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Citing Papers
Bifluoride Ion Mediated SuFEx Trifluoromethylation of Sulfonyl Fluorides and Iminosulfur Oxydifluorides
2019 StandoutNobel
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2012
Three‐component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts
2012
Acid-mediated formation of trifluoromethyl sulfonates from sulfonic acids and a hypervalent iodine trifluoromethylating agent
2009
Zinc‐Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents
2009
Ethynyl Benziodoxolones for the Direct Alkynylation of Heterocycles: Structural Requirement, Improved Procedure for Pyrroles, and Insights into the Mechanism
2012
Iron‐Catalyzed Cyclopropanation with Trifluoroethylamine Hydrochloride and Olefins in Aqueous Media: In Situ Generation of Trifluoromethyl Diazomethane
2009
Highly Selective Trifluoromethylation of 1,3‐Disubstituted Arenes through Iridium‐Catalyzed Arene Borylation
2011
Iron-catalyzed trifluoromethylation with concomitant C–C bond formation via 1,2-migration of an aryl group
2013
Visible-light-induced synthesis of a variety of trifluoromethylated alkenes from potassium vinyltrifluoroborates by photoredox catalysis
2013
Ethynyl‐1,2‐benziodoxol‐3(1 H)‐one (EBX): An Exceptional Reagent for the Ethynylation of Keto, Cyano, and Nitro Esters
2010
Intermolecular hydroamination of oxygen-substituted allenes. New routes for the synthesis of N,O-chelated zirconium and titanium amido complexes
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Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation
2010
Asymmetric synthesis of α-amino acids via homologation of Ni(II) complexes of glycine Schiff bases. Part 2: Aldol, Mannich addition reactions, deracemization and (S) to (R) interconversion of α-amino acids
2013
An Efficient Palladium‐Catalyzed CH Alkoxylation of Unactivated Methylene and Methyl Groups with Cyclic Hypervalent Iodine (I3+) Oxidants
2013
Metal‐Free Aryltrifluoromethylation of Activated Alkenes
2013
Copper‐Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur
2012
Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides
2012
General and Practical Formation of Thiocyanates from Thiols
2014
Catalysis for fluorination and trifluoromethylation
2011 StandoutNature
[Ind2TiMe2]: A Catalyst for the Hydroaminomethylation of Alkenes and Styrenes
2010
Introduction of Fluorine and Fluorine‐Containing Functional Groups
2013 Standout
Direct Alkynylation of Indole and Pyrrole Heterocycles
2009
Asymmetric Brønsted Acid Catalyzed Synthesis of Triarylmethanes—Construction of Communesin and Spiroindoline Scaffolds
2015
Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective
2010
Pd‐Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions
2011
Trifluoromethylation of Allylsilanes under Copper Catalysis
2012
6‐Trifluoromethyl‐Phenanthridines through Radical Trifluoromethylation of Isonitriles
2013
Copper‐Catalyzed Trifluoromethylation of N,N‐Dialkylhydrazones
2013
Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper‐Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes
2013
In Situ Generation of PhI+CF3 and Transition‐Metal‐Free Oxidative sp2 CH Trifluoromethylation
2013
Trifluoromethylation Reactions for the Synthesis of β‐Trifluoromethylamines
2013
Copper‐Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: A Simple Approach to Allylic Trifluoromethylation
2012
Copper‐Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts
2011
Copper‐Catalyzed Trifluoromethylation of Aryl Iodides with Potassium (Trifluoromethyl)trimethoxyborate
2011
Enzymatic assembly of carbon–carbon bonds via iron-catalysed sp3 C–H functionalization
