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Hypervalent Iodine Mediated para-Selective Fluorination of Anilides
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Radical Pd(iii )/Pd(i ) reductive elimination in palladium sequences
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Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes
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An Improved Catalyst System for the Pd-Catalyzed Fluorination of (Hetero)Aryl Triflates
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Palladium‐Catalyzed CF Bond Formation via Directed CH Activation
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Organic Photoredox Catalysis
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Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIII Catalytic Cycle
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Nickel-Mediated Oxidative Fluorination for PET with Aqueous [18F] Fluoride
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Iron(II)-Catalyzed Intramolecular Olefin Aminofluorination
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Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas
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C–H Bond Activation at Palladium(IV) Centers
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2018
Copper-Catalyzed Oxidative Cyclization of Carboxylic Acids
2016
Development and Applications of Disulfonimides in Enantioselective Organocatalysis
2015 StandoutNobel
Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination
2013
Boron Trifluoride Etherate Functioning as a Fluorine Source in an Iodosobenzene-Mediated Intramolecular Aminofluorination of Homoallylic Amines
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Palladium-Catalyzed Transformations of Alkyl C–H Bonds
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Silver-Catalyzed Radical Fluorination of Alkylboronates in Aqueous Solution
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Precise Modulation of CO2 Sorption in Ti8Ce2–Oxo Clusters: Elucidating Lewis Acidity of the Ce Metal Sites and Structural Flexibility
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Palladium-Catalyzed Tandem Fluorination and Cyclization of Enynes
2011
Mechanistic Studies of the Rhodium-Catalyzed Direct C–H Amination Reaction Using Azides as the Nitrogen Source
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Plasmonic photothermic directed broadband sunlight harnessing for seawater catalysis and desalination
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Metal-Catalyzed Decarboxylative C–H Functionalization
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Recent Applications of Rh‐ and Pd‐Catalyzed C(sp3)–H Functionalization in Natural Product Total Synthesis
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Palladium‐Catalyzed Intramolecular Fluorooxylation of Styrenes
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Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates
2014 StandoutNobel
Cp*CoIII-catalyzed directed C–H trifluoromethylthiolation of 2-phenylpyridines and 6-arylpurines
2017
The medicinal chemist's toolbox for late stage functionalization of drug-like molecules
2015
Iron-Catalyzed, Fluoroamide-Directed C–H Fluorination
2016
Rhodium-catalyzed regioselective opening of vinyl epoxides with Et3N·3HF reagent – formation of allylic fluorohydrins
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Copper/B2pin2-catalyzed C–H difluoroacetylation–cycloamidation of anilines leading to the formation of 3,3-difluoro-2-oxindoles
2016
Copper-Catalyzed, Directing Group-Assisted Fluorination of Arene and Heteroarene C–H Bonds
2013
Oxidative Coupling of Terminal Alkyne with α-Hydroxy Ketone: An Expedient Approach toward Ynediones
2014
Copper-Mediated Fluorination of Arylboronate Esters. Identification of a Copper(III) Fluoride Complex
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Mechanistic Investigations of Palladium-Catalyzed Allylic Fluorination
