Citation Impact
Citing Papers
Subpolar addition of new cell wall is directed by DivIVA in mycobacteria
2014 StandoutNobel
The first Lewis acid mediated asymmetric Torgov cyclisation
1998
β-Amino alcohols as ligands for asymmetric transfer hydrogenation of ketones in water
2006
Synthesis of novel axially chiral Rh–NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones
2003
Double CH Activation of an N‐Heterocyclic Carbene Ligand in a Ruthenium Olefin Metathesis Catalyst
2007 Nobel
Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis
2009
Water‐Soluble IrIII N‐Heterocyclic Carbene Based Catalysts for the Reduction of CO2 to Formate by Transfer Hydrogenation and the Deuteration of Aryl Amines in Water
2011
A planar chelating bitriazole N-heterocyclic carbene ligand and its rhodium(iii) and dirhodium(ii) complexes
2007
F-block N-heterocyclic carbene complexes
2006
Efficient Palladium‐Catalyzed Coupling of Aryl Chlorides and Tosylates with Terminal Alkynes: Use of a Copper Cocatalyst Inhibits the Reaction
2003
Titanium N-heterocyclic carbene complexes incorporating an imidazolium-linked bis(phenol)Electronic supplementary information (ESI) available: full experimental, NMR and analytical data. See http://www.rsc.org/suppdata/cc/b3/b305745c/
2003
Highly Diastereoselective Formation of Ruthenium Complexes for Efficient Catalytic Asymmetric Transfer Hydrogenation
2007
Cyclic (alkyl)(amino)carbene gold(I) complexes: A synthetic and structural investigation
2008
A new synthetic method for the preparation of protonated-NHCs and related compounds
2006
The active role of NHC ligands in platinum-mediated tandem hydroboration–cross coupling reactions
2007
Preparation of a series of Ru(ii ) complexes with N-heterocyclic carbeneligands for the catalytic transfer hydrogenation of aromatic ketones
2011
Synthesis and catalytic activity of histidine-based NHC ruthenium complexes
2011
One-N, six-membered heterocyclic carbene complexes and the remote heteroatom concept
2007
The Measure of All Rings—N‐Heterocyclic Carbenes
2010 Standout
Asymmetric Allylic Substitution Catalyzed by C1‐Symmetrical Complexes of Molybdenum: Structural Requirements of the Ligand and the Stereochemical Course of the Reaction
2006
Preparation of Mononuclear, Homodinuclear, and Heterotrinuclear Complexes by Salicylaldiminato‐Functionalized Imidazolium Salt: Approach to Multifunctional Catalysts
2011
Testing Racemic Chiral Catalysts for Kinetic Resolution Potential
2001
Palladium Complexes of N‐Heterocyclic Carbenes as Catalysts for Cross‐Coupling Reactions—A Synthetic Chemist's Perspective
2007 Standout
Dendrimer N-heterocyclic carbene complexes with rhodium(i) at the core
2005
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
2009 StandoutNobel
Synthesis and Ligand Properties of a Persistent, All‐Carbon Four‐Membered‐Ring Allene
2009
Bifunctional Rhenium Complexes for the Catalytic Transfer‐Hydrogenation Reactions of Ketones and Imines
2012
Palladium–NHC complexes do catalyse the diboration of alkenes: mechanistic insights
2007
RhIII‐ and IrIII‐Catalyzed Asymmetric Transfer Hydrogenation of Ketones in Water
2007
Efficiency in Nonenzymatic Kinetic Resolution
2005
Heterocyclic Carbenes
2006
IPr* an easily accessible highly hindered N-heterocyclic carbene
2009
Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes
2009
Asymmetric transfer hydrogenation: chiral ligands and applications
2005
Highly Enantioselective Synthesis of 3‐Substituted Furanones by Palladium‐Catalyzed Kinetic Resolution of Unsymmetrical Allyl Acetates
2012 StandoutNobel
(Pyridyl)benzoazole ruthenium(ii ) and ruthenium(iii ) complexes: role of heteroatom and ancillary phosphine ligand in the transfer hydrogenation of ketones
2013
Characterising the Electronic Structure of Ionic Liquids: An Examination of the 1‐Butyl‐3‐Methylimidazolium Chloride Ion Pair
2006
Cycloisomerization of 1,n‐Enynes: Challenging Metal‐Catalyzed Rearrangements and Mechanistic Insights
2008
Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes
2004
Nickel(II) Complexes of Bidentate N‐Heterocyclic Carbene/Phosphine Ligands: Efficient Catalysts for Suzuki Coupling of Aryl Chlorides
2006
Synthesis and catalytic alcohol oxidation and ketone transfer hydrogenation activity of donor-functionalized mesoionic triazolylidene ruthenium(ii ) complexes
2013
An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine
2006
Synthesis, characterization and catalytic activity of saturated and unsaturated N-heterocyclic carbene iridium(i ) complexes
2008
Abnormally Bound N‐Heterocyclic Carbene Complexes of Ruthenium: CH Activation of Both C4 and C5 Positions in the Same Ligand
2007
Influence of geometry on reductive elimination of hydrocarbyl–palladium–carbene complexes
2005
Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry
2010
Combinatorial Transition‐Metal Catalysis: Mixing Monodentate Ligands to Control Enantio‐, Diastereo‐, and Regioselectivity
2008
Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes
2010
Terminal and Bridging Parent Amido 1,5‐Cyclooctadiene Complexes of Rhodium and Iridium
2013
Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes
2005
Ligand-induced distortion of a tetranuclear manganese butterfly complex
2006
Rhodium(i ) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks
2006
New Benzo[h]quinoline‐Based Ligands and their Pincer Ru and Os Complexes for Efficient Catalytic Transfer Hydrogenation of Carbonyl Compounds
2008
Unprecedented use of silver(i) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters
2005
Pentamethylcyclopentadienyl–Ruthenium Catalysts for Regio‐ and Enantioselective Allylation of Nucleophiles
2006
Nickel‐Catalyzed Asymmetric Transfer Hydrogenation of Hydrazones and Other Ketimines
2015
N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivity
2008
Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand
2008
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron‐Rich Ligands for Transition‐Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
2005
N-heterocyclic carbenes bearing two, one and no nitrogen atoms at the ylidene carbon: insight from theoretical calculations
2009
Organolanthanide‐Mediated Intermolecular Hydroamination of 1,3‐Dienes: Mechanistic Insights from a Computational Exploration of Diverse Mechanistic Pathways for the Stereoselective Hydroamination of 1,3‐Butadiene with a Primary Amine Supported by an ansa‐Neodymocene‐Based Catalyst
2005
Synthesis and Application of Water‐Soluble NHC Transition‐Metal Complexes
2012
An [(NHC)(NHCEWG)RuCl2(CHPh)] Complex for the Efficient Formation of Sterically Hindered Olefins by Ring‐Closing Metathesis
2009
Synthesis and Ligand Properties of Stable Five‐Membered‐Ring Allenes Containing Only Second‐Row Elements
2008
Regioselective Iron‐Catalyzed Allylic Amination
2006
Osmium(II) CNN Pincer Complexes as Efficient Catalysts for Both Asymmetric Transfer and H2 Hydrogenation of Ketones
2008
Platinum‐Mediated Oxidative Addition and Reductive Elimination of Imidazolium Salts at C4 and C5
2005
Rapid Ketone Transfer Hydrogenation by Employing Simple, In Situ Prepared Iridium(I) Precatalysts Supported by “Non‐NH” P,N Ligands
2008
Chiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysis
2004
Oxidative Addition of Imidazolium Salts to Ni0 and Pd0: Synthesis and Structural Characterization of Unusually Stable Metal–Hydride Complexes
2004
A ligand knowledge base for carbenes (LKB-C): maps of ligand space
2009
Unexpected oxidative C–C cleavage in the metallation of 2-substituted imidazolium salts to give N-heterocyclic carbene complexes
2004
Triazolediylidenes: A Versatile Class of Ligands for the Preparation of Discrete Molecules of Homo‐ and Hetero‐Binuclear Complexes for Improved Catalytic Applications
2007
Metal‐Catalyzed Enantioselective Allylation in Asymmetric Synthesis
2007 Standout
Diastereoselective metal-catalyzed [4 + 2 + 2] carbocyclization reactions utilizing a rhodium N-heterocyclic carbene (NHC) complex: the first example of a rhodium NHC-catalyzed [m+n+o] carbocyclization
2004
Borrowing hydrogen: a catalytic route to C–C bond formation from alcohols
2003
Catalytic Asymmetric Allylation of Aldehydes and Related Reactions with Bis(((S)‐binaphthoxy)(isopropoxy)titanium) Oxide as a μ‐Oxo‐Type Chiral Lewis Acid
2003
Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Amino Acid Derived Rhodium Complexes: On the Origin of Enantioselectivity and Enantioswitchability
2009
“Pincer” Pyridine–Dicarbene–Iridium Complexes: Facile CH Activation and Unexpected η2‐Imidazol‐2‐ylidene Coordination
2008
Mild and rational synthesis of palladium complexes comprising C(4)-bound N-heterocyclic carbenes
2006
Acute Pancreatitis
1994 Standout
Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
2010 StandoutNobel
N-Heterocyclic carbeneligands bearing hydrophilic and/or hydrophobic chains: Rh(i ) and Pd(ii ) complexes and their catalytic activity
2007
The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(ii )
2004
N-heterocyclic carbenes of iridium(I): ligand effects on the catalytic activity in transfer hydrogenation
2009
Designing the “Search Pathway” in the Development of a New Class of Highly Efficient Stereoselective Hydrosilylation Catalysts
2005
Osmium Pyme Complexes for Fast Hydrogenation and Asymmetric Transfer Hydrogenation of Ketones
2007
Application of 1,2,3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond
2012
Structural variation, dynamics, and catalytic application of palladium(ii ) complexes of di-N-heterocyclic carbene–amine ligands
2007
A Modular Assembly of Chiral Oxazolinylcarbene–Rhodium Complexes: Efficient Phosphane‐Free Catalysts for the Asymmetric Hydrosilylation of Dialkyl Ketones
2004
Biaryl Phosphane Ligands in Palladium‐Catalyzed Amination
2008 Standout
A Highly Practical and Enantioselective Reagent for the Allylation of Aldehydes
2003
