Standout Papers
Citation Impact
Citing Papers
Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life
2016 StandoutScienceNobel
Palladium-catalyzed amination and cyclization to heteroannellated indoles and carbazoles
2003
Palladium-catalyzed N-arylation of 2-aminobenzothiazole-4-carboxylates/carboxamides: facile synthesis of PARP14 inhibitors
2014
Pd-catalyzed amidation of aryl(Het) halides with tert-butyl carbamate
2010
Single-crystal x-ray diffraction structures of covalent organic frameworks
2018 StandoutScienceNobel
Palladium-catalyzed Suzuki–Miyaura cross-coupling reaction of potassium 2-pyridyl trifluoroborate with aryl (heteroaryl) halides
2011
2- and 3-substituted imidazo[1,2-a]pyrazines as inhibitors of bacterial type IV secretion
2014
Novel synthetic routes to thienocarbazoles via palladium or copper catalyzed amination or amidation of arylhalides and intramolecular cyclization
2002
Synthesis of 3-alkoxycarbonyl-1β-methylcarbapenem using palladium-catalyzed amidation of vinyl halide
2002
N‐Trialkylsilylimines as Coupling Partners for Pd‐Catalyzed CN Bond‐Forming Reactions: One‐Step Synthesis of Imines and Azadienes from Aryl and Alkenyl Bromides
2003
A soluble polyethyleneglycol-anchored phosphine as a highly active, reusable ligand for Pd-catalyzed couplings of aryl chlorides: comparison with cross and non-cross-linked polystyrene and silica supports
2007
Structure–activity relationship (SAR) investigations of substituted imidazole analogs as TRPV1 antagonists
2007
Design of New Ligands for the Palladium‐Catalyzed Arylation of α‐Branched Secondary Amines
2015
A Convenient Procedure for the Palladium‐Catalyzed Cyanation of Aryl Halides
2003
Synthesis of pyrido[2,3-b]indoles and pyrimidoindoles via Pd-catalyzed amidation and cyclization
2012
Synthesis of two novel dinuclear palladium(i ) complexes and studies of their catalytic activity in amination reactions
2004
Multi-component syntheses of heterocycles by transition-metal catalysis
2007
Ammonia: An Environmentally Friendly Nitrogen Source for Primary Aniline Synthesis
2010
Synthesis of (±)‐Tetrapetalone A‐Me Aglycon
2014
Iron‐Catalyzed CO Cross‐Couplings of Phenols with Aryl Iodides
2007
Azaborine Compounds for Organic Field‐Effect Transistors: Efficient Synthesis, Remarkable Stability, and BN Dipole Interactions
2013
Cross‐Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)
2011 StandoutNobel
Development of a general route to periphery-functionalized azaborines and ladder-type azaborines by using common intermediates
2007
The syntheses and catalytic applications of unsymmetrical ferrocene ligands
2004
A new reactivity pattern for vinyl bromides: cine-substitution via palladium catalysed C–N coupling/Michael addition reactions
2005
N-Acridin-9-yl-butane-1,4-diamine derivatives: high-affinity ligands of the α2δ subunit of voltage gated calcium channels
2004
Discovery of heterobicyclic templates for novel metabotropic glutamate receptor subtype 5 antagonists
2007
An N‐Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross‐Coupling of Sterically Hindered Aryl Chlorides at Room Temperature
2003
Transmetalation in the Suzuki–Miyaura Coupling: The Fork in the Trail
2013
Chemoselective Benzylic CH Activations for the Preparation of Condensed N‐Heterocycles
2006
Suzuki–Miyaura Coupling Reaction by PdII‐Catalyzed Aromatic CH Bond Activation Directed by an N‐Alkyl Acetamino Group
2007
Palladium catalyzed amination of vinyl chlorides: a new entry to imines, enamines and 2-amino-1,3-butadienes
2004
Palladium‐Catalyzed Cross‐Coupling Reactions of Amines with Alkenyl Bromides: A New Method for the Synthesis of Enamines and Imines
2004
Palladium- and copper-mediated N-aryl bond formation reactions for the synthesis of biological active compounds
2011
Carbon–heteroatom bond formation catalysed by organometallic complexes
2008 StandoutNature
Palladium catalysed aryl amination reactions in supercritical carbon dioxide
2005
Amination of Benzylic CH Bonds by Arylazides Catalyzed by CoII–Porphyrin Complexes: A Synthetic and Mechanistic Study
2002
Highly Functionalized Organomagnesium Reagents Prepared through Halogen–Metal Exchange
2003
N-Aryl 2,6-Dimethoxybiphenylalanine Analogues as VLA-4 Antagonists
2002
Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling
2009
Synthesis and catalytic activity of a poly(N,N-dialkylcarbodiimide)/palladium nanoparticle composite: a case in the Suzuki coupling reaction using microwave and conventional heating
2004
Highly Active Palladium/Activated Carbon Catalysts for Heck Reactions: Correlation of Activity, Catalyst Properties, and Pd Leaching
2002
Coupling of ortho-substituted aryl chlorides with bulky amides
2011
The Azaallylic Anion as a Synthon for Pd‐Catalyzed Synthesis of Heterocycles: Domino Two‐ and Three‐Component Synthesis of Indoles
2007
8-Fluoroimidazo[1,2-a]pyridine: Synthesis, physicochemical properties and evaluation as a bioisosteric replacement for imidazo[1,2-a]pyrimidine in an allosteric modulator ligand of the GABAA receptor
2006
A General Palladium‐Catalyzed Amination of Aryl Halides with Ammonia
2009
Antitumour polycyclic acridines. Palladium(0 ) mediated syntheses of quino[4,3,2-kl]acridines bearing peripheral substituents as potential telomere maintenance inhibitors
2003
Selection of boron reagents for Suzuki–Miyaura coupling
2013 Standout
The First Phosphine Oxide Ligand Precursors for Transition Metal Catalyzed Cross-Coupling Reactions: C−C, C−N, and C−S Bond Formation on Unactivated Aryl Chlorides
2001
Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process
2012
Orthopalladated and ‐platinated Bulky Triarylphosphite Complexes: Synthesis, Reactivity and Application as High‐Activity Catalysts for Suzuki and Stille Coupling Reactions
2003
A Flexible and Catalytic One‐Pot Procedure for the Synthesis of Indoles
2003
Ligand‐Promoted ortho‐CH Amination with Pd Catalysts
2015
A Convenient Oxime-Carbapalladacycle-Catalyzed Suzuki Cross-Coupling of Aryl Chlorides in Water
2002
Intermolecular Olefin Functionalisation Involving Aryl Radicals Generated from Arenediazonium Salts
2008
Identification of purine inhibitors of phosphodiesterase 7 (PDE7)
2004
Cascade Alkenyl Amination/Heck Reaction Promoted by a Bifunctional Palladium Catalyst: A Novel One‐Pot Synthesis of Indoles from o‐Haloanilines and Alkenyl Halides
2005
Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides
2003
Selective Monoarylation of Primary Amines Using the Pd‐PEPPSI‐IPentCl Precatalyst
2015
Palladium-catalyzed sequential one-pot reaction of aryl bromides with O-homoallylhydroxylamines: synthesis of N-aryl-β-amino alcohols
2007
Synthesis and X-ray Structure Determination of Highly Active Pd(II), Pd(I), and Pd(0) Complexes of Di(tert-butyl)neopentylphosphine (DTBNpP) in the Arylation of Amines and Ketones
2010
Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality
2009 Standout
Ammonium salts as an inexpensive and convenient nitrogen source in the Cu-catalyzed amination of aryl halides at room temperature
2008
Palladium‐Catalyzed Aryl Amination–Heck Cyclization Cascade: A One‐Flask Approach to 3‐Substituted Indoles
2007
Palladium‐Catalyzed Cross‐Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize
2012 Standout
Unparalleled Rates for the Activation of Aryl Chlorides and Bromides: Coupling with Amines and Boronic Acids in Minutes at Room Temperature
2002
Acceleration of Reductive Elimination of [Ar‐Pd‐C] by a Phosphine/Electron‐Deficient Olefin Ligand: A Kinetic Investigation
2009
On the industrial applications of MCRs: molecular diversity in drug discovery and generic drug synthesis
2010
Synthesis of Indolines and Tetrahydroisoquinolines from Arylethylamines by PdII‐Catalyzed CH Activation Reactions
2008
Widely Applicable Pd‐Catalyzed trans‐Selective Monoalkylation of Unactivated 1,1‐Dichloro‐1‐alkenes and Pd‐Catalyzed Second Substitution for the Selective Synthesis of E or Z Trisubstituted Alkenes
2005 StandoutNobel
Palladium catalyzed alkenyl amination: from enamines to heterocyclic synthesis
2005
Relativistic Functional Groups: Aryl Carbon–Gold Bond Formation by Selective Transmetalation of Boronic Acids
2006
Direct amination of aryl halides with ammonia
2010
CuI-catalyzed intramolecular O-vinylation of carbonyl compounds
2005
4,5-Dihydro-1H-pyrazolo[4,3-h]quinazolines as potent and selective Polo-like kinase 1 (PLK1) inhibitors
2010
Suzuki–Miyaura Cross‐Coupling Reactions in Aqueous Media: Green and Sustainable Syntheses of Biaryls
2010
Atroposelective Synthesis of Axially Chiral Biaryl Compounds
2005 Standout
A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes
2004
Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
2003 Standout
Synthesis of the kappa-agonist CJ-15,161 via a palladium-catalyzed cross-coupling reaction
2002
Annulative Tandem Reactions Based on Pd0/tBu3P‐Catalyzed Cross‐Coupling and C(sp3)H Bond Activation
2006
A More Efficient Catalyst for the Carbonylation of Chloroarenes
2001
Solid-phase analogue synthesis of caspase-3 inhibitors via palladium-catalyzed amination of 3-bromopyrazinones
2007
Total Synthesis Guided Structure Elucidation of (+)‐Psychotetramine
2011
Catalytic Organometallic Reactions of Ammonia
2010
Organosulfur Compounds: Electrophilic Reagents in Transition‐Metal‐Catalyzed Carbon–Carbon Bond‐Forming Reactions
2005
The Mechanisms of the Stille Reaction
2004
From Dioxin to Drug Lead—The Development of 2,3,7,8‐Tetrachlorophenothiazine
2007
Synthesis of 7‐Aminocoumarin by Buchwald–Hartwig Cross Coupling for Specific Protein Labeling in Living Cells
2010
Planar chiral [2.2]paracyclophane-based bis(thiourea) catalyst: application to asymmetric Henry reaction
2013
Synthesis of 3,7‐Disubstituted Imipramines by Palladium‐Catalysed Amination/Cyclisation and Evaluation of Their Inhibition of Monoamine Transporters
2011
Delta agonist hydroxy bioisosteres: The discovery of 3-((1-benzylpiperidin-4-yl){4-[(diethylamino)carbonyl]phenyl}amino)benzamide with improved delta agonist activity and in vitro metabolic stability
