Standout Papers
Citation Impact
Citing Papers
Chiral Aziridines—Their Synthesis and Use in Stereoselective Transformations
1994
Computational Design of an Enzyme Catalyst for a Stereoselective Bimolecular Diels-Alder Reaction
2010 StandoutScienceNobel
Gating the Selectivity Filter in ClC Chloride Channels
2003 StandoutScienceNobel
Gold‐Catalyzed Regioselective Meyer–Schuster Rearrangement and Ring Expansion Cascade Leading to α‐Hydroxy‐α‐vinylcyclopentanones
2014
Oxindole Synthesis by Direct Coupling of CH and CH Centers
2009
Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis
2005 Standout
Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes
2013 Standout
Migratory Insertion of Alkenes into Metal–Oxygen and Metal–Nitrogen Bonds
2013
Decarboxylative alkenylation
2017 Nature
Demonstration by NMR of folding domains in lysozyme
1991 StandoutNatureNobel
Catalytic platinum-initiated cation-olefin reactions with alkene terminating groups
2013
Asymmetric Counteranion‐Directed Catalysis: Concept, Definition, and Applications
2012 StandoutNobel
Gold‐Catalyzed Intermolecular Addition of Carbonyl Compounds to 1,6‐Enynes
2007
Synthesis of (−)‐Okilactomycin by a Prins‐Type Fragment‐Assembly Strategy
2011
Reticular synthesis and the design of new materials
2003 StandoutNatureNobel
A supramolecular approach to combining enzymatic and transition metal catalysis
2013
Indoles from Simple Anilines and Alkynes: Palladium‐Catalyzed CH Activation Using Dioxygen as the Oxidant
2009
Green Chemistry: Principles and Practice
2009 Standout
Macrocyclic Ferrocenyl–Bisimidazoline Palladacycle Dimers as Highly Active and Enantioselective Catalysts for the Aza‐Claisen Rearrangement of Z‐Configured N‐para‐Methoxyphenyl Trifluoroacetimidates
2007
Catalyzed Asymmetric Arylation Reactions
2001
Highly controlled acetylene accommodation in a metal–organic microporous material
2005 StandoutNatureNobel
Unprecedented synergistic effects between weak Lewis and Brønsted acids in Prins cyclization
2012
An efficient synthesis of dihydro- and tetrahydropyrans via oxonium–ene cyclization reaction
2011
Oxazoline‐Mediated Interannular Cyclopalladation of Ferrocene: Chiral Palladium(II ) Catalysts for the Enantioselective Aza‐Claisen Rearrangement
2005
Non‐metathesis reactions of ruthenium carbene catalysts and their application to the synthesis of nitrogen‐containing heterocycles
2007
Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling
2009
“Designer Acids”: Combined Acid Catalysis for Asymmetric Synthesis
2005
Ruthenium‐Catalyzed Reactions—A Treasure Trove of Atom‐Economic Transformations
2005
Probing the mechanism of Prins cyclisations and application to the synthesis of 4-hydroxytetrahydropyrans
2005
Synthesis of Phenanthrenes and Polycyclic Heteroarenes by Transition‐Metal Catalyzed Cycloisomerization Reactions
2004
Gold(I)‐Catalyzed Highly Diastereo‐ and Enantioselective Alkyne Oxidation/Cyclopropanation of 1,6‐Enynes
2014
Integration of molecular and enzymatic catalysts on graphene for biomimetic generation of antithrombotic species
2014
Catalyst versus Substrate Induced Selectivity: Kinetic Resolution by Palladacycle Catalyzed Allylic Imidate Rearrangements
2010
Bicyclic Oxygen Heterocycles from γ,δ‐Unsaturated Alcohols: Synthetic Targets Inspired by Blepharocalyxin D
2012
A Highly Enantioselective Overman Rearrangement through Asymmetric Counteranion‐Directed Palladium Catalysis
2011 StandoutNobel
Gold(I)‐Catalyzed Cyclizations of Silyl Enol Ethers: Application to the Synthesis of (+)‐Lycopladine A
2006
Structural and functional insights into asymmetric enzymatic dehydration of alkenols
2017
Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality
2009 Standout
Enantioselective Formation of All‐Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group
2014
Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin‐Metathesis Catalysts
2003 StandoutNobel
NHC‐Capped Cyclodextrins (ICyDs): Insulated Metal Complexes, Commutable Multicoordination Sphere, and Cavity‐Dependent Catalysis
2013
An Investigation into the Allylic Imidate Rearrangement of Trichloroacetimidates Catalysed by Cobalt Oxazoline Palladacycles
2007
Recent advances in the stereoselective synthesis of tetrahydrofurans
2006
Asymmetric Formation of Allylic Amines with N‐Substituted Quaternary Stereocenters by PdII‐Catalyzed Aza‐Claisen Rearrangements
2007
Collective Synthesis of Cladiellins Based on the Gold‐Catalyzed Cascade Reaction of 1,7‐Diynes
2014
Enantioselective Oxidative Cross‐Coupling Reaction of 3‐Indolylmethyl CH Bonds with 1,3‐Dicarbonyls Using a Chiral Lewis Acid‐Bonded Nucleophile to Control Stereochemistry
2010
Enzymatic assembly of carbon–carbon bonds via iron-catalysed sp3 C–H functionalization
2018 StandoutNatureNobel
Oxidative demethylation by Escherichia coli AlkB directly reverts DNA base damage
2002 StandoutNatureNobel
Rapid stereocontrolled assembly of the fully substituted C-aryl glycoside of kendomycin with a Prins cyclization: a formal synthesis
2006
Prins Cyclizations in Au‐Catalyzed Reactions of Enynes
2006
Gold‐Catalyzed Intermolecular Addition of Carbonyl Compounds to 1,6‐Enynes: Reactivity, Scope, and Mechanistic Aspects
2009
Collective synthesis of natural products by means of organocascade catalysis
2011 Nature
Gold‐ or Platinum‐Catalyzed Cascade Processes of Alkynol Derivatives Involving Hydroalkoxylation Reactions Followed by Prins‐Type Cyclizations
2009
Click Chemistry: Diverse Chemical Function from a Few Good Reactions
2001 StandoutNobel
Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies
2011
1,2‐Alkyl Migration as a Key Element in the Invention of Cascade Reactions Catalyzed by π‐Acids
2008
Total Synthesis of (+)‐Gliocladin C Enabled by Visible‐Light Photoredox Catalysis
2011
Palladium‐Catalyzed Selective Anti‐Markovnikov Oxidation of Allylic Esters
2013 StandoutNobel
A Concise Formal Total Synthesis of (��)-Strychnine by Using a Transannular Inverse-Electron-Demand Diels���Alder Reaction of a [3](1,3)Indolo[3](3,6)pyridazinophane
2002
Palladium‐Catalyzed Intermolecular Alkenylation of Indoles by Solvent‐Controlled Regioselective CH Functionalization
2005
Palladium‐Catalyzed anti‐Markovnikov Oxidation of Terminal Alkenes
2014 StandoutNobel
One‐Pot Enantioselective Aziridination of Olefins Catalyzed by a Copper(I ) Complex of a Novel Diimine Ligand by Using PhI(OAc)2 and Sulfonamide as Nitrene Precursors
2006
Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
2010 StandoutNobel
Stereoselective synthesis of tetracyclic indolines via gold-catalyzed cascade cyclization reactions
2011
A Catalytic Asymmetric 6 π Electrocyclization: Enantioselective Synthesis of 2‐Pyrazolines
2009 StandoutNobel
Enantioselective Tsuji Allylations
2007
Iridium‐Catalyzed Enantioselective Synthesis of Allylic Alcohols: Silanolates as Hydroxide Equivalents
2006
Assembly of fused indenesvia Au(i )-catalyzed C1–C5 cyclization of enediynes bearing an internal nucleophile
2012
Synthesis of Nearly Enantiopure Allylic Amines by Aza‐Claisen Rearrangement of Z‐Configured Allylic Trifluoroacetimidates Catalyzed by Highly Active Ferrocenylbispalladacycles
2007
Practical, Highly Active, and Enantioselective Ferrocenyl–Imidazoline Palladacycle Catalysts (FIPs) for the Aza‐Claisen Rearrangement of N‐para‐Methoxyphenyl Trifluoroacetimidates
2006
The Asymmetric Aza‐Claisen Rearrangement: Development of Widely Applicable Pentaphenylferrocenyl Palladacycle Catalysts
2009
Total synthesis of the Daphniphyllum alkaloid daphenylline
2013
Tuning the Reactivity of Oxygen/Sulfur by Acidity of the Catalyst in Prins Cyclization: Oxa- versus Thia-Selectivity
2014
The Organocatalytic Asymmetric Prins Cyclization
2015 StandoutNobel
Allylic Imidate Rearrangements Catalyzed by Planar Chiral Palladacycles
2010
Enantioselective Allylation of Aromatic Amines after In Situ Generation of an Activated Cyclometalated Iridium Catalyst
2004
Catalyzed Tandem Reaction of 3‐Silyloxy‐1,5‐enynes Consisting of Cyclization and Pinacol Rearrangement
2007
Versatile Access to Chiral Indolines by Catalytic Asymmetric Fischer Indolization
2013 StandoutNobel
The B-Alkyl Suzuki-Miyaura Cross-Coupling Reaction: Development, Mechanistic Study, and Applications in Natural Product Synthesis
2001
Palladium-catalysed polycyclisation-anion capture processes
1990
Die organokatalytische asymmetrische Prins‐Cyclisierung
2015 StandoutNobel
Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products
2010 Standout
TMSBr/InBr3-promoted Prins cyclization/homobromination of dienyl alcohol with aldehyde to construct cis-THP containing an exocyclic E-alkene
2015
Asymmetric synthesis of chiral ferrocenyl fulleropyrrolidines as potential building blocks for new materials
2001
Racemization in Prins Cyclization Reactions
2006
Suzuki–Miyaura Cross‐Coupling Reactions of Alkylboronic Acid Derivatives or Alkyltrifluoroborates with Aryl, Alkenyl or Alkyl Halides and Triflates
2008
Alkylpalladium(II) species. Reactive intermediates in a bis-cyclisation route to strained polyfused ring systems.
