Citation Impact
Citing Papers
Synthesis of PdII complexes bearing an enantiomerically resolved seven-membered N-heterocyclic carbene ligand and initial studies of their use in asymmetric Wacker-type oxidative cyclization reactions
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Synthesis of Stable Isothiazole Carbenes
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A stable crystalline N-heterocyclic carbene with a 1,1′-ferrocenediyl backbone
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Recently Reported Crystalline Isothiazole Carbenes: Myth or Reality
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Readily Available Onio‐Substituted Methyleneiminium Salts: Single Precursors for a Variety of Aminocarbenes
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Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
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pKas of the conjugate acids of N-heterocyclic carbenes in water
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Stoichiometric and catalytic reactivity of the N-heterocyclic carbene ruthenium hydride complexes [Ru(NHC)(L)(CO)HCl] and [Ru(NHC)(L)(CO)H(η2-BH4)] (L = NHC, PPh3)
2008
A Diaminocarbene–Phosphonium Ylide: Direct Access to C,C Chelating Ligands
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An overview of N-heterocyclic carbenes
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Quantifying and understanding the electronic properties of N-heterocyclic carbenes
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Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes
2009
A Rigid Cyclic (Alkyl)(amino)carbene Ligand Leads to Isolation of Low‐Coordinate Transition‐Metal Complexes
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One‐Pot Synthesis of Polyheterocycles by a Palladium‐Catalyzed Intramolecular N‐Arylation/CH Activation/Aryl–Aryl Bond‐Forming Domino Process
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General Catalysts for the Suzuki–Miyaura and Sonogashira Coupling Reactions of Aryl Chlorides and for the Coupling of Challenging Substrate Combinations in Water
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Heterocyclic Carbenes: Synthesis and Coordination Chemistry
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Development of 7-membered N-heterocyclic carbene ligands for transition metals
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Triazole-Based Monophosphines for Suzuki−Miyaura Coupling and Amination Reactions of Aryl Chlorides
2005
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
2008
A Mild and Versatile Method for Palladium‐Catalyzed Cross‐Coupling of Aryl Halides in Water and Surfactants
2003
Proton Affinities of N-Heterocyclic Carbene Super Bases
2005
Triazole-Based Monophosphine Ligands for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Chlorides
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Ein homoleptischer Carben-Lithium-Komplex
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Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis
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Nickel(0) Complexes of N-Alkyl-Substituted N-Heterocyclic Carbenes and Their Use in the Catalytic Carbon−Carbon Bond Activation of Biphenylene
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Chemistry of Polyvalent Iodine
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Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes
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Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities
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A straight forward in situ preparation of NHC-substituted phosphapalladacycles
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Six‐Membered N‐Heterocyclic Carbenes with a 1,1′‐Ferrocenediyl Backbone: Bulky Ligands with Strong Electron‐Donor Capacity and Unusual Non‐Innocent Character
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Dinitroxidcarbene, eine neue Klasse selbstumpolungsfähiger Carbene: Herstellung in Lösung und Stabilisierung in Übergangsmetallkomplexen
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Persistent Triplet Carbenes
