Standout Papers
- Synthesis, characterization, and molecular structures of binary and ternary copper(I) complexes with 1,5-cyclooctadiene (cod): [Cu(cod)2]ClO4 and [cu(cod)(2,2'-bipyridine)]PF6 (1991)
- Structure and1H n.m.r. spectrum of a binuclear copper(
I ) complex with non-bridging and bridging 2-vinylpyridine ligands (vpy), [Cu2(µ-vpy)2(vpy)2](ClO4)2 (1987) - Structural studies of copper(I) complexes with ethylene. Crystal structures of [Cu(2,2′-bipyridine)(ethylene)]ClO4 and [Cu(1,10-phenanthroline)(ethylene)]ClO4 (1987)
- Structure of bis(2,6-dimethylpyridine)copper(I) perchlorate. The relationship between the CuN(pyridine) distance and Cu···CH3(methyl group) contacts (1989)
- Synthesis, properties and crystal structures of dicopper(I) and disilver(I) complexes with 1,8-naphthyridine (napy): [Cu2(napy)2](ClO4)2 and [Ag2(napy)2](ClO4)2 (1990)
- Synthesis and crystal structure of hexanuclear copper(
I ) complexes of µ3-pyridine-2-thionate (1990) - Synthesis and structures of (2,9-dimethyl-1,10-phenanthroline)(acetonitrile)copper(I) perchlorate and hexafluorophosphate. A correlation between bond angles and bond distances in T- and Y-shaped three-coordinate copper(I) complexes (1989)
- Crystal Structure of Bis(2,2′-bipyridine)copper(I) Perchlorate (1987)
- Raman spectra of copper(I) and silver(I) complexes with 1,5-cyclooctadiene and the nature of metal-olefin bonds. Possibility of a copper(I)-olefin bond in cytochrome oxidase (1990)
- Crystal structure of an infinite stair-type chain compound [{Cu2(tc)2(ClO4)2} n ](tc = thiochrome) (1991)
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Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes
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The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals
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Gas in a straitjacket
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2003 StandoutNobel
Three-Dimensional Structure of a Purple Lipoxygenase
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Einander durchdringende Netze: geordnete, periodische Verschlingung
1998 StandoutNobel
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Biomimetic nonheme iron catalysts for alkane hydroxylation
2000
Dye-Sensitized Solar Cells
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Models for Nonheme Diiron Enzymes. Assembly of a High-Valent Fe2(μ-O)2 Diamond Core from Its Peroxo Precursor
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1998
Dioxygen Activation by Enzymes Containing Binuclear Non-Heme Iron Clusters
1996
Porous Siloxane Linked Phenylacetylene Nitrile Silver Salts from Solid State Dimerization and Low Polymerization
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Histidine-Controlled Two-Dimensional Assembly of Zinc Phosphite Four-Ring Units
2006
Assembly of a Porous Three-Dimensional Coordination Polymer: Crystal Structure of {[La2(adipate)3(H2O)4]6H2O}n
1998
Carboxylate-Bridged Diiron(II) Complexes: Synthesis, Characterization, and O2-Reactivity of Models for the Reduced Diiron Centers in Methane Monooxygenase and Ribonucleotide Reductase
1997
Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid
1996 StandoutNobel
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2000 Science
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1999
[Cobalt(ii)l-glutamate(H2O)·H2O]∞: a new 3D chiral metal–organic interlocking network with channels
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Crystal Structure Analysis of a Synthetic Non‐Heme DiironO2 Adduct: Insight into the Mechanism of Oxygen Activation
1996
Chiroptical Molecular Switches
2000 StandoutNobel
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2003
Functional Micropore Chemistry of Crystalline Metal Complex-Assembled Compounds
1998 StandoutNobel
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1996
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2003
