Standout Papers
Citation Impact
Citing Papers
Anti-Markovnikov alkene oxidation by metal-oxo–mediated enzyme catalysis
2017 StandoutScienceNobel
Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life
2016 StandoutScienceNobel
Organic Synthesis—Where now?
1990
Hypervalent iodine reagents in the total synthesis of natural products
2011
Dynamic Covalent Chemistry
2002 StandoutNobel
Brønsted Acid Catalyzed Enantioselective Semipinacol Rearrangement for the Synthesis of Chiral Spiroethers
2009
1,4‐Pentenyne as a Five‐Carbon Synthon for Efficient and Selective Syntheses of Natural Products Containing 2,4‐Dimethyl‐1‐penten‐1,5‐ylidene and Related Moieties by Means of Zr‐Catalyzed Carboalumination of Alkynes and Alkenes
2007 StandoutNobel
Dynamic imine chemistry
2012 StandoutNobel
Asymmetric spiroacetalization catalysed by confined Brønsted acids
2012 StandoutNatureNobel
The crystal structure of the Dess–Martin periodinane
2012
2‐Iodoxybenzoic Acid—A Simple Oxidant with a Dazzling Array of Potential Applications
2011
Click Chemistry: Diverse Chemical Function from a Few Good Reactions
2001 StandoutNobel
o‐Iodoxybenzoic Acid (IBX): pKa and Proton‐Affinity Analysis
2006
IBX—New Reactions with an Old Reagent
2001
Olefin Metathesis Involving Ruthenium Enoic Carbene Complexes
2001 StandoutNobel
Enantioselective Mannich-Type Reactions Using a Novel Chiral Zirconium Catalyst for the Synthesis of Optically Active β-Amino Acid Derivatives
2000
A ligand assisted Claisen rearrangement
1993
Retro-Diels−Alder Femtosecond Reaction Dynamics
1996 StandoutNobel
Spatial Arrangement and Preparative Organic Synthesis
1967
Chemistry of Polyvalent Iodine
2008 Standout
Self-Assembly of Dendrimers by Slippage
2002 StandoutNobel
Total Synthesis and Bioactivity of an Unnatural Enantiomer of Merrilactone A: Development of an Enantioselective Desymmetrization Strategy
2007
Total Synthesis of (+)-Azaspiracid-1. An Exhibition of the Intricacies of Complex Molecule Synthesis
2008
Asymmetric Activation of Racemic Ruthenium(II) Complexes for Enantioselective Hydrogenation
1998 StandoutNobel
Femtosecond Dynamics of Transition States and the Concept of Concertedness: Nitrogen Extrusion of Azomethane Reactions
1998 StandoutNobel
DMP-mediated one-pot oxidative olefination of silyl ethers
2005
A General Model for Selectivity in Olefin Cross Metathesis
2003 StandoutNobel
Computer-Assisted Design of Complex Organic Syntheses
1969 StandoutScienceNobel
Chemie und Biologie der Saragossasäuren/Squalestatine
1996
Transition Structures of Hydrocarbon Pericyclic Reactions
1992 Standout
Ring Expansion via Olefin Metathesis
2002 StandoutNobel
Asymmetric heck reaction-anion capture process. A catalytic asymmetric synthesis of the key intermediates for the Capnellenols
1993
A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds
1997 Standout
Efficient Regio‐ and Enantioselective Mannich Reactions
1996
Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts
2001 StandoutNobel
Preparation of Dess–Martin periodinane—the role of the morphology of 1-hydroxy-1,2-benziodoxol-3(1H )-one 1-oxide precursor
1997
Stereo-controlled synthesis of prelasalocid, a key precursor proposed in the biosynthesis of polyether antibiotic lasalocid A
2007
Synthesis of Functionalized Olefins by Cross and Ring-Closing Metatheses
2000 StandoutNobel
Strategy and Methodology Development for the Total Synthesis of Polyether Ionophore Antibiotics
2000
Mechanisms of Bile Acid Biosynthesis Studied with 3α-3H- and 4β-3H-Cholesterol
1964 StandoutNobel
Nonanomeric Spiroketals in Natural Products: Structures, Sources, and Synthetic Strategies
