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Mechanism of olefin polymerization by a soluble zirconium catalyst1Dedicated to Prof. Roy M. Adams, Geneva College, Beaver Falls, PA, USA, on the occasion of his 71st birthday.1
1998
Dynamic Covalent Chemistry
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Solvent polarity and hydrogen-bonding effects on the nitrogen NMR shieldings of N-nitrosamines and DFT calculations of the shieldings of C-, N-, and O-nitroso systems
2003
Unidirectional molecular motor on a gold surface
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Quantitative Measures of Solvent Polarity
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Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin‐Metathesis Catalysts
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2008
Noncoordinating Anions—Fact or Fiction? A Survey of Likely Candidates
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KINETIC STUDY OF THE HELIX TO COIL DARK REACTION OF POLY(SPIROPYRAN‐l‐GLUTAMATE)*
1992
Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry
2014 StandoutNobel
Polarization transfer by cross-correlated relaxation in solution NMR with very large molecules
1999 StandoutNobel
A Reversible, Unidirectional Molecular Rotary Motor Driven by Chemical Energy
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Seven‐Membered Heterodimetallic Ring Systems from (Conjugated Diene) Group 4 Metallocene Complexes and Organoaluminium Reagents
1994
Rotational Reorganization of Doped Cholesteric Liquid Crystalline Films
2006 StandoutNobel
Metathesis polymerization
1993
Reversible Three-State Switching of Luminescence: A New Twist to Electro- and Photochromic Behavior
2006 StandoutNobel
Dimethylzirconocene−Methylaluminoxane Catalyst for Olefin Polymerization: NMR Study of Reaction Equilibria
1997
Conformational Analysis of Cyclohexane Derivatives by Nuclear Magnetic Resonance Spectroscopy
1965
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
2011 Standout
CH/π interaction: Implications in organic chemistry
1989
Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
1995 Standout
Syntheses of Hemoprotein Models that can be Covalently Attached onto Electrode Surfaces by Click Chemistry
2007
Isolation by crystallization of translational isomers of a bistable donor-acceptor [2]catenane
2010 StandoutNobel
TROSY in triple-resonance experiments: New perspectives for sequential NMR assignment of large proteins
1998 StandoutNobel
Sliding-Ring Catenanes
2016 StandoutNobel
Concerning the reaction of zirconocene dichloride and methylalumoxane: Homogeneous Ziegler‐Natta catalytic system for olefin polymerization
1992
Chiroptical Molecular Switches
2000 StandoutNobel
Physical Chemistry of Equilibrium Polymerization
1998
High-Resolution Nuclear Magnetic Resonance Spectroscopy
1967 StandoutScienceNobel
Optimizing rotary processes in synthetic molecular motors
2009 StandoutNobel
Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligands [(i-PrN-o-C6H4)2O]2-([i-PrNON]2-) and [(C6H11N-o-C6H4)2O]2-([CyNON]2-)
1999 StandoutNobel
Theoretical Studies on Reactions of Transition-Metal Complexes
2000
Artificial Molecular Rotors
2005
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
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Multiple Mechanistic Pathways for Zirconium-Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C−H Activation
1996 StandoutNobel
Synthesis of Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligand, [((t-Bu-d6)N-o-C6H4)2O]2- ([NON]2-) and the Living Polymerization of 1-Hexene by Activated [NON]ZrMe2
1997 StandoutNobel
Experimentally-Based Recommendations of Density Functionals for Predicting Properties in Mechanically Interlocked Molecules
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Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment
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Cyclodextrin-Based Catenanes and Rotaxanes
1998 StandoutNobel
Cationic Group 4 metallocene complexes and their role in polymerisation catalysis: the chemistry of well defined Ziegler catalysts
1996
Interlocked Macromolecules
1999 StandoutNobel
Product operator formalism for the description of NMR pulse experiments
1984 StandoutNobel
Complexation of Cp2MCl2 in a chloroaluminate molten salt: relevance to homogeneous Ziegler-Natta catalysis
1990
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2014
Unified Approach to Imidodiphosphate-Type Brønsted Acids with Tunable Confinement and Acidity
2021 StandoutNobel
Darstellung, Struktur und Olefinpolymerisationsaktivität basenfreier kationischer 14‐Elektronen‐Alkyltitan‐ und ‐zirconiumkomplexe
1990
Evidence of Zircononium−Polymeryl Ion Pairs from 13C NMR in Situ 13C2H4 Polymerization with Cp2Zr(13CH3)2-Based Catalysts
1998
Determination of aluminium electronegativity in new ambient-temperature acidic molten salts based on 3-butyl-1-methylimidazolium chloride and ALEt3–xClx(x= 0–3) by1H nuclear magnetic resonance spectroscopy
1993
Kationische Alkylkomplexe für die Olefinpolymerisation
1993
Molecular Stirrers in Action
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2010
Base-free cationic 14-electron alkyls of Ti, Zr and Hf as polymerisation catalysts: A comparison
1992
Undecafluorodiarsenate Anion: Synthesis and Crystal Structure of (MeS)2CSH+As2F11-
1999
