Citation Impact

Citing Papers

Discrete Metal‐Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism
2004 Standout
Selective Catalysis and Nanoscience: An Inseparable Pair
2007
Determining accurate molecular sizes in solution through NMR diffusion spectroscopy
2007 Standout
Organocatalytic Ring-Opening Polymerization
2007 Standout
Noncoordinating Anions—Fact or Fiction? A Survey of Likely Candidates
2004 Standout
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
2008 Standout
Merging homogeneous catalysis with biocatalysis; papain as hydrogenation catalyst
2005 StandoutNobel
Stereochemical Communication within a Chiral Ion Pair Catalyst
2015 StandoutNobel
Frustrated Lewis Pair Chemistry: Development and Perspectives
2015 Standout
Decomposition pathways of homogeneous catalysts
2001
Iron-Catalyzed Reactions in Organic Synthesis
2004 Standout
Aspects of hydrogen activation in propene polymerization using MgCl2/TiCl4/diether catalysts
1996
A Comparison of Cationic Zirconium Methyl and Isobutyl Initiators that Contain an Arylated Diamido-Pyridine Ligand for Polymerization of 1-Hexene. Elucidation of a Dramatic “Initiator Effect”
2000 StandoutNobel
3d Transition Metals for C–H Activation
2018 Standout
On the mechanisms of growing-chain-end isomerization and transfer reactions in propylene polymerization with isospecific, C2-symmetric zirconocene catalysts
1999
Development of Improved Amidoquinoline Polyolefin Catalysts with Ultrahigh Molecular Weight Capacity
2015
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals
2007 Standout
On the Mechanism of Stereospecific Polymerization—Development of a Universal Model to Demonstrate the Relationship Between Metallocene Structure and Polymer Microstructure
1997
Nanoparticle, Size, Shape, and Interfacial Effects on Leakage Current Density, Permittivity, and Breakdown Strength of Metal Oxide−Polyolefin Nanocomposites: Experiment and Theory
2010
Photoactivation of Ruthenium Olefin Metathesis Initiators
2009
Influence of propene pressure on the isotacticity of polypropene produced with typical C1‐symmetric metallocene and Ziegler‐Natta catalysts
1997
Bis(imino)pyridines:  Surprisingly Reactive Ligands and a Gateway to New Families of Catalysts
2007 Standout
13C and 2D NMR Analysis of Propylene Polymers Made with α-Diimine Late Metal Catalysts
2000
Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
2008 Standout
Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
1995 Standout
Zr−Alkyl Isomerization in ansa-Zirconocene-Catalyzed Olefin Polymerizations. Contributions to Stereoerror Formation and Chain Termination1
1996
New NMR Spectroscopic Probe of the Absolute Stereoselectivity for Metal-Hydride and Metal-Alkyl Additions to the Carbon−Carbon Double Bond. Demonstration with a Single-Component, Isospecific Ziegler−Natta α-Olefin Polymerization Catalyst
1996
Synthesis of High-Melting, Isotactic Polypropene with C2- and C1-Symmetrical Zirconocenes
1996
Electrophile-Functionalized Metallocene Intermediates. Application in the Diastereoselective Synthesis of a Tetramethyldisiloxane-Bridged C2-Symmetric ansa-Zirconocene Dibromide
1999
Theoretical studies of the mechanism of ethylene polymerization reaction catalyzed by diimine-M(II) (M = Ni, Pd and Pt) and Ti- and Zr-chelating alkoxides
1999
Polymer Microstructure as a Probe into Hydrogen Activation Effect in ansa-Zirconocene/Methylaluminoxane Catalyzed Propene Polymerizations
1997
Zirconium−Alkyl Isomerizations in Zirconocene-Catalyzed Olefin Polymerization:  A Density Functional Study
1997
Metallocene catalysts for olefin polymerization
1999
New bridged zirconocenes for olefin polymerization: Binuclear and hybrid structures1Dedicated to Professor Dr. Gottfried Huttner on the occasion of his 60th birthday.1
