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1995
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2006
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2000
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1998
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1984
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2001
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Fine Feathers Make Fine Birds: The Heck Reaction in Modern Garb
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Hydrophobic Effects. Opinions and Facts
1993
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2013
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1998
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2008
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2003
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Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media
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Diastereoselective addition of the 2-phenylsulfonyl-substituted allylic bromides to aldehydes in the presence of zinc or chromium (II) chloride
1986
Preparation of α-allenic and β-acetylenic alcohols by treatment of a mixture of Bu,SnCHCCH;; and RCHO with Bu2SnCl2 and water
1985
Highly efficient carbonyl allylation of 1,3-dicarbonyl compounds in aqueous medium
1995
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1999
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1994
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2008
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2004
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1995
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1994 StandoutNobel
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2005
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2013
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1991
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2002
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2013 StandoutNobel
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1990
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1998 Standout
A Push-Button Molecular Switch
2009 StandoutNobel
DNA-Based Asymmetric Catalysis: Sequence-Dependent Rate Acceleration and Enantioselectivity
2008 StandoutNobel
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1999
Selective allylation of carbonyl compounds in aqueous media
1987
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1984
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2005
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2016
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2001
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1996 Standout
Rhenium(VII) Catalysis of Prins Cyclization Reactions
2008
Activation of olefins via asymmetric Brønsted acid catalysis
2018 StandoutScienceNobel
Organometallic Reactions in Aqueous Media. Indium- and Zinc-Mediated Allylation of Sulfonimines1
2000
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2017
Protein Glycoengineering Enabled by the Versatile Synthesis of Aminooxy Glycans and the Genetically Encoded Aldehyde Tag
2011 StandoutNobel
Gallium-mediated allylation of carbonyl compounds in water
2002
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2000
An efficient synthesis of 3-chlorohomoallyl alcohols. Zinc-promoted 2-chloroallylation of carbonyl compounds with 2,3-dichloropropene in an aqueous solvent system
1992
Nitrated Confined Imidodiphosphates Enable a Catalytic Asymmetric Oxa-Pictet–Spengler Reaction
2016 StandoutNobel
Hydrated σ-bonded organometallic cations in organic synthesis
1988
The Proline-Catalyzed Direct Asymmetric Three-Component Mannich Reaction: Scope, Optimization, and Application to the Highly Enantioselective Synthesis of 1,2-Amino Alcohols
2002 StandoutNobel
Kombinatorische Materialforschung und Katalyse
1999
Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones
2019 StandoutNobel
Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides
2003
An Unusual Approach to the Synthesis of Enantiomerically Cis Linear Homoallylic Alcohols Based on the Steric Interaction Mechanism of Camphor Scaffold
2004
Oxonia-Cope Rearrangement and Side-Chain Exchange in the Prins Cyclization
2002
Asymmetric Enamine Catalysis
2007 StandoutNobel
Synthesis of Chiral Cyclopentenones
2016
Aldehyde Selective Wacker Oxidations of Phthalimide Protected Allylic Amines: A New Catalytic Route to β3-Amino Acids
2009 StandoutNobel
A novel one-pot reformatsky type reaction via bismuth salt in aqueous media
1997
Aldehydes from Pd-catalysed oxidation of terminal olefins
2007
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
2000 Standout
Stereodivergent Route to the Carbocyclic Core of 2′,3′-Olefinic Carbanucleosides: Toward the Synthesis of (l )-(+)- and (d )-(−)-Carbovir
2011
New Chiral Synthons for Efficient Introduction of Bispropionates via Stereospecific Oxonia−Cope Rearrangements
2006
Mercury(II )‐ and Palladium(II )‐Catalyzed [3,3]‐Sigmatropic Rearrangements [New Synthetic Methods (46)]
1984
Utilization of an Oxonia-Cope Rearrangement as a Mechanistic Probe for Prins Cyclizations
