Standout Papers

Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated wit... 1996 2026 2006 2016 473
  1. Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated with Phosphine and N-Heterocyclic Carbene Ligands (2003)
    Tina M. Trnka, John P. Morgan et al. Journal of the American Chemical Society
  2. Reactivity of Ru(H)(H2)Cl(PCy3)2 with Propargyl and Vinyl Chlorides:  New Methodology To Give Metathesis-Active Ruthenium Carbenes (1997)
    Thomas Wilhelm, Tomás R. Belderraín et al. Organometallics
  3. Synthesis of Titanium Complexes That Contain Triamido−Amine Ligands (1996)
    Richard R. Schrock, Christopher C. Cummins et al. Organometallics

Citation Impact

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Tandem Catalysis:  Three Mechanistically Distinct Reactions from a Single Ruthenium Complex
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Olefin metathesis
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Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization
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Chelated Ruthenium Catalysts for Z-Selective Olefin Metathesis
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Tandem catalysis: a taxonomy and illustrative review
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1998
NHC–Ru complexes—Friendly catalytic tools for manifold chemical transformations
2006
Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts
2001 StandoutNobel
Development of novel reactions using ruthenium carbene catalyst and its application to novel methods for preparing nitrogen-containing heterocycles
2005
Origin of Enantioselectivity in the Asymmetric Ru-Catalyzed Metathesis of Olefins
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RuCl3, P(C6H11)3, 1-Alkine, Mg, H2 und H2O: Komponenten einer effizienten Eintopfsynthese von Ru-Olefinmetathese- Katalysatoren
1998
Polymer-Supported N-Heterocyclic Carbene−Palladium Complex for Heterogeneous Suzuki Cross-Coupling Reaction
2005
Ruthenium-Based Olefin Metathesis Catalysts Bearing N-Heterocyclic Carbene Ligands
2009
Stability and reactivity of N-heterocyclic carbene complexes
2004
Synthesis of Functionalized Olefins by Cross and Ring-Closing Metatheses
2000 StandoutNobel
Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis Reactions
2004 StandoutNobel
Titanium and Zirconium Complexes Containing a Novel Dianionic Trifunctional Amido Ligand
1997
NHC ligands versus cyclopentadienyls and phosphines as spectator ligands in organometallic catalysis
2005
Efficient Removal of Ruthenium Byproducts from Olefin Metathesis Products by Simple Aqueous Extraction
2007 Nobel
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2010
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1997 StandoutNobel
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2009
Metathesis Activity and Stability of New Generation Ruthenium Polymerization Catalysts
2003
A convenient catalyst system employing RuCl3 or RuBr3 for metathesis of acyclic olefins
1999
Stabilization of Organometallic Species Achieved by the Use of N‐Heterocyclic Carbene (NHC) Ligands
2005
Preparation of a Series of “Ru(p-cymene)” Complexes with Different N-Heterocyclic Carbene Ligands for the Catalytic β-Alkylation of Secondary Alcohols and Dimerization of Phenylacetylene
2008
Bis-coordination of N-(Alkyl)-N‘-(2,6-diisopropylphenyl) Heterocyclic Carbenes to Grubbs Catalysts
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Imidazol(in)ium carboxylates as N-heterocyclic carbene ligand precursors for Suzuki–Miyaura reactions
2006
Betaine Adducts of N‐Heterocyclic Carbenes: Synthesis, Properties, and Reactivity
2009
Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligands [(i-PrN-o-C6H4)2O]2-([i-PrNON]2-) and [(C6H11N-o-C6H4)2O]2-([CyNON]2-)
1999 StandoutNobel
An "Endless" Route to Cyclic Polymers
2002 StandoutScienceNobel
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
2009 Standout
Synthesis of Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligand, [((t-Bu-d6)N-o-C6H4)2O]2- ([NON]2-) and the Living Polymerization of 1-Hexene by Activated [NON]ZrMe2
1997 StandoutNobel
Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET
2006 StandoutNobel
Single-Component Catalyst/Initiators for the Organocatalytic Ring-Opening Polymerization of Lactide
2005
Tungsten and Molybdenum Alkyl or Aryl Complexes That Contain the [(C6F5NCH2CH2)3N]3- Ligand
1998 StandoutNobel
Olefin Metathesis and Beyond