2009
Advances in Functional‐Group‐Tolerant Metal‐Catalyzed Alkyl–Alkyl Cross‐Coupling Reactions
2003
Catalytic Asymmetric Cross‐Couplings of Racemic α‐Bromoketones with Arylzinc Reagents
2008
A Mild, One‐Pot Stadler–Ziegler Synthesis of Arylsulfides Facilitated by Photoredox Catalysis in Batch and Continuous‐Flow
2013
Ru(ii)-catalyzed intermolecular ortho-C–H amidation of aromatic ketones with sulfonyl azides
2013
A Triphenylamine Double‐Decker: From a Delocalized Radical Cation to a Diradical Dication with an Excited Triplet State
2012
Pd‐Catalyzed Amination of Nucleoside Arylsulfonates to yield N6‐Aryl‐2,6‐Diaminopurine Nucleosides
2004
The Double N‐Arylation of Primary Amines: Toward Multisubstituted Carbazoles with Unique Optical Properties
2003
Palladium-catalyzed coupling of functionalized primary and secondary amines with aryl and heteroaryl halides: two ligands suffice in most cases
2010
4-(Anilino)pyrrole-2-carboxamides: Novel non-steroidal/non-anilide type androgen antagonists effective upon human prostate tumor LNCaP cells with mutated nuclear androgen receptor
2008
Homogeneous Catalysts Supported on Soluble Polymers: Biphasic Suzuki–Miyaura Coupling of Aryl Chlorides Using Phase‐Tagged Palladium–Phosphine Catalysts
2004
Novel non-steroidal/non-anilide type androgen antagonists: discovery of 4-substituted pyrrole-2-carboxamides as a new scaffold for androgen receptor ligands
2005
Diazaspirocyclic compounds as selective ligands for the α4β2 nicotinic acetylcholine receptor
2012
Highly Reactive, General, and Long‐Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles
2005
Significantly Improved Method for the Pd‐Catalyzed Coupling of Phenols with Aryl Halides: Understanding Ligand Effects
2006
The first tandem double palladium-catalyzed aminations: synthesis of dipyrido[1,2-a∶3′,2′-d]imidazole and its benzo- and aza-analogues
2004
Highly Efficient and Mild Copper‐Catalyzed N‐ and C‐Arylations with Aryl Bromides and Iodides
2004
A General Method for the Direct α‐Arylation of Aldehydes with Aryl Bromides and Chlorides
2007
An active ferrocenyl triarylphosphine for palladium-catalyzed Suzuki–Miyaura cross-coupling of aryl halides
2004
Estrogen receptor ligands. Part 5: The SAR of dihydrobenzoxathiins containing modified basic side chains
2004
Efficient and recyclable dendritic Buchwald-type catalyst for the Suzuki reaction
2007
Discovery of potent and liver-targeted stearoyl-CoA desaturase (SCD) inhibitors in a bispyrrolidine series
2011
PdII‐Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands
2008
Concise total synthesis of the aporphine alkaloid 7,7′-bisdehydro-O-methylisopiline by an InCl3mediated cycloisomerization reaction
2003
Monodentate Phosphines Provide Highly Active Catalysts for Pd‐Catalyzed CN Bond‐Forming Reactions of Heteroaromatic Halides/Amines and (H)N‐Heterocycles
2006
Sterically demanding trialkylphosphines for palladium-catalyzed cross coupling reactions—alternatives to PtBu3
2009
Advances in selective activation and application of ammonia in homogeneous catalysis
2010
Novel method for the synthesis of enamines by palladium catalyzed amination of alkenyl bromides
2002
Catalytic CH Amination with Unactivated Amines through Copper(II) Amides
2010
Rapid Access to Oxindoles by the Combined Use of an Ugi Four-Component Reaction and a Microwave-Assisted Intramolecular Buchwald−Hartwig Amidation Reaction
2006
Asymmetric Synthesis of Antimicrotubule Biaryl Hybrids of Allocolchicine and Steganacin
2007
Biaryl Phosphane Ligands in Palladium‐Catalyzed Amination
2008 Standout
Palladium‐Catalyzed Three‐Component Approach to Promazine with Formation of One Carbon–Sulfur and Two Carbon–Nitrogen Bonds
2008
A Versatile and Efficient Ligand for Copper‐Catalyzed Formation of CN, CO, and PC Bonds: Pyrrolidine‐2‐Phosphonic Acid Phenyl Monoester
2006
A ferrocene based palladacyclic precatalyst for the Suzuki cross-coupling of aryl chlorides
2003
Preparation and Characterization of N‐Anisyl‐Substituted Hexaaza[16]paracyclophane
2010
Metal‐Catalyzed α‐Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization
2010
Diels–Alder Approach to Polysubstituted Biaryls: Rapid Entry to Tri‐ and Tetra‐ortho‐substituted Phosphorus‐Containing Biaryls
2006
Evidence for the Formation and Structure of Palladacycles during Pd‐Catalyzed CN Bond Formation with Catalysts Derived from Bulky Monophosphinobiaryl Ligands
2006
An straightforward entry to new pyrazolo-fused dibenzo[1,4]diazepines
2011
Progress in the Palladium‐Catalyzed Cyanation of Aryl Chlorides
2003
Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes
2016
Controlled Microwave Heating in Modern Organic Synthesis
2004 Standout
New Ligands for a General Palladium‐Catalyzed Amination of Aryl and Heteroaryl Chlorides
2004
Carbon–carbon bonding made easy
2005 StandoutNobel
Rational Ligand Design in Constructing Efficient Catalyst Systems for Suzuki–Miyaura Coupling
2004
CuI catalyzed N-arylation of amide as a key step for the preparation of 3-aryl β-carbolin-1-ones
2004
One‐Pot Synthesis of Polyheterocycles by a Palladium‐Catalyzed Intramolecular N‐Arylation/CH Activation/Aryl–Aryl Bond‐Forming Domino Process
2003
Palladium-Catalyzed Amidation of Aryl Halides Using 2-Dialkylphosphino-2′-alkoxyl-1,1′-binaphthyl as Ligands
2012
Redefining the structure–activity relationships of 2,6-methano-3-benzazocines. Part 7: Syntheses and opioid receptor properties of cyclic variants of cyclazocine
2008
The B-Alkyl Suzuki-Miyaura Cross-Coupling Reaction: Development, Mechanistic Study, and Applications in Natural Product Synthesis
2001
Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups
2011
Metal‐Catalyzed Cycloetherification Reactions of β,γ‐ and γ,δ‐Allendiols: Chemo‐, Regio‐, and Stereocontrol in the Synthesis of Oxacycles
2010
Monoligated Palladium Species as Catalysts in Cross‐Coupling Reactions
2004
Copper/Amino Acid Catalyzed Cross-Couplings of Aryl and Vinyl Halides with Nucleophiles
2008
Atroposelective Synthesis of Axially Chiral Biaryl Compounds
2005
Selective palladium-catalyzed amination of the heterocyclic core of variolins
2007
Oligoarene Strategy for Catalyst Development. Hydroxylated Oligoarene-type Phosphines for Palladium-catalyzed Cross Coupling
2007
PdII‐Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands
2008
A modular route to nonracemic cyclo-NOBINs. Preparation of the parent ligand for homo- and heterogeneous catalysis
2004
Efficient Synthesis of Well-Defined, High Molecular Weight, and Processible Polyanilines under Mild Conditions via Palladium-Catalyzed Amination
2000
Syntheses and characterizations of methylpalladium complexes bearing a biphenyl-based bulky phosphine ligand: Weak interactions suggested by NBO and QTAIM analyses
2006
Novel Synthesis of Carbapenam by Intramolecular Attack of Lactam Nitrogen toward η1-Allenyl and η3-Propargylpalladium Complex
2003
A Comparison of Cationic Zirconium Methyl and Isobutyl Initiators that Contain an Arylated Diamido-Pyridine Ligand for Polymerization of 1-Hexene. Elucidation of a Dramatic “Initiator Effect”
2000 StandoutNobel
Nickel-on-Charcoal-Catalyzed Aromatic Aminations and Kumada Couplings: Mechanistic and Synthetic Aspects
2002
Can a Ketone Be More Reactive than an Aldehyde? Catalytic Asymmetric Synthesis of Substituted Tetrahydrofurans
2018 StandoutNobel
Synthesis of Bulky Phosphines by Rhodium-Catalyzed Formal [2 + 2 + 2] Cycloaddition Reactions of Tethered Diynes with 1-Alkynylphosphine Sulfides
2007
Palladium-catalyzed cross-coupling reaction of organic halides with Grignard reagents, organolithium compounds and heteroatom nucleophiles
2002
Highly Efficient Suzuki Coupling Reaction of α‐Chloroalkylidene‐β‐lactones and β‐Lactams with Organoboronic Acids
2006
Cross-Coupling Reactions of Aromatic and Heteroaromatic Silanolates with Aromatic and Heteroaromatic Halides
2009
A Novel Synthesis of 2-Aryl-2H-indazoles via a Palladium-Catalyzed Intramolecular Amination Reaction
2000
Synthesis of Tetra-ortho-substituted, Phosphorus-Containing and Carbonyl-Containing Biaryls Utilizing a Diels−Alder Approach
2007
Triazole-Based Monophosphines for Suzuki−Miyaura Coupling and Amination Reactions of Aryl Chlorides
2005
Pd(II)-Catalyzed Cross-Coupling of sp3 C−H Bonds with sp2 and sp3 Boronic Acids Using Air as the Oxidant
2008
Rhodium(III)-Catalyzed C–H Activation and Amidation of Arenes Using N-Arenesulfonated Imides as Amidating Reagents
2013
Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis
2008 Standout
Asymmetric Synthesis of Axially Chiral Biaryls via Desymmetrization of 2,2‘,6,6‘-Tetrahydroxybiphenyl Using 1,4-Di-O-benzyl-l -threitol as a Chiral Template
2000
Remarkably selective palladium-catalyzed amination process: Rapid assembly of multiamino based structures
1998
Synthesis of pinacol arylboronates via cross-coupling reaction of bis(pinacolato)diboron with chloroarenes catalyzed by palladium(0)–tricyclohexylphosphine complexes
2001
Mild conditions for Pd-catalyzed conversion of aryl bromides to primary anilines using benzophenone imine
2009
Optimization and Scale-up of a Pd-Catalyzed Aromatic C−N Bond Formation: A Key Step in the Synthesis of a Novel 5-HT1B Receptor Antagonist
2008
Amination of aryl halides using copper catalysis
2001
Synthesis of Indolines and Tetrahydroisoquinolines from Arylethylamines by PdII‐Catalyzed CH Activation Reactions
2008
Nickel on Charcoal (“Ni/C”): An Expedient and Inexpensive Heterogeneous Catalyst for Cross-Couplings between Aryl Chlorides and Organometallics. I. Functionalized Organozinc Reagents
1999
Distinguishing Between Pathways for Transmetalation in Suzuki−Miyaura Reactions
2011
Convergent Synthesis of Complex Diketopiperazines Derived from Pipecolic Acid Scaffolds and Parallel Screening against GPCR Targets
2006
Cross-Coupling Reactions of Organosilicon Compounds: New Concepts and Recent Advances.
