Standout Papers
Citation Impact
Citing Papers
Anti-Markovnikov alkene oxidation by metal-oxo–mediated enzyme catalysis
2017 StandoutScienceNobel
Palladium‐Catalyzed Oxidative Wacker Cyclizations in Nonpolar Organic Solvents with Molecular Oxygen: A Stepping Stone to Asymmetric Aerobic Cyclizations
2003
Migratory Insertion of Alkenes into Metal–Oxygen and Metal–Nitrogen Bonds
2013
The coordination chemistry of TCNE, TCNQ and related polynitrileπ acceptors
1994
“On Water”: Unique Reactivity of Organic Compounds in Aqueous Suspension
2005 StandoutNobel
Characterization of the pufferfish (Fugu) genome as a compact model vertebrate genome
1993 StandoutNatureNobel
Asymmetric Counteranion‐Directed Catalysis: Concept, Definition, and Applications
2012 StandoutNobel
Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions
2005
DNA-based asymmetric catalysis
2010 StandoutNobel
C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation
2012 Standout
Effect of the Metal‐Assisted Assembling Mode on the Redox States of Hexaazatriphenylene Hexacarbonitrile
2005 StandoutNobel
Carbon–heteroatom bond formation catalysed by organometallic complexes
2008 StandoutNature
Asymmetric Disulfonimide‐Catalyzed Synthesis of δ‐Amino‐β‐Ketoester Derivatives by Vinylogous Mukaiyama–Mannich Reactions
2014 StandoutNobel
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
2009 StandoutNobel
Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity
2009 Standout
Catalytic Asymmetric Reaction with Water: Enantioselective Synthesis of α‐Hydroxyesters by a Copper–Carbenoid OH Insertion Reaction
2007
A Chiral Lewis Acid Strategy for Enantioselective Allylic CH Oxidation
2008
Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes
2011
Palladium‐Catalyzed Oxidative Carbonylation Reactions
2013
Catalysis for fluorination and trifluoromethylation
2011 StandoutNature
Palladium‐Catalyzed Oxidative Wacker Cyclizations in Nonpolar Organic Solvents with Molecular Oxygen: A Stepping Stone to Asymmetric Aerobic Cyclizations
2003
A Highly Enantioselective Overman Rearrangement through Asymmetric Counteranion‐Directed Palladium Catalysis
2011 StandoutNobel
Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality
2009 Standout
Toward Waste‐Free Production of Heck Products with a Catalytic Palladium System under Oxygen
2003
An Investigation into the Allylic Imidate Rearrangement of Trichloroacetimidates Catalysed by Cobalt Oxazoline Palladacycles
2007
Hydroxypalladation Precedes the Rate‐Determining Step in the Wacker Oxidation of Ethene
2013
Palladium‐Catalyzed Cross‐Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize
2012 Standout
Aldehyde‐Selective Wacker‐Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co‐Catalyst
2013 Nobel
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
2008 StandoutNature
Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium
2009
Evidence that the availability of an allylic hydrogen governs the regioselectivity of the Wacker oxidation
2001
Transition‐Metal‐Catalyzed Synthesis of Hydroxylated Arenes
2010
The Catalytic Asymmetric Acetalization
2013 StandoutNobel
Palladium‐Catalyzed Selective Anti‐Markovnikov Oxidation of Allylic Esters
2013 StandoutNobel
Palladium‐Catalyzed anti‐Markovnikov Oxidation of Terminal Alkenes
2014 StandoutNobel
Hindered Aryllithium Reagents as Partners in Palladium‐Catalyzed Cross‐Coupling: Synthesis of Tri‐ and Tetra‐ortho‐Substituted Biaryls under Ambient Conditions
2013 StandoutNobel
Enzymatic functionalization of carbon–hydrogen bonds
2010 StandoutNobel
Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
2010 StandoutNobel
The Nature of [PdCl2(C2H4)(H2O)] as an Active Species in the Wacker Process: New Insights from Ab Initio Molecular Dynamics Simulations
2012
A Catalytic Asymmetric 6 π Electrocyclization: Enantioselective Synthesis of 2‐Pyrazolines
2009 StandoutNobel
Electrophilic Activation of Alkenes by Platinum(II): So Much More Than a Slow Version of Palladium(II)
2007
Carboxylation of anisole derivatives with CO and O2 catalyzed by Pd(OAc)2 and molybdovanadophosphates
2004
Bystanding F+ Oxidants Enable Selective Reductive Elimination from High‐Valent Metal Centers in Catalysis
2011
Catalytic enantioselective syn hydration of enones in water using a DNA-based catalyst
2010 StandoutNobel
DNA‐Based Catalytic Enantioselective Michael Reactions in Water
2007 StandoutNobel
Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach
2008
Reductive Amination without an External Hydrogen Source
2014 StandoutNobel
Beyond Directing Groups: Transition‐Metal‐Catalyzed CH Activation of Simple Arenes
2012 Standout
A Common Language for Physical Mapping of the Human Genome
1989 StandoutScience
Katalytische Oxidation von organischen Substraten durch molekularen Sauerstoff und Wasserstoffperoxid über einen mehrstufigen Elektronentransfer – ein biomimetischer Ansatz
2008
Selective oxidation of styrene to acetophenone in the presence of ionic liquidsPresented, in part, at the IUPAC CHEMRAWN XIV Conference on Green Chemistry:Toward Environmentally Benign Processes and Products, Boulder, Colorado, USA, 9–13 June 2001.