2005
Efficient and Stereoselective Synthesis of Freelingyne via Pd-Catalyzed Cross Coupling and Lactonization1
1997 StandoutNobel
Catalytic Enantioselective Conversion of Epoxides to Thiiranes
2016 StandoutNobel
A Stabilized Formulation of IBX (SIBX) for Safe Oxidation Reactions Including a New Oxidative Demethylation of Phenolic Methyl Aryl Ethers
2003
Tetrahydrofuran-Containing Macrolides: A Fascinating Gift from the Deep Sea
2013
Synthesis of Discodermolide Subunits by SE2‘ Addition of Nonracemic Allenylstannanes to Aldehydes
1998
Regio‐ and Stereoselective Syntheses with Organocopper Reagents
1997
Total Synthesis of α-Pyrone Meroterpenoids, Novel Bioactive Microbial Metabolites
2005 StandoutNobel
Highly Stereo- and Regioselective Synthesis of (Z)-Trisubstituted Alkenes via 1-Bromo-1-alkyne Hydroboration−Migratory Insertion−Zn-Promoted Iodinolysis and Pd-Catalyzed Organozinc Cross-Coupling
2007 StandoutNobel
Catalytic, Asymmetric Transannular Aldolizations: Total Synthesis of (+)-Hirsutene
2008 StandoutNobel
Preparation of optically active α-silylcarbonyl compounds using asymmetric alkylation of α-silylacetic esters and asymmetric metal-carbene insertion into the SiH bond
1997
Synthesis of (tetrahydrofuran-2-yl)acetates based on a ‘cyclization/hydrogenation/enzymatic kinetic resolution’ strategy
2006
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Reactivity in the formation of lactones from aromatic carboxylic acids with organohypervalent iodine compounds in the Suárez system
1999
Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates
2014 StandoutNobel
On the stereochemistry of biogenetic-like olefin cyclizations
1973
The stereocontrolled Claisen rearrangement of tertiary allylic sulphone esters: stereoselective formation of trisubstituted double bonds
1991
Ground- and Excited-State Reactions of Norbornene and Isomers: A CASSCF Study and Comparison with Femtosecond Experiments
1999 StandoutNobel
Boron Reagents in Process Chemistry: Excellent Tools for Selective Reductions
2006
Why Is Tetrazole Formation by Addition of Azide to Organic Nitriles Catalyzed by Zinc(II) Salts?
2003 StandoutNobel
Computer-Assisted Analysis in Organic Synthesis
1985 StandoutScienceNobel
Enantio- and Diastereoselective Stepwise Cyclization of Polyprenoids Induced by Chiral and Achiral LBAs. A New Entry to (−)-Ambrox, (+)-Podocarpa-8,11,13-triene Diterpenoids, and (−)-Tetracyclic Polyprenoid of Sedimentary Origin
2002
Organic Polyvalent Iodine Compounds
1996 Standout
Novel catalytic bromolactonization of alkenoic acids using iodobenzene and Oxone®
2011
One-pot selective oxidation/olefination of primary alcohols using TEMPO–BAIB system and stabilized phosphorus ylides
2005
Total Synthesis of Isoroquefortine C
2001
Biomimetic polyene cyclizations
1976
Stereocontrolled functionalization in acyclic systems by exploiting internal 1,2-asymmetric induction — generation of polypropionate and related motifs
1996
Chemistry and Biology of the Zaragozic Acids (Squalestatins)
1996
Highly stereoselective synthesis of mupirocin H
2017
Synthetic Studies of Antitumor Macrolide Rhizoxin: Stereoselective Syntheses of the C(1)−C(9) and C(12)−C(26) Subunits
1998
A synthesis of C1–C22 fragment of the immunosuppressant FK 506. Stereoselective construction of (E)-trisubstituted double bond (C19–C20) via ester-enolate claisen rearrangement
1991
Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction
2012 Standout
Mechanisms of Nucleophilic Organocopper(I) Reactions
2011
Recent aspects of thiirane chemistry
1993
Click Chemistry: Diverse Chemical Function from a Few Good Reactions