2000 Standout
A most user-friendly protocol for ring closing metathesis reactions
1999
Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts:  The Role of Ligands and Substrates from a Theoretical Perspective
2004
Convenient Synthesis of Ruthenium(II) Dihydride Phosphine Complexes Ru(H)2(PP)2and Ru(H)2(PR3)x(x= 3 and 4)
1997 StandoutNobel
Facile one-step synthesis of bis(NHC) ruthenium benzylidene catalyst for ring-closing metathesis
2007
Ring-Opening Metathesis Polymerization of Norbornene by Cp*2Os2Br4 and Related Compounds
1999
The chemistry of the carbon-transition metal double and triple bond: annual survey covering the year 1997
1999
A Stable Crystalline Imino-N-Heterocyclic Carbene Ligand and Its Corresponding Palladium(II) and Rhodium(I) Complexes
2005
Living ring-opening metathesis polymerization
2006 Nobel
Carbonyl-Amplified Catalyst Performance: Balancing Stability against Activity for Five-Coordinate Ruthenium Hydride and Hydridocarbonyl Catalysts
2008
Catalysis at the Interface of Ruthenium Carbene and Ruthenium Hydride Chemistry: Organometallic Aspects and Applications to Organic Synthesis
2004
“Fixation” of Dinitrogen by Molybdenum and the Formation of a Trigonal Planar Iron−Tris[molybdenum(dinitrogen)] Complex
1997 StandoutNobel
Silver(I)−Carbene Complexes/Ionic Liquids:  Novel N-Heterocyclic Carbene Delivery Agents for Organocatalytic Transformations
2005
(p-cymene)RuLCl2 (L = 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene and 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and Related Complexes as Ring Closing Metathesis Catalysts
1999
Tandem Catalysis:  The Sequential Mediation of Olefin Metathesis, Hydrogenation, and Hydrogen Transfer with Single-Component Ru Complexes
2001 StandoutNobel
Understanding Structural Isomerization during Ruthenium-Catalyzed Olefin Metathesis:  A Deuterium Labeling Study
2006
Reductive Cyclization of Diynes and Enynes Catalyzed by Allyl Platinum N-Heterocyclic Carbene Complexes
2006
Structure and Reactivity of Alkynyl Ruthenium Alkylidenes
2008
The synthesis and structures of tantalum complexes that contain a triamido or a diamidoamine ligand
1998 StandoutNobel
Ruthenium Metathesis Catalysts with Saturated Unsymmetrical N-Heterocyclic Carbene Ligands
2005
Degradation of the Second‐Generation Grubbs Metathesis Catalyst with Primary Alcohols and Oxygen − Isomerization and Hydrogenation Activities of Monocarbonyl Complexes
2003
Synthesis of Ruthenium Olefin Metathesis Catalysts with Linear Alkyl Carbene Complexes
2005
Control of Stereoselectivity in the Ring-Opening Metathesis Polymerization of Norbornene by the Auxiliary Ligands Butadiene and o-Xylylene in Well-Defined Pentamethylcyclopentadiene Tantalum Carbene Complexes
1998
Rhodium N-Heterocyclic Carbene-Catalyzed [4 + 2] and [5 + 2] Cycloaddition Reactions
2005
Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene
2009
Confined acids catalyze asymmetric single aldolizations of acetaldehyde enolates
2018 StandoutScienceNobel
Molybdenum Triamidoamine Complexes that Contain Hexa-tert-butylterphenyl, Hexamethylterphenyl, or p-Bromohexaisopropylterphenyl Substituents. An Examination of Some Catalyst Variations for the Catalytic Reduction of Dinitrogen
2004 StandoutNobel
Imidazol(in)ium-2-carboxylates as N-heterocyclic carbene precursors in ruthenium–arene catalysts for olefin metathesis and cyclopropanation
2006
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
Stabilization of (Trialkylphosphine)ruthenium Alkylidene Metathesis Catalysts using Phosphine Exchange
2007
Bredereck's Reagent Revisited: Latent Anionic Ring‐Opening Polymerization and Transesterification Reactions
2004
Towards the rational design of palladium-N-heterocyclic carbene catalysts by a combined experimental and computational approach
2005
Coordinatively Unsaturated 16-Electron Ruthenium Allenylidene Complexes:  Synthetic, Structural, and Catalytic Studies
1999
Synthesis, Structure, and Activity of Enhanced Initiators for Olefin Metathesis
2003 StandoutNobel
Indenylidene‐Ruthenium Complexes Bearing Saturated N‐Heterocyclic Carbenes: Synthesis and Catalytic Investigation in Olefin Metathesis Reactions
2007
Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications
2009
Development of Isomerization and Cycloisomerization with Use of a Ruthenium Hydride with N-Heterocyclic Carbene and Its Application to the Synthesis of Heterocycles
2006