1998
Oligomerisation of ethene by new palladium iminophosphine catalysts
1998 StandoutNobel
Aspects of transition metal mediated polymerizations
1997
A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions
2006 Standout
Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts
2000
Polymerization of Propylene by a New Generation of Iron Catalysts:  Mechanisms of Chain Initiation, Propagation, and Termination
1999
Chain transfer reaction by trialkylaluminum (AIR3) in the stereospecific polymerization of propylene with metallocene — AIR3/Ph3CB(C6F5)4
1998
Pyrolytic Depolymerization of Polyolefins Catalysed by Zirconium‐based UiO‐66 Metal–Organic Frameworks
2024 StandoutNobel
Ion Pairing in Transition-Metal Organometallic Chemistry
2005
Group 4 Cs symmetric catalysts and 1-olefin polymerization
1999
Influence of π-Ligand Substitutions on the Regiospecificity and Stereospecificity in Isospecific Zirconocenes for Propene Polymerization. A Molecular Mechanics Analysis
1998
Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligands [(i-PrN-o-C6H4)2O]2-([i-PrNON]2-) and [(C6H11N-o-C6H4)2O]2-([CyNON]2-)
1999 StandoutNobel
Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes:  Stereocontrol and Mechanism
2001 Standout
Stoichiometric Compounds of Magnesium Dichloride with Ethanol for the Supported Ziegler−Natta Catalysis:  First Recognition and Multidimensional MAS NMR Study
2003
Synthesis of Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligand, [((t-Bu-d6)N-o-C6H4)2O]2- ([NON]2-) and the Living Polymerization of 1-Hexene by Activated [NON]ZrMe2
1997 StandoutNobel
Chain transfer reactions in propylene polymerization with zirconocene catalysts
1999
Synthesis and Structural Characterization of {[Me2Si(C5Me4)2]Zr(η2-C2H4)H}2Mg:  An ansa-Zirconocene Ethylene−Hydride Complex
1998
Late-Metal Catalysts for Ethylene Homo- and Copolymerization
2000 Standout
Regio‐ and stereospecificity in propene polymerization with MgCl2‐supported Ziegler‐Natta catalysts: effects of hydrogen and the external donor
1995
Functionalization of the C−H Bond of N‐Heteroaromatics Assisted by Early Transition‐Metal Complexes
2018
Polymerization catalysis
2000
Flexible Nanodielectric Materials with High Permittivity for Power Energy Storage
2013 Standout
Propene Polymerization with the Isospecific, Highly Regiospecificrac-Me2C(3-t-Bu-1-Ind)2ZrCl2/MAO Catalyst. 1. Influence of Hydrogen on Initiation and Propagation:  Experimental Detection and Theoretical Investigation of 2,1 Propene Insertion into the Zr−H Bond1
1999
Efficient Synthesis of Chiral ansa-Metallocenes by Amine Elimination. Synthesis, Structure, and Reactivity of rac-(EBI)Zr(NMe2)2
1996
Core–Shell Structured High‐k Polymer Nanocomposites for Energy Storage and Dielectric Applications
2014 Standout
Recent Progress on Ferroelectric Polymer-Based Nanocomposites for High Energy Density Capacitors: Synthesis, Dielectric Properties, and Future Aspects
2016 Standout
Zirconocene Allyl Complexes:  Dynamics in Solution, Reaction with Aluminum Alkyls, B(C6F5)3-Induced Propene Insertion, and Density-Functional Calculations on Possible Formation and Reaction Pathways
2000
Advances in Non-Metallocene Olefin Polymerization Catalysis
2002 Standout
Rapid Cu-Free Click Chemistry with Readily Synthesized Biarylazacyclooctynones
2010 StandoutNobel
Cationic Hafnium Alkyl Complexes that Are Stable toward β-Hydride Elimination below 10 °C and Active as Initiators for the Living Polymerization of 1-Hexene
2001 StandoutNobel
New polymers by metallocene catalysis
1996
Pressure Modulates Stereoregularities in the Polymerization of Propylene Promoted by rac-Octahedral Heteroallylic Complexes
1998