2002
Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides
1998
Palladium-catalyzed N-arylation of O-methylamidoximes
2002
Cross-Coupling Reactions of Arylsilanols with Substituted Aryl Halides
2003
Triazole-Based Monophosphine Ligands for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Chlorides
2006
CuI-Catalyzed Tandem Intramolecular Amidation Using gem-Dibromovinyl Systems
2006
Accelerating Effect Induced by the Structure of α-Amino Acid in the Copper-Catalyzed Coupling Reaction of Aryl Halides with α-Amino Acids. Synthesis of Benzolactam-V8
1998
Strictly Regiocontrolled α-Monosubstitution of Cyclic Carbonyl Compounds with Alkynyl and Alkyl Groups via Pd-Catalyzed Coupling of Cyclic α-Iodoenones with Organozincs
2000 StandoutNobel
Efficient Nickel-Mediated Intramolecular Amination of Aryl Chlorides
2003
Multiple Arylation of Phenols around the Oxygen under Palladium Catalysis
1999
Palladium‐Catalyzed CN and CO Coupling–A Practical Guide from an Industrial Vantage Point†
2004
Stereoselective Radical Amination of Electron-Deficient C(sp3)–H Bonds by Co(II)-Based Metalloradical Catalysis: Direct Synthesis of α-Amino Acid Derivatives via α-C–H Amination
2012
Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation: Dissecting the Importance of Chelation and Steric Hindrance
1999
Copper-catalyzed amination of aryl halides: single-step synthesis of triarylamines
2002
Copper-Promoted C−N Bond Cross-Coupling with Hypervalent Aryl Siloxanes and Room-Temperature N-Arylation with Aryl Iodide
2000
Pd-Catalyzed N-Arylation of Heteroarylamines
2002
Microwave-assisted organic synthesis: scale-up of palladium-catalyzed aminations using single-mode and multi-mode microwave equipment
2005
Nickel-catalysed sequential amination of aryl- and heteroaryl di- and trichlorides
2001
Rh[III]-Catalyzed C–H Amidation Using Aroyloxycarbamates To Give N-Boc Protected Arylamines
2013
Phenyl Backbone-Derived P,O- and P,N-Ligands for Palladium/Ligand-Catalyzed Aminations of Aryl Bromides, Iodides, and Chlorides. Syntheses and Structures of (P,O)n-Palladium(II)Aryl(Br) Complexes
1999
N-Arylation of aliphatic, aromatic and heteroaromatic amines catalyzed by copper bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
2007
An improved synthesis of 3-aminoestrone
2005
Achiral Pyridine Ligand‐Enabled Enantioselective Radical Oxytrifluoromethylation of Alkenes with Alcohols
2017
Highly Efficient Copper-Catalyzed N-Arylation of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl Halides
2007
Identification of the Effective Palladium(0) Catalytic Species Generatedin Situfrom Mixtures of Pd(dba)2and Bidentate Phosphine Ligands. Determination of Their Rates and Mechanism in Oxidative Addition
1997
Highly efficient and practical phosphoramidite–copper catalysts for amination of aryl iodides and heteroaryl bromides with alkylamines and N(H)-heterocycles
2006
Effect of the Leaving Ligand X on Transmetalation of Organostannanes (vinylSnR3) with LnPd(Ar)(X) in Stille Cross-Coupling Reactions. A Density Functional Theory Study
2006
Expedited Palladium-Catalyzed Amination of Aryl Nonaflates through the Use of Microwave-Irradiation and Soluble Organic Amine Bases
2005
A new route to phenazines
2000
Insights into the Origin of High Activity and Stability of Catalysts Derived from Bulky, Electron-Rich Monophosphinobiaryl Ligands in the Pd-Catalyzed C−N Bond Formation
2003
Tricarbonyl-η6-[(2-thiophenyl)arene]- and -η6-[(2-thiophenyl)carbonylarene]- chromium Complexes: Preparation and Conformational Study
2000
Oxidative Cyclizations in a Nonpolar Solvent Using Molecular Oxygen and Studies on the Stereochemistry of Oxypalladation
2005
Synthesis of 2D Imine-Linked Covalent Organic Frameworks through Formal Transimination Reactions
2017
A new palladium catalyst system for the cyanation of aryl chlorides with K4[Fe(CN)6]
2007
Amination of Aryl Halides: Quantitative Assessment of Stoichiometric and Catalytic Kinetic Studies
2007
Palladium-catalyzed double N-arylation to synthesize multisubstituted dibenzoazepine derivatives
2012
Synthesis of 8-arylated catechin and epicatechin derivatives via Suzuki cross-coupling
2007
Copper-Catalyzed Synthesis of Medium- and Large-Sized Nitrogen Heterocycles via N-Arylation of Phosphoramidates and Carbamates
2005
New aryl/heteroaryl CN bond cross-coupling reactions via arylboronic acid/cupric acetate arylation
1998
Palladium‐Catalyzed Allylation of Pronucleophiles with Alkynes at 50 °C – Remarkable Effect of 2‐(Dicyclohexylphosphanyl)‐2′‐(dimethylamino)biphenyl as Ligand
2006
Metal-Initiated Amination of Alkenes and Alkynes
1998 Standout
Synthesis of a TRPV1 Receptor Antagonist
2009
Amination Reactions of Aryl Halides with Nitrogen-Containing Reagents Mediated by Palladium/Imidazolium Salt Systems
2001
Catalysts for Suzuki−Miyaura Coupling Processes: Scope and Studies of the Effect of Ligand Structure
2005 Standout
Synthesis of pyrrolo[1,2-a]quinolines and ullazines by visible light mediated one- and twofold annulation of N-arylpyrroles with arylalkynes
2016
Versatile Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Benzoic and Phenyl Acetic Acids
2008
Suzuki–Miyaura cross-coupling of lithium n-alkylborates
2001
Palladium-Catalyzed Arylation of Fluoroalkylamines
2015
Electronic Effects on Reductive Elimination To Form Carbon−Carbon and Carbon−Heteroatom Bonds from Palladium(II) Complexes
2007
Asymmetric Suzuki Cross-Couplings of Activated Secondary Alkyl Electrophiles: Arylations of Racemic α-Chloroamides
2010
Highly Selective Palladium‐Catalyzed Oxidative Csp2Csp3 Cross‐Coupling of Arylzinc and Alkylindium Reagents through Double Transmetallation
2009
Palladium catalysed enamine synthesis from vinyl triflates
2002
Carbon−Sulfur Bond-Forming Reductive Elimination Involving sp-, sp2-, and sp3-Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation
1998
Palladium-Catalyzed Monoarylation of Nitroalkanes
2001
Palladium-Catalyzed Annulation of Arynes byo-Halobenzamides: Synthesis of Phenanthridinones
2012
An Efficient Ullmann-Type C−O Bond Formation Catalyzed by an Air-Stable Copper(I)−Bipyridyl Complex
2008
Organotrifluoroborate Hydrolysis: Boronic Acid Release Mechanism and an Acid–Base Paradox in Cross-Coupling
2012
Air-Stable Pd(R-allyl)LCl (L= Q-Phos, P(t-Bu)3, etc.) Systems for C–C/N Couplings: Insight into the Structure–Activity Relationship and Catalyst Activation Pathway
2011
Regioselective arylation of benzanilides with aryl triflates or bromides under palladium catalysis
2000
Zinc Trimethylsilylamide as a Mild Ammonia Equivalent and Base for the Amination of Aryl Halides and Triflates
2005
An Improved Synthesis of Functionalized Biphenyl-Based Phosphine Ligands
2000
Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications
2011
Chemoselektive benzylische C‐H‐Aktivierungen für die Synthese kondensierter N‐Heterocyclen
2006
Cross-Coupling Reactions of Potassium Alkyltrifluoroborates with Aryl and 1-Alkenyl Trifluoromethanesulfonates
2001
The synthesis of potentially selective inhibitors of dihydroorotate dehydrogenase. The utilization of chemoselective Suzuki cross-coupling reactions in a parallel synthesis
2001
Copper-Catalyzed Arylation of β-Amino Alcohols
2002
One-step construction of carbazoles by way of the palladium-catalyzed double N-arylation reaction and its application to the total synthesis of murrastifoline-A
2006
An Improved Procedure for the Synthesis of Benzimidazoles, Using Palladium-Catalyzed Aryl-Amination Chemistry
2003
B-Alkyl Suzuki−Miyaura Cross-Coupling Reactions with Air-Stable Potassium Alkyltrifluoroborates
2003
Cobalt-catalyzed oxidative cyclization of gem -disubstituted conjugated alkenols
2016
Mechanistic Pathways for Oxidative Addition of Aryl Halides to Palladium(0) Complexes: A DFT Study
2005
Copper-Catalyzed C−P Bond Construction via Direct Coupling of Secondary Phosphines and Phosphites with Aryl and Vinyl Halides
2003
Palladium-Catalyzed Amination of Unprotected Five-Membered Heterocyclic Bromides
2014
Pd–EDTA as an efficient catalyst for Suzuki–Miyaura reactions in water
2005
Easily Accessible and Highly Tunable Indolyl Phosphine Ligands for Suzuki−Miyaura Coupling of Aryl Chlorides
2007
Palladium-catalyzed direct arylation of thiazoles with aryl bromides
2003
Ag(I)-promoted Suzuki–Miyaura cross-couplings of n -alkylboronic acids
2001
Antiadhesion Therapy for Urinary Tract Infections—A Balanced PK/PD Profile Proved To Be Key for Success
2012
A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate
2002
Development of a New Variant of the Migita Reaction for Carbon−Sulfur Bond Formation Used in the Manufacture of Tetrahydro-4-[3-[4-(2-methyl-1H-imidazol-1-yl)phenyl]thio]phenyl-2H-pyran-4-carboxamide
2008
A General Strategy for the Synthesis of Amino-Substituted 2-Pyridones Using a Palladium-Catalyzed Amination Reaction
2007
Copper-catalyzed synthesis of primary arylamines from aryl halides and 2,2,2-trifluoroacetamide
2007
Copper-Catalyzed Aerobic Oxidative Intramolecular C–H Amination Leading to Imidazobenzimidazole Derivatives
2011
1,1,1-Tris(hydroxymethyl)ethane as a New, Efficient, and Versatile Tripod Ligand for Copper-Catalyzed Cross-Coupling Reactions of Aryl Iodides with Amides, Thiols, and Phenols
2006
An Electron‐Deficient Diene as Ligand for Palladium‐Catalyzed Cross‐Coupling Reactions: An Efficient Alkylation of Aryl Iodides by Primary and Secondary Alkylzinc Reagents
2008
Suzuki–Miyaura Coupling Reaction by PdII‐Catalyzed Aromatic CH Bond Activation Directed by an N‐Alkyl Acetamino Group
2007
The Potential of Palladacycles: More Than Just Precatalysts
2005
A Route to Pdo from PdII Metallacycles in Animation and Cross‐Coupling Chemistry
1996
Kreuzkupplungen von Organoboranen: ein einfacher Weg zum Aufbau von C‐C‐Bindungen (Nobel‐Aufsatz)
2011 Nobel
Rhodium(III)-Catalyzed Intermolecular Direct Amination of Aromatic C–H Bonds with N-Chloroamines
2011
Investigating the Effects of a Hydrolytically Stable Hapten and a Th1 Adjuvant on Heroin Vaccine Performance
2012
Highly selective arylation of disubstituted hydrazines by pentavalent organobismuth reagents
2002
The Slow‐Release Strategy in Suzuki–Miyaura Coupling
2010
Role of dba in the reactivity of palladium(0) complexes generated in situ from mixtures of Pd(dba)2 and phosphines
1998
Synthesis of Acridone Derivatives Using Polymer-Supported Palladium and Scandium Catalysts
2006
Palladium catalysed cross-coupling of (fluoroarene)tricarbonylchromium(0) complexes
2000
An Air-Stable Palladium/N-Heterocyclic Carbene Complex and Its Reactivity in Aryl Amination
2002
Preparation of Enamides via Palladium-Catalyzed Amidation of Enol Tosylates
2005
A convenient palladium/ligand catalyst for Suzuki cross-coupling reactions of arylboronic acids and aryl chlorides
1999
The Synthesis of Important Pharmaceutical Building Blocks by Palladium‐Catalyzed Coupling Reaction: Access to Various Arylhydrazines
2005
Palladium‐Catalyzed N‐Arylation of N,N‐Dialkylhydrazines with Aryl Chlorides
2007
Suzuki Reaction Takes a “Naked Hot Bath”: Coupling in High‐Temperature Water without Transition Metals
2003
Concise and Efficient Synthesis of 4-Fluoro-1H-pyrrolo[2,3-b]pyridine
2003
Enantioselective Arylation of 2-Methylacetoacetates Catalyzed by CuI/trans-4-Hydroxy-l -proline at Low Reaction Temperatures
2006
Palladium-Catalyzed Synthesis of 1-Azaazulenes from Cycloheptatrienylmethyl Ketone O-Pentafluorobenzoyl Oximes
2002
Photoinduced Ullmann C–N Coupling: Demonstrating the Viability of a Radical Pathway
2012 Science
Synthesis of Chiral 1,4‐Benzodioxanes and Chromans by Enantioselective Palladium‐Catalyzed Alkene Aryloxyarylation Reactions
2016
Synthesis of Benzocyclobutenes by Palladium-Catalyzed C−H Activation of Methyl Groups: Method and Mechanistic Study
2008
A novel catalytic one-pot synthesis of carbazoles via consecutive amination and C–H activation
2002
Chemical Glycobiology
2001 StandoutScienceNobel
Palladium-catalyzed synthesis of triarylamines from aryl halides and diarylamines
1998
Development of Preformed Pd Catalysts for Cross-Coupling Reactions, Beyond the 2010 Nobel Prize
2012
Palladium−Imidazolium Carbene Catalyzed Aryl, Vinyl, and Alkyl Suzuki−Miyaura Cross Coupling
2001
Planar Chiral (η6-Arene) Ruthenium Cp Complexes in Organic Synthesis: Diastereoselective Complexation of Arene Compounds with Benzylic Alcohol and Its Synthetic Application to Chiral Biaryls
2003
Cupric acetate mediated N-arylation by arylboronic acids: A preliminary investigation into the scope of application
1998
The First General Method for Palladium-Catalyzed Negishi Cross-Coupling of Aryl and Vinyl Chlorides: Use of Commercially Available Pd(P(t-Bu)3)2as a Catalyst
2001
Biarylphosphanliganden in der palladiumkatalysierten Aminierung
2008
Reaction of Aryl Iodides with (PCP)Pd(II)—Alkyl and Aryl Complexes: Mechanistic Aspects of Carbon—Carbon Bond Formation
2001
Several Convenient Methods for the Synthesis of 2-Amido Substituted Furans
2003
The first synthesis of optically pure biscarbazoles and determination of their absolute configurations
1999
Improvements in Cross Coupling Reactions of Hypervalent Siloxane Derivatives
1999
The Medicinal Chemist’s Toolbox: An Analysis of Reactions Used in the Pursuit of Drug Candidates
2011 Standout
A Copper-Catalyzed C−N Bond Formation Involving sp-Hybridized Carbons. A Direct Entry to Chiral Ynamides via N-Alkynylation of Amides
2003
Unusual in Situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C−O Bond Formation
2000
Recent applications of the Suzuki–Miyaura cross-coupling reaction in organic synthesis
2002 Standout
Synthesis of α-Carbolines via Pd-Catalyzed Amidation and Vilsmeier−Haack Reaction of 3-Acetyl-2-chloroindoles
2011
Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates
1998
Application of a New Bicyclic Triaminophosphine Ligand in Pd-Catalyzed Buchwald−Hartwig Amination Reactions of Aryl Chlorides, Bromides, and Iodides
2003
Development of the Suzuki−Miyaura Cross-Coupling Reaction: Use of Air-Stable Potassium Alkynyltrifluoroborates in Aryl Alkynylations
2002
Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions
2000
Synthesis of (R)‐(–)‐2‐Fluoronorapomorphine — A Precursor for the Synthesis of (R)‐(–)‐2‐Fluoro‐N‐[11C]propylnorapomorphine for Evaluation as a Dopamine D2 Agonist Ligand for PET Investigations
2005
Synthesis of Enantiomerically Pure Dissymmetric 2,2'‐Disubstituted9,9'‐Spirobifluorenes
2005
Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners
2011 Standout
A novel class of amide-derived air-stable P,O-ligands for Suzuki cross-coupling at low catalyst loading
2004
Highly Efficient Ligands for the Palladium‐Assisted Double N‐Arylation of Primary Amines for One‐Sep Construction of Carbazoles
2010
Recent Trends in Copper‐Catalyzed C−H Amination Routes to Biologically Important Nitrogen Scaffolds
2015
Copper- and Palladium-Catalyzed Intramolecular Aryl Guanidinylation: An Efficient Method for the Synthesis of 2-Aminobenzimidazoles
2002
Facile Amine Formation by Intermolecular Catalytic Amidation of Carbon−Hydrogen Bonds
2006
Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides
2009
Cross-Coupling and Dehalogenation Reactions Catalyzed by (N-Heterocyclic carbene)Pd(allyl)Cl Complexes
2004
N‐Trialkylsilylimines as Coupling Partners for Pd‐Catalyzed CN Bond‐Forming Reactions: One‐Step Synthesis of Imines and Azadienes from Aryl and Alkenyl Bromides
2003
Copper(II)-catalyzed O-Phenylation of Tertiary Alcohols with Organobismuth(V) Reagents
2006
PdCl2(SEt2)2 and Pd(OAc)2: simple and efficient catalyst precursors for the Suzuki cross-coupling reaction
2000
Microwave-Assisted Synthesis of Diaryl Ethers without Catalyst
2003
Pd(PhCN)2Cl2/P(t-Bu)3: A Versatile Catalyst for Sonogashira Reactions of Aryl Bromides at Room Temperature
2000
High-Throughput Screening Studies of Fiber-Supported Catalysts Leading to Room-Temperature Suzuki Coupling
2002
Scope and Limitations of Pd2(dba)3/P(i-BuNCH2CH2)3N-Catalyzed Buchwald−Hartwig Amination Reactions of Aryl Chlorides
2004
Formation of Enamides via Palladium(II)-Catalyzed Vinyl Transfer from Vinyl Ethers to Nitrogen Nucleophiles
2004
Relativistic Functional Groups: Aryl Carbon–Gold Bond Formation by Selective Transmetalation of Boronic Acids
2006
Copper-Catalyzed Synthesis of Unsymmetrical Triarylphosphines
2003
Efficient Palladium-Catalyzed N-Arylation of Indoles
2000
A Highly Active Suzuki Catalyst for the Synthesis of Sterically Hindered Biaryls: Novel Ligand Coordination
2002
Construction of a carbapenam skeleton using palladium-catalyzed cyclization
2001
Phospha-palladacycles and N-heterocyclic carbene palladium complexes: efficient catalysts for CC-coupling reactions
2003
Synthesis of Unsymmetrical Triarylamines for Photonic Applications via One-Pot Palladium-Catalyzed Aminations
1997
Coupling of Bulky, Electron-Deficient Partners in Aryl Amination in the Preparation of Tridentate Bis(oxazoline) Ligands for Asymmetric Catalysis
2002
Übergangsmetall-katalysierte Synthese von Arylaminen und Arylethern aus Arylhalogeniden und -triflaten: Anwendungen und Reaktionsmechanismus
1998
Development of a Scalable Synthesis of a Bruton’s Tyrosine Kinase Inhibitor via C–N and C–C Bond Couplings as an End Game Strategy
2013
Mechanistic Studies on the Aryl−Aryl Interchange Reaction of ArPdL2I (L = Triarylphosphine) Complexes
1997
Molecularly defined palladium(0) monophosphine complexes as catalysts for efficient cross-coupling of aryl chlorides and phenylboronic acid1
2000
Effective Pd-Nanoparticle (PdNP)-Catalyzed Negishi Coupling Involving Alkylzinc Reagents at Room Temperature
2008
A Copper‐Catalyzed C—N Bond Formation Involving sp‐Hybridized Carbons. Direct Entry to Chiral Ynamides via N‐Alkynylation of Amides.
2003
Palladiumkatalysierte Kreuzkupplungen: eine historische Perspektive im Kontext der Nobel‐Preise 2010
2012
Effect of Solvents on the Product Distribution and Reaction Rate of a Buchwald−Hartwig Amination Reaction
2006
Selective Palladium-Catalyzed Arylation of Ammonia: Synthesis of Anilines as Well as Symmetrical and Unsymmetrical Di- and Triarylamines
2007
Pd‐Catalyzed N‐Arylation of Heteroarylamines.
2003
o,p-Polyaniline: A New Form of a Classic Conducting Polymer
2003
The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)3 and PCy3 as Ligands
2008
General and Efficient Synthesis of Arylamino- and Alkylamino-Substituted Diphenylporphyrins and Tetraphenylporphyrins via Palladium-Catalyzed Multiple Amination Reactions
2003
Formation of arylnitrogen bonds using a soluble copper(I) catalyst
2001
Copper-catalyzed amidations of bromo substituted furans and thiophenes
2002
Palladium-Catalyzed Multiple Arylation of Thiophenes
2002
Suzuki Cross-Coupling Reactions Catalyzed by Palladium Nanoparticles in Aqueous Solution
2000
Orthogonal Reactivity in Boryl-Substituted Organotrifluoroborates
2008
Pd/C as a Reusable Catalyst for the Coupling Reaction of Halophenols and Arylboronic Acids in Aqueous Media
2002
An Efficient and Stereoselective Synthesis of the Monomeric Counterpart of Marinomycin A
2007
A family of simple amide-derived air-stable P,O-ligands for Suzuki cross-coupling of unactivated aryl chlorides
2005
Regioselective and Enantiospecific Rhodium-Catalyzed Allylic Amination withN-(Arylsulfonyl)anilines
2001
Total Synthesis of the Cyclopeptide Alkaloid Paliurine E. Insights into Macrocyclization by Ene−Enamide RCM
2008
Palladium-Catalyzed Cross-Coupling of Pyrrole Anions with Aryl Chlorides, Bromides, and Iodides
2004
Alkyl Carbon−Nitrogen Reductive Elimination from Platinum(IV)−Sulfonamide Complexes
2007
Applicability Aspects of Transition Metal‐Catalyzed Aromatic Amination Protocols in Medicinal Chemistry
2007
Highly Ortho-Selective Cross-Coupling of Dichlorobenzene Derivatives with Grignard Reagents
2007
Rh(III)-Catalyzed C–H Amidation withN-Hydroxycarbamates: A New Entry toN-Carbamate-Protected Arylamines
2013
Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions of Potassium Aryl- and Heteroaryltrifluoroborates
2003
An Efficient Intermolecular Palladium-Catalyzed Synthesis of Aryl Ethers
2001
Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles
2003
Rhodium(III)‐Catalyzed C(sp2)H Activation and Electrophilic Amidation with N‐Fluorobenzenesulfonimide
2013
Suzuki–Miyaura cross-coupling of aryl and alkyl halides using palladium/imidazolium salt protocols
2004
Enantioselective Organocatalytic Indole Alkylations. Design of a New and Highly Effective Chiral Amine for Iminium Catalysis
2002 Standout
Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
2000
Nickel-catalysed amination of aryl chlorides using a dihydroimidazoline carbene ligand
2001
Room-Temperature Pd-Catalyzed Amidation of Aryl Bromides Using tert-Butyl Carbamate
2009
DoubleN-Arylation of Primary Amines: Carbazole Synthesis from 2,2‘-Biphenyldiols
2004
Combinatorial Design of Copper‐Based Mixed Nanoclusters: New Catalysts for Suzuki Cross‐Coupling
2003
Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands
2008 Standout
New Air-Stable Planar Chiral Ferrocenyl Monophosphine Ligands: Suzuki Cross-Coupling of Aryl Chlorides and Bromides
2003
New Triarylamine-Containing Polymers as Hole Transport Materials in Organic Light-Emitting Diodes: Effect of Polymer Structure and Cross-Linking on Device Characteristics
1998 StandoutNobel
Multiple arylation of carbonyl compounds via palladium catalysis
2002
Synthesis of Triamidoamine Ligands of the Type (ArylNHCH2CH2)3N and Molybdenum and Tungsten Complexes That Contain an [(ArylNCH2CH2)3N]3-Ligand
2001 StandoutNobel
Base and Cation Effects on the Suzuki Cross-Coupling of Bulky Arylboronic Acid with Halopyridines: Synthesis of Pyridylphenols
1998
Microwave-Assisted Sequential Amide Bond Formation and Intramolecular Amidation: A Rapid Entry to Functionalized Oxindoles
2005
Recent advances in the synthesis of tetrahydrofurans and applications in total synthesis
2016
Palladium-Catalyzed Cross-Coupling Reactions of Organosilanols and Their Salts: Practical Alternatives to Boron- and Tin-Based Methods
2008
Catalytic Direct Arylation with Aryl Chlorides, Bromides, and Iodides: Intramolecular Studies Leading to New Intermolecular Reactions
2005
Phosphines Having a 2,3,4,5-Tetraphenylphenyl Moiety: Effective Ligands in Palladium-Catalyzed Transformations of Aryl Chlorides
2006
[(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides
2008
Carbon–Heteroatom Coupling Using Pd-PEPPSI Complexes
2013
Experimental and Theoretical Investigations of New Dinuclear Palladium Complexes as Precatalysts for the Amination of Aryl Chlorides
2006
Halide and Amine Influence in the Equilibrium Formation of Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes from Palladium Aryl Halide Dimers
1996
Palladium-Catalyzed C–N Cross Coupling of Sulfinamides and Aryl Halides
2012
Palladium catalysed cross-coupling of (fluoroarene)tricarbonylchromium(0) complexes
1999
A New General Preparation of Polyfunctional Diarylamines by the Addition of Functionalized Arylmagnesium Compounds to Nitroarenes
2002
