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Citing Papers

Oxindole Synthesis by Direct Coupling of CH and CH Centers
2009
Copper-catalyzed cyanation of arenes using benzyl nitrile as a cyanide anion surrogate
2012
Palladium complexes of abnormal N-heterocyclic carbenes as precatalysts for the much preferred Cu-free and amine-free Sonogashira coupling in air in a mixed-aqueous medium
2009
Copper-free Sonogashira cross-coupling reaction catalyzed by polymer-supported N-heterocyclic carbene palladium complex
2007
Efficient Synthesis of Hydroxyl Isoindolones by a Pd‐Mediated CH Activation/Annulation Reaction
2013
Copper‐Mediated CH/CH Biaryl Coupling of Benzoic Acid Derivatives and 1,3‐Azoles
2013
Steric and Electronic Effects on the Configurational Stability of Residual Chiral Phosphorus‐Centered Three‐Bladed Propellers: Tris‐aryl Phosphanes
2012
RhIII‐Catalyzed Oxidative Olefination of Vinylic CH Bonds: Efficient and Selective Access to Di‐unsaturated α‐Amino Acid Derivatives and Other Linear 1,3‐Butadienes
2011
Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant
2012
Copper‐Catalyzed Aromatic CH Bond Cyanation by CCN Bond Cleavage of Inert Acetonitrile
2013
Iron‐Facilitated Oxidative Dehydrogenative CO Bond Formation by Propargylic CH Functionalization
2012
Copper-promoted decarboxylative direct C3-acylation of N-substituted indoles with α-oxocarboxylic acids
2013
Copper-mediated oxidative direct C–C (hetero)aromatic cross-coupling
2012
Direct 2-acetoxylation of quinoline N-oxides via copper catalyzed C–H bond activation
2013
Palladium-catalyzed direct arylation of benzoxazoles with unactivated simple arenes
2012
Cobalt‐Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides
2011
Asymmetric Disulfonimide‐Catalyzed Synthesis of δ‐Amino‐β‐Ketoester Derivatives by Vinylogous Mukaiyama–Mannich Reactions
2014 StandoutNobel
Development of Novel Thiazolopyrimidines as CDC25B Phosphatase Inhibitors
2009
Copper‐Catalyzed Oxidative Coupling of Alkenes with Aldehydes: Direct Access to α,β‐Unsaturated Ketones
2013
Transition-metal mediated carbon–sulfur bond activation and transformations
2012 Standout
A Novel and Convenient Synthesis of Benzonitriles: Electrophilic Cyanation of Aryl and Heteroaryl Bromides
2011
Copper-catalyzed phosphorylation of sp2C–H bonds
2014
Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process
2012
Recent developments and perspectives in palladium-catalyzed cyanation of aryl halides: synthesis of benzonitriles
2011
Catalysis for fluorination and trifluoromethylation
2011 StandoutNature
C–H bond halogenation catalyzed or mediated by copper: an overview
2015
Iodine‐Catalyzed Oxidative Coupling Reactions Utilizing CH and XH as Nucleophiles
2015
Highly Selective Iron‐Catalyzed Synthesis of Alkenes by the Reduction of Alkynes
2011
Ru-catalyzed aerobic oxidative coupling of arylboronic acids with arenes
2010
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
Copper‐Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights
2011
Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds
2009
Cobalt‐Catalyzed C(sp2)H Alkoxylation of Aromatic and Olefinic Carboxamides
2014
Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality
2009 Standout
Improved Palladium‐Catalyzed Sonogashira Coupling Reactions of Aryl Chlorides
2009
Direct CH Arene Homocoupling over Gold Nanoparticles Supported on Metal Oxides
2015
Palladium‐Catalyzed Direct Arylation of Cyclic Enamides with Aryl Silanes by sp2 CH Activation
2009
Highly Convenient Amine‐Free Sonogashira Coupling in Air in a Polar Mixed Aqueous Medium by trans‐ and cis‐[(NHC)2PdX2] (X=Cl, Br) Complexes of N/O‐Functionalized N‐Heterocyclic Carbenes
2008
Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
2010 Standout
Palladium Catalysts for Highly Selective Sonogashira Reactions of Aryl and Heteroaryl Bromides
2007
Palladium‐Based Catalytic Systems for the Synthesis of Conjugated Enynes by Sonogashira Reactions and Related Alkynylations
2007
Synthesis of Extended π‐Systems through C–H Activation
2014 Standout
Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components
2007
Copper-catalyzed, aerobic oxidative cross-coupling of alkynes with arylboronic acids: remarkable selectivity in 2,6-lutidine media
2011
Ligand‐Free Sonogashira Coupling Reactions with Heterogeneous Pd/C as the Catalyst
2008
Rhodium-catalyzed oxidative C2-acylation of indoles with aryl and alkyl aldehydes
2012
Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation
2009
Direct Cross‐Coupling of CH Bonds with Grignard Reagents through Cobalt Catalysis
2010
Copper‐Catalyzed Dehydrogenative Coupling of Arenes with Alcohols
2013
Rhodium(III)‐ and Iridium(III)‐Catalyzed C7 Alkylation of Indolines with Diazo Compounds
2014
Copper‐Mediated C6‐Selective Dehydrogenative Heteroarylation of 2‐Pyridones with 1,3‐Azoles
2014
Direct C–H bond arylation of arenes with aryltin reagents catalysed by palladium complexes
2008
Palladium‐Catalyzed ortho‐Acylation of Acetanilides with Aldehydes through Direct CH Bond Activation
2011
Room‐Temperature Palladium‐Catalyzed CH Activation: ortho‐Carbonylation of Aniline Derivatives
2009
Copper-catalyzed direct thiolation of azoles with aliphatic thiols
2011
Electrochemical generation of silver acetylides from terminal alkynes with a Ag anode and integration into sequential Pd-catalysed coupling with arylboronic acids
2010
Rhodium‐Catalyzed Oxidative Olefination of CH Bonds in Acetophenones and Benzamides
2010
Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation
2010
Heterogeneously Catalyzed Direct CH Thiolation of Heteroarenes
2015
Copper-catalyzed aromatic C–H bond halogenation with lithium halides under aerobic conditions