Synthetic Models for the Cysteinate-Ligated Non-Heme Iron Enzyme Superoxide Reductase: Observation and Structural Characterization by XAS of an FeIII−OOH Intermediate
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Synthesis, Characterization, and Polymerization Activity of [Bis(4,4‘-bis(neophyldimethylsilylmethyl)-2,2‘-bipyridyl)copper(I)]+CuBr2- and Implications for Copper(I) Catalyst Structures in Atom Transfer Radical Polymerization
2000
Characterization of imidazolate-bridged Cu(ii)–Zn(ii) heterodinuclear and Cu(ii)–Cu(ii) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn–SOD
2000
O2 Activation and Aromatic Hydroxylation Performed by Diiron Complexes
1998
A Contrivance for a Dynamic Porous Framework: Cooperative Guest Adsorption Based on Square Grids Connected by Amide−Amide Hydrogen Bonds
2004 StandoutNobel
The Quest For Extra‐Large Pore, Crystalline Molecular Sieves
1997
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2001
Reactivity of Copper(I) Complexes Towards Dioxygen
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Crystal Engineering of Multidimensional Copper(I) and Silver(I) Coordination Supermolecules and Polymers with Functions
1997
Pterin-Dependent Amino Acid Hydroxylases
1996
Structure and Mössbauer Spectrum of a (μ-1,2-Peroxo)bis(μ-carboxylato)diiron(III) Model for the Peroxo Intermediate in the Methane Monooxygenase Hydroxylase Reaction Cycle
1996
Syntheses and Characterization of Microporous Coordination Polymers with Open Frameworks
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Cyclodextrin-Based Catenanes and Rotaxanes
1998 StandoutNobel
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Kinetic Study of the Homogeneous Atom Transfer Radical Polymerization of Methyl Methacrylate
1997
Copper(I)−Dioxygen Reactivity of [(L)CuI]+ (L = Tris(2-pyridylmethyl)amine): Kinetic/Thermodynamic and Spectroscopic Studies Concerning the Formation of Cu−O2 and Cu2−O2 Adducts as a Function of Solvent Medium and 4-Pyridyl Ligand Substituent Variations
2003
Hydrogen-Bonding Cavities about Metal Ions: Synthesis, Structure, and Physical Properties for a Series of Monomeric M−OH Complexes Derived from Water
2001
Exogenous Substrate Reactivity with a [Cu(III)2O2]2+ Core: Structural Implications
1999
Spectroscopic Study of [Fe2(O2)(OBz)2{HB(pz‘)3}2]: Nature of the μ-1,2 Peroxide−Fe(III) Bond and Its Possible Relevance to O2Activation by Non-Heme Iron Enzymes
1998
Exchange Properties of the Three-Dimensional Coordination Compound 1,3,5-Tris(4-ethynylbenzonitrile)benzene·AgO3SCF3
1996
Bimetallic dioxygen complexes derived from ‘end-off’ compartmental ligands
2000
Electronic properties, hydrogen bonding, stacking, and cation binding of DNA and RNA bases
2001
Anion coordination and anion-directed assembly: highlights from 1997 and 1998
2000
Crystal Engineering of Metalloporphyrin Zeolite Analogues
2000
Metric Engineering of Crystalline Inclusion Compounds by Structural Mimicry
2000
Syntheses, Structures, and Reactivity of Low Spin Iron(III) Complexes Containing a Single Carboxamido Nitrogen in a [FeN5L] Chromophore
2001
Synthesis and Spectroscopic Studies of Non-Heme Diiron(III) Species with a Terminal Hydroperoxide Ligand: Models for Hemerythrin
2001
Desolvatisierung eines neuartigen, durch H-Brücken gebildeten mikroporösen Gerüsts: Charakterisierung durch In-situ-Einkristall- und -Pulverröntgendiffraktometrie
1998
Self‐Assembly in Natural and Unnatural Systems
1996 StandoutNobel
Cyclobis(Paraquat‐4,4′‐Biphenylene)–an Organic Molecular Square
1996 StandoutNobel
Supertetrahedral Sulfide Crystals with Giant Cavities and Channels
1999 StandoutScienceNobel
Structures of Metal–Organic Frameworks with Rod Secondary Building Units
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2000
Nanoporous and mesoporous organic structures: new openings for materials research
1999
Double Hydrogen Bond- and π−π-Stacking-Assembled Two-Dimensional Copper(I) Complex of 2-Hydroxