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Catalytic Asymmetric Torgov Cyclization: A Concise Total Synthesis of (+)‐Estrone
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Chemistry and biochemistry of 4-hydroxynonenal, malonaldehyde and related aldehydes
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An efficient cyclopentenone formation via an allene oxide
1988
Catalytic kinetic resolution of 5-alkoxy-2(5H)-furanones
1994 StandoutNobel
π-Allylpalladium-Mediated Catalytic Synthesis of Functionalized Allenes
2000
The two component palladium catalyst system for intermolecular hydroamination of allenes
1997
Development, Mechanism, and Scope of the Palladium-Catalyzed Enantioselective Allene Diboration
2007
Synthesis of allenes by 1,6‐addition of organocuprates to polarized enynes
1990
Metal-Catalyzed Intermolecular Hydrofunctionalization of Allenes: Easy Access to Allylic Structures via the Selective Formation of C–N, C–C, and C–O Bonds
2020
2-Substituted-3-allenyl-benzo[b]furans through the palladium-catalysed cyclization of propargylic o-(alkynyl)phenyl ethers
1998
Palladium-catalyzed coupling of aryl iodides with 2-alkynylbenzonitriles
2000
Hydroamination of Alkynes Catalyzed by Palladium/Benzoic Acid
2002
Metal-Initiated Amination of Alkenes and Alkynes
1998 Standout
Cyclizations via Palladium‐Catalyzed Allylic Alkylations [New Synthetic Methods (79)]
1989
Stereocontrolled cyclofunctionalizations of double bonds through heterocyclic intermediates
1990
Rhenium-Catalyzed Insertion of Terminal Acetylenes into a C−H Bond of Active Methylene Compounds
2005
Ring Expansion via Olefin Metathesis
2002 StandoutNobel
Intramolecular Heck-type reactions in aqueous medium. Dramatic change in regioselectivity
1996
Enantioselective Synthesis of an Allenyl Derivative of Pipecolic Acid
1998
Palladium-catalyzed Inter- and Intramolecular Hydroamination of Methylenecyclopropanes with Amines
2001
General synthetic access to α-allenyl amines and α-allenyl-α-aminoacids as potential enzyme activated irreversible inhibitors of PLP dependent enzymes
1984
Ring Opening in the Hydroamination of Methylenecyclopropanes Catalyzed by Palladium
1998
Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
2008 Standout
Quecksilber(II)- und Palladium(II)-katalysierte [3.3]-sigmatrope Umlagerungen
1984
Modular N,O‐Chelating Ligands: Group‐4 Amidate Complexes for Catalytic Hydroamination
2007
Palladium-catalysed coupling of aryl and vinyl triflates or halides with 2-ethynylaniline: An efficient route to functionalized 2-substituted indoles
1989
Fine Feathers Make Fine Birds: The Heck Reaction in Modern Garb
1995
The palladium-catalysed synthesis of 2,3,5-trisubstituted furans from 2-propargyl-1,3-dicarbonyl compounds and vinylic or aryl triflates or halides.
