 Standout
Palladium/2,2′-bipyridyl/Ag2CO3 catalyst for C–H bond arylation of heteroarenes with haloarenes
2011
Copper(II)-Catalyzed Ortho-Acyloxylation of the 2-Arylpyridines sp2 C−H Bonds with Anhydrides, Using O2 as Terminal Oxidant
2010
Recent advances in the stereoselective synthesis of β-amino acids
2002
Synthesis, Structure and Conformation of Partially‐Modified Retro‐ and Retro‐Inverso ψ[NHCH(CF3)]Gly Peptides
2003
Homocoupling of Arylboronic Acids Catalyzed by 1,10‐Phenanthroline‐Ligated Copper Complexes in Air
2009
Pd(OAc)2/o-Chloranil/M(OTf)n: A Catalyst for the Direct C–H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl-, Silyl-, and Unfunctionalized Arenes
2011
Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids
2009
Phosphine-Free Palladium(II)-Catalyzed Arylation of Naphthalene and Benzene with Aryl Iodides
2008
Catalytic C–C coupling through C–H arylation of arenes or heteroarenes
2009
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
A Novel B(C6F5)3-Catalyzed Reduction of Alcohols and Cleavage of Aryl and Alkyl Ethers with Hydrosilanes
2000
Nickel-Catalyzed Direct Arylation of Azoles with Aryl Bromides
2009
Direct Arylation of Thiazoles on Water
2007
Cu(OAc)2-Catalyzed Coupling of Aromatic C–H Bonds with Arylboron Reagents
2014
Industrial biotechnology—the future of green chemistry?
2011
Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts
2012
Palladium-Catalyzed Methylation of Aryl C−H Bond by Using Peroxides
2008
Copper-Catalyzed Thiolation of the Di- or Trimethoxybenzene Arene C−H Bond with Disulfides
2010
Mechanistic Analysis of Azine N-Oxide Direct Arylation: Evidence for a Critical Role of Acetate in the Pd(OAc)2 Precatalyst
2010
Rhodium-Catalyzed One-Pot Synthesis of Substituted Pyridine Derivatives from α,β-Unsaturated Ketoximes and Alkynes
2007
Palladium-Catalyzed C−H Arylation of 2,5-Substituted Pyrroles
2010
Catalytic Direct Arylation of Heteroaromatic Compounds
2006
Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme
2017 StandoutNobel
Nickel-Catalyzed C–H/C–O Coupling of Azoles with Phenol Derivatives
2011
Works of Tomoko Sudo being referenced
Responses of Tracheobronchial Receptors to Inhaled Furosemide in Anesthetized Rats
2000
Inhaled Furosemide Greatly Alleviates the Sensation of Experimentally Induced Dyspnea
2000
Direct coupling of arenes and iodoarenes catalyzed by a rhodium complex with a strongly π-accepting phosphite ligand
2008 Nobel
Lewis Acid Catalyzed Highly Regio- and Stereocontrolled Trans-Hydrosilylation of Alkynes and Allenes
1999
Lewis Acid-Catalyzed trans-Hydrosilylation of Alkynes
1996
Copper-Mediated C−H Bond Arylation of Arenes with Arylboronic Acids
2008
Lewis acid-mediated intramolecular addition of silyl enol ethers to internal unactivated alkynes
2001
Properties of a new enzyme, nucleoside oxidase, from Pseudomonas maltophilia LB-86.
1989
Direct C−H Arylation of (Hetero)arenes with Aryl Iodides via Rhodium Catalysis
2006 Nobel
Lewis Acid-Catalyzed trans-Hydrosilylation of Alkynes
1997
Highly Diastereoselective Conjugate Addition of Lithium Dialkylamides to α,β-Unsaturated Esters Having a Chiral Center at the γ-Position
1997