Stoichiometric and catalytic reactivity of the N-heterocyclic carbene ruthenium hydride complexes [Ru(NHC)(L)(CO)HCl] and [Ru(NHC)(L)(CO)H(η2-BH4)] (L = NHC, PPh3)
2008
Coordination Chemistry of Ene‐1,1‐diamines and a Prototype “Carbodicarbene”
2008
Functional Porous Coordination Polymers
2004 StandoutNobel
Catalytically active palladium pyridylidene complexes: pyridinium ionic liquids as N-heterocyclic carbene precursors
2005
An overview of N-heterocyclic carbenes
2014 StandoutNature
Diaminocarbene‐ and Fischer‐Carbene Complexes of Palladium and Nickel by Oxidative Insertion: Preparation, Structure, and Catalytic Activity
2005
A Highly Regioselective Salt‐Free Iron‐Catalyzed Allylic Alkylation
2006
Bis(imidazolylidene)s as modular building blocks for monomeric and macromolecular organometallic materials
2006
Photochemical Conversion of Solar Energy
2007
Rhodium(iii) complexes with a bidentate N-heterocyclic carbene ligand bearing flexible dendritic frameworks
2007
Oxidative addition of 2-substituted azolium salts to Group-10 metal zero complexes—A DFT study
2007
Easily Prepared Air‐ and Moisture‐Stable Pd–NHC (NHC=N‐Heterocyclic Carbene) Complexes: A Reliable, User‐Friendly, Highly Active Palladium Precatalyst for the Suzuki–Miyaura Reaction
2006
Structure and reactivity of a new anionic N-heterocyclic carbene silver(i) complex
2005
Tetrametallic molecular catalysts for photochemical water oxidation
2012
cis‐Selective Single‐Cleavage Skeletal Rearrangement of 1,6‐Enynes Reveals the Multifaceted Character of the Intermediates in Metal‐Catalyzed Cycloisomerizations
2008
Neutral Ligands with Exceptional Donor Ability for Palladium‐Catalyzed Alkene Hydrogenation
2007
Asymmetric transfer hydrogenation of ketones catalyzed by rhodium complexes containing amino acid triazole ligands
2010
Chiral Relay: A Novel Strategy for the Control and Amplification of Enantioselectivity in Chiral Lewis Acid Promoted Reactions
2002
Quantifying and understanding the electronic properties of N-heterocyclic carbenes
2013
Crystalline 1H‐1,2,3‐Triazol‐5‐ylidenes: New Stable Mesoionic Carbenes (MICs)
2010
N-Heterocyclic carbenes/imidazolium salts as substrates in catalysis: the catalytic 2-substitution and annulation of heterocyclic compounds
2008
An N‐Heterocyclic Carbene/Iridium Hydride Complex from the Oxidative Addition of a Ferrocenyl–Bisimidazolium Salt: Implications for Synthesis
2004
Heterocyclic Carbenes: Synthesis and Coordination Chemistry
2008 Standout
Development of 7-membered N-heterocyclic carbene ligands for transition metals
2005
Chiral Pincer Ruthenium and Osmium Complexes for the Fast and Efficient Hydrogen Transfer Reduction of Ketones
2010
Syntheses and characterizations of methylpalladium complexes bearing a biphenyl-based bulky phosphine ligand: Weak interactions suggested by NBO and QTAIM analyses
2006
Ruthenium(II) and rhodium(III) catalyzed asymmetric transfer hydrogenation (ATH) of acetophenone in isopropanol and in aqueous sodium formate using new chiral substituted aromatic monosulfonamide ligands derived from (1R,2R)-diaminocyclohexane
2008
Ag(I) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Application
2005
Allylic Amination Using Well‐Defined [(NHC)Pd(η3‐allyl)Cl] Complexes and PPh3
2009
Design of chiral ligands for asymmetric catalysis: From C 2 -symmetric P,P- and N,N-ligands to sterically and electronically nonsymmetrical P,N-ligands
2004
Ir-Catalyzed Regio- and Enantioselective Decarboxylative Allylic Alkylations
2007
Metallacyclopentane Formation: A Deactivation Pathway for a Tungsten(VI) Alkylidene Complex in Olefin Metathesis Reactions
1998
PhosphinooxazolinesA New Class of Versatile, Modular P,N-Ligands for Asymmetric Catalysis
2000
Iridium(III)-Induced Isomerization of 2-Substituted Pyridines to N-Heterocyclic Carbenes
2006
Metallkatalysierte enantioselektive Allylierungen in der asymmetrischen Synthese
2007
Oxidationsreaktionen von Molybdän- und wolframcarbonyl-carbinkomplexen. Koordination der W≠C-Einheit an palladium(0) aktiviert carbonyl- und schützt carbinliganden bei der synthese von wolfram(VI)-chlorocarbinkomplexen
1995
Chiral Recognition in π Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectivities
1997
The Golden Age of Transfer Hydrogenation
2015 Standout
Phosphine- and Pyridine-Functionalized N-Heterocyclic Carbene Methyl and Allyl Complexes of Palladium. Unexpected Regiospecificity of the Protonation Reaction of the Dimethyl Complexes
2006
A New Approach to the Reduction of Carbon Dioxide: CO2 Reduction to Formate by Transfer Hydrogenation in iPrOH
2009
N-Alkoxyimidazolylidene Transition-Metal Complexes: Application to [5+2] and [4+2] Cycloaddition Reactions
2007
Synthesis of novel rhodium‐xylyl linked N‐heterocyclic carbene complexes as hydrosilylation catalysts
2008
Novel N-heterocyclic-carbene–rhodium complexes as hydrosilylation catalysts
2005
π‐Face Donor Properties of N‐Heterocyclic Carbenes in Grubbs II Complexes
2008
N-Heterocyclic Carbenes as Activating Ligands for Hydrogenation and Isomerization of Unactivated Olefins
2005
Iridium/Monodentate Phosphoramidite Catalyzed Asymmetric Hydrogenation ofN-Aryl Imines
2009 StandoutNobel
Donor Properties of a Series of Two-Electron Ligands
2009
Synthesis of Well-Defined N-Heterocyclic Carbene Silver(I) Complexes
2005
Transfer Hydrogenation Catalysis by a N‐Heterocyclic Carbene Iridium Complex on a Polyoxometalate Platform
2014
Intramolecular Hydroamination with Rhodium(I) and Iridium(I) Complexes Containing a Phosphine−N-Heterocyclic Carbene Ligand
2005
Abnormal N-heterocyclic carbenes
2006
An N‐Heterocyclic Carbene/Iridium Hydride Complex from the Oxidative Addition of a Ferrocenyl–Bisimidazolium Salt: Implications for Synthesis
2004
Platinum(II) Complexes Featuring Chiral Diphosphines and N-Heterocyclic Carbene Ligands: Synthesis and Evaluation as Cycloisomerization Catalysts
2008
Intramolecular “Hydroiminiumation and -amidiniumation” of Alkenes: A Convenient, Flexible, and Scalable Route to Cyclic Iminium and Imidazolinium Salts
2007
Triazolediylidenes: A Versatile Class of Ligands for the Preparation of Discrete Molecules of Homo‐ and Hetero‐Binuclear Complexes for Improved Catalytic Applications
2007
Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization
2009
Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation
2012 StandoutNobel
Polymer supported palladium N-heterocyclic carbene complexes: long lived recyclable catalysts for cross coupling reactions
2004
Identification of the "Active Sites" of a Surface-Catalyzed Reaction
1996 StandoutScienceNobel
On the Chemical Stabilities of Ionic Liquids
2009
Synthesis and Structural Characterization of N-Heterocyclic Carbene Gold(I) Complexes
2005
Building Bridges Between Inorganic and Organic Chemistry (Nobel Lecture)
1982 StandoutNobel
New chiral phosphinite ligands with C2‐symmetric axis and their possible applications in Ru‐catalyzed asymmetric transfer hydrogenation
2009
Synthesis and catalytic properties of N -functionalised carbene complexes of rhodium(I)
2007
An improved synthesis of bis(1,3-di-N-tert-butylimidazol-2-ylidene)palladium(0) and its use in C–C and C–N coupling reactions
2001
Novel quasi-scorpionate ligand structures based on a bis-N-heterocyclic carbene chelate core: synthesis, complexation and catalysis
2011
Redox-Active N-Heterocyclic Carbenes: Design, Synthesis, and Evaluation of Their Electronic Properties
2009
A Class of Ruthenium(II) Catalyst for Asymmetric Transfer Hydrogenations of Ketones
2005
Cyclometalated iridium complexes for transfer hydrogenation of carbonyl groups in water
2013
Recent homogeneous catalytic applications of chelate and pincer N-heterocyclic carbenes
2004 Standout
Alkenyl-functionalized NHC iridium-based catalysts for hydrosilylation
2007
Cp*Ir Complexes Bearing N-Heterocyclic Carbene Ligands as Effective Catalysts for Oppenauer-Type Oxidation of Alcohols
2004
Nonlinear stereochemical effects in asymmetric reactions
1997
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
2011 Standout
Pd-Catalyzed Asymmetric Allylic Amination Using Aspartic Acid Derived P-Chirogenic Diaminophosphine Oxides: DIAPHOXs
2005
An Anion-Dependent Switch in Selectivity Results from a Change of C−H Activation Mechanism in the Reaction of an Imidazolium Salt with IrH5(PPh3)2
2005
The palladium complexes of a C3-bridged di(benzimidazol-2-ylidene) ligand via cleavage of a dibenzotetraazafulvalene
2005
Abnormally Bound N‐Heterocyclic Carbene Complexes of Ruthenium: CH Activation of Both C4 and C5 Positions in the Same Ligand
2007
Asymmetric Activation of Racemic Ruthenium(II) Complexes for Enantioselective Hydrogenation
1998 StandoutNobel
Coordination Chemistry of a Modular N,C-Chelating Oxazole-Carbene Ligand and Its Applications in Hydrosilylation Catalysis
2006
Complexation of Polyoxometalates with Cyclodextrins
2015 StandoutNobel
Synthesis of iridium complexes with new planar chiral chelating phosphinyl-imidazolylidene ligands and their application in asymmetric hydrogenation
2004
Platinum‐Mediated Oxidative Addition and Reductive Elimination of Imidazolium Salts at C4 and C5
2005
C−H Oxidative Addition of Bisimidazolium Salts to Iridium and Rhodium Complexes, and N-Heterocyclic Carbene Generation. A Combined Experimental and Theoretical Study
2006
Synthesis and Application of Chiral Cyclopropane-Based Ligands in Palladium-Catalyzed Allylic Alkylation
2004
Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex: Catalytic activity of the di-Rh and CCC–NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes
2005
Chiral–achiral ligand synergy: activation of a zirconium–BINOL Lewis acid complex by the addition of 4-tert-butylcalix[4]arene
1997
Asymmetric allylation of aromatic aldehydes catalyzed by chiral phosphoramides prepared from (S)-proline
1997
Asymmetric Activation/Deactivation of Racemic Ru Catalysts for Highly Enantioselective Hydrogenation of Ketonic Substrates