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13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II)
2009
Rapid Screening of New Polymer‐Supported Palladium (II ) Bis(3,4,5,6‐tetrahydropyrimidin‐2‐ylidenes)
2004
A highly active palladium-phosphoramidite catalyst for the Suzuki cross-coupling of aryl bromides
2005
Nucleophilic carbenes and the wanzlick equilibrium: A reinvestigation
1999
Carbene Ligands in Surface Chemistry: From Stabilization of Discrete Elemental Allotropes to Modification of Nanoscale and Bulk Substrates
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Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
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The Potential of Palladacycles: More Than Just Precatalysts
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Heterocyclische Carbene
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State of the Art and Prospects in Metal–Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis
2019 Standout
Carbon−Carbon Coupling Reactions Catalyzed by Heterogeneous Palladium Catalysts
2006 Standout
Catalytic iron-carbene intermediate revealed in a cytochrome c carbene transferase
2018 StandoutNobel
Stable Carbenes
1999 Standout
C−H Activation for the Construction of C−B Bonds
2009 Standout
Imidazolylidenes, imidazolinylidenes and imidazolidines
1999 Standout
PdII Complexes Possessing a Seven‐Membered N‐Heterocyclic Carbene Ligand
2005
Basicity of Nucleophilic Carbenes in Aqueous and Nonaqueous SolventsTheoretical Predictions
2004
Isolation of Cyclopropenylidene–Lithium Adducts: The Weiss–Yoshida Reagent
2006
Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners
2011 Standout
Design of Sterically Demanding, Electron-Rich Carbene Ligands with the Perimidine Scaffold
2007
Scope and Limitations of Pd2(dba)3/P(i-BuNCH2CH2)3N-Catalyzed Buchwald−Hartwig Amination Reactions of Aryl Chlorides
2004
Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated with Phosphine and N-Heterocyclic Carbene Ligands
2003 StandoutNobel
The Sonogashira Reaction: A Booming Methodology in Synthetic Organic Chemistry
2007 Standout
Palladacyclic catalysts in C–C and C–heteroatom bond-forming reactions
2003
Nanoparticulate Palladium Supported by Covalently Modified Silicas: Synthesis, Characterization, and Application as Catalysts for the Suzuki Coupling of Aryl Halides
2005
Palladium(II) Pyrazolin-4-ylidenes: Remote N-Heterocyclic Carbene Complexes and Their Catalytic Application in Aqueous Suzuki−Miyaura Coupling
2007
Well-Defined N-Heterocyclic Carbenes−Palladium(II) Precatalysts for Cross-Coupling Reactions
2008
Imidazol(in)ium carboxylates as N-heterocyclic carbene ligand precursors for Suzuki–Miyaura reactions
2006
Betaine Adducts of N‐Heterocyclic Carbenes: Synthesis, Properties, and Reactivity
2009
Diaminocarbene[3]ferrocenophanes and Their Transition‐Metal Complexes
2008
A σ‐Donor with a Planar Six‐π‐Electron B2N2C2 Framework: Anionic N‐Heterocyclic Carbene or Heterocyclic Terphenyl Anion?
2006
Chiral NHC–metal-based asymmetric catalysis
2011
Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope
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Palladium Charcoal-Catalyzed Suzuki−Miyaura Coupling To Obtain Arylpyridines and Arylquinolines
2003
Aus der Sicht des Synthetikers: Palladiumkomplexe N‐heterocyclischer Carbene als Katalysatoren für Kreuzkupplungen
2007
SambVca: A Web Application for the Calculation of the Buried Volume of N‐Heterocyclic Carbene Ligands
2009
Palladium-Catalyzed Transformations of Alkyl C–H Bonds
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N-Heterocyclic Carbenes in Late Transition Metal Catalysis
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Stable four-π-electron, four-membered heterocyclic cations and carbenes
2006
The “Wanzlick Equilibrium”
2000
Selected Patented Cross-Coupling Reaction Technologies
2006 Standout
Reply to “Recently Reported Crystalline Isothiazole Carbenes: Myth or Reality”
2007
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation
2007 Standout
Recent Advances in Polyoxometalate-Catalyzed Reactions
2015 Standout
Beyond TPPTS: New Approaches to the Development of Efficient Palladium‐Catalyzed Aqueous‐Phase Cross‐Coupling Reactions
2006