1991
Intramolecular Dipolar Cycloaddition Reactions of Azomethine Ylides
2005
Total Synthesis of the Teicoplanin Aglycon
2000
Synthesis of bridged azabicyclic compounds using radical translocation reactions of 1-(o-bromobenzoyl)-2-(prop-2-enyl)pyrrolidines
1995
Studies toward the Total Synthesis of the Oxindole Alkaloid Gelsedine: An Efficient Allene-Terminated N-Acyliminium Ion Cyclization
1997
Copper Catalyzed Asymmetric Synthesis of Chiral Allylic Esters
2006 StandoutNobel
Rhodium-Catalyzed Regio- and Enantioselective Addition of N-Hydroxyphthalimide to Allenes: A Strategy To Synthesize Chiral Allylic Alcohols
2017
Total synthesis of (ent)-korupensamine D
1996
Enantioselective Thiourea-Catalyzed Cationic Polycyclizations
2010
Palladium-catalyzed polycyclizations of substituted dienynes: Stereoselective routes to highly complex polycycles
1992
Bicyclic Oxygen Heterocycles from γ,δ‐Unsaturated Alcohols: Synthetic Targets Inspired by Blepharocalyxin D
2012
Diastereofacial selectivity in azomethine ylide cycloaddition reactions derived from chiral α-cyanoaminosilanes
1985
Intramolecular carbometallation of organozinc reagents.
1994
Sequenced reactions with samarium(II) iodide
1998
α-N-acyliminium ion - 2-bromoalkene cyclizations.
1993
Chemistry of Polyvalent Iodine
2008 Standout
The Thionium/N-Acyliminium Ion Cyclization Cascade as a Strategy for the Synthesis of Azapolycyclic Ring Systems
2000
Primary Amine, Thiourea-Based Dual Catalysis Motif for Synthesis of Stereogenic, All-Carbon Quaternary Center-Containing Cycloalkanones
2012
Stereochemical features of oxidative mannich cyclizations of vinyl- and allyl-silane containing α-silyl-amines and -amides
1996
Asymmetric Synthesis of Carboxylic Acid Derivatives Having an All-Carbon α-Quaternary Center through Cu-Catalyzed 1,4-Addition of Dialkylzinc Reagents to 2-Aryl Acetate Derivatives
2008
Intermediates in the Intermolecular, Asymmetric Heck Arylation of Dihydrofurans
1997
Enantioselective Prins cyclization: BINOL-derived phosphoric acid and CuCl synergistic catalysis
2014
Natural Product Synthesis Using Multicomponent Reaction Strategies
2009 Standout
Studies Dealing with Thionium Ion Promoted Mannich Cyclization Reactions
2000
An oxidative coupling for the synthesis of arylated quaternary stereocentres and its application in the total synthesis of powelline and buphanidrine
2010
Enantioselective synthesis of a key tricyclic intermediateen route to (+)-gelsemine
1999
Silver-Mediated Synthesis of Heterocycles
2008
Mechanistic and synthetic aspects of amine-enone single electron transfer photochemistry
1992
Contemporary Carbocation Chemistry: Applications in Organic Synthesis
2013
Intramolecular Electrophilic Cyclization of Doubly Activated Imines Induced by Lewis Acids and Trialkylsilyl Triflates. An Efficient Route to Substituted Piperidines and Annulated Piperidine Lactones
1989
Enantioselective Formation of All‐Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group
2014
Regioselective synthesis of (±)-gabaculine
1986
Intermolecular Hydroamination of Allenes with N-Unsubstituted Carbamates Catalyzed by a Gold(I) N-Heterocyclic Carbene Complex
2008
Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex: Catalytic activity of the di-Rh and CCC–NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes
2005
Stereoselective Synthesis of Vinylsilanes by a Gold(I)-Catalyzed Acetylenic Sila-Cope Rearrangement
2006
Tandem carbophilic addition-N-acyliminium ion cyclization for the synthesis of functionalized pyrrolo[2,1-a]isoquinolones: Key intermediates for the preparation of Erythrina-type alkaloids
1996
Air- and Water-Stable Catalysts for Hydroamination/Cyclization. Synthesis and Application of CCC−NHC Pincer Complexes of Rh and Ir
2008
Intramolecular Heck-type reactions in aqueous medium. Dramatic change in regioselectivity
1996
Diastereoselective Synthesis of Enantioenriched, Annulated Tetrahydrofurans by Simultaneous Formation of the O‐1C‐5 and the C‐5C‐4 Bonds
2005
The palladium-catalysed arylation and vinylation of alkenes—enantioselective fashion
1999
Stereochemical Control in Organic Synthesis Using Silicon-Containing Compounds
1997
Confinement as a Unifying Element in Selective Catalysis
2020 StandoutNobel
Experimental Determination of the Absolute Enantioselectivity of an Antibody-Catalyzed Diels−Alder Reaction and Theoretical Explorations of the Origins of Stereoselectivity
2003
Strategies for the Total Synthesis of C2−C11 Cyclized Cembranoids
2008
Eight membered ethers via diene metathesis: Synthetic approach to laureatin natural products
1999
Katalysierte asymmetrische Arylierungen
2001
Stereoselective Synthesis of cis- and trans-2,3-Disubstituted Tetrahydrofurans via Oxonium−Prins Cyclization: Access to the Cordigol Ring System
2010
The Silylalkyne-Prins Cyclization: Stereoselective Synthesis of Tetra- and Pentasubstituted Halodihydropyrans
2006
A General Catalytic Asymmetric Prins Cyclization
2016 StandoutNobel
N-Acyliminium ion cyclisation versus rearrangement. The synthesis of 13,13-dimethylberberines and 3,4-dimethylisoquinolin-1-ones
2000
Graphene-Based Nanomaterials as Efficient Peroxidase Mimetic Catalysts for Biosensing Applications: An Overview
2015
Intramolecular reactions of N-acyliminium intermediates
1985 Standout
Branch-Selective Hydroarylation: Iodoarene–Olefin Cross-Coupling
2016
The Potential of Palladacycles: More Than Just Precatalysts
2005
Completely OH-Selective FeCl3-Catalyzed Prins Cyclization: Highly Stereoselective Synthesis of 4-OH-Tetrahydropyrans
2012
Samarium(II)-Iodide-Mediated Cyclizations in Natural Product Synthesis
2004 Standout
Ag-Mediated Reactions: Coupling and Heterocyclization Reactions
2008
Diverse Cyclization Catalyzed by In(OTf)3 for the Convergent Assembly of Substituted Tetrahydrofurans and Tetrahydropyrans
2001
Fine Feathers Make Fine Birds: The Heck Reaction in Modern Garb
1995
Synthesis and Diastereoselectiveortho-Lithiation/Cyclopalladation of Enantiopure [2-Imidazolyl]-1‘,2‘,3‘,4‘,5‘-pentamethylferrocenes and -1‘,2‘,3‘,4‘,5‘-pentaphenylferrocenes
2006
Gold-catalyzed reactivity of 3-silyloxy-1,5-enynes: a synthetic tool for the synthesis of complex structures and its limitations
2008
Stereocontrol in the synthesis of acyclic systems: applications to natural product synthesis
1980 Standout
Synthesis of cyclic α-hydrazino acid derivatives via N-acylhydrazonium ions
1993
Pd-Catalyzed Enantioselective Hydroalkoxylation of Alkoxyallenes with Phenol for Construction of Acyclic O,O-Acetals
2015
Enantioselective Synthesis of Pyrroloindolines via Noncovalent Stabilization of Indole Radical Cations and Applications to the Synthesis of Alkaloid Natural Products
2018
Palladium-Mediated Cyclization on Carbohydrate Templates. 1. Synthesis of Enantiopure Bicyclic Compounds
1997
[(NHC)AuI]-Catalyzed Rearrangement of Allylic Acetates
2007
A total synthesis of gelsemine: synthesis of a key tetracyclic intermediate
1994
Synthesis of the C22−C26 Tetrahydropyran Segment of Phorboxazole by a Stereoselective Prins Cyclization
2000
The Reincarnation of the Hieber Anion [Fe(CO)3(NO)]– – a New Venue in Nucleophilic Metal Catalysis
2008
Recent applications of the Suzuki–Miyaura cross-coupling reaction in organic synthesis
2002 Standout
Catalytic Asymmetric Prins Bicyclization for the endo‐Selective Formation of 2,6‐dioxabicyclo[2.2.2]octanes
2016
Palladium-Catalyzed Anti-Markovnikov Oxidation of Allylic Amides to Protected β-Amino Aldehydes
2014 StandoutNobel
Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions
2000
An Enantioselective Total Synthesis and Stereochemical Revision of (+)-Citrinadin B
2013