2001 StandoutNobel
Organic Iodine(I, III, and V) Chemistry: 10 Years of Development at the Medical University of Warsaw, Poland
2000
Synthesis of Trisubstituted Alkenes via Olefin Cross-Metathesis
1999 StandoutNobel
Confined acids catalyze asymmetric single aldolizations of acetaldehyde enolates
2018 StandoutScienceNobel
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
Confined Acid-Catalyzed Asymmetric Carbonyl–Ene Cyclization
2015 StandoutNobel
Advances in Synthetic Applications of Hypervalent Iodine Compounds
2016 Standout
Synthesis, Structure, and Activity of Enhanced Initiators for Olefin Metathesis
2003 StandoutNobel
Der Stand der Totalsynthese zu Beginn des 21. Jahrhunderts
2000
Polyvalent Scaffolds. Counting the Number of Seats Available for Eosin Guest Molecules in Viologen-Based Host Dendrimers
2003 StandoutNobel
Disulfonimide-Catalyzed Asymmetric Synthesis of β3-Amino Esters Directly from N-Boc-Amino Sulfones
2013 StandoutNobel
Synthesis of Novel Di‐ and Trisaccharide Mimetics with Non‐Glycosidic Amino Bridges
2007
Rapid and Stereoselective Synthesis of Spirocyclic Ethers via the Intramolecular Piancatelli Rearrangement
2013
Organoiodine(V) Reagents in Organic Synthesis
2011
Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts
2016 StandoutScience
Asymmetric Catalysis via Cyclic, Aliphatic Oxocarbenium Ions
2017 StandoutNobel
Syntheses of new chiral bicyclic sultams and their use as auxiliaries in asymmetric conjugate addition of Grignard reagents
2002
Regio- and Stereoselective Synthesis of (E)-Alkene trans-Xaa-Pro Dipeptide Mimetics Utilizing Organocopper-Mediated Anti-SN2‘ Reactions
2002
The Claisen Rearrangement. Response to Solvents and Substituents: The Case for Both Hydrophobic and Hydrogen Bond Acceleration in Water and for a Variable Transition State
1997
Applications of the β-Azidonation Reaction to Organic Synthesis. α,β-Enones, Conjugate Addition, and γ-Lactam Annulation
1998
Die faszinierenden Alkaloide aus Yuzuriha
1992
The Enchanting Alkaloids of Yuzuriha
1992
Activation of olefins via asymmetric Brønsted acid catalysis
2018 StandoutScienceNobel
Asymmetric Total Synthesis of Neoxaline
2013 StandoutNobel
New Insights into the Mechanism of Ruthenium-Catalyzed Olefin Metathesis Reactions
2001 StandoutNobel
Claisen Rearrangement over the Past Nine Decades
2004
Catalytic Asymmetric Transacetalization
2010 StandoutNobel
2-Iodoxybenzoic acid (IBX): an efficient hypervalent iodine reagent
2010
A Solid-Phase Approach to Mouse Melanocortin Receptor Agonists Derived from a Novel Thioether Cyclized Peptidomimetic Scaffold
2002 StandoutNobel
Asymmetric Enamine Catalysis
2007 StandoutNobel
Amino Acid Mediated Intramolecular Asymmetric Aldol Reaction to Construct a New Chiral Bicyclic Enedione Containing a Seven-Membered Ring: Remarkable Inversion of Enantioselectivity Compared to the Six-Membered Ring Example
2006
Scope and Limitation of Organocuprates, and Copper or Nickel Catalyst-Modified Grignard Reagents for Installation of an Alkyl Group onto cis-4-Cyclopentene-1,3-diol Monoacetate
2001
Unraveling the Photoswitching Mechanism in Donor–Acceptor Stenhouse Adducts
2016 StandoutNobel
Concerted Rearrangement versus Heterolytic Cleavage in Anionic [2,3]- and [3,3]-Sigmatropic Shifts. A DFT Study of Relationships among Anion Stabilities, Mechanisms, and Rates
2003
Hypervalent Iodine Reagents for the Oxidation of Alcohols and Their Application to Complex Molecule Synthesis
2004
Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents
2012 StandoutNobel
The syntheses of large-ring compounds
1995
Organische Synthese — wohin?
