Standout Papers
- Solvolysis of 1-(p-cyclopropylphenyl)- and 1-(p-isopropylphenyl)-1-arylethyl chlorides. Test of the tool of increasing electron demand to systems with relatively small electronic response (1975)
- Solvolysis of 9-aryl-9-pentacyclo[4.3.0.02,4.03,8.05,7]nonyl p-nitrobenzoates. Unambiguous evidence for the presence of carbon participation by the application of the tool of increasing electron demand (1977)
- Structural effects in solvolytic reactions. 28. Solvolysis of 1-aryl-1-cyclopropyl 3,5-dinitrobenzoates containing strongly electron-supplying aryl groups. Evidence for two distinct reaction processes involving assisted (K.DELTA.) and unassisted (Kc) mechanisms (1978)
- Solvolysis of the 2-[3,5-bis(trifluoromethyl)phenyl]-2-norbornyl p-nitrobenzoates and the 1-arylcyclopentyl p-nitrobenzoates. Failure of a further increase in electron demand to alter the exo:endo rate ratio (1975)
- Structural effects in solvolytic reactions. 22. Effect of ring size on the stabilization of developing carbocations as revealed by the tool of increasing electron demand (1977)
- Structural effects in solvolytic reactions. 23. New .sigma.+ constants for activating substituents. The solvolysis of 1-aryl-1-cyclopropyl 3,5-dinitrobenzoates containing activating substituents in the aryl group. The tool of increasing electron demand and I-strain (1977)
- Structural effects in solvolytic reactions. 19. The relative electron releasing capability of methyl, phenyl, and cyclopropyl groups as measured by the tool of increasing electron demand (1977)
- Structural effects in solvolytic reactions. 26. A critical study of the effect of solvent on the exo:endo rate ratio in the solvolysis of 2-norbornyl derivatives. Evidence that the exo:endo rate ratio is not the result of K.DELTA./Ks processes (1978)
- Chemical effects of steric strains. 22. Rates of solvolysis of dimethyl(2-norbornyl)carbinyl p-nitrobenzoates and of the quaternization of 2-dimethylaminonorbornanes. A critical examination of the significance of steric factors in the chemistry of exo- and endo-norbornyl derivatives (1978)
- Structural effects in solvolytic reactions. 29. Solvolysis of tertiary allylic p-nitrobenzoates. Effect of the allylic double bond on the rates of solvolysis of representative tertiary p-nitrobenzoates (1978)
- Rates and products of solvolysis of 2-methyl-2-norbornenyl and 2,5-dimethyl-2-norbornenyl p-nitrobenzoates. Evidence for increasing .pi.-participation with increasing electron demand (1975)
- Structural effects in solvolytic reactions. 21. Solvolysis of 2-aryl-2-norbornyl and 2-aryl-2-camphenilyl p-nitrobenzoates. Critical examination of the importance of .sigma.-participation in the solvolysis of tertiary 2-norbornyl derivatives by the application of the tool of increasing electron demand (1977)
- Solvolysis of 2-aryl-2-bicyclo[2.1.1]hexyl p-nitrobenzoates. Evidence for the absence of .sigma.-participation by the application of the tool of increasing electron demand (1977)
- Structural effects in solvolytic reactions. 17. Solvolysis of 1-aryl-1-cyclopropyl-1-ethyl p-nitrobenzoates. Major increases in electron supply by the cyclopropyl group with increasing electron demand at the cationic center. Effect of substituents on the cyclopropane ring (1977)
- Structural effects in solvolytic reactions. 27. Solvolysis of the exo- and endo-1,2-diphenyl-2-norbornyl and -1,2-dimethyl-2-norbornyl p-nitrobenzoates and chlorides. Evidence for the classical nature of 1,2-disubstituted tertiary 2-norbonyl cations and structure of the parent 2-norbornyl cation (1978)
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