Mechanisms of Stereocontrol for Doubly Silylene-BridgedCs- andC1-Symmetric Zirconocene Catalysts for Propylene Polymerization. Synthesis and Molecular Structure of Li2[(1,2-Me2Si)2{C5H2-4-(1R,2S,5R-menthyl)}{C5H-3,5-(CHMe2)2)}]·3THF and [(1,2-Me2Si)25-C5H2-4-(1R,2S,5R-menthyl)}{η5-C5H-3,5-(CHMe2)2}]ZrCl2
1998
Agostic interactions in transition metal compounds
2007 Standout
Selectivity in Propene Polymerization with Metallocene Catalysts
2000 Standout
A kinetic approach to homogeneous Ziegler type polymerization. Steady state
1997
Synthesis, Characterization, and Polymerization Behavior of Zirconium and Hafnium Complexes that Contain Asymmetric Diamido-N-Donor Ligands
2004 StandoutNobel
Living alkene polymerization: New methods for the precision synthesis of polyolefins
2007
Synthesis of group 4 complexes that contain the tridentate diamido ligands [(ArNCH2CH2)2O]2− (Ar = C6H3-Me2-2,6 or C6H3Pri2-2,6)
1998 StandoutNobel
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
Simultaneous Polymerization and Schulz−Flory Oligomerization of Ethylene Made Possible by Activation with MAO of a C1-Symmetric [2,6-Bis(arylimino)pyridyl]iron Dichloride Precursor
2004
Supported Metallocene Catalysis for In Situ Synthesis of High Energy Density Metal Oxide Nanocomposites
2007
Lanthanocene Catalysts in Selective Organic Synthesis
2002
Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms
2000 StandoutScienceNobel
NOE and PGSE NMR Spectroscopic Studies of Solution Structure and Aggregation in Metallocenium Ion-Pairs
2004
Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
2016 Standout
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
2016 Standout
Zirconium Complexes That Contain a Diamido O-Donor Ligand with a Restricted Geometry
1999 StandoutNobel
Nanochannels of Two Distinct Cross-Sections in a Porous Al-Based Coordination Polymer
2008 StandoutNobel
Effect of the Nature of Metallocene Complexes of Group IV Metals on Their Performance in Catalytic Ethylene and Propylene Polymerization
2000 Standout
Phosphorus-bridged metallocenes: New homogeneous catalysts for the polymerization of propene
1998
Probing β-alkyl elimination and selectivity in polyolefin hydrogenolysis through DFT
2021
Oscillating Stereocontrol: A Strategy for the Synthesis of Thermoplastic Elastomeric Polypropylene
1995 Science
(Phenylboratabenzene)zirconium Complexes:  Tuning the Reactivity of an Olefin Polymerization Catalyst
1997
Dendrimers Designed for Functions: From Physical, Photophysical, and Supramolecular Properties to Applications in Sensing, Catalysis, Molecular Electronics, Photonics, and Nanomedicine
2010 Standout
Kinetic Investigation of the Polymerization of 1-Hexene by the {[t-BuNON]ZrMe}[B(C6F5)4] Initiator
2001 StandoutNobel
Diastereoselective Synthesis, Molecular Structure, and Solution Dynamics of meso- and rac-[Ethylenebis(4,7-dimethyl-η5-1-indenyl)]zirconium Dichloride Isomers and Chain Transfer Reactions in Propene Polymerization with the rac Isomer
1996
Kinetic Study of Propylene Polymerization Using Et(H4Ind)2ZrCl2/Methylalumoxane Catalysts
1997
Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene
1998 Standout
Formation of Elastomeric Polypropylene Promoted by Racemic Acetylacetonate Group 4 Complexes
2000
Highly active metallocene catalysts for olefin polymerization
1998
Synthesis of Titanium, Zirconium, and Hafnium Complexes that Contain Diamido Donor Ligands of the Type [(t-BuN-o-C6H4)2O]2-and an Evaluation of Activated Versions for the Polymerization of 1-Hexene
1999 StandoutNobel
Formation of elastomeric polypropylene promoted by the dynamic complexes [TiCl2{N(PPh2)2}2] and [Zr(NPhPPh2)4]
2000
Modeling Metal-Catalyzed Olefin Polymerization
2000