Olefin Metathesis Catalyst: Stabilization Effect of Backbone Substitutions of N-Heterocyclic Carbene
2008 Nobel
Stable Aminooxy- and Aminothiocarbenes
1998
Synthesis and Catalytic Application of Chiral 1,1‘-Bi-2-naphthol- and Biphenanthrol-Based Pincer Complexes: Selective Allylation of Sulfonimines with Allyl Stannane and Allyl Trifluoroborate
2007
An evaluation of phosphine and carbene adducts of phosphite- and phosphinite-based palladacycles in the coupling of alkyl bromides with aryl boronic acids
2005
From Mono‐Triazolium Salt to Bis‐Triazolium Salt: Improvement of the Asymmetric Intermolecular Benzoin Condensation
2008
High‐Turnover Palladium Catalysts in Cross‐Coupling and Heck Chemistry: A Critical Overview
2004
Palladium(II) Complexes of a Sterically Bulky, Benzannulated N-Heterocyclic Carbene with Unusual Intramolecular C−H···Pd and Ccarbene···Br Interactions and Their Catalytic Activities
2006
First silver complexes of tetrahydropyrimid-2-ylidenes
2004
Dimerization mechanisms of heterocyclic carbenes
2004
Electron Delocalization in Acyclic andN-Heterocyclic Carbenes and Their Complexes: A Combined Experimental and Theoretical Charge-Density Study
2002
An ab initio study of the NMR properties (absolute shieldings and NICS) of a series of significant aromatic and antiaromatic compounds
2001
Synthesis and Structural Features of Rhodium Complexes of Expanded Ring N‐Heterocyclic Carbenes
2009
Synthesis and NHC Lability of d0 Lithium, Yttrium, Titanium, and Zirconium Amido Bis(N-heterocyclic carbene) Complexes
2007
A Diaminocarbene–Phosphonium Ylide: Direct Access to C,C Chelating Ligands
2007
Iron−Phosphine, −Phosphite, −Arsine, and −Carbene Catalysts for the Coupling of Primary and Secondary Alkyl Halides with Aryl Grignard Reagents
2005
Synthese stabiler Isothiazolcarbene
2007
Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance
2017 Standout
Stable Noncyclic Singlet Carbenes
2009
First Examples of Diazepanylidene Carbenes and Their Late-Transition-Metal Complexes
2007
Rhodium and iridium complexes of N-heterocyclic carbenes: Structural investigations and their catalytic properties in the borylation reaction
2006
Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization
2012 Standout
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
2015 Standout
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
2006 Science
Recently Reported Crystalline Isothiazole Carbenes: Myth or Reality
2007
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
2006 Standout
An N,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry
2009
Organic Reactions in Aqueous Media with a Focus on Carbon−Carbon Bond Formations: A Decade Update
2005 Standout
A Stable Four-Membered N-Heterocyclic Carbene
2004 StandoutNobel
Persistent (Amino)(Silyl)Carbenes
2005
An Assessment of Theoretical Protocols for Calculation of the pKa Values of the Prototype Imidazolium Cation
2004
Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands: A quest for understanding
2006
Controlled Ring-Opening Polymerization of Lactide and Glycolide
2004 Standout
Superoxide Ion: Generation and Chemical Implications
2016 Standout
Chemistry and Properties of Nanocrystals of Different Shapes
2005 Standout
One-Pot Electrosynthesis of Substituted Imidazolinium and Tetrahydropyrimidinium Salts from Secondary Alkyldiamines: An Electrochemical Route toward Ionic Liquids
2009
Catalysis in Ionic Liquids
2007 Standout
Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications
2009
Dissecting Alkynes: Full Cleavage of Polarized C≡C Moiety via Sequential Bis-Michael Addition/Retro-Mannich Cascade
2011
Heterocyclische Carbene – Synthese und Koordinationschemie
2008
Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
2016 Standout
Recent advances in enantioselective copper-catalyzed 1,4-addition
2009 StandoutNobel
Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts
2009 StandoutNobel
Synthetic and Structural Studies of Silver(I )‐ and Gold(I )‐ContainingN‐Heterocyclic Carbene Metallacrown Ethers
2005
Formation and Stability of N-Heterocyclic Carbenes in Water: The Carbon Acid pKaof Imidazolium Cations in Aqueous Solution
2004
A Stable Anionic N-Heterocyclic Carbene and Its Zwitterionic Complexes
2008
