Citation Impact
Citing Papers
SuFEx-enabled, agnostic discovery of covalent inhibitors of human neutrophil elastase
2019 StandoutNobel
Cp*CoIII‐Catalyzed Bis‐isoquinolone Synthesis by C−H Annulation of Arylamide with 1,3‐Diyne
2017
Direct alkenylation of non-aromatic enamides via palladium-catalyzed oxidative coupling: Synthetic developments and applications
2013
A temporary stereocentre approach for the asymmetric synthesis of chiral cyclopropane-carboxaldehydes
2009
Recent advances in the catalytic asymmetric synthesis of β-amino acids
2010 StandoutNobel
Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups
2013 Standout
Direct CH Amidation of Benzoic Acids to Introduce meta‐ and para‐Amino Groups by Tandem Decarboxylation
2015
RhIII‐Catalyzed Oxidative Olefination of Vinylic CH Bonds: Efficient and Selective Access to Di‐unsaturated α‐Amino Acid Derivatives and Other Linear 1,3‐Butadienes
2011
Aerobic Double Dehydrogenative Cross Coupling between Cyclic Saturated Ketones and Simple Arenes
2014
Catalytic asymmetric conjugate addition of dialkylzinc reagents to α,β-unsaturated sulfones
2009 StandoutNobel
The syntheses and catalytic applications of unsymmetrical ferrocene ligands
2004
Copper/Silver‐Mediated Direct ortho‐Ethynylation of Unactivated (Hetero)aryl CH Bonds with Terminal Alkyne
2014
Copper-mediated oxidative direct C–C (hetero)aromatic cross-coupling
2012
Recent advances in homogeneous nickel catalysis
2014 StandoutNature
Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper‐Catalyzed 1,6‐Boration
2014
Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
2018
Selective Ruthenium‐Catalyzed Three‐Component Synthesis of Pyrroles
2012
The Asymmetric Hetero‐Diels–Alder Reaction in the Syntheses of Biologically Relevant Compounds
2014
Chiral Brønsted Acid Catalyzed Enantioselective Aza‐Diels–Alder Reaction of Brassard's Diene with Imines
2006
Mild and Efficient C2‐Alkenylation of Indoles with Alkynes Catalyzed by a Cobalt Complex
2012
Silanol as a Removable Directing Group for the PdII‐Catalyzed Direct Olefination of Arenes
2011
C–H bond halogenation catalyzed or mediated by copper: an overview
2015
Regioselective C3 Alkenylation of 4 H‐pyrido[1,2‐a]pyrimidin‐4‐ones via Palladium‐Catalyzed CH Activation
2014
Diastereoselective Carbometalation of Oxa‐ and Azabicyclic Alkenes under Iron Catalysis
2010
Rh-catalyzed sulfonic acid group directed ortho C–H olefination of arenes
2013
Enantioselective 1,3‐Dipolar Cycloaddition of Cyclic Enones Catalyzed by Multifunctional Primary Amines: Beneficial Effects of Hydrogen Bonding
2007
Palladium‐Catalyzed Dehydrogenation/Oxidative Cross‐Coupling Sequence of β‐Heteroatom‐Substituted Ketones
2012
Palladium‐Catalyzed Oxidative Cross‐Coupling between Heterocycles and Terminal Alkynes with Low Catalyst Loading
2013
Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation
2011 Standout
Genetically programmed chiral organoborane synthesis
2017 StandoutNatureNobel
Catalytic decarboxylative alkylation of β-keto acids with sulfonamides via the cleavage of carbon–nitrogen and carbon–carbon bonds
2011
Rhodium(III)‐Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group
2012
Rhodium-catalyzed oxidative C2-acylation of indoles with aryl and alkyl aldehydes
2012
Ruthenium(II)‐Catalyzed CH Alkenylations of Phenols with Removable Directing Groups
2013
Chiral Copper(II)‐Catalyzed Enantioselective Boron Conjugate Additions to α,β‐Unsaturated Carbonyl Compounds in Water
2012
Profound Methyl Effects in Drug Discovery and a Call for New CH Methylation Reactions
2013
Dehydrogenative Heck coupling of biologically relevant N-heteroarenes with alkenes: discovery of fluorescent core frameworks
2012
Controllable Mono‐/Dialkenylation of Benzyl Thioethers through Rh‐Catalyzed Aryl CH Activation
2013
Copper‐Mediated C6‐Selective Dehydrogenative Heteroarylation of 2‐Pyridones with 1,3‐Azoles
2014
Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group
2013
Direct Oxidative Coupling of Arenes with Olefins by Rh‐Catalyzed CH Activation in Air: Observation of a Strong Cooperation of the Acid
2012
Dehydrogenative Heck Reaction of Furans and Thiophenes with Styrenes under Mild Conditions and Influence of the Oxidizing Agent on the Reaction Rate
2011
2-Pyridylmethyl ether: a readily removable and efficient directing group for amino acidligand accelerated ortho-C–H olefination of phenols
2012
Metal‐Catalyzed Enantioselective Allylation in Asymmetric Synthesis
2007 Standout
Palladium-catalyzed oxidative direct C–H/C–H cross coupling of anilides with β-keto esters
2013
Copper-catalyzed direct thiolation of azoles with aliphatic thiols
2011
Relativistic effects in homogeneous gold catalysis
2007 StandoutNature
Rhodium‐Catalyzed Oxidative Olefination of CH Bonds in Acetophenones and Benzamides
2010
Catalytic Enantioselective Reduction of β,β‐Disubstituted Vinyl Phenyl Sulfones by Using Bisphosphine Monoxide Ligands
2007
A New Direction in CH Alkenylation: Silanol as a Helping Hand
2012
Copper‐Mediated and Copper‐Catalyzed Cross‐Coupling of Indoles and 1,3‐Azoles: Double CH Activation
2012
Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
2010 StandoutNobel
Removable Directing Groups in Organic Synthesis and Catalysis
2011