Synthesis, Ion Aggregation, Alkyl Bonding Modes, and Dynamics of 14-Electron Metallocenium Ion Pairs [(SBI)MCH2SiMe3+···X-] (M = Zr, Hf):  Inner-Sphere (X = MeB(C6F5)3) versus Outer-Sphere (X = B(C6F5)4) Structures and the Implications for “Continuous” or “Intermittent” Alkene Polymerization Mechanisms
2005
Highly Regiospecific Zirconocene Catalysts for the Isospecific Polymerization of Propene
1998
A Density Functional and Molecular Mechanics Study Of β-Hydrogen Transfer in Homogeneous Ziegler−Natta Catalysis
1996
Synthesis of Group 4 Complexes that Contain the Diamidoamine Ligands, [(2,4,6-Me3C6H2NCH2CH2)2NR]2- ([Mes2N2NR]2-; R = H or CH3), and Polymerization of 1-Hexene by Activated [Mes2N2NR]ZrMe2 Complexes
1999 StandoutNobel
Termination, Isomerization, and Propagation Reactions during Ethene Polymerization Catalyzed by Cp2Zr−R+ and Cp*2Zr−R+. An Experimental and Theoretical Investigation
1998
Regioirregular Propene Insertion in Polypropenes Synthesized with Unbridged Bis(2-aryl)indenyl Zirconium Dichloride Catalysts:  Implications on Activity
1999
Propene polymerization using homogeneous MAO‐activated metallocene catalysts: Me2Si(Benz[e]Indenyl)2ZrCl2/MAO vs. Me2Si(2‐Me‐Benz[e]Indenyl)2ZrCl2/MAO
1995
Stereospezifische Olefinpolymerisation mit chiralen Metallocenkatalysatoren
1995
Control of Stereoerror Formation with High-Activity “Dual-Side” Zirconocene Catalysts:  A Novel Strategy To Design the Properties of Thermoplastic Elastic Polypropenes
1999
Cocatalysts for Metal-Catalyzed Olefin Polymerization:  Activators, Activation Processes, and Structure−Activity Relationships
2000 Standout
A Possible Interpretation of the Nonlinear Propagation Rate Laws for Insertion Polymerizations:  A Kinetic Model Based on a Single-Center, Two-State Catalyst
1999
Relationship between Regiospecificity and Type of Stereospecificity in Propene Polymerization with Zirconocene-Based Catalysts1
1997
Statistical Analysis and Simulation of Pentad Distributions of Stereoblock Polypropylenes
1998
Heterocycle-Fused Indenyl Silyl Amido Dimethyl Titanium Complexes as Catalysts for High Molecular Weight Syndiotactic Amorphous Polypropylene
2004
An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes
1996 StandoutNobel

Works of Roberta Cipullo being referenced

“Oscillating” Metallocene Catalysts: How Do They Oscillate?
2002
Nonconventional Catalysts for Isotactic Propene Polymerization in Solution Developed by Using High‐Throughput‐Screening Technologies
2006
Metallocene-Catalyzed Propene Polymerization:  From Microstructure to Kinetics. 1. C2-Symmetric ansa-Metallocenes and the "Trigger" Hypothesis
2001
Highly Regioselective Transition-Metal-Catalyzed 1-Alkene Polymerizations:  A Simple Method for the Detection and Precise Determination of Regioirregular Monomer Enchainments
1998
Influence of Monomer Concentration on the Stereospecificity of 1-Alkene Polymerization Promoted by C2-symmetric ansa-Metallocene Catalysts
1994
Ziegler‐Natta oligomerization of 1‐alkenes: a catalyst's “fingerprint”, 1. Hydrooligomerization of propene in the presence of a highly isospecific MgCl2‐supported catalyst
1993
C2-symmetric ansa-metallocene catalysts for propene polymerization: Stereoselectivity and enantioselectivity
1998
Isotactic 1‐butene polymerization promoted by C2‐symmetric metallocene catalysts
1997
Nonconventional Catalysts for Isotactic Propene Polymerization in Solution Developed by Using High‐Throughput‐Screening Technologies
2006
Microstructure of polypropylene
2001
Growing chain isomerizations in metallocene-catalyzed Ziegler-Natta 1-alkene polymerization
1995
Improving the Performance of Methylalumoxane:  A Facile and Efficient Method to Trap “Free” Trimethylaluminum
2003
Block Copolymers of Highly Isotactic Polypropylene via Controlled Ziegler−Natta Polymerization
2004
“Oscillating” Metallocene Catalysts:  What Stops the Oscillation?
