Citation Impact
Citing Papers
Potassium t -Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes
2008
The Catalytic Cross-Coupling of Unactivated Arenes
2007 Science
Oxindole Synthesis by Direct Coupling of CH and CH Centers
2009
Iron-catalyzed aryl-aryl cross coupling route for the synthesis of 1-(2-amino)-phenyl)dibenzo[b,d]furan-2-ol derivatives and their biological evaluation
2013
Directed Amination of Non‐Acidic Arene CH Bonds by a Copper–Silver Catalytic System
2013
Solvent-free aromatic C–H functionalisation/halogenation reactions
2010
Postsynthetic Modification of Peptides: Chemoselective C‐Arylation of Tryptophan Residues
2009
Aromatic Homologation by Non‐Chelate‐Assisted RhIII‐Catalyzed CH Functionalization of Arenes with Alkynes
2014
Ruthenium(II)‐Catalyzed Oxidative CH Alkenylations of Sulfonic Acids, Sulfonyl Chlorides and Sulfonamides
2014
Visible‐Light‐Promoted Stereoselective Alkylation by Combining Heterogeneous Photocatalysis with Organocatalysis
2012
One‐Step Synthesis of the Benzocyclo[penta‐ to octa‐]isoindole Core
2009
Mechanisms of C–H bond activation: rich synergy between computation and experiment
2009
Allylic CH Alkylation of Unactivated α‐Olefins: Serial Ligand Catalysis Resumed
2011
Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups
2013 Standout
Copper‐Mediated Direct Cross‐Coupling of 1,3,4‐Oxadiazoles and Oxazoles with Terminal Alkynes
2010
Rhodium-Catalyzed C–H Bond Arylation of Arenes
2009
Ruthenium‐Catalyzed Direct Arylations of N‐Aryl 1,2,3‐Triazoles with Aryl Chlorides as Electrophiles
2009
Towards mild metal-catalyzed C–H bond activation
2011 Standout
Visible light photoredox catalysis: applications in organic synthesis
2010 Standout
Intermolecular oxidative cross-coupling of arenes
2009
Palladium‐Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates
2008
Copper as a Powerful Catalyst in the Direct Alkynylation of Azoles
2009
RuCl3⋅x H2O‐Catalyzed Direct Arylation of Arenes with Aryl Chlorides in the Presence of Triphenylphosphine
2009
C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation
2012 Standout
Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds
2009
Rhodium‐Catalyzed Oxidative Coupling between Salicylaldehydes and Internal Alkynes with CH Bond Cleavage To Produce 2,3‐Disubstituted Chromones
2008
Palladium(II)‐Catalyzed Oxidative CH/CH Cross‐Coupling between Two Structurally Similar Azoles
2012
Suzuki–Miyaura Coupling Reaction by PdII‐Catalyzed Aromatic CH Bond Activation Directed by an N‐Alkyl Acetamino Group
2007
Indoles from Simple Anilines and Alkynes: Palladium‐Catalyzed CH Activation Using Dioxygen as the Oxidant
2009
Copper‐Catalyzed Direct C Arylation of Heterocycles with Aryl Bromides: Discovery of Fluorescent Core Frameworks
2009
C–H bond activation enables the rapid construction and late-stage diversification of functional molecules
2013 Standout
Pd(ii)-catalyzed direct C5-arylation of azole-4-carboxylates through double C–H bond cleavage
2012
Cobalt‐Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides
2011
Copper‐Catalyzed Direct Carboxylation of CH Bonds with Carbon Dioxide
2010
CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals
2012 Standout
Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides
2010
Nickel‐Catalyzed CH Arylation of Azoles with Haloarenes: Scope, Mechanism, and Applications to the Synthesis of Bioactive Molecules
2011
Tandem CH Activation/Arylation Catalyzed by Low‐Valent Iron Complexes with Bisiminopyridine Ligands
2014
Palladium/Copper‐Catalyzed Oxidative CH Alkenylation/N‐Dealkylative Carbonylation of Tertiary Anilines
2013
Ligand‐Free Palladium‐Catalysed Direct Arylation of Heteroaromatics Using Low Catalyst Loadings
2008
Amide-directed arylation of sp3 C–H bonds using Pd(II) and Pd(0) catalysts
2010
A facile route to isoflavone quinones via the direct cross-coupling of chromones and quinones
2012
Fluorescent Diarylindoles by Palladium‐Catalyzed Direct and Decarboxylative Arylations of Carboxyindoles
2009
An Efficient Palladium‐Catalyzed CH Alkoxylation of Unactivated Methylene and Methyl Groups with Cyclic Hypervalent Iodine (I3+) Oxidants
2013
An efficient organocatalytic method for constructing biaryls through aromatic C–H activation
2010
Catalytic C–H amination: recent progress and future directions
2009
Constructing Multiply Substituted Arenes Using Sequential Palladium(II)‐Catalyzed CH Olefination
2010
A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene
2012
Catalysis for fluorination and trifluoromethylation
2011 StandoutNature
Palladium‐Catalyzed β‐Selective Direct Arylation of Porphyrins
2011
Introduction of Fluorine and Fluorine‐Containing Functional Groups
2013 Standout
Direct Arylation of Thiazoles on Water
2007
Metal‐ and Reagent‐Free Highly Selective Anodic Cross‐Coupling Reaction of Phenols
2014
Direct Alkynylation of Indole and Pyrrole Heterocycles
2009
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
How Can Theory Predict the Selectivity of Palladium‐Catalyzed Cross‐Coupling of Pristine Aromatic Molecules?
2011
Aryl triflates: useful coupling partners for the direct arylation of heteroaryl derivatives via Pd-catalyzed C–H activation–functionalization
2007
If CH Bonds Could Talk: Selective CH Bond Oxidation
2011
A Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading
2010
Regioselective syntheses of fully-substituted 1,2,3-triazoles: the CuAAC/C–H bond functionalization nexus
2010
Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds
2009
Direct arylations on water: synthesis of 2,5-disubstituted oxazoles balsoxin and texaline
2008
Iron‐Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides
2010
Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality
2009 Standout
Palladium‐Catalyzed Direct Arylation of Cyclic Enamides with Aryl Silanes by sp2 CH Activation
2009
A Highly Para‐Selective Copper(II)‐Catalyzed Direct Arylation of Aniline and Phenol Derivatives
2010
Tertiary Carbinamine Synthesis by Rhodium‐Catalyzed [3+2] Annulation of N‐Unsubstituted Aromatic Ketimines and Alkynes
2010
Visible light photocatalysis as a greener approach to photochemical synthesis
2010 Standout
Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
2010 Standout
Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation
2011 Standout
Direct palladium-catalyzed alkenylation, benzylation and alkylation of ethyl oxazole-4-carboxylate with alkenyl-, benzyl- and alkyl halides
2009
Computational study of ethene hydroarylation at [Ir(κ2-OAc)(PMe3)Cp]+
2010
Arylation of unactivated arenes
2010
Microwave‐Assisted Palladium‐Catalyzed Direct Arylation of 1,4‐Disubstituted 1,2,3‐Triazoles with Aryl Chlorides
2007
Synthesis of Extended π‐Systems through C–H Activation
2014 Standout
Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components
2007
Synthesis of Naphtho[1,8‐bc]pyran Derivatives and Related Compounds through Hydroxy Group Directed CH Bond Cleavage under Rhodium Catalysis
2010
Enzymatic assembly of carbon–carbon bonds via iron-catalysed sp3 C–H functionalization
2018 StandoutNatureNobel
Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp3)H Activation
2010
Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers
2011
Direct Arylation of 6‐Phenylpurine and 6‐Arylpurine Nucleosides by Ruthenium‐Catalyzed CH Bond Activation
2011
Construction of Nitrogen‐Containing Heterocycles by CH Bond Functionalization
2009
Rhodium(III) and Hexabromobenzene—A Catalyst System for the Cross‐Dehydrogenative Coupling of Simple Arenes and Heterocycles with Arenes Bearing Directing Groups
2012
Palladium‐Catalyzed Direct Functionalization of 2‐Aminobutanoic Acid Derivatives: Application of a Convenient and Versatile Auxiliary
2013