1993
Synthesis of furans by cyclization of 2-En-4-yn-1-ols in the presence of ruthenium and palladium catalysts
1995
A new method for the synthesis of nitrogen heterocycles via palladium catalyzed intramolecular hydroamination of allenes
1998
An Efficient Synthesis of Polysubstituted Naphthalene Derivatives by Gold‐Catalyzed Cyclization of 1‐Arylalka‐2,3‐dienyl Acetates
2010
Intermolecular Additions and Cycloisomerizations by a Pd‐Catalyzed Sequence of an Intramolecular Redox Reaction and an Addition
1992
Enantioselective Catalytic Transannular Ketone–Ene Reactions
2013
One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate)
2002 StandoutNobel
Studies on total syntheses of antitumor styryllactones: Stereoselective total syntheses of (+)-goniofufurone, (+)-goniobutenolide A, and (−)-goniobutenolide B
1996
Synthese und Eigenschaften allenischer Natur‐ und Wirkstoffe
2004
π-Allylpalladium-Mediated Catalytic Synthesis of Functionalized Allenes
2000
Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination
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Ring closing metathesis for the formation of medium ring ethers: the total synthesis of (−)-isolaurallene
2002
Extremely Active Organocatalysts Enable a Highly Enantioselective Addition of Allyltrimethylsilane to Aldehydes
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Bis(amidate) titanium precatalyst for the intermolecular hydroamination of allenes
2006
Highly Stereo- and Regioselective Synthesis of (Z)-Trisubstituted Alkenes via 1-Bromo-1-alkyne Hydroboration−Migratory Insertion−Zn-Promoted Iodinolysis and Pd-Catalyzed Organozinc Cross-Coupling
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Heterocycles via cyclization of alkynes promoted by organopalladium complexes
1999
Iron‐Catalyzed Cross‐Coupling Reactions: Efficient Synthesis of 2,3‐Allenol Derivatives
2003
Catalytic, Asymmetric Transannular Aldolizations: Total Synthesis of (+)-Hirsutene
2008 StandoutNobel
Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones
2001 StandoutNobel
Allenes as Carbon Nucleophiles in Palladium-Catalyzed Reactions: Observation of Anti Attack of Allenes on (π-Allyl)palladium Complexes
2002
A Ruthenium-Catalyzed Two-Component Addition To Form 1,3-Dienes
1999
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
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The Atom Economy—A Search for Synthetic Efficiency
1991 StandoutScience
Synthesis of Enantiopure Estrone via a Double Heck Reaction
1998
Silver Mediated Cyclizations of 4-Allenyl-and 4-(2-Propynyl)azetidinones. A Stereoselective Synthesis of 3-Substituted Δ1-Carbapenems Via N-C3 Closure.
1988
Generation and Trapping of Cyclopentenylidene Gold Species: Four Pathways to Polycyclic Compounds
2009
Palladium catalysed pronucleophile addition to unactivated carbon–carbon multiple bonds
1999
Palladium-Catalyzed Reactions of Allenes
2000
Synthesis of optically active forms of methyl (E)-2,4,5-tetradecatrienoate, the pheromone of the male dried bean beetle
1981
Homogeneous Catalysis in Supercritical Fluids
1999 StandoutNobel
On the Mechanism of Pd0-Initiated Coupling−Cyclization of γ-Aminoalkynes
2000
A Stereoselective Carbocyclization of Bis(allenes) with Germylstannane Catalyzed by Palladium Complexes
2004
Catalytic Intramolecular Hydroamination of Substituted Aminoallenes by Chiral Titanium Amino-Alcohol Complexes
2004
Synthesis of functionalized THF and THP through Au-catalyzed cyclization of acetylenic alcohols
2006
Synthesis of 2,5-Disubstituted Furans via Palladium-Catalyzed Annulation of Alkyl 3-Oxo-6-heptynoates
1997
Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral (Allenylmethyl)silanes and Chirality Transfer to Stereogenic Carbon Centers in SE‘ Reactions
2002
Group VI metal-promoted endo-carbocyclizations via alkyne-derived metal vinylidene carbenes
1997
Anion-Accelerated Palladium-Catalyzed Intramolecular Coupling of Phenols with Aryl Halides
1997
Palladium catalyzed hydroamination of conjugated enynes
1998
The conversion of vinyl triflates into γ'-hydroxy-α,β-enones
1993
Asymmetric Transfer Hydrogenation of α, β-Acetylenic Ketones
1997 StandoutNobel
Catalytic Enantioselective Conia-Ene Reaction
2005
Highly Active Au(I) Catalyst for the Intramolecularexo-Hydrofunctionalization of Allenes with Carbon, Nitrogen, and Oxygen Nucleophiles
2006
Studies on K2CO3-Catalyzed 1,4-Addition of 1,2-Allenic Ketones with Diethyl Malonate: Controlled Selective Synthesis of β,γ-Unsaturated Enones and α-Pyrones
2003
Alternative Synthetic Methods through New Developments in Catalysis by Gold
2008 Standout
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
Palladium-Catalyzed Cyclization of o-Alkynyltrifluoroacetanilides with Allyl Esters. A Regioselective Synthesis of 3-Allylindoles
1998
Amplification of chirality by transition metal coordination: synthesis of chiral allenes and allene manganese complexes of high enantiomeric purity. Synthesis of methyl ( R , E )-(−)-(2,4,5-tetradecatrienoate (pheromone of Acanthoscelides obtectus (say))
1998
A Highly Enantioselective Catalyst for the Asymmetric Nozaki–Hiyama–Kishi Reaction of Allylic and Vinylic Halides
2003
A Highly Reactive Titanium Precatalyst for Intramolecular Hydroamination Reactions
2002
Efficient synthesis of 4-(2′-alkenyl)-2,5-dihydrofurans via PdCl2-catalyzed coupling–cyclization reaction of 2,3-allenols with allylic halides
2000
Concise total synthesis of (+)-goniofufurone and goniobutenolides A and B
1996
Confined Acid-Catalyzed Asymmetric Carbonyl–Ene Cyclization
2015 StandoutNobel
Efficient Synthesis of 4-(2‘-Alkenyl)-2,5-dihydrofurans and 5,6-Dihydro-2H-pyrans via the Pd-Catalyzed Cyclizative Coupling Reaction of 2,3- or 3,4-Allenols with Allylic Halides
2002
Intramolecular Hydroamination/Cyclization of Aminoallenes Catalyzed by Organolanthanide Complexes. Scope and Mechanistic Aspects
1999
Use of Group 4 Bis(sulfonamido) Complexes in the Intramolecular Hydroamination of Alkynes and Allenes
2003
Intramolecular carbocupration reaction of unactivated alkynes bearing a stabilized nucleophile: Application to the synthesis of iridoid monoterpenes
1999
Catalysis of the Claisen Rearrangement of Aliphatic Allyl Vinyl Ethers
2002
Chiral Allenes via Alkynylogous Mukaiyama Aldol Reaction
2016 StandoutNobel
Palladium catalyzed cyclization reactions of acetylenic lactams
2001
An efficient synthesis of (±)-pinidine
1985
Palladium-Catalyzed Cyclization of Silyl-Substituted Bis(homo)propargylic Alcohols to 2,3-Dihydrofurans
1998
Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes
2011 Standout
Enantioselective Synthesis of α-Tertiary Hydroxyaldehydes by Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates
2006
Synthesis of variously substituted allenediynes and their cobalt (I)-mediated [2+2+2] cycloaddition reactions
1998
Expanding the Substrate Tolerance of Biotin Ligase through Exploration of Enzymes from Diverse Species
2008
The Thermal Cyclisation of Unsaturated Carbonyl Compounds
1975
Palladium-Catalyzed Addition of Nitrogen Pronucleophiles to Alkylidenecyclopropanes
2005
Allylic Amination
1998
Carbocyclization Reaction of Active Methine Compounds with Unactivated Alkenyl or Alkynyl Groups Mediated by TiCl4−Et3N
1998
Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes
2004 Standout
Recent developments in general methodologies for the synthesis of linear triquinanest
1998
HIF-1 regulates CD47 expression in breast cancer cells to promote evasion of phagocytosis and maintenance of cancer stem cells
2015 StandoutNobel
The Allylic Azide Rearrangement: Achieving Selectivity
2005 StandoutNobel
Palladium-catalyzed synthesis of stereodefined 3-[(1,1-unsymmetrically disubstituted)methylidene]isobenzofuran-1(3H)-ones and stereodefined 5-[(1,1-unsymmetrically disubstituted)methylidene]furan-2(5H)-ones
2000
Nitrated Confined Imidodiphosphates Enable a Catalytic Asymmetric Oxa-Pictet–Spengler Reaction
2016 StandoutNobel
A Suite of Novel Allenes from Australian Melolonthine Scarab Beetles. Structure, Synthesis, and Stereochemistry
2002
Silver(I) catalyzed amino cyclization of O-(2,3-butadienyl) carbamates: an efficient and stereoselective synthesis of 4-vinyl-2-oxazolidinones
1991
Silver-Catalyzed Cyclization of Acetylenic Alcohols: Synthesis of Functionalized 2-Methylene-oxolanes
2000
Palladium-Catalyzed Heteroannulation Leading to Heterocyclic Structures with Two Heteroatoms: A Highly Convenient and Facile Method for a Totally Regio- and Stereoselective Synthesis of (Z)-2,3-Dihydro-2-(ylidene)-1,4-benzo- and -naphtho[2,3-b]dioxins
1998
Studies on the transition metal-catalyzed synthesis of variously substituted (E)-3-[1-(aryl)methylidene]- and (E)-3-(1-alkylidene)-3H-furan-2-ones
1998
2-Substituted-3-acylindoles through the Palladium-Catalysed Carbonylative Cyclization of 2-Alkynyltrifluoroacetanilides with Aryl Halides and Vinyl Triflates
1994
Powerful control by organoruthenium catalysts of the regioselective addition to C(1) or C(2) of the prop-2-ynyl ethers CC triple bond
1998
β-Phosphorylated cyclic nitroxides. 2. Synthesis of pyrrolidin- and piperidin-2-yl phosphonates and the corresponding stable nitroxides.
1991
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
2000 Standout
Gold-catalyzed intramolecular hydroamination of allenes: a case of chirality transfer
2006
Palladium-Catalyzed Hydrocarboxylation of Allenes
1998
Palladium-Catalyzed Reaction of o-Ethynylphenols, o-((Trimethylsilyl)ethynyl)phenyl Acetates, and o-Alkynylphenols with Unsaturated Triflates or Halides: A Route to 2-Substituted-, 2,3-Disubstituted-, and 2-Substituted-3-acylbenzo[b]furans
1996
Lipase-Catalyzed Second-Order Asymmetric Transformations as Resolution and Synthesis Strategies for Chiral 5-(Acyloxy)-2(5H)-furanone and Pyrrolinone Synthons
1996 StandoutNobel
Vinylallenes—VI
1977
Clean Inversion of Configuration in the Pd-Catalyzed Cross-Coupling of 2-Bromo-1,3-dienes
2003 StandoutNobel
The syntheses of large-ring compounds
1995
Mercury(II )‐ and Palladium(II )‐Catalyzed [3,3]‐Sigmatropic Rearrangements [New Synthetic Methods (46)]
1984
Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds
1996 StandoutNobel
New and Selective Transition Metal Catalyzed Reactions of Allenes
2000
Studies on structurally simple α,β-butenolides—I
1982
Obtention de δ-methylene δ-lactones et de δ-lactones γ-ethyleniques
1984
Silver-catalyzed cyclization of acetylenic alcohols and acids: a remarkable accelerating effect of a propargylic C–O bond
1999
Regio- and stereoselective synthesis of γ-alkylidenebutenolides and related compounds
1997 StandoutNobel
Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes
1996 StandoutNobel
Recent advances in the preparation and synthetic applications of oxiranes
1983
Stereoselective Palladium-Catalyzed Carbocyclization of Allenic Allylic Carboxylates
2003
Palladium-catalysed reactions of alcohols. Part C: Formation of ether linkages
2005
Catalytic, Efficient, and syn-Selective Construction of Deoxypolypropionates and Other Chiral Compounds via Zr-Catalyzed Asymmetric Carboalumination of Allyl Alcohol
2006 StandoutNobel
Titanium complexes with chiral amino alcohol ligands: synthesis and structure of complexes related to hydroamination catalysts
2004
Silver and Gold Catalysis for Cycloisomerization Reactions
2009
W(CO)5(L)-catalyzed 6-endo-selective cyclization and formal Cope rearrangement of allenyl silyl enol ethers
2006
Works of J. GORÉ being referenced
Protodesilylation of α-Silyl-Allenes. Highly Stereoselective Synthesis of Conjugated Dienes
1982
Sensitization by docosahexaenoic acid (DHA) of breast cancer cells to anthracyclines through loss of glutathione peroxidase (GPx1) response
2008
Voltage-gated Sodium Channel Activity Promotes Cysteine Cathepsin-dependent Invasiveness and Colony Growth of Human Cancer Cells
2009
NaV1.5 sodium channels allosterically regulate the NHE-1 exchanger and promote breast cancer cell invadopodial activity
2013
Attaque nucleophile du carbone central de l'enchainement cumule lors de la cyclisation de diols ω,ω′-alleniques
1986
Rearrangement of α-hydroxy imines to α-amino ketones: Mechanistic aspects and synthetic applications
1996
Réaction de l'oxygène singulet avec quelques vinylallènes
1979
Palladium-mediated intramolecular cyclization of substituted pentynoic acids. A new route to γ-arylidenebutyrolactones
1996
A general solution to the synthesis of triquinanes by a palladium catalyzed process
1994
Copper-Promoted Cyclisation of α-Sulfonyl ε-Acetylenic Esters: A Route to Allylic Cyclopentanic Sulfones
1992
Palladium-catalyzed synthesis of dienic α-amino acids from allenes
1989
Thermal rearrangement of enantioenriched α-hydroxy imines -I. Enantiocontrolled synthesis of α-substituted α-amino ketones
1995
Carbopalladation-sulphonylation of allene: A versatile preparation of 2-vinyl or 2-aryl allyl sulphones
1996
Chiral recognition of allenic hydrocarbons by 1H NMR
1986
Obtention de cyclopentenones par acetoxymercuration et acetoxythallation de vinylallenes
1980
Spectres de masse de composes alleniques—I
1979
Palladium-Catalyzed Synthesis of γ-Allenic α-Amino Acids
1988
Enantioselective Synthesis of Homoallylic Alcohols
1983
Transposition d'oxy-cope a temperature ambiante catalysee par le dichlorure de palladium-bisbenzonitrile.
1983
Synthese d'amino-alcools alleniques.
1982
Thermolyse et photolyse des cetones non saturees
1971
Palladium(II)-catalyzed formation of γ-butyrolactones from 4-trimethylsilyl-3-alkyn-1-ols: Synthetic and mechanistic aspects
1996
Easy access to 5-(E)-alkynylidene tetrahydro-2 furanones by a palladium catalyzed process
1992
Palladium Carbenoids from Enolates of α-Sulfonyl ε-Acetylenic Esters, Nitriles or Ketones : Evidence for the Existence of these Intermediates.
1994
Synthese de (e)-arylidene et allylidene cyclopentanes par une annelation catalysee par un complexe de palladium(0)
1991
Carbopalladation of functionalized allenes : regioselectivity of the reaction of carbonucleophiles with the intermediate π-allyl palladium complexes.
1991
New Synthesis of a Pheromone with a Vinyl Allenic Linkage
1974
Synthesis of silylated 1,3-dienes via the carbopalladation of allenes.
1988
Biotin uptake by isolated rat intestinal cells
1986
Synthesis of allylic amines through the palladium-catalyzed hydroamination of allenes
1995
Carbopalladation des alkylidenecyclopropanes-I capture intermoleculaire de l'organopalladique intermediaire
1988
Palladium-catalysed alkylative cyclisation of 2,3-butadienylmalonates to γ-lactones
1994
A New Synthesis of γ-ButyrolactonesviaPalladium(II)-Catalyzed Cyclization of Trimethylsilylalkynes
1994
From Vinylallenes to Ketones of the Dihydrojasmone Type
1976
Reaction des hexadiene-1,5 ols-3 avec le trifluoroacetate mercurique ; transposition d'oxy-cope a temperature ambiante.
1982
Stereoselectivity of the carbopalladation-functionalization of allenic compounds: A mechanistic study
1998
Heterocyclisation de diols βγ′-alleniques.