2003
On the First Insertion of α-Olefins in Hafnium Pyridyl-Amido Polymerization Catalysts
2009
A High‐Throughput Approach to Repurposing Olefin Polymerization Catalysts for Polymer Upcycling
2022
Stopped-flow polymerizations of ethene and propene in the presence of the catalyst systemrac-Me2Si(2-methyl-4-phenyl-1-indenyl)2ZrCl2/methylaluminoxane
1999
Propene polymerization in the presence of MgCl2‐supported Ziegler‐Natta catalysts, 5. Microstructural characterization of the “isotactic” (heptane‐insoluble) polypropene fractions
1995
Hydrooligomerization of propene: a “fingerprint” of a Ziegler‐Natta catalyst, 2. A reinterpretation of results for isospecific homogeneous systems
1992
High-Field 13C NMR Characterization of Ethene-1-13C/Propene Copolymers Prepared with Cs-Symmetric ansa-Metallocene Catalysts:  A Deeper Insight into the Regio- and Stereoselectivity of Syndiotactic Propene Polymerization
1998
Hydrooligomerization of propene: a “fingerprint” of a Ziegler‐Natta catalyst, 1. Preliminary results for MgCl2‐supported systems
1992
Metallocene-Catalyzed Propene Polymerization:  From Microstructure to Kinetics. Cs-Symmetric ansa-Zirconocenes
2003
Mimicking Ziegler-Natta Catalysts in Homogeneous Phase, 1.C2-Symmetric Octahedral Zr(IV) Complexes with Tetradentate [ONNO]-Type Ligands
2001
Ziegler‐Natta oligomerization of 1‐alkenes: A catalyst's “fingerprint”, 2. Preliminary results of propene hydrooligomerization in the presence of the homogeneous isospecific catalyst system rac‐(EBI)ZrCl2/MAO
1993
Intra- and Intermolecular NMR Studies on the Activation of Arylcyclometallated Hafnium Pyridyl-Amido Olefin Polymerization Precatalysts
2008
Polymerization of 3‐methyl‐1‐butene promoted by metallocene catalysts
1996
Propene Polymerization Promoted by C2-Symmetric Metallocene Catalysts:  From Atactic to Isotactic Polypropene in Consequence of an Isotope Effect
1996
Interfering Effects of Growing Chain Epimerization on Metallocene-Catalyzed Isotactic Propene Polymerization
1997
New Evidence on the Nature of the Active Sites in Heterogeneous Ziegler−Natta Catalysts for Propene Polymerization
1997
Advances in the 13C NMR Microstructural Characterization of Propene Polymers
1995
Effects of Regiochemical and Stereochemical Errors on the Course of Isotactic Propene Polyinsertion Promoted by Homogeneous Ziegler-Natta Catalysts
1994
The First Molecularly Characterized Isotactic Polypropylene-block-polyethylene Obtained via “Quasi-Living” Insertion Polymerization
2003
Full Assignment of the 13C NMR Spectra of Regioregular Polypropylenes:  Methyl and Methylene Region
1997
Advances in the 13C NMR characterization of ethene/propene copolymers, 1
2002
Syndiotactic Poly(propylene) from [Me2Si(3,6‐di‐tert‐butyl‐9‐fluorenyl)(Ntert‐butyl)]TiCl2–Based Catalysts: Chain‐End or Enantiotopic‐Sites Stereocontrol?
2003
Backbone rearrangement during olefin capture as the rate limiting step in molecular olefin polymerization catalysis and its effect on comonomer affinity
2017
Rankless by CCL
2026