Regioselective palladium-catalyzed direct cross-coupling of coumarins with simple arenes
2012
Rhodium(III)‐Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group
2012
Iron‐Catalyzed Chemoselective ortho Arylation of Aryl Imines by Directed CH Bond Activation
2009
Recyclable Solid Ruthenium Catalysts for the Direct Arylation of Aromatic CH Bonds
2010
Iron(II)‐Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates
2012
Palladium-catalysed direct arylation of a tris-cyclometallated Ir(iii ) complex bearing 2,2′-thienylpyridine ligands: a powerful tool for the tuning of luminescence properties
2011
Catalytic Functionalization of Indoles in a New Dimension
2009 Standout
Transition‐Metal‐Catalyzed Synthesis of Hydroxylated Arenes
2010
Palladium‐Catalyzed CH Bond Functionalization of a Metal–Organic Framework (MOF): Mild, Selective, and Efficient
2011
Ruthenium‐Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds
2011
New method for C–H arylation/alkylation at α-position of cyclic aliphatic ethers by iron-oxide mediated reaction
2012
CH Activation: A Complementary Tool in the Total Synthesis of Complex Natural Products
2012
Copper‐Mediated C6‐Selective Dehydrogenative Heteroarylation of 2‐Pyridones with 1,3‐Azoles
2014
Synthesis of 5‐Alkyl[3,4‐c]thienopyrrole‐4,6‐dione‐Based Polymers by Direct Heteroarylation
2011
The Catalytic Ability of Various Transition Metals in the Direct Functionalization of Aromatic CH Bonds
2011
Iron‐Catalyzed Synthesis of 2‐Vinylquinolines via sp3 CH Functionalization and Subsequent CN Cleavage
2013
Rhodium‐Catalyzed Direct Addition of Aryl CH Bonds to N‐Sulfonyl Aldimines
2011
Mild Copper‐Mediated Direct Oxidative Cross‐Coupling of 1,3,4‐Oxadiazoles with Polyfluoroarenes by Using Dioxygen as Oxidant
2013
Direct C–H bond arylation of arenes with aryltin reagents catalysed by palladium complexes
2008
Recent advances in aryl–aryl bond formation by direct arylation
2009
Visible‐Light Photoredox Catalysis
2012 Standout
Palladium(II)‐Catalyzed CH Bond Arylation of Electron‐Deficient Arenes at Room Temperature
2010
Room‐Temperature Palladium‐Catalyzed CH Activation: ortho‐Carbonylation of Aniline Derivatives
2009
Direct Arylation of Benzene with Aryl Bromides using High‐Temperature/High‐Pressure Process Windows: Expanding the Scope of CH Activation Chemistry
2012
Enantioselective Catalysis of Photochemical Reactions
2015
Applications of and alternatives to π-electron-deficient azine organometallics in metal catalyzed cross-coupling reactions
2007
Phosphine‐Free, Palladium‐Catalyzed Arylation of Heterocycles through CH Bond Activation with Pivalic Acid as a Cocatalyst
2008
Readily Removable Directing Group Assisted Chemo‐ and Regioselective C(sp 3 )H Activation by Palladium Catalysis
2015
Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution
2011
Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation
2010
Palladium‐Catalyzed Oxidative Cyclization of N‐Aryl Enamines: From Anilines to Indoles
2008
DFT study of the mechanism of benzocyclobutene formation by palladium-catalysed C(sp3)–H activation: role of the nature of the base and the phosphine
2010
Palladium‐Catalyzed Dehydrogenative Cross‐Couplings of Benzazoles with Azoles
2011
Rhodium‐Catalyzed Silylation of Aromatic Carbon–Hydrogen Bonds in 2‐Arylpyridines with Disilane
2008
Copper‐Mediated and Copper‐Catalyzed Cross‐Coupling of Indoles and 1,3‐Azoles: Double CH Activation
2012
Oxidative Cross‐Coupling of Arenes Induced by Single‐Electron Transfer Leading to Biaryls by Use of Organoiodine(III) Oxidants
2007
Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
2010 StandoutNobel
Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C–H bond cleavage
2009
Palladium catalyzed arylation for the synthesis of polyarenes
2007
Regioselective synthesis of isocoumarins by ruthenium-catalyzed aerobic oxidative cyclization of aromatic acids with alkynes
2011
The Norbornene Shuttle: Multicomponent Domino Synthesis of Tetrasubstituted Helical Alkenes through Multiple CH Functionalization
2009
Iron‐Catalyzed C(sp3)C(sp3) Bond Formation through C(sp3)H Functionalization: A Cross‐Coupling Reaction of Alcohols with Alkenes
2009
Direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes via Pd/Cu-catalyzed phosphonium coupling
2010
PdII‐Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands
2008
Organopalladium(iv) chemistry
2009
Carbonates: Ecofriendly Solvents for Palladium‐Catalyzed Direct 2‐Arylation of Oxazole Derivatives
2009
Palladium(II)‐Catalyzed ortho Alkylation of Benzoic Acids with Alkyl Halides
2009
Copper‐Catalyzed CC Bond Formation through CH Functionalization: Synthesis of Multisubstituted Indoles from N‐Aryl Enaminones
2009
Fluorous silica gel-supported perfluoro-tagged palladium nanoparticles: an efficient and reusable catalyst for direct C-2 arylation of indoles
2010
Ruthenium‐Catalyzed Oxidative Cross‐Coupling of Chelating Arenes and Cycloalkanes
2008
Palladium‐Catalyzed Annulation of Acyloximes with Arynes (or Alkynes): Synthesis of Phenanthridines and Isoquinolines
2008
Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus
2009
Undirected Arene and Chelate‐Assisted Olefin C‐H Bond Activation: [RhIIICp*]‐Catalyzed Dehydrogenative Alkene–Arene Coupling as a New Pathway for the Selective Synthesis of Highly Substituted Z Olefins
2012
Pd-catalysed regioselective C–H functionalisation of 2-pyrones
2010
Recent Progress in Coupling of Two Heteroarenes
2011
Copper(ii)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides
2011
Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds
2011
Palladium-catalyzed direct oxidative Heck–Cassar–Sonogashira type alkynylation of indoles with alkynes under oxygen
2010
Bystanding F+ Oxidants Enable Selective Reductive Elimination from High‐Valent Metal Centers in Catalysis
2011
Nonnatural Amino Acid Synthesis by Using Carbon–Hydrogen Bond Functionalization Methodology
2012
Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents
2010
Silver‐Mediated Direct Amination of Benzoxazoles: Tuning the Amino Group Source from Formamides to Parent Amines
2009
Iron‐Catalyzed CH Bond Activation for the ortho‐Arylation of Aryl Pyridines and Imines with Grignard Reagents
2011
Transition‐Metal‐Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage
2009 Standout
Cross Dehydrogenative Arylation (CDA) of a Benzylic CH Bond with Arenes by Iron Catalysis
2009
Palladium‐Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids
2008
Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages
2009
Access to β‐Lactams by Enantioselective Palladium(0)‐Catalyzed C(sp3)H Alkylation
2014
An overview of N-heterocyclic carbenes
2014 StandoutNature
Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation
2011 Standout
Palladium‐Catalyzed C(sp3)H Activation: A Facile Method for the Synthesis of 3,4‐Dihydroquinolinone Derivatives
2014
CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems
2010
Palladium‐Catalyzed Tandem Heck Reaction/CH Functionalization—Preparation of Spiro‐Indane‐Oxindoles
2008
Ruthenium‐Catalyzed Regioselective Direct Alkylation of Arenes with Unactivated Alkyl Halides through CH Bond Cleavage
2009
Ruthenium(IV) Alkylidenes as Precatalysts for Direct Arylations of Alkenes with Aryl Chlorides and an Application to Sequential Catalysis
2007
CH Functionalization/CN Bond Formation: Copper‐Catalyzed Synthesis of Benzimidazoles from Amidines
2008
Direct Azole Amination: CH Functionalization as a New Approach to Biologically Important Heterocycles
2010
Iron‐Mediated Direct Arylation of Unactivated Arenes
2008
Carboxylic Acids as Traceless Directing Groups for Formal meta‐Selective Direct Arylation
2011
