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2000
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1996
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2010 Standout
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2010
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1998 StandoutNobel
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1999
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2015 StandoutNobel
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2001
Functional Mimic of Dioxygen-Activating Centers in Non-Heme Diiron Enzymes: Mechanistic Implications of Paramagnetic Intermediates in the Reactions between Diiron(II) Complexes and Dioxygen
2002
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1992
A Multiplet Analysis of Fe K-Edge 1s → 3d Pre-Edge Features of Iron Complexes
1997
Design of Heme Enzymes with a Tunable Substrate Binding Pocket Adjacent to an Open Metal Coordination Site
2023 StandoutNobel
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1999
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1997
Modeling the Oxygen Activation Chemistry of Methane Monooxygenase and Ribonucleotide Reductase
1996
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2003
Transition Metal Photoredox Catalysis of Radical Thiol-Ene Reactions
2012
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1996
EPR Study of the Mixed-Valent Diiron Sites in Mouse and Herpes Simplex Virus Ribonucleotide Reductases. Effect of the Tyrosyl Radical on Structure and Reactivity of the Diferric Center
1997
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2003 StandoutNobel
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2000
Mechanistic Studies of the Formation and Decay of Diiron(III) Peroxo Complexes in the Reaction of Diiron(II) Precursors with Dioxygen
1996
Assembly and Self-Organization of Silver Nanocrystal Superlattices: Ordered “Soft Spheres”
1998
Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme
2017 StandoutNobel
Bioinspired Catalyst Design and Artificial Metalloenzymes
2011
Structure and Chemistry of Cytochrome P450
2005 Standout
Artificial Metalloenzymes and Metallopeptide Catalysts for Organic Synthesis
2013
Novel artificial metalloenzymes by in vivo incorporation of metal-binding unnatural amino acids
2014
Dioxygen Activation by Enzymes with Mononuclear Non-Heme Iron Active Sites
1996
Works of Stéphane Ménage being referenced
H2O2-Dependent Fe-Catalyzed Oxidations: Control of the Active Species
2001
The Protein Environment Drives Selectivity for Sulfide Oxidation by an Artificial Metalloenzyme
2009
Crystallographic snapshots of the reaction of aromatic C–H with O2 catalysed by a protein-bound iron complex
2010
Sulfide Oxidation by Hydrogen Peroxide Catalyzed by Iron Complexes: Two Metal Centers Are Better Than One
2002
A Ruthenium(II)–Copper(II) Dyad for the Photocatalytic Oxygenation of Organic Substrates Mediated by Dioxygen Activation
2015
An Artificial Oxygenase Built from Scratch: Substrate Binding Site Identified Using a Docking Approach
2013
A new chiral diiron catalyst for enantioselective epoxidation
2007
The structure of the periplasmic nickel-binding protein NikA provides insights for artificial metalloenzyme design
2012
Formation of an Alkylperoxoiron(III ) Complex during Oxidations Catalyzed by μ‐Oxodiiron(III ) Complexes
1995
A Chiral Poly(2,2′-bipyridyl rhodium(III) complex) Film Electrode for Asymmetric Induction in Electrosynthesis
1998
Durch einen μ‐Oxodieisen(III)‐Komplex katalysierte Hydroxylierung eines Arylliganden mit H2O2 und O2
1996
A [MnIII2O(MeCO2)2(H2O)2(bipy)2]2+(bipy = 2,2′-bipyridine) unit with accessible co-ordination sites. Contribution to the modelling of the photosynthetic oxygen evolving centre
1988
Models for iron-oxo proteins: dioxygen binding to a diferrous complex
1990
H2O2-Dependent Fe-Catalyzed Oxidations: Control of the Active Species
2001
Bildung einer Alkylperoxoeisen(III )‐Zwischenstufe bei μ‐Oxodieisen(III )‐katalysierten Oxidationen
1995
Aromatic Hydroxylation by H2O2 and O2 Catalyzed by a μ‐Oxo Diiron(III ) Complex
1996
Structure and reactivity of a bis(.mu.-acetato-O,O')diiron(II) complex, [Fe2(O2CCH3)2(TPA)2](BPh4)2. A model for the diferrous core of ribonucleotide reductase
1992
Spectroscopic characterization of diferric peroxide complexes.
1991
μ-Oxo diferric complexes as oxidation catalysts with hydrogen peroxide and their potential in asymmetric oxidation
1997
Dioxygen binding to diferrous centers. Models for diiron-oxo proteins
1993
X-ray absorption of tetraoxomanganates (MnO4n−: Experimental and MS LSD computational studies
1990
O2 Activation and Aromatic Hydroxylation Performed by Diiron Complexes
1998
Mixed-valent μ-oxo-bridged diiron complexes produced by radiolytic reduction at 77 K studied by EPR
1997
New Polydentate Ligand and Catalytic Properties of the Corresponding Ruthenium Complex During Sulfoxidation and Alkene Epoxidation
2008
Hydroxylation of alkanes catalysed by a chiral μ-oxo diferric complex: a metal-based mechanism
2000
Mechanistic Tuning of Hydrocarbon Oxidations with H2O2, Catalyzed by Hexacoordinate Ferrous Complexes
2004
Functional models of non-heme diiron enzymes
1998
A New Type of Mn–O Cluster with a Mn4 Chain Unit—Relevance to the Photosynthetic Oxygen Evolving Center
1992
Oxidation of alkanes catalyzed by binuclear metal complexes: Control by the coordination sphere
1994
Catalysis without a headache: Modification of ibuprofen for the design of artificial metalloenzyme for sulfide oxidation
2016
Ru- and Fe-based N,N′-bis(2-pyridylmethyl)-N-methyl-(1S,2S)-1,2-cyclohexanediamine complexes immobilised on mesoporous MCM-41: Synthesis, characterization and catalytic applications
2007
Alkane oxidation catalyzed by μ-oxo bridged diferric complexes: an overall mechanism
1996
Manganese(II ) based oxidation of alkanes: generation of a high valent binuclear catalyst in situ
1994
Structure of the linear trinuclear complex hexakis(acetato)bis(2,2'-bipyridine)trimanganese (II). Determination of the J electron-exchange parameter through magnetic susceptibility and high-field magnetization measurements
1991
µ-Oxo-bridged diiron(III ) complexes and H2O2: monooxygenase- and catalase-like activities
1994
A Diferric Peroxo Complex with an Unprecedented Spin Configuration: AnS=2 System Arising from anS=5/2, 1/2 Pair
2002
Photocatalyzed Sulfide Oxygenation with Water as the Unique Oxygen Atom Source
2012
Alkane oxidation catalyzed by .mu.-oxo-bridged diferric complexes: a structure/reactivity correlation study
1993
A bis(.mu.-alkoxo)diiron complex with novel terminally ligated carboxylates
1990
Enantioselective Sulfoxidation as a Probe for a Metal-Based Mechanism in H2O2-Dependent Oxidations Catalyzed by a Diiron Complex
1999
A New Type of Trinuclear Oxoiron(III ) Cluster
1995
“Chiral-at-Metal” Octahedral Ruthenium(II) Complexes with Achiral Ligands: A New Type of Enantioselective Catalyst
2003
Structures and properties of dibridged (.mu.-oxo)diiron(III) complexes. Effects of the Fe-O-Fe angle
1990
A first model for the oxidized active form of the active site in galactose oxidase: a free-radical copper complex
1997
Multistep anchoring of a catalytically active ruthenium complex in porous mesostructured silica
2008
Oxidation Catalysis by Rationally Designed Artificial Metalloenzymes
2014