2014
Cu(ClO4)2-Mediated Arene C–H Bond Halogenations of Azacalixaromatics Using Alkali Metal Halides as Halogen Sources
2012
Bimetallic Redox Synergy in Oxidative Palladium Catalysis
2011
Nucleophilic Deoxyfluorination of Phenols via Aryl Fluorosulfonate Intermediates
2017
Azine Activation via Silylium Catalysis
2021 StandoutNobel
Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents
2014 Standout
Copper-Catalyzed Amidation of 2-Phenylpyridine with Oxygen as the Terminal Oxidant
2011
Metal free fluoroamination of allylsilanes: A route to 3-fluoropyrrolidines
2012
Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions
2011 Standout
Silver-mediated fluorination of potassium aryltrifluoroborates with Selectfluor®
2014
Palladium–Silver Cooperativity in an Aryl Amination Reaction through C–H Functionalization
2015
Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes
2014
Aerobic Copper-Catalyzed Organic Reactions
2013 Standout
Cu(OTf)2-Mediated Fluorination of Aryltrifluoroborates with Potassium Fluoride
2013
Silver-Catalyzed Radical Aminofluorination of Unactivated Alkenes in Aqueous Media
2013
Silver‐Assisted Difunctionalization of Terminal Alkynes: Highly Regio‐ and Stereoselective Synthesis of Bromofluoroalkenes
2012
Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance
2017 Standout
Recent Advances in Radical C–H Activation/Radical Cross-Coupling
2017
Identification of simple arylfluorosulfates as potent agents against resistant bacteria
2021 StandoutNobel
Unexpected Formation of Ferrocenyl(vinyl)benzoquinoline Ligands by Oxidation of an Alkyne Benzoquinolate Platinum(II) Complex
2013
Harnessing the biocatalytic potential of iron- and α-ketoglutarate-dependent dioxygenases in natural product total synthesis
2020
Palladium-Catalyzed Site-Selective Fluorination of Unactivated C(sp3)–H Bonds
2015
Oxidatively Induced C–H Activation at High Valent Nickel
2017
18F-Labeling of Arenes and Heteroarenes for Applications in Positron Emission Tomography
2016
Copper-catalyzed fluorination of 2-pyridyl aryl bromides
2013
Metalltriflimidate sind bessere Katalysatoren für die organische Synthese als Metalltriflate – der Effekt eines stark delokalisierten Gegenions
2010
Dual Catalysis Strategies in Photochemical Synthesis
2016 Standout
A novel improvement in ArLPdF catalytic fluorination of aromatic compounds
2011
Accelerating Palladium‐Catalyzed CF Bond Formation: Use of a Microflow Packed‐Bed Reactor
2011
Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-Fluoroisoquinolines and 4-Fluoropyrrolo[α]isoquinolines
2012
Advances in Synthetic Applications of Hypervalent Iodine Compounds
2016 Standout
Diversity Oriented Clicking (DOC): Divergent Synthesis of SuFExable Pharmacophores from 2‐Substituted‐Alkynyl‐1‐Sulfonyl Fluoride (SASF) Hubs
2020 StandoutNobel
Facial Tridentate Ligands for Stabilizing Palladium(IV) Complexes
2011
Palladium-Catalyzed ortho-Selective C–H Fluorination of Oxalyl Amide-Protected Benzylamines
2014
Palladium(II)‐Catalyzed Selective Monofluorination of Benzoic Acids Using a Practical Auxiliary: A Weak‐Coordination Approach
2011
Catalytic Enantioselective Cyclization and C3-Fluorination of Polyenes
2013
Fluorination Enhances NIR‐II Emission and Photothermal Conversion Efficiency of Phototheranostic Agents for Imaging‐Guided Cancer Therapy
2022
Copper-Mediated Fluorination of Aryl Iodides
2012
Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides
2014
Enantioselective Fluorination Reaction of β-Ketoester–Catalyzed Chiral Primary Amine–Based Multifunctional Catalyst Systems
2013
Aromatic Trifluoromethylation with Metal Complexes
2011 Standout
Copper-mediated C(sp2)–H amination using TMSN3as a nitrogen source: redox-neutral access to primary anilines
2014
Ag-catalyzed C–H/C–C bond functionalization
2016
Einführung von Fluor und fluorhaltigen funktionellen Gruppen
2013
Modern Carbon–Fluorine Bond Forming Reactions for Aryl Fluoride Synthesis