Fluorescent Naphthyl‐ and Anthrylazoles from the Catalytic Coupling of Phenylazoles with Internal Alkynes through the Cleavage of Multiple CH Bonds
2008
Copper‐Catalyzed Direct Alkenylation ofN‐Iminopyridinium Ylides
2009
Beyond Directing Groups: Transition‐Metal‐Catalyzed CH Activation of Simple Arenes
2012 Standout
Copper(II)‐Catalyzed meta‐Selective Direct Arylation of α‐Aryl Carbonyl Compounds
2010
Investigating N-methoxy-N′-aryl ureas in oxidative C–H olefination reactions: an unexpected oxidation behaviour
2011
Palladium(II)‐Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by the N‐(2‐Pyridyl)sulfonyl Protecting Group
2009
Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups
2011
Facile construction of highly functionalized 2-pyrrolines via FeCl3-catalyzed reaction of aziridines with arylalkynes
2009
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
2010
Ruthenium(II)-Catalyzed Alkenylation of Ferrocenyl Ketones via C–H Bond Activation
2012
Chelation-assisted carbonylation reactions catalyzed by Rh and Ru complexes
2010
Regioselective synthesis of 3,3-bis(indolyl)propanoic acid derivatives by iron(III)-catalyzed hydroarylation of propynoic acid derivatives with indoles
2011
PdII‐Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands
2008
Programmed synthesis of arylthiazoles through sequential C–H couplings
2013
Organocatalyzed Asymmetric Oxidative Coupling of α-Csp3-H of Tertiary Amines to α,β-Unsaturated γ-Butyrolactam: Synthesis of MBH-Type Products
2014
Copper-Mediated Intermolecular Direct Biaryl Coupling
2011
Establishment of Broadly Applicable Reaction Conditions for the Palladium-Catalyzed Direct Arylation of Heteroatom-Containing Aromatic Compounds
2009
Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates
2008 Standout
Palladium-catalyzed oxidative C–H bond coupling of indoles and benzaldehydes: a new approach to the synthesis of 3-benzoylindoles
2013
Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles
2008
Stereoselective Direct Copper-Catalyzed Alkenylation of Oxazoles with Bromoalkenes
2008
tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative
2010
Ruthenium-Catalyzed Direct C–H Bond Arylations of Heteroarenes
2011
Iron-Catalyzed Regioselective Direct Oxidative Aryl–Aryl Cross-Coupling
2011
Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene
2011
Iron Catalysis in Organic Synthesis
2015 Standout
Copper‐Catalyzed Direct Carboxylation of CH Bonds with Carbon Dioxide
2010
Modular Approach to Silicon‐Bridged Biaryls: Palladium‐Catalyzed Intramolecular Coupling of 2‐(Arylsilyl)aryl Triflates
2008
Rh(I)-Catalyzed Direct Arylation of Azines
2010
Pd-Catalyzed β-Selective Direct C–H Bond Arylation of Thiophenes with Aryltrimethylsilanes
2012
Cross‐Coupling of Heteroarenes by CH Functionalization: Recent Progress towards Direct Arylation and Heteroarylation Reactions Involving Heteroarenes Containing One Heteroatom
2014
Ruthenium‐Catalyzed Oxidative Homo‐Coupling of 2‐Arylpyridines
2009
SuFEx Click Chemistry Enabled Late-Stage Drug Functionalization
2018 StandoutNobel
Modulating Reactivity and Diverting Selectivity in Palladium-Catalyzed Heteroaromatic Direct Arylation Through the Use of a Chloride Activating/Blocking Group
2010
Transition-metal-catalyzed direct arylations via C–H bond cleavages
2010
Palladium(II)-Catalyzed Direct Intermolecular Alkenylation of Chromones
2011
Iron‐Catalyzed ortho Monoarylation of Benzamide Derivatives
2012
Palladium-catalyzed unactivated β-methylene C(sp3)–H bond alkenylation of aliphatic amides and its application in a sequential C(sp3)–H/C(sp2)–H bond alkenylation
2014
Highly Efficient Alkyne Hydroarylation with Chelating Dicarbene Palladium(II) and Platinum(II) Complexes
2007
Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery
2008
Copper‐Catalyzed Direct Alkenylation ofN‐Iminopyridinium Ylides
2009
Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions
2011 Standout
Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)
2013 Standout
Iron‐Catalyzed Chemoselective ortho Arylation of Aryl Imines by Directed CH Bond Activation
2009
Proton-Abstraction Mechanism in the Palladium-Catalyzed Intramolecular Arylation: Substituent Effects
2007
Rhodium-Catalyzed Regioselective C−H Functionalization via Decarbonylation of Acid Chlorides and C−H Bond Activation under Phosphine-Free Conditions
2008
A Simple and Direct Method for the Palladium‐Catalyzed Oxidative Coupling of Unactivated Allylarenes with Classic Arenes
2014
Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile
2011
Palladium(II)‐Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by the N‐(2‐Pyridyl)sulfonyl Protecting Group
2009
Direct arylation of azine N-oxides with aryl triflates
2009
Silver-Mediated Oxidative C–H/C–H Functionalization: A Strategy To Construct Polysubstituted Furans
2012
Palladium-Catalyzed Perarylation of 3-Thiophene- and 3-Furancarboxylic Acids Accompanied by C−H Bond Cleavage and Decarboxylation
2008
Application of Daugulis Copper-Catalyzed Direct Arylation to the Synthesis of 5-Aryl Benzotriazepines
2009
A New Oxidative Addition of Ruthenium(0) into an Aryl Halide Bond and Subsequent Intermolecular C−H Insertion
2009
Sc(OTf)3-Catalyzed Direct Alkylation of Quinolines and Pyridines with Alkanes
2009
Iron‐Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides
2010
Palladiumkatalysierte direkte Arylierungen von Heteroarenen mit Tosylaten und Mesylaten
2008
Palladium-Catalyzed Aerobic Oxidative Cross-Coupling Reactions of Terminal Alkynes with Alkylzinc Reagents
2010
Palladium-Catalyzed Direct Arylations, Alkenylations, and Benzylations through C−H Bond Cleavages with Sulfamates or Phosphates as Electrophiles
2010
Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines
2011
A Highly Para‐Selective Copper(II)‐Catalyzed Direct Arylation of Aniline and Phenol Derivatives
2010
Synthesis of Alternariol through an Intramolecular Biaryl Coupling Reaction Using Palladium Reagent
2007
Palladium-Catalyzed Direct (Hetero)arylation of Ethyl Oxazole-4-carboxylate: An Efficient Access to (Hetero)aryloxazoles
2008
Palladium(II)‐Catalyzed Direct ortho‐CH Acylation of Anilides by Oxidative Cross‐Coupling with Aldehydes using tert‐Butyl Hydroperoxide as Oxidant
2011
C–H Arylation of Pyridines: High Regioselectivity as a Consequence of the Electronic Character of C–H Bonds and Heteroarene Ring
2011
Rutheniumkatalysierte regioselektive direkte Alkylierungen von Arenen mit nichtaktivierten Alkylhalogeniden unter C‐H‐Bindungsspaltung
2009
Covalent Organic Frameworks for Carbon Dioxide Capture from Air
2022 StandoutNobel
Design and Synthesis of 2‐Methyl‐7‐aminobenzoxazole as Auxiliary in the Palladium(II)‐Catalyzed Arylation of a beta‐Positioned C(sp3)H Bond
2016
Direct C-2 Arylation of Alkyl 4-Thiazolecarboxylates: New Insights in Synthesis of Heterocyclic Core of Thiopeptide Antibiotics
2008
Catalytic Direct Arylations in Polyethylene Glycol (PEG): Recyclable Palladium(0) Catalyst for C−H Bond Cleavages in the Presence of Air
2009
Palladium‐Catalyzed β‐Selective Direct Arylation of Porphyrins
2011
Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates
2009
Palladium-Catalyzed Decarboxylative Arylation of C−H Bonds by Aryl Acylperoxides
2009
Organic Photoredox Catalysis
2016 Standout
Elements of Regiocontrol in Palladium-Catalyzed Oxidative Arene Cross-Coupling
2007 Standout
Rh(I)-Catalyzed Direct Arylation of Pyridines and Quinolines
2008
Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions
2009
Direct Arylation of Primary and Secondary sp3 C–H Bonds with Diarylhyperiodonium Salts via Pd Catalysis
2013
Ligandless Microwave-Assisted Pd/Cu-Catalyzed Direct Arylation of Oxazoles
2008
The Ru(cod)(cot)‐Catalyzed Alkenylation of Aromatic C—H Bonds with Alkenyl Acetates.