2018 StandoutNatureNobel
Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α‐Trifluoromethyl Carbonyl Compounds
2011
Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp3)H Activation
2010
Photochemical Perfluoroalkylation with Pyridine N -Oxides: Mechanistic Insights and Performance on a Kilogram Scale
2016
Genetically programmed chiral organoborane synthesis
2017 StandoutNatureNobel
Copper-mediated C–H trifluoromethylation of quinones
2013
Iron(II)‐Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates
2012
A “Renaissance” in Radical Trifluoromethylation
2012
Reaction of a P/Al‐Based Frustrated Lewis Pair with Ammonia, Borane, and Amine–Boranes: Adduct Formation and Catalytic Dehydrogenation
2013
Direct Electrophilic N‐Trifluoromethylation of Azoles by a Hypervalent Iodine Reagent
2012
Oxidative Trifluoromethylthiolations of Aryl Boronic Acids Using a Copper/O2‐Based Protocol
2012
Synergistic catalysis: A powerful synthetic strategy for new reaction development
2012
Trifluoromethyl ethers – synthesis and properties of an unusual substituent
2008
2′‐SCF3 Uridine—A Powerful Label for Probing Structure and Function of RNA by 19F NMR Spectroscopy
2012
Copper‐Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols
2013
Synthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3H-1λ3,2-benziodaoxol-3-one
2014
Alkene Trifluoromethylation Coupled with CC Bond Formation: Construction of Trifluoromethylated Carbocycles and Heterocycles
2013
Copper-catalyzed synthesis of trifluoromethyl-substituted isoxazolines
2013
Copper‐Catalyzed Trifluoromethylation–Cyclization of Enynes: Highly Regioselective Construction of Trifluoromethylated Carbocycles and Heterocycles
2013
Fluoroform‐Derived CuCF3 for Low‐Cost, Simple, Efficient, and Safe Trifluoromethylation of Aryl Boronic Acids in Air
2012
Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes
2011
CuCl-catalyzed ortho trifluoromethylation of arenes and heteroarenes with a pivalamido directing group
2013
Copper‐Catalyzed Trifluoromethylation of Allylsilanes
2012
Recent Advances in Trifluoromethylation Reactions with Electrophilic Trifluoromethylating Reagents
2014
Copper‐Catalyzed Trifluoromethylation of Unactivated Olefins
2011
Probing the interactions of an acyl carrier protein domain from the 6‐deoxyerythronolide B synthase
2011
Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions
2010
A 2,6‐Bis(phenylamino)pyridinato Titanium Catalyst for the Highly Regioselective Hydroaminoalkylation of Styrenes and 1,3‐Butadienes
2014
Rapid Trifluoromethylation and Perfluoroalkylation of Five‐Membered Heterocycles by Photoredox Catalysis in Continuous Flow
2014
Catalytic Asymmetric Synthesis of Phosphine Boronates
2015 StandoutNobel
P‐Stereogenic Trifluoromethyl Derivatives of Josiphos: Synthesis, Coordination Properties, and Applications in Asymmetric Catalysis
2011
Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride
2013
Stereospecific Couplings of Secondary and Tertiary Boronic Esters
2014
Transition‐Metal‐Free Trifluoromethylaminoxylation of Alkenes
2012
Efficient Copper‐Catalyzed Direct Intramolecular Aminotrifluoromethylation of Unactivated Alkenes with Diverse Nitrogen‐Based Nucleophiles
2013
Aminopyridinato Titanium Catalysts for the Hydroaminoalkylation of Alkenes and Styrenes
2012
Trifluoromethoxylation of Arenes: Synthesis of ortho‐Trifluoromethoxylated Aniline Derivatives by OCF3 Migration
2014
Difluoro‐ and Trifluoromethylation of Electron‐Deficient Alkenes in an Electrochemical Microreactor
2013
Selective difluoromethylation and monofluoromethylation reactions
2009
Visible‐Light‐Induced Trifluoromethylation of N‐Aryl Acrylamides: A Convenient and Effective Method To Synthesize CF3‐Containing Oxindoles Bearing a Quaternary Carbon Center