Copper-catalyzed asymmetric ring opening of oxabicyclic alkenes with organolithium reagents
2012 StandoutNobel
endo-Selective Intramolecular Pauson-Khand Reactions ofγ-Oxygenated-α,β-unsaturated Phenylsulfones
2001
A Cationic High‐Valent Cp*CoIII Complex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed CH Bond Activation
2013
Catalytic Enantioselective 1,3‐Dipolar Cycloaddition Reactions of Azomethine Ylides and Alkenes by Using Phosphoramidite–Silver(I) Complexes
2008
Nickel catalyzed alkylation of N-aromatic heterocycles with Grignard reagents through direct C–H bond functionalization
2012
Cp*CoIII‐Catalyzed C2‐Selective Addition of Indoles to Imines
2013
Catalytic Enantioselective Addition of Dialkylzinc Reagents to N‐Acylpyridinium Salts
2009 StandoutNobel
Catalytic Asymmetric Synthesis of Phosphine Boronates
2015 StandoutNobel
The Organic Approach to Asymmetric Catalysis
2006 StandoutScienceNobel
Synthesis of Conjugated Dienes via a Biomimetic Aerobic Oxidative Coupling of Two CvinylH Bonds
2013
Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)‐Catalyzed CH Bond Activation
2013
Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
2006
Diversity‐Oriented Enantioselective Synthesis of Highly Functionalized Cyclic and Bicyclic Alcohols
2012 StandoutNobel
Design, synthesis, and biological evaluation of cytotoxic 11-aminoalkenylindenoisoquinoline and 11-diaminoalkenylindenoisoquinoline topoisomerase I inhibitors
2004
Dehydrogenative alkenylation of uracils via palladium-catalyzed regioselective C–H activation
2013
Pd‐Catalyzed C–H Olefination of (Hetero)Arenes by Using Saturated Ketones as an Olefin Source
2012
Copper‐Promoted Site‐Selective Acyloxylation of Unactivated C(sp3)H Bonds
2014
Iron‐Catalyzed C(sp2)H and C(sp3)H Methylations of Amides and Anilides
2015
Carboxylic Acids as Traceless Directing Groups for Formal meta‐Selective Direct Arylation
2011
Enantioselective Synthesis of Boron‐Substituted Quaternary Carbon Stereogenic Centers through NHC‐Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones
2014
Beyond Directing Groups: Transition‐Metal‐Catalyzed CH Activation of Simple Arenes
2012 Standout
Organocatalysed asymmetric Mannich reactions
2007
Highly Enantioselective Copper‐Catalyzed Ring Opening of Oxabicyclic Alkenes with Grignard Reagents
2008
Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups
2011
Copper-catalyzed direct alkylation of 1,3-azoles with N-tosylhydrazones bearing a ferrocenyl group: a novel method for the synthesis of ferrocenyl-based ligands
2014
Copper(ii )-catalyzed methoxylation of unactivated (hetero)aryl C–H bonds using a removable bidentate auxiliary
2014
Carboxylate‐Assisted Iridium‐Catalyzed C−H Amination of Arenes with Biologically Relevant Alkyl Azides
2015
Ruthenium-Catalyzed Direct C–H Bond Arylations of Heteroarenes
2011
Carbon−Carbon Bond Formation through Double sp2 C−H Activations: Synthesis of Ferrocenyl Oxazoline Derivatives
2007
FeCl3: an efficient catalyst for reactions of electron-rich arenes with imines or aziridines
2008
Iron Catalysis in Organic Synthesis
2015 Standout
Metallkatalysierte enantioselektive Allylierungen in der asymmetrischen Synthese
2007
3d Transition Metals for C–H Activation
2018 Standout
Iridium(iii )-catalyzed regioselective C7-sulfonamidation of indoles
2016
Copper-Mediated Direct C2-Cyanation of Indoles Using Acetonitrile as the Cyanide Source
2013
A Click Ligation Based on SuFEx for the Metal‐Free Synthesis of Sugar and Iminosugar Clusters
2016
Sulfones and sulfoxides in the total synthesis of biologically active natural compounds
2000
Cu(I)‐Catalyzed Site Selective Acyloxylation of Indoline Using O2 as the Sole Oxidant
2018
Copper-catalyzed C–C direct cross-coupling: an efficient approach to phenyl-2-(phenylthiophenyl)-methanones
2017
Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile
2011
Rhodium(iii )-catalyzed regioselective C2-amidation of indoles with N-(2,4,6-trichlorobenzoyloxy)amides and its synthetic application to the development of a novel potential PPARγ modulator
2014
Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation
2012 StandoutNobel
A Unified Strategy Towards N‐Aryl Heterocycles by a One‐Pot Copper‐Catalyzed Oxidative C–H Amination of Azoles
2014
Cobalt-Catalyzed Oxidative Cyclization of Benzamides with Maleimides: Synthesis of Isoindolone Spirosuccinimides
2017
An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and Alkenes via CH Functionalization
2014
Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes
2012
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
2011 Standout
Iron-Catalyzed Cascade Arene−Aldehyde Addition/Cyclizations for the Highly Efficient Synthesis of Xanthenes and Its Analogous: Observation of a C−C Bond Cleavage in Indole-Based Triarylmethanes
2009
Recent developments in asymmetric catalytic addition to CN bonds
2006
A simple access to triarylmethane derivatives from aromatic aldehydes and electron-rich arenes catalyzed by FeCl3
2007
Copper-Catalyzed Diels−Alder Reactions
2008
A Concise Update on the Applications of Chiral Ferrocenyl Phosphines in Homogeneous Catalysis Leading to Organic Synthesis
2003
Ligand Effects in Gold‐ and Platinum‐Catalyzed Cyclization of Enynes: Chiral Gold Complexes for Enantioselective Alkoxycyclization.