2002
Biphasic oxidation of arenes with oxygen catalysed by Pd(II)—heteropoly acid system: oxidative coupling versus hydroxylation
2002
Can a Ketone Be More Reactive than an Aldehyde? Catalytic Asymmetric Synthesis of Substituted Tetrahydrofurans
2018 StandoutNobel
Design and Preparation of 3,3‘-Disubstituted 2,2‘-Bis(oxazolyl)-1,1‘-binaphthyls (boxax): New Chiral Bis(oxazoline) Ligands for Catalytic Asymmetric Wacker-Type Cyclization
1999
Stereoselective Organic Reactions in Water
2002 Standout
Observations on the unusual stereochemistry of the oxidative cleavage of palladium–carbon bonds
1995
Parallel kinetic resolution of propargyl ketols: formal synthesis of (+)-bakkenolide A
2008
Palladium in some selective oxidation reactions
1983
Aldehyde‐Selective Wacker‐Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co‐Catalyst
2013 Nobel
A Physical Map of the Escherichia coli K12 Genome
1987 Science
Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes
2010
Regiochemistry of Wacker-type oxidation of vinyl group in the presence of neighboring oxygen functions. Part 2
1997
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
2011 Standout
Enantioselective Halocyclization Using Reagents Tailored for Chiral Anion Phase-Transfer Catalysis
2012
Scope and selectivity in palladium-catalyzed directed C–H bond halogenation reactions
2006
Kinetics of absorption of oxygen in aqueous solutions of cuprous chloride
1967
Toward Waste‐Free Production of Heck Products with a Catalytic Palladium System under Oxygen
2003
C-H Bond Functionalization in Complex Organic Synthesis
2006 StandoutScience
Catalytic Enantioselective Iodocyclization of γ-Hydroxy-cis-alkenes
2003
Quecksilber(II)- und Palladium(II)-katalysierte [3.3]-sigmatrope Umlagerungen
1984
Strong and Confined Acids Catalyze Asymmetric Intramolecular Hydroarylations of Unactivated Olefins with Indoles
2021 StandoutNobel
Oxidative Coupling of 1-(2,6-Dichlorobenzoyl)pyrroles and -pyrazoles and Alkyl Acrylates by Palladium(II) Acetate
1984
Palladium-Catalyzed Anti-Markovnikov Oxidation of Allylic Amides to Protected β-Amino Aldehydes
2014 StandoutNobel
Palladium catalyzed enantioselective rearrangement of allylic imidates to allylic amides
1999
Reactions of Hypervalent Iodine Reagents with Palladium: Mechanisms and Applications in Organic Synthesis
2007
Palladiumkatalysierte Kreuzkupplungen: eine historische Perspektive im Kontext der Nobel‐Preise 2010
2012
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
PyDipSi: A General and Easily Modifiable/Traceless Si-Tethered Directing Group for C−H Acyloxylation of Arenes
2010
Inaccessibility of β-Hydride Elimination from −OH Functional Groups in Wacker-Type Oxidation
2006
A Chiral Lewis Acid Strategy for Enantioselective Allylic CH Oxidation
2008
Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates
2014 StandoutNobel
Ru3(CO)12-Catalyzed Reaction of Pyridylbenzenes with Carbon Monoxide and Olefins. Carbonylation at a C−H Bond in the Benzene Ring
1997
Morphology of as‐polymerized polythylene II. Electron microscopy
1968
Anti-Markovnikov Oxidation of β-Alkyl Styrenes with H2O as the Terminal Oxidant
2016
Carbon−Oxygen Bond Formation at Metal(IV) Centers: Reactivity of Palladium(II) and Platinum(II) Complexes of the [2,6-(Dimethylaminomethyl)phenyl-N,C,N]-(Pincer) Ligand toward Iodomethane and Dibenzoyl Peroxide; Structural Studies of M(II) and M(IV) Complexes
2004
Regiochemistry of wacker-type oxidation of vinyl group in the presence of neighboring oxygen functions
1994
A Simple Catalytic Method for the Regioselective Halogenation of Arenes
2006
Regiochemistry of Wacker-type oxidation of vinyl group in the presence of neighboring oxygen functions. Part 1
1997
Stereochemistry of the oxidative cleavage of palladium-carbon bonds by cupric chloride