2000 StandoutNobel
Preparation and application of N-heterocyclic carbene complexes of Ag(I)
2006
Transfer Hydrogenation of Imines and Alkenes and Direct Reductive Amination of Aldehydes Catalyzed by Triazole-Derived Iridium(I) Carbene Complexes
2007
Active ruthenium-(N-heterocyclic carbene) complexes for hydrogenation of ketones
2006
Synthesis, characterization, and transfer hydrogenation of Ru(II)-N-heterocyclic carbene complexes
2014
Highly Stable Cp*−Ir(III) Complexes with N-Heterocyclic Carbene Ligands as C−H Activation Catalysts for the Deuteration of Organic Molecules
2006
Base-Free Dynamic Kinetic Resolution of Secondary Alcohols Using “Piano-Stool” Complexes of N-Heterocyclic Carbenes
2007
Air- and Water-Stable Catalysts for Hydroamination/Cyclization. Synthesis and Application of CCC−NHC Pincer Complexes of Rh and Ir
2008
Palladium-Catalyzed Suzuki Cross-Coupling Reactions in Ambient Temperature Ionic Liquids: Evidence for the Importance of Palladium Imidazolylidene Complexes
2003
13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II)
2009
Ruthenium(II)‐Catalyzed Asymmetric Transfer Hydrogenation Using Unsymmetrical Vicinal Diamine‐Based Ligands: Dramatic Substituent Effect on Catalyst Efficiency
2011
Tolman’s Electronic Parameters for Divalent Carbon(0) Compounds
2009
Palladium-Catalyzed, Asymmetric Hetero- and Carboannulation of Allenes Using Functionally-Substituted Aryl and Vinylic Iodides
1999
Dihydrogen Complexes as Homogeneous Reduction Catalysts
1998
Ruthenium complexes of aminophosphine ligands and their use as pre-catalysts in the transfer hydrogenation of aromatic ketones: X-ray crystal structure of thiophene-2-(N-diphenylthiophosphino)methylamine
2010
New chiral ruthenium(II)–phosphinite complexes containing a ferrocenyl group in enantioselective transfer hydrogenations of aromatic ketones
2013
The ONIOM Method and Its Applications
2015
Synthesis and Reactivity of Heteroditopic Dicarbene Rhodium(I) and Iridium(I) Complexes Bearing Chelating 1,2,3-Triazolylidene–Imidazolylidene Ligands
2014
N-Benzyl Substituted N-Heterocyclic Carbene Complexes of Iridium(I): Assessment in Transfer Hydrogenation Catalyst
2013
Effizienz in der nichtenzymatischen kinetischen Racematspaltung
2005
Strained Silacycles in Organic Synthesis: A New Reagent for the Enantioselective Allylation of Aldehydes
2002
Disubstituted Imidazolium-2-Carboxylates as Efficient Precursors to N-Heterocyclic Carbene Complexes of Rh, Ru, Ir, and Pd
2005
Symmetry Breaking in Asymmetric Catalysis: Racemic Catalysis to Autocatalysis
2003
Synthesis and Structural Characterization of Monomeric Manganese(II ) N‐Heterocyclic Carbene Complexes [MnX2(C{N(iPr)C(Me)}2)2] (X = Cl, I, and MeCOO)
2004
Palladium-catalyzed asymmetric synthesis of allylic alcohols from unsymmetrical and symmetrical racemic allylic carbonates featuring C–O-bond formation and dynamic kinetic resolution
2005
Synthesis and reactivity of zirconium and hafnium complexes incorporating chelating diamido-N-heterocyclic-carbene ligands
2005
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
2008
Asymmetric transfer hydrogenation of acetophenone derivatives with novel chiral phosphinite based η6-p-cymene/ruthenium(II) catalysts
2011
Konformativ flexible Biphenyl-Phosphanliganden für Ru-katalysierte enantioselektive Hydrierungen
1999 StandoutNobel
A ruthenium(II) bipyridine complex containing a 4,5-diazafluorene moiety: Synthesis, characterization and its applications in transfer hydrogenation of ketones and dye sensitized solar cells
2015
Arene–Ruthenium(II) and −Iridium(III) Complexes with “Click”-Based Pyridyl-triazoles, Bis-triazoles, and Chelating Abnormal Carbenes: Applications in Catalytic Transfer Hydrogenation of Nitrobenzene
2013
Neutral Ligands with Exceptional Donor Ability for Palladium‐Catalyzed Alkene Hydrogenation
2007
Reactivity of chelating dicarbene metal complex catalysts, I: An investigation on the Heck reaction
2006
NHC–Ru complexes—Friendly catalytic tools for manifold chemical transformations
2006
Extending the NHC Concept: C–C Coupling Catalysis by a PdII Carbene (rNHC) Complex with Remote Heteroatoms
2005
Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
2008 Standout
Syntheses and Structures of Alkyl and Aryl Halide Complexes of the Type [(PiPr3)2PtH(η1-XR)]BArf and Analogues with Et2O, THF, and H2 Ligands. Halide-to-Metal π Bonding in Halocarbon Complexes
1996
N-Heterocyclic Carbenes: Synthesis, Structures, and Electronic Ligand Properties,
2006
Cyclometalated cis-Chelated Bidentate N-Heterocyclic Carbene Palladium Complexes: Synthetic, Structural, and Catalytic Studies
2008
Alternative Energy Input for Transfer Hydrogenation using Iridium NHC Based Catalysts in Glycerol as Hydrogen Donor and Solvent
2012
Heterocyclische Carbene
2006
The application of tunable tridendate P‐based ligands for the Ru(II)‐catalysed transfer hydrogenation of various ketones
2014
1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals
2008
The “Reverse-Tethered” Ruthenium (II) Catalyst for Asymmetric Transfer Hydrogenation: Further Applications
2006
Second‐Generation Amino Acid Furanoside Based Ligands from D ‐Glucose for the Asymmetric Transfer Hydrogenation of Ketones
2013
Mechanistic Insights into Transfer Hydrogenation Catalysis by [Ir(cod)(NHC)2]+Complexes with Functionalized N-Heterocyclic Carbene Ligands
2015
New Rhodium(I) Carbene Complexes from Carbene Transfer Reactions
2006
Asymmetric transfer hydrogenation of aromatic ketones catalyzed by the iridium hydride complex under ambient conditions
2004
Iridium phosphine abnormal N-heterocyclic carbene complexes in catalytic hydrogen transfer reactions
2011
Rhodium‐Catalyzed Asymmetric Transfer Hydrogenation of Aryl Alkyl Ketones Employing Ligands Derived from Amino Acids
2007
N-Heterocyclic Carbenes: Versatile Reagents for Nickel-Catalyzed Coupling Reactions
2010
Thermal Activation of Hydrocarbon C−H Bonds by Tungsten Alkylidene Complexes
2001
A Modular Approach to Main-Chain Organometallic Polymers
2005
Ruthenium-Based Olefin Metathesis Catalysts Bearing N-Heterocyclic Carbene Ligands
2009
Thione complexes of Rh(i): a first comparison with the bonding and catalytic activity of related carbene and imine compounds
2004
Synthesis of New Iridium N-Heterocyclic Carbene Complexes and Facile Intramolecular Alkyl C−H Bond Activation Reactions of the Carbene Ligand
2006
Non-Metathesis Ruthenium-Catalyzed C−C Bond Formation
2001
C-Phosphanylated sulfoximines: synthesis and applications in asymmetric allylic substitution reactions
2006
Complete Control of the Chemoselectivity in Catalytic Carbene Transfer Reactions from Ethyl Diazoacetate: An N-Heterocyclic Carbene−Cu System That Suppresses Diazo Coupling
2004
Enantioselective Allylic Substitution of Cinnamyl Esters Catalyzed by Iridium−Chiral Aryl Phosphite Complex: Conspicuous Change in the Mechanistic Spectrum by a Countercation and Solvent
2004
Half-Sandwich Ruthenium(II) Picolyl-NHC Complexes: Synthesis, Characterization, and Catalytic Activity in Transfer Hydrogenation Reactions
2011
First Example of a Gold(I) N‐Heterocyclic‐Carbene‐Based Initiator for the Bulk Ring‐Opening Polymerization of L ‐Lactide
2006
Stereoselective Synthesis of Rhodium(I) 4-(Dialkylamino)triazol-5-ylidene Complexes
2008
Hydrogen Transfer Reduction of Aldehydes with Alkali-Metal Carbonates and Iridium NHC Complexes
2004
Nichtlineare Effekte bei asymmetrischen Synthesen und stereoselektiven Reaktionen
1998
Phosphorus-substituted carbene complexes: Chelates, pincers and spirocycles
2005
Asymmetric Addition of Allylic Stannanes to Aldehydes Catalyzed by BINAP•Ag(I) Complex
2001
Metal complexes with ‘pincer’-type ligands incorporating N-heterocyclic carbene functionalities
2006
Stability and reactivity of N-heterocyclic carbene complexes
2004
Palladium‐Catalyzed Allylic Alkylation with Phosphinoaryldihydrooxazole Ligands: First Evidence and NMR Spectroscopic Structure Determination of a Primary Olefin–Pd0 Complex
1997
BINOL: A Versatile Chiral Reagent
2005 Standout
Bimacrocyclic NHC transition metal complexes
2008
Catalytic iron-carbene intermediate revealed in a cytochrome c carbene transferase
2018 StandoutNobel
Asymmetric Lewis acid organocatalysis of the Diels–Alder reaction by a silylated C–H acid
2016 StandoutScienceNobel
Redox processes involving hydrocarbylmetal (N-heterocyclic carbene) complexes and associated imidazolium salts: ramifications for catalysis
2004
Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation
2003 Standout
The Potential Use of Rhodium N-Heterocyclic Carbene Complexes as Radiopharmaceuticals: The Transfer of a Carbene from Ag(I) to RhCl3·3H2O
2004
Fast transfer hydrogenation using a highly active orthometalated heterocyclic carbene ruthenium catalyst
2005
A Trinuclear Silver(I) Functionalized N-Heterocyclic Carbene Complex and Its Use in Transmetalation: Structure and Catalytic Activity for Olefin Polymerization
2006
Anticancer and Antimicrobial Metallopharmaceutical Agents Based on Palladium, Gold, and Silver N-Heterocyclic Carbene Complexes
2007
Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective
2008 Standout
Use of Achiral and Meso Ligands To Convey Asymmetry in Enantioselective Catalysis
2003
Asymmetric Catalysis of New Generation Chiral Metallosalen Complexes
1999
A New Tridentate Pincer Phosphine/N-Heterocyclic Carbene Ligand: Palladium Complexes, Their Structures, and Catalytic Activities
2004
Synthesis, Structure, and Applications of N-Dialkylamino-N‘-alkylimidazol-2-ylidenes as a New Type of NHC Ligands
2006
Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts
2007
Divergent Enantioselective Synthesis of (−)-Galanthamine and (−)-Morphine
2005
On the Mechanism of the Puzzling “Endocyclic” Skeletal Rearrangement of 1,6‐Enynes
2007