Novel Pt(II) Mono- and Biscarbene Complexes: Synthesis, Structural Characterization and Application in Hydrosilylation Catalysis
2009
Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners
2011 Standout
Synthesis of new annelated indole systems: New entry in the E-azaeburnane series
1995
Carbon−Carbon Bond Forming Reactions Mediated by Silicon Lewis Acids
2003 Standout
Enantioselective Allylation of Aromatic Amines after In Situ Generation of an Activated Cyclometalated Iridium Catalyst
2004
Practical Methodologies for the Synthesis of Indoles
2006 Standout
Diastereoselective Synthesis of Polysubstituted Tetrahydropyrans and Thiacyclohexanes via Indium Trichloride Mediated Cyclizations1
2001
Synthesis and Functionalization of Indoles Through Palladium-catalyzed Reactions
2005 Standout
Gold Approaches to Polycyclic Indole Alkaloids
2014
Intermolecular Enolate Heterocoupling: Scope, Mechanism, and Application
2008
Metal‐Catalyzed Asymmetric Michael Addition in Natural Product Synthesis
2016
Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions
2008
Synthesis of (−)‐Okilactomycin by a Prins‐Type Fragment‐Assembly Strategy
2011
Tandem Pummerer/Mannich Cyclization Cascade of α-Sulfinylamides as a Method To Prepare Aza-Heterocycles
2002
Generation and intramolecular cationic cyclizations of N-tosylimines derived from enolizable aldehydes
1988
The bis(homoallylic) stabilisation of an acyliminium ion and reactions with nucleophiles
1998
Ni-promoted Cyclopentenone Formation by Intramolecular Cyclocarbonylation of 1-Bromo-1,4-dienes
1993
Recent developments in indole ring synthesis—methodology and applications
2000 Standout
Enantioselective Cyclizations of Silyloxyenynes Catalyzed by Cationic Metal Phosphine Complexes
2012
Asymmetric catalysis in complex target synthesis
2004
The synthesis of thiols, selenols, sulfides, selenides, sulfoxides, selenoxides, sulfones and selenones
2001
Synthesis of 7-Epi (+)-FR900482: An Epimer of Comparable Anti-Cancer Activity
2008
Gold(I)-Catalyzed Enantioselective Polycyclization Reactions
2010
Influence of a Very Bulky N-Heterocyclic Carbene in Gold-Mediated Catalysis
2011
Desymmetrization construction of chiral lactones by synergistic Cu(II) complex and organic base
2020
Experimental studies of protein folding and unfolding
1979
Electrophilic Pt(II) Complexes: Precision Instruments for the Initiation of Transformations Mediated by the Cation–Olefin Reaction
2014
A Short Diastereoselective Synthesis of the Putative Alkaloid Jamtine, Using a Tandem Pummerer/Mannich Cyclization Sequence
2003
Pd(II)-Catalyzed Enantioselective C−H Olefination of Diphenylacetic Acids
2009
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Synthesis and Properties of Cationic Organopalladium Complexes. Remarkable Rate Enhancement in Olefin Insertion into the Palladium–Aryl Bond by the Generation of a Cationic Palladium Complex from trans-[PdBr(Ph)(PMe3)2]
1995
Total Synthesis of Michellamines A−C, Korupensamines A−D, and Ancistrobrevine B
1999
Highly Stereoselective Synthesis of 2,5-Disubstituted 3-Vinylidene Tetetrahydrofurans via Prins-Type Cyclization
2005
Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N3Pt2+ Catalysts
2014
Symmetric Macrocycles by a Prins Dimerization and Macrocyclization Strategy
2009
Transition metal-catalysed organic reactions promoted by chelating or metallacycle-forming substrates
1995
Enantioselective Gold-Catalyzed Synthesis of Polycyclic Indolines
2012
N-acyliminium ions: detection of a hidden 2-aza-cope rearrangement
1981
Operationally Simple, Efficient, and Diastereoselective Synthesis of cis-2,6-Disubstituted-4-Methylene Tetrahydropyrans Catalyzed by Triflic Acid
2006 Nobel
Control of the exo and endo Pathways of the Diels-Alder Reaction by Antibody Catalysis
1993 Science
Synthesis of Enantiopure Estrone via a Double Heck Reaction
1998
Cascade Processes of Metallo Carbenoids
1996 Standout
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
2009 Standout
Molecular Structure and Physiological Function of Chloride Channels
2002
Radical Cyclization by Ipso Substitution of the Methoxy Group: Considerable Effect of HMPA on Samarium-Mediated Cyclization
2003
Construction of Azaspirocyclic Ketones through α-Hydroxyiminium Ion or α-Siloxy Epoxide Semipinacol Rearrangements
2001
A Sakurai−Prins−Ritter Sequence for the Three-Component Diastereoselective Synthesis of 4-Amino Tetrahydropyrans
2006
Polyammonium macrocycles as catalysts for phosphoryl transfer: the evolution of an enzyme mimic
1990
Highly Stereoselective Prins Cyclization of Silylmethyl-Substituted Cyclopropyl Carbinols to 2,4,6-Trisubstituted Tetrahydropyrans
2004
Circular Dichroism and Magnetic Circular Dichroism Spectroscopic Studies of the Non-Heme Ferrous Active Site in Clavaminate Synthase and Its Interaction with α-Ketoglutarate Cosubstrate
1998
Palladium-Catalyzed Allylic Amination Using Aqueous Ammonia for the Synthesis of Primary Amines
2009
Enantioselective Construction of Spirocyclic Oxindolic Cyclopentanes by Palladium-Catalyzed Trimethylenemethane-[3+2]-Cycloaddition
2007
Characterization of Reactive Intermediates in Palladium‐Catalyzed Arylation of Methyl Acrylate (Heck Reaction)
1996
Alkyne hydrosilylation catalyzed by nickel complexes of N-heterocyclic carbenes
2006
Topological Ideas in Stereochemistry
1973
Cobalt-catalyzed benzyl–alkynyl coupling
2006
A Complex Catalytic Cycle Leading to a Regioselective Synthesis of o,o′‐Disubstituted Vinylarenes
1997
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Dramatic Increase of Turnover Numbers in Palladium-Catalyzed Coupling Reactions Using High-Pressure Conditions
1996
Conjugate addition of amines and thiols to (R)-1-acetyl-5-isopropoxy-3-pyrrolin-2-one; Preparation of enantiopure N-acyliminium ion precursors
1993
A convergent synthesis of the trans-fused hexahydrooxonine ring system and reproduction of conformational behavior shown by ring F of ciguatoxin
1999
Synthesis of spirooxindoles via asymmetric 1,3-dipolar cycloaddition
2005
Biomimetic Reactions Catalyzed by Cyclodextrins and Their Derivatives
1998
A novel tandem ene/Prins cyclization for the synthesis of octahydropyrano[2,3-c]pyrrole derivatives
2012
Synthesis of (±)-hirsutene by a catalytic allylpalladium-alkyne cyclization/carbonylation cascade
1994
Hydrosilylation of Alkynes Mediated by N-Heterocyclic Carbene Platinum(0) Complexes
2006
Diastereoselective Synthesis of Dihydropyrans via Prins Cyclization of Enol Ethers: Total Asymmetric Synthesis of (+)-Civet Cat Compound
2013
Highly Enantioselective Ag(I)-Catalyzed [3 + 2] Cycloaddition of Azomethine Ylides
2002
Convergent Approach to Pumiliotoxin Alkaloids. Asymmetric Total Synthesis of (+)-Pumiliotoxins A, B, and 225F
2002
Praktikable, hochaktive und enantioselektive Ferrocenyl‐Imidazolin‐Palladacyclus(FIP)‐Katalysatoren für die Aza‐Claisen‐Umlagerung von N‐para‐Methoxyphenyltrifluoracetimidaten
2006
Efficient heterocyclisation via 2-aza-cope rearrangements of α-acyliminium intermediates. Formation of pyrrolizidines and somel thia-analogues
1982
First and Second Generation Total Synthesis of the Teicoplanin Aglycon
2001
Iridium‐Catalyzed Enantioselective Synthesis of Allylic Alcohols: Silanolates as Hydroxide Equivalents
2006
A Highly Enantioselective Intramolecular Heck Reaction with a Monodentate Ligand
2001 StandoutNobel
Application of the β-azidonation reaction to the synthesis of the antitumor alkaloid (+)-pancratistatin
1998
Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids
2011
An Oxidative Prins Cyclization Methodology
2000
Electrophilic Cyclization of Doubly Activated Imines with Lewis Acids and Trialkylsilyl Triflates Synthesis of Pyrrole and Azepine Derivatives