2013
Copper‐Catalyzed Trifluoromethylation‐Initiated Radical 1,2‐Aryl Migration in α,α‐Diaryl Allylic Alcohols
2013
Frustrated Lewis Pair Chemistry: Development and Perspectives
2015 Standout
Copper‐Catalyzed Cyclic Oxytrifluoromethylation of 2,3‐Allenoic Acids to Trifluoromethylated Butenolides
2013
Catalytic Hydroaminoalkylation
2009
Trifluoromethylation of Alkenes with Concomitant Introduction of Additional Functional Groups
2014
PhI(OAc)2‐Mediated Radical Trifluoromethylation of Vinyl Azides with Me3SiCF3
2013
The Mechanism of the Titanium‐Catalyzed Hydroaminoalkylation of Alkenes
2011
Recent Developments on the Trifluoromethylation of (Hetero)Arenes
2012
trans Influences on Hypervalent Bonding of Aryl λ3‐Iodanes: Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones
2006
Room temperature decarboxylative trifluoromethylation of α,β-unsaturated carboxylic acids by photoredox catalysis
2013
Copper-Mediated α-Trifluoromethylation of N-Phenylcinnamamides Coupled with Dearomatization: Access to Trifluoromethylated 1-Azaspiro[4.5]decanes
2014
Halogens and noble gases
2007
Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage
2012
Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur
2012
Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters
2012
Copper‐Catalyzed Trifluoromethylation of Unactivated Olefins
2011
Iron Catalysis in Organic Synthesis
2015 Standout
Highly Selective Trifluoromethylation of 1,3‐Disubstituted Arenes through Iridium‐Catalyzed Arene Borylation
2011
Mechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation
2011
Aminotrifluoromethylation of Olefins via Cyclic Amine Formation: Mechanistic Study and Application to Synthesis of Trifluoromethylated Pyrrolidines
2015
3d Transition Metals for C–H Activation
2018 Standout
The Golden Age of Transfer Hydrogenation
2015 Standout
Metal-Free sp2-C–H Borylation as a Common Reactivity Pattern of Frustrated 2-Aminophenylboranes
2016
Strategies for nucleophilic, electrophilic, and radical trifluoromethylations
2007
Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)
2013 Standout
(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed Direct Trifluoromethylthiolation of Arenes via C−H Activation
2017
Enantioselective α-Arylation of Aldehydes via the Productive Merger of Iodonium Salts and Organocatalysis
2011
Copper-Catalyzed Regioselective Trifluoromethylthiolation of Pyrroles by Trifluoromethanesulfonyl Hypervalent Iodonium Ylide
2015
Catalytic enantioselective synthesis of chiral tetraarylmethanes
2020
Die Reaktionen eines P/Al‐basierten frustrierten Lewis‐Paars mit Ammoniak, Boran und Aminboranen: Adduktbildung und katalytische Wasserstoffeliminierung
2013
Polyvalent perfluoroorgano- and selected polyfluoroorgano-halogen(III and V) compounds
2008
Synthesis of a Range of Iodine(III) Compounds Directly from Iodoarenes
2011
N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions
2015
Direct Access to α-Trifluoromethyl Enones via Efficient Copper-Catalyzed Trifluoromethylation of Meyer–Schuster Rearrangement
2014
Chemistry of Polyvalent Iodine
2008 Standout
The Phosphinoboration Reaction
2014
Reactivity of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With Phenols
2008
Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes
2015
Copper-promoted direct C–H alkoxylation of S,S-functionalized internal olefins with alcohols
2017
2-Pyridonate Titanium Complexes for Chemoselectivity. Accessing Intramolecular Hydroaminoalkylation over Hydroamination
2013
Organic Photoredox Catalysis
2016 Standout