Design of Sterically Demanding, Electron-Rich Carbene Ligands with the Perimidine Scaffold
2007
NHC ligands versus cyclopentadienyls and phosphines as spectator ligands in organometallic catalysis
2005
Quinoline-functionalized N-heterocyclic carbene complexes of iridium: Synthesis, structures and catalytic activities in transfer hydrogenation
2009
Synthesis and Characterization of Palladium(II) π-Allyl Complexes with Chiral Phosphinocarbene Ligands. Kinetics and Mechanism of Allylic Amination
2007
A potentially general intramolecular biaryl coupling approach to optically pure 2,2′-BINOL analogs
1997
Synthesis and Reaction of MnII Iodides Bearing the β‐Diketiminate Ligand: the First Divalent Manganese N‐Heterocyclic Carbene Complexes [{HC(CMeNAr)2}MnI{C[N(iPr)CMe]2}] and [{HC(CMeNAr)2}MnNHAr{C[N(iPr)CMe]2}] (Ar = 2,6‐iPr2C6H3)
2003
Electrospray Ionization Mass Spectrometry Studies on the Mechanism of Hydrosilylation of Terminal Alkynes Using an N-Heterocyclic Carbene Complex of Iridium, Allow Detection/Characterization of All Reaction Intermediates
2006
Syntheses, Structures, and Catalytic Properties of Ruthenium(II) Nitrosyl Complexes with Pyridine-Functionalized N-Heterocyclic Carbenes
2009
Synthesis of chiral N-heterocyclic carbene (NHC) ligand precursors and formation of ruthenium(II) complexes for transfer hydrogenation catalysts
2012
New efficient P,N,O-tridentate ligands for Ru-catalyzed asymmetric transfer hydrogenation
2003
Recent Advances in Osmium-Catalyzed Hydrogenation and Dehydrogenation Reactions
2015
Immobilization of a Rhodium Carbene Complex to an Amphiphilic Block Copolymer for Hydroformylation of 1-Octene under Aqueous Two-Phase Conditions
2004
Kinetic resolution strategies using non-enzymatic catalysts
2003
Phospha-palladacycles and N-heterocyclic carbene palladium complexes: efficient catalysts for CC-coupling reactions
2003
Predicting the Stereochemistry of Diphenylphosphino Benzoic Acid (DPPBA)-Based Palladium-Catalyzed Asymmetric Allylic Alkylation Reactions: A Working Model
2006
A modular design of metal catalysts for the transfer hydrogenation of aromatic ketones
2012
New iminophosphine–Ru(II) complexes and their application in hydrogenation and transfer hydrogenation
2014
N-Heterocyclic Carbenes in the Synthesis of Axially Chiral Square-Planar Platinum Complexes
2007
Hydroxyl and ester functionalized N-heterocyclic carbene complexes of iridium(i ): efficient catalysts for transfer hydrogenation reactions
2014
Tunable ferrocenyl-phosphinite ligands for the ruthenium(II)-catalyzed asymmetric transfer hydrogenation of ketones
2013
Stabilization of Organometallic Species Achieved by the Use of N‐Heterocyclic Carbene (NHC) Ligands
2005
Arylation of Carbonyl Compounds Catalyzed by Rhodium and Iridium 1,3‐R2‐Tetrahydropyrimidin‐2‐ylidenes: Structure‐Reactivity Correlations
2004
Asymmetric Strecker Reactions
2011
Novel neutral phosphinite bridged dinuclear ruthenium(II) arene complexes and their catalytic use in transfer hydrogenation of aromatic ketones: X-ray structure of a new Schiff base, N3,N3′-di-2-hydroxybenzylidene-[2,2′]bipyridinyl-3,3′-diamine
2010
Acceptor substituted N-heterocyclic carbenes and their Rh(I)complexes: Synthesis, structure and properties
2008
Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Rhenium Complexes with Chiral Ferrocenylphosphane Ligands
2012
Total Synthesis of α-Pyrone Meroterpenoids, Novel Bioactive Microbial Metabolites
2005 StandoutNobel
Triaryl phosphine-functionalized N-heterocyclic carbene ligands for Heck reaction
2004
Chiral N-Heterocyclic Carbenes with Restricted Flexibility in Asymmetric Catalysis
2006
Symmetric and dissymmetric N‐heterocyclic carbene rhodium(I) complexes: a comparative study of their catalytic activities in transfer hydrogenation reaction
2012
Synthesis of new boron complexes: application to transfer hydrogenation of acetophenone derivatives
2011
Synthesis of Palladium and Platinum Complexes with Phosphine-Functionalized Benzimidazolin-2-ylidene Ligands
2006
Oxidative Addition of MeI to a Rhodium(I) N-Heterocyclic Carbene Complex. A Kinetic Study
2003
Preparation of a Series of “Ru(p-cymene)” Complexes with Different N-Heterocyclic Carbene Ligands for the Catalytic β-Alkylation of Secondary Alcohols and Dimerization of Phenylacetylene
2008
Synthesis, Structural Characterization, Computational Study, and Catalytic Activity of Metal Complexes Based on Tetradentate Pyridine/N-Heterocyclic Carbene Ligand
2005
Novel cyclohexyl‐based aminophosphine ligands and use of their Ru(II) complexes in transfer hydrogenation of ketones
2014
Iridium(I)-catalysed asymmetric hydrosilylation of ketones using a chiral oxazolylferrocene-phosphine hybrid ligand
1996
Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones
2001 StandoutNobel
Gold(I) N-heterocyclic carbene based initiators for bulk ring-opening polymerization of l-lactide
2007
Development and Applications of Disulfonimides in Enantioselective Organocatalysis
2015 StandoutNobel
Chiral NHC–metal-based asymmetric catalysis
2011
Aus der Sicht des Synthetikers: Palladiumkomplexe N‐heterocyclischer Carbene als Katalysatoren für Kreuzkupplungen
2007
Asymmetric Synthesis of Quaternary Centers. Total Synthesis of (−)-Malyngolide
2000
Enantioselective Oxidative Biaryl Coupling Reactions Catalyzed by 1,5-Diazadecalin Metal Complexes: Efficient Formation of Chiral Functionalized BINOL Derivatives
2003
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Synthesis and Characterization of N‐Heterocyclic Carbene Substituted Phosphine and Phosphite Rhodium Complexes and their Catalytic Properties in Hydrogenation Reactions
2007
Insight into the Mechanism of the Asymmetric Addition of Alkyl Groups to Aldehydes Catalyzed by Titanium−BINOLate Species
2002
Synthesis of New Iridium N-Heterocyclic Carbene Complexes Bearing a Functionalized Cp* Ligand and Their High Catalytic Activities in the Oppenauer-Type Oxidation of Alcohol
2006
The search for new hydrogenation catalyst motifs based on N-heterocyclic carbene ligands
2006
Synthesis and Characterization of a Novel Cobalt Carbonyl N-Heterocyclic Carbene Salt. Crystal Structure of [Co(CO)3(IMes)2]+[Co(CO)4]-
2007
Preparation, Structure, and Olefin Polymerization Behavior of Functionalized Nickel(II) N-Heterocyclic Carbene Complexes
2004
Double CH Activation of an N‐Heterocyclic Carbene Ligand in a Ruthenium Olefin Metathesis Catalyst
2007 Nobel
Flexible, Bowl-Shaped N-Heterocyclic Carbene Ligands: Substrate Specificity in Iridium-Catalyzed Ketone Hydrosilylation
2008
Amino acid derived amides and hydroxamic acids as ligands for asymmetric transfer hydrogenation in aqueous media
2011
The Atom Economy—A Search for Synthetic Efficiency
1991 StandoutScience
Unifying the mechanisms for alkane dehydrogenation and alkene H/D exchange with [IrH2(O2CCF3)(PAr3)2]: the key role of CF3CO2 in the “sticky’' alkane route
2001
Comparative reactivities of hydrocarbon carbon-hydrogen bonds with a transition-metal complex
1989
Readily available ferrocenyl-phosphinite ligands for Ru(II)-catalyzed enantioselective transfer hydrogenation of ketones and fabrication of hybrid heterojunctions
2013
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
2009 Standout
POP–Pincer Ruthenium Complexes: d6 Counterparts of Osmium d4 Species
2014
Mechanistic Investigation of the Hydrogenation of Ketones Catalyzed by a Ruthenium(II) Complex Featuring an N-Heterocyclic Carbene with a Tethered Primary Amine Donor: Evidence for an Inner Sphere Mechanism
2011
Ruthenium(II) carbonyl chloride complexes containing pyridine-functionalised bidentate N-heterocyclic carbenes: Synthesis, structures, and impact of the carbene ligands on catalytic activities
2011
Imidazo[1,5-a]pyridin-3-ylidene/Thioether Mixed C/S Ligands and Complexes Thereof
2007
Preparation, X-ray Structure, and Reactivity of an Osmium-Hydroxo Complex Stabilized by an N-Heterocyclic Carbene Ligand: A Base-Free Catalytic Precursor for Hydrogen Transfer from 2-Propanol to Aldehydes
2008
Imidazolium Carboxylates as Versatile and Selective N-Heterocyclic Carbene Transfer Agents: Synthesis, Mechanism, and Applications
2007
Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands
2008
Enantioselective conjugate addition of diethylzinc to chalcones catalysed by chiral Ni(II) aminoalcohol complexes
1994 StandoutNobel
Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones
2003 Standout
Gold(I) N-Heterocyclic Carbene and Carbazolate Complexes
2005
Comparison of palladium carbene and palladium phosphine catalysts for catalytic coupling reactions of aryl halides
2004
Coordination Versatility of Pyridine-Functionalized N-Heterocyclic Carbenes: A Detailed Study of the Different Activation Procedures. Characterization of New Rh and Ir Compounds and Study of Their Catalytic Activity
2005
Catalysis by Rhodium and Iridium Complexes in the Nucleophilic Addition of Allylic Stannanes to Carbonyl Compounds
1993
Missing cyclization pathways and new rearrangements unveiled in the gold(I) and platinum(II)-catalyzed cyclization of 1,6-enynes
2007
Enantioselective Palladium-Catalysed Allylation of 1,5-Dimethylbarbituric Acid
1998
New N-Heterocyclic Carbene Palladium Complex/Ionic Liquid Matrix Immobilized on Silica: Application as Recoverable Catalyst for the Heck Reaction
2006
Bis-chelate N-heterocyclic tetracarbene Ru(II) complexes: Synthesis, structure, and catalytic activity toward transfer hydrogenation of ketones
2013
Chiral (η6-p-Cymene)ruthenium(II) Complexes Containing Monodentate Acylthiourea Ligands for Efficient Asymmetric Transfer Hydrogenation of Ketones
2014
Synthesis and Structural Characterization of N-Heterocyclic Carbene Complexes of Silver(I) and Rhodium(I) from Caffeine
2004
A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium
2008
Pd‐Komplex‐katalysierte allylische Alkylierung mit Phosphanylaryldihydrooxazol‐Liganden: erster Nachweis und NMR‐spektroskopische Strukturbestimmung eines primären Olefin‐Pd0‐Komplexes
1997
Regio- and Enantioselective Allylic Alkylation of an Unsymmetrical Substrate: A Working Model
1999
Rhodium complexes of PCNHCP: Oxidative addition of dichloromethane and catalytic hydrosilylation of alkynes affording (E)-alkenylsilanes
2005
Heteroleptic ruthenium(II) complexes of 2-(2-pyridyl)benzimidazoles: A study of catalytic efficiency towards transfer hydrogenation of acetophenone
2014
Syntheses, structures and catalytic activities of ruthenium (II) carbonyl iodide complexes with CNC-pincer bis (carbene) ligand
2011
Stable N-functionalised ‘pincer’ bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies
2002
Direct Coupling of Oxazolines and N-Heterocyclic Carbenes: A Modular Approach to a New Class of C−N Donor Ligands for Homogeneous Catalysis
2002
Effective Modulation of the Donor Properties of N-Heterocyclic Carbene Ligands by “Through-Space” Communication within a Planar Chiral Scaffold
2007
Synthesis and Reactivity of New Complexes of Rhodium and Iridium with Bis(dichloroimidazolylidene) Ligands. Electronic and Catalytic Implications of the Introduction of the Chloro Substituents in the NHC Rings
2006
Iridium Abnormal N-Heterocyclic Carbene Hydrides via Highly Selective C−H Activation
2008
Atom-Efficient Catalytic Coupling of Imidazolium Salts with Ethylene Involving Ni−NHC Complexes as Intermediates: A Combined Experimental and DFT Study
2007
Synthesis and Coordination Chemistry of a New Chiral Tridentate PCP N-Heterocyclic Carbene Ligand Based on a Ferrocene Backbone
2004
Synthesis and Characterization of a Saddle-Shaped Nickel−Carbene Complex Derived from an Imidazolium-Linked meta-Cyclophane
2002
Efficient Transfer Hydrogenation Using Iridium and Rhodium Complexes of Benzannulated N‐Heterocyclic Carbenes
2008
Synthesis and structure of N-heterocyclic carbene complexes of rhodium and iridium derived from an imidazolium-linked cyclophane
2005
Ionic liquid based Ru(II)–phosphinite compounds and their catalytic use in transfer hydrogenation: X-ray structure of an ionic compound 1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol
2014
Metal/linked-BINOL complexes: Applications in direct catalytic asymmetric Mannich-type reactions
2005
Non-Symmetrically Substituted 1,1‘-Binaphthyls in Enantioselective Catalysis
2003
High‐Turnover Palladium Catalysts in Cross‐Coupling and Heck Chemistry: A Critical Overview
2004
The Synthesis and X-ray Structure of the First Cobalt Carbonyl−NHC Dimer. Implications for the Use of NHCs in Hydroformylation Catalysis
2004
Synthesis of Chiral Chromans by the Pd-Catalyzed Asymmetric Allylic Alkylation (AAA): Scope, Mechanism, and Applications
2004
Palladium(II) Complexes of a Sterically Bulky, Benzannulated N-Heterocyclic Carbene with Unusual Intramolecular C−H···Pd and Ccarbene···Br Interactions and Their Catalytic Activities
2006
A multimethod study of the adsorption of NO on Ru(001)
1979
Asymmetric hydrosilylation, transfer hydrogenation and hydrogenation of ketones catalyzed by iridium complexes
2009
A-Frame Complexes of Dirhodium Bridged by Dicarbene and Diphosphine Ligands
2008
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
2007
Direct Visualization of the Outer Membrane of Mycobacteria and Corynebacteria in Their Native State
2008 StandoutNobel
New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation
2008
Tandem Catalysis: The Sequential Mediation of Olefin Metathesis, Hydrogenation, and Hydrogen Transfer with Single-Component Ru Complexes
2001 StandoutNobel
Chelating and ‘pincer’ dicarbene complexes of palladium; synthesis and structural studiesElectronic supplementary information (ESI) available: crystallographic data and ORTEP plot for compound 5c. See http://www.rsc.org/suppdata/dt/b2/b209739g/
2003
Flexibility of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis and Their Impact in the First Coordination Sphere of the Metal
2010
Palladium‐Catalyzed Diastereoselective and Enantioselective Allylic Alkylations of Ketone Enolates
2008
Synthesis and Structural Features of Rhodium Complexes of Expanded Ring N‐Heterocyclic Carbenes
2009
Synthesis, Structure, and Reactivity of New Rhodium and Iridium Complexes, Bearing a Highly Electron-Donating PNP System. Iridium-Mediated Vinylic C−H Bond Activation
2002
Diether functionalized rhodium(I)–N-heterocyclic carbene complexes and their catalytic application for transfer hydrogenation reactions
2010
Synthesis and NHC Lability of d0 Lithium, Yttrium, Titanium, and Zirconium Amido Bis(N-heterocyclic carbene) Complexes
2007
Benzothiazolin-2-ylidene Complexes of Iridium(I)
2006
Observations on the intramolecular Heck reactions of aromatic chlorides using palladium/imidazolium salts
2002
Constructing a Stable Carbene with a Novel Topology and Electronic Framework
2003
Bis-N-heterocyclic carbene ruthenium(II) carbonyl complexes: Synthesis, structural characterization and catalytic activities in transfer hydrogenation of ketones
2009
C–H activation with N-heterocyclic carbene complexes of iridium and rhodium
2002
Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren für die ringöffnende metathetische Polymerisation von Cycloolefinen
1998
Ruthenium-Catalyzed Reactions for Organic Synthesis
1998
Synthesis of P- and S-Functionalized Chiral Imidazolium Salts and Their Rh and Ir Complexes
2003
Air stable NHCs: a study of stereoelectronics and metallorganic catalytic activity
2014
Kinetic Resolution of Homoaldols via Catalytic Asymmetric Transacetalization
2010 StandoutNobel
Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Enantiopure Osmium(II) Pybox Complexes
2013
Half-Sandwich Complexes of Osmium(II) withl -α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity
2012
Stable Noncyclic Singlet Carbenes
2009
Titanium catalysed enantioselective addition of allyltributyltin to aldehydes: a simple and easily reproducible procedure
2000
Synthesis of Novel Chelating Benzimidazole-Based Carbenes and Their Nickel(II) Complexes: Activity in the Kumada Coupling Reaction
2009
Self‐Assembly of Several Components into a Highly Enantioselective Ti Catalyst for Carbonyl‐Ene Reactions
1997
Synthesis, Characterization and Catalytic Activity of New N‐Heterocyclic Bis(carbene)ruthenium Complexes
2009
First Examples of Diazepanylidene Carbenes and Their Late-Transition-Metal Complexes
2007
Chiral poisoning in the kinetic resolution of allylic alcohols
1993
A new paradigm in N-heterocyclic carbenoid ligands
2005
Asymmetric synthesis by enantiomer-selective activation of racemic catalysts
1997 Nature
Methyl-palladium(II) complexes of pyridine-bridged bis(nucleophilic heterocyclic carbene) ligands: Substituent effects on structure, stability, and catalytic performance
2006
Indenyl- and Fluorenyl-Functionalized N-Heterocyclic Carbene Complexes of Titanium and Vanadium
2006
Synthesis of monodentate bis(N-heterocyclic carbene) complexes of iridium: Mixed complexes of abnormal NHCs, normal NHCs, and triazole NHCs
2008
Synthetic, Structural, and Thermochemical Studies of N-Heterocyclic Carbene (NHC) and Tertiary Phosphine Ligands in the [(L)2Ni(CO)2] (L = PR3, NHC) System
2008
Olefin‐Gold‐Komplexe, VIII. Cyclooctatetraen‐Goldchlorid‐Komplexe
1974
Interplay of Linker,N-Substituent, and Counterion Effects in the Formation and Geometrical Distortion ofN-Heterocyclic Biscarbene Complexes of Rhodium(I)
2006
Synthesis and Characterization ofN-Heterocyclic Carbene Phospha-Palladacycles and Their Properties in Heck Catalysis
2005
Highly Regio- and Enantioselective Palladium-Catalyzed Allylic Alkylation and Amination of Dienyl Esters with 1,1‘-P,N-Ferrocene Ligands
2005
Highly Diastereoselective Formation of Ruthenium Complexes for Efficient Catalytic Asymmetric Transfer Hydrogenation
2007
Aliphatic versus Aromatic C−H Activation in the Formation of Abnormal Carbenes with Iridium: A Combined Experimental and Theoretical Study
2007
Palladium N-methylimidazolium supported complexes as efficient catalysts for the Heck reaction
2006
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
2006 Standout
Axially chiral P,S-heterodonor ligands with a binaphthalene framework for palladium-catalyzed asymmetric allylic substitutions: experimental investigation on the reversal of enantioselectivity between different alkyl groups on sulfur atom
2004
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
Counter-ion effects switch ligand binding from C-2 to C-5 in kinetic carbenes formed from an imidazolium salt and IrH5(PPh3)2
2002
Sterically Congested “Roofed” 2-Iminothioethers as New Chiral Ligands for Palladium-catalyzed Asymmetric Allylic Alkylation
2005
Synthesis and Catalytic Activity of a Pincer-Type Bis(imidazolin-2-ylidene) Nickel(II) Complex
2006
TiIV‐BINOLate‐Catalyzed Highly Enantioselective Additions of β‐Substituted Allylstannanes to Aldehydes
1996
A Simple Route to Novel Palladium(II) Catalysts with Oxazolin-2-ylidene Ligands
2005
Rhodium(I) complexes containing a bulky pyridinyl N-heterocyclic carbene ligand: Preparation and reactivity
2006
Imidazo[1,5-a]pyridine: A Versatile Architecture for Stable N-Heterocyclic Carbenes
2005
N-Heterocyclic Pincer Dicarbene Complexes of Iron(II): C-2 and C-5 Metalated Carbenes on the Same Metal Center
2003
Influence of the Anion of the Salt Used on the Coordination Mode of an N-Heterocyclic Carbene Ligand to Osmium
2007
Functionalized N-heterocyclic carbene iridium complexes: Synthesis, structure and addition polymerization of norbornene
2008
Stabilization of Fully Reduced Iron−Sulfur Clusters by Carbene Ligation: The [FenSn]0 Oxidation Levels (n = 4, 8)
2008
Reactivity of Phosphane–Imidazolium Salts Towards [Ir(COD)Cl]2: Preparation of New Hydridoiridium(III) Complexes Bearing Abnormal Carbenes
2008
Amine-tethered N-heterocyclic carbene complexes of rhodium(I)
2008
Activation of C−H Bonds by Metal Complexes