1989
Synthetic Aspects of Metal‐Catalyzed Oxidations of Amines and Related Reactions
1995
Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit
2009
High‐Turnover Palladium Catalysts in Cross‐Coupling and Heck Chemistry: A Critical Overview
2004
All-Carbon Quaternary Centers via Catalytic Asymmetric Hydrovinylation. New Approaches to the Exocyclic Side Chain Stereochemistry Problem
2006
Generation and utilization of carbonyl ylides via the tandem cyclization-cycloaddition method
1991
Metal-Mediated Synthesis of Medium-Sized Rings
2000
New Developments in the Chemistry of N-Acyliminium Ions and Related Intermediates
2000 Standout
A Kulinkovich Entry into Tertiary N-Acyliminium Ion Chemistry
1999
Three-component synthesis of 2-aryl-4-arylthio-tetrahydro-2H-pyrans via the Prins-cyclization
2009
Intramolecular Heck Reaction for the Synthesis of Isochromanes under Ambient and High pressure
1997
Gold(I)-Catalyzed Tandem Cyclization Approach to Tetracyclic Indolines
2010
Direct and Regioselective C−H Alkenylation of Tetrahydropyrido[1,2-a]pyrimidines
2009
Stereoselective One-Pot, Three-Component Synthesis of 4-Aryltetrahydropyran via Prins−Friedel−Crafts Reaction
2009
Synthesis of medium ring ethers. Part 2. Synthesis of the fully saturated carbon skeleton of Laurencia non-terpenoid ether metabolites containing seven-, eight- and nine-membered rings
1992
Acyclic Aminocarbenes in Catalysis
2012
Asymmetrische Synthese von Allylaminen mit N‐substituierten quartären Stereozentren durch Palladium(II)‐katalysierte Aza‐Claisen‐Umlagerungen
2007
Aiming for the Ideal Synthesis
2010
Axial-Selective Prins Cyclizations by Solvolysis of α-Bromo Ethers
2004
Stereoselective Construction of Quaternary Stereocenters
2005
Palladiumkatalysierte Kreuzkupplungen in der Totalsynthese
2005
Chirale Aziridine — Herstellung und stereoselektive Transformationen
1994
Organic Chemistry on Solid Supports
1996
Chelating diphosphine–palladium(ii) dihalides; outstandingly good catalysts for Heck reactions of aryl halides
1998
Trimethylsilyl triflate catalysed Diels-Alder reaction of TMS ethers of conjugated dienols with cyclic enones: Evidence for an endo transition state, and first application to synthesis of enantiopure octalins
1999
Palladium-catalyzed cycloisomerizations of enynes and related reactions
1990
Recent Developments and New Perspectives in the Heck Reaction
1995
Diastereoselective Synthesis of Substituted Tetrahydrofurans via Prins Cyclization of Enol Ethers
2014
Prins Cyclizations: Labeling Studies and Application to Natural Product Synthesis
2002
Regio‐ and Enantioselective Silane‐Terminated Intramolecular Heck Reactions
1994
Total Synthesis of (±)-Rhazinal Using Novel Palladium-Catalyzed Cyclizations
2009
Organische Chemie an fester Phase
1996
An Organocatalytic Oxidative Coupling Strategy for the Direct Synthesis of Arylated Quaternary Stereogenic Centers
2007
Recent advances in the synthetic applications of the oxazaborolidine-mediated asymmetric reduction
2006
Makrocyclische Ferrocenyl‐Bisimidazolin‐Palladacyclus‐Dimere als hoch aktive und enantioselektive Katalysatoren für die Aza‐Claisen‐Umlagerung von Z‐konfigurierten N‐para‐Methoxyphenyltrifluoracetimidaten
2007
From Understanding to Prediction: Gold- and Platinum-Based π-Acid Catalysis for Target Oriented Synthesis
2013
Biomimetic Chemistry and Artificial Enzymes: Catalysis by Design
1995
Cyclizations of N-Acyliminium Ions
2004 Standout
Rh-catalyzed alkene oxidation: a highly efficient and selective process for preparing N-alkoxysulfonyl aziridines
2006
Molecular Borromean Rings
2004 StandoutScienceNobel
Ruthenium Carbene Complexes with N,N‘-Bis(mesityl)imidazol-2-ylidene Ligands: RCM Catalysts of Extended Scope
2000
Recent Developments in the Chemistry of Polyvalent Iodine Compounds
2002
Rearrangements of N-acyl-2-aza-1,5-hexadienes: application to synthesis of traechelanthamidine and supinidine
1982
Lewis acid-mediated cyclizations of (2′-amino-N′-tert-butoxycarbonyl-benzylidene)-3-alkenylamines
1998
Total Synthesis of (±)-Jamtine Using a Thionium/N-Acyliminium Ion Cascade
2002
Diels−Alder Reactions of N-Acyl-2-alkyl(aryl)-5-vinyl-2,3-dihydro-4-pyridones
2005
Stereoselectivity and Regioselectivity in the Segment-Coupling Prins Cyclization
2001
Asymmetric Catalysis with CO2: The Direct α‐Allylation of Ketones
2016 StandoutNobel
A Novel Synthesis of Enantiopure Octahydropyrrolo[3,4-b]pyrroles by Intramolecular [3 + 2] Dipolar Cycloaddition on Chiral Perhydro-1,3-benzoxazines
2002
Synthesis of (−)-Centrolobine by Prins Cyclizations that Avoid Racemization
2002
Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis
2010
Gold-catalyzed spiro-N,O-ketal synthesis
2014
Unique one step, multicomponent α,β,β-oxidations of carbamates with Willgerodt-like hypervalent iodine reagents—an example of triple C–H bond activation
2005
Novel synthetic approach to carbapenems utilizing aza-Cope Mannich cyclization
1995
Asymmetric Total Syntheses of Tuberostemonine, Didehydrotuberostemonine, and 13-Epituberostemonine
2004
C−C, C−O, C−N Bond Formation on sp2 Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents
2007
Sequential Catalytic Isomerization and Allylic Substitution. Conversion of Racemic Branched Allylic Carbonates to Enantioenriched Allylic Substitution Products
2006
Strategic innovation in the total synthesis of complex natural products using gold catalysis
2014
Asymmetric synthesis of the core structure of the Melodinus alkaloids
1999
A facile and efficient stereoselective synthesis of 6-hydroxy--4a-phenyldecahydroisoquinoline
1983
IDPi Catalysis
2019 StandoutNobel
Direct Cross-Coupling Reaction of Simple Alkenes with Acrylates Catalyzed by Palladium Catalyst
2009
Construction of Enantiopure Pyrrolidine Ring System via Asymmetric [3+2]-Cycloaddition of Azomethine Ylides
2006 Standout
First Total Synthesis of ent-Gelsedine via a Novel Iodide-Promoted Allene N-Acyliminium Ion Cyclization
2000
Enantioselective Synthesis of Polycyclic Carbocycles via an Alkynylation–Allylation–Cyclization Strategy
2014
Palladium-Catalyzed Asymmetric Decarboxylative Lactamization of γ-Methylidene-δ-valerolactones with Isocyanates: Conversion of Racemic Lactones to Enantioenriched Lactams
2008
Stereoselective Total Syntheses of the Racemic Form and the Natural Enantiomer of the Marine Alkaloid Lepadiformine via a Novel N-Acyliminium Ion/Allylsilane Spirocyclization Strategy
2002
Catalytic Coupling of Arene C–H Bonds and Alkynes for the Synthesis of Coumarins: Substrate Scope and Application to the Development of Neuroimaging Agents
2012
Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-Transfer Conditions
2013
Palladium-catalyzed α-arylation of vinyl butyl ether with aryl halides
1991
Cationic NHC–gold(I) complexes: Synthesis, isolation, and catalytic activity
2008
Samarium(II)-Promoted Radical Spirocyclization onto an Aromatic Ring
2003
Concise, Asymmetric Total Synthesis of Spirotryprostatin A
2003
[Pd/Base/QX] catalyst systems for directing Heck-type reactions
1998
Allylic Amination
1998
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Rhenium(VII) Catalysis of Prins Cyclization Reactions
2008
Ni ion-containing ionic liquid salt and Ni ion-containing immobilized ionic liquid on silica: Application to Suzuki cross-coupling reactions between chloroarenes and arylboronic acids
2006
On the Role of Silver Salts in Asymmetric Heck-type Reaction. A Greatly Improved Catalytic Asymmetric Synthesis of cis-Decalin Derivatives
1990
Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters
2011
Diastereo‐ and Regioselective Intramolecular Heck Reaction of α‐Amino Alcohol Derivatives for the Synthesis of Enantiomerically Pure Isoquinolines and Benzazepines at Ambient and High Pressure
