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INCORPORATION OF CARBON DIOXIDE IN ALKYNE OLIGOMERIZATION CATALYZED BY NICKEL(0) COMPLEXES. FORMATION OF SUBSTITUTED 2-PYRONES
1977
Binuclear zirconocene cations with μ-CH3-bridges in homogeneous Ziegler-Natta catalyst systems
1996
Works of John J. Eisch being referenced
Synthesis of pentaphenylborole, a potentially antiaromatic system
1969
Allylmagnesium Bromide as a Selective Nucleophile toward Aza-aromatic Heterocycles
1957
Organosilicon compounds with functional groups proximate to silicon
1988
Facile metalation of terminal alkynes by triphenylaluminum
1964
Carbocyclic ring expansions with alkyne and carbene sources mediated by nickel(0) complexes: Structure of the critical organonickel intermediates
1998
Mechanism of the Kulinkovich Cyclopropanol Synthesis: Transfer‐Epititanation of the Alkene in Generating the Key Titanacyclopropane Intermediate
2003
Organometallic compounds of Group III. 52. Active sites for ethylene polymerization with titanium(IV) catalysts in homogeneous media: multinuclear NMR study of ion-pair equilibria and their relation to catalyst activity
1993
Nickel-catalyzed hydralumination of alkynes and the nickel effect in the ziegler dimerization of ethylene
1968
The synthesis and the antiaromatic character of dibenz[,,1]azapentalenes
1976
Sulfone reagents in organic synthesis
1985
Facile Addition of a Grignard Reagent to an Unconjugated Ethylenic Linkage
1965
Organometallic compounds of Group III. XXX. Kinetic, stereochemical, and molecular association factors in the hydralumination of Group IV substituted alkynes. Role of p.pi.-d.pi. conjugation in the addition of diisobutylaluminum hydride to trimethyl(phenylethynyl)silane
1975
1,4- and 3,4-Cycloaddition Reactions of 1,1-Diphenyl-1,3-butadiene with Tetracyanoethylene
1966
Synthesis of cyclopropanes via the addition of organometallics to 3-substituted-1-alkenyl sulfones
1979
The titanocene methylene-zinc halide complex: a convenient synthesis and its methylenating action on unsaturated carbon centers
1983
Nickel(O) -induced geminal bond cleavages leading to carbon-carbon double bonds: intermediacy of nickel(O) -carbene complexes as a unifying hypothesis
1996
Single electron transfers in the reactions of carbanions
1996
The role of nickelole intermediates in the oligomerization of alkynes
1975
Bora-aromatic systems VI. Dehalogenation of organoboron dihalides in the search for borenes
1979
Selectivity in organometallic reactions through anchimeric coordination
1980
Henry Gilman: American Pioneer in the Rise of Organometallic Chemistry in Modern Science and Technology
2002
Organometallic compounds of Group III. XVI. Polar and stereochemical effects in the addition of triphenylaluminum to para-substituted diphenylacetylenes
1971
Functionalized organolithium reagents. 8. Novel (.alpha.,.beta.-epoxyalkyl)lithium reagents via the lithiation of organyl-substituted epoxides
1990
Organosilicon compounds with functional groups proximate to silicon. Feasible route to 1,2-epoxyalkyllithium reagents via the lithiation of epoxyethylsilanes
1976
Rearrangements of organometallic compounds. 15. Structural factors in the facile carbomagnesiation of isolated carbon-carbon double bonds
1979
Sulfone reagents in organic synthesis. Part 4. [2 + 2]-Cycloadditions of ynamines with .alpha.,.beta.-unsaturated sulfones: approach to versatile four-membered carbocyclic intermediates
1982
Forty years of Umpolung in organometallic chemistry: from carbanionic nucleophiles to metallic electrophiles
1995
Organometallic compounds of Group III. Part 41. Direct observation of the initial insertion of an unsaturated hydrocarbon into the titanium-carbon bond of the soluble Ziegler polymerization catalyst Cp2TiCl2-MeAlCl2
1985
Organic chemistry of subvalent transition metal complexes
1986
Rearrangements of organometallic compounds
1974
Karl Ziegler: master advocate for the unity of pure and applied research
1983
Intramolecular coordinative assistance in the addition of Grignard reagents to unconjugated carbon-carbon unsaturation
1969
Generation of .alpha.-sulfonylvinyllithium reagents by the lithiation of vinylic sulfones