1997 Standout
Detour-free synthesis of platinum-bis-NHC chloride complexes, their structure and catalytic activity in the CH activation of methane
2006
Chiral Sulfur Ligands for Asymmetric Catalysis
2007
Pincer Complexes of Palladium- and Nickel-Containing 3-Butyl-1-(1,10-phenanthrolin-2-yl)imidazolylidene as Efficient Aqueous Sonogashira and Kumada Coupling Reactions
2009
Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts
2011
Modular Chelated Palladium Diaminocarbene Complexes: Synthesis, Characterization, and Optimization of Catalytic Suzuki−Miyaura Cross-Coupling Activity by Ligand Modification
2005
An Assessment of Theoretical Protocols for Calculation of the pKa Values of the Prototype Imidazolium Cation
2004
Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands: A quest for understanding
2006
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O)
2008
Synthetic and structural studies of NHC–Pt(dvtms) complexes and their application as alkene hydrosilylation catalysts (NHC = N-heterocyclic carbene, dvtms = divinyltetramethylsiloxane)
2005
Chirale Erkennung in π‐Komplexen von Alkenen, Aldehyden und Ketonen mit Übergangsmetall‐Lewis‐Säuren; Entwicklung eines allgemeinen Modells für enantiofaciale Komplexierungsselektivitäten
1997
Synthesis of Chiral Ferrocenyl Imidazolium Salts and Their Rhodium(I) and Iridium(I) Complexes
2003
Borylation of Aryldiazonium Ions with N-Heterocyclic Carbene−Palladium Catalysts Formed without Added Base
2003
Synthesis of ruthenium(II) N-heterocyclic carbene complexes and their catalytic activities in transfer hydrogenation of ketones
2012
Theoretical Organometallic Chemistry
1981 StandoutScienceNobel
Piano-Stool Iron(II) Complexes as Probes for the Bonding of N-Heterocyclic Carbenes: Indications for π-Acceptor Ability
2006
Ionic Liquids: Media for Better Molecular Catalysis
2004
Applications of transition metal complexes containing aminophosphine ligand to transfer hydrogenation of ketones
2011
Chelating η6‐Arene‐η1‐carbene Ligands in Ruthenium Complexes
2007
Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis
2004
Chromium− and Manganese−salen Promoted Epoxidation of Alkenes
2005
Palladium Complexes with Pyrimidine-Functionalized N-Heterocyclic Carbene Ligands: Synthesis, Structure and Catalytic Activity
2009
Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine
2008
Asymmetric activation of chiral BINOL-zirconium catalysts: Effect of a product-like activator
1998
Mechanistic Features of Iridium Pincer Complex Catalyzed Hydrocarbon Dehydrogenation Reactions: Inhibition upon Formation of a μ-Dinitrogen Complex
1998
Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications
2009
Chiral, bridged bis(imidazolin-2-ylidene) complexes of palladium
2007
Heterocyclische Carbene – Synthese und Koordinationschemie
2008
Donor‐Functionalised N‐Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions
2008
1,8-Bis(imidazolin-2-yliden-1-yl)carbazolide (bimca): A New CNC Pincer-Type Ligand with Strong Electron-Donating Properties. Facile Oxidative Addition of Methyl Iodide to Rh(bimca)(CO)
2007
A Bis-Carbenealkenyl Copper(I) Complex from a Tripodal Tris-Carbene Ligand
2003
Catalytic Asymmetric Epoxidation of α-Branched Enals
2010 StandoutNobel
Synthesis and Ligand Properties of a Persistent, All‐Carbon Four‐Membered‐Ring Allene
2009
Importance of chiral activators in the asymmetric catalysis of Diels-Alder reactions by chiral titanium(IV) complexes
1997
Experimental and Computational Studies on the Mechanism ofN-Heterocycle C−H Activation by Rh(I)
2006
Palladium Catalyzed Kinetic and Dynamic Kinetic Asymmetric Transformations of γ-Acyloxybutenolides. Enantioselective Total Synthesis of (+)-Aflatoxin B1 and B2a
2003
Indenyl- and Fluorenyl-Functionalized N-Heterocyclic Carbene Complexes of Titanium, Zirconium, Vanadium, Chromium, and Yttrium
2007
Kombinatorische Übergangsmetallkatalyse: Mischungen einzähniger Liganden zur Kontrolle der Enantio‐, Diastereo‐ und Regioselektivität
2008
Synthetic and Structural Studies of Silver(I )‐ and Gold(I )‐ContainingN‐Heterocyclic Carbene Metallacrown Ethers
2005
Preparation and X-ray Structures of Alkyl−Titanium(IV) Complexes Stabilized by Indenyl Ligands with a Pendant Ether or Amine Substituent and Their Use in the Catalytic Hydroamination of Alkynes
2006
Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling Reactions
2008
First Enantioselective Alkylations of Monosubstituted Allylic Acetates Catalyzed by Chiral Iridium Complexes
1997
Fluorotitanium Compounds—Novel Catalysts for the Addition of Nucleophiles to Aldehydes
1997
Preferential C-Binding versus N-Binding in Imidazole Depends on the Metal Fragment Involved
2001
Designing a Receptor for Molecular Recognition in a Catalytic Synthetic Reaction: Allylic Alkylation
1996
Direct β-Alkylation of Secondary Alcohols with Primary Alcohols Catalyzed by a Cp*Ir Complex
2005
Tuning the Electronic Properties of N‐Heterocyclic Carbenes
2007
Paraconic Acids—The Natural Products from Lichen Symbiont
2017
Konformation und Struktur von Organometallkomplexen im Festkörper: zwei für das Verständnis chemischer Reaktionen wichtige Studien
1990
Intramolecular Alkyne Hydroalkoxylation and Hydroamination Catalyzed by Iridium Hydrides
2005
Transfer Hydrogenation of Imines Catalyzed by a Nickel(0)/NHC Complex
2003
A New Class of “Tethered” Ruthenium(II) Catalyst for Asymmetric Transfer Hydrogenation Reactions
2004
Rhodium(I) Complexes of New Ferrocenyl Benzimidazol‐2‐ylidene Ligands: The Importance of the Chelating Effect for Ketone Hydrosilylation Catalysis
2009
Rhodium-benzimidazolidin-2-ylidene catalyzed addition of arylboronic acids to aldehydes
2005
New tripodal N-heterocyclic carbene chelators for small molecule activation
2005
Testing Racemic Chiral Catalysts for Kinetic Resolution Potential
2001
The Synthesis of Ruthenium and Rhodium Complexes with Functionalized N‐Heterocyclic Carbenes and Their Use in Solid Phase Peptide Synthesis
2008
N-Heterocyclic carbenes: deducing σ- and π-contributions in Rh-catalyzed hydroboration and Pd-catalyzed coupling reactions
2008
Catalytic Annulation of Heterocycles via a Novel Redox Process Involving the Imidazolium Salt N-Heterocyclic Carbene Couple
2008
Ionic Liquids, 3. Synthesis and Utilisation of Protic Imidazolium Salts in Homogeneous Catalysis
2003
Rhodium‐catalyzed transfer hydrogenation with aminophosphines and analysis of electrical characteristics of rhodium(I) complex/n‐Si heterojunctions
2014
A Cationic 1-(2-Methylpyridine)Phosphole Cymene Ruthenium Chloride Complex as an Efficient Catalyst in the Transfer Hydrogenation of Ketones
2003
Catalytic Enantioselective Arylation of N-Tosylarylimines with Arylboronic Acids Using C2-Symmetric Cationic N-Heterocyclic Carbene Pd2+ Diaquo Complexes
2009
Steric Effects in the Aerobic Oxidation of π-Allylnickel(II) Complexes with N-Heterocyclic Carbenes
2006
Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Systems: Multiple C−H Activation Processes and Isomeric Normal/Abnormal Carbene Complexes
2009
Palladium complexes with ethylene-bridged bis(N-heterocyclic carbene) for C–C coupling reactions
2004
(Diphenylphosphino)alkyl-Functionalized Nucleophilic Carbene Complexes of Palladium
2003
First Cp*-Functionalized N-Heterocyclic Carbene and Its Coordination to Iridium. Study of the Catalytic Properties
2008
Synthesis and Catalytic Activity of Pincer-Type Bis(benzimidazolin-2-ylidene) Palladium Complexes
2005
Convenient Entry to Mono- and Dinuclear Palladium(II) Benzothiazolin-2-ylidene Complexes and Their Activities toward Heck Coupling
2006
Coordination compounds of N,N′-olefin functionalized imidazolin-2-ylidenes
2007
Steric and electronic effects in the bonding of N-heterocyclic ligands to transition metals
2005
Conversion of Propargylic Alcohols to β‐Oxo Esters Catalyzed by Novel Ruthenium‐Phosphoramidite Complexes
2008
Strong Closed-Shell Interactions in Inorganic Chemistry
1997 Standout
Heck and Suzuki coupling reactions in water using poly(2-oxazoline)s functionalized with palladium carbene complexes as soluble, amphiphilic polymer supports
2005
Novel rhodium N-heterocyclic carbene catalysed arylation of aldehydes with phenylboronic acid
2007
Ruthenium-Catalyzed Cycloaddition of Alkynes and Organic Azides
2005 StandoutNobel
1Pyridine and phosphine functionalised N-heterocyclic carbene complexes of rhodium and iridium
2005
Organopalladium intermediates in organic synthesis
1977
A modular design of ruthenium(II) catalysts with chiral C2-symmetric phosphinite ligands for effective asymmetric transfer hydrogenation of aromatic ketones
2010
Synthesis and asymmetric catalytic application of chiral imidazolium–phosphines derived from (1R,2R)-trans-diaminocyclohexane
2005
Carbene Complexes of Rhodium and Iridium from Tripodal N-Heterocyclic Carbene Ligands: Synthesis and Catalytic Properties
2004
Synthesis of a Dirhodium(I) Bisimidazolium Carbene Complex and Catalytic Activity toward Hydroformylation of Olefins. High-Pressure NMR Spectroscopy of the Catalyst under Catalytic Conditions
2002
Efficient Palladium‐Catalyzed Coupling of Aryl Chlorides and Tosylates with Terminal Alkynes: Use of a Copper Cocatalyst Inhibits the Reaction
2003
Arene Ruthenium Complexes as Versatile Catalysts in Water in both Transfer Hydrogenation of Ketones and Oxidation of Alcohols. Selective Deuterium Labeling of rac-1-Phenylethanol
2012
Quinoline-Tethered N-Heterocyclic Carbene Complexes of Rhodium and Iridium: Synthesis, Catalysis, and Electrochemical Properties
2008
Ir(III)-Induced C-Bound to N-Bound Tautomerization of a N-Heterocyclic Carbene
2007
Novel rhodium-1,3-dialkyl-3,4,5,6-tetrahydropyrimidin-2-ylidene complexes as catalysts for arylation of aromatic aldehydes
2005
An Outstanding Catalyst for Asymmetric Transfer Hydrogenation in Aqueous Solution and Formic Acid/Triethylamine.
