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1997 StandoutNobel
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1997 StandoutNobel
Specific Covalent Labeling of Recombinant Protein Molecules Inside Live Cells
1998 StandoutScienceNobel
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1991
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2002 Standout
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2001
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2006
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Synthesis and Structure of the First Stable Iminoarsane
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1989
The fluorine effect on the stability of phosphaalkenes, phosphasilenes, oxophosphane, thioxophosphane and their rearranged isomers
1997
Tellurium
1980
Niederkoordinierte Phosphorverbindungen, 56 Valenzisomerisierung eines 3,4‐Diphospha‐1,5‐hexadiins zu einem 3,4‐Bis(phosphamethylen)‐1‐cyclobuten
1987
Hochtemperaturhydrolyse von PCl3 und PBr3: IR‐spektroskopischer Nachweis der matrixisolierten Moleküle OPCl und OPBr
1987
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Works of Ingo Ruppert being referenced
Diorganylchalkogen(S,Se,Te)‐difluoride durch Direktfluorierung der Sulfide, Selenide und Telluride
1979
Synthesis and properties of (trifluoromethyl)trichlorosilane, a versatile precursor for CF3Si compounds
1986
The First 1,3,4,6‐Tetraphospha‐1,5‐hexadiene, a Molecule with Fluxinonal Bonds (Identical Tetraphospha Cope Rearrangement) and Configurational Isomerism
1979
Nucleophilic trifluoromethylation with the reagent combination (Et2N)3P/CF3Br
1985
Schwefeltrioxid‐Einschiebung an silylierten Iminophosphoranen1)
1976
Alkylenbis(difluorphosphorane) durch Hydrofluorierung silylierter Phosphor(V)‐imide
1975
Über die Darstellung neuer Fluorphosphazophosphonium‐Salze
1975
Vinyldifluorphosphorane: Synthese durch Direktfluorierung und Additionsverhalten [1]. / Vinyldifluorophosphoranes: Synthesis by Direct Fluorination and Addition Behaviour [1].
1979
Configurational Identity (Solid, Liquid), (N → P)‐Silatropism and Rotamer Detection in the Methylenephosphane PhPC(NArylSiMe3)(PPhSiMe3)
1982
Über die Umsetzung N‐trimethylsilylierter Sulfodiimide und Iminophosphorane mit Phosphor(V)‐fluoriden
1972
Konfigurationsidentität (fest, gelöst), (N→P)-Silatropie und Rotameren-Nachweis am Beispiel des Methylenphosphans PhPC(NArylSiMe3)(PPhSiMe3)
2006
CFCl2-substituierte Silane aus Chlorsilanen
1987
Die ersten CF3-substituierten organyl(chlor)silane
1984
Phospha‐alkene und Phospha‐alkine, Genese und Charakteristika ihrer (p‐p)π‐Mehrfachbindung
1981
CF3-P(NEt2)2 als schlüsselsubstanz für CF3-substituierte phosphane - direktsynthese und verwendung
1983
Das erste 1, 3, 4, 6‐Tetraphospha‐1, 5‐hexadien, ein Molekül mit fluktuierenden Bindungen (identische Tetraphospha‐Cope‐Umlagerung) und Konfigurationsisomerie
1979
Darstellung und Reaktionsverhalten monosilylierter Organylschwefeldiimide
1975
Arylioddifluoride durch direktfluorierung von iodaromaten
1980
Über die Cycloaddition von Sulfonylisocyanaten an Tetraschwefeltetranitrid
1975
Ein neues Verfahren zur Darstellung von N‐Cyaniminophosphoranen
1978
Darstellung silylierter Alkylen‐bisiminophosphorane und ihre Cyclisierung mit Phosphor(V)‐fluoriden
1974
Phospha‐alkenes and Phospha‐alkynes, Genesis and Properties of the (p‐p)π‐Multiple Bond
1981