1982
Carbopalladation of allenic hydrocarbons.
1987
Palladium(II)-mediated oxidative cyclization of N-carbamoyl aminoalkynes: a new route to γ-lactams
1999
Regio et stereochimie de la reduction de derives d'alcools propargyliques catalysee par un complexe de palladium (O)
1984
Formation de cyclopentanes a partir de malonates δ-ethyleniques par un processus catalytique en palladium(O) stereochimie et mecanisme
1992
Palladium-catalyzed addition of malonate type compounds to allenes via a hydropalladation process
1995
Malondialdehyde production from spermine by homogenates of normal and transformed cells
1987
Photoepoxidation of vinylallenes
1979
A New Route to γ-Arylidenebutyrolactones via a tandem carbopalladation-heterocyclisation sequence: a formal synthesis of U-68,215
1996
Préparation d'allènes α-triméthysilylés
1980
Vinyl trifluorosulfonates in the carbopalladation of allenic hydrocarbons
1988
Organopalladiques issus des esters d'alcools α-alleniques : reactions avec les anions delocalises
1987
Palladium-mediated cyclopentanation of alkenes bearing a nucleophilic substituent. Stereochemistry and mechanism.
1991
Carbopalladation of β-allenylmalonates : a way to cyclopentenyl or vinylcyclopropyl derivatives.
1985
Palladium-catalyzed hydrostannation of alkoxyallenes. A new access to functionalized allylstannanes.
1991
Cyclisation of ω-unsaturated β-dicarbonylcompounds catalyzed by a palladium hydride species
1991
Preparation d'α-alcenyl-2 tetrahydropyrannes par cyclisation d'alcohols δ-alleniques.
1982
Carbopalladation des alkylidenecyclopropanes-II capture intramoleculaire de l'organopalladique intermediaire
1988
Formation de derives cyclopentaniques assistee par une espece hydrure de palladium : Aspects synthetiques et mecanisme
1992
Synthése d'alcools α-alléniques par réaction d'organochromiques propargyliques sur les aldéhydes et les cétones
1981
Acétoxymercuration des vinylallènes
1976
New palladium mediated cyclopentanation of alkenes bearing a δ nucleophilic substituent
1989
Formation de derives cyclopenteniques et vinylcyclopropaniques lors de la carbopalladation de diesters et d' α-sulfonylesters alleniques
1987
Carbopalladation des alkylidenecyclopropanes. obtention de dienes-1,3 et de styrenes fonctionnalises.
1986
Attaque nucleophile intramoleculaire d'organopalladiques issus de la carbopalladation d'alkylidenecyclopropanes.
1987
New Preparation of Bromoallenes
1980
Preparation et epoxydation de trienes-1,2,4 ynes-6 (allenenynes)
1977
Formation de cyclopentanes lors de réactions de Heck
1990
Reactive D'esters α-Alleniques. Synthese regiospecifique de diesters γ-alleniques et de dienes−1,3.
1984
Cyclisation d'amines γ et δ-alleniques. Synthese d'alcenyl-2 pyrrolidines et d'alcenyl-2 piperidines.
1983
Stereospecific synthesis of arylidene and allylidene cyclopentanes by a palladium-catalyzed cylisation
1990
Total synthesis of (+)-goniodiol
1996
Synthesis of ethynylidene cyclopentanes by a cyclisation catalyzed by the simultaneous presence of palladium (0) and copper (I)
1991
Synthese de Δ-2 butenolides a partir du furfural.
1981
Palladium-catalyzed synthesis of new unsaturated exo-enol lactones with potential biological activity.
1993
Use of the carbopalladation of 1,2-propadiene in a two step synthesis of steroids
1991
Transposition oxy-cope assistee par le trifluoroacetate mercurique en quantite stoechiometrique et en quantite catalytique
1984
Synthese de dienes-1,3 et de styrenes fonctionnalises par carbopalladation catalytique d'allenes
1984