Synthesis of 1-aryl-1 H -indazoles via the palladium-catalyzed cyclization of N -aryl- N ′-( o -bromobenzyl)hydrazines and [ N -aryl- N ′-( o -bromobenzyl)-hydrazinato- N ′]-triphenylphosphonium bromides
2001
The Complementary Competitors: Palladium and Copper in C–N Cross-Coupling Reactions
2012
Dechlorination of Aryl Chlorides with Sodium Formate Using a Homogeneous Palladium Catalyst
2006
N-Acyl-N,N-dipyridyl and N-acyl-N-pyridyl-N-quinoyl amine based palladium complexes. Synthesis, X-ray structures, heterogenization and use in Heck couplings
2001
Palladium-catalyzed coupling of lactams with bromobenzenes
1999
Palladium-catalyzed biaryl-coupling reaction of arylboronic acids in water using hydrophilic phosphine ligands
2002
Removal of Palladium from Organic Reaction Mixtures by Trimercaptotriazine
1997
Synthesis of Diazacalix[8]arene and Triazacalix[12]arene Methyl Ethers via Intramolecular Aryl Amination
2009
Stille Couplings Catalytic in Tin: The “Sn−O” Approach
2001
Iron-Catalyzed Cross-Coupling Reactions of Alkyl-Grignard Reagents with Aryl Chlorides, Tosylates, and Triflates
2002
The First General Palladium Catalyst for the Suzuki−Miyaura and Carbonyl Enolate Coupling of Aryl Arenesulfonates
2003
Suzuki Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates
2001
Copper(I)-catalyzed intramolecular cyclization reaction of 2-(2′-chlorophenyl)ethanol to give 2,3-dihydrobenzofuran
2000
An Efficient Diamine·Copper Complex-Catalyzed Coupling of Arylboronic Acids with Imidazoles
2000
Phosphorus Heterocycles: From Laboratory Curiosities to Ligands in Highly Efficient Catalysts
2002
Synthesis and Reactions of Molybdenum Triamidoamine Complexes Containing Hexaisopropylterphenyl Substituents
2003 StandoutNobel
Selected Patented Cross-Coupling Reaction Technologies
2006 Standout
2‐(2‐Haloalkenyl)‐aryl Halides as Substrates for Palladium‐Catalysed Tandem CN Bond Formation: Efficient Synthesis of 1‐Substituted Indoles
2006
Highly Efficient CuI-Catalyzed Coupling of Aryl Bromides with Oxazolidinones Using Buchwald's Protocol: A Short Route to Linezolid and Toloxatone
2003
Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation
2007 Standout
Utilization of a copper-catalyzed diaryl ether synthesis for the preparation of verbenachalcone
2002
Beyond TPPTS: New Approaches to the Development of Efficient Palladium‐Catalyzed Aqueous‐Phase Cross‐Coupling Reactions
2006
Modified (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes for Room-Temperature Suzuki−Miyaura and Buchwald−Hartwig Reactions
2006
Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate
1997
Utilization of Potassium Vinyltrifluoroborate in the Development of a 1,2-Dianion Equivalent
2009
Exploration of New C−O Electrophiles in Cross-Coupling Reactions
2010
Switching the Chemoselectivity in the Amination of 4-Chloroquinazolines with Aminopyrazoles
2009
Ugi-Post Functionalization, from a Single Set of Ugi-Adducts to Two Distinct Heterocycles by Microwave-Assisted Palladium-Catalyzed Cyclizations: Tuning the Reaction Pathways by Ligand Switch
2009
On the Nature of the ‘Heterogeneous' Catalyst: Nickel-on-Charcoal
2002
Synthesis of diaryl ethers through the copper-catalyzed arylation of phenols with aryl halides using microwave heating
2003
Scope and Mechanism of Palladium-Catalyzed Amination of Five-Membered Heterocyclic Halides
2003
Mechanism of the Stille Reaction. 2. Couplings of Aryl Triflates with Vinyltributyltin. Observation of Intermediates. A More Comprehensive Scheme
2000
Synthesis of new tetracyclic azaheteroaromatic cores via auto-tandem Pd-catalyzed and one-pot Pd- and Cu-catalyzed double C–N bond formation
2010
Fluorous-Tagged Carbamates for the Pd-Catalyzed Amination of Aryl Halides
2007
Regioselective Synthesis of 1-Alkyl- or 1-Aryl-1H-indazoles via Copper-Catalyzed Cyclizations of 2-Haloarylcarbonylic Compounds
2007
Cross-coupling of chloroarenes with boronic acids using a water-soluble nickel catalyst
1999
Palladium-Catalyzed Methylation and Arylation of sp2 and sp3 C−H Bonds in Simple Carboxylic Acids
2007
Carbon−Oxygen Bond Formation at Metal(IV) Centers: Reactivity of Palladium(II) and Platinum(II) Complexes of the [2,6-(Dimethylaminomethyl)phenyl-N,C,N]-(Pincer) Ligand toward Iodomethane and Dibenzoyl Peroxide; Structural Studies of M(II) and M(IV) Complexes
2004
A Rapid, Large-Scale Synthesis of a Potent Cholecystokinin (CCK) 1R Receptor Agonist
2008
Direct homocoupling of aryl halides catalyzed by palladium
1998
An Improved Method for the Palladium-Catalyzed Amination of Aryl Iodides
2001
Optimisation of Permanganate Oxidation and Suzuki−Miyaura Coupling Steps in the Synthesis of a Nav1.8 Sodium Channel Modulator
2009
Synthesis of Ladder-Type π-Conjugated Heteroacenes via Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation
2007
Pd-Catalyzed N-Arylation of Secondary Acyclic Amides: Catalyst Development, Scope, and Computational Study
2009
Synthesis and Antibacterial Activity of Pentacyclines: A Novel Class of Tetracycline Analogs
2011
The Development of Efficient Protocols for the Palladium-Catalyzed Cyclization Reactions of Secondary Amides and Carbamates
1999
Combining N-heterocyclic carbenes and phosphines: improved palladium(II) catalysts for aryl coupling reactions
1999
Synthesis and Opioid Receptor Binding Affinities of 2-Substituted and 3-Aminomorphinans: Ligands for μ, κ, and δ Opioid Receptors
2009
Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit
2009
Selective N-Arylation of Aminobenzanilides under Mild Conditions Using Triarylbismuthanes
2000
Asymmetric 5-endo chloroetherification of homoallylic alcohols toward the synthesis of chiral β-chlorotetrahydrofurans
2012
Palladium-catalysed reactions of aryl halides with soft, non-organometallic nucleophiles
2002
Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers
1999
Single Component Self‐Assembled Monolayers of Aromatic Azo‐Biphenyl: Influence of the Packing Tightness on the SAM Structure and Light‐Induced Molecular Movements
2008 StandoutNobel
Ortho-selective Cross Coupling of Dibromophenols and Dibromoanilines with Grignard Reagents in the Presence of Palladium Catalysts Bearing Hydroxylated Oligoarene-type Phosphine
2007
Palladium-Catalyzed α-Vinylation of Carbonyl Compounds
2007
High‐Turnover Palladium Catalysts in Cross‐Coupling and Heck Chemistry: A Critical Overview
2004
Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines
2009
Nickel N-Heterocyclic Carbene Catalyst for Cross-Coupling of Neopentyl Arenesulfonates with Methyl and Primary Alkyl Grignard Reagents
2009
Metal-Mediated Synthesis of Medium-Sized Rings
2000
Highly Active and Selective Catalysts for the Formation of α-Aryl Ketones
2000
Reductive Elimination of Aryl Halides from Palladium(II)
2001
Design, Synthesis, and Biological Evaluation of Chromone-Based p38 MAP Kinase Inhibitors
2011
Application of the palladium-catalyzed N-arylation of hydrazones to deactivated heteroaryl halides in the synthesis of pyrazoles
2004
Transition metal-catalysed addition reactions of H–heteroatom and inter-heteroatom bonds to carbon–carbon unsaturated linkages via oxidative additions
1999
Regioselective synthesis of aryl hydrazides by palladium-catalyzed coupling of t-butylcarbazate with substituted aryl bromides
1999
A Highly Active Catalyst for Pd-Catalyzed Amination Reactions: Cross-Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides
2008
Palladium- and Nickel-Catalyzed Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Protons with Organozinc Reagents
2008
Efficient aqueous-phase Suzuki coupling of activated aryl chlorides with arylboronic acids using d-glucosamine-based dicyclohexylarylphosphine
2005
Palladium-catalyzed arylation of N,N-dialkylhydrazines and the subsequent conversion to anilines
2007
One-Pot Synthesis of Unsymmetrical Triarylamines from Aniline Precursors
2000
Palladium-catalyzed domino N-arylation/carbopalladation/C–H functionalization: three-component synthesis of 3-(diarylmethylene)oxindoles
2009
Palladium–tetraphosphine catalysed cross coupling of aryl bromides with arylboronic acids: remarkable influence of the nature of the ligand
2001
A General and Efficient Copper Catalyst for the Amidation of Aryl Halides
2002
Synthesis and characterization of poly(p-phenylenephosphine)s
2000
Enantioselective Ruthenium-Catalyzed Ring-Closing Metathesis
2001 StandoutNobel
Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides and Lithium Bis(trimethylsilyl)amide as an Ammonia Equivalent
2001
Organotrifluorborate und einfach koordinierte Palladiumkomplexe als Katalysatoren – die perfekte Kombination für die Suzuki‐Miyaura‐Kupplung
2009
Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products
2013 Standout
Preparation, Structure, and Reactivity of Nonstabilized Organoiron Compounds. Implications for Iron-Catalyzed Cross Coupling Reactions
2008
Significantly Improved Method for the Pd‐Catalyzed Coupling of Phenols with Aryl Halides: Understanding Ligand Effects
2006
Design and synthesis of a biphenyl-based chiral amino sulfonamide with high catalytic performance in Mannich reactions
2014
A General Modular Method of Azaindole and Thienopyrrole Synthesis via Pd-Catalyzed Tandem Couplings of gem-Dichloroolefins
2007
Dialkylphosphinoimidazoles as New Ligands for Palladium‐Catalyzed Coupling Reactions of Aryl Chlorides
2004
Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds
2010
Highly active PdII cyclometallated imine catalyst for the Suzuki reaction
1999
Diastereoselective synthesis of 2,5-disubstituted tetrahydrofurans
2009
Rh-Catalyzed N–O Bond Cleavage of Anthranil: A C–H Amination Reagent for Simultaneous Incorporation of Amine and a Functional Group
2016
Eine bequeme und allgemein anwendbare Methode für Pd-katalysierte Suzuki- Kreuzkupplungen von Arylchloriden und Arylboronsäuren
1998
Palladium bis(phosphinite) ‘PCP’-pincer complexes and their application as catalysts in the Suzuki reaction
2000
Anionic Pd(0) and Pd(II) Intermediates in Palladium-Catalyzed Heck and Cross-Coupling Reactions
2000
Total Synthesis of (±)-Murrayazoline
2008
Palladium Catalysis for the Synthesis of Hydrophobic C-6 and C-2 Aryl 2‘-Deoxynucleosides. Comparison of C−C versus C−N Bond Formation as well as C-6 versus C-2 Reactivity
2001
Two-Faced Reactivity of Alkenes: cis- versus trans-Aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions
2007
A convenient and efficient procedure for the palladium-catalyzed cyanation of aryl halides using trimethylsilylcyanide
2003
Asymmetric Synthesis of an Axially Chiral Antimitotic Biaryl via an Atropo-Enantioselective Suzuki Cross-Coupling
2003
Palladium-Catalyzed Amination of Aryl Bromides with Hindered N-Alkyl-Substituted Anilines Using a Palladium(I) Tri-tert-butylphosphine Bromide Dimer
2003
Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross‐Coupling of Primary Aryl Amines with Aryl Halides
2016
Palladium-catalyzed reaction of aryl halides with ureas
2001
Sulfoximine Directed Intermolecular o-C–H Amidation of Arenes with Sulfonyl Azides
2013
Novel Inhibitors of the v-raf Murine Sarcoma Viral Oncogene Homologue B1 (BRAF) Based on a 2,6-Disubstituted Pyrazine Scaffold
2008
Expanding Pd-Catalyzed C−N Bond-Forming Processes: The First Amidation of Aryl Sulfonates, Aqueous Amination, and Complementarity with Cu-Catalyzed Reactions
2003
Auto‐Tandem Catalysis: Synthesis of Acridines by Pd‐Catalyzed C=C Bond Formation and C(sp2)–N Cross‐Coupling
2012
Einfach koordinierte Palladiumspezies als Katalysatoren in Kreuzkupplungen
2004
Stereoselective synthesis of 3,4-disubstituted tetrahydrofurans and 2,3,4-trisubstituted tetrahydrofurans using an intramolecular allylation strategy employing allylsilanes