Synthesis and Reactions of 2‐[1‐Methyl‐1‐(pyrrolidin‐2‐yl)ethyl]‐1H‐pyrrole and Some Derivatives with Aldehydes: Chiral Structures Combining a Secondary‐Amine Group with an 1H‐Pyrrole Moiety as Excellent H‐Bond Donor
2012
Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides
2012
NMR‐Solution Structures and Affinities for the Human Somatostatin G‐Protein‐Coupled Receptors hsst1–5 of CF3 Derivatives of Sandostatin® (Octreotide)
2009
Direct trifluoro-methoxylation of aromatics with perfluoro-methyl-hypofluorite
2012
Synthesis of α-CF3-Substituted Carbonyl Compounds with Relative and Absolute Stereocontrol Using Electrophilic CF3-Transfer Reagents
2011
Copper-Catalyzed Intermolecular Chloro- and Bromotrifluoromethylation of Alkenes
2016
Reactivity of a Hypervalent Iodine Trifluoromethylating Reagent toward THF: Ring Opening and Formation of Trifluoromethyl Ethers
2010
Copper-Catalyzed Direct C–H Trifluoromethylation of Quinones
2013
The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes
2010
Strong and Confined Acids Catalyze Asymmetric Intramolecular Hydroarylations of Unactivated Olefins with Indoles
2021 StandoutNobel
Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis
2009
The Hitchhiker’s Guide to Flow Chemistry
2017 Standout
Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent
2011
An Unexpected α‐Oxidation of Cyclic Ketones with 1,4‐Benzoquinone by Enol Catalysis
2018 StandoutNobel
Copper‐Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts
2011
Pd-Catalyzed Intramolecular Oxyalkynylation of Alkenes with Hypervalent Iodine
2009
Evidence for the Existence of Terminal Scandium Imidos: Mechanistic Studies Involving Imido–Scandium Bond Formation and C–H Activation Reactions
2012
Direct C2-trifluoromethylation of indole derivatives catalyzed by copper acetate
2010
Copper-Catalyzed Three-Component Cyanotrifluoromethylation/Azidotrifluoromethylation and Carbocyclization of 1,6-Enynes
2014
One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation
2013
Recent advances in the trifluoromethylation methodology and new CF3-containing drugs
2014
An Aminopyridinato Titanium Catalyst for the Intramolecular Hydroaminoalkylation of Secondary Aminoalkenes
2015
Enantioselective Iron-Catalyzed Azidation of β-Keto Esters and Oxindoles
2013
One-Pot Anti-Markovnikov Hydroamination of Unactivated Alkenes by Hydrozirconation and Amination
2013
Electrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagents
2010
Room-temperature base-free copper-catalyzed trifluoromethylation of organotrifluoroborates to trifluoromethylarenes
2012
Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas
2016 Standout
Synthesis of α-Trifluoromethyl Ketones via the Cu-Catalyzed Trifluoromethylation of Silyl Enol Ethers Using an Electrophilic Trifluoromethylating Agent
2014
Direkte elektrophile N‐Trifluormethylierung von Azolen mit einem hypervalenten Iodreagens
2012
Ruthenium-Catalyzed C–C Coupling of Amino Alcohols with Dienes via Transfer Hydrogenation: Redox-Triggered Imine Addition and Related Hydroaminoalkylations
2015
Recent Progress in Visible-Light Photoredox-Catalyzed Intermolecular 1,2-Difunctionalization of Double Bonds via an ATRA-Type Mechanism
2016
Rapid Trifluoromethylation of Indole Derivatives
2012
Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope
2011 Standout
Visible-light radical reaction designed by Ru- and Ir-based photoredox catalysis
2014
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α‐Trifluoromethyl Carbonyl Compounds
2011
Copper‐Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur
2012
Palladium-Catalyzed Transformations of Alkyl C–H Bonds
2016 Standout
Catalytic C–H α-Trifluoromethylation of α,β-Unsaturated Carbonyl Compounds
2014