2013
Iron catalysed direct alkylation of amines with alcohols
2014 StandoutNobel
Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
2010 StandoutNobel
Manganese‐Catalyzed Direct Nucleophilic C(sp2)H Addition to Aldehydes and Nitriles
2015
Iron Pincer Complex Catalyzed, Environmentally Benign, E‐Selective Semi‐Hydrogenation of Alkynes
2013
Selective N-monoalkylation of aromatic amines with benzylic alcohols by a hydrogen autotransfer process catalyzed by unmodified magnetite
2009
Cu(ii)-mediated oxidative intermolecular ortho C–H functionalisation using tetrahydropyrimidine as the directing group
2009
Selectivity enhancement in functionalization of C–H bonds: A review
2010
Oxidative Biaryl Coupling of Thiophenes and Thiazoles with Arylboronic Acids through Palladium Catalysis: Otherwise Difficult C4‐Selective CH Arylation Enabled by Boronic Acids
2011
Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents
2010
Copper‐Catalyzed Regioselective Intramolecular Oxidative α‐Functionalization of Tertiary Amines: An Efficient Synthesis of Dihydro‐1,3‐Oxazines
2013
Transition‐Metal‐Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage
2009 Standout
Metal‐Free Arylation of Oxygen Nucleophiles with Diaryliodonium Salts
2012
Copper-catalyzed ortho-halogenation of protected anilines
2013
Palladium‐Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids
2008
An overview of N-heterocyclic carbenes
2014 StandoutNature
High-valent organometallic copper and palladium in catalysis
2012 Nature
Synthesis of Acrylonitriles through an FeCl3‐Catalyzed Domino Propargylic Substitution/Aza‐Meyer–Schuster Rearrangement Sequence
2012
Cobalt-catalyzed arylation of aldimines via directed C–H bond functionalization: addition of 2-arylpyridines and self-coupling of aromatic aldimines
2012
Iron‐Mediated Direct Arylation of Unactivated Arenes
2008
A diversity oriented four-component approach to tetrahydro-β-carbolines initiated by Sonogashira coupling
2005
Beyond Directing Groups: Transition‐Metal‐Catalyzed CH Activation of Simple Arenes
2012 Standout
Recent advances in copper-catalyzed C–H bond amidation
2015
Synthesis of Aryl Ethers from Benzoates through Carboxylate‐Directed CH‐Activating Alkoxylation with Concomitant Protodecarboxylation
2013
Recent advances in Sonogashira reactions
2011 Standout
Rhodium(III)‐Catalyzed [4+1] Annulation of Aromatic and Vinylic Carboxylic Acids with Allenes: An Efficient Method Towards Vinyl‐Substituted Phthalides and 2‐Furanones
2015
Cu(TFA)2‐Catalyzed Picolinamido‐Directed C(sp2)−H Cyanation of Naphthalenes by Using Benzoyl Cyanide as a Cyano Source
2017
Click Chemistry for Drug Development and Diverse Chemical–Biology Applications
2013 Standout
Copper-Mediated Intermolecular Direct Biaryl Coupling
2011
Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates
2008 Standout
Copper-Catalyzed Three-Component Reaction for Regioselective Aryl- and Heteroarylselenation of Indoles using Selenium Powder
2016
Copper- and Ligand-Free Sonogashira Reaction Catalyzed by Pd(0) Nanoparticles at Ambient Conditions under Ultrasound Irradiation
2005
Copper‐Catalyzed ortho ‐Thiomethylation of Benzamides via 8‐Aminoquinoline‐Assisted C‐H Activation with Dimethyl Sulfoxide
2017
Iron-Catalyzed Regioselective Direct Oxidative Aryl–Aryl Cross-Coupling
2011
Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene
2011
Iron Catalysis in Organic Synthesis
2015 Standout
Regioselective copper-catalyzed thiolation of imidazo[1,2-a]pyridines: an efficient C–H functionalization strategy for C–S bond formation
2015
3d Transition Metals for C–H Activation
2018 Standout
SuFEx Click Chemistry Enabled Late-Stage Drug Functionalization
2018 StandoutNobel
Palladiumkatalysierte oxidative Kupplung von Thiophenen und Thiazolen mit Arylboronsäuren: ungewöhnliche C4‐selektive C‐H‐Arylierung durch den Einsatz von Boronsäuren
2011
Microwave-Assisted Cp*CoIII-Catalyzed C–H Activation/Double C–N Bond Formation Reactions to Thiadiazine 1-Oxides
2017
Copper Acetate–DMSO Promoted Methylthiolation of Arenes and Heteroarenes
2015
Copper-Mediated Direct C2-Cyanation of Indoles Using Acetonitrile as the Cyanide Source
2013
Carboxylate‐Directed CH Functionalization
2014
Copper-free and amine-free Sonogashira coupling in air in a mixed aqueous medium by palladium complexes of N/O-functionalized N-heterocyclic carbenes
2009
Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions
2011 Standout
N,N‐Dimethylacetamide (DMA) as a Methylene Synthon for Regioselective Linkage of Imidazo[1,2‐a]pyridine
2016
Cu(I)‐Catalyzed Site Selective Acyloxylation of Indoline Using O2 as the Sole Oxidant
2018
Copper-Catalyzed Selective Benzylic C–O Cyclization ofN-o-Tolylbenzamides: Synthesis of 4H-3,1-Benzoxazines
2012
Copper‐Catalyzed Coupling of Arylboronic Acids with Potassium Cyanate: A New Approach to the Synthesis of Aryl Carbamates
2011
Copper-mediated regioselective C–H etherification of naphthylamides with arylboronic acids using water as an oxygen source
2018
Lewis Acid-Catalyzed, Copper(II)-Mediated Synthesis of Heteroaryl Thioethers under Base-Free Conditions
2012
Ruthenium(II)‐Catalyzed Chelation‐Assisted Arylation of CH Bonds with Diaryliodonium Salts
2013
Copper-catalyzed domino synthesis of benzo[b]thiophene/imidazo[1,2-a]pyridines by sequential Ullmann-type coupling and intramolecular C(sp2)–H thiolation
2015
Benzoyl Peroxide Promoted Radical ortho‐Alkylation of Nitrogen Heteroaromatics with Simple Alkanes and Alcohols
2015
Palladium-catalyzed cyanide metathesis: utilization of benzyl cyanide as an operator-benign reagent for aryl halide cyanations
2012