2014
Carbon(sp3)Fluorine Bond‐Forming Reductive Elimination from Palladium(IV) Complexes
2012
Site-Selective Aliphatic C–H Chlorination Using N-Chloroamides Enables a Synthesis of Chlorolissoclimide
2015
Pd(PPh3)4-catalyzed direct ortho-fluorination of 2-arylbenzothiazoles with an electrophilic fluoride N-fluorobenzenesulfonimide (NFSI)
2013
Beyond the Balz–Schiemann Reaction: The Utility of Tetrafluoroborates and Boron Trifluoride as Nucleophilic Fluoride Sources
2014
Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions
2011 Standout
Navigating the Chiral Pool in the Total Synthesis of Complex Terpene Natural Products
2017
Protein Glycoengineering Enabled by the Versatile Synthesis of Aminooxy Glycans and the Genetically Encoded Aldehyde Tag
2011 StandoutNobel
Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications
2017 Standout
Applications of Fluorine in Medicinal Chemistry
2015 Standout
Site-selective 18F fluorination of unactivated C–H bonds mediated by a manganese porphyrin
2017
Iridium-Catalyzed Allylic Fluorination of Trichloroacetimidates
2011
Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution
2012
Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones
2019 StandoutNobel
Photothermal Nanomaterials: A Powerful Light-to-Heat Converter
2023 Standout
Sulfur(VI) Fluoride Exchange (SuFEx)-Enabled High-Throughput Medicinal Chemistry
2020 StandoutNobel
Silver‐Catalyzed Intramolecular Aminofluorination of Activated Allenes
2011
Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex
2010
A New Portal to SuFEx Click Chemistry: A Stable Fluorosulfuryl Imidazolium Salt Emerging as an “F−SO2+” Donor of Unprecedented Reactivity, Selectivity, and Scope
2017 StandoutNobel
Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation
2016
Steric Crowding Makes Challenging Csp3–F Reductive Eliminations Feasible
2011
Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity
2015 Standout
Late-Stage Fluorination: From Fundamentals to Application
2014
Visible‐Light‐Promoted Trifluoromethylthiolation of Styrenes by Dual Photoredox/Halide Catalysis
2016
Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme
2017 StandoutNobel
Efficient SN2 Fluorination of Primary and Secondary Alkyl Bromides by Copper(I) Fluoride Complexes
2013
Nickel-Catalyzed C–H/C–O Coupling of Azoles with Phenol Derivatives
2011
Mild Silver‐Mediated Geminal Difluorination of Styrenes Using an Air‐ and Moisture‐Stable Fluoroiodane Reagent
2014
Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin
2012 Science
Works of Pingping Tang being referenced
Silver‐Catalyzed Oxidative Activation of Benzylic CH Bonds for the Synthesis of Difluoromethylated Arenes
2014
Silver‐Mediated Oxidative Aliphatic CH Trifluoromethylthiolation
2015
Asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes with a new trifluoromethoxylation reagent
2017
Total Synthesis of Schilancitrilactones B and C
2015
Silver-mediated fluorination of aryl silanes
2011
Gold(I)-Catalyzed Glycosidation of 1,2-Anhydrosugars
2008
Silver-Catalyzed Late-Stage Fluorination
2010
Transition-metal free oxidative aliphatic C–H fluorination
2015
Late-Stage Deoxyfluorination of Alcohols with PhenoFluor
2013
Silver‐Mediated Oxidative Aliphatic CH Trifluoromethylthiolation
2015
Carbohydrate Chemistry in the Total Synthesis of Saponins
2007
Deoxyfluorination of Phenols
2011
Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides
2010
Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives
2013
OSW Saponins: Facile Synthesis toward a New Type of Structures with Potent Antitumor Activities
2005
Total Synthesis of Lobatoside E, A Potent Antitumor Cyclic Triterpene Saponin
2008
Transition-Metal-Free Oxidative Aliphatic C–H Azidation
2015
Total Synthesis of Candicanoside A, a Rearranged Cholestane Disaccharide, and Its 4″‐O‐(p‐Methoxybenzoate) Congener
2008
Silver‐Catalyzed Oxidative Activation of Benzylic CH Bonds for the Synthesis of Difluoromethylated Arenes
2014