Visible Light-Induced Trifluoromethylation and Perfluoroalkylation of Cysteine Residues in Batch and Continuous Flow
2016
Tetrabenzyltitanium: An Improved Catalyst for the Activation of sp3 CH Bonds Adjacent to Nitrogen Atoms
2009
CF3 Oxonium Salts, O-(Trifluoromethyl)dibenzofuranium Salts: In Situ Synthesis, Properties, and Application as a Real CF3+ Species Reagent
2007
Stereospezifische Kupplungen von sekundären und tertiären Boronsäureestern
2014
Copper(i)-catalyzed diastereoselective hydroxytrifluoromethylation of dienes accelerated by phosphine ligands
2013
Electrophilic Trifluoromethylation of Primary Phosphines: Synthesis of a P-Bis(trifluoromethyl) Derivative of BINAP
2010
Assessment of heat-sensitive thiophosphate protecting groups in the development of thermolytic DNA oligonucleotide prodrugs
2009
[(acridine)BCl2]+: A Borenium Cation That Is a Strong Boron- and Carbon-Based Lewis Acid
2013
Pd‐Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions
2011
Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines
2016
Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates
2014 StandoutNobel
Advances in the Chemistry of Tetrahydroquinolines
2011 Standout
Enantioselective Organocatalytic Synthesis of Fluorinated Molecules
2011
Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations
2009
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes
2012
Highly selective catalytic trans-hydroboration of alkynes mediated by borenium cations and B(C6F5)3
2016
Copper-catalyzed trifluoromethylation of arylsulfinate salts using an electrophilic trifluoromethylation reagent
2013
Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides
2010
Palladium-Catalyzed C–H Perfluoroalkylation of Arenes
2011
Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents
2014 Standout
Ni(ii )–salt catalyzed activation of primary amine-sp3Cα–H and cyclization with 1,2-diketone to tetrasubstituted imidazoles
2013
New hypervalent iodine reagents for electrophilic trifluoromethylation and their precursors: synthesis, structure, and reactivity
2010
Axially Chiral 1,1'‐Binaphthyl‐2‐Carboxylic Acid (BINA‐Cox) as Ligands for Titanium‐Catalyzed Asymmetric Hydroalkoxylation
2020
Oxytrifluoromethylation of multiple bonds using copper catalyst under mild conditions
2012
Asymmetrische Brønsted‐Säure‐katalysierte Synthese von Triarylmethanen – Aufbau von Communesin‐ und Spiroindolin‐Gerüsten
2015
Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions
2014
Metal-Free Direct 1,6- and 1,2-Difunctionalization Triggered by Radical Trifluoromethylation of Alkenes
2015
Enantioselective electrophilic trifluoromethylation of β-keto esters with Umemoto reagents induced by chiral nonracemic guanidines
2009
Transition-Metal-Catalyzed C–H Alkylation Using Alkenes
2017
Fluorinated Johnson Reagent for Transfer‐Trifluoromethylation to Carbon Nucleophiles
2008
The broadening reach of frustrated Lewis pair chemistry
2016 StandoutScience
Organocatalyzed Regio- and Enantioselective Allylic Trifluoromethylation of Morita–Baylis–Hillman Adducts Using Ruppert–Prakash Reagent
2011
O‐Trifluoromethylation of N,N‐Disubstituted Hydroxylamines with Hypervalent Iodine Reagents
2014
Zinc‐Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents
2009
Titanium‐Catalyzed Intermolecular Hydroaminoalkylation of Conjugated Dienes
2013
Recent advances in enantioselective trifluoromethylation reactions
2008
Cu-Mediated Chemoselective Trifluoromethylation of Benzyl Bromides Using Shelf-Stable Electrophilic Trifluoromethylating Reagents
2011
Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance
2017 Standout
Intermolecular hydroaminoalkylation of alkenes and dienes using a titanium mono(formamidinate) catalyst