Radical Arylalkoxycarbonylation of 2-Isocyanobiphenyl with Carbazates: Dual C–C Bond Formation toward Phenanthridine-6-carboxylates
2014
Electrochemical synthesis of benzoxazoles mediated by 2,3-dichloro-5,6-dicyano-p-hydroquinone (DDH) as a redox catalyst
2016
Palladium(II)‐Catalyzed Direct ortho‐CH Acylation of Anilides by Oxidative Cross‐Coupling with Aldehydes using tert‐Butyl Hydroperoxide as Oxidant
2011
Use of Molecular Oxygen as a Reoxidant in the Synthesis of 2‐Substituted Benzothiazoles via Palladium‐Catalyzed CH Functionalization/Intramolecular CS Bond Formation
2010
Cobalt(iii)-catalyzed annulation of esters and alkynes: a facile route to indenones
2016
A Noble‐Metal‐Free Metal–Organic Framework (MOF) Catalyst for the Highly Efficient Conversion of CO2 with Propargylic Alcohols
2018
Immobilized Palladium on Organic‐inorganic Hybrid Materials: A Novel and Reusable Catalyst for the Copper‐Free Sonogashira Coupling Reaction
2008
Copper-Catalyzed Cyanation of Heterocycle Carbon−Hydrogen Bonds
2010
Palladium-Catalyzed Decarboxylative Arylation of C−H Bonds by Aryl Acylperoxides
2009
Copper-Mediated Sequential Cyanation of Aryl C–B and Arene C–H Bonds Using Ammonium Iodide and DMF
2012
Organic Photoredox Catalysis
2016 Standout
Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions
2009
Copper-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling of Amine and α-Carbonyl Aldehyde: A Practical and Efficient Approach to α-Ketoamides with Wide Substrate Scope
2012
Nitrogen-directed ortho-arylation and -heteroarylation of aromatic rings catalyzed by ruthenium complexes
2008
Synthesis of 2-Substituted-5-halo-2,3-dihydro-4(H)-pyrimidin-4-ones and Their Derivatization Utilizing the Sonogashira Coupling Reaction in the Enantioselective Synthesis of α-Substituted β-Amino Acids
2007
A copper-free Sonogashira reaction using a Pd/MgLa mixed oxide
2006
Cu(II)-Mediated C–S/N–S Bond Formation via C–H Activation: Access to Benzoisothiazolones Using Elemental Sulfur
2014
A highly active palladium-phosphoramidite catalyst for the Suzuki cross-coupling of aryl bromides
2005
Multidimensional SuFEx Click Chemistry: Sequential Sulfur(VI) Fluoride Exchange Connections of Diverse Modules Launched From An SOF4 Hub
2017 StandoutNobel
Tandem Rh(III)-Catalyzed Oxidative Acylation of Secondary Benzamides with Aldehydes and Intramolecular Cyclization: The Direct Synthesis of 3-Hydroxyisoindolin-1-ones
2012
Copper-catalyzed direct oxidative C(sp 2 )-H α -sulfenylation of enaminones with disulfides or thiophenols: Synthesis of polyfunctionalized aminothioalkenes
2018
Copper- and base-free Sonogashira-type cross-coupling reaction of triarylantimony dicarboxylates with terminal alkynes under an aerobic condition
2009
Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations
2015 Standout
NHC−Iron-Catalyzed Aerobic Oxidative Aromatic Esterification of Aldehydes using Boronic Acids
2010
Benzenesulfonyl chlorides: new reagents for access to alternative regioisomers in palladium-catalysed direct arylations of thiophenes
2013
Direct ortho-Thiolation of Arenes and Alkenes by Nickel Catalysis
2015
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
2018 Standout
Copper-Catalyzed Formal [4 + 1] Cycloaddition of Benzamides and Isonitriles via Directed C–H Cleavage
2015
Iron-Mediated Direct Suzuki−Miyaura Reaction: A New Method for the ortho-Arylation of Pyrrole and Pyridine
2010
Cooperative capture synthesis: yet another playground for copper-free click chemistry
2016 StandoutNobel
Palladium-catalyzed C2-acylation of indoles with aryl and alkyl aldehydes
2014
Iron‐Mediated Direct Arylation of Unactivated Arenes
2008
Expedient C–H Chalcogenation of Indolines and Indoles by Positional-Selective Copper Catalysis
2016
Ortho-selective Arylation of Arylazoles with Aryl Bromides Catalyzed by Ruthenium Complexes
2008
Palladium-Catalyzed Direct Arylation of Azine and Azole N-Oxides: Reaction Development, Scope and Applications in Synthesis
2009
Highly Efficient Catalytic System for C–H Activation: A Practical Approach to Angiotensin II Receptor Blockers
2011
Copper-Mediated Direct Aryl C–H Cyanation with Azobisisobutyronitrile via a Free-Radical Pathway
2013
Aromatic C–H coupling with hindered arylboronic acids by Pd/Fe dual catalysts
2013
SuFEx Chemistry of Thionyl Tetrafluoride (SOF4) with Organolithium Nucleophiles: Synthesis of Sulfonimidoyl Fluorides, Sulfoximines, Sulfonimidamides, and Sulfonimidates
2018 StandoutNobel
Highly efficient Cu-catalyzed oxidative coupling of tertiary amines and siloxyfurans
2008
Rhodium-Catalyzed Oxidative ortho-Acylation of Benzamides with Aldehydes: Direct Functionalization of the sp2 C–H Bond
2011
Iron-catalyzed arylation of benzoazoles with aromatic aldehydes using oxygen as oxidant
2012
Copper catalyzed oxidative ortho-C–H benzoxylation of 2-phenylpyridines with benzyl alcohols and benzyl amines as benzoxylation sources
2014
Palladium‐Catalyzed Oxidative Acylation of N‐Benzyltriflamides with Aldehydes via CH Bond Activation
2013
Mechanism for Carbon−Oxygen Bond-Forming Reductive Elimination from Palladium(IV) Complexes
2008
Synthesis of Isoquinolines from Benzimidates and Alkynes via Cobalt(III)-Catalyzed C–H Functionalization/Cyclization
2017
A new, efficient, and inexpensive copper(II)/salicylic acid complex catalyzed Sonogashira-type cross-coupling of haloarenes and iodoheteroarenes with terminal alkynes
2010
Transition metals in organic synthesis: Highlights for the year 2005
2007
A New Combined Source of “CN” from N,N-Dimethylformamide and Ammonia in the Palladium-Catalyzed Cyanation of Aryl C−H Bonds
2010