Reply to “Recently Reported Crystalline Isothiazole Carbenes: Myth or Reality”
2007
On the Organocatalytic Activity of N-Heterocyclic Carbenes: Role of Sulfur in Thiamine
2012
Recent Applications of Palladium‐Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries
2009
Nucleus-Independent Chemical Shifts (NICS) as an Aromaticity Criterion
2005 Standout
An Acidity Scale of 1,3-Dialkylimidazolium Salts in Dimethyl Sulfoxide Solution
2007
Proton Transfer Reactions of Triazol-3-ylidenes: Kinetic Acidities and Carbon Acid pKa Values for Twenty Triazolium Salts in Aqueous Solution
2012
The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
2000 StandoutNobel
Das „Wanzlick-Gleichgewicht“
2000
Steric and Electronic Effects in the Dimerization of Wanzlick Carbenes: The Alkyl Effect
2007
Direct C−H Transformation via Iron Catalysis
2010 Standout
Understanding the M (NHC) (NHC = N-heterocyclic carbene) bond
2008
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
2010 Standout
N-Heterocyclic Carbenes with Inorganic Backbones: Electronic Structures and Ligand Properties
2008
Cu-Catalyzed Azide−Alkyne Cycloaddition
2008 StandoutNobel
PEG-400 promoted Pd(OAc)2/DABCO-catalyzed cross-coupling reactions in aqueous media
2005
Stable non-N-heterocyclic carbenes (non-NHC): recent progress
2004
Thermodynamics of a Diaminocarbene−Tetraaminoethylene Equilibrium
1999
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
2009 Standout
Isolation of a C5-Deprotonated Imidazolium, a Crystalline “Abnormal” N-Heterocyclic Carbene
2009 Science
Carbenes: Synthesis, properties, and organometallic chemistry
2008
Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications
2014
Bonding capabilities of imidazol-2-ylidene ligands in group-10 transition-metal chemistry
2008
Stable Planar Six-π-Electron Six-Membered N-Heterocyclic Carbenes with Tunable Electronic Properties
2005
Tridentate Amido Carbene Ligands in Early-Transition-Metal Coordination Chemistry
2004
Contributions to the chemistry of carbenemetal chemistry
2005
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
Concerning the ‘Wanzlick equilibrium’
2000
Gold-Catalyzed Organic Transformations
2008 Standout
A Rigid Cyclic (Alkyl)(amino)carbene Ligand Leads to Isolation of Low‐Coordinate Transition‐Metal Complexes
2005
N-Heterocyclic carbenes: state of the art in transition-metal-complex synthesis
2000
Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives
2009
Suzuki–Miyaura and Related Cross‐Couplings in Aqueous Solvents Catalyzed by Di(2‐pyridyl)methylamine‐Palladium Dichloride Complexes
2004
A Metal−Organic Framework with Covalently Bound Organometallic Complexes
2010 StandoutNobel
A Reassessment of the Transition-Metal Free Suzuki-Type Coupling Methodology
2004
13C NMR Spectroscopy of “Arduengo-type” Carbenes and Their Derivatives
2009
Looking for Stable Carbenes: The Difficulty in Starting Anew
1999 Standout
The development of palladium catalysts for CC and Cheteroatom bond forming reactions of aryl chloride substrates
2004
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron‐Rich Ligands for Transition‐Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
2005
Enantioselective copper-catalyzed conjugate addition using chiral diaminocarbene ligands
2001
Carbene Complexes of Nonmetals
2004
Works of Michael E. Blake being referenced
N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes
2005
When and How Do Diaminocarbenes Dimerize?
2004
The Suzuki coupling of aryl chlorides in TBAB–water mixtures
2003
Chiral palladium bis(phosphite) PCP-pincer complexes via ligand C–H activation
2006
The first example of a doubly orthometallated aryl bis(phosphinite) ligand
2003
Mixed Phosphite‐Phosphine and Phosphinite‐Phosphine Palladacyclic Complexes as Highly Active Catalysts for the Amination of Aryl Chlorides
2003
Wann und wie dimerisieren Diaminocarbene?
2004
Diaminocarbenes; Calculation of Barriers to Rotation about Ccarbene−N Bonds, Barriers to Dimerization, Proton Affinities, and 13C NMR Shifts
1999
Preparation of tetraalkylformamidinium salts and related species as precursors to stable carbenes
2001
Bis(N-piperidyl)carbene and its slow dimerisation to tetrakis(N-piperidyl)ethene
1997
Complexation of stable carbenes with alkali metals
1999