2007
Palladium-Catalyzed Alkylation of ortho-C(sp2)–H Bonds of Benzylamide Substrates with Alkyl Halides
2011
Nitrogen-directed ortho-arylation and -heteroarylation of aromatic rings catalyzed by ruthenium complexes
2008
Ligand-Free Palladium-Catalyzed Direct Arylation of Thiazoles at Low Catalyst Loadings
2009
Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation
2009
C−H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene
2008
Iron-Catalysed C-3 Functionalisation of Indolizines via C–H Bond Cleavage
2012
Rhodium-catalyzed Oxidative Coupling/Cyclization of Benzamides with Alkynes via C–H Bond Cleavage
2010
Pd-Catalyzed Dehydrogenative Cross-Coupling of Polyfluoroarenes with Heteroatom-Substituted Enones
2012
Efficient Palladium-Catalyzed C–H Fluorination of C(sp3)–H Bonds: Synthesis of β-Fluorinated Carboxylic Acids
2015
Palladium‐Catalyzed Annulation of Acyloximes with Arynes (or Alkynes): Synthesis of Phenanthridines and Isoquinolines
2008
Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations
2015 Standout
Synthesis of Highly Substituted Naphthalene and Anthracene Derivatives by Rhodium-Catalyzed Oxidative Coupling of Arylboronic Acids with Alkynes
2009
Ruthenium(II)-Catalyzed Regio- and Stereoselective Hydroarylation of Alkynes via Directed C–H Functionalization
2012
Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C–H Bond Cleavage Directed by a Nitrogen-containing Group
2011
Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex
2008
Copper-Catalyzed Oxidative sp3 C−H Bond Arylation with Aryl Boronic Acids
2008
Benzenesulfonyl chlorides: new reagents for access to alternative regioisomers in palladium-catalysed direct arylations of thiophenes
2013
C–H Arylation Reaction: Atom Efficient and Greener Syntheses of π-Conjugated Small Molecules and Macromolecules for Organic Electronic Materials
2013
Rh[III]-Catalyzed Direct C–H Amination Using N-Chloroamines at Room Temperature
2011
Grignard‐Type Arylation of Aldehydes via a Rhodium‐Catalyzed CH Activation under Mild Conditions
2011
Site-Selective Azaindole Arylation at the Azine and Azole Rings via N-Oxide Activation
2009
Diethyl carbonate as a solvent for ruthenium catalysed C–H bond functionalisation
2009
Straightforward access to aryl-substituted tetrathiafulvalenes by palladium-catalysed direct C–H arylation and their photophysical and electrochemical properties
2011
Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions
2008
Suzuki–Miyaura Coupling Reaction by PdII‐Catalyzed Aromatic CH Bond Activation Directed by an N‐Alkyl Acetamino Group
2007
Rhodium(III)-Catalyzed Intermolecular Direct Amination of Aromatic C–H Bonds with N-Chloroamines
2011
Iron-Catalyzed Heterocycle and Arene Deprotonative Alkylation
2010
One-pot Sequential Direct C–H Bond Arylation of Azoles Catalyzed by [Pd(phen)2](PF6)2: Synthetic Methods for Triarylated Azoles
2012
Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A
2012
Direct Synthesis of Pyrazolo[5,1‐a]isoindoles via Intramolecular Palladium‐Catalyzed CH Bond Activation
2010
Palladium-Catalyzed C–H Homocoupling of Furans and Thiophenes Using Oxygen as the Oxidant
2014
Synthesis of Highly Substituted Acenes through Rhodium-Catalyzed Oxidative Coupling of Arylboron Reagents with Alkynes
2011
Palladium-Catalyzed Synthesis of 2-Substituted Benzothiazoles via a C−H Functionalization/Intramolecular C−S Bond Formation Process
2008
Iron‐Mediated Direct Arylation of Unactivated Arenes
2008
Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation
2011
Synthesis of Benzocyclobutenes by Palladium-Catalyzed C−H Activation of Methyl Groups: Method and Mechanistic Study
2008
Rhodium(III)-Catalyzed Regioselective C–H Alkenylation of Phenylphosphine Sulfides
2014
Rhodium-Catalyzed ortho-Benzoxylation of sp2 C−H Bond
2009
Chelation-assisted palladium-catalyzed acyloxylation of benzyl sp3 C–H bonds using PhI(OAc)2 as oxidant
2010
Pd(OAc)2-Catalyzed Oxidative C−H/C−H Cross-Coupling of Electron-Deficient Polyfluoroarenes with Simple Arenes
2010
Rhodium(III)‐Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group
2012
Palladium-catalyzed direct heteroarylation of chloropyridines and chloroquinolines
2008
Ortho-selective Arylation of Arylazoles with Aryl Bromides Catalyzed by Ruthenium Complexes
2008
Mild and efficient palladium-catalyzed intramolecular direct arylation reactions
2008
Palladium-catalysed direct 3- or 4-arylation of thiophene derivatives using aryl bromides
2009
Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes
2007
Control of Product Selectivity by a Styrene Additive in Ruthenium-Catalyzed C−H Arylation
2010
On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation
2010
Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes
2010
Rh(III)-Catalyzed Amide-Directed Cross-Dehydrogenative Heteroarylation of Pyridines
2013
Palladium-Catalyzed C−H Bond Functionalization with Arylsulfonyl Chlorides
2009
Rhodium-Catalyzed Oxidative 1:1, 1:2, and 1:4 Coupling Reactions of Phenylazoles with Internal Alkynes through the Regioselective Cleavages of Multiple C−H Bonds
2010
Palladium-Catalyzed C–H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation
2012
Aromatic C–H coupling with hindered arylboronic acids by Pd/Fe dual catalysts
2013
Rhodium-Catalyzed Oxidative ortho-Acylation of Benzamides with Aldehydes: Direct Functionalization of the sp2 C–H Bond
2011
Transition-Metal-Free Coupling Reactions
2014
Copper-Catalyzed Oxidative Cross-Coupling ofN,N-Dimethylanilines with Heteroarenes under Molecular Oxygen
2011
Iron-catalyzed arylation of benzoazoles with aromatic aldehydes using oxygen as oxidant
2012
Metal–organic frameworks for artificial photosynthesis and photocatalysis
2014 Standout
Synthesis of 1-Aminoisoquinolines via Rh(III)-Catalyzed Oxidative Coupling
2011
Pd-catalyzed ortho-arylation of phenylacetamides, benzamides, and anilides with simple arenes using sodium persulfate
2010
Direct Pd-Catalyzed Arylation of 1,2,3-Triazoles
2007
Iron‐Catalyzed Cross Dehydrogenative Coupling (CDC) of Indoles and Benzylic CH Bonds
2015
Cp2Ni-KOt-Bu-BEt3 (or PPh3) Catalyst System for Direct C−H Arylation of Benzene, Naphthalene, and Pyridine
2009
Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides
2009
Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene
2010
Plasmon-Enhanced Photocatalytic CO2 Conversion within Metal–Organic Frameworks under Visible Light
2016 StandoutNobel
Highly Regioselective C2-Alkenylation of Indoles Using the N-Benzoyl Directing Group: An Efficient Ru-Catalyzed Coupling Reaction
2013
Nitrogen-Directed Ortho-Selective Homocoupling of Aromatic Compounds Catalyzed by Ruthenium Complexes
2008
Synthesis of α‐Carbolines Starting from 2,3‐Dichloropyridines and Substituted Anilines
2008
Rhodium-Catalyzed Dehydrogenative Coupling of Phenylheteroarenes with Alkynes or Alkenes
2015
Efficient Cross‐Coupling Reactions of Nitrogen Nucleophiles with Aryl Halides in Water
2009
On the role of anionic ligands in the site-selectivity of oxidative C–H functionalization reactions of arenes
2013
Palladium-Catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C−H Activation
2009
Palladium‐Catalyzed Monoselective Halogenation of CH Bonds: Efficient Access to Halogenated Arylpyrimidines using Calcium Halides
2010
Pd-Catalyzed Oxidative CH/CH Direct Coupling of Heterocyclic N-Oxides
2013
Ruthenium‐Catalyzed Oxidative Cross‐Coupling of Chelating Arenes and Cycloalkanes
2008
Rhodium-Catalyzed Oxidative C−H Arylation of 2-Arylpyridine Derivatives via Decarbonylation of Aromatic Aldehydes
2010