Highly Site‐Selective and Direct Ortho‐C−H Nitration, Trifluoromethylation and Cyanation at the C1‐Position of Carbazole Frameworks
2016
Synthesis of Indolines by Copper-Mediated Intramolecular Aromatic C–H Amination
2015
The Sonogashira Reaction:  A Booming Methodology in Synthetic Organic Chemistry
2007 Standout
Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components
2007
Nickel-catalyzed synthesis of diarylsulfides and sulfones via C–H bond functionalization of arylamides
2015
Palladium‐Catalyzed Acylation of 2‐Aryl‐1,2,3‐triazoles with Aldehydes
2014
Copper-Catalyzed Direct Amination of Quinoline N-Oxides via C–H Bond Activation under Mild Conditions
2014
Cu-Catalyzed Cyanation of Indoles with Acetonitrile as a Cyano Source
2015
C–O Bonds from Pd‐Catalyzed C(sp3)–H Reactions Mediated by Heteroatomic Groups
2018
Facile synthesis of palladium nanoclusters and their catalytic activity in Sonogashira coupling reactions
2008
Iron‐Catalyzed Direct C–H Arylation of Heterocycles and Quinones with Arylboronic Acids
2013
An Efficient Copper-Catalyzed Carbon−Sulfur Bond Formation Protocol in Water
2010
Copper(II)-catalyzed direct thiolation of C–H bonds in aromatic amides with aryl and aliphatic thiols
2014
Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope
2011 Standout
Expedient cobalt(ii)-catalyzed site-selective C7-arylation of indolines with arylboronic acids
2018
Highly Convenient, Clean, Fast, and Reliable Sonogashira Coupling Reactions Promoted by Aminophosphine‐Based Pincer Complexes of Palladium Performed under Additive‐ and Amine‐Free Reaction Conditions
2009
Recent advances in the ruthenium-catalyzed hydroarylation of alkynes with aromatics: synthesis of trisubstituted alkenes
2015
Advances in C–CN Bond Formation via C–H Bond Activation
2016
Co(II)-Catalyzed Regioselective Cross-Dehydrogenative Coupling of Aryl C–H Bonds with Carboxylic Acids
2017
Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3
2010
Cu(II)-catalyzed acetoxylation of arenes by 1,2,3-triazole-directed C–H activation
2017
A diphenylphosphinoethane-functionalized polystyrene resin-supported Pd(0) complex as an effective catalyst for copper-free Sonogashira coupling reactions under aerobic conditions
2009
Dibenzothiophene Sulfoximine as an NH3 Surrogate in the Synthesis of Primary Amines by Copper‐Catalyzed C−X and C−H Bond Amination
2017
Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development
2014
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
2009 Standout
Benzylamine as an arylcarboxy surrogate: a copper catalysed o-benzoxylation of 2-phenylpyridines using benzyl amines
2014
Chelation-Assisted Copper-Mediated Direct Acetylamination of 2-Arylpyridine C–H Bonds with Cyanate Salts
2016
Bidentate Directing-Enabled, Traceless Heterocycle Synthesis: Cobalt-Catalyzed Access to Isoquinolines
2016
Iron‐Catalyzed Synthesis of Indenones through Cyclization of Carboxamides with Alkynes
2018
Facile Synthesis of Substituted Alkynes by Cyclopalladated Ferrocenylimine Catalyzed Cross‐Coupling of Arylboronic Acids/Esters with Terminal Alkynes
2007
Synthesis of Isoquinolines via Rh(III)-Catalyzed C–H Activation Using Hydrazone as a New Oxidizing Directing Group
2013
Regioselective ortho-hydroxylation of 2-arylbenzothiazole via substrate directed C–H activation
2013
Copper-Mediated Dehydrogenative Biaryl Coupling of Naphthylamines and 1,3-Azoles
2013
Convenient copper- and solvent-free Sonogashira-type alkynylation of aryl iodides and bromides using Pd EnCat™
2008
Cobalt(III)-Catalyzed Oxadiazole-Directed C–H Activation for the Synthesis of 1-Aminoisoquinolines
2017
Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates
2014 StandoutNobel
Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C–H Oxidation
2013
Recent Advances in Organic Reactions Involving Elemental Sulfur
2017
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
2019 StandoutNobel
Palladium‐Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids
2008
Copper-Catalyzed Synthesis of Benzoxazoles via a Regioselective C−H Functionalization/C−O Bond Formation under an Air Atmosphere
2009
Iron or boron-catalyzed C–H arylthiation of substituted phenols at room temperature
2014
Nickel-catalyzed ortho-halogenation of unactivated (hetero)aryl C–H bonds with lithium halides using a removable auxiliary
2016
Rhodium-Catalyzed Synthesis of Isoquinolines and Indenes from Benzylidenehydrazones and Internal Alkynes
2014
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Copper‐Catalyzed Selective Oxidative Acylation of Secondary Anilines with Ethyl Glyoxalate: Domino Synthesis of Indoline‐2,3‐diones
2013
Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides
2016
Cu-Catalyzed Mild C(sp2)–H Functionalization Assisted by Carboxylic Acids en Route to Hydroxylated Arenes
2013
Copper-Catalyzed Direct Acyloxylation of C(sp2)–H Bonds in Aromatic Amides
2017
Iridium(III)-Catalyzed C-7 Selective C–H Alkynylation of Indolines at Room Temperature
2015
Copper‐Mediated Thiolation of Unactivated Heteroaryl C−H Bonds with Disulfides under Ligand‐ and Metal‐Oxidant‐Free Conditions
2017
Growth mechanisms and anisotropic softness–dependent conductivity of orientation-controllable metal–organic framework nanofilms
2023 StandoutNobel
Metal-Free Synthesis of Aryl Esters from Carboxylic Acids and Diaryliodonium Salts
2011
Copper-catalyzed direct C–H arylation of pyridine N-oxides with arylboronic esters: one-pot synthesis of 2-arylpyridines
2014
Copper-catalyzed carboxylation reactions using carbon dioxide
2016
Copper-Catalyzed Coupling of Aryl Halides with Terminal Alkynes in the Presence of KF/Al2O3
2009
A General Rhodium‐Catalyzed Cyanation of Aryl and Alkenyl Boronic Acids