2006
First Kumada reaction of alkyl chlorides using N-heterocyclic carbene/palladium catalyst systems
2003
Synthesis, structure and catalytic activity of the first iridium(I) siloxide versus chloride complexes with 1,3-mesitylimidazolin-2-ylidene ligand
2007
Hydrogen Migration in Transition Metal Alkyne and Related Complexes
1985 Nobel
Donor‐Functionalised Expanded Ring N‐Heterocyclic Carbenes: Highly Effective Ligands in Ir‐Catalysed Transfer Hydrogenation
2010
Axially chiral dimeric Ir and Rh complexes bridged by flexible NHC ligands
2011
Iridium NHC Based Catalysts for Transfer Hydrogenation Processes Using Glycerol as Solvent and Hydrogen Donor
2011
Iridium Complexes withN-Allyl-Substituted Benzimidazol-2-ylidene Ligands and Their Application in Catalytic Transfer Hydrogenation
2005
Enantioselective Preparation of a Chiral-at-Metal Cp*Ir(NHC) Complex and Its Application in the Catalytic Diboration of Olefins
2007
On the Conformation and Structure of Organometal Complexes in the Solid State: Two Studies Relevant to Chemical Synthesis
1990
Stable non-N-heterocyclic carbenes (non-NHC): recent progress
2004
Transfer Hydrogenation of Ketones and Activated Olefins Using Chelating NHC Ruthenium Complexes
2011
Chloro(η6‐p‐cymene)(phosphoramidite)ruthenium(II), a 16‐Electron Fragment Stabilized by an η2‐Aryl–Metal Interaction, and Its Use in Asymmetric Cyclopropanation
2006
Sequential Formation of [Ru(IPr)2(CO)H(OH2)]+ and [Ru(IPr)(η6-C6H6)(CO)H]+ upon Protonation of Ru(IPr)2(CO)H(OH) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)
2009
Transfer hydrogenation reduction of ketones, aldehydes and imines using chelated iridium(III) N-heterocyclic bis-carbene complexes
2004
Efficient transfer hydrogenation of ketones in the presence of ruthenium N-heterocyclic carbene catalysts
2006
Synthesis, Structure and Stability of New PtII–Bis(N‐Heterocyclic Carbene) Complexes
2006
Isolation of a C5-Deprotonated Imidazolium, a Crystalline “Abnormal” N-Heterocyclic Carbene
2009 Science
Synthesis of new NHC–rhodium and iridium complexes derived from 2,2′-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones
2007
Asymmetric Enamine Catalysis
2007 StandoutNobel
Asymmetrische Aktivierung
2000
Synthesis of iridium complexes with novel planar chiral chelating imidazolylidene ligands
2003
Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
2008 StandoutNobel
New general synthetic methods involving π-allylpalladium complexes as intermediates and neutral reaction conditions
1986
Axially Chiral Bidentate N-Heterocyclic Carbene Ligands Derived from BINAM: Rhodium and Iridium Complexes in Asymmetric Ketone Hydrosilylation
2005
Symmetrically bridged bis-N-heterocyclic carbene rhodium (I) complexes and their catalytic application for transfer hydrogenation reaction
2011
Isolation and Synthesis of Biologically Active Carbazole Alkaloids
2002 Standout
Abnormal and Normal N-Heterocyclic Carbene Osmium Polyhydride Complexes Obtained by Direct Metalation of Imidazolium Salts
2008
Ruthenium(II) Picolyl-NHC Complexes: Synthesis, Characterization, and Catalytic Activity in Amine N-alkylation and Transfer Hydrogenation Reactions
2012
Coinage Metal−N-Heterocyclic Carbene Complexes
2009
Heck reaction catalysed by palladium supported with an electron-rich benzimidazolylidene generated in situ: remarkable ligand electronic effects and controllable mono- and di-arylation
2006
Allylation of Unactivated Ketones by Tetraallyltin Accelerated by Phenol. Application to Asymmetric Allylation Using a Tetraallyltin-BINOL System
1998
Chiral monodentate phosphoramidite ligands control the absolute configuration at pseudotetrahedral ruthenium: asymmetric catalytic cyclopropanation of olefins
2004
N-Heterocyclic Carbene Ligands in Nonsymmetric Diiron Models of Hydrogenase Active Sites
2007
Synthesis and Catalytic Properties of Two Trinuclear Complexes of Rhodium and Iridium with the N-Heterocyclic Tris-carbene Ligand TIMENiPr
2005
Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds
1996 StandoutNobel
Iridium and Ruthenium Complexes with Chelating N-Heterocyclic Carbenes: Efficient Catalysts for Transfer Hydrogenation, β-Alkylation of Alcohols, and N-Alkylation of Amines
2008
Synthetic, Structural, and Mechanistic Studies on the Oxidative Addition of Aromatic Chlorides to a Palladium (N-Heterocyclic Carbene) Complex: Relevance to Catalytic Amination
2003
Ti(IV)/BINOL-catalyzed asymmetric aldol reaction of a masked acetoacetic ester: pronounced influence of catalyst concentration on nonlinear effects
2003
Fluorine/phenyl chelated boron complexes: Synthesis, fluorescence properties and catalyst for transfer hydrogenation of aromatic ketones
2014
Oxidative Addition of Imidazolium Salts to Ni0 and Pd0: Synthesis and Structural Characterization of Unusually Stable Metal–Hydride Complexes
2004
Asymmetric Activation
2000
New Ruthenium(II) CNC-Pincer Bis(carbene) Complexes: Synthesis and Catalytic Activity
2003
Synthesis of Iridium Pyridinyl N-Heterocyclic Carbene Complexes and Their Catalytic Activities on Reduction of Nitroarenes
2007
Synthesis and structural characterisation of rhodium hydride complexes bearing N-heterocyclic carbene ligands
2005
Homogeneous catalysis. transition metal based lewis acid catalysts.
1993
Diene, Alkyne, Alkene, and Alkyl Complexes of Early Transition Metals: Structures and Synthetic Applications in Organic and Polymer Chemistry
1987
Synthesis of Pincer-Type Bis(benzimidazolin-2-ylidene) Palladium Complexes and Their Application in C−C Coupling Reactions
2006
Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis
2011 Nobel
Diaminoarylnickel(II) “Pincer” Complexes: Mechanistic Considerations in the Kharasch Addition Reaction, Controlled Polymerization, and Dendrimeric Transition Metal Catalysts
1998
Multifaceted Coordination of Naphthyridine−Functionalized N-Heterocyclic Carbene: A Novel “IrIII(C∧N)(C∧C)” Compound and Its Evaluation as Transfer Hydrogenation Catalyst
2009
Transfer hydrogenation of ketones catalyzed by new rhodium and iridium complexes of aminophosphine containing cyclohexyl moiety and photosensing behaviors of rhodium and iridium based devices
2014
Efficient and versatile transfer hydrogenation catalysts: Iridium (III) and ruthenium (II) complexes with 4-acetylbenzyl-N-heterocyclic carbenes
2014
A Metal−Organic Framework with Covalently Bound Organometallic Complexes
2010 StandoutNobel
Rhodium Complexes Bearing 1,10-Phenanthroline Analogue Bis-NHC Ligands Are Active Catalysts for Transfer Hydrogenation of Ketones
2012
Catalytic, Enantioselective Addition of Allylsilanes to Aldehydes: Generation of a Novel, Reactive TiIV Complex from TiF4
1996
Irreversible cleavage of a carbene–rhodium bond in Rh-N-heterocyclic carbene complexes: implications for catalysis
2004
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
2015 StandoutScience
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
2008
Novel half‐sandwich η5‐Cp *–rhodium(III) and η5‐Cp *–ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation of aromatic ketones
2013
Synthesis and Decomposition of Alkyl Complexes of Tungsten(IV) That Contain a [(Me3SiNCH2CH2)3N]3- Ligand
1997 StandoutNobel
Visible Light Water Splitting Using Dye-Sensitized Oxide Semiconductors
2009
Kinetic Resolution of 2,3-Dihydro-2-substituted 4-Quinolones by Palladium-Catalyzed Asymmetric Allylic Alkylation
2009
N-Heterocyclic Carbene−Transition Metal Complexes: Spectroscopic and Crystallographic Analyses of π-Back-bonding Interactions
2007
Organolanthanide-Mediated Intramolecular Hydroamination/Cyclization of Conjugated Aminodienes: A Computational Exploration of Diverse Mechanistic Pathways for the Regioselective Generation of Functionalized Azacycles Supported by a Lanthanocene-Based Catalyst Complex
2005
Steric and Electronic Properties of N-Heterocyclic Carbenes (NHC): A Detailed Study on Their Interaction with Ni(CO)4
2005
A Highly Efficient, Recyclable Catalyst for C−C Coupling Reactions in Ionic Liquids: Pyrazolyl-Functionalized N-Heterocyclic Carbene Complex of Palladium(II)
2005
Catalytic asymmetric allylation of aldehydes with BINOL-Ti(IV) complex accelerated by i-PrSSiMe3
1996
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron‐Rich Ligands for Transition‐Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
2005
Polymerization of Norbornene and Methyl Acrylate by a Bimetallic Palladium(II) Allyl Complex
2008
Annulated N-Heterocyclic Carbene Ligands Derived from 2-Methylaminopiperidine: Their Complexes and Catalytic Applications
2008
In situ generated rhodium-based catalyst for addition of phenylboronic acid to aldehydes
2005
Synthesis and Reactivity of Ru(NHC)(dppp)(CO)H2 and Ru(NHC)(dppp)(CO)HF Complexes: C–H and C–F Activation
2009
Works of J.W. Faller being referenced
Acute Pancreatitis and Normoamylasemia
1989
Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex
2001
Effect of ligand asymmetry on the structure and reactivity of CpMLL'(allyl) (Cp = cyclopentadienyl, M = metal, L = ligand) and -(ethylene) complexes
1979 StandoutNobel
Chelated Iridium(III) Bis-carbene Complexes as Air-Stable Catalysts for Transfer Hydrogenation
2002
Ruthenium catalyzed enyne cycloisomerizations and hydroxycyclizations with skeletal rearrangement
2006
General Synthesis of Di-μ-oxo Dimanganese Complexes as Functional Models for the Oxygen Evolving Complex of Photosystem II
2005
Enantioselective Routes to Both Enantiomers of Aryl Alcohols with a Single Catalyst Antipode: Ru and Os Transfer Hydrogenation Catalysts
2001
Organometallic conformational equilibria
1972
Asymmetric synthesis of (+)-2,2,3-trimethylhex-4-enal via nucleophilic attack on .eta.3-1,3-dimethylallyl complexes of molybdenum
1983
Tungsten(VI) hexahydride complexes supported by chelating triphosphine ligands: protonation to give .eta.2-dihydrogen complexes and catalytic dehydrogenation of cyclooctane to cyclooctene
1993
STEREOCHEMICALLY NONRIGID ORGANOMETALLIC MOLECULES, VII. FLUXIONAL BEHAVIOR OF CYCLOOCTATETRAENERUTHENIUM TRICARBONYL
1967