1997
Sequential Transformations in Organic Chemistry: A Synthetic Strategy with a Future
1993
Gold(I)‐Catalyzed Reactions of 1‐(ortho‐Alkynylaryl)ureas: Highly Selective Heterocyclization and Synthesis of Mixed N,O‐Acetals
2014
Asymmetric, stereocontrolled total synthesis of (+) and (−)-spirotryprostatin B via a diastereoselective azomethine ylide [1,3]-dipolar cycloaddition reaction
2002
Azomethine Ylide Cycloaddition/Reductive Heterocyclization Approach to Oxindole Alkaloids: Asymmetric Synthesis of (−)-Horsfiline
2001
Gold(I)-Catalyzed Intramolecular Hydroamination of Alkyne with Trichloroacetimidates
2006
Syntheses of piperidine and perhydroazepine derivatives, precursors of two selective antagonists of muscarinic M2 receptors: AF-DX 384 and its perhydroazepine isomer
1996
Claisen Rearrangement over the Past Nine Decades
2004
Iron(III)-Catalyzed Prins-Type Cyclization Using Homopropargylic Alcohol: A Method for the Synthesis of 2-Alkyl-4-halo-5,6-dihydro-2H-pyrans
2003
Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism
2010
Formic acid-induced π-cyclization of glycine cation equivalents to substituted pipecolic acid derivatives
1991
Chiral Calcium VAPOL Phosphate Mediated Asymmetric Chlorination and Michael Reactions of 3-Substituted Oxindoles
2011
Synthesis of Indolizidine and Quinolizidine Derivatives via Intramolecular Cyclization of Alkynyltungsten Compounds with N-Acyliminium Ion
2001
Alternate Heme Ligation Steers Activity and Selectivity in Engineered Cytochrome P450-Catalyzed Carbene-Transfer Reactions
2018 StandoutNobel
Enantioselective Synthesis of 3,3-Disubstituted Oxindoles through Pd-Catalyzed Cyanoamidation
2008
Generation and Trapping of N-Acyliminium Ions Derived from Isomünchnone Cycloadducts. A Versatile Route to Functionalized Heterocycles
1999
Asymmetric synthesis by metal BINAP catalysts
1995
Enantioselective Fujiwara–Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)–NicOx Complexes
2009
Asymmetrische Gegenanionen‐vermittelte Katalyse: Konzept, Definition und Anwendungen
2012 StandoutNobel
Stereoselective Total Syntheses of Three Lycopodium Alkaloids, (−)-Magellanine, (+)-Magellaninone, and (+)-Paniculatine, Based on Two Pauson−Khand Reactions
2007
Monodentate phosphoramidites; versatile ligands in catalytic asymmetric intramolecular Heck reactions
2003 StandoutNobel
Variations on a theme—recent developments on the mechanism of the Heck reaction and their implications for synthesis
1998
Synthesis of the Tricyclic Core of Sarain A. Use of Formaldehyde in an Intramolecular Grigg Azomethine Ylide Cyclization
1998
Oxonia-Cope Rearrangement and Side-Chain Exchange in the Prins Cyclization
2002
Synthesis of the perhydroindole nucleus by a Pummerer/Mannich induced cyclization cascade
1998
Recent developments in alkaloid synthesis
1981
Total Synthesis and Absolute Stereochemical Assignment of (−)-Communesin F
2010
Cyclisation d'allyl silanes. Une voie d'acces efficace aux squelettes indolizidine et quinolizidine.
1985
Modified BINOL Ligands in Asymmetric Catalysis
2003
A novel synthetic route to 6‐azabicyclo[3.2.1]oct‐3‐enes via silicon directed N‐Acyliminium chemistry: Synthesis of (±)‐gabaculine
1986
Enantioselective Rhodium‐Catalyzed Atom‐Economical Macrolactonization
2016
Synthesis of Enantiopure Functionalized Pipecolic Acids via Amino Acid DerivedN-Acyliminium Ions
1999
The total synthesis of (±)-gelsemine
1994
Heck reactions: a caveat on the use of palladium(II) PCP-type catalysts
1999
Construction of fused oxonene ring and reproduction of conformational behavior shown by ring F of ciguatoxin
1997
Tin tetrachloride-induced π-cyclizations of glycine cation equivalents to substituted pipecolic acid derivatives
1991
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
2000 Standout
Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
2008 StandoutNobel
Oxazoline‐Mediated Interannular Cyclopalladation of Ferrocene: Chiral Palladium(II ) Catalysts for the Enantioselective Aza‐Claisen Rearrangement
2005
Highly Enantioselective Biginelli Reaction Catalyzed by Double Axially Chiral Bisphosphorylimides
2013
Stereoselective Total Synthesis of Natural (+)-Streptazolin via a Palladium-Catalyzed Enyne Bicyclization Approach
1996
Electronic Fine‐Tuning of Carbene Ligands and its Impact on Gold Catalysis
2011
Utilization of an Oxonia-Cope Rearrangement as a Mechanistic Probe for Prins Cyclizations
2005
Electrophilic Aromatic Substitution on Pyridine Rings. Intramolecular Cyclization Using N-Acyliminium Ions
1997
Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds
1996 StandoutNobel
An approach to the synthesis of gelsemine: the intramolecular reaction of an allylsilane with an acyliminium ion for the synthesis of one of the quaternary centres
1988
The vinylation of aryl iodides catalysed by Co, Rh and Ir complexes
1995
Molybdenum Trioxide Nanoparticles with Intrinsic Sulfite Oxidase Activity
2014
Stereoselective Synthesis of 4-Hydroxy-2,3,6-trisubstituted Tetrahydropyrans
2003
Role of 2-Oxonia Cope Rearrangements in Prins Cyclization Reactions
2001
Hypervalent Iodine-Mediated Vicinal Syn Diazidation: Application to the Total Synthesis of (±)-Dibromophakellstatin
2004
An Efficient Enantioselective Entry to the Piperidino-Quinolizidine Ring System of Lupine Alkaloids by Means of N-Acyliminium Ion Initiated Cyclization Reactions
2001
Heterocyclic Synthesis via the Tandem Thionium/N-Acyliminium Ion Cascade
1998
Syntheses of 3-amino-2-azetidinones: A literature survey
1991
Catalytic Asymmetric Synthesis of Thiols
2014 StandoutNobel
Enamides and Enesulfonamides as Nucleophiles: Formation of Complex Ring Systems through a Platinum(II)-Catalyzed Addition/Friedel−Crafts Pathway
2009
Synthesis of tetrahydropyrans and related heterocycles via prins cyclization; extension to aza-prins cyclization
2009
Effects of high pressure on the heck reaction. Is it possible to control dehydropalladation of alkylpalladium intermediates having β-hydrogens?
1995
Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes
1996 StandoutNobel
Enantioselective Redox-Neutral Rh-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters
2015
Catalytic Asymmetric Vinylogous Prins Cyclization: A Highly Diastereo- and Enantioselective Entry to Tetrahydrofurans
2016 StandoutNobel
Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity
2015 Standout
The silyl modified sakurai (SMS) reaction. An efficient and versatile one-pot synthesis of homoallylic ethers
1991
The asymmetric Heck reaction
1997
Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid
2002 StandoutScienceNobel
Prins‐Type Cyclization Reactions in Natural Product Synthesis
2013
Synthesis of oxa-bicyclic ring systems via a tandem Rh(II) catalyzed cyclization-cycloaddition sequence
1993
Der katalytische enantioselektive Aufbau von Molekülen mit quartären Kohlenstoff-Stereozentren
1998 Nobel
Enantioselective Polyene Cyclization via Organo-SOMO Catalysis
2010
From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids
2001 Standout
Mechanism of the [(NHC)AuI]-Catalyzed Rearrangement of Allylic Acetates. A DFT Study
2008
Sequentielle Transformationen in der Organischen Chemie eine Synthesestrategie mit Zukunft
1993
The intramolecular silyl modified sakurai (ISMS) reaction. A novel and highly convergent synthesis of oxocenes
1991
Works of Larry E. Overman being referenced
Controlling stereoselection in intramolecular heck reactions by tailoring the palladium catalyst
1992
Catalytic Asymmetric Synthesis of Quaternary Carbon Centers by Intramolecular Heck Reaction. Synthetic Developments and Mechanistic Studies.