2015
Structural Reevaluation of the Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation Supported by the Crystalline Sponge Method for X‐ray Analysis
2014
Three‐component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts
2012
Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions
2014
Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization
2012 Standout
Fluoroalkyl-containing phosphines
2012
Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation
2011
A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis
2015
Copper-catalyzed olefinic trifluoromethylation of enamides at room temperature
2012
Mechanistic Insights into Scandium-Catalyzed Hydroaminoalkylation of Olefins with Amines: Origin of Regioselectivity and Charge-Based Prediction Model
2017
Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes
2013
2-Trifluoromethylated Indoles via Radical Trifluoromethylation of Isonitriles
2014
Dual Catalysis Strategies in Photochemical Synthesis
2016 Standout
Scandium-catalyzed C(sp3)–H alkylation of N,N-dimethyl anilines with alkenes
2017
Electrophilic S‐Trifluoromethylation of Cysteine Side Chains in α‐ and β‐Peptides: Isolation of Trifluoro‐methylated Sandostatin® (Octreotide) Derivatives
2008
Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters
2013
Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation
2011
Advances in Synthetic Applications of Hypervalent Iodine Compounds
2016 Standout
New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines
2009
Planar‐Chiral [2.2]Paracyclophane‐Based Amides as Proligands for Titanium‐ and Zirconium‐Catalyzed Hydroamination
2017
Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds
2016
Cyclization Cascades viaN-Amidyl Radicals toward Highly Functionalized Heterocyclic Scaffolds
2015
Conversion of Carbon–Fluorine Bonds α to Transition Metal Centers to Carbon–Hydrogen, Carbon–Carbon, and Carbon–Heteroatom Bonds
2009
One‐Pot Procedure for the Synthesis of 1,5‐Benzodiazepines from N‐Allyl‐2‐bromoanilines
2016
Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond
2014
Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design
2021 StandoutNobel
Aromatic Trifluoromethylation with Metal Complexes
2011 Standout
Benchmark and Solvent‐Free Preparation of Sulfonium Salt Based Electrophilic Trifluoromethylating Reagents
2009
The Halogen Bond
2016 Standout
Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates
2014 Standout
Catalytic Asymmetric Intramolecular [4+2] Cycloaddition of In Situ Generated ortho‐Quinone Methides
2017 StandoutNobel
Enantioselective organocatalysis using SOMO activation
2016
Mild copper-catalyzed trifluoromethylation of terminal alkynes using an electrophilic trifluoromethylating reagent
2012
Electrophilic Trifluoromethylation of S-Hydrogen Phosphorothioates
2011
The Phosphinoboration Reaction
2014
Einführung von Fluor und fluorhaltigen funktionellen Gruppen
2013
Catalytic Enantioselective Transformations Involving C–H Bond Cleavage by Transition-Metal Complexes
2017
α-Arylation of Saturated Azacycles and N-Methylamines via Palladium(II)-Catalyzed C(sp3)–H Coupling
2015
Copper‐Catalyzed Trifluoromethylation of Allylsilanes
2012
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Preparation and X-ray Crystal Study of Benziodoxaborole Derivatives: New Hypervalent Iodine Heterocycles
2011
P‐Stereogenic Ferrocene‐Based (Trifluoromethyl)phosphanes: Synthesis, Structure, Coordination Properties and Catalysis
2010
Frustrated Lewis Pairs
2015 Standout
Stereoselective Radical Azidooxygenation of Alkenes
2013
Visible‐Light Photocatalysis: Does It Make a Difference in Organic Synthesis?