1990
Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds
1996 StandoutNobel
Synthesis of Zaragozic Acid A/Squalestatin S1
1995
Simple, stereocontrolled synthesis of thromboxane B2 from -glucose
1977 StandoutNobel
Works of Robert E. Ireland being referenced
Studies directed towards the total synthesis of FK-506 preparation of a C(1) to C(15) segment
1989
Experiments directed toward the total synthesis of terpenes. XVII. Development of methods for the synthesis of pentacyclic triterpenes based on a mechanistic interpretation of the stereochemical outcome of the Friedel-Crafts cyclialkylation reaction
1972
An improved procedure for the preparation of the Dess-Martin periodinane
1993
3-Acyltetramic acid antibiotics. 1. Synthesis of tirandamycic acid
1981
Convergent synthesis of polyether ionophore antibiotics: an approach to the synthesis of the monensin tetrahydropyran-bis(tetrahydrofuran) via the ester enolate Claisen rearrangement and reductive decarboxylation
1985
Experiments Directed toward the Total Synthesis of Terpenes. VII. The Synthesis of (±)-8β-Carbomethoxy-13-oxopodocarpanone, a Degradation Product of Phyllocladene1
1966
A new method for the synthesis of structurally specific olefins from enolate anions
1969
The total synthesis of ionophore antibiotics. A convergent synthesis of lasalocid A (X537A)
1983
Macrolide total synthesis. The synthesis of spiro ketal intermediates and their cleavage into open-chain derivatives
1983
An Approach to the Total Synthesis of Steroids1a
1963
Convergent synthesis of polyether ionophore antibiotics: the synthesis of the monensin spiroketal
1985
Macrocyclic lactone formation through sulfide contraction. Synthesis of (.+-.)-diplodialide A
1980
Total synthesis of dl-shionone, a tetracyclic triterpene
1974
Enolate Claisen rearrangement of esters from furanoid and pyranoid glycals
1980
Total synthesis of FK-506. Part 1: Construction of the C16–C34 fragment
1997
Application of the Swern oxidation to the manipulation of highly reactive carbonyl compounds
1985
Experiments directed toward the total synthesis of terpenes. XXI. Alternate total synthesis of dl-alnusenone via polyene cyclization
1975
Claisen rearrangement of allyl esters
1972
Use of a masked aldol unit in the synthesis of the right side of FK-506
1990
A chiral primary alcohol equivalent: silyl-assisted asymmetric induction in the ester enolate Claisen rearrangement
1984
Experiments directed toward the total synthesis of terpenes. 23. Synthesis of 4a-methyl-4,4a,7,8-tetrahydro-9H-benzocycloheptene-2(3H),5(6H)-dione (B-homo Wieland-Miescher ketone): a versatile intermediate for terpene synthesis
1979
Pheromonsynthesen ‐ Modellreaktionen zur Synthese von Polyether‐Antibiotika
1981
Synthesis of the 9,10-acetonide of 9-dihydro-FK-506
1992
Total synthesis of an unsymmetrical pentacyclic triterpene. DL-germanicol
1970
Total synthesis of terpenes. XIX. Synthesis of 8-methoxy-4a.beta., 10b.beta., 12a.alpha.-trimethyl-3,4,4a,4b.alpha.,5,6,10b,11,12,12a-decahydrochrysen-1(2H)-one, a key intermediate in the total synthesis of (+-)-shionone
1975
Methodology for the enantioselective synthesis of aldols and other 1,3-dioxygenated systems
1990
A Total Synthesis of FK-5061
1996
Approach to the total synthesis of chlorothricolide: synthesis of "7-epi-bottom half" and its union with "top half" systems
1981
Approach to the total synthesis of chlorothricolide: synthesis of (.+-.)-19,20-dihydro-24-O-methylchlorothricolide methyl ester ethyl carbonate
1986
Convergent synthesis of polyether ionophore antibiotics: the synthesis of the monensin bis(tetrahydrofuran) via the Claisen rearrangement of an ester enolate with a .beta.-leaving group
1985
The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation
1976 Standout
Carboalumination of 1-alkynes and in situ transmetalation to higher order cyanocuprates. Stereospecific synthesis of tri- and disubstituted olefins by conjugate addition to enones
1990
Allylic Rearrangements. XLV.1 The Reaction of Thionyl Chloride with 4β-Hydroxycholesteryl Benzoate
1959
Macrolide total synthesis. The synthesis of seco-acid derivatives for the synthesis of methymycin and 10-deoxymethymycin
1983
Convergent synthesis of polyether ionophore antibiotics: protective manipulation and synthesis of monensin A
1993
The convergent synthesis of polyether ionophore antibiotics: the synthesis of the A ring carbamonensin spiro ether
1988
Efficient, stereoselective total synthesis of (.+-.)-aphidicolin
1981
Stereospecific synthesis and acid-catalyzed cyclization of 4,6-dimethyl-trans-5,9-decadienal
1970
3-Acyltetramic acid antibiotics. 2. Synthesis of (+)-streptolic acid
1988
Stereochemistry of the Claisen rearrangement of derivatives of 5-tert-butyl-1-(hydroxymethyl)-1-cyclohexene: preferred axial attachment of the side chain
1983
A stereoselective method For the generation of aldol-type systems
1977
Stereochemical control in the ester enolate Claisen rearrangement. 1. Stereoselectivity in silyl ketene acetal formation
1991
Convergent synthesis of polyether ionophore antibiotics: synthesis of the spiroketal and tricyclic glycal segments of monensin
1993
Total synthesis of lasalocid A (X537A)
1980
The stereoselective generation of ester enolates
1975
Total synthesis of terpenes. XXII. Polyene cyclization approach to tetradecahydropicene derivatives for pentacyclic triterpene synthesis
1975
An approach to the total synthesis of aplysiatoxin
1988
Stereochemical control in the ester enolate Claisen rearrangement. 2. Chairlike vs boatlike transition-state selection
1991