Deuterium Relaxation in a Uniformly 15N-Labeled Homeodomain and Its DNA Complex1
1997 StandoutNobel
A Push-Button Molecular Switch
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Perfluoroalkyl borates: congeners of perfluoroalkanes
2001
Metallocene/polypropylene structural relationships: Implications on polymerization and stereochemical control mechanisms
1991
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2008 StandoutNobel
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
2003 StandoutScienceNobel
Enabling Nucleophilic Substitution Reactions of Activated Alkyl Fluorides through Hydrogen Bonding
2013
BPh as a Ligand in Cationic Zirconium Complexes: Novel Bonding Mode and Fluxionality
1991
Effect of the Nature of Metallocene Complexes of Group IV Metals on Their Performance in Catalytic Ethylene and Propylene Polymerization
2000 Standout
Fine Tuning of the Rotary Motion by Structural Modification in Light-Driven Unidirectional Molecular Motors
2006 StandoutNobel
Relative Abilities of Fluorine and Chlorine to Stabilize Carbenium Ions: Crystal Structures of Two Fluoro-Substituted Carbocations and of As2F11-
1999 Nobel
β-Hydrogen-Containing Zirconium Alkyls with the Doubly-Bridged Bis(dimethylsilanediyl)dicyclopentadienyl Ligand. X-ray Molecular Structures of [Zr{(SiMe2)2(η5-C5H3)2}ClEt] and [Zr{(SiMe2)2(η5-C5H3)2}Et]2(μ-CH2CH2)
1997
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Selectivity Control By Temperature Variation in the Formation of Isotactic vs. Syndiotactic Polypropylene with a Titanocene/Alumoxane Catalyst
1992
Quantum Mechanical Continuum Solvation Models
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Continuous Flow Hyperpolarized129Xe NMR for Studying Porous Polymers and Blends
2006
Cu-Catalyzed Azide−Alkyne Cycloaddition
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Correlations between solvatochromism, Lewis acid-base equilibrium and photochromism of an indoline spiropyran
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Acidity of Strong Acids in Water and Dimethyl Sulfoxide
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Attenuated T 2 relaxation by mutual cancellation of dipole–dipole coupling and chemical shift anisotropy indicates an avenue to NMR structures of very large biological macromolecules in solution
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Control of Surface Wettability Using Tripodal Light-Activated Molecular Motors
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Stereospezifische Olefinpolymerisation mit chiralen Metallocenkatalysatoren
1995
Synthesis and Characterisation of New Arsonium Salts and Crystal Structures of Trimethylarsonium Undecafluorodiarsenate (CH3)3AsH+As2F11− and Trimethylarsonium Hexafluoroantimonate (CH3)3AsH+SbF6−
1999
A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound
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2000 StandoutNobel
Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships
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Redox Control of the Binding Modes of an Organic Receptor
2015 StandoutNobel
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Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
1999 Standout
Chemical Redox Agents for Organometallic Chemistry
1996 Standout
Reduction of Dinitrogen to Ammonia at a Well-Protected Reaction Site in a Molybdenum Triamidoamine Complex
2002 StandoutNobel
An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes
1996 StandoutNobel
Polymer NMR Spectroscopy. XI. Polystyrene and Polystyrene Model Compounds
1965
The Study of Chemical Rate Processes in Liquids by Nuclear Magnetic Resonance
1963
Works of S. Brownstein being referenced
The proton resonance spectra of poly‐α‐methylstyrenes
1961
The Barrier to Rotation About the N—N Bond in N-Nitrosamines as Determined by Nuclear Magnetic Resonance Total Line Shape Analysis
1974
Complexing, exchange, and redistribution reactions of some Group III and Group V fluorides and their anions
1969
Conformation and rotational barriers in sym-tetra-tert-butylethane and sym-tetra(trimethylsilyl)ethane
1977
ENERGY BARRIERS AND STRUCTURE OF cis-, MUCO-, AND ALLO-INOSITOL HEXAACETATES IN SOLUTION
1962
Intensity variations in two-dimensional multiquantum proton resonance spectroscopy: Design of a pulse sequence using the superspin formalism
1982
Complex fluoroanions in solution. IX. BF3–anion complexes and their disproportionation
1978
Conformational Analysis of Disubstituted Cyclohexanes by Proton Resonance Spectroscopy
1959
Ternary charge-transfer complexes. III. Complexes with Group V elements in the anion
1986
Organometallic compounds of Group III. Part 41. Direct observation of the initial insertion of an unsaturated hydrocarbon into the titanium-carbon bond of the soluble Ziegler polymerization catalyst Cp2TiCl2-MeAlCl2
1985
Hindered Rotation in Styryl Anions
1972
Complexes of BrF3 with BF3, PF5 and AsF5
1977
Mechanism of Friedel-Crafts acetylation of acetylene with acetyl chloride
1985
THE EFFECT OF SOLVENTS UPON EQUILIBRIA, SPECTRA, AND REACTION RATES
1960
Proton Resonance Shifts of Acids in Liquid Sulfur Dioxide
1959
PROTON RESONANCE SPECTRA AND TACTICITY OF POLYSTYRENE AND DEUTERIOPOLYSTYRENES1,2
1962
129Xe line widths in block copolymers
1988
The Effect of Coördination on Electron Withdrawal
1959