L.A. Tyler

Transition-metal mediated carbon–sulfur bond activation and transformations

Structural variation in copper(i) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ₄

Cobalt(ii) and cobalt(iii) complexes of thioether-containing hexadentate pyrazine amide ligands: C–S bond cleavage and cyclometallation reaction

Photoactive ruthenium nitrosyls: Effects of light and potential application as NO donors

Photoremovable Protecting Groups in Chemistry and Biology: Reaction Mechanisms and Efficacy

A Synthetic Analogue of the Active Site of Fe-Containing Nitrile Hydratase with Carboxamido N and Thiolato S as Donors:  Synthesis, Structure, and Reactivities

Proton Transfer to Nickel−Thiolate Complexes. 1. Protonation of [Ni(SC₆H₄R-4)₂(Ph₂PCH₂CH₂PPh₂)] (R = Me, MeO, H, Cl, or NO₂)

Hydroperoxo−Copper(II) Complex Stabilized by N₃S-Type Ligand Having a Phenyl Thioether

Structure and Spectroscopy of Copper−Dioxygen Complexes

First {Fe−NO}⁶ Complex with an N₂S₃Fe−NO Core as a Model of NO-Inactivated Iron-Containing Nitrile Hydratase. Are Thiolates and Thioethers Equivalent Donors in Low-Spin Iron Complexes?

Getting Harder: Cobalt(III)-Template Synthesis of Catenanes and Rotaxanes

Zinc(II)/Ketoxime System as a Simple and Efficient Catalyst for Hydrolysis of Organonitriles

Platinum-Catalyzed Selective Hydration of Hindered Nitriles and Nitriles with Acid- or Base-Sensitive Groups

Modeling the Active Site of Nitrile Hydratase:  Synthetic Strategies to Ensure Simultaneous Coordination of Carboxamido-N and Thiolato-S to Fe(III) Centers

Why Is There an “Inert” Metal Center in the Active Site of Nitrile Hydratase? Reactivity and Ligand Dissociation from a Five-Coordinate Co(III) Nitrile Hydratase Model

Additions to Metal-Activated Organonitriles

Hydro(solvo)thermal in situ ligand syntheses

Coordination of carboxamido nitrogen to tervalent iron: insight into a new chapter of iron chemistry

Dioxygen Activation at Mononuclear Nonheme Iron Active Sites:  Enzymes, Models, and Intermediates

Synthesis of Binucleating Macrocycles and Their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features

Syntheses, Structures, and Reactivity of Low Spin Iron(III) Complexes Containing a Single Carboxamido Nitrogen in a [FeN₅L] Chromophore

Artificial Molecular Machines

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO₂ Fixation

How Do Oxidized Thiolate Ligands Affect the Electronic and Reactivity Properties of a Nitrile Hydratase Model Compound?

A square-planar di-N-carboxamido, dithiolato–cobalt(III) complex related to nitrile hydratase metallic site. Addition of axial ligands and EXAFS study of the derived dicyano and diisocyanido complexes

Modulation of the pK_aof Metal-Bound Water via Oxidation of Thiolato Sulfur in Model Complexes of Co(III) Containing Nitrile Hydratase:  Insight into Possible Effect of Cysteine Oxidation in Co−Nitrile Hydratase

Co(III) Complexes with Coordinated Carboxamido Nitrogens and Thiolato Sulfurs as Models for Co-Containing Nitrile Hydratase and Their Conversion to the Corresponding Sulfinato Species

Oxidation of Metal-Bound Thiolato Sulfur Centers in Fe(III) and Co(III) Complexes with Carboxamido Nitrogens and Thiolato Sulfurs as Donors:  Relevance to the Active Sites of Nitrile Hydratases

Thioether ligation in Co(III) complexes with carboxamido nitrogens as donors: implications on the coordination structure of the cobalt site in nitrile hydratase

Change in the Spin State of an Fe^III Center upon One N‐to‐O Switch in the Coordination of a 2,6‐Pyridinedicarboxamido Unit: The Effect of Methyl Thioether and Methyl Ether Appendages at the Ligand Periphery