2005
Copper-Mediated Oxidative Coupling of Benzamides with Maleimides via Directed C–H Cleavage
2015
Scalable and Highly Diastereo- and Enantioselective Catalytic Diels–Alder Reaction of α,β-Unsaturated Methyl Esters
2018 StandoutNobel
An expedient synthesis of 3-arylmethylbutenolides from α-methylene-γ-butyrolactones: a useful synthetic application of palladium-catalyzed chelation-controlled oxidative arylation protocol
2012
Pd(II)-Catalyzed Hydroxyl-Directed C−H Olefination Enabled by Monoprotected Amino Acid Ligands
2010
Switch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic Olefins
2016
Copper-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Grignard Reagents
2005
Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation
2010
Catalytic Enantioselective Addition of Diorganozinc Reagents to Vinyl Sulfones
2008
Copper‐Catalyzed or ‐Mediated CH Bond Functionalizations Assisted by Bidentate Directing Groups
2016
Iron-catalyzed sulfonylimine synthesis under neutral conditions
2009
Computational Studies of Carboxylate-Assisted C–H Activation and Functionalization at Group 8–10 Transition Metal Centers
2017
Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations
2015 Standout
Copper-Catalyzed Regio- and Enantioselective Synthesis of Chiral Enol Acetates and β-Substituted Aldehydes
2010 StandoutNobel
Iron‐Catalyzed Directed Alkylation of Alkenes and Arenes with Alkylzinc Halides
2015
Palladium‐Catalyzed, Chelation‐Assisted Stereo‐ and Regioselective Synthesis of Tetrasubstituted Olefins by Oxidative Heck Arylation
2012
Iron-Catalyzed Cross-Coupling of Unactivated Secondary Alkyl Thio Ethers and Sulfones with Aryl Grignard Reagents
2013
Nickel-Catalyzed Stereoselective Alkenylation of C(sp3)–H Bonds with Terminal Alkynes
2017
Palladium‐Catalyzed Intermolecular C‐2 Alkenylation of Indoles Using Oxygen as the Oxidant
2014
Rhodium(III)‐Catalyzed in situ Oxidizing Directing Group‐ Assisted CH Bond Activation and Olefination: A Route to 2‐Vinylanilines
2015
Copper-Catalyzed Formal [4 + 1] Cycloaddition of Benzamides and Isonitriles via Directed C–H Cleavage
2015
Aerobic Direct C–H Arylation of Nonbiased Olefins
2014
Application of the aza-Diels–Alder reaction in the synthesis of natural products
2017
On the Mechanism of Cu-Catalyzed Enantioselective Extended Conjugate Additions: A Structure-Based Approach
2014 StandoutNobel
Catalytic Enantioselective 1,3‐Dipolar Cycloaddition Reactions of Azomethine Ylides and Alkenes by Using Phosphoramidite–Silver(I) Complexes
2008
Controlled Regiodivergent C–H Bond Activation of Imidazo[1,5-a]pyridine via Synergistic Cooperation between Aluminum and Nickel
2014
Expedient C–H Chalcogenation of Indolines and Indoles by Positional-Selective Copper Catalysis
2016
Cu-mediated C2-dehydrogenative homocoupling of indoles via C–H activation assisted by a removable N-pyrimidyl group
2016
Catalytic Asymmetric Epoxidation of Cyclic Enones
2008 StandoutNobel
Rhodium(III)‐Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group
2012
Phosphoramidite: privilegierte Liganden in der asymmetrischen Katalyse
2010
Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates
2012
Rhodium-Catalyzed Oxidative ortho-Acylation of Benzamides with Aldehydes: Direct Functionalization of the sp2 C–H Bond
2011
Nickel-Catalyzed Reaction of C–H Bonds in Amides with I2: ortho-Iodination via the Cleavage of C(sp2)–H Bonds and Oxidative Cyclization to β-Lactams via the Cleavage of C(sp3)–H Bonds
2016
Copper-/Silver-Mediated Arylation of C(sp2)–H Bonds with 2-Thiophenecarboxylic Acids
2015
Recent Trends in Copper‐Catalyzed C−H Amination Routes to Biologically Important Nitrogen Scaffolds
2015
Group 11 Metal Complexes of the Mesocyclic Thioether Aminophosphonites [‐OC10H6(μ‐S)C10H6O‐]PNC4H8E (E = O, NMe)
2006
BODIPY Peptide Labeling by Late‐Stage C(sp3)−H Activation
2018
Highly Regioselective C2-Alkenylation of Indoles Using the N-Benzoyl Directing Group: An Efficient Ru-Catalyzed Coupling Reaction
2013
Highly Site‐Selective and Direct Ortho‐C−H Nitration, Trifluoromethylation and Cyanation at the C1‐Position of Carbazole Frameworks
2016
Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated with Phosphine and N-Heterocyclic Carbene Ligands
2003 StandoutNobel
Synthesis of Indolines by Copper-Mediated Intramolecular Aromatic C–H Amination
2015
Palladium-Catalyzed Oxidative Olefination of Phenols Bearing Removable Directing Groups under Molecular Oxygen
2014
Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to α,β-Unsaturated Imines Derived from α-Aminoacids. Enantioselective Synthesis of γ-Substituted α-Dehydroaminoesters
2006
Cobalt(II)-Catalyzed C–H Amination of Arenes with Simple Alkylamines
2016
Ligand promoted Pd-catalyzed dehydrogenative alkenylation of hetereoarenes
2013
Rhodium‐Catalyzed CH Olefination of Aryl Weinreb Amides
2013
A sustainable and simple catalytic system for direct alkynylation of C(sp2)–H bonds with low nickel loadings
2015
A Novel, Stereoselective Silyl-Directed Stevens [1,2]-Shift of Ammonium Ylides
2002
Electrochemical Cobalt‐Catalyzed C−H Activation
2018
Copper(II)-Catalyzed Aerobic Oxidative Synthesis of Substituted 1,2,3- and 1,2,4-Triazoles from Bisarylhydrazones via C–H Functionalization/C–C/N–N/C–N Bonds Formation
2012
Development and Applications of Disulfonimides in Enantioselective Organocatalysis
2015 StandoutNobel
Ni(II)-Catalyzed C(sp2)–H Alkynylation/Annulation with Terminal Alkynes under an Oxygen Atmosphere: A One-Pot Approach to 3-Methyleneisoindolin-1-one
2016
Synthesis of Olefin‐Oxazoline Ligands (OlefOx) by Rhodium(III)‐Catalyzed Oxidative Olefination
2012
Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis
2013 StandoutScience
Co(II)-Catalyzed Regioselective Cross-Dehydrogenative Coupling of Aryl C–H Bonds with Carboxylic Acids
2017
Lanthanum Aryloxide/Pybox-Catalyzed Direct Asymmetric Mannich-Type Reactions Using a Trichloromethyl Ketone as a Propionate Equivalent Donor
2007
Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization
2012
Enantioselective Synthesis of Triarylmethanes by Chiral Imidodiphosphoric Acids Catalyzed Friedel–Crafts Reactions
2014
Nickel-Catalyzed Direct Amination of Arenes with Alkylamines
2015
Iridium(III)-Catalyzed Direct C-7 Amination of Indolines with Organic Azides
2014
Ligand Effects in Gold- and Platinum-Catalyzed Cyclization of Enynes: Chiral Gold Complexes for Enantioselective Alkoxycyclization
2005
Pyridine Ligands as Promoters in PdII/0-Catalyzed C–H Olefination Reactions
2012
Synthesis of Polymer Dielectric Layers for Organic Thin Film Transistors via Surface-Initiated Ring-Opening Metathesis Polymerization
2004 StandoutNobel
Asymmetric Synthesis of α-Substituted β-Amino Sulfones by Aza-Michael Addition to Alkenyl Sulfones and Subsequent α-Alkylation
2000
Iron‐Catalyzed C−H Alkynylation through Triazole Assistance: Expedient Access to Bioactive Heterocycles
2017
Retention or Inversion in Stereospecific Nickel-Catalyzed Cross-Coupling of Benzylic Carbamates with Arylboronic Esters: Control of Absolute Stereochemistry with an Achiral Catalyst
2013
Nickel-catalyzed ortho-halogenation of unactivated (hetero)aryl C–H bonds with lithium halides using a removable auxiliary
2016
A Dirhodium(II)−Carbenoid Route to (−)- and (+)-Geissman−Waiss Lactone: Synthesis of (1R,7R,8R)-(−)-Turneforcidine
2001
Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents
2009
Catalytic Regioselective Synthesis of Structurally Diverse Indene Derivatives from N-Benzylic Sulfonamides and Disubstituted Alkynes
2010
Enantioselective Imidation of Sulfides via Enzyme-Catalyzed Intermolecular Nitrogen-Atom Transfer
2014 StandoutNobel
Catalytic Enantioselective C−C Bond Forming Conjugate Additions with Vinyl Sulfones
2005
Coordinating Activation Strategy‐Induced Selective C−H Trifluoromethylation of Anilines
2017
Palladium(II)-Catalyzed Direct Alkenylation and Arylation of Arenes: Removable 2-Pyridylsulfinyl Group Assisted C–H Bond Activation
2011
Copper‐Mediated Thiolation of Unactivated Heteroaryl C−H Bonds with Disulfides under Ligand‐ and Metal‐Oxidant‐Free Conditions
2017
Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules
2015
The Phenylsulfonyl Group as anendo Stereochemical Controller in Intramolecular Pauson–Khand Reactions of 3-Oxygenated 1,6-Enynes
2000
Rh Catalyzed C–H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes
2011
Pd(II)-Catalyzed Primary-C(sp3)–H Acyloxylation at Room Temperature
2012
Catalytic Asymmetric Conjugate Addition of Grignard Reagents to α,β-Unsaturated Sulfones
2008 StandoutNobel
Isothiocyanate-Directed Ortho-Selective Halogenation of Arenes via C–H Functionalization
2017
Carboxylic Acids as Traceless Directing Groups for Formal meta‐Selective Direct Arylation
2011
Ester‐Directed Selective Olefination of Acrylates by Rhodium Catalysis
2014
Chiral Copper(II)‐Catalyzed Enantioselective Boron Conjugate Additions to α,β‐Unsaturated Carbonyl Compounds in Water
2012