2008
Directing‐Group‐Assisted Transition‐Metal‐Catalyzed Direct Intermolecular C−H Amidation and Amination of Arenes
2016
Regioselective synthesis of benzimidazole thiophene inhibitors of polo-like kinase 1
2008
Total Synthesis of (−)-Archazolid B
2007
A Reliable Multikilogram-Scale Synthesis of 2-Acetamido-5-Vinylpyridine Using Catalytic BINAP in a Modified Heck Reaction
2001
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
2006 Standout
Confined acids catalyze asymmetric single aldolizations of acetaldehyde enolates
2018 StandoutScienceNobel
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
An efficient, palladium-catalysed, amination of aryl bromides
1999
Molybdenum Triamidoamine Complexes that Contain Hexa-tert-butylterphenyl, Hexamethylterphenyl, or p-Bromohexaisopropylterphenyl Substituents. An Examination of Some Catalyst Variations for the Catalytic Reduction of Dinitrogen
2004 StandoutNobel
Fabrication of Hollow Palladium Spheres and Their Successful Application to the Recyclable Heterogeneous Catalyst for Suzuki Coupling Reactions
2002
Multikilogram-Scale Synthesis of a Biphenyl Carboxylic Acid Derivative Using a Pd/C-Mediated Suzuki Coupling Approach
1999
A New Highly Efficient Catalyst System for the Coupling of Nonactivated and Deactivated Aryl Chlorides with Arylboronic Acids
2000
Rhodium-Catalyzed Direct C−H Addition of 3,4-Dihydroquinazolines to Alkenes and Their Use in the Total Synthesis of Vasicoline
2006
A Second-Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by (DPPF)PdCl2
1996
Palladium-catalyzed amination of aryl halides and sulfonates
1999
A new improved catalyst for the palladium-catalyzed amination of aryl chlorides
2002
Palladacycles in catalysis – a critical survey
2004
Synthesis of functionalized hydroxy-thiophene motifs as amido- and sulfonamido-phenol bioisosteres
2009
Octaethyldiphosphaferrocene: An Efficient Ligand in the Palladium-Catalyzed Suzuki Cross-Coupling Reaction
2000
Tandem Palladium-Catalyzed Urea Arylation−Intramolecular Ester Amidation: Regioselective Synthesis of 3-Alkylated 2,4-Quinazolinediones
2006
Transfer of Amido Groups from Isolated Rhodium(I) Amides to Alkenes and Vinylarenes
2005
A Catalytic Asymmetric Suzuki Coupling for the Synthesis of Axially Chiral Biaryl Compounds
2000
A General Method for the Direct α‐Arylation of Aldehydes with Aryl Bromides and Chlorides
2007
An efficient copper-catalyzed N-arylation of pyridazinones with a structurally well-defined copper complex
2005
Studies of Reductive Elimination Reactions To Form Carbon−Oxygen Bonds from Pt(IV) Complexes
2001
Halobenzyl Ethers as Protecting Groups for Organic Synthesis
2000
N-Heterocyclic carbenes
2000
Orthogonal and Auto-Tandem Catalysis: Synthesis of Dipyrido[1,2-a:2‘,3‘-d]imidazole and Its Benzo and Aza Analogues via Inter- and Intramolecular C−N Bond Formation
2005
Formation of Aryl−Nitrogen, Aryl−Oxygen, and Aryl−Carbon Bonds Using Well-Defined Copper(I)-Based Catalysts
2001
Catalytic CC, CN, and CO Ullmann‐Type Coupling Reactions: Copper Makes a Difference
2008
Asymmetric Catalytic Cycloetherification Mediated by Bifunctional Organocatalysts
2011
Efficient Synthesis of N-Aryl-Aza-Crown Ethers via Palladium-Catalyzed Amination
2000
Total Syntheses of (−)-Asperlicin and (−)-Asperlicin C
1998
Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals
2011 Standout
A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes
2004
Selective catch and release of a synthetically useful phosphine ligand
2003
Carbon−Oxygen Reductive-Elimination from Nickel(II) Oxametallacycles and Factors That Control Formation of Ether, Aldehyde, Alcohol, or Ester Products
1997
DieB-Alkyl-Suzuki-Miyaura-Kreuzkupplung: Entwicklung, Untersuchungen zum Mechanismus und Anwendungen in der Naturstoffsynthese
2001
Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis
2004
Application of Selective Palladium‐Mediated Functionalization of the Pyrido[3′,2′:4,5]pyrrolo[1,2‐c]pyrimidine Heterocyclic System for the Total Synthesis of Variolin B and Deoxyvariolin B
2010
Ionic Liquid (Molten Salt) Phase Organometallic Catalysis
2002 Standout
Synthesis and properties of bis(pyrazino[2′,3′:4,5]imidazole)-fused 1,2,5,6-tetrahydro-1,4,5,8,9,10-hexaazaanthracenes: a new fluorescent nitrogen-rich heterocycle
2010
Air Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium-Catalyzed C−C, C−N, and C−O Bond-Forming Cross-Couplings
2002
Multiple arylation of alkyl aryl ketones and α,β-unsaturated carbonyl compounds via palladium catalysis
2001
Revisiting the Ullmann−Ether Reaction: A Concise and Amenable Synthesis of Novel Dibenzoxepino[4,5-d]pyrazoles by Intramolecular Etheration of 4,5-(o,o‘-Halohydroxy)arylpyrazoles
2002
Atom-Efficient Metal-Catalyzed Cross-Coupling Reaction of Indium Organometallics with Organic Electrophiles
2001
Insights into Amine Binding to Biaryl Phosphine Palladium Oxidative Addition Complexes and Reductive Elimination from Biaryl Phosphine Arylpalladium Amido Complexes via Density Functional Theory
2007
Mild Pd-Catalyzed N-Arylation of Methanesulfonamide and Related Nucleophiles: Avoiding Potentially Genotoxic Reagents and Byproducts
2011
Synthesis of 5-Fluoroalkylated Pyrimidine Nucleosides via Negishi Cross-Coupling
2008
Direct Amination of Azoles via Catalytic C−H, N−H Coupling
2009
Transition metal mediated routes to poly(arylphosphine)s: investigation of novel phosphorus containing conjugated polymers
2002
Total synthesis of (±)-rocaglamide and some aryl analogues
2001
Copper-catalyzed N-arylation of diazoles with aryl bromides using KF/Al2O3: an improved protocol
2006
Palladium-catalysed synthesis of biaryl phosphines
2004
Pd-Catalyzed Intramolecular Aerobic Oxidative C–H Amination of 2-Aryl-3-(arylamino)quinazolinones: Synthesis of Fluorescent Indazolo[3,2-b]quinazolinones
2014
Copper-catalyzed coupling of aryl halides and nitrite salts: a mild Ullmann-type synthesis of aromatic nitro compounds
2005
Copper-Mediated, Palladium-Catalyzed Coupling of Thiol Esters with Aliphatic Organoboron Reagents
2004
Die Mechanismen der Stille‐Reaktion
2004
Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
2016 Standout
Convenient Synthesis of 1H‐Indol‐1‐yl Boronates via Palladium(0)‐Catalyzed Borylation of Bromo‐1H‐indoles with ‘Pinacolborane’
2006
Catalytic amination of 5-iodouracil derivatives
2001
Bulky Alkylphosphines with Neopentyl Substituents as Ligands in the Amination of Aryl Bromides and Chlorides
2006
The Generation of Dihydropyrimidine Libraries Utilizing Biginelli Multicomponent Chemistry
2003
Palladium‐catalyzed amination with benzophenone imine as a new, safe and practical alternative to nitration for the synthesis of 7‐amino‐2,1,3‐benzothiadiazoles
2003
Palladium-catalyzed C–N and C–C cross-couplings as versatile, new avenues for modifications of purine 2′-deoxynucleosides
2002
Palladium-Catalyzed Intermolecular Coupling of Aryl Halides and Amides
2000
Reactions of the 21st Century: Two Decades of Innovative Catalyst Design for Palladium-Catalyzed Cross-Couplings
2015
Palladium-Catalyzed Benzylic C−H Insertion of 2-Substituted N-Iminopyridinium Ylides
2008
Von PdII‐Metallacyclen zu Pd0‐Komplexen in Aminierungen und Kreuzkupplungen
1996
Divergent and Stereocontrolled Synthesis of the Enamide Side Chains of Oximidines I/II/III, Salicylihalamides A/B, Lobatamides A/D, and CJ-12,950
2004
Suzuki cross-coupling of aryl halides with aryl boronic acids catalyzed by phosphine-free NiCl2·6H2O
2002
Inhibition of Cytosolic Phospholipase A2α: Hit to Lead Optimization
2005
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
2003 StandoutScienceNobel
Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions
2011
“Befreite” Suzuki‐Reaktion: Kupplung in Wasser bei hoher Temperatur ohne Übergangsmetallreagens
2003
Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis
2004 Standout
N‐Arylation of indoles with 4‐[18F]fluoroiodobenzene: synthesis of 18F‐labelled σ2 receptor ligands for positron emission tomography (PET)
2004
Development of Two Complementary Syntheses for a Privileged CGRP Receptor Antagonist Substructure
2012
Asymmetric Catalysis via Cyclic, Aliphatic Oxocarbenium Ions
2017 StandoutNobel
Palladium(II) Complexes of 2-Dimethylamino-2‘- diphenylphosphino-1,1‘-binaphthyl (MAP) with Unique P,Cσ-Coordination and Their Catalytic Activity in Allylic Substitution, Hartwig−Buchwald Amination, and Suzuki Coupling
1999
Industrial R&D on Catalytic CC and CN Coupling Reactions: A Personal Account on Goals, Approaches and Results
2004
Metallkatalysierte α‐Arylierungen von Carbonylen und verwandten Molekülen: aktuelle Trends bei der C‐C‐Kupplung über C‐H‐Funktionalisierung
2010
Palladium-Catalyzed α-Arylation of Esters
2001
Rapid palladium-catalyzed aminations of aryl chlorides with aliphatic amines under temperature-controlled microwave heating
2004
Palladium-Catalyzed Amidation of Enol Triflates: A New Synthesis of Enamides
2003
Comparative Investigations of Cp*-Based Group 9 Metal-Catalyzed Direct C–H Amination of Benzamides
2014
Advances in the Heck chemistry of aryl bromides and chlorides
2001
Nickel-Catalyzed Cross-Coupling of Neopentyl Arenesulfonates with Methyl and Primary Alkylmagnesium Bromides
2005
Copper-in-Charcoal (Cu/C) Promoted Diaryl Ether Formation
2007
Immobilization of copper in organic–inorganic hybrid materials: a highly efficient and reusable catalyst for the Ullmann diaryl etherification
2006
A General and Efficient Copper Catalyst for the Amidation of Aryl Halides and the N-Arylation of Nitrogen Heterocycles
2001
Modern Amination Reactions
2007
14C-Labeled and Large-Scale Synthesis of the Angiotensin-(1−7)-receptor Agonist AVE 0991 by Cross-Coupling Reactions
2003
Highly Active Oxime-Derived Palladacycle Complexes for Suzuki−Miyaura and Ullmann-Type Coupling Reactions
2002
An Efficient Assembly of Heterobenzazepine Ring Systems Utilizing an Intramolecular Palladium-Catalyzed Cycloamination
2002
Use of Polymer-Supported Dialkylphosphinobiphenyl Ligands for Palladium-Catalyzed Amination and Suzuki Reactions
2001
Palladium-Catalyzed Cross-Coupling between Vinyl Halides and tert-Butyl Carbazate: First General Synthesis of the Unusual N-Boc-N-alkenylhydrazines
2006
Unparalleled Rates for the Activation of Aryl Chlorides and Bromides: Coupling with Amines and Boronic Acids in Minutes at Room Temperature
2002
Solid-Phase Oligosaccharide Synthesis and Combinatorial Carbohydrate Libraries
2000
Anionic Amino Acid [closo-1-CB9H8-1-COO-10-NH3]− and Dinitrogen Acid [closo-1-CB9H8-1-COOH-10-N2] as Key Precursors to Advanced Materials: Synthesis and Reactivity
2009
Variation of xanthene-based bidentate ligands in the palladium-catalyzed arylation of ureas
2003
Cyclopropylboronic acid: synthesis and Suzuki cross-coupling reactions
2002
Activation of olefins via asymmetric Brønsted acid catalysis
2018 StandoutScienceNobel
Pd/Norbornene: A Winning Combination for Selective Aromatic Functionalization via C–H Bond Activation
2016
Palladium-catalyzed multiple arylation of phenyl ketones with aryl bromides
1999
Catalytic Asymmetric Vinylation of Ketone Enolates
2001
Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C−N Bond Formation with a Commercial Ligand
1999
2-Amino-3-(phenylsulfanyl)norbornane-2-carboxylate: An Appealing Scaffold for the Design of Rac1–Tiam1 Protein–Protein Interaction Inhibitors
2014
Solid-phase synthesis of 2,6- and 2,7-diamino-4(3H)-quinazolinones via palladium-catalyzed amination
2003
Visible‐Light Photocatalysis: Does It Make a Difference in Organic Synthesis?