Amyloid precursor protein (APP) traffics from the cell surface via endosomes for amyloid β (Aβ) production in the trans -Golgi network
2012 StandoutNobel
The metathesis reactions: from a historical perspective to recent developments
2004
Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts
2009 StandoutNobel
Preparation of NHC–ruthenium complexes and their catalytic activity in metathesis reaction
2006
Olefin Metathesis-Active Ruthenium Complexes Bearing a Nucleophilic Carbene Ligand
1999
Water-Soluble Ruthenium Alkylidenes:  Synthesis, Characterization, and Application to Olefin Metathesis in Protic Solvents
2000 StandoutNobel
New Insights into the Mechanism of Ruthenium-Catalyzed Olefin Metathesis Reactions
2001 StandoutNobel
The Development of L2X2RuCHR Olefin Metathesis Catalysts:  An Organometallic Success Story
2000 StandoutNobel
Room temperature operating allenylidene precatalyst [LnRuξCξCξCR2]+X- for olefin metathesis: dramatic influence of the counter anion X-
1999
C−H Bond Activation through σ-Bond Metathesis and Agostic Interactions: Deactivation Pathway of a Grubbs Second-Generation Catalyst
2008
Novel Reactivity of Ruthenium Alkylidenes in Protic Solvents:  Degenerate Alkylidene Proton Exchange
2001 StandoutNobel
Ruthenium Alkylidenes:  Fast Initiators for Olefin Metathesis
2005
Triamidoamine Complexes of Molybdenum and Tungsten That Contain Metal−E (E = N, P, and As) Single, Double, or Triple Bonds
1997 StandoutNobel
Cationic ruthenium allenylidene complexes as a new class of performing catalysts for ring closing metathesis
1998
Carbenes: Synthesis, properties, and organometallic chemistry
2008
Decomposition of Ruthenium Olefin Metathesis Catalysts
2007 Nobel
Enyne Metathesis (Enyne Bond Reorganization)
2004
Rate Acceleration in Olefin Metathesis through a Fluorine−Ruthenium Interaction
2006 Nobel
Transition Metal Complexes That Contain a Triamidoamine Ligand
1997 StandoutNobel
Cyclic [2]Pseudorotaxane Tetramers Consisting of Two Rigid Rods Threaded through Two Bis-Macrocycles: Copper(I)-Templated Synthesis and X-ray Structure Studies
2008 StandoutNobel
Alkyl and Alkylidene Complexes of Tantalum That Contain a Triethylsilyl-Substituted Triamido−Amine Ligand
1996 StandoutNobel
Ligand-Promoted Carbene Insertion into the Aryl Substituent of an N-Heterocyclic Carbene Ligand in Ruthenium-Based Metathesis Catalysts
2009
Synthesis of Group 4 Complexes that Contain the Diamidoamine Ligands, [(2,4,6-Me3C6H2NCH2CH2)2NR]2- ([Mes2N2NR]2-; R = H or CH3), and Polymerization of 1-Hexene by Activated [Mes2N2NR]ZrMe2 Complexes
1999 StandoutNobel
Ruthenium‐Based NHC‐Arene Systems as Ring‐Opening Metathesis Polymerisation Catalysts
2007
Hexafunctionalized Borromeates Using Olefin Cross Metathesis
2007 StandoutNobel
Thermochemical Investigation of Phosphine Ligand Substitution Reactions Involving trans-(PR3)2Cl2RuCH−CHCPh2 Complexes
1998 StandoutNobel
A Rapid and Simple Cleanup Procedure for Metathesis Reactions
2007
Catalytic Dehalogenation of Aryl Chlorides Mediated by Ruthenium(II) Phosphine Complexes
1999 StandoutNobel
Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis
2011 Nobel
C−(Halide) Oxidative Addition Routes to Ruthenium Carbenes
1999
Efficient Allyl to Propenyl Isomerization in Functionally Diverse Compounds with a Thermally Modified Grubbs Second-Generation Catalyst
2006
Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers
2007 StandoutNobel
N-Heterocyclic Carbene−Osmium Complexes for Olefin Metathesis Reactions
2005
Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations
2003 StandoutNobel
Generation of Anti-trypanosomal Agents through Concise Synthesis and Structural Diversification of Sesquiterpene Analogues
2011 StandoutNobel

Works of Thomas Wilhelm being referenced

Parallel evolution of genome structure and transcriptional landscape in the Epsilonproteobacteria
2013
Posttranscriptional Expression Regulation: What Determines Translation Rates?
2007
Post-transcriptional Expression Regulation in the Yeast Saccharomyces cerevisiae on a Genomic Scale
2004
Reactivity of Ru(H)(H2)Cl(PCy3)2 with Propargyl and Vinyl Chlorides:  New Methodology To Give Metathesis-Active Ruthenium Carbenes
1997 StandoutNobel
Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated with Phosphine and N-Heterocyclic Carbene Ligands
2003 StandoutNobel
Synthesis of Titanium Complexes That Contain Triamido−Amine Ligands
1996 StandoutNobel
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2026