Modifiable Sulfur Tethers as Directing Groups for Aromatic CH Acetoxylation Reactions
2011
Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation
2017
Palladium‐Catalyzed Highly Regioselective Arylation of Allylamines with Thiophenes and Furans
2012
Asymmetric β-boration of α,β-unsaturated carbonyl compounds with chiral Rh[bis(oxazolinyl)phenyl] catalysts
2013
Unified Approach to Imidodiphosphate-Type Brønsted Acids with Tunable Confinement and Acidity
2021 StandoutNobel
Directed C–H Alkenylation of Aryl Imines with Alkenyl Phosphates Promoted by a Cobalt–N‐Heterocyclic Carbene Catalyst
2017
Copper(II) Triflate Catalyzed Amination and Aziridination of 2-Alkyl Substituted 1,3-Dicarbonyl Compounds
2012
Iron Halide-Mediated Regio- and Stereoselective Halosulfonylation of Terminal Alkynes with Sulfonylhydrazides: Synthesis of (E)-β-Chloro and Bromo Vinylsulfones
2013
Is Spin-Component Scaled Second-Order Møller−Plesset Perturbation Theory an Appropriate Method for the Study of Noncovalent Interactions in Molecules?
2007
Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies
2011
A consistent and accurateab initioparametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
2010 Standout
Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper‐Catalyzed 1,6‐Boration
2014
Direct Catalytic Enantioselective Aza‐Diels–Alder Reactions
2005
Manganese(II/III/I)-Catalyzed C–H Arylations in Continuous Flow
2018
Copper-Catalyzed Direct Nitration on Aryl C–H Bonds by Concomitant Azidation–Oxidation with TMS Azide and TBHP under Aerobic Conditions
2017
Direct and Site‐Selective Palladium‐Catalyzed C‐7 Acylation of Indolines with Aldehydes
2015
ortho‐Olefination of Arylaldehyde O‐Methyloximes through Palladium‐Catalyzed C–H Activation
2012
Versatile palladium-catalyzed C–H olefination of (hetero)arenes at room temperature
2014
Cobalt‐Catalyzed Direct Amination of Arenes with Alkylamines via Bidentate‐Chelation Assistance
2016
A novel Fe(II)/diaryl prolinol catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with alkenes
2010
Preparation of Chiral Homoannularly Bridged N,P‐Ferrocenyl Ligands by Intramolecular Coupling of 1,5‐Dilithioferrocenes and Their Application in Asymmetric Allylic Substitution Reactions
2007
Directing‐Group‐Assisted Transition‐Metal‐Catalyzed Direct Intermolecular C−H Amidation and Amination of Arenes
2016
Noncovalent Interactions between Graphene Sheets and in Multishell (Hyper)Fullerenes
2007
Highly regioselective palladium-catalyzed direct alkenylation of thiazolo[3,2-b]-1,2,4-triazoles via CH activation
2014
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
Entfernbare dirigierende Gruppen in der organischen Synthese und Katalyse
2011
Pd-Catalyzed Arylation/Oxidation of Benzylic C–H Bond
2012
Cobalt‐Catalyzed C(sp2)−H Methylation by using Dicumyl Peroxide as both the Methylating Reagent and Hydrogen Acceptor
2016
Redox of ferrocene controlled asymmetric dehydrogenative Heck reaction via palladium-catalyzed dual C–H bond activation
2013
Chiral Sulfur Ligands for Asymmetric Catalysis
2007
Mannich-type Reactions of in Situ Generated N-Acyliminium Ions from α-Amido p-Tolylsulfones with Silyl Enolates
2011
Enantioselective Synthesis of Chiral Sulfones by Rh-Catalyzed Asymmetric Addition of Boronic Acids to α,β-Unsaturated 2-Pyridyl Sulfones
2007
Cp∗Co(III)-catalyzed ortho C H amidation of 2-pyridinyl ferrocenes with 1,4,2-dioxazol-5-ones
2018
Ohne dirigierende Gruppen: übergangsmetallkatalysierte C‐H‐Aktivierung einfacher Arene
2012
Nickel(II)‐Mediated Regioselective CH Monoiodination of Arenes and Heteroarenes by using Molecular Iodine
2016
Iron-Catalyzed Directed C(sp2)–H and C(sp3)–H Functionalization with Trimethylaluminum
2015
Intermolecular Dehydrogenative Heck Reactions
2011
Intermolecular Amination of Unactivated C(sp3)−H Bonds with Cyclic Alkylamines: Formation of C(sp3)−N Bonds through Copper/Oxygen‐Mediated C(sp3)−H/N−H Activation
2016
Atropodiastereoselective CH Olefination of Biphenyl p‐Tolyl Sulfoxides with Acrylates
2013
Identification of a New Endogenous Metabolite and the Characterization of Its Protein Interactions through an Immobilization Approach
2008 StandoutNobel
Planar‐Chiral [2.2]Paracyclophane‐Based Amides as Proligands for Titanium‐ and Zirconium‐Catalyzed Hydroamination
2017
Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group
2012
Simple and Sustainable Iron-Catalyzed Aerobic C–H Functionalization of N,N-Dialkylanilines
2013
Disulfonimide-Catalyzed Asymmetric Synthesis of β3-Amino Esters Directly from N-Boc-Amino Sulfones
2013 StandoutNobel
Enantiodivergent Brucine Diol‐Catalyzed 1,3‐Dipolar Cycloaddition of Azomethine Ylides with α,β‐Unsaturated Ketones
2016
Palladium-catalyzed arylation of α,β-unsaturated Weinreb amides
2012
Recent advances in enantioselective copper-catalyzed 1,4-addition
2009 StandoutNobel
Copper-Catalyzed Enantioselective Synthesis of trans-1-Alkyl-2-substituted Cyclopropanes via Tandem Conjugate Addition−Intramolecular Enolate Trapping
2010 StandoutNobel
Nickel Complex Catalyzed Efficient Activation of sp3 and sp2 C–H Bonds for Alkylation and Arylation of Oxygen Containing Heterocyclic Molecules
2013
Copper(ii )-mediated regioselective N-arylation of pyrroles, indoles, pyrazoles and carbazole via dehydrogenative coupling
2016
Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions
2011
Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis
2004 Standout
Copper-catalyzed ortho-halogenation of arenes and heteroarenes directed by a removable auxiliary
2015
Palladium-Catalyzed Dehydrogenative β′-Functionalization of β-Keto Esters with Indoles at Room Temperature
2012
Pd-Catalyzed Olefination of Furans and Thiophenes with Allyl Esters
2011
Enantioselective Synthesis of Boron‐Substituted Quaternary Carbon Stereogenic Centers through NHC‐Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones
2014
Palladium-Catalyzed C–H Alkenylation of Arenes Using Thioethers as Directing Groups
2012
Copper-Catalyzed Electrochemical C–H Amination of Arenes with Secondary Amines
2018
Copper-mediated thiolation of carbazole derivatives and related N-heterocycle compounds
2015
Cu-mediated direct regioselective C-2 chlorination of indoles
2015
Cobalt‐Catalyzed Annulation Reactions via C−H Bond Activation
2017
Phenyltrimethylammonium Salts as Methylation Reagents in the Nickel‐Catalyzed Methylation of C−H Bonds
2016
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Access to Cinnamyl Derivatives from Arenes and Allyl Esters by a Biomimetic Aerobic Oxidative Dehydrogenative Coupling
2014
Copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones
2004 StandoutNobel
Palladium(II)-Catalyzed Direct Alkenylation of Nonaromatic Enamides
2012
Synthesis of Pyrrole‐Annulated Heterocycles through Copper‐Catalyzed Site‐Selective Dehydrogenative Cross‐Coupling
2017
Palladium-Catalyzed Direct Oxidative Alkenylation of Azoles
2010
Cobalt-Catalyzed, Aminoquinoline-Directed Coupling of sp2 C–H Bonds with Alkenes
2014
Iridium-Catalyzed Direct C–H Amination with Alkylamines: Facile Oxidative Insertion of Amino Group into Iridacycle
2015
Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications
2017 Standout
The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
2000 StandoutNobel
Functionalization of Azacalixaromatics by Cu(II)-Catalyzed Oxidative Cross-Coupling Reaction between the Arene C–H Bond and Boronic Acids
2016
Nitrated Confined Imidodiphosphates Enable a Catalytic Asymmetric Oxa-Pictet–Spengler Reaction
2016 StandoutNobel
Copper(II)-Mediated Chelation-Assisted Regioselective N-Naphthylation of Indoles, Pyrazoles and Pyrrole through Dehydrogenative Cross-Coupling
2017
Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides
2010
Site- and Regioselective Monoalkenylation of Pyrroles with Alkynes via Cp*CoIII Catalysis
2016
FeCl3·6H2O-Catalyzed Alkenylation of Indoles with Aldehydes
2012
Synthesis of Indolines via Pd(II)-Catalyzed Amination of C–H Bonds Using PhI(OAc)2 as the Bystanding Oxidant
2013
Copper-catalyzed oxidative C–H/C–H cross-coupling of benzamides and thiophenes
2015
Rhodium(III)‐Catalyzed Regioselective Direct C‐2 Alkenylation of Indoles Assisted by the Removable N‐(2‐Pyrimidyl) Group
2014
Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions
2008
Regioselective Ortho Olefination of Aryl Sulfonamide via Rhodium-Catalyzed Direct C–H Bond Activation
2014
Solar Synthesis: Prospects in Visible Light Photocatalysis
2014 StandoutScience
Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides
2003
Silanol: A Traceless Directing Group for Pd-Catalyzed o-Alkenylation of Phenols
2011
Asymmetric Enamine Catalysis
2007 StandoutNobel
Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update
2016
The Phenylsulfonyl Group as anendo Stereochemical Controller in Intramolecular Pauson–Khand Reactions of 3-Oxygenated 1,6-Enynes
2000
Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence
2014
Palladium(II)/Polyoxometalate‐Catalyzed Direct C‐3 Alkenylation of Indoles using Dioxygen as the Terminal Oxidant
2013
Electrochemical C−H/N−H Activation by Water‐Tolerant Cobalt Catalysis at Room Temperature
2018
Palladium-catalyzed N-(2-pyridyl)sulfonyl-directed C(sp3)–H γ-arylation of amino acid derivatives
2012
Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C−H Functionalization
2010
Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents
2012 StandoutNobel
Ligand-Induced Acceleration of the Intramolecular [3 + 2] Cycloaddition between Alkynes and Alkylidenecyclopropanes
2005
Palladium(II)-Catalyzed Dehydrogenative Alkenylation of Cyclic Enaminones via the Fujiwara–Moritani Reaction
2011
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
Palladium-catalyzed direct alkenylation of 2-methyl-4H-pyrido[1,2-a]pyrimidin-4-ones using oxygen as the oxidant
2015
Cobalt(III)-Catalyzed C2-Selective C–H Alkynylation of Indoles
2015
Catalytic Asymmetric Pictet–Spengler-Type Reaction for the Synthesis of Optically Active Indolo[3,4-cd][1]benzazepines
2011
Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation
2016
Rhodium(III)-Catalyzed Intermolecular Amidation with Azides via C(sp3)–H Functionalization
2014
ESI-MS Studies of the Dehydrogenative Heck Reaction of Furans with Acrylates Using Benzoquinone as the Reoxidant and DMSO as the Solvent
2012
Transition Metal Photoredox Catalysis of Radical Thiol-Ene Reactions
2012
Catalytic Asymmetric Vinylogous Prins Cyclization: A Highly Diastereo- and Enantioselective Entry to Tetrahydrofurans
2016 StandoutNobel
Copper-Catalyzed Carboxamide-Directed Ortho Amination of Anilines with Alkylamines at Room Temperature
2014
Iron‐Catalyzed CC Bond Cleavage and CN Bond Formation
2013
Recent Advances in Transition Metal‐Catalyzed Methylation Reactions
2015
Copper-Catalyzed Asymmetric Borylation: Construction of a Stereogenic Carbon Center Bearing Both CF3 and Organoboron Functional Groups
2017
Synthesis of Carbazoles by Copper-Catalyzed Intramolecular C–H/N–H Coupling
2014
Palladium-Catalyzed C−H Arylation of 2,5-Substituted Pyrroles
2010
Recent advances in copper-mediated chelation-assisted functionalization of unactivated C–H bonds
2016
Copper-catalyzed peri-selective direct sulfenylation of 1-naphthylamines with disulfides
2018
Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme
2017 StandoutNobel
Novel Iminium Ion Equivalents Prepared through C−H Oxidation for the Stereocontrolled Synthesis of Functionalized Propargylic Amine Derivatives
2003
Copper-Catalyzed C–H Azidation of Anilines under Mild Conditions
2012
Works of Ramón Goméz Arrayás being referenced
2‐Pyridyl Sulfoxide: A Versatile and Removable Directing Group for the PdII‐Catalyzed Direct CH Olefination of Arenes
2011
Recent Applications of Chiral Ferrocene Ligands in Asymmetric Catalysis
2006
Copper‐Catalyzed Mild Nitration of Protected Anilines
2014
Catalytic asymmetric conjugate boration of α,β-unsaturated sulfones
2011
First planar chiral bidentate ligand based on a (η5-cyclopentadienyl)(η4-cyclobutadiene) cobalt backbone: high efficiency in enantioselective palladium-catalyzed allylic substitutions
2004
A Copper(II )‐Catalyzed Aza‐Friedel–Crafts Reaction of N‐(2‐Pyridyl)sulfonyl Aldimines: Synthesis of Unsymmetrical Diaryl Amines and Triaryl Methanes
2005
Catalytic asymmetric direct Mannich reaction: a powerful tool for the synthesis of α,β-diamino acids
2009
Copper-catalyzed ortho-C–H amination of protected anilines with secondary amines
2014
Chiral thioether-based catalysts in asymmetric synthesis: recent advances
2010
PdII‐Catalyzed CH Olefination of N‐(2‐Pyridyl)sulfonyl Anilines and Arylalkylamines
2011
PdII‐Catalysed CH Functionalisation of Indoles and Pyrroles Assisted by the Removable N‐(2‐Pyridyl)sulfonyl Group: C2‐Alkenylation and Dehydrogenative Homocoupling
2010
Copper-catalyzed ortho-halogenation of protected anilines
2013
Catalytic Asymmetric Conjugate Reduction of β,β‐Disubstituted α,β‐Unsaturated Sulfones
2007
Cationic Planar Chiral Palladium P,S Complexes as Highly Efficient Catalysts in the Enantioselective Ring Opening of Oxa‐ and Azabicyclic Alkenes
2004
Palladium(II)‐Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by the N‐(2‐Pyridyl)sulfonyl Protecting Group
2009
Enantiocontrolled Synthesis of β‐Branched α‐Amino Acids by Using CuI‐Catalyzed 1,4‐Addition of Glycine Imines to β‐Substituted gem‐Diactivated Olefins
2011
Highly Enantioselective Copper(I)−Fesulphos-Catalyzed 1,3-Dipolar Cycloaddition of Azomethine Ylides
2005