2018 Standout
General Synthesis of meso-Amidoporphyrins via Palladium-Catalyzed Amidation
2004
Rational Ligand Design for the Arylation of Hindered Primary Amines Guided by Reaction Progress Kinetic Analysis
2015
Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications
2017 Standout
Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure–Activity Relationships
2008
Synthesis of Bulky and Electron-Rich MOP-type Ligands and Their Applications in Palladium-Catalyzed C−N Bond Formation
2006
Palladium-Catalyzed Phosphorylation of Aryl Mesylates and Tosylates
2015
Target-Directed Synthesis of Antibacterial Drug Candidate GSK966587
2010
Oxidative Cross-Coupling of N-(2‘-Phenylphenyl)benzene- sulfonamides or Benzoic and Naphthoic Acids with Alkenes Using a Palladium−Copper Catalyst System under Air
1998
Palladium-Catalyzed Synthesis of Benzimidazoles and Quinazolinones from Common Precursors
2012
Synthesis of Chiral 1,4‐Benzodioxanes and Chromans by Enantioselective Palladium‐Catalyzed Alkene Aryloxyarylation Reactions
2016
Palladium mediated intramolecular multiple C–X/C–H cross coupling and C–H activation: synthesis of carbazole alkaloids calothrixin B and murrayaquinone A
2014
A Mild, One‐Pot Stadler–Ziegler Synthesis of Arylsulfides Facilitated by Photoredox Catalysis in Batch and Continuous‐Flow
2013
Catalytic Asymmetric Synthesis of Cyclic Ethers Containing an α‐Tetrasubstituted Stereocenter
2013
Tariquidar Analogues: Synthesis by CuI‐Catalysed N/O–Aryl Coupling and Inhibitory Activity against the ABCB1 Transporter
2007
Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes
2013
Palladium-Catalyzed Amination of Aryl Nonaflates
2003
The first total synthesis of trichostatin D
2004
Palladium- and Copper-Catalyzed Synthesis of Medium- and Large-Sized Ring-Fused Dihydroazaphenanthrenes and 1,4-Benzodiazepine-2,5-diones. Control of Reaction Pathway by Metal-Switching
2004
Superior Effect of a π-Acceptor Ligand (Phosphine−Electron-Deficient Olefin Ligand) in the Negishi Coupling Involving Alkylzinc Reagents
2007
Pyrroloquinolone PDE5 Inhibitors with Improved Pharmaceutical Profiles for Clinical Studies on Erectile Dysfunction
2004
Pd‐Catalyzed Amination of Nucleoside Arylsulfonates to yield N6‐Aryl‐2,6‐Diaminopurine Nucleosides
2005
Katalytische C‐C‐, C‐N‐ und C‐O‐Ullmann‐Kupplungen
2009
A Dicoordinate Palladium(0) Complex with an Unusual Intramolecular η-Arene Coordination
2003
Synthesis of Unsymmetrical Biaryls from Arylsilacyclobutanes
1999
Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides
2008 Standout
Synthetic Approaches to the Microtubule-Stabilizing Sponge Alkaloid Ceratamine A and Desbromo Analogues
2009
Poly-p-phenylene Phosphine/Polyaniline Alternating Copolymers: Electronic Delocalization through Phosphorus
2005
Cu-Catalyzed Azide−Alkyne Cycloaddition
2008 StandoutNobel
Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes
2014
Efficient Synthesis and In Vivo Incorporation of Acridon-2-ylalanine, a Fluorescent Amino Acid for Lifetime and Förster Resonance Energy Transfer/Luminescence Resonance Energy Transfer Studies
2013
Site-selective arene C-H amination via photoredox catalysis
2015 Science
Synthesis of Heterocycles via Palladium-Catalyzed Oxidative Addition
2006
Performances of symmetrical achiral ferrocenylphosphine ligands in palladium-catalyzed cross-coupling reactions: A review of syntheses, catalytic applications and structural properties
2007
Palladium‐Iminodiacetic Acid Immobilized on pH‐Responsive Polymeric Microspheres: Efficient Quasi‐Homogeneous Catalyst for Suzuki and Heck Reactions in Aqueous Solution
2008
Easy Access to Novel Substituted 6-Aminoimidazo[1,2-a]pyridines Using Palladium- and Copper-Catalyzed Aminations
2003
Evidence for the Formation and Structure of Palladacycles during Pd‐Catalyzed CN Bond Formation with Catalysts Derived from Bulky Monophosphinobiaryl Ligands
2006
User‐Friendly Methylation of Aryl and Vinyl Halides and Pseudohalides with DABAL‐Me3
2006
NiCl2(PCy3)2: A Simple and Efficient Catalyst Precursor for the Suzuki Cross-Coupling of Aryl Tosylates and Arylboronic Acids
2001
Palladium−Phosphinous Acid-Catalyzed Cross-Coupling of Aryl and Acyl Halides with Aryl-, Alkyl-, and Vinylzinc Reagents
2008
Carotenoid Photoprotection in Artificial Photosynthetic Antennas
2011
P(i-BuNCH2CH2)3N: An Effective Ligand in the Palladium-Catalyzed Amination of Aryl Bromides and Iodides
2002
Palladium-Catalyzed α-Arylation of Ketones
1997
Synthesis of Novel Imidazo[1,2-a]pyridines with Potent Activity against Herpesviruses
2003
Developing Transition-Metal Catalysts for the Intramolecular Hydroamination of Alkynes
1999
Organic Two-Layer Light-Emitting Diodes Based on High-Tg Hole-Transporting Polymers with Different Redox Potentials
1999 StandoutNobel
Using Intelligent/Random Library Screening To Design Focused Libraries for the Optimization of Homogeneous Catalysts: Ullmann Ether Formation
2000
Substituted 2,5-diazabicyclo[4.1.0]heptanes and their application as general piperazine surrogates: synthesis and biological activity of a Ciprofloxacin analogue
2010
Asymmetric Suzuki cross-coupling reaction: chirality reversal depending on the palladium–chiral phosphine ratio
2002
Bioinspired Synthesis of a Sedaxane Metabolite Using Catalytic Vanadyl Acetylacetonate and Molecular Oxygen
2015
Synthesis and Applications of tert-Butanesulfinamide
2010
Palladium-Catalyzed Coupling of Ammonia and Lithium Amide with Aryl Halides
2006
A Palladium-Catalyzed Method for the Preparation of Indoles via the Fischer Indole Synthesis
1999
Diels–Alder Approach to Polysubstituted Biaryls: Rapid Entry to Tri‐ and Tetra‐ortho‐substituted Phosphorus‐Containing Biaryls
2006
Synthesis of the C8-Deoxyguanosine Adduct of the Food Mutagen IQ
2001
Oxyarylation and Aminoarylation of Styrenes Using Photoredox Catalysis
2013
Stereoselective Synthesis of Azetidines and Pyrrolidines from N-tert-Butylsulfonyl(2-aminoalkyl)oxiranes
2009
Carbanionic Friedel−Crafts Equivalents. Regioselective Directed Ortho and Remote Metalation−C−N Cross Coupling Routes to Acridones and Dibenzo[b,f]azepinones
2008
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
2000 Standout
Palladium-Catalyzed Intramolecular C−O Bond Formation
2001
Preparation of C8-Amine and Acetylamine Adducts of 2‘-Deoxyguanosine Suitably Protected for DNA Synthesis
2002
Design and Implementation of an Efficient Synthetic Approach to Furanosylated Indolocarbazoles: Total Synthesis of (+)- and (−)-K252a
1997
Selection and Development of the Manufacturing Route for EP1 Antagonist GSK269984B
2010
Successful application of microstructured continuous reactor in the palladium catalysed aromatic amination
2005
Synthesis of biaryls by intramolecular radical transfer: use of phosphinates
2000
Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents
2012 StandoutNobel
A General and Mild Ullmann-Type Synthesis of Diaryl Ethers
2004
Isolation and Synthesis of Biologically Active Carbazole Alkaloids
2002 Standout
Annulative Tandem Reactions Based on Pd0/tBu3P‐Catalyzed Cross‐Coupling and C(sp3)H Bond Activation
2006
Synthesis of Group 4 Complexes that Contain the Diamidoamine Ligands, [(2,4,6-Me3C6H2NCH2CH2)2NR]2- ([Mes2N2NR]2-; R = H or CH3), and Polymerization of 1-Hexene by Activated [Mes2N2NR]ZrMe2 Complexes
1999 StandoutNobel
Copper-Catalyzed Coupling of Aryl Iodides with Aliphatic Alcohols
2002
Visible-Light-Promoted Redox Neutral C–H Amidation of Heteroarenes with Hydroxylamine Derivatives
2014
Aryl−Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction
2002 Standout
Palladium-Catalyzed Coupling of Vinylogous Amides with Aryl Halides: Applications to the Synthesis of Heterocycles
2000
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross‐Coupling of Primary Aryl Amines with Aryl Halides
2016
Synthesis of Aryl-Substituted Triamidoamine Ligands and Molybdenum(IV) Complexes that Contain Them
1998 StandoutNobel
Palladium-Catalyzed C−N(sp2) Bond Formation: N-Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes
1998
Moderne Synthesemethoden: Kupfer‐vermittelte C(Aryl)‐O‐, C(Aryl)‐N‐ und C(Aryl)‐S‐Verknüpfungen
2003
Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer
2015
Biaryls via Suzuki Cross-Couplings Catalyzed by Nickel on Charcoal
2000
Nickel-catalysed couplings of aryl chlorides with secondary amines and piperazines
1999
Achiral Pyridine Ligand‐Enabled Enantioselective Radical Oxytrifluoromethylation of Alkenes with Alcohols
2017
A Practical Synthesis of a Diazepinylbenzoic Acid, a Retinoid X Receptor Antagonist
2008
Ein neues hocheffizientes Katalysatorsystem für die Kupplung von nichtaktivierten und desaktivierten Arylchloriden mit Arylboronsäuren
2000
SYNTHESIS OF DIARYL ETHERS USING AN EASY-TO-PREPARE, AIR-STABLE, SOLUBLE COPPER(I) CATALYST
2001
Cross‐Coupling of Triallyl(aryl)silanes with Aryl Bromides and Chlorides: An Alternative Convenient Biaryl Synthesis
2004
Visible-light-mediated oxidative arylation of vinylarenes under aerobic conditions
2014
Palladium-Catalyzed Method for the Synthesis of Carbazoles via Tandem C−H Functionalization and C−N Bond Formation
2008
Sulfur-Containing Palladacycles: Efficient Phosphine-Free Catalyst Precursors for the Suzuki Cross-Coupling Reaction at Room Temperature
2000
Enantioselective oxidative coupling of methyl 3-hydroxy-2-naphthoate using mono-N-alkylated octahydrobinaphthyl-2,2′-diamine ligand
2004
Negishi Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Hydrogen Atoms with Organozinc Reagents
2008
Cu-Catalyzed Direct Amidation of Aromatic C–H Bonds: An Access to Arylamines
2014
Introduction of Allyl and Prenyl Side‐Chains into Aromatic Systems by Suzuki Cross‐Coupling Reactions
2009
Mild Conditions for Copper‐Catalyzed Coupling Reaction of Phenols and Aryl Iodides and Bromides
2006
Aryl amination using ligand-free Ni(II) salts and photoredox catalysis
2016 Science
Microwave-promoted synthesis of amino-substituted 2-pyridone derivatives via palladium-catalyzed amination reaction
2005
A Redox-Gated Slow-Fast-Stop Molecular Rotor
2011
Aryl Amidation Routes to Dihydropyrrolo[3,2-e]indoles and Pyrrolo[3,2-f]tetrahydroquinolines: Total Synthesis of the (±)-CC-1065 CPI Subunit
2006
Total Synthesis of the N,C-Coupled Naphthylisoquinoline Alkaloids Ancistrocladinium A and B and Related Analogues
2009
Enzyme-Catalyzed Intramolecular Enantioselective Hydroalkoxylation
2017
Copper‐Mediated, Palladium‐Catalyzed Coupling of Thiol Esters with Aliphatic Organoboron Reagents.