Palladium-Catalyzed C−H Functionalization of Pyridine N-Oxides: Highly Selective Alkenylation and Direct Arylation with Unactivated Arenes
2008
Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components
2007
Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas
2016 Standout
Palladium-Catalyzed Selective β-Arylation of Aliphatic Amides Using a Removable N,O-Bidentate Auxiliary
2015
Silver-Promoted, Palladium-Catalyzed Direct Arylation of Cyclopropanes: Facile Access to Spiro 3,3′-Cyclopropyl Oxindoles
2013
Oxidative dimerization of azoles via copper(II)/silver(I)-catalyzed CH homocoupling
2009
Ruthenium-Catalyzed Oxidative Synthesis of 2-Pyridones through C–H/N–H Bond Functionalizations
2011
Programmed Synthesis of Tetraarylthiophenes through Sequential C−H Arylation
2009
Iridium-Catalyzed Direct Tetraborylation of Perylene Bisimides
2011
Remote C–H bond functionalization reveals the distance-dependent isotope effect
2008
Copper-Mediated Formally Dehydrative Biaryl Coupling of Azine N-Oxides and Oxazoles
2015
Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C–H bond functionalization
2014
Iron‐Catalyzed Direct C–H Arylation of Heterocycles and Quinones with Arylboronic Acids
2013
Pd(II)-Catalyzed para-Selective C–H Arylation of Monosubstituted Arenes
2011
Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope
2011 Standout
FeCl3-Catalyzed Stereoselective Construction of Spirooxindole Tetrahydroquinolines via Tandem 1,5-Hydride Transfer/Ring Closure
2012
Pd(OAc)2 catalyzed C–H activation of 1,3,4-oxadiazoles and their direct oxidative coupling with benzothiazoles and aryl boronic acids using Cu(OAc)2 as an oxidant
2013
Copper‐Catalyzed Direct C Arylation of Heterocycles with Aryl Bromides: Discovery of Fluorescent Core Frameworks
2009
Synthesis of Olefin‐Oxazoline Ligands (OlefOx) by Rhodium(III)‐Catalyzed Oxidative Olefination
2012
Synthesis of Biaryls through Aromatic CH Bond Activation: A Review of Recent Developments
2014
Palladium-Catalyzed Direct Arylation of Nitro-Substituted Aromatics with Aryl Halides
2008
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Density Functional Theory Study of the Mechanisms of Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents
2013
An Aromatic Glaser−Hay Reaction
2009
Iron-Catalyzed Direct Arylation through an Aryl Radical Transfer Pathway
2010
Synthesis of 2-Substituted Pyrazolo[1,5-a]pyridines through Cascade Direct Alkenylation/Cyclization Reactions
2010
Palladium-Catalyzed Transformations of Alkyl C–H Bonds
2016 Standout
Regioselective Palladium-Catalyzed Arylation of 4-Chloropyrazoles
2010
Controlling Site Selectivity in Pd-Catalyzed Oxidative Cross-Coupling Reactions
2011
Carbonates: eco-friendly solvents for palladium-catalysed direct arylation of heteroaromatics
2010
Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization
2012
Palladium-Catalyzed Direct Synthesis of Carbazoles via One-Pot N-Arylation and Oxidative Biaryl Coupling: Synthesis and Mechanistic Study
2009
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
2009 Standout
Waste-Free Synthesis of Condensed Heterocyclic Compounds by Rhodium-Catalyzed Oxidative Coupling of Substituted Arene or Heteroarene Carboxylic Acids with Alkynes
2009
Synthesis and characterization of a cyclic vinylpalladium(ii) complex: vinylpalladium species as the possible intermediate in the catalytic direct olefination reaction of enamide
2011
Palladium(II)-Catalyzed Regioselective Arylation of Naphthylamides with Aryl Iodides Utilizing a Quinolinamide Bidentate System
2013
Transition Metal‐Mediated Direct CH Arylation of Heteroarenes Involving Aryl Radicals
2014
Palladium‐Catalyzed Direct C‐4 Arylation of 2,5‐Disubstituted Furans with Aryl Bromides
2008
PyDipSi: A General and Easily Modifiable/Traceless Si-Tethered Directing Group for C−H Acyloxylation of Arenes
2010
Synthesis of 6-oxacyclopropa[a]indene derivatives starting from Baylis–Hillman adducts via Pd-mediated C(sp3)–H activation
2008
Pd-catalyzed Highly Regio- and Stereocontrolled Direct Alkenylation of Electron-deficient Polyfluoroarenes
2011
Copper-Mediated Dehydrogenative Biaryl Coupling of Naphthylamines and 1,3-Azoles
2013
Intramolecular Pd(II)-Catalyzed Oxidative Biaryl Synthesis Under Air: Reaction Development and Scope
2008
Synthesis of Dragmacidin D via Direct C–H Couplings
2011
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
2019 StandoutNobel
Palladium‐Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids
2008
Palladium‐katalysierte oxidative Cyclisierung von N‐Aryl‐Enaminen: von Anilinen zu Indolen
2008
Iron-Catalyzed Arylation of Heterocycles via Directed C–H Bond Activation
2014
Ligand and solvent-free iron catalyzed oxidative alkynylation of azoles with terminal alkynes
2011
Direct Functionalization Processes: A Journey from Palladium to Copper to Iron to Nickel to Metal-Free Coupling Reactions
2012
Domino Palladium-Catalyzed Heck-Intermolecular Direct Arylation Reactions
2009
Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation
2012
Ligand-Promoted C3-Selective Arylation of Pyridines with Pd Catalysts: Gram-Scale Synthesis of (±)-Preclamol
2011
Iron or boron-catalyzed C–H arylthiation of substituted phenols at room temperature
2014
Mechanistic understanding of Rh-catalyzed N-sulfonylaldimine insertion into aryl C–H bonds
2012
Asymmetric synthesis of optically active spiroacetals from alkynyl glycols catalyzed by gold complex/Brønsted acid binary system
2015
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Modified palladium-catalyzed regioselective ortho-arylation of sp2 C–H bond substrates with a low catalyst loading
2008
C−H Bonds as Ubiquitous Functionality: A General Approach to Complex Arylated Pyrazoles via Sequential Regioselective C-Arylation and N-Alkylation Enabled by SEM-Group Transposition
2009
Ruthenium-Catalyzed Meta Sulfonation of 2-Phenylpyridines
2011
Synthesis of 2-Pyridones and Iminoesters via Rh(III)-Catalyzed Oxidative Coupling between Acrylamides and Alkynes
2010
Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes
2008
Phosphonium Coupling in the Direct Bond Formations of Tautomerizable Heterocycles via C–OH Bond Activation
2008
Predictable and Site-Selective Functionalization of Poly(hetero)arene Compounds by Palladium Catalysis
2010
Iron-catalyzed Cross-Coupling of Electron-Deficient Heterocycles and Quinone with Organoboron Species via Innate C–H Functionalization: Application in Total Synthesis of Pyrazine Alkaloid Botryllazine A
2013
Selective ortho-Bromination of Substituted Benzaldoximes Using Pd-Catalyzed C–H Activation: Application to the Synthesis of Substituted 2-Bromobenzaldehydes
2011
Palladium(II)-Catalyzed Direct Alkenylation and Arylation of Arenes: Removable 2-Pyridylsulfinyl Group Assisted C–H Bond Activation
2011
Palladium-Catalyzed Benzylation of Heterocyclic Aromatic Compounds
2009
RuCl3-Catalyzed Alkenylation of Aromatic C−H Bonds with Terminal Alkynes
2008
Ruthenium(II) Acetate Catalyst for Direct Functionalisation of sp2‐CH Bonds with Aryl Chlorides and Access to Tris‐ Heterocyclic Molecules
2009
Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides
2010
Rh Catalyzed C–H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes
2011
Direct coupling of arenes and iodoarenes catalyzed by a rhodium complex with a strongly π-accepting phosphite ligand
2008 Nobel
Direct arylation of dithienylperfluorocyclopentenes via palladium-catalysed C–H bond activation: a simpler access to photoswitches
2012
Catalytic Sequential Reactions Involving Palladacycle-Directed Aryl Coupling Steps
2008