1977
Palladium‐Catalyzed Selective Anti‐Markovnikov Oxidation of Allylic Esters
2013 StandoutNobel
Modifiable Sulfur Tethers as Directing Groups for Aromatic CH Acetoxylation Reactions
2011
Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit
2009
Heterodimetallic PdII-based carboxylate-bridged complexes: Synthesis and structure of single-crystalline PdII–M (M = MnII, CoII, NiII, CuII, ZnII, NdIII, EuIII, CeIV) acetates
2006
Studies on PdII-catalyzed cyclization of 4′-hydroxy-2′-alkenyl 2-alkynoates
1993
Transition metal catalyzed oxidative functionalization of carbon–hydrogen bonds
2006
Palladium(II)-Catalyzed Asymmetric Coupling of Allylic Alcohols and Vinyl Ethers: Insight into the Palladium and Copper Bimetallic Catalyst
2009
Passive F+‐Oxidationsmittel ermöglichen die selektive reduktive Eliminierung hochvalenter Metallzentren in der Katalyse
2011
Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization
2012
Development of organopalladium(IV) chemistry: fundamental aspects and systems for studies of mechanism in organometallic chemistry and catalysis
1992
Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes
2016
Efficient and Highly Aldehyde Selective Wacker Oxidation
2012 Nobel
Catalyst-Controlled Wacker-Type Oxidation: Facile Access to Functionalized Aldehydes
2014 Nobel
Stereochemistry of Halogenation of some enyl complexes of palladium(II)
1974
Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis
2010
Carbon-carbon bond formation via palladium complexes
1969
The multistep avalanche chamber: A new high-rate, high-accuracy gaseous detector
1978 StandoutNobel
Pd(OAc)2-catalyzed oxidation of alcohols to aldehydes and ketones by molecular oxygen
1998
Intermolecular Dehydrogenative Heck Reactions
2011
Chemomimetic Biocatalysis: Exploiting the Synthetic Potential of Cofactor-Dependent Enzymes To Create New Catalysts
2015 StandoutNobel
C−C, C−O, C−N Bond Formation on sp2 Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents
2007
Catalysis of the Claisen Rearrangement of Aliphatic Allyl Vinyl Ethers
2002
An enantioselective artificial metallo-hydratase
2013
Catalytic conversions in water
2000
Green, Catalytic Oxidation of Alcohols in Water
2000 StandoutScience
Catalytic Asymmetric Intramolecular [4+2] Cycloaddition of In Situ Generated ortho‐Quinone Methides
2017 StandoutNobel
Asymmetric Catalysis via Cyclic, Aliphatic Oxocarbenium Ions
2017 StandoutNobel
TCNQ Dianion-Based Coordination Polymer Whose Open Framework Shows Charge-Transfer Type Guest Inclusion
2006 StandoutNobel
Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes
2011
Palladium(II)‐katalysierte aromatische Acetoxylierung, VIII. Zum Mechanismus der Acetoxylierung aromatischer Verbindungen mit Kaliumperoxydisulfat/Eisessig und 2,2′‐Bipyridinpalladium(II)‐acetat als Katalysator
1977
Recent Progress in Wacker Oxidations: Moving toward Molecular Oxygen as the Sole Oxidant
2007
Imparting Catalyst Control upon Classical Palladium-Catalyzed Alkenyl C–H Bond Functionalization Reactions
2011
PALLADIUM(II) CATALYZED SYNTHESIS OF ARYL CYANIDES FROM ARYL HALIDES
1973
Organopalladium intermediates in organic synthesis
1977
Aldehyde Selective Wacker Oxidations of Phthalimide Protected Allylic Amines: A New Catalytic Route to β3-Amino Acids
2009 StandoutNobel
Aldehydes from Pd-catalysed oxidation of terminal olefins
2007
Artificial concurrent catalytic processes involving enzymes
2014
Enantioselective Functionalization of Allylic C–H Bonds Following a Strategy of Functionalization and Diversification
2013
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
Palladium-Catalyzed Enantioselective Addition of Two Distinct Nucleophiles across Alkenes Capable of Quinone Methide Formation
2009
Mercury(II )‐ and Palladium(II )‐Catalyzed [3,3]‐Sigmatropic Rearrangements [New Synthetic Methods (46)]