2010
Novel pyridine‐bis(ferrocene‐isoxazole) ligand: synthesis and application to palladium‐catalyzed Sonogashira cross‐coupling reactions under copper‐ and phosphine‐free conditions
2008
Synthesis of Angiotensin II Receptor Blockers by Means of a Catalytic System for C–H Activation
2011
General, Green, and Scalable Synthesis of Imines from Alcohols and Amines by a Mild and Efficient Copper‐Catalyzed Aerobic Oxidative Reaction in Open Air at Room Temperature
2012
Oxidative Coupling of Arylboronic Acids with Arenes via Rh-Catalyzed Direct C−H Arylation
2007
Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit
2009
Benzylic-acetoxylation of alkylbenzenes with PhI(OAc)2 in the presence of catalytic amounts of TsNH2 and I2
2011
Mild Palladium‐Catalyzed Oxidative Direct ortho‐CH Acylation of Anilides under Aqueous Conditions
2013
Pd-catalyzed oxidative coupling of monosubstituted sydnones and terminal alkynes
2011
Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions
2011 Standout
Copper-catalyzed, oxidative sp2 C-H cyanation: facile synthesis of aromatic carbonitriles
2014
Iron(II)‐Catalyzed Direct Cyanation of Arenes with Aryl(cyano)iodonium Triflates
2014
Organocatalytic C–H Bond Arylation of Aldehydes to Bis-heteroaryl Ketones
2013
Rhodium(I)-Catalyzed Direct Carboxylation of Arenes with CO2 via Chelation-Assisted C−H Bond Activation
2010
Copper-Catalyzed Etherification of Arene C–H Bonds
2013
Iron-Catalyzed Cross-Dehydrogenative Coupling Esterification of Unactive C(sp3)–H Bonds with Carboxylic Acids for the Synthesis of α-Acyloxy Ethers
2014
Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates
2009
Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate
2010
A simple catalyst system for the palladium-catalyzed coupling of aryl halides with terminal alkynes
2005
A Palladium/Perfluoroalkylated Pyridine Catalyst for Sonogashira Reaction of Aryl Bromides and Chlorides in a Fluorous Biphasic System
2007
Efficient silver-catalyzed direct sulfenylation and selenylation of rich arenes
2014
Chemicals from Alkynes with Palladium Catalysts
2013
Highly Efficient Copper‐Catalyzed Synthesis of Internal Alkynes via Aerobic Oxidative Arylation of Terminal Alkynes
2010
Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization
2012
Catalytic Electrochemical C–H Iodination and One-Pot Arylation by ON/OFF Switching of Electric Current
2012
Aerobic Copper-Catalyzed Organic Reactions
2013 Standout
Palladium-Catalyzed Direct Alkynylation of C−H Bonds in Benzenes
2009
Copper-Catalyzed Intramolecular C−H Oxidation/Acylation of Formyl-N-arylformamides Leading to Indoline-2,3-diones
2010
Copper- and phosphine-free Sonogashira coupling reactions of aryl iodides catalyzed by an N,N-bis(naphthylideneimino)diethylenetriamine-functionalized polystyrene resin supported Pd(II) complex under aerobic conditions
2010
Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance
2017 Standout
Iron-Catalyzed Direct C-H Thiolation of Trimethoxybenzene with Disulfides
2012
Palladium-Catalyzed Alkoxylation of N-Methoxybenzamides via Direct sp2 C−H Bond Activation
2009
Direct and Site‐Selective Palladium‐Catalyzed C‐7 Acylation of Indolines with Aldehydes
2015
Cu‐Mediated Direct Aryl CH Halogenation: a Strategy to Control Mono‐ and Di‐Selectivity
2013
Rhodium‐Catalyzed Oxidative ortho‐Acylation of Aryl Ketone O‐Methyl Oximes with Aryl and Alkyl Aldehydes
2012
Iron‐Catalyzed Generation of α‐Amino Nitriles from Tertiary Amines
2013
Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization
2012 Standout
Mechanical Stabilization of Helical Chirality in a Macrocyclic Oligothiophene
2019 StandoutNobel
Sonogashira reactions catalyzed by water-soluble, β-cyclodextrin-capped palladium nanoparticles
2007
Cu-mediated C–H cyanation of arenes using N,N-dimethylformamide (DMF) as the “CN” source
2014
Recent Advances in Radical C–H Activation/Radical Cross-Coupling
2017
Insights into Directing Group Ability in Palladium-Catalyzed C−H Bond Functionalization
2008
Highly mono-selective ortho-methylthiolation of benzamides via cobalt-catalyzed sp2 C–H activation
2017
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
2006 Standout
Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
2019 Standout
Palladium-catalysed regioselective aroylation and acetoxylation of 3,5-diarylisoxazole via ortho C–H functionalisations
2013
Copper-Mediated Selective Cyanation of Indoles and 2-Phenylpyridines with Ammonium Iodide and DMF
2012
Neopentylphosphines as effective ligands in palladium-catalyzed cross-couplings of aryl bromides and chlorides
2008
Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C–H hydroxylation and amination
2016
Cobalt-Catalyzed C–H Cyanation of (Hetero)arenes and 6-Arylpurines withN-Cyanosuccinimide as a New Cyanating Agent
2015
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
Palladium-Catalyzed Arylation and Alkylation of 3,5-Diphenylisoxazole with Boronic Acids via C−H Activation
2008
Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds
2009 Standout
Oxidative Nickel–Air Catalysis in CH Arylation: Direct Cross‐Coupling of Azoles with Arylboronic Acids using Air as Sole Oxidant
2010
Efficient Rh(I)-Catalyzed Direct Arylation and Alkenylation of Arene C−H Bonds via Decarbonylation of Benzoic and Cinnamic Anhydrides
2009
Palladium-catalyzed Direct C–H Bond Arylation of Simple Arenes with Aryltrimethylsilanes
2011
Direct ortho‐Acylation of Azoxybenzenes with Aldehydes via Palladium‐Catalyzed Regioselective CH Bond Activation
2014
Iron-Catalyzed Cascade Carbochloromethylation of Activated Alkenes: Highly Efficient Access to Chloro-Containing Oxindoles
2014