Carbon−Hydrogen Bond Functionalization Approach for the Synthesis of Fluorenones and ortho-Arylated Benzonitriles
2008
Evaluation of Electron‐Deficient Phosphine Ligands for Direct Arylation of Heterocycles
2010
Carboxylic Acids as Traceless Directing Groups for Formal meta‐Selective Direct Arylation
2011
Ester‐Directed Selective Olefination of Acrylates by Rhodium Catalysis
2014
Pd-Catalyzed Direct Arylation of Polyfluoroarenes on Water under Mild Conditions Using PPh3 Ligand
2012
Oxidative Coupling of Arylboronic Acids with Arenes via Rh-Catalyzed Direct C−H Arylation
2007
Modifiable Sulfur Tethers as Directing Groups for Aromatic CH Acetoxylation Reactions
2011
Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit
2009
Synthesis of Arylated Perylene Bisimides through C−H Bond Cleavage under Ruthenium Catalysis
2009
Highly Regioselective Palladium-Catalyzed Direct Arylation of Oxazole at C-2 or C-5 with Aryl Bromides, Chlorides, and Triflates
2010
Regioselective Cross‐Dehydrogenative Coupling of Chromones and Non‐Activated Arenes
2012
Anti-Markovnikov hydroarylation of styrenes catalyzed by an in situ generated ruthenium complex
2008
Copper-Catalyzed Oxidative Amination of Benzoxazoles via C−H and C−N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources
2010
Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene)
2010
Palladium-Catalyzed Aryl C−H Bonds Activation/Acetoxylation Utilizing a Bidentate System
2009
Palladium‐Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation
2009
Direct Transition-Metal-Free Intramolecular Arylation of Phenols
2008
Heterocycle Formation via Palladium-Catalyzed Intramolecular Oxidative C−H Bond Functionalization: An Efficient Strategy for the Synthesis of 2-Aminobenzothiazoles
2009
Para-Selective Gold-Catalyzed Direct Alkynylation of Anilines
2012
Cu(II)-mediated oxidative dimerization of 2-phenylpyridine derivatives
2008
Pd(ii )-Catalyzed arylation of unactivated methylene C(sp3)–H bonds with aryl halides using a removable auxiliary
2014
Palladium-Catalyzed Oxidative Ethoxycarbonylation of Aromatic C−H Bond with Diethyl Azodicarboxylate
2008
Electrochemically addressable trisradical rotaxanes organized within a metal–organic framework
2015 StandoutNobel
Mechanistic Study of Acetate-Assisted C−H Activation of 2-Substituted Pyridines with [MCl2Cp*]2(M = Rh, Ir) and [RuCl2(p-cymene)]2
2008
[RuCl3(H2O)n]-catalyzed direct arylations
2008
Direkte Azolaminierung: C‐H‐Funktionalisierung zur Herstellung biologisch wichtiger Heterocyclen
2010
Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates
2009
Visible light photocatalysis – from racemic to asymmetric activation strategies
2020
C–H Bond Functionalization of Arylpyrimidines Catalyzed by an in situ Generated Ruthenium(II) Carboxylate System and the Construction of Tris(heteroaryl)‐Substituted Benzenes
2011
Palladium-Catalyzed Benzylic Addition of 2-Methyl Azaarenes to N-Sulfonyl Aldimines via C−H Bond Activation
2010
Passive F+‐Oxidationsmittel ermöglichen die selektive reduktive Eliminierung hochvalenter Metallzentren in der Katalyse
2011
Rhodium-Catalyzed C3-Selective Alkenylation of Substituted Thiophene-2-carboxylic Acids and Related Compounds
2013
Pd/Cu‐Catalyzed Direct Alkenylation of Azole Heterocycles with Alkenyl Halides
2010
Palladium-Catalyzed C−H Functionalization of Heteroarenes with Aryl Bromides and Chlorides
2010
Palladium-Catalyzed Direct Alkynylation of C−H Bonds in Benzenes
2009
Total Synthesis of Diptoindonesin G via a Highly Efficient Domino Cyclodehydration/Intramolecular Friedel−Crafts Acylation/Regioselective Demethylation Sequence
2010
Highly Regio- and Stereoselective Ruthenium(II)-Catalyzed Direct ortho-Alkenylation of Aromatic and Heteroaromatic Aldehydes with Activated Alkenes under Open Atmosphere
2012
Nickel-Catalyzed Direct Alkynylation of Azoles with Alkynyl Bromides
2009
Regioselective Ruthenium-Catalyzed Direct Benzylations of Arenes through C−H Bond Cleavages
2009
Highly Efficient and Versatile Pd-Catalyzed Direct Alkynylation of Both Azoles and Azolines
2010
Assessment of the Intermediacy of Arylpalladium Carboxylate Complexes in the Direct Arylation of Benzene: Evidence for C−H Bond Cleavage by “Ligandless” Species
2011
Rhodium(III) und Hexabrombenzol – ein Katalysatorsystem zur gekreuzten dehydrierenden Kupplung einfacher Arene und Heterocyclen mit Arenen mit dirigierenden Gruppen
2012
Synthesis of 5‐Alkyl[3,4‐c]thienopyrrole‐4,6‐dione‐Based Polymers by Direct Heteroarylation
2011
Copper-Catalyzed Direct Amination of Electron-Deficient Arenes with Hydroxylamines
2011
ortho‐Olefination of Arylaldehyde O‐Methyloximes through Palladium‐Catalyzed C–H Activation
2012
Palladium-Catalyzed Aerobic Dehydrogenative Cross-Coupling of Polyfluoroarenes with Thiophenes: Facile Access to Polyfluoroarene–Thiophene Structure
2011
Synthesis, Characterization and Catalytic Activity of New N‐Heterocyclic Bis(carbene)ruthenium Complexes
2009
Copper(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Azoles
2012
Copper-Promoted Sulfenylation of sp2 C–H Bonds
2012
Iron-catalyzed oxidative homo-coupling of indoles via C–H cleavage
2010
Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization
2012 Standout
Pd-Catalyzed Intermolecular ortho-C−H Amidation of Anilides by N-Nosyloxycarbamate
2010
Palladium(ii)-catalyzed cross-coupling of simple alkenes with acrylates: a direct approach to 1,3-dienes through C–H activation
2013
A General Method for Copper-Catalyzed Arene Cross-Dimerization
2011
Insights into Directing Group Ability in Palladium-Catalyzed C−H Bond Functionalization
2008
Ruthenium-Catalyzed C–H/N–O Bond Functionalization: Green Isoquinolone Syntheses in Water
2011
Rhodium(III)-Catalyzed Oxidative Alkenylation of 1,3-Dithiane-Protected Arenecarbaldehydes via Regioselective C–H Bond Cleavage
2015
Palladium-catalysed regioselective aroylation and acetoxylation of 3,5-diarylisoxazole via ortho C–H functionalisations
2013
Rhodium-Catalyzed Direct Oxidative Carbonylation of Aromatic C−H Bond with CO and Alcohols
2008
Brønsted Acidity in Metal–Organic Frameworks
2015 StandoutNobel
Ruthenium-Catalyzed Carbonylation at Ortho C−H Bonds in Aromatic Amides Leading to Phthalimides: C−H Bond Activation Utilizing a Bidentate System
2009
Stepwise Construction of Head-to-Tail-Type Oligothiophenes via Iterative Palladium-Catalyzed CH Arylation and Halogen Exchange
2009
Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes
2011
A Highly Efficient Ruthenium(II) Catalyst with (1,2-Diarylvinyl)phosphine Ligands for Direct Ortho Arylation of 2-Arylpyridine with Aryl Chlorides
2010
The Ru(cod)(cot)-Catalyzed Alkenylation of Aromatic C−H Bonds with Alkenyl Acetates
2007
Cross Dehydrogenative Arylation (CDA) of a Benzylic CH Bond with Arenes by Iron Catalysis
2009
Copper-Catalyzed Dehydrogenative Cross-Coupling of Benzothiazoles with Thiazoles and Polyfluoroarene
2012
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
Palladium-Catalyzed Arylation and Alkylation of 3,5-Diphenylisoxazole with Boronic Acids via C−H Activation
2008
Oxidative C–H/C–H Coupling of Azine and Indole/Pyrrole Nuclei: Palladium Catalysis and Synthesis of Eudistomin U
2011
Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds
2009 Standout
Oxidative Nickel–Air Catalysis in CH Arylation: Direct Cross‐Coupling of Azoles with Arylboronic Acids using Air as Sole Oxidant
2010
A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds
2008
Efficient Rh(I)-Catalyzed Direct Arylation and Alkenylation of Arene C−H Bonds via Decarbonylation of Benzoic and Cinnamic Anhydrides
2009
“On Water” Direct and Site‐Selective Pd‐Catalysed CH Arylation of (NH)‐Indoles