1984
Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds
1996 StandoutNobel
Crystallization and melting of copolymers of polymethylene
1963 StandoutNobel
Nascent morphology of polyacetylene
1979 StandoutNatureNobel
Pd(II) catalyzed acetoxylation of arenes with iodosyl acetate
1996
Palladium(II)‐Catalyzed Isomerization of (Z)‐1,4‐Diacetoxy‐2‐Butene: Solvent Effects
2007
Works of Patrick M. Henry being referenced
The Mechanism of the Wacker Reaction: A Tale of Two Hydroxypalladations
2009
Palladium(II)-catalyzed aromatic substitution
1971
Equilibria between Palladium(II) Acetate and Olefins in Acetic Acid containing Sodium Acetate
1975
Stereochemistry of the Wacker Reaction: Modes of Addition of Hydroxide, Methoxide, and Phenyl at High and Low [Cl-]. A Study Using Chirality Transfer
1997
Oxidation of olefins by palladium(II). VII. Comparison of palladium(II) chloride with other noble metal salts in the copper(II) chloride promoted oxidation in acetic acid
1974
Palladium(II)-catalyzed exchange and isomerization reactions. II. Allylic ester exchange catalyzed by palladium(II) chloride in acetic acid
1972
Evidence for a second mode of hydroxypalladation in aqueous solution
1981
Palladium(II)-catalyzed exchange and isomerization reactions. I. Exchange of enol acetates with acetic acid catalyzed by palladium(II) chloride
1971
Oxidation of Olefins by Palladium(II). 15.1 Oxidation of (R)-(−)-(Z)- and (R)-(+)-(E)-3-Penten-2-ol Using Several Nucleophiles To Give Chiral β-Substituted Ketones. A Method of Finding Modes of Palladation of Olefins Using Chirality Transfer
1997
Stereochemistry of phenylpalladation of cyclohexene
1972
Comment on “Mechanism and Kinetics of the Wacker Process: A Quantum Mechanical Approach”
2009
Oxidation of olefins by palladium(II). VI. Ethylene oxidation by palladium(II) acetate in acetic acid promoted by various oxidants
1973
High-resolution imaging x-ray detector
1976
Fractionation of polyethylene
1959
Conversion of cyclo-octa-1,5-diene into 2,6-diacetoxybicyclo[3,3,0]octane by palladium(II ) chloride–lead tetra-acetate in acetic acid; X-ray determination of the structure of the product
1974
Some observations on the Pd(II)-catalysed ferrocenylation of acrylonitrile
1982 StandoutNobel
Oxidation of olefins by palladium(II). 18. Effect of reaction conditions, substrate structure and chiral ligand on the bimetallic palladium(II) catalyzed asymmetric chlorohydrin synthesis
2002
Palladium(II)-catalyzed exchange and isomerization reactions. III. Allylic esters isomerization in acetic acid catalyzed by palladium(II) chloride
1972
Kinetics of the Oxidation of Ethylene by Aqueous Palladium(II) Chloride
1964
Oxidation of Olefins by Palladium(II). 16. A New Palladium(II)-Catalyzed Asymmetric Chlorohydrin Synthesis
1998
Deuterium isotope effects in the palladium(II) and thallium(III) oxidation of ethylene
1973
Palladium(II)-catalyzed exchange and isomerization reactions. 15. Kinetics and stereochemistry of the isomerization of 2-(methyl-d3)-4-methyl-1,1,1,5,5,5-hexafluoro-3-penten-2-ol in aqueous solution catalyzed by PdCl42- at high chloride concentrations
1992
Mixed-valence ions of ruthenium containing fumaronitrile and tetracyanoethylene as bridging groups
1983
New Palladium(II)-Catalyzed Asymmetric 1,2-Dibromo Synthesis
2003
Palladium(II)-catalyzed exchange and isomerization reactions. IV. Exchange of vinylic chloride with radioactive lithium chloride catalyzed by palladium(II) chloride in acetic acid
1972
Palladium(II) catalyzed carbonylation of ketones
2000
Oxidation of olefins by palladium(II). 9. Mechanism of the oxidation of olefins by the dimeric species, disodium dipalladium hexaacetate, in acetic acid
1976
Oxidation of Olefins by Palladium(II). II. Effect of Structure on Rate in Aqueous Solution1