2000
Enantioselective Total Synthesis of the Cyclotryptamine Alkaloid Idiospermuline
2003
The tethered Biginelli condensation in natural product synthesis
2004
Total Synthesis of (−)‐Sarain A
2006
Catalytic enantioselective synthesis of quaternary carbon stereocentres
2014 Nature
Evaluation of Strategies for the Synthesis of the Guanidine Hemiaminal Portion of Palau’amine
2006
Molecular rearrangements in the construction of complex molecules
2009
Total Synthesis of Complex Cyclotryptamine Alkaloids: Stereocontrolled Construction of Quaternary Carbon Stereocenters
2007
Thwartingβ-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction
2001
A Concise Synthesis of (−)‐Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition
2012
Enantioselective Total Syntheses of the Cyclotryptamine Alkaloids Hodgkinsine and Hodgkinsine B
2003
Design and in vitro pharmacology of a selective gamma-aminobutyric acidC receptor antagonist.
1996
Total Synthesis of (±)- and (−)-Actinophyllic Acid
2010
Enantioselective Total Syntheses of Ditryptophenaline and ent-WIN 64821
2001
A New Asymmetric Synthesis of trans-Hydroisoquinolones
2001
Mannich Biscyclizations. Total Synthesis of (-)-Ajmalicine
1995
Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene
1995
Strategic Use of Pinacol-Terminated Prins Cyclizations in Target-Oriented Total Synthesis
2003
Chair topology of the palladium dichloride catalyzed Cope rearrangement of acyclic 1,5-dienes
1982
Synthesis applications of aza-Cope rearrangements. 12. Applications of cationic aza-Cope rearrangements for alkaloid synthesis. Stereoselective preparation of cis-3a-aryloctahydroindoles and a new short route to Amaryllidaceae alkaloids
1983
Synthetic applications of N-acylamino-1,3-dienes. 10. Importance of allylic interactions and stereoelectronic effects in dictating the steric course of the reaction of iminium ions with nucleophiles. An efficient total synthesis of (.+-.)-gephyrotoxin
1983
Halide-Terminated N-Acyliminium Ion−Alkyne Cyclizations: A New Construction of Carbacephem Antibiotics
1997
Evolution of a Strategy for the Synthesis of Structurally Complex Batzelladine Alkaloids. Enantioselective Total Synthesis of the Proposed Structure of Batzelladine F and Structural Revision
2006
Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions. Model studies for the total synthesis of complex cardenolides.
1994
Synthesis of 2-Azatricyclo[5.2.1.04,10]decanes and 2,5-Diazatricyclo[5.2.1.04,10]decanes by Intramolecular Azomethine Ylide Cycloadditions
1996
Total Synthesis of the Strychnos Alkaloid (+)-Minfiensine: Tandem Enantioselective Intramolecular Heck−Iminium Ion Cyclization
2008
Synthetic applications of N-acylamino-1,3-dienes. An efficient stereospecific total synthesis of dl-pumiliotoxin C, and a general entry to cis-decahydroquinoline alkaloids
1978
trans-1-N-Acylamino-1,3-dienes: preparation from dienoic acids
1978
On the Structure of Palau'amine: Evidence for the Revised Relative Configuration from Chemical Synthesis
2007
Origin of Stereocontrol in the Construction of the 12-Oxatricyclo[6.3.1.02,7]dodecane Ring System by Prins−Pinacol Reactions
2009
Enantioselective total syntheses of pumiliotoxin B and pumiliotoxin 251D. A general entry to the pumiliotoxin A alkaloids via stereospecific iminium ion-vinylsilane cyclizations
1984
Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion
2001
Enantioselective Synthesis of Six-Membered Palladacycles Having Metal-Bound Stereogenic Carbons: Isolation and Reactivity of Palladacycles Containing Readily Accessible β-Hydrogens
2004
Stereocontrolled construction of carbocyclic rings by sequential cationic cyclization-pinacol rearrangements
1989
How important is secondary overlap in determining the regioselectivity of Diels-Alder reactions?
1978
Total Synthesis of (±)-Gelsemine
1999
Catalytic Asymmetric Synthesis of Allylic Thiol Derivatives
2008
Asymmetric Synthesis of Pyrrolidinoindolines. Application for the Practical Total Synthesis of (−)-Phenserine
2004
An unexpected product arising from metal alkylidene mediated ring-closing diene metathesis
1997
Synthesis applications of aza-Cope rearrangements. Stereoselective synthesis of cis-3a-aryloctahydroindoles and a new short entry to Amaryllidaceae alkaloids
1981
Total Synthesis of (+)-Isolaurepinnacin. Use of Acetal-Alkene Cyclizations To Prepare Highly Functionalized Seven-Membered Cyclic Ethers
1997
Synthesis applications of aza-Cope rearrangements. Part 10. A new approach for the total synthesis of pentacyclic Aspidosperma alkaloids. Total synthesis of dl-16-methoxytabersonine
1983
ChemInform Abstract: CATALYZED SIGMATROPIC REARRANGEMENTS. 8. PALLADIUM DICHLORIDE‐CATALYZED COPE REARRANGEMENTS OF FUNCTIONALIZED ACYCLIC 1,5‐DIENES
1983
Chemical behavior of o-bis(phenylethynyl)benzene toward some electrophilic and nucleophilic reagents
1969
The Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis
2003 Standout
"Artificial enzyme" combining a metal catalytic group and a hydrophobic binding cavity
1970
Synthesis studies directed toward gelsemine. Preparation of an advanced pentacyclic intermediate
1988
Vinylsilane- and alkynylsilane-terminated cyclization reactions
1986
Allylic and propargylic imidic esters in organic synthesis
1980
Quecksilber(II)- und Palladium(II)-katalysierte [3.3]-sigmatrope Umlagerungen
1984
General approach to halogenated tetrahydrofuran natural products from red algae of the genus Laurencia. Total synthesis of (.+-.)-trans-kumausyne and demonstration of an asymmetric synthesis strategy
1991
Synthesis applications of cationic aza-Cope rearrangements. Part 17. Transition-state geometry of [3,3]-sigmatropic rearrangements of iminium ions
1988
Total Synthesis of (+)-Laurencin. Use of Acetal-Vinyl Sulfide Cyclizations for Forming Highly Functionalized Eight-Membered Cyclic Ethers
1995
Total synthesis of (.+-.)-scopadulcic acid A. An illustration of the utility of palladium catalyzed polyene cyclizations
1993
Asymmetric Total Syntheses of (-)- and (+)-Strychnine and the Wieland-Gumlich Aldehyde
1995
Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Investigations of Intramolecular Heck Reactions of (E)-α,β-Unsaturated 2-Haloanilides and Analogues To Form Enantioenriched Spirocyclic Products
1998
High Enantioselection in the Rearrangement of Allylic Imidates with Ferrocenyl Oxazoline Catalysts
1999
Total Synthesis of (−)‐Sarain A
2006
Enantioselective total synthesis of the pumiliotoxin a alkaloids via reductive iminium ion-alkyne cyclizations. Total synthesis of (+)-pumiliotoxin a
1988
Total Synthesis of (−)-Sarain A
2007
Concise Synthesis of Guanidine-Containing Heterocycles Using the Biginelli Reaction
2006
Catalytic Asymmetric Intramolecular Aminopalladation: Improved Palladium(II) Catalysts
2005
A general method for the synthesis of amines by the rearrangement of allylic trichloroacetimidates. 1,3 Transposition of alcohol and amine functions
1976
Asymmetric Construction of Rings A−D of Daphnicyclidin-Type Alkaloids
2009
Synthesis of trichloroacetamido-1,3-dienes. Useful aminobutadiene equivalents for the Diels-Alder reaction
1976
A short stereospecific total synthesis of dl-pumiliotoxin C
1977
Palladium catalyzed enantioselective rearrangement of allylic imidates to allylic amides
1999
Monomeric Cobalt Oxazoline Palladacycles (COP). Useful Catalysts for Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates
2004
Preparation of eight-membered cyclic ethers by Lewis acid promoted acetal-alkene cyclizations
1990
Total syntheses of (+)-geissoschizine, (.+-.)-geissoschizine, and (.+-.)-(Z)-isositsirikine. Stereocontrolled synthesis of exocyclic double bonds by stereospecific iminium ion-vinylsilane cyclizations
1989
Ring-enlarging furan annulations
1987
Total Synthesis of (+)-Sieboldine A
2010
Asymmetrische Heck‐Reaktionen über neutrale Intermediate: Verstärkung der Enantioselektion durch Halogenid‐Additive und Einblicke in den Mechanismus
1997
Stereoselection in the Prins-Pinacol Synthesis of Acyltetrahydrofurans
2001
Thermal rearrangements of propargylic trichloroacetimidates. Synthesis of (trichloroacetamido)-1,3-dienes and -1,2-dienes
1981
Iminium ion and acyl iminium ion initiated cyclizations of vinylsilanes. Regiocontrolled construction of unsaturated azacyclics
1983
Thermal and mercuric ion catalyzed [3,3]-sigmatropic rearrangement of allylic trichloroacetimidates. 1,3 Transposition of alcohol and amine functions
1974
Stereocontrolled Synthesis of Trisubstituted Tetrahydropyrans
1999
Catalytic Asymmetric Synthesis of Allylic Aryl Ethers
2007
Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Studies of Intramolecular Heck Reactions of (Z)-α,β-Unsaturated Anilides and Mechanistic Investigations of Asymmetric Heck Reactions Proceeding via Neutral Intermediates
1998
Synthesis applications of cationic aza-Cope rearrangements. 24. The aza-Cope-Mannich approach to Strychnos alkaloids. Short stereocontrolled total syntheses of (.+-.)-dehydrotubifoline and (.+-.)-akuammicine
1993
Enantioselective total synthesis of (+)-isolaurepinnacin
1993
Intramolecular N-(acyloxy)iminium ion-alkyne cycloadditions. A new route to bicyclic .alpha.-amino ketones
1990
Catalyzed sigmatropic rearrangements. 10. Mechanism of the palladium dichloride catalyzed Cope rearrangement of acyclic dienes. A substituent effect study
1990
Prins-pinacol spiroannulations
1997
First Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allylic Amides
1997
The importance of vinylsilane stereochemistry and σ - π stabilization in iminium ion-vinylsilane cyclizations. A short total synthesis of the alkaloid (−) −epielwesine.