2005
Recent Advances in the Baylis−Hillman Reaction and Applications
2003 Standout
“Inverse Drug Discovery” Strategy To Identify Proteins That Are Targeted by Latent Electrophiles As Exemplified by Aryl Fluorosulfates
2017 StandoutNobel
Role of 2-Oxonia Cope Rearrangements in Prins Cyclization Reactions
2001
Synthesis of tetrahydropyrans and related heterocycles via prins cyclization; extension to aza-prins cyclization
2009
Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes
1996 StandoutNobel
Catalytic Asymmetric Vinylogous Prins Cyclization: A Highly Diastereo- and Enantioselective Entry to Tetrahydrofurans
2016 StandoutNobel
A Novel Aqueous Barbier-Grignard-Type Allylation of Aldehydes in a Mg/BiCl3 Bimetal System
1997
A Highly Efficient Three-Component Coupling of Aldehyde, Alkyne, and Amines via C−H Activation Catalyzed by Gold in Water
2003
Synthesis of α-Methylene-γ-Lactones via Cr and Sn Complexes of β-Carbethoxy and β-Nitrile Allyl Bromides
1985
Generation of Anti-trypanosomal Agents through Concise Synthesis and Structural Diversification of Sesquiterpene Analogues
2011 StandoutNobel
Works of Junzo Nokami being referenced
Highly Stereoselective Alk-2-enylation of Aldehyde via Allyl-Transfer Reaction
2003
Highly Enantioselective Alk‐2‐enylation of Aldehydes through an Allyl‐Transfer Reaction
2003
A New Synthetic Method for β-Substituted γ-Butyrolactones via Palladium-Catalyzed Reaction of 2-Butene-1,4-diol with Aryl and 1-Alkenyl Halides, and Subsequent Oxidation
1990
Facile one-pot synthesis of bromo homoallyl alcohols and 1,3-keto acetates via allyltin intermediates
1984
Stereoselective 4-Benzyloxybut-2-enylation of Aldehydes via an Allyl-Transfer Reaction Using a Chiral Allyl Donor
2005
A Novel Enantioselective (2Z)-Alk-2-enylation of Aldehydes via an Allyl-Transfer Reaction from Chiral Allyl Donors Prepared from (+)-Isomenthone
2004
FACILE SYNTHESIS OF 2-METHYLENE-4-BUTYROLACTONES
1986
Electrochemical O-glycosylation using thioglycosides as glycosyl donors in the presence of a catalytic amount of sodium trifluoromethanesulfonate as a supporting electrolyte
2007
Highly Enantioselective Alk‐2‐enylation of Aldehydes through an Allyl‐Transfer Reaction
2003
New and Stereoselective Synthesis of 1,4-Disubstituted Buten-4-ols (Homoallylic Alcohol α-Adducts) from the Corresponding γ-Isomers (3,4-Disubstituted Buten-4-ols) via an Acid-Catalyzed Allyl-Transfer Reaction with Aldehydes
2000
Allylation of aldehydes and ketones in the presence of water by allylic bromides, metallic tin, and aluminum
1983
Convenient synthesis of a marine cyclopentanoid: untenone A
2010
A new synthetic method for γ-butyrolactols by the paladium-catalyzed regioselective oxidation of 1-alken-4-ols
1988
Convenient synthesis of highly optically active 2,3,4,6-tetrasubstituted tetrahydropyrans via Prins cyclization reaction (PCR) of optically active homoallylic alcohols with aldehydes
2006
Palladium-catalyzed coupling reactions of bromobenzaldehydes with 3,4-di(tert-butyldimethylsilyloxy)-1-alkene to (3,4-dihydroxyalkenyl)benzaldehydes in the synthesis of lipoxin analogues
1998
A new chiral disulfonamide ligand derived from α-amino acid for catalytic enantioselective cyclopropanation
1997
β-Disulfoxides. II. The Preparation of Some Optically Active β-Disulfoxides
1976
INTRAMOLECULAR ALLYLATION OF CARBONYL COMPOUNDS. A NEW METHOD FOR FIVE AND SIX MEMBERED RING FORMATION
1984
A new total synthesis of dl-sirenin
1983
Efficient Electrochemical N-Glycosylation of Silylated Pyrimidines with Protected Arylthioriboses in the Presence of a Catalytic Amount of NBS or Br2
1999
The First and Highly Enantioselective Crotylation of Aldehydes via an Allyl-Transfer Reaction from a Chiral Crotyl-Donor
2001
The palladium-catalyzed directed aldol reaction of aldehydes with ketone enolates generated by the decarboxylation of allyl .beta.-keto carboxylates under neutral conditions
1989
Palladium-catalyzed Chemoselective Reaction of Allylic Carbonate with Nucleoside Bases and Its Application for the Synthesis of Carbocyclic Nucleosides. (−)- and (+)-Carbovirs
1994
REACTION OF PROPARGYL BROMIDE AND TRIMETHYLSILYLPROPARGYL IODIDE WITH METALLIC TIN, ALUMINUM, AND ALDEHYDES OR KETONES. SELECTIVE SYNTHESIS OF β-ACETYLENE, β-TRIMETHYLSILYLACETYLENE, AND α-TRIMETHYLSILYLALLENE ALCOHOLS
1984
Facile transformation of substituted allyl malonates to monocarboxylic acids and esters by the reaction with ammonium formate catalyzed by palladium complexes
1989
New Concept in the Allylation of Aldehydes: Regiospecific Allylation of Aldehydes by an Allyl-Transfer Reaction of Homoallylic Alcohols
1998
New Route toα-Adducts of Homoallylic Alcohols by an Acid-Catalyzed Stereospecific Allyl-Transfer Reaction fromγ-Adducts
2000
New synthetic reaction by electrolysis malonic acid as a ketone synthon
1979
Design, Synthesis, and Biological Evaluation of Artemisinin-Indoloquinoline Hybrids as Potent Antiproliferative Agents
2014
Spiroannelation via intramolecular ketocarbenoid addition. Stereocontrolled synthesis of (-)-acorenone B and (.+-.)-.alpha.-chamigrene
1981