Preparation of 3-Acyl-4-arylcoumarins via Metal-Free Tandem Oxidative Acylation/Cyclization between Alkynoates with Aldehydes
2014
Copper-Mediated C–H Activation/C–S Cross-Coupling of Heterocycles with Thiols
2011
Oxidative Palladium(II)‐Catalyzed Dehydrogenative CH/CH Cross‐Coupling of 2,3‐Substituted Indolines with Arenes at the C7 Position
2013
Nickel(II)‐Mediated Regioselective CH Monoiodination of Arenes and Heteroarenes by using Molecular Iodine
2016
Copper-Mediated C−H Bond Arylation of Arenes with Arylboronic Acids
2008
Advances in Synthetic Applications of Hypervalent Iodine Compounds
2016 Standout
Diversity Oriented Clicking (DOC): Divergent Synthesis of SuFExable Pharmacophores from 2‐Substituted‐Alkynyl‐1‐Sulfonyl Fluoride (SASF) Hubs
2020 StandoutNobel
Übergangsmetallkatalysierte direkte Arylierungen von (Hetero)Arenen durch C‐H‐Bindungsbruch
2009
Cobalt-Catalyzed Carbonylation of C(sp2)–H Bonds with Azodicarboxylate as the Carbonyl Source
2016
Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate
2009
Fluorosulfuryl Isocyanate Enabled SuFEx Ligation of Alcohols and Amines
2021 StandoutNobel
Disulfonimide-Catalyzed Asymmetric Synthesis of β3-Amino Esters Directly from N-Boc-Amino Sulfones
2013 StandoutNobel
Weak O‐Assistance Outcompeting Strong N,N‐Bidentate Directing Groups in Copper‐Catalyzed C−H Chalcogenation
2016
Nickel-catalyzed thiolation of unactivated aryl C–H bonds: efficient access to diverse aryl sulfides
2015
Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides
2016
Palladium-Catalyzed 1,2-Addition of Potassium Aryl- and Alkenyltrifluoroborates to Aldehydes using Thioether−Imidazolinium Carbene Ligands
2008
Directing Group‐Assisted Copper(II)‐Catalyzed ortho‐Carbonylation to Benzamide using 2,2′‐Azobisisobutyronitrile (AIBN)
2016
In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy
2020
A Novel Water‐Soluble m‐TPPTC Ligand: Steric and Electronic Features –Recent Developments in Pd‐ and Rh‐Catalyzed CC Bond Formations
2004
Distinct Reactivity of Pd(OTs)2: The Intermolecular Pd(II)-Catalyzed 1,2-Carboamination of Dienes
2008
Rhodium-catalyzed regioselective arylation of phenylazoles and related compounds with arylboron reagents via C–H bond cleavage
2008
Acetonitrile as a Cyanating Reagent: Cu-Catalyzed Cyanation of Arenes
2015
Direct Ortho-Acetoxylation of Anilides via Palladium-Catalyzed sp2 C−H Bond Oxidative Activation
2008
Copper-catalyzed aromatic C–H alkoxylation with alcohols under aerobic conditions
2017
Polymer-supported palladium perfluorooctanesulfonate [Pd(OPf)2]: A recyclable and ligand-free palladium catalyst for copper-free Sonogashira coupling reaction in water under aerobic conditions
2008
FeCl3-Catalyzed 1,2-Addition Reactions of Aryl Aldehydes with Arylboronic Acids
2008
Ruthenium-Catalyzed Oxidative C–H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones
2011
Sonogashira cross-coupling reactions with heteroaryl halides in the presence of a tetraphosphine–palladium catalyst
2005
Copper-catalyzed ortho-halogenation of arenes and heteroarenes directed by a removable auxiliary
2015
Copper-Mediated Remote C–H Bond Chalcogenation of Quinolines on the C5 Position
2015
Copper-mediated thiolation of carbazole derivatives and related N-heterocycle compounds
2015
Cu-mediated direct regioselective C-2 chlorination of indoles
2015
One-Pot Procedure for the Synthesis of Unsymmetrical Diarylalkynes
2010
Direct Arylation of Polycyclic Aromatic Hydrocarbons through Palladium Catalysis
2011
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 Carbon−Hydrogen Bonds
2010
Sonogashira Couplings of Aryl Bromides: Room Temperature, Water Only, No Copper
2008
Copper-Mediated Annulative Direct Coupling of o-Alkynylphenols with Oxadiazoles: A Dehydrogenative Cascade Construction of Biheteroaryls
2011
Copper‐Catalyzed Direct Sulfoximination of Heteroaromatic N‐Oxides by Dual C−H/N−H Dehydrogenative Cross‐Coupling
2015
Direct Synthesis of Quinolines via Co(III)-Catalyzed and DMSO-Involved C–H Activation/Cyclization of Anilines with Alkynes
2018
RuH2(CO)(PPh3)3-catalyzed arylation of aromatic esters using arylboronates via C–H bond cleavages
2010
Copper-Mediated Direct Alkoxylation of Arenes Using an N,O-Bidentate Directing System
2014
Copper-mediated C–H cyanation of (hetero)arenes with ethyl (ethoxymethylene)cyanoacetate as a cyanating agent
2017
Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents
2010
Synthesis and characterization of a polymer-anchored palladium(II) Schiff base complex and its catalytic efficiency in phosphine-free Sonogashira coupling reactions
2010
Iron-Catalyzed Direct Suzuki–Miyaura Reaction: Theoretical and Experimental Studies on the Mechanism and the Regioselectivity
2012
Copper‐Catalyzed Direct Arylselenation of Anilines by CH Bond Cleavage
2015
Nickel‐Catalyzed C−H Chalcogenation of Anilines
2016
Direct Regioselective Oxidative Cross-Coupling of Indoles with Methyl Ketones: A Novel Route to C3-Dicarbonylation of Indoles
2014
Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides
2010
Zinc Chloride-Promoted Aryl Bromide−Alkyne Cross-Coupling Reactions at Room Temperature
2009
Efficient Indirect Electrochemical Synthesis of 2‐Substituted Benzoxazoles using Sodium Iodide as Mediator
2013
Nickel-catalyzed direct thiolation of unactivated C(sp3)–H bonds with disulfides
2015
Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes
2015
Application of recoverable nanosized palladium(0) catalyst in Sonogashira reaction
2005
A [4 + 1] Cyclative Capture Access to Indolizines via Cobalt(III)-Catalyzed Csp2–H Bond Functionalization
2016
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
2009 Standout