2010
Intramolecular Palladium-Catalyzed Direct Arylation of Alkenyl Triflates
2007
Direct Palladium-Catalyzed Alkynylation of N-Fused Heterocycles
2007
Recent Developments in Catalytic Aryl Coupling Reactions
2007
Synthesis of Stilbene and Distyrylbenzene Derivatives through Rhodium-Catalyzed Ortho-Olefination and Decarboxylation of Benzoic Acids
2010
Dual Catalysis Strategies in Photochemical Synthesis
2016 Standout
Palladium(II)-Catalyzed Oxidative C−H/C−H Cross-Coupling of Heteroarenes
2010
Advances in asymmetric visible-light photocatalysis, 2015–2019
2019
Selective Synthesis of 3-Aryl Quinolin-2(1H)-ones and 3-(1-Arylmethylene)oxindoles Involving a 2-Fold Arene C−H Activation Process
2009
Ortho Arylation of Acetanilides via Pd(II)-Catalyzed C−H Functionalization
2007
Copper-Catalyzed “Click” Reaction/Direct Arylation Sequence: Modular Syntheses of 1,2,3-Triazoles
2008
Ruthenium-Catalyzed Hydroarylations of Methylenecyclopropanes: Mild C−H Bond Functionalizations with Conservation of Cyclopropane Rings
2008
Regioselective Functionalization of the Imidazole Ring via Transition Metal‐Catalyzed CN and CC Bond Forming Reactions
2010
Palladium-catalyzed Direct C–H Bond Arylation of Simple Arenes with Aryltrimethylsilanes
2011
Rhodium-catalyzed and Coordination-assisted Regioselective Alkenylation of Aromatic C–H Bonds with Terminal Silylacetylenes
2008
Ohne dirigierende Gruppen: übergangsmetallkatalysierte C‐H‐Aktivierung einfacher Arene
2012
Ligand-less palladium-catalyzed direct 5-arylation of thiophenes at low catalyst loadings
2009
Fluorescent Naphthyl‐ and Anthrylazoles from the Catalytic Coupling of Phenylazoles with Internal Alkynes through the Cleavage of Multiple CH Bonds
2008
Intermolecular Dehydrogenative Heck Reactions
2011
Pd(ii )-catalyzed β-C–H arylation of O-methyl ketoximes with iodoarenes
2016
Copper-Mediated C−H Bond Arylation of Arenes with Arylboronic Acids
2008
Constructing Multiply Substituted Arenes Using Sequential Palladium(II)‐Catalyzed CH Olefination
2010
Ruthenium-Catalyzed Ortho-Alkenylation of Aromatic Ketones with Alkenes by C–H Bond Activation
2011
Rhodium-Catalyzed Oxidative Coupling/Cyclization of 2-Phenylindoles with Alkynes via C−H and N−H Bond Cleavages with Air as the Oxidant
2010
Direct Palladium-Catalyzed C-3 Arylation of Free (NH)-Indoles with Aryl Bromides under Ligandless Conditions
2008
The Fe(PDP)-catalyzed aliphatic C–H oxidation: a slow addition protocol
2008
Übergangsmetallkatalysierte direkte Arylierungen von (Hetero)Arenen durch C‐H‐Bindungsbruch
2009
Synthesis of Quinolines via Rh(III)-Catalyzed Oxidative Annulation of Pyridines
2011
Bidentate phosphines as ligands in the palladium-catalyzed intramolecular arylation: the intermolecular base-assisted proton abstraction mechanism
2008
Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate
2009
Direct Amination of Azoles via Catalytic C−H, N−H Coupling
2009
Palladium/Copper‐Catalyzed Oxidative CH Alkenylation/N‐Dealkylative Carbonylation of Tertiary Anilines
2013
Heterocycle Synthesis via Direct C–H/N–H Coupling
2011
Copper-mediated direct arylation of benzoazoles with aryl iodides
2008
Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H Functionalization
2011
Palladium-Catalyzed Direct C-2 Arylation of Indoles with Potassium Aryltrifluoroborate Salts
2008
Direct Cross-Coupling Reaction of Simple Alkenes with Acrylates Catalyzed by Palladium Catalyst
2009
Ruthenium-Catalyzed Oxidative Vinylation of Heteroarene Carboxylic Acids with Alkenes via Regioselective C−H Bond Cleavage
2011
Distinct Reactivity of Pd(OTs)2: The Intermolecular Pd(II)-Catalyzed 1,2-Carboamination of Dienes
2008
Synthesis of Phenanthrone Derivatives from sec-Alkyl Aryl Ketones and Aryl Halides via a Palladium-Catalyzed Dual C−H Bond Activation and Enolate Cyclization
2010
Direct Arylation of Oxazoles at C2. A Concise Approach to Consecutively Linked Oxazoles
2008
Superacidity in Sulfated Metal–Organic Framework-808
2014 StandoutNobel
Exceptional Sensitivity of Metal−Aryl Bond Energies to ortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M−C/H−C Bond Energy Correlations
2009
Palladium-Catalyzed Benzylic C−H Insertion of 2-Substituted N-Iminopyridinium Ylides
2008
Copper‐Catalyzed Cross‐Dehydrogenative Coupling (CDC) of Alkynes and Benzylic CH Bonds
2010
Copper-Catalyzed Arylation and Alkenylation of Polyfluoroarene C−H Bonds
2008
Intramolecular Palladium-Catalyzed Alkane C−H Arylation from Aryl Chlorides
2010
Rhodium-catalyzed Oxidative Coupling of Benzylamines with Alkynes through Dehydrogenation and Dehydrogenative Cyclization
2011
Aromatic Homologation by Non‐Chelate‐Assisted RhIII‐Catalyzed CH Functionalization of Arenes with Alkynes
2014
Functionalization of a Simple Dithienylethene via Palladium-Catalyzed Regioselective Direct Arylation
2011
High-Yielding Palladium-Catalyzed Intramolecular Alkane Arylation: Reaction Development and Mechanistic Studies
2007
Synthesis and Late-Stage Functionalization of Complex Molecules through C–H Fluorination and Nucleophilic Aromatic Substitution
2014
Ruthenium-Catalyzed Oxidative C–H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones
2011
Palladium-Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air
2008
Ruthenium‐Catalyzed Regioselective Cyclization of Aromatic Ketones with Alkynes: An Efficient Route to Indenols and Benzofulvenes
2011
A chiral ion-pair photoredox organocatalyst: enantioselective anti-Markovnikov hydroetherification of alkenols
2017
Palladium‐Catalyzed Direct Arylations of 1,2,3‐Triazoles with Aryl Chlorides using Conventional Heating
2008
Double C−H Activation: The Palladium-Catalyzed Direct C-Arylation of Xanthines with Arenes
2011
Palladium-Catalyzed C–H Alkenylation of Arenes Using Thioethers as Directing Groups
2012
Ruthenium‐Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds
2011
Palladium-Catalyzed Dehydrogenative Direct Arylations of 1,2,3-Triazoles
2010
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Catalytic Regioselective Oxidative Coupling of Furan-2-Carbonyls with Simple Arenes
2012
Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation
2008
Palladium-catalyzed direct C–H arylation of unactivated arenes with aryl Halides
2011
Recent Progress in Nickel‐Catalyzed Biaryl Coupling
2012
Copper-Catalyzed Arylation of Heterocycle C−H Bonds
2007
Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 Carbon−Hydrogen Bonds
2010
Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group
2011
Activation of olefins via asymmetric Brønsted acid catalysis
2018 StandoutScienceNobel
Synthesis of Annulated 2H-Indazoles and 1,2,3- and 1,2,4-Triazoles via a One-Pot Palladium-Catalyzed Alkylation/Direct Arylation Reaction
2008
Synthesis of Isoquinolines via Rhodium(III)‐Catalyzed Dehydrative CC and CN Coupling between Oximines and Alkynes
2011
Mechanistic Comparison between Pd-Catalyzed Ligand-Directed C−H Chlorination and C−H Acetoxylation
2009
Directed Amination of Non‐Acidic Arene CH Bonds by a Copper–Silver Catalytic System
2013
Highly Regioselective Palladium-Catalyzed Oxidative Coupling of Indolizines and Vinylarenes via C−H Bond Cleavage
2009
RuH2(CO)(PPh3)3-catalyzed arylation of aromatic esters using arylboronates via C–H bond cleavages
2010
Ruthenium-catalyzed aerobic oxidative coupling of alkynes with 2-aryl-substituted pyrroles
2011
Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway
2010 Standout
Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents
2010
Visible‐Light Photocatalysis: Does It Make a Difference in Organic Synthesis?