1966
A new synthesis of carboxylic acids by a Pd(II)-catalyzed carbon monoxide insertion
1968
Stereochemistry of acetoxypalladation of cyclohexene
1971
Interaction of Palladium(II) Acetate with Sodium and Lithium Acetate in Acetic Acid
1974
Oxidation of Cuprous Chloride by Oxygen in Glacial Acetic Acid
1966
Oxidation of olefins by palladium(II). 13. Product distribution and kinetics of the oxidation of 2-cyclohexenol and 2-cyclohexenol-1-d by PdCl42- in aqueous solution
1992
Palladium (II)-Catalyzed Exchange and Isomerization Reactions. VII. Isomerization and Exchange of Enol Propionates in Acetic Acid Catalyzed by Palladium (II) Chloride
1972
Oxidation of olefins by palladium(II). V. Oxidation of cyclohexene by a combination of palladium(II) chloride and copper(II) chloride in acetic acid
1972
Heterogenized polymetallic catalysts: Part III11For part 2 see Zaw et al., J. Mol. Catal. A 101 (1995) 187.. Catalytic air oxidation of alcohols by Pd(II) complexed to a polyphenylene polymer containing β-di- and tri-ketone surface ligands
1997
Palladium(II)-catalyzed exchange and isomerization reactions. 12. Isomerization and water exchange of allyl alcohol in aqueous solution catalyzed by tetrachloropalladate(II)
1984
Palladium(II)-catalyzed exchange and isomerization reactions. 14. Kinetics and stereochemistry of the isomerization and water exchange of 2-(methyl-d3)-4-methyl-1,1,1,5,5,5-hexafluoro-3-penten-2-ol in aqueous solution catalyzed by PdCl42-. Two new mechanistic probes for catalytic chemistry
1991
A novel palladium(II) catalysed allylic isomerization
1971
Palladium(II)-Catalyzed Exchange and Isomerization Reactions. 17. Exchange of Chiral Allyl Alcohols with Hydroxide, Methoxide, and Phenyl at High [Cl-]. Stereochemistry of the Wacker Reaction
1999
Zum Mechanismus der Wacker‐Reaktion: zwei Hydroxypalladierungen!
2009
Oxidation of olefins by palladium(II). 10. Products of the reaction of tetrachloropalladate(II) with allyl alcohol in aqueous solution
1985
Evidence for the rate determining step in the wacker reaction
1982
Palladium(II)-catalyzed exchange and isomerization reactions. 13. Palladium(II) chloride catalyzed exchange and isomerization of 2-(methyl-d3)-4-methyl-3-penten-2-ol and its ethyl ether in methanol
1991
Oxidation of olefins by palladium(II). Part XIV11For Part XIII see ref. [1].. Product distribution and kinetics of the oxidation of ethene by PdCl3 (pyridine)− in aqueous solution in the presence and absence of CuCl2: a modified Wacker catalyst with altered reactivity
1995
An air oxidizable bimetallic palladium(II) catalyst for asymmetric allylic oxidation of olefins in acetic acid
2002
A New Palladium(II)-Catalyzed Asymmetric Chlorohydrin Synthesis
1998
Palladium(II)-catalyzed exchange and isomerization reactions
1973
Palladium(II)-Catalyzed Oxidation of Aldehydes and Ketones. 1. Carbonylation of Ketones with Carbon Monoxide Catalyzed by Palladium(II) Chloride in Methanol
2000
π-Complex equilibria between ethylene and PdCl42− in aqueous solution
1979
Oxidation of olefins by palladium(II). 12. Product distributions and kinetics of the oxidation of 3-buten-2-ol and 2-buten-1-ol by tetrachloropalladate (PdCl42-) in aqueous solution
1990
Oxidation of olefins by palladium(II). IV. Effect of palladium(II) chloride concentration on rate in aqueous solution
1972
Palladium(II)-catalyzed exchange and isomerization reactions. X. Acid-catalyzed exchange of 2-cyclohexen-1-yl esters with acetic acid
1973
Palladium(II)-catalyzed exchange and isomerization reactions. XVI11For Part XV see Ref. [9]. The kinetics and stereochemistry of the oxidation and isomerization of hexafluoro allylic alcohols in aqueous solution catalyzed by PdCl3(pyridine)−
1996
MECHANISMS OF PALLADIUM(II)‐CATALYZED REACTIONS*,†
1971