A palladium-catalyzed one-pot procedure for the regioselective dimerization and cyanation of indoles
2012
Rhodium(iii)-catalyzed C7-position C–H alkenylation and alkynylation of indolines
2014
Pd(OAc)2/p‐Benzoquinone‐Catalyzed Anaerobic Electrooxidative Homocoupling of Arylboronic Acids, Arylboronates and Aryltrifluoroborates in DMF and/or Water
2008
Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update
2016
Palladium-Catalyzed Direct Arylation of Electron-Deficient Polyfluoroarenes with Arylboronic Acids
2009
Direct ortho‐Acyloxylation of Arenes and Alkenes by Cobalt Catalysis
2017
A Convenient High Activity Catalyst for the Sonogashira Coupling of Aryl Bromides
2005
Recent progress in copper-catalyzed electrophilic amination
2014
Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex
2010
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
Copper‐Mediated ortho‐Arylation of Benzamides with Arylboronic Acid
2016
Copper-catalyzed cross-dehydrogenative coupling of pyridine N-oxides with cyclic ethers
2015
Palladium(II) Chloride and a (Dipyridin‐2‐ylmethyl)amine‐Derived Palladium(II) Chloride Complex as Highly Efficient Catalysts for the Synthesis of Alkynes in Water or in NMP and of Diynes in the Absence of Reoxidant
2005
A General Copper/Manganese Cocatalyzed C‐H Selenation of Arenes, Heteroarenes, and Alkenes under Air
2017
Cyanation of indoles with benzyl cyanide as the cyanide anion surrogate
2013
Twofold C−H Functionalization: Palladium-Catalyzed Ortho Arylation of Anilides
2008
Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation
2016
Copper-catalyzed direct acyloxylation of C(sp2)-H bonds with Benzoic acids
2015
Cyclopalladated ferrocenylimines: efficient catalysts for homocoupling and Sonogashira reaction of terminal alkynes
2006
Palladium-Catalyzed Cross-Coupling of Electron-Poor Terminal Alkynes with Arylboronic Acids under Ligand-Free and Aerobic Conditions
2010
Synthesis, Characterization and Catalytic Application of Iron Complexes Modified by Monodentate Phosphane Ligands
2011
Ruthenium-catalyzed Acylation of Arylpyridines with Acyl Chlorides via ortho-Selective C–H Bond Cleavage
2011
Two Competing Mechanisms for the Copper-Free Sonogashira Cross-Coupling Reaction
2008
Terminal Aryl Alkenes and Alkynes as Arylcarboxy Surrogates towardo-Benzoxylation of 2-Phenylpyridine Catalyzed by Copper
2014
Recent Advances in Transition Metal‐Catalyzed Methylation Reactions
2015
Aerobic Pd-Catalyzed sp3 C−H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes
2011
Recent advances in copper-mediated chelation-assisted functionalization of unactivated C–H bonds
2016
Sodium Iodide‐Catalyzed Direct α‐Alkoxylation of Ketones with Alcohols via Oxidation of α‐Iodo Ketone Intermediates
2015
Cu(OAc)2 catalyzed Sonogashira cross-coupling reaction in amines
2007
Pd-Catalyzed Oxidative ortho-C–H Borylation of Arenes
2011
High-Yielding, Versatile, and Practical [Rh(III)Cp*]-Catalyzed Ortho Bromination and Iodination of Arenes
2012
Pd-Catalyzed Ortho-C−H Acylation/Cross Coupling of Aryl Ketone O-Methyl Oximes with Aldehydes Using tert-Butyl Hydroperoxide as Oxidant
2010
Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme
2017 StandoutNobel
Cobalt-Promoted Dimerization of Aminoquinoline Benzamides
2015
Indoles in Multicomponent Processes (MCPs)
2012

Works of Jiang Cheng being referenced

Copper-mediated C3-cyanation of indoles by the combination of amine and ammonium
2014
Suzuki–Miyaura Coupling Reaction by PdII‐Catalyzed Aromatic CH Bond Activation Directed by an N‐Alkyl Acetamino Group
2007
Palladium-catalyzed desulfitative C-arylation of a benzo[d]oxazole C–H bond with arene sulfonyl chlorides
2011
The use of calcium carbide in one-pot synthesis of symmetric diaryl ethynes
2006
Rhodium‐Catalyzed Cascade Reaction: Aryl Addition/Intramolecular Esterification to Access 3‐Aryl and 3‐Alkenyl Phthalides
2010
The Bu4NI-catalyzed alfa-acyloxylation of ketones with benzylic alcohols
2014
The palladium-catalyzed desulfitative cyanation of arenesulfonyl chlorides and sodium sulfinates
2011
The ammonium-promoted formylation of indoles by DMSO and H2O
2013
The palladium-catalyzed cyanation of indole C–H bonds with the combination of NH4HCO3 and DMSO as a safe cyanide source
2011
Copper-mediated methylthiolation of aryl halides with DMSO
2011
Copper-TBAF catalyzed arylation of amines and amides with aryl trimethoxysilane
2009
Copper(ii)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides
2011
TBHP-promoted sequential carboxamidation and aromatisation of aryl isonitriles with formamides
2014
The carbomethylation of arylacrylamides leading to 3-ethyl-3-substituted indolin-2-one by cascade radical addition/cyclization
2014
Palladium/NHC-catalyzed oxidative esterification of aldehydes with phenols
2011
Palladium-catalyzed Suzuki–Miyaura reaction using aminophosphine as ligand
2003
One-pot synthesis of diaryl ketones from aldehydes via palladium-catalyzed reaction with aryl boronic acids
2007
Silver-Mediated N-Trifluoromethylation of Sulfoximines
2015
Cesium hydroxide-promoted aerobic oxidation of sec-aromatic alcohols
2008
Radical–Polar Crossover Reactions: Oxidative Coupling of 1,3-Dioxolanes with Electron-Deficient Alkenes and Vinylarenes Based on a Radical Addition and Kornblum–DeLaMare Rearrangement
2014
Copper-catalyzed halogenation of arylboronic acids
2011
Palladium/NHC-catalyzed tandem benzylic oxidation/oxidative esterification of benzylic alcohols with phenols
2011
Base-Promoted Formal Arylation of Benzo[d]oxazoles with Acyl Chloride
2013
Suzuki–Miyaura Coupling Reaction by PdII‐Catalyzed Aromatic CH Bond Activation Directed by an N‐Alkyl Acetamino Group