2018 Standout
Palladium-Catalyzed Direct Oxidative Alkenylation of Azoles
2010
Formal Synthesis of Nitidine and NK109 via Palladium-Catalyzed Domino Direct Arylation/N-Arylation of Aryl Triflates
2011
Palladium-Catalyzed Oxidative C−H Bond and C═C Double Bond Cleavage: C-3 Acylation of Indolizines with α,β-Unsaturated Carboxylic Acids
2011
Direct α‐Arylation of Ethers through the Combination of Photoredox‐Mediated CH Functionalization and the Minisci Reaction
2014
Direct arylation of oxazole and benzoxazole with aryl or heteroaryl halides using a palladium–diphosphine catalyst
2007
Rh-Catalyzed Oxidative Coupling between Primary and Secondary Benzamides and Alkynes: Synthesis of Polycyclic Amides
2010
DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones
2012
Copper(II)‐Catalyzed meta‐Selective Direct Arylation of α‐Aryl Carbonyl Compounds
2010
Palladium-Catalyzed Direct Arylation of Aryl(azaaryl)methanes with Aryl Halides Providing Triarylmethanes
2007
Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism
2010
Palladium-Catalyzed Direct C−H Arylation of N-Iminopyridinium Ylides: Application to the Synthesis of (±)-Anabasine
2007
Direct C−H Transformation via Iron Catalysis
2010 Standout
Asymmetric C–H functionalization of cyclopropanes using an isoleucine-NH2 bidentate directing group
2015
Room-Temperature Direct Arylation of Polyfluorinated Arenes under Biphasic Conditions
2010
A Meta-Selective Copper-Catalyzed C–H Bond Arylation
2009 Science
Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C–H Bond Cleavage
2012
Ruthenium(IV)‐Alkylidene als Katalysatorvorstufen für direkte Arylierungen von Alkenen mit Chlorarenen und eine Anwendung auf die sequenzielle Katalyse
2007
Hindered biaryls by C–H coupling: bisoxazoline-Pd catalysis leading to enantioselective C–H coupling
2012
Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents
2008
Asymmetric photocatalysis over robust covalent organic frameworks with tetrahydroquinoline linkage
2020
Catalyst and base controlled site-selective sp2 and sp3 direct arylation of azine N-oxides
2008
Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of the meta-Regioselectivity
2011
Pd-catalyzed oxidative cross-coupling between two electron rich heteroarenes
2013
Regioselective Ortho Olefination of Aryl Sulfonamide via Rhodium-Catalyzed Direct C–H Bond Activation
2014
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
2009 Standout
Palladium/2,2′-bipyridyl/Ag2CO3 catalyst for C–H bond arylation of heteroarenes with haloarenes
2011
Solar Synthesis: Prospects in Visible Light Photocatalysis
2014 StandoutScience
Funktionalisierung von C‐H‐Bindungen: neue Synthesemethoden für Naturstoffe und Pharmazeutika
2012
Highly efficient aerobic ruthenium-catalyzed oxidative cross-dehydrogenative coupling for sp3–sp3 carbon–carbon bond formation
2009
Palladium-catalyzed selective oxidative olefination and arylation of 2-pyridones
2012
Silanol: A Traceless Directing Group for Pd-Catalyzed o-Alkenylation of Phenols
2011
Allylic Carbon–Carbon Double Bond Directed Pd-Catalyzed Oxidative ortho-Olefination of Arenes
2012
Chemoselective Activation of sp3 vs sp2 C–H Bonds with Pd(II)
2014
Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines
2014
Palladium-catalyzed oxidative C–H/C–H cross-couplings of thiazolo[5,4-d]pyrimidine with aromatic (hetero)cycles
2014
Highly Efficient and Versatile Synthesis of Polyarylfluorenes via Pd-Catalyzed C−H Bond Activation
2009
New functionalized N‐heterocyclic carbene ligands for arylation of benzaldehydes
2009
Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids
2009
Iron-Catalyzed, Microwave-Promoted, One-Pot Synthesis of 9-Substituted Xanthenes by a Cascade Benzylation−Cyclization Process
2009
Phosphine-Free Palladium(II)-Catalyzed Arylation of Naphthalene and Benzene with Aryl Iodides
2008
Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes
2011
Palladium-catalyzed N-(2-pyridyl)sulfonyl-directed C(sp3)–H γ-arylation of amino acid derivatives
2012
Catalytic C–C coupling through C–H arylation of arenes or heteroarenes
2009
Dehydrative Direct Arylations of Arenes with Phenols via Ruthenium-Catalyzed C−H and C−OH Bond Functionalizations
2008
Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C−H Functionalization
2010
The Norbornene Shuttle: Multicomponent Domino Synthesis of Tetrasubstituted Helical Alkenes through Multiple CH Functionalization
2009
Palladium(II)-Catalyzed Dehydrogenative Alkenylation of Cyclic Enaminones via the Fujiwara–Moritani Reaction
2011
Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism
2008
Palladium N‐heterocyclic‐carbene‐catalyzed ortho‐arylation of benzaldehyde derivatives
2008
TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines
2009
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
Ligand-Promoted C-3 Selective C–H Olefination of Pyridines with Pd Catalysts
2011
Dual C–H activations of electron-deficient heteroarenes: palladium-catalyzed oxidative cross coupling of thiazoles with azine N-oxides
2012
A Catalytic, Brønsted Base Strategy for Intermolecular Allylic C−H Amination
2009
Room-Temperature Regioselective C−H/Olefin Coupling of Aromatic Ketones Using an Activated Ruthenium Catalyst with a Carbonyl Ligand and Structural Elucidation of Key Intermediates
2010
Total Syntheses of (−)-α-Kainic Acid and (+)-α-Allokainic Acid via Stereoselective C−H Insertion and Efficient 3,4-Stereocontrol
2007
Transition‐Metal‐Catalyzed Direct C–H Alkenylation, Alkynylation, Benzylation, and Alkylation of (Hetero)arenes
2010
Iron-catalyzed arylation of α-aryl-α-diazoesters
2016
Palladium‐Catalyzed/Lewis Acid‐Promoted Alkene Dimerization and Cross‐Coupling with Alcohols via CH Bond Activation
2008
Twofold C−H Functionalization: Palladium-Catalyzed Ortho Arylation of Anilides
2008
Direct ortho-arylation of 2-arylbenzoxazoles via C–H activation
2008
Modular Approach to Silicon‐Bridged Biaryls: Palladium‐Catalyzed Intramolecular Coupling of 2‐(Arylsilyl)aryl Triflates
2008
Rhodium-Catalyzed Mono- and Divinylation of 1-Phenylpyrazoles and Related Compounds via Regioselective C−H Bond Cleavage
2009
Nickel-Catalyzed Direct Arylation of Azoles with Aryl Bromides
2009
Oxindole Synthesis by Direct Coupling of CH and CH Centers
2009
Direct Arylation of Thiazoles on Water
2007
Copper-Catalyzed Oxidative Coupling of Benzylic C−H Bonds with 1,3-Dicarbonyl Compounds
2008
Pd(ii )-catalyzed C(sp3)–H arylation of amino acid derivatives with click-triazoles as removable directing groups
2015
Palladium-Catalyzed Regioselective Oxidative Coupling of Indoles and One-Pot Synthesis of Acetoxylated Biindolyls
2009
Regioselective Oxidative Arylation of Indoles Bearing N-Alkyl Protecting Groups: Dual C−H Functionalization via a Concerted Metalation−Deprotonation Mechanism
2010
Iron-Catalyzed Direct Arylation through Directed C−H Bond Activation
2008
Transition metal-free direct amination of benzoxazoles using formamides as nitrogen sources
2014
Total Synthesis of (±)-Kainic Acid: A Photochemical C–H Carbamoylation Approach
2011
Palladium(II)-Catalyzed Oxidative C–H/C–H Coupling and Eliminative SNH Reactions in Direct Functionalization of Imidazole Oxides with Indoles
2012
Pd-catalyzed dehydrogenative cross-coupling of pyridine-N-oxides with uracils
2014
Synthesis of Complex Allylic Esters via C−H Oxidation vs C−C Bond Formation
2010
Amine directed Pd(ii )-catalyzed C–H bond functionalization under ambient conditions
2010
Organometallic Approaches for Direct Modification of Peripheral CH Bonds in Porphyrin Cores
2013
A novel three-step synthesis of Celecoxib via palladium-catalyzed direct arylation
2011
Copper-Catalyzed Direct Sulfoximination of Azoles and Polyfluoroarenes under Ambient Conditions
2010
Mechanistic Analysis of Azine N-Oxide Direct Arylation: Evidence for a Critical Role of Acetate in the Pd(OAc)2 Precatalyst
2010
Synthesis of Functionalized Spiroindolines via Palladium-Catalyzed Methine C–H Arylation
2013
Challenge and progress: palladium-catalyzed sp3 C–H activation
2011
Nickel, Manganese, Cobalt, and Iron-Catalyzed Deprotonative Arene Dimerization
2010
Rhodium-Catalyzed One-Pot Synthesis of Substituted Pyridine Derivatives from α,β-Unsaturated Ketoximes and Alkynes
2007
Iron‐Catalyzed Nitrogen‐Directed Coupling of Arene and Aryl Bromides Mediated by Metallic Magnesium
2012
CH Functionalization/CN Bond Formation: Copper‐Catalyzed Synthesis of Benzimidazoles from Amidines
2008
An organic cation as a silver(i ) analogue for the arylation of sp2 and sp3 C–H bonds with iodoarenes
2014
High-Yielding, Versatile, and Practical [Rh(III)Cp*]-Catalyzed Ortho Bromination and Iodination of Arenes
2012
Preparation of indoles via iron catalyzed direct oxidative coupling
2010
Nickel-Catalyzed C–H/C–O Coupling of Azoles with Phenol Derivatives
2011
Wenn C‐H‐Bindungen sprechen könnten – selektive Oxidationen von C‐H‐Bindungen
2011
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
2011 Standout
Efficient Iron/Copper Cocatalyzed Alkynylation of Aryl Iodides with Terminal Alkynes
2008
Works of Mark E. Scott being referenced
Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis
2009
Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation
2007 Standout
Total Synthesis of (−)-(α)-Kainic Acid via a Diastereoselective Methylenecyclopropane Ring Expansion
2005