CuI–Fesulphos complexes: efficient chiral catalysts for asymmetric 1,3-dipolar cycloaddition of azomethine ylides
2007
Stereoselective synthesis of hydroxypyrrolidines and hydroxypiperidines by cyclization of γ-oxygenated-α,β-unsaturated sulfones
1996
Catalytic Enantioselective Approach to the Stereodivergent Synthesis of (+)-Lasubines I and II
2007
Palladium(II)‐Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by the N‐(2‐Pyridyl)sulfonyl Protecting Group
2009
Synthesis of alkylidene pyrrolo[3,4-b]pyridin-7-one derivatives via RhIII-catalyzed cascade oxidative alkenylation/annulation of picolinamides
2014
5- and 6-Exo Radical Cyclizations of γ-Oxygenated-α,β-Unsaturated Sulfones
1996
RhI/RhIII catalyst-controlled divergent aryl/heteroaryl C–H bond functionalization of picolinamides with alkynes
2015
Fesulphos-Palladium(II) Complexes as Well-Defined Catalysts for Enantioselective Ring Opening of Meso Heterobicyclic Alkenes with Organozinc Reagents
2005
Catalytic Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides with Vinyl Sulfones
2006
Pd-Catalyzed Directed ortho-C–H Alkenylation of Phenylalanine Derivatives
2015
Understanding the Behavior of N-Tosyl and N-2-Pyridylsulfonyl Imines in CuII-Catalyzed Aza-Friedel−Crafts Reactions
2008
Cobalt‐Catalyzed ortho‐C−H Functionalization/Alkyne Annulation of Benzylamine Derivatives: Access to Dihydroisoquinolines
2017
Palladium-Catalyzed Coupling of Arene C–H Bonds with Methyl- and Arylboron Reagents Assisted by the Removable 2-Pyridylsulfinyl Group
2011
Cationic Planar Chiral Palladium P,S Complexes as Highly Efficient Catalysts in the Enantioselective Ring Opening of Oxa‐ and Azabicyclic Alkenes
2004
Stereoselective Synthesis of Polyhydroxylated Indolizidines from γ-Hydroxy α,β-Unsaturated Sulfones
1998
1-Phosphino-2-sulfenylferrocenes: efficient ligands in enantioselective palladium-catalyzed allylic substitutions and ring opening of 7-oxabenzonorbornadienes
2002
PdII-Catalyzed Di-o-olefination of Carbazoles Directed by the Protecting N-(2-Pyridyl)sulfonyl Group
2013
Sulfoxide-Mediated Asymmetric Synthesis of Glycosidase Inhibitor Precursors
1997
Copper-Catalyzed Anti-Stereocontrolled Ring Opening of Oxabicyclic Alkenes with Grignard Reagents
2003
Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes
2012
Chelation‐Induced Catalytic Multiple Arylation of Allylic 2‐Pyridyl Sulfones
2004
Facile Enantiodivergent Approach to 5-Hydroxy-5,6-dihydro-2(1H)-pyridones. First Total Synthesis of Both Enantiomers of Pipermethystine
2001
Palladium-Catalyzed Carbonylative Cyclization of Amines via γ-C(sp3)–H Activation: Late-Stage Diversification of Amino Acids and Peptides
2016
Transition Metal Complexes of Fesulphos Ligands in Enantioselective Catalytic Transformations
2005
1-Phosphino-2-sulfenylferrocenes as Planar Chiral Ligands in Enantioselective Palladium-Catalyzed Allylic Substitutions
2003
PdII‐Catalyzed CH Olefination of N‐(2‐Pyridyl)sulfonyl Anilines and Arylalkylamines
2011
Copper-Catalyzed Enantioselective Conjugate Addition of Dialkylzinc Reagents to (2-Pyridyl)sulfonyl Imines of Chalcones
2005
An efficient and stereoselective synthesis of enantiopure 1,2,7-trihydroxylated pyrrolizidines
1999
Palladium Complexes of Chiral Planar 1-Phosphino-2-sulfenylferrocenes as Efficient Catalysts in Enantioselective Diels−Alder Reactions
2005
Copper-Catalyzed Ring-Opening of Heterobicyclic Alkenes with Grignard Reagents: Remarkably Highanti-Stereocontrol
2006
Chiral Copper Complexes of Phosphino Sulfenyl Ferrocenes as Efficient Catalysts for Enantioselective Formal Aza Diels−Alder Reactions of N-Sulfonyl Imines
2003
A stereoselective approach to polyhydroxylated quinolizidine alkaloids
1997
Copper(I)-Fesulphos Lewis Acid Catalysts for Enantioselective Mannich-Type Reaction of N-Sulfonyl Imines
2006
Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides with α,β-Unsaturated Ketones
2008
Catalytic Asymmetric Conjugate Reduction of β,β‐Disubstituted α,β‐Unsaturated Sulfones
2007
Copper-Catalyzed Anti-Stereocontrolled Ring-Opening of Azabicyclic Alkenes with Grignard Reagents
2004
Catalytic Asymmetric Inverse-Electron-Demand Diels−Alder Reaction of N-Sulfonyl-1-Aza-1,3-Dienes
2007
Sulfenylphosphinoferrocenes: Novel planar chiral ligands in enantioselective catalysis
2006
Chirale Ferrocenliganden in der asymmetrischen Katalyse
2006
A Copper(II )‐Catalyzed Aza‐Friedel–Crafts Reaction of N‐(2‐Pyridyl)sulfonyl Aldimines: Synthesis of Unsymmetrical Diaryl Amines and Triaryl Methanes
2005