1984
Synthesis applications of cationic aza-Cope rearrangements. Part 13. Stereoselective synthesis of cis- and trans-3a-aryl-4-oxodecahydrocyclohepta[b]pyrroles
1983
Catalytic Asymmetric Synthesis of Chiral Allylic Amines. Evaluation of Ferrocenyloxazoline Palladacycle Catalysts and Imidate Motifs
2004
Preparation of functionalized hydroindol-3-ols via tandem aza-Cope rearrangement-mannich cyclizations. Formal total synthesis of (±)-6a-epipretazettine and related alkaloids
1989
Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C via Convergent Fragment Coupling Using a Tertiary Carbon Radical
2017
Short Enantioselective Total Syntheses of trans-Clerodane Diterpenoids: Convergent Fragment Coupling Using a trans-Decalin Tertiary Radical Generated from a Tertiary Alcohol Precursor
2016
Aloperine: Stereocontrolled Synthesis of Two Stereoisomers and Determination of Absolute Configuration
1997
Catalytic Asymmetric Intramolecular Aminopalladation: Enantioselective Synthesis of Vinyl-Substituted 2-Oxazolidinones, 2-Imidazolidinones, and 2-Pyrrolidinones
2001
Stereocontrolled preparation of tetrahydrofurans by acid-catalyzed rearrangement of allylic acetals
1987
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
2004
Use of aza-Cope rearrangement-Mannich cyclization reactions to achieve a general entry to Melodinus and Aspidosperma alkaloids. Stereocontrolled total syntheses of (.+-.)-deoxoapodine, (.+-.)-meloscine, and (.+-.)-epimeloscine and a formal synthesis of (.+-.)-1-acetylaspidoalbidine
1991
Enantioselective Total Synthesis of Shahamin K
2001
A Suzuki Coupling Method for Directly Introducing a Protected β-Aminoethyl Group into Arenes and Alkenes. Convenient Synthesis of Phenethyl and Homoallylic Amines
1999
Enantioselective Syntheses of Authentic Sclerophytin A, Sclerophytin B, and Cladiell-11-ene-3,6,7-triol
2000
Acetal-initiated cyclizations of vinylsilanes. A general synthesis of allylically unsaturated oxacyclics
1986
Diels-Alder reactions of 1-(acylamino)-1,3-dienes
1981
Synthesis of substituted tetrahydropyridines by cyclizations of silicon-containing iminium ions
1988
Synthesis of 3-acyltetrahydrofurans from formaldehyde acetals of allylic diols
2000
Studies towards the total synthesis of palau'amine. Formation of 4,5-dihydropyrrole-2-carboxylate intermediates by alkene–enamide ring-closing metathesis
2004
Palladium-catalyzed, polyene cyclizations
1992
Intramolecular Heck cyclization of α-sulfenyl enol triflates. Asymmetric synthesis of a pentacyclic cardenolide precursor having functionality at C-11
1998
Synthesis applications of cationic aza-Cope rearrangements. 20. Total synthesis of (.+-.)-meloscine and (.+-.)-epimeloscine
1989
Total Synthesis of (+)-Sieboldine A: Evolution of a Pinacol-Terminated Cyclization Strategy
2012
Sequential Catalytic Asymmetric Heck−Iminium Ion Cyclization: Enantioselective Total Synthesis of the Strychnos Alkaloid Minfiensine
2005
Enantioselective Total Synthesis of (-)-Ptilomycalin A
1995
Total Synthesis of (±)-Actinophyllic Acid
2008
Asymmetric synthesis of either enantiomer of opium alkaloids and morphinans. Total synthesis of (-)- and (+)-dihydrocodeinone and (-)- and (+)-morphine
1993
Stereocontrolled Synthesis of Functionalized cis-Cyclopentapyrazolidines by 1,3-Dipolar Cycloaddition Reactions of Azomethine Imines
2006
Preparation of seven-membered ring cyclic ethers and 3-alkylidenetetrahydropyrans from the cyclization of oxonium cations derived from unsubstituted and silicon-containing 4-alken-1-ols
1989
Stereocontrolled Total Syntheses of meso-Chimonanthine and meso-Calycanthine via a Novel Samarium Mediated Reductive Dialkylation
1996
Total Synthesis of (−)-Spirotryprostatin B and Three Stereoisomers
2000
Mercury(II)-catalyzed 3,3-sigmatropic rearrangements of allylic N,N-dimethylcarbamates. A mild method for allylic equilibrations and contrathermodynamic allylic isomer enrichments
1976
Enantioselective Total Synthesis of (+)-Gliocladin C
2006
Enantioselective Total Syntheses of Allopumiliotoxins 267A, 323B‘, and 339A. Application of Iodide-Promoted Iminium Ion−Alkyne Cyclizations for Forming Allopumiliotoxin A Alkaloids
1996
Scope and Facial Selectivity of the Prins-Pinacol Synthesis of Attached Rings
2006
Catalytic Asymmetric Synthesis of Either Enantiomer of the Calabar Alkaloids Physostigmine and Physovenine
1998
Synthesis applications of cationic aza-Cope rearrangements. Part 18. Scope and mechanism of tandem cationic aza-Cope rearrangement-Mannich cyclization reactions
1988
Nucleophilic cleavage of the sulfur-sulfur bond by phosphorus nucleophiles. IV. Kinetic study of the reduction of alkyl disulfides with triphenylphosphine and water
1976
Mild procedures for interconverting allylic oxygen functionality. Cyclization-induced [3,3] sigmatropic rearrangement of allylic carbamates
1978
Reaction of Na2Fe(CO)4 with an unsaturated aziridinium ion. Unprecedented rearrangement of an alkyltetracarbonylferrate intermediate
1992
Synthesis applications of cationic aza-Cope rearrangements. 26. Enantioselective total synthesis of (-)-strychnine
1993
Enantioselective Total Synthesis of Briarellins E and F: The First Total Syntheses of Briarellin Diterpenes
2003
Palladium-catalyzed polyene cyclizations of trienyl triflates
1989
Stereoselective synthesis of carbocyclic ring systems by pinacol-terminated Prins cyclizations
2002
Enantioselective Total Synthesis of Quadrigemine C and Psycholeine
2002
A convenient synthesis of 4-unsubstituted .beta.-lactams
1985
Hemiacetal mediated reactions. Directed synthesis of diols and acetals
1974
Enantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- andmeso-Chimonanthine
2000
Enantioselective synthesis of cardenolide precursors using an intramolecular Heck reaction
1998
Asymmetric Heck Reactions via Neutral Intermediates: Enhanced Enantioselectivity with Halide Additives Gives Mechanistic Insights
1997
A new strategy for synthesis of attached rings
2000
Palladium-catalyzed polyene cyclizations of dienyl aryl iodides
1988
Total Synthesis of (−)-Spirotryprostatin B and Three Stereoisomers
2000
Stereoselection in the Prins-Pinacol Synthesis of 2,2-Disubstituted 4-Acyltetrahydrofurans. Enantioselective Synthesis of (−)-Citreoviral
1999
Catalyzed sigmatropic rearrangements. 5. Palladium(II) chloride catalyzed Cope rearrangements of acyclic 1,5-dienes
1980
Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)‐Allylic Alcohols
2009
Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity
2003
N-acyl-1-amino-1,3-dienes: 1-amino-1,3-diene synthetic equivalents for the diels-alder reaction
1976
Catalytic Asymmetric Synthesis of Chiral Allylic Esters
2010
Preparation of opium alkaloids by palladium catalyzed bis-cyclizations. Formal total synthesis of morphine
1994
Kinetic and Computational Analysis of the Palladium(II)-Catalyzed Asymmetric Allylic Trichloroacetimidate Rearrangement: Development of a Model for Enantioselectivity
2007
Preparation of enantioenriched tetrahydropyridines by iminium ion-vinylsilane cyclizations
1993
Stereoselective total synthesis of (.+-.)-perhydrogephyrotoxin. Synthetic applications of directed 2-azonia-[3,3]-sigmatropic rearrangements
1980
Iminium ion and acyliminium ion initiated cyclization reactions of vinylsilanes. Regiocontrolled synthesis of tetrahydropyridines and related heterocycles
1987
Synthesis of tert-Leucine-Derived Cobalt Oxazoline Palladacycles. Reversal of Palladation Diastereoselectivity and Application to the Asymmetric Rearrangement of N-Aryl Trifluoroacetimidates