2004
A Practical Lewis Base Catalyzed Electrophilic Chlorination of Arenes and Heterocycles
2015
Oxidative Pd(II)-Catalyzed C−H Bond Amination to Carbazole at Ambient Temperature
2008
A Ruthenium-Catalyzed Hydrative Cyclization and [4 + 2] Cycloaddition of Yne-enones
2000
Catalytic Asymmetric Vinylogous Prins Cyclization: A Highly Diastereo- and Enantioselective Entry to Tetrahydrofurans
2016 StandoutNobel
Palladium-bisimidazol-2-ylidene complexes as catalysts for general and efficient Suzuki cross-coupling reactions of aryl chlorides with arylboronic acids
2000
Diastereoselective Ruthenium−Cp Complexation of Enantiopure Arene Compounds Possessing Stereogenic Benzylic Alcohol Functionalities
2001
Carbamic acid 2-trimethylsilylethyl ester as a new ammonia equivalent for palladium-catalyzed amination of aryl halides
2010
Microwave-Assisted Palladium-Catalyzed Cross-Coupling of Aryl and Vinyl Halides with H-Phosphonate Diesters
2008
Palladium-Catalyzed Synthesis of N-Vinyl Pyrroles and Indoles
2005
Axially chiral bidentate ligands in asymmetric catalysis
2001
Efficient copper-catalyzed amination of aryl halides with amines and NH heterocycles using rac-BINOL as ligand
2006
Synthesis of Secondary Arylamines through Copper-Mediated Intermolecular Aryl Amination
2003
Nickel Complexes of a Pincer NN2 Ligand: Multiple Carbon−Chloride Activation of CH2Cl2 and CHCl3 Leads to Selective Carbon−Carbon Bond Formation
2008
Iron-Catalyzed Cross-Coupling Reactions
2002
Stereospecific Palladium-Catalyzed Cross-Coupling of (E)- and (Z)-Alkenylsilanolates with Aryl Chlorides
2006
Reduction of Dinitrogen to Ammonia at a Well-Protected Reaction Site in a Molybdenum Triamidoamine Complex
2002 StandoutNobel
Use of Tunable Ligands Allows for Intermolecular Pd-Catalyzed C−O Bond Formation
2005
A Palladium-Catalyzed Strategy for the Preparation of Indoles: A Novel Entry into the Fischer Indole Synthesis
1998
Amido Pincer Complexes of Nickel(II): Synthesis, Structure, and Reactivity
2006
Completely N1-Selective Palladium-Catalyzed Arylation of Unsymmetric Imidazoles: Application to the Synthesis of Nilotinib
2011
Macroporous Polystyrene-Supported Palladium Catalyst Containing a Bulky N-Heterocyclic Carbene Ligand for Suzuki Reaction of Aryl Chlorides
2008
Organophosphorus π-Conjugated Materials
2006 Standout
Palladium-Catalyzed Direct Arylation of Methyl Sulfoxides with Aryl Halides
2013
The Azaallylic Anion as a Synthon for Pd‐Catalyzed Synthesis of Heterocycles: Domino Two‐ and Three‐Component Synthesis of Indoles
2007
Catalytic Asymmetric Carbohydroxylation of Alkenes by a Tandem Diboration/Suzuki Cross-Coupling/Oxidation Reaction
2003
Pd‐Catalyzed Amination of Nucleoside Arylsulfonates to yield N6‐Aryl‐2,6‐Diaminopurine Nucleosides
2005
Tetraphosphine/palladium catalysed Suzuki cross-coupling reactions of aryl halides with alkylboronic acids
2004
An Expedient and Multikilogram Synthesis of a Naphthalenoid H3 Antagonist
2007
A Modified Synthesis of Iodoazidoaryl Prazosin
2002
Palladium‐Catalyzed Amination of 1‐Bromo‐ and 1‐Chloro‐1,3‐butadienes: A General Method for the Synthesis of 1‐Amino‐1,3‐butadienes
2004
Works of John P. Wolfe being referenced
Recent Developments in Palladium-Catalyzed Alkene Aminoarylation Reactions for the Synthesis of Nitrogen Heterocycles
2012
Development of Enantioselective Palladium‐Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of Tetrahydrofurans
2015
Recent advances in the stereoselective synthesis of tetrahydrofurans
2006
Synthesis of polysubstituted tetrahydrofurans via Pd-catalyzed carboetherification reactions
2006
Influence of Catalyst Structure and Reaction Conditions on anti‐ versus syn‐Aminopalladation Pathways in Pd‐Catalyzed Alkene Carboamination Reactions of N‐Allylsulfamides
2014
Synthesis of N‐Aryl‐2‐allylpyrrolidines via Palladium‐Catalyzed Carboamination Reactions of γ‐(N‐Arylamino)alkenes with Vinyl Bromides
2005
Desymmetrization of meso‐2,5‐Diallylpyrrolidinyl Ureas through Asymmetric Palladium‐Catalyzed Carboamination: Stereocontrolled Synthesis of Bicyclic Ureas
2013
Synthesis of chromans viaPd-catalyzed alkene carboetherification reactions
2011
Palladium-catalyzed alkene carboamination reactions for the synthesis of substituted piperazines
2009
Palladium‐Catalyzed Synthesis of N‐Aryl Pyrrolidines from γ‐(N‐Arylamino) Alkenes: Evidence for Chemoselective Alkene Insertion into PdN Bonds
2004
Palladium‐Catalyzed Carboetherification and Carboamination Reactions of γ‐Hydroxy‐ and γ‐Aminoalkenes for the Synthesis of Tetrahydrofurans and Pyrrolidines
2006
Synthesis of Enantiomerically Enriched Imidazolidin‐2‐Ones through Asymmetric Palladium‐Catalyzed Alkene Carboamination Reactions
2012
Highly Diastereoselective Pd-Catalyzed Carboetherification Reactions of Acyclic Internal Alkenes. Stereoselective Synthesis of Polysubstituted Tetrahydrofurans
2010
Nickel-Catalyzed Amination of Aryl Chlorides
1997
Simple, Efficient Catalyst System for the Palladium-Catalyzed Amination of Aryl Chlorides, Bromides, and Triflates
2000
New Strategy for the Synthesis of Substituted Morpholines
2009
A Highly Active Catalyst for the Room-Temperature Amination and Suzuki Coupling of Aryl Chlorides
1999
A Highly Active Catalyst for Palladium-Catalyzed Cross-Coupling Reactions: Room-Temperature Suzuki Couplings and Amination of Unactivated Aryl Chlorides
1998
Enantioselective synthesis of tetrahydroquinolines, tetrahydroquinoxalines, and tetrahydroisoquinolines via Pd-Catalyzed alkene carboamination reactions
2014
Stereoselective Synthesis of Saturated Heterocycles via Palladium-Catalyzed Alkene Carboetherification and Carboamination Reactions
2008
Intramolecular Pd-Catalyzed Carboetherification and Carboamination. Influence of Catalyst Structure on Reaction Mechanism and Product Stereochemistry
2006
Stereoselective synthesis of N-protected pyrrolidines via Pd-catalyzed reactions of γ-(N-acylamino) alkenes and γ-(N-Boc-amino) alkenes with aryl bromides
2005
Asymmetric Arylation of Ketone Enolates
1998
Selective Synthesis of 5- or 6-Aryl Octahydrocyclopenta[b]pyrroles from a Common Precursor through Control of Competing Pathways in a Pd-Catalyzed Reaction
2005
Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation
1998 Standout
Highly Active Palladium Catalysts for Suzuki Coupling Reactions
1999
Synthesis of Oxygen Heterocycles via a Palladium-Catalyzed C−O Bond-Forming Reaction
1996
Desymmetrization of meso‐2,5‐Diallylpyrrolidinyl Ureas through Asymmetric Palladium‐Catalyzed Carboamination: Stereocontrolled Synthesis of Bicyclic Ureas
2013
A New Synthesis of Imidazolidin-2-ones via Pd-Catalyzed Carboamination of N-Allylureas
2006
Development of Enantioselective Palladium‐Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of Tetrahydrofurans
2015
Asymmetric Palladium-Catalyzed Carboamination Reactions for the Synthesis of Enantiomerically Enriched 2-(Arylmethyl)- and 2-(Alkenylmethyl)pyrrolidines
2010
Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers
1999
Synthesis of Enantiomerically Enriched Imidazolidin‐2‐Ones through Asymmetric Palladium‐Catalyzed Alkene Carboamination Reactions
2012
Intramolecular Alkene Carboamination Reactions for the Synthesis of Enantiomerically Enriched Tropane Derivatives
2011
An Ammonia Equivalent for the Palladium-Catalyzed Amination of Aryl Halides and Triflates
1997
Palladium-Catalyzed Synthesis of N-Aryl-2-benzylindolines via Tandem Arylation of 2-Allylaniline: Control of Selectivity through in Situ Catalyst Modification
2004
Recent Developments in Palladium-Catalyzed Heterocycle Synthesis and Functionalization
2005
Pd-Catalyzed Carboamination of Oxazolidin-2-ones: A Stereoselective Route to trans-2,5-Disubstituted Pyrrolidines
2010
Palladium-Catalyzed Synthesis of Tetrahydrofurans from γ-Hydroxy Terminal Alkenes: Scope, Limitations, and Stereoselectivity
2005
A Concise Stereoselective Synthesis of Preussin, 3-epi-Preussin, and Analogues
2006
Intramolecular palladium-catalyzed aryl amination and aryl amidation
1996
Palladium-Catalyzed Tandem N-Arylation/Carboamination Reactions for the Stereoselective Synthesis of N-Aryl-2-benzyl Pyrrolidines
2005
Intramolecular Alkene Aminopalladation Reactions of (dppf)Pd(Ar)[N(Ar1)(CH2)3CH═CH2] Complexes. Insertion of Unactivated Alkenes into Pd−N Bonds
2010
Improved Functional Group Compatibility in the Palladium-Catalyzed Amination of Aryl Bromides
1997
Synthesis of Polycyclic Nitrogen Heterocycles via Alkene Aminopalladation/Carbopalladation Cascade Reactions
2010
Mild Conditions for the Synthesis of Functionalized Pyrrolidines via Pd-Catalyzed Carboamination Reactions
2007
An Improved Catalyst System for Aromatic Carbon−Nitrogen Bond Formation: The Possible Involvement of Bis(Phosphine) Palladium Complexes as Key Intermediates
1996
Palladium-Catalyzed Amination of Aryl Iodides
1996
Intramolecular Pd-Catalyzed Carboetherification and Carboamination
2006
Palladium‐Catalyzed Synthesis of N‐Aryl Pyrrolidines from γ‐(N‐Arylamino) Alkenes: Evidence for Chemoselective Alkene Insertion into PdN Bonds
2004
Palladium-Catalyzed Amination of Aryl Triflates
1997
Synthesis of Polycyclic Guanidines by Cyclocondensation Reactions of N-Amidinyliminium Ions
2001
A Concise Asymmetric Synthesis of cis-2,6-Disubstituted N-Aryl Piperazines via Pd-Catalyzed Carboamination Reactions
2007
Use of Aryl Chlorides as Electrophiles in Pd-Catalyzed Alkene Difunctionalization Reactions
2010
Ein hochaktiver Katalysator für Aminierung und Suzuki-Kupplung von Arylchloriden bei Raumtemperatur
1999
Synthesis of Fused-Ring and Attached-Ring bis-Tetrahydrofurans via Pd-Catalyzed Carboetherification
2009
Intramolecular Insertion of Alkenes into Pd−N Bonds. Effects of Substrate and Ligand Structure on the Reactivity of (P−P)Pd(Ar)[N(Ar1)(CH2)3CR═CHR′] Complexes
2011
Stereoselective Synthesis of Tetrahydrofurans via the Palladium-Catalyzed Reaction of Aryl Bromides with γ-Hydroxy Alkenes: Evidence for an Unusual Intramolecular Olefin Insertion into a Pd(Ar)(OR) Intermediate
2004
Room Temperature Catalytic Amination of Aryl Iodides
1997
Palladium-Catalyzed Intermolecular Carbon−Oxygen Bond Formation: A New Synthesis of Aryl Ethers
1997
Palladium-Catalyzed Synthesis of 2,1‘-Disubstituted Tetrahydrofurans from γ-Hydroxy Internal Alkenes. Evidence for Alkene Insertion into a Pd−O Bond and Stereochemical Scrambling via β-Hydride Elimination
2005
Scope and Limitations of the Pd/BINAP-Catalyzed Amination of Aryl Bromides
2000
Palladium‐Catalyzed Synthesis of N‐Aryl‐2‐benzylindolines via Tandem Arylation of 2‐Allylaniline: Control of Selectivity Through in situ Catalyst Modification.
2005
Mild Conditions for Pd-Catalyzed Carboamination of N-Protected Hex-4-enylamines and 1-, 3-, and 4-Substituted Pent-4-enylamines. Scope, Limitations, and Mechanism of Pyrrolidine Formation
2008