2007
Copper-mediated intramolecular aza-Wacker-type cyclization of 2-alkenylanilines toward 3-aryl indoles
2016
Palladium-Catalyzed Acylation of sp2 C−H bond: Direct Access to Ketones from Aldehydes
2009
Rhodium-Catalyzed ortho-Benzoxylation of sp2 C−H Bond
2009
Chelation-assisted palladium-catalyzed acyloxylation of benzyl sp3 C–H bonds using PhI(OAc)2 as oxidant
2010
Rh-catalyzed sequential oxidative C–H activation/annulation with geminal-substituted vinyl acetates to access isoquinolines
2015
Palladium-Catalyzed Aromatic Esterification of Aldehydes with Organoboronic Acids and Molecular Oxygen
2008
Facile Synthesis of Pyrido[2,1-a]isoindoles via Iron-Mediated 2-Arylpyridine C-H Bond Cleavage
2013
Direct arylation of benzoxazole C–H bonds with iodobenzene diacetates
2012
Rhodium or palladium-catalyzed cascade aryl addition/intramolecular lactonization of phthalaldehydonitrile to access 3-aryl and 3-alkenyl phthalides
2011
Palladium-Catalyzed Arylcarboxylation of Propargylic Alcohols with CO2 and Aryl Halides: Access to Functionalized α-Alkylidene Cyclic Carbonates
2017
Cu(OTf)2-Mediated Chan-Lam Reaction of Carboxylic Acids to Access Phenolic Esters
2010
Copper-Catalyzed N-Cyanation of Sulfoximines by AIBN
2015
Copper-Catalyzed Cyanation of Arylboronic Acids Using DDQ as Cyanide Source
2012
Chelation-Assisted Palladium-Catalyzed Cascade Bromination/Cyanation Reaction of 2-Arylpyridine and 1-Arylpyrazole C−H Bonds
2009
Copper‐ and Silver‐Mediated Cyanation of Aryl Iodides Using DDQ as Cyanide Source
2013
The Copper‐Catalyzed C‐3‐Formylation of Indole CH Bonds using Tertiary Amines and Molecular Oxygen
2012
Ligand-free copper(Ι)-catalyzed Sonogashira-type coupling of arylboronic acids with terminal alkynes
2009
Rhodium‐Catalyzed Cascade Reaction: Aryl Addition/Intramolecular Esterification to Access 3‐Aryl and 3‐Alkenyl Phthalides
2010
Copper-catalyzed cyanation of disulfides by azobisisobutyronitrile leading to thiocyanates
2014
Palladium-Catalyzed Tandem Cyclization/Suzuki Coupling of 1,6-Enynes:  Reaction Scope and Mechanism
2005
Di-tert-butyl Peroxide-Promoted α-Alkylation of α-Amino Carbonyl Compounds by Simple Alkanes
2014
Rhodium-Catalyzed Annulation of Primary Benzylamine with α-Diazo Ketone toward Isoquinoline
2016
Palladium-Catalyzed Cyanation of Aryl Halides with CuSCN
2013
Radical N-cyanation of sulfoximine through acetonitrile CCN cleavage
2015
Copper-catalyzed oxidative C(sp3)–H/N–H coupling of sulfoximines and amides with simple alkanes via a radical process
2015
Rhodium-catalyzed hydroarylation of alkynes via tetrazole-directed C–H activation
2015
Di‐tert Butyl Peroxide‐Promoted Sequential Methylation and Intramolecular Aromatization of Isonitriles
2014
Copper-Mediated Cyanation of Aryl Halide with the Combined Cyanide Source
2011
Rhodium-Catalyzed Direct Annulation of Aldehydes with Alkynes Leading to Indenones: Proceeding through in Situ Directing Group Formation and Removal
2013
A Simple Access to Symmetric Diarylamines via Copper(II)-catalyzed Coupling of Aqueous Ammonia with Arylboronic Acids
2009
Copper(II)-catalyzed ortho-Benzoxylation of 2-Arylpyridines with Sodium Carboxylates
2012
Copper(I)‐Mediated Cyanation of Boronic Acids
2011
Iron-Catalyzed Cyclization of Nitrones with Geminal-Substituted Vinyl Acetates: A Direct [4 + 2] Assembly Strategy Leading to 2,4-Disubstituted Quinolines
2016
Chelation-Assisted Palladium-Catalyzed Direct Cyanation of 2-Arylpyridine C−H Bonds
2009
Copper(II)-Catalyzed Esterification of Arenecarboxylic Acids with Aryl- and Vinyl-Substituted Trimethoxysilanes
2010
Transition-Metal-Catalyzed Synthesis of Aromatic Ketones via Direct C-H Bond Activation
2012
A Facile Route for Constructing Effective Cu−Nx Active Sites for Oxygen Reduction Reaction
2019
Palladium-catalyzed cross-coupling reaction of aryl trimethoxysilanes with terminal alkynes
2008
Copper(I)‐Catalyzed Desulfinative Carboxylation of Sodium Sulfinates using Carbon Dioxide
2015
Iron-Mediated Cyanation of Methoxybenzene, Indole, and 2-Arylpyridine C-H Bonds
2011
The Palladium-Catalyzed Addition of Aryl- and Heteroarylboronic Acids to Aldehydes
2007
Carbon annulation of ortho-vinylanilines with dimethyl sulfoxide to access 4-aryl quinolines
2017
ChemInform Abstract: Copper(II)‐Catalyzed ortho‐Acyloxylation of the 2‐Arylpyridines sp2 C—H Bonds with Anhydrides, Using O2 as Terminal Oxidant.
2010
Suzuki–Miyaura Coupling Reaction by PdII‐Catalyzed Aromatic CH Bond Activation Directed by an N‐Alkyl Acetamino Group
2007
Copper(II)-Catalyzed Ortho-Acyloxylation of the 2-Arylpyridines sp2 C−H Bonds with Anhydrides, Using O2 as Terminal Oxidant
2010
Palladium-Catalyzed Cascade Aryl Addition/Intramolecular Lactonization of Phthalaldehyde To Access 3-Aryl- and Alkenylphthalides
2010
An efficient and solvent-free one-pot synthesis of dihydropyrimidinones under microwave irradiation
2007
TBAI-Catalyzed Reaction between N-Tosylhydrazones and Sulfur: A Procedure toward 1,2,3-Thiadiazole
2015
Iodine-catalyzed ammoxidation of methyl arenes
2015
A Copper- and Amine-Free Sonogashira Reaction Employing Aminophosphines as Ligands
2004
The Benzoyl Peroxide Promoted Dual C–C Bond Formation via Dual C–H Bond Cleavage: α-Phenanthridinylation of Ether by Isocyanide
2014
Palladium-catalyzed reduction of alkynes employing HSiEt3: stereoselective synthesis of trans- and cis-alkenes
2009
Copper-Catalyzed Thiolation of the Di- or Trimethoxybenzene Arene C−H Bond with Disulfides
2010
Multicomponent Coupling Reactions of Two N-Tosyl Hydrazones and Elemental Sulfur: Selective Denitrogenation Pathway toward Unsymmetric 2,5-Disubstituted 1,3,4-Thiadiazoles
2016
Rankless by CCL
2026