2004
Direct Stereo- and Enantiocontrolled Synthesis of Vicinal Stereogenic Quaternary Carbon Centers. Total Syntheses of meso- and (−)-Chimonanthine and (+)-Calycanthine
1999
Asymmetric Construction of the Diazatricyclic Core of the Marine Alkaloids Sarains A−C
1998
Catalytic asymmetric synthesis of either enantiomer of physostigmine. Formation of quaternary carbon centers with high enantioselection by intramolecular Heck reactions of (Z)-2-butenanilides
1993
Planar-chiral cyclopalladated ferrocenyl amines and imines as enantioselective catalysts for allylic imidate rearrangements
1998
Versatile Construction of 6-Substituted cis-2,8-Dioxabicyclo[3.3.0]octan-3-ones: Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C
2017
A General Strategy for the Synthesis of Cladiellin Diterpenes: Enantioselective Total Syntheses of 6-Acetoxycladiell-7(16),11-dien-3-ol (Deacetoxyalcyonin Acetate), Cladiell-11-ene-3,6,7-triol, Sclerophytin A, and the Initially Purported Structure of Sclerophytin A
2001
Enantioselective total synthesis of streptazolin. The tandem use of iminium ion vinylsilane cyclizations and intramolecular acylations
1987
Total synthesis of (+)-asperazine
2007
Synthesis applications of aza-Cope rearrangements. 11. Carbon-carbon bond formation under mild conditions via tandem cationic aza-Cope rearrangement-Mannich reactions. A convenient synthesis of polysubstituted pyrrolidines
1983
A short total synthesis of (.+-.)-perhydrogephyrotoxin
1981
Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions
2003
Application of intramolecular Heck reactions for forming congested quaternary carbon centers in complex molecule total synthesis
1994
Stereocontrolled Synthesis of Triazacyclopenta[cd]pentalenes by Intramolecular 1,3-Dipolar Cycloaddition Reactions of Azomethine Imines
2002
A Strategy for Total Synthesis of Complex Cardenolides
1996
Enantioselective Total Synthesis of the Kinesin Motor Protein Inhibitor Adociasulfate 1
1999
Stereocontrolled preparation of tetrahydrofurans from acid-promoted rearrangements of allylic acetals
1991
First total synthesis of Lycopodium alkaloids of the magellanane group. Enantioselective total syntheses of (-)-magellanine and (+)-magellaninone
1993
Synthetic applications of N-(acylamino)-1,3-dienes. Control of endo stereoselectivity by the acyl substituent. Stereospecific synthesis of the analgesic Tilidine
1979
Acid-promoted reaction of cyclic allylic diols with carbonyl compounds. Stereoselective ring-enlarging tetrahydrofuran annulations
1991
Construction of quaternary carbon centers by palladium-catalyzed intramolecular alkene insertions. Total synthesis of the Amaryllidaceae alkaloids (.+-.)-tazettine and (.+-.)-6a-epipretazettine
1990
Total synthesis of (-)-laurenyne. Use of acetal-initiated cyclizations to prepare functionalized eight-membered cyclic ethers
1988
Total Synthesis and Properties of the Crambescidin Core Zwitterionic Acid and Crambescidin 359
2005
Diels-Alder reactions between trans-1-N-acylamino-1,3-dienes and methyl acrylate. A correlation between diene photoelectron ionization potentials and reactivity, stereoselectivity, and regioselectivity
1978
Total Synthesis of the Reputed Structure of Alcyonin and Reassignment of Its Structure
2003
Total Synthesis of the Supposed Structure of (−)-Sclerophytin A and an Improved Route to (−)-7-Deacetoxyalcyonin Acetate
2000
Catalytic Asymmetric Synthesis of Chiral Allylic Esters
2005
Total Synthesis of (±)-Didehydrostemofoline (Asparagamine A) and (±)-Isodidehydrostemofoline
2003
Contiguous stereogenic quaternary carbons: A daunting challenge in natural products synthesis
2004
Catalytic asymmetric synthesis of quarternary carbon centers. Palladium-catalyzed formation of either enantiomer of spirooxindoles and related spirocyclics using a single enantiomer of a chiral diphosphine ligand
1992
Allylic Transposition of Alcohol and Amine Functionality by Thermal or Palladium(II)-Catalyzed Rearrangements of Allylic N-Benzoylbenzimidates
1997
New approach to Strychnos alkaloids. Stereocontrolled total synthesis of (.+-.)-dehydrotubifoline
1991
Palladium (II) - catalyzed rearrangement of allylic acetates
1979
Palladium dichloride catalyzed cope rearrangements of functionalized acyclic 1,5-dienes
1983
First total synthesis of scopadulcic acid B
1993
Medium effects and the nature of the rate-determining step in Mannich-type cyclizations
1987
Enantioselective total synthesis of allopumiliotoxin A alkaloids 267A and 339B
1984
Carbon-carbon bond formation via directed 2-azonia-[3,3]-sigmatropic rearrangements. A new pyrrolidine synthesis
1979
Enantioselective Total Synthesis of Hispidospermidin
1998
Charge as a key component in reaction design. The invention of cationic cyclization reactions of importance in synthesis
1992
Totalsynthese komplexer Cyclotryptaminalkaloide: stereokontrollierter Aufbau quartärer Kohlenstoffstereozentren
2007
Enantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- andmeso-Chimonanthine
2000
Formation of .DELTA.4-oxocenes from Lewis acid promoted cyclizations of 5-hexenyl acetals. Evidence for a concerted ene cyclization mechanism
1990
New Cationic Olefin Cyclization−Pinacol Reactions. Ring-Expanding Cyclopentane Annulations That Directly Install Useful Functionality in the Cyclopentane Ring
2002
Complementary use of iminium ion and N-acyl iminium ion cyclization initiators for asymmetric synthesis of both enantiomers of hydroxylated indolizidines
1989
Total Synthesis of (−)-Crambidine and Definition of the Relative Configuration of Its Unique Tetracyclic Guanidinium Core
2005
Cyclopalladated ferrocenyl amines as enantioselective catalysts for the rearrangement of allylic imidates to allylic amides
1997
The cyanomethyl group for nitrogen protection and iminium ion generation in ring-enlarging pyrrolidine annulations. A short synthesis of the amaryllidaceae alkaloid d,1-crinine
1982
Mercury(II )‐ and Palladium(II )‐Catalyzed [3,3]‐Sigmatropic Rearrangements [New Synthetic Methods (46)]
1984
Total Synthesis of Asperazine
2001
Catalytic Asymmetric Rearrangement of Allylic N-Aryl Trifluoroacetimidates. A Useful Method for Transforming Prochiral Allylic Alcohols to Chiral Allylic Amines
2003
Application of the Tethered Biginelli Reaction for Enantioselective Synthesis of Batzelladine Alkaloids. Absolute Configuration of the Tricyclic Guanidine Portion of Batzelladine B
1999
Total Synthesis of (+)-Aloperine. Use of a Nitrogen-Bound Silicon Tether in an Intramolecular Diels−Alder Reaction
1999
Palladium(II)-Catalyzed Enantioselective Synthesis of 2-Vinyl Oxygen Heterocycles
2012
4-Methylene-4,5-dihydrooxazoles: isolation, properties, and use for the preparation of substituted oxazoles
1979
Efficient preparations of 8- and 9-membered cyclic ethers
1986
Enantioselective Total Synthesis of (+)-Gliocladine C: Convergent Construction of Cyclotryptamine-Fused Polyoxopiperazines and a General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors
2011
Synthesis applications of cationic aza-Cope rearrangements. 23. First total synthesis of amaryllidaceae alkaloids of the 5,11-methano morphanthridine type. An efficient total synthesis of (.+-.)-pancracine
1991
Intramolecular alkene arylations for rapid assembly of polycyclic systems containing quaternary centers. A new synthesis of spirooxindoles and other fused and bridged ring systems
1987