Synthesis, reactivity, and stereochemistry of .eta.4-diene-molybdenum complexes. Metallocyclopentene intermediacy in an intramolecular trans-cis olefin isomerization
1977
The application of ESCA to the study of bonding in nitrosyls
1975
Controlling the regiochemistry of nucleophilic attack on unsymmetrical allyl complexes
1990
[HC(py)3W(NO)2(CO)](SbF6)2 as a Lewis acid precursor in additions of silylated C-nucleophiles to carbonyl compounds
1993
Isotopic perturbation of degeneracy. A new technique for distinguishing monohapto and pentahapto cyclopentadienyl rings in fluxional systems with low rearrangement barriers
1980
An Application of Electronic Asymmetry to Highly Enantioselective Catalytic Diels−Alder Reactions
2001
Tunable Stereoselective Hydrosilylation of PhC⋮CH Catalyzed by Cp*Rh Complexes
2002
Application of the Chiral Poisoning Strategy: Enantioselective Diels−Alder Catalysis with a Racemic Ru/BINAP-Monoxide Lewis Acid
2002
Synthesis and characterization of a planar chiral and chiral-at-metal ruthenium N-heterocyclic carbene complex
2006
Kinetic Resolution and Unusual Regioselectivity in Palladium-Catalyzed Allylic Alkylations with a Chiral P,S Ligand
2004
Abnormal C5-Bound N-Heterocyclic Carbenes: Extremely Strong Electron Donor Ligands and Their Iridium(I) and Iridium(III) Complexes
2004
Reversible α-elimination in the conversion of N–CH3 to N–CHIr by double C–H activation
2001
Chiral poisoning: a novel strategy for asymmetric catalysis
1993
Strong Lewis acids derived from molybdenum and tungsten nitrosyls containing the tri-2-pyridylmethane ligand. Dynamic NMR studies of their adducts with aldehydes, ketones, and esters
1991
Stoichiometric C−C Coupling Reactions in the Coordination Sphere of an Iridium(III) Alkyl
2004
Stereoselectivity in a Chiral Ruthenium Ethylene Hydride Complex: Evidence of an Agostic Intermediate
2007
Chiral Poisoning and Asymmetric Activation
2003
Efficient chiral poisoning of racemic titanium catalysts for the asymmetric chloral-ene reaction
1996
Organometallic conformational equilibria
1975
Control of slippage and conformation in indenyl complexes
1985
Organometallic conformational equilibriums. X. Steric factors and their mechanistic implications in .pi.-allyl(amine)chloropalladium(II) complexes
1971
Chiral poisoning of rac-diop iridium complexes in the catalytic enantioselective hydrogenation of imines
1997
ChemInform Abstract: ORGANOMETALLIC CONFORMATIONAL EQUILIBRIA PART 19, LANTHANIDE SHIFT REAGENT STUDIES OF ROTATIONAL BARRIERS AND PREFERRED ORIENTATIONS IN PHOSPHINE DERIVATIVES OF CYCLOPENTADIENYL COMPLEXES OF IRON AND NICKEL
1975
Enantioselective Hydrosilylation of Ketones with L*/[Rh(COD)Cl]2 and L*/[Ir(COD)Cl]2 Catalysts (L* = Ph2P(O)nCH2CH(NMe2)(CH2)mSMe (n = 0, 1; m = 1, 2))
1994
Novel peroxo- and oxo-alkyl complexes of (pentamethylcyclopentadienyl)tungsten
1988
Paramagnetic phosphine shift reagents. 2. Study of the structures of (substituted-allyl)palladium complexes in solution
1985
Controlling stereochemistry in C-C and C-H bond formation with electronically asymmetric organometallics and chiral poisons
1994
Stereoselective syntheses of some cyclohexene derivatives using complexes of molybdenum
1983
Bis-carbene complexes from oxidative addition of imidazolium C–H bonds to palladium(0)
2002
Diastereoselectivity in Chiral Ruthenium Complexes of Bidentate Bisphosphine Monoxide Ligands: Controlling Epimerization in Aldehyde Complexes and 16-Electron Intermediates
1999
Palladium/BINAP(S)-Catalyzed Asymmetric Allylic Amination
2005
Organometallic conformational equilibriums. XX. Preferred orientations and rotational barriers of .pi.-olefins in chiral tin-iron compounds. The isolation of diastereoisomers in prochiral olefin derivatives
1976
Interplay of Weak Interactions: An Iridium(III) System with an Agostic tert-Butyl but a Nonagostic Isopropyl Group
2002
ChemInform Abstract: ORGANOMETALLIC CONFORMATIONAL EQUILIBRIUMS. XX. PREFERRED ORIENTATIONS AND ROTATIONAL BARRIERS OF Π‐OLEFINS IN CHIRAL TIN‐IRON COMPOUNDS. THE ISOLATION OF DIASTEREOISOMERS IN PROCHIRAL OLEFIN DERIVATIVES
1976
Homogeneous catalytic activation of vinylic carbon-hydrogen bonds. Stereoselective hydrogen-deuterium exchange in neohexene
1985
Stereodynamics and Asymmetric Hydrosilylation with Chiral Rhodium Complexes Containing a Monodentate N-Heterocyclic Carbene
2006
Reversal of stereochemical path in allylic alkylations promoted by palladium and molybdenum complexes
1988
Imine hydrogenation catalyzed by iridium complexes comprising monodentate chiral phosphoramidites and N-donor ligands
2006
Stereospecificity in reactions of activated .eta.3-allyl complexes of molybdenum
1979
A General Strategy for Improving Enantiomeric Purities via the Tandem Use of Mirror-Image Catalysts
2002
Stereoselective formation of substituted tetrahydropyrans by reaction of aldehydes with (.eta.3-allyl)molybdenum complexes
1990
Regioselectivity in the Palladium/(S)-BINAP(S)-Catalyzed Asymmetric Allylic Amination: Reaction Scope, Kinetics, and Stereodynamics
2005
Highly enantioselective Diels–Alder catalysis with a chiral ruthenium bisoxazoline complex
2001
Double Geminal C−H Activation and Reversible α-Elimination in 2-Aminopyridine Iridium(III) Complexes: The Role of Hydrides and Solvent in Flattening the Free Energy Surface
2004
Controlling stereochemistry in crotyl additions to aldehydes with crotylmolybdenum complexes
1989
Enantioselective synthesis of acyclic allylic esters catalyzed by a palladium/BINAP(S) system
2004
Stereoselectivity in nucleophilic addition to unsaturated ligands bound to molybdenum
1985
Retention of configuration in displacement of carbonyl ligands from allyl(cyclopentadienyl)carbonylnitrosylmolybdenum cations
1980
Iridium complexes of some halocarbons and the crystal and molecular structure of cis,trans-[IrH2(o-C6H4I2)(PPh3)2]BF4
1982
Enantioselective Syntheses of Nonracemic Benzyl-α-dAlcohols via Catalytic Transfer-Hydrogenation with Ru, Os, Rh, and Ir Catalysts
2002
Reactivity Differences in the Syntheses of Chelating N-Heterocyclic Carbene Complexes of Rhodium Are Ascribed to Ligand Anisotropy
2004
Organometallic conformational equilibria. VIII. Spin saturation labeling studies of the epimerization and isomerization mechanism of 1,2,3-trihapto-(3-acetyl-2-methylallyl)[(S)-.alpha.-phenethylamine]-chloropalladium(II)
1969
Tridentate Carbene CCC and CNC Pincer Palladium(II) Complexes: Structure, Fluxionality, and Catalytic Activity
2001
Conformational interconversion in the formation of .eta.5-cyclopentadienyl-.eta.3-allylmolybdenum carbonyl nitrosyl cations
1976
Catalysts for the Asymmetric Transfer Hydrogenation of Ketones Derived froml -Prolinamide and (p-CymeneRuCl2)2or (Cp*RhCl2)2
2001
Binding and activation of halocarbons by iron(II) and ruthenium(II)
1990
Palladium Complexes with Tridentate Pincer Bis-Carbene Ligands as Efficient Catalysts for C−C Coupling
2002
Retention of Configuration and Regiochemistry in Allylic Alkylations via the Memory Effect
2004
Outer sphere anion participation can modify the mechanism for conformer interconversion in Pd pincer complexes
2003
A New Chiral at Metal Catalyst for Enantioselective Diels−Alder Reactions: Observation of Isomeric Intermediates
2001
The chemical nature of osmium tetroxide fixation and staining of membranes by X-ray photoelectron spectroscopy
1976
High oxidation state organometallics. Pentamethylcyclopentadienyloxo-molybdenum(VI) and -tungsten(VI) complexes
1988
Dimer-of-Dimers Model for the Oxygen-Evolving Complex of Photosystem II. Synthesis and Properties of [MnIV4O5(terpy)4(H2O)2](ClO4)6
2004
Catalytic Asymmetric Synthesis of Homoallylic Alcohols: Chiral Amplification and Chiral Poisoning in a Titanium/BINOL Catalyst System
1996
Planar Chirality in Tethered η6:η1-(Phosphinophenylenearene-P)ruthenium(II) Complexes and Their Potential Use as Asymmetric Catalysts
2003
Resolution and Diels−Alder Catalysis with Planar Chiral Arene-Tethered Ruthenium Complexes
2005
Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation: Structure and Dynamics
2003
Novel Binding Modes and Hemilability in Atropisomeric Phosphino−Amino Palladium Complexes
2004
Use of organometallic complexes of ruthenium in the Lewis acid catalyzed hetero Diels-Alder reaction
1989
Organometallic conformational equilibriums. XV. Preparation and resolution of 1,2,3-h3-(1-acetyl-2,3-dimethylallyl)[(S)-.alpha.-phenethylamine]chloropalladium
1972
Cycloiridation of α,β-Unsaturated Ketones, Esters, and Acetophenone
2005
Abnormal Ligand Binding and Reversible Ring Hydrogenation in the Reaction of Imidazolium Salts with IrH5(PPh3)2
2002
Stoichiometric and Catalytic Reactions of Thermally Stable Nickel(0) NHC Complexes
2012
Alkynyl germatranes as alternative reagents for the preparation of biarylethynes
2003
Ethylene Insertion into a Ruthenium-Phenyl Bond of a Chiral Lewis Acid. A Facile Method of Preparing Olefin-Hydride Complexes. The Crystal Structure of [CyRuH(C2H3Ph)(PPh3)] SbF6.cntdot.CH2Cl2
1995
Enantioselective syntheses of secondary homoallyl alcohols with optically active .eta.3-allylmolybdenum complexes
1989
Seven-Coordinate Iridium(V) Polyhydrides with Chelating Bis(silyl) Ligands
1995
Preparation and reactions of sulfido and persulfido complexes of (pentamethylcyclopentadienyl)tungsten
1990
Controlling the regioselectivity of nucleophilic addition on unsaturated ligands bound to molybdenum. The cationic [CpMo(NO)(CO)(cyclooctenyl)]+ system
1984
Organometallic conformational equilibria VII. On the planar rotation of π-allyl ligands in metal complexes
1969
Synthesis, characterization and structural investigation of new rhenium-oxo complexes containing bidentate phosphine ligands: an exploration of chirality and conformation in chelate rings of small and large bite angle ligands
2005
New Linear High-Valent Tetranuclear Manganese-Oxo Cluster Relevant to the Oxygen-Evolving Complex of Photosystem II with Oxo, Hydroxo, and Aqua Coordinated to a Single Mn(IV)
2005
Stereochemically Nonrigid Organometallic Compounds. III. Concerning the Structure of Cyclooctatetraeneiron Tricarbonyl in Solution
1966