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Signaling Recognition Events with Fluorescent Sensors and Switches
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Organometallic “Carbon Chains”: They Just Keep Getting Longer!
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1997
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2003
The chemistry of the carbon–transition metal double and triple bond: annual survey covering the year 1998
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Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation
2007 Standout
Enantioselective Imidation of Sulfides via Enzyme-Catalyzed Intermolecular Nitrogen-Atom Transfer
2014 StandoutNobel
Asymmetric Hydrogenation of Heteroarenes and Arenes
2011
Methods for the Synthesis of μ‐Hydrocarbon Transition Metal Complexes without Metal–Metal Bonds
1993
Methods for attaching metal-capped sp carbon chains to metal clusters: synthesis, structure and reactivity of rhenium–triosmium carbon complexes [(η5-C5Me5)Re(NO)(PPh3)(C C)nOs3(CO)10H]
1997
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2003
Recent topics of transfer hydrogenation
2014
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2014
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2010
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2006
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1999
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2018
Transition Metal-Catalyzed Enantioselective Hydrogenation of Enamines and Imines
2010
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2003
Synthesis and Application of Chiral Phospholane Ligands Bearing a Sterically and Electrically Adjustable Moiety
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New Ruthenium Catalysts for Asymmetric Transfer Hydrogenation of Prochiral Ketones
2007
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2012 Standout
pH-Regulated transfer hydrogenation of quinoxalines with a Cp*Ir–diamine catalyst in aqueous media
2011
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
New Chiral Phosphorus Ligands for Enantioselective Hydrogenation
2003 Standout
Novel Carbon Compounds with “Naked” Cn Units
1994
A RuH2(CO)(PPh3)3-Catalyzed Regioselective Arylation of Aromatic Ketones with Arylboronates via Carbon−Hydrogen Bond Cleavage
2005
Chiral Ligand-Modified Metal Nanoparticles as Unique Catalysts for Asymmetric C–C Bond-Forming Reactions: How Are Active Species Generated?
2016
Molecular Rods. 1. Simple Axial Rods
1999 Standout
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
Chirale Erkennung in π‐Komplexen von Alkenen, Aldehyden und Ketonen mit Übergangsmetall‐Lewis‐Säuren; Entwicklung eines allgemeinen Modells für enantiofaciale Komplexierungsselektivitäten
1997
First C4bridged mixed-valence iron(II )–iron(III ) complex delocalized on the infrared timescale
1993
New families of coordinated carbon: oxidative coupling and cross-coupling of a transition metal butadiynyl complex to bimetallic M–CCCCCCCC–M and M–CCCCCC–M adducts
1994
Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands
2015
Large-Scale Candoxatril Asymmetric Hydrogenation
2001
Ru-TsDPEN with Formic Acid/Hünig’s Base for Asymmetric Transfer Hydrogenation, a Practical Synthesis of Optically Enriched N-Propyl Pantolactam
2008
Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
2016 Standout
Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates
2014 Standout
Catalytic Asymmetric Intramolecular [4+2] Cycloaddition of In Situ Generated ortho‐Quinone Methides
2017 StandoutNobel
Single-Site Cobalt Catalysts at New Zr8(μ2-O)8(μ2-OH)4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles
2016
Diversified facile synthesis of benzimidazoles, quinazolin-4(3H)-ones and 1,4-benzodiazepine-2,5-diones via palladium-catalyzed transfer hydrogenation/condensation cascade of nitro arenes under microwave irradiation
2015
Asymmetric Hydrosilylation of Ketones Catalyzed by Magnetically Recoverable and Reusable Copper Ferrite Nanoparticles
2009
A Li2Ti2‐Substituted Acetylene Formed from Ethylene by Reaction with (meso‐Octaethylporphyrinogen)titanium
1995
Photochromism of Diarylethene Molecules and Crystals: Memories, Switches, and Actuators
2014 Standout
Catalytic C−H/Olefin Coupling
2002
A Step‐Growth Approach to Metal‐Capped One‐Dimensional Carbon Allotropes: Syntheses of C12, C16, and C20 μ‐Polyynediyl Complexes
1996
An Outstanding Catalyst for Asymmetric Transfer Hydrogenation in Aqueous Solution and Formic Acid/Triethylamine.
2006
Formamides derived from N-methyl amino acids serve as new chiral organocatalysts in the enantioselective reduction of aromatic ketimines with trichlorosilane
2005
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
2009 Standout
Regioselective Alkenylation of Aromatic Ketones with Alkenylboronates Using a RuH2(CO)(PPh3)3 Catalyst via Carbon−Hydrogen Bond Cleavage
2007
Synthesis of Chiral Hydroxyl Phospholanes from d -mannitol and Their Use in Asymmetric Catalytic Reactions
2000
Practical Aspects and Mechanism of Asymmetric Hydrogenation with Chiral Half-Sandwich Complexes
2013
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
Reactions of TpRu(CO)(NCMe)(Me) (Tp = Hydridotris(pyrazolyl)borate) with Heteroaromatic Substrates: Stoichiometric and Catalytic C−H Activation
2004
Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination
2014 StandoutNobel
Asymmetric Carbon–Carbon Bond Formation under Solventless Conditions in Ball Mills
2015
Works of James A. Ramsden being referenced
An Enantioselective Synthesis of (S)-(+)-3-Aminomethyl-5-methylhexanoic Acid via Asymmetric Hydrogenation
2003
An Efficient Catalytic Asymmetric Route to 1-Aryl-2-imidazol-1-yl-ethanols
2004
Asymmetric enamide hydrogenation in the synthesis of N-acetylcolchinol: a key intermediate for ZD6126
2007
Synthesis, Structure, and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC2M', MC4M', and MC4M'C4M Linkages. Transmetalations of Lithiocarbon Complexes (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CLi) and (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CC.tplbond.CLi)
1995
The synthesis of S 18986, a chiral AMPA receptor modulator, via catalytic asymmetric hydrogenation
2003
Synthesis, structure, and reactivity of (pentamethylcyclopentadienyl)rhenium aldehyde complexes [(.eta.5-C5Me5)Re(NO)(PPh3)(.eta.2-O:CHR)]+ BF4-: highly diastereoselective deuteride additions
1992
A versatile new route to carbon complexes of the formula LnMC.tplbond.CM'L'n': deprotonation and metalation of the terminal acetylide complex (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CH)
1992
Ether-tethered Ru(ii)/TsDPEN complexes; synthesis and applications to asymmetric transfer hydrogenation
2011
New Forms of Coordinated Carbon: Wirelike Cumulenic C3 and C5 sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer
1998
Deprotonation of rhenium terminal acetylide complexes (.eta.5-C5R5)Re(NO)(PPh3)(C.tplbond.CH): generation and reactivity of rhenium/lithium C2 complexes
1992
Industrial-Scale Synthesis and Applications of Asymmetric Hydrogenation Catalysts
2007
On the economic application of DuPHOS rhodium(I) catalysts: a comparison of COD versus NBD precatalysts
2001
Asymmetric transfer hydrogenation of quinolines using tethered Ru(II) catalysts
2010
Me-DuPHOS-Rh-Catalyzed Asymmetric Synthesis of the Pivotal Glutarate Intermediate for Candoxatril
1999
A new form of coordinated carbon: an unsupported linear C3 chain spanning two different transition metals
1993
Efficient Synthesis of an Imidazole-Substituted δ-Amino Acid by the Integration of Chiral Technologies
2005
The Large-Scale Synthesis of (S)-N-Boc-bis(4-fluorophenyl)alanine
2012