1979
Kinetic study of the formation of dihydrogen from the reaction of [1.1]ferrocenophanes with strong acids. 2. Tensiometry, spectrometry, and deuterium exchange studies
1988
Organometallic compounds of Group III
1971
Organometallic compounds of Group III. 48. High regioselectivity in the alternative, reductive cleavages of terminal epoxides with aluminum reagents
1992
Functionalized organolithium reagents. 10. Synthesis of amines via carbon-sulfur bond cleavages of substituted aminomethyl sulfides with organolithium reagents: aminocarbene route to enamines and sterically hindered amines
1994
Stereospecific preparation of 1,2-epoxyalkyllithium reagents via the generalized lithiation of a-heterosubstituted epoxides1
1976
Re-investigation of the reported synthesis of benz[]azapentalenium salts: action of bromine on 2,3-dihydrocyclopent[]indole
1972
Rearrangement of organometallic compounds. 25. Carbon-skeletal [1,2]anionic rearrangements and the .pi.-orbital overlap constraint: the question of nucleophilic attack versus electron transfer
1989
Stereospecific alkylation of alkynes by bis(π-allyl)nickel and the mechanism of oligomerization of alkynes by nickel(0)
1975
Organometallic Compounds of Group III. II. the Reaction of Gallium Alkyls and Alkyl Hydrides with Unsaturated Hydrocarbons
1962
Lithium Chromium(I) Dihydride: A Novel Reagent for the Versatile Reductive Metathesis, Reductive Cyclization, Oligomerization, or Polymerization of Diverse Organic Substrates1
2000
Organometallic compounds of group III. XXII. Steric effects in the hydralumination, carbalumination, and oligomerization of tert-butyl(phenyl)acetylene
1972
PREPARATION AND STABILITY OF SOME ORGANOTIN AND ORGANOLEAD COMPOUNDS
1955
Organometallic compounds of Group III. XIX. Regiospecificity and stereochemistry in the hydralumination of unsymmetrical acetylenes. Controlled cis or trans reduction of 1-alkynyl derivatives
1971
Kinetics and mechanism in the electrophilic addition of triphenylaluminum to p-substituted diphenylacetylenes
1971
The π-orbital overlap requirement in 1,2-anionic rearrangements
1971
Organometallic compounds of Group III. 40. Kinetic control and locoselectivity in the electrophilic cleavage of allylic aluminum compounds: reactions of acenaphthenylaluminum reagents with carbonyl substrates
1984
Formation of ion pairs in the Ziegler ethylene polymerization catalyst system Cp2Ti(Cl)CH2SiMe3-AlCl3
1991
Rearrangements of organometallic compounds
1978
Stereochemistry of the Bimolecular Metal Reduction of Benzalaniline1
1966
Organosilicon compounds with functional groups proximate to silicon. 13. Cleavage and rearrangement reactions of epoxyethylsilanes
1976
Directed diastereotopic lithiation of .beta.-heterosubstituted alkyl sulfones
1980
Addition and oligomerization products from the reaction of diphenylacetylene with triphenylaluminum
1969
Carbon–carbon bond formation via oxidative-addition processes of titanium(II) reagents with π-bonded organic substrates. Reactivity modifications by Lewis acids and Lewis bases
2001
Stereospecific Formation of cis-Hydrindan via an Organoaluminum Cyclization Reaction1a
1966
The carbonation of unsaturated organoaluminum compounds
1968
Regiospecific and stereoselective carbometallation of alkynylsilanes by Ziegler-Natta alkylating agents
1978
1,2 Rearrangement in the reactions of lithium with β-(2- and 4-pyridyl)ethyl chlorides
1970
Rearrangements of organometallic compounds. XIII. Boraaromatic systems. IV. Synthesis of heptaphenylborepin via the thermal rearrangement of heptaphenyl-7-borabicyclo[2.2.1]heptadiene
1975
Electron-transfer processes in the alkylation of α,β-unsaturated sulfones by organometallic reagents
1984
Early transition metal carbenoid reagents in epimetallation and metallative dimerization of unsaturated organic substrates
2001
The photochemical generation of a subvalent phenylaluminum species from triphenylaluminum(III)
1968
Carbon-Carbon Bond Formation by Reductive Coupling with Titanium(II) Chloride Bis(tetrahydrofuran)
1995
Organometallic Compounds of Group III. I. The Preparation of Gallium and Indium Alkyls from Organoaluminum Compounds
1962