2018 Standout
Chiral Brønsted acid-catalyzed Friedel–Crafts alkylation of electron-rich arenes with in situ-generated ortho-quinone methides: highly enantioselective synthesis of diarylindolylmethanes and triarylmethanes
2014
Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications
2017 Standout
Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)–CF2SO2Ph reagent
2008
Fluoroform‐Derived CuCF3 for Low‐Cost, Simple, Efficient, and Safe Trifluoromethylation of Aryl Boronic Acids in Air
2012
Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions
2008
Copper‐Promoted Trifluoromethylation of Primary and Secondary Alkylboronic Acids
2012
Solar Synthesis: Prospects in Visible Light Photocatalysis
2014 StandoutScience
Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications
2016 Standout
2-Aminopyridinate Titanium Complexes for the Catalytic Hydroamination of Primary Aminoalkenes
2013
Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines
2015
Amide Groups Switch Selectivity: C–H Trifluoromethylation of α,β-Unsaturated Amides and Subsequent Asymmetric Transformation
2014
The New Age of Electrophilic Perfluoroalkylation Reactions
2012
Concise synthesis of oxindole derivatives bearing a 3-trifluoroethyl group: Copper-catalyzed trifluoromethylation of acryloanilides
2013
Notification about the Explosive Properties of Togni’s Reagent II and One of Its Precursors
2013
Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex
2010
Reducing CO2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism of Phosphine–Borane-Mediated Hydroboration of CO2
2014
The direct electrophilic cyanation of β-keto esters and amides with cyano benziodoxole
2014
Übergangsmetallfreie Trifluormethylaminoxylierung von Alkenen
2012
Iron(II)‐Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates
2012
Radical trifluoromethylation of ammonium enolates
2007
Chemo-, Regio-, and Stereoselective Trifluoromethylation of Styrenes via Visible Light-Driven Single-Electron Transfer (SET) and Triplet–Triplet Energy Transfer (TTET) Processes
2014
Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents
2012
Metal–Organic Frameworks for Heterogeneous Basic Catalysis
2017 Standout
Lithiation–Borylation Methodology and Its Application in Synthesis
2014
Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/Desulfonylation and C(sp2)–N Bond Formation of Conjugated Tosyl Amides
2013
Thieme Chemistry Journals Awardees – Where Are They Now? Titanium-Catalyzed Hydroaminoalkylation of Vinylsilanes and a One-Pot Procedure for the Synthesis of 1,4-Benzoazasilines
2017
Dimethylamine as a Substrate in Hydroaminoalkylation Reactions
2017
A mild and fast photocatalytic trifluoromethylation of thiols in batch and continuous-flow
2014
Mild Silver‐Mediated Geminal Difluorination of Styrenes Using an Air‐ and Moisture‐Stable Fluoroiodane Reagent
2014
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
2011 Standout
Works of Patrick Eisenberger being referenced
Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene‐Stabilized Borenium Catalysts
2015
Tantalum–Amidate Complexes for the Hydroaminoalkylation of Secondary Amines: Enhanced Substrate Scope and Enantioselective Chiral Amine Synthesis
2009
Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents
2008
Mild Electrophilic Trifluoromethylation of Carbon‐ and Sulfur‐Centered Nucleophiles by a Hypervalent Iodine(III)–CF3 Reagent
2006
Novel 10‐I‐3 Hypervalent Iodine‐Based Compounds for Electrophilic Trifluoromethylation
2006
Recent Advances in Electrophilic CF3-Transfer Using Hypervalent Iodine(III) Reagents
2008
Synthesis of Enantiomerically Enriched Triarylmethanes by Enantiospecific Suzuki–Miyaura Cross-Coupling Reactions
2014
Chiral carbene–borane adducts: precursors for borenium catalysts for asymmetric FLP hydrogenations
2016
ChemInform Abstract: Mild Electrophilic Trifluoromethylation of Secondary and Primary Aryl‐ and Alkylphosphines Using Hypervalent Iodine(III)—CF3 Reagents.
2008
Selective C−H Activation α to Primary Amines. Bridging Metallaaziridines for Catalytic, Intramolecular α-Alkylation
2009
Mild Electrophilic Trifluoromethylation of Carbon‐ and Sulfur‐Centered Nucleophiles by a Hypervalent Iodine(III)–CF3 Reagent
2006
Tantalum–Amidate Complexes for the Hydroaminoalkylation of Secondary Amines: Enhanced Substrate Scope and Enantioselective Chiral Amine Synthesis
2009
Taking the F out of FLP: Simple Lewis Acid–Base Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis
2012
Tantalum Catalyzed Hydroaminoalkylation for the Synthesis of α- and β-Substituted N-Heterocycles
2013
Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions
2010
Amidate Complexes of Tantalum and Niobium for the Hydroaminoalkylation of Unactivated Alkenes
2017