Standout Papers

Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer:  The R... 1998 2026 2007 2016 4.3k
  1. Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer:  The RAFT Process (1998)
    John Chiefari, Yu Chong et al. Macromolecules

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Electrochemically Mediated Atom Transfer Radical Polymerization
2011 Science
Cu-Catalyzed Azide−Alkyne Cycloaddition
2008 StandoutNobel
Living polymerization: Rationale for uniform terminology
2000
Production of crosslinked, hollow nanoparticles by surface‐initiated living free‐radical polymerization
2002
Radical addition–fragmentation chemistry in polymer synthesis
2007 Standout
Phosphazene Bases:  A New Category of Organocatalysts for the Living Ring-Opening Polymerization of Cyclic Esters
2007
Atom Transfer Radical Polymerization of (Meth)acrylamides
1999
Catalyst separation in atom transfer radical polymerization
2004
Dual Roles of a Xanthate as a Radical Source and Chain Transfer Agent in the Photoinitiated RAFT Polymerization of Vinyl Acetate
2014
Exploration, Optimization, and Application of Supramolecular Thiourea−Amine Catalysts for the Synthesis of Lactide (Co)polymers
2006
Reversible-Deactivation Radical Polymerization in the Presence of Metallic Copper. A Critical Assessment of the SARA ATRP and SET-LRP Mechanisms
2013
Kinetic Analysis of Controlled/“Living” Radical Polymerizations by Simulations. 2. Apparent External Orders of Reactants in Atom Transfer Radical Polymerization
2000
Raft mediated surface grafting of t‐butyl acrylate onto an ethylene–propylene copolymer initiated by gamma radiation
2007
Continuous flow synthesis of poly(methyl methacrylate) via a light‐mediated controlled radical polymerization
2015
Effect of rate retardation in RAFT grafting polymerization from silicon wafer surface
2007
Development of Thermal and Photochemical Strategies for Thiol−Ene Click Polymer Functionalization
2008
Microflow Technology in Polymer Synthesis
2012
Design and synthesis of well-defined glycopolymers for the control of biological functionalities
2012
Dimanganese decacarbonyl/2-cyanoprop-2-yl-1-dithionaphthalate: toward sunlight induced RAFT polymerization of MMA
2014
Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials
2009
Advances in RAFT polymerization: the synthesis of polymers with defined end-groups
2005
Radical Polymerization of Styrene Controlled by Half-Sandwich Mo(III)/Mo(IV) Couples:  All Basic Mechanisms Are Possible
2001
Mechanism and kinetics of dithiobenzoate‐mediated RAFT polymerization. I. The current situation
2006
Block Copolymerizations of Vinyl Acetate by Combination of Conventional and Atom Transfer Radical Polymerization
1999
Structural Control of Poly(Methyl Methacrylate)-g-poly(Lactic Acid) Graft Copolymers by Atom Transfer Radical Polymerization (ATRP)
2001
A simple method to convert atom transfer radical polymerization (ATRP) initiators into reversible addition fragmentation chain-transfer (RAFT) mediators
2003
Effect of Mild Visible Light on Rapid Aqueous RAFT Polymerization of Water-Soluble Acrylic Monomers at Ambient Temperature: Initiation and Activation
2009
RAFT Polymerization of N-Isopropylacrylamide in the Absence and Presence of Y(OTf)3: Simultaneous Control of Molecular Weight and Tacticity
2004
Controlled grafting from poly(vinylidene fluoride) films by surface‐initiated reversible addition–fragmentation chain transfer polymerization
2006
pH-Responsive Polymeric Micelle Carriers for siRNA Drugs
2010
Miktoarm star polymers via cyclodextrin-driven supramolecular self-assembly
2012
Benzoyl Phenyltelluride as Highly Reactive Visible-Light TERP-Reagent for Controlled Radical Polymerization
2014
Kinetics of living radical polymerization
2004 Standout
Synthesis of Surface Initiated Diblock Copolymer Brushes from Flat Silicon Substrates Utilizing the RAFT Polymerization Technique
2007
Development of organotellurium‐mediated and organostibine‐mediated living radical polymerization reactions
2005
Copper(II)/Tertiary Amine Synergy in Photoinduced Living Radical Polymerization: Accelerated Synthesis of ω-Functional and α,ω-Heterofunctional Poly(acrylates)
2013
Aqueous RAFT Polymerization:  Recent Developments in Synthesis of Functional Water-Soluble (Co)polymers with Controlled Structures
2004
50th Anniversary Perspective: Polymer Brushes: Novel Surfaces for Future Materials
2017
Ab Initio Emulsion Polymerization by RAFT-Controlled Self-Assembly
2005
Water-Compatible Molecularly Imprinted Microspheres in Pipette Tip Solid-Phase Extraction for Simultaneous Determination of Five Fluoroquinolones in Eggs
2013
Reversible Addition−Fragmentation Chain Transfer Polymerization:  End Group Modification for Functionalized Polymers and Chain Transfer Agent Recovery
2005
Continuous Miniemulsion Polymerization
2008
Reversible addition–fragmentation chain‐transfer graft polymerization of styrene: Solid phases for organic and peptide synthesis
2002
Organocatalytic Ring Opening Polymerization of Trimethylene Carbonate
2006
Molecular imprinting: perspectives and applications
2016 Standout
Copper(I)-Catalyzed Atom Transfer Radical Polymerization
1999
Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques
2015
Synthesis of TiO2/PAA nanocomposite by RAFT polymerization
2007
Controlled Radical Polymerization of Vaporized Vinyl Monomers on Solid Surfaces under UV Irradiation
2004

Works of John Chiefari being referenced

Chain Transfer to Polymer:  A Convenient Route to Macromonomers
1999
Continuous Flow Aminolysis of RAFT Polymers Using Multistep Processing and Inline Analysis
2014
A Continuous Flow Process for the Radical Induced End Group Removal of RAFT Polymers
2012
Tailored polymer architectures by reversible addition-frasmentation chain transfer
2001
Sequential flow process for the controlled polymerisation and thermolysis of RAFT-synthesised polymers
2014
Thiocarbonylthio Compounds (SC(Z)S−R) in Free Radical Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT Polymerization). Effect of the Activating Group Z
2003
Initiating free radical polymerization
2002
Universal (Switchable) RAFT Agents
2009
Binary Copolymerization with Catalytic Chain Transfer. A Method for Synthesizing Macromonomers Based on Monosubstituted Monomers
2005
Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT Polymerization) Using Dithiocarbamates as Chain Transfer Agents
1999
Acid−Amide Intermolecular Hydrogen Bonding
1997
Tailored polymers by free radical processes
1999
Thermo-Induced Self-Assembly of Responsive Poly(DMAEMA-b-DEGMA) Block Copolymers into Multi- and Unilamellar Vesicles
2012
Living Polymers by the Use of Trithiocarbonates as Reversible Addition−Fragmentation Chain Transfer (RAFT) Agents:  ABA Triblock Copolymers by Radical Polymerization in Two Steps
2000
Quasi-block copolymer libraries on demand via sequential RAFT polymerization in an automated parallel synthesizer
2013
Synthesis and conformation of a bilirubin analog with propionic acid side chains extended to undecanoic acid
1992
Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer:  The RAFT Process
1998 Standout
Controlled RAFT Polymerization in a Continuous Flow Microreactor
2011
Living free radical polymerization with reversible addition - fragmentation chain transfer (the life of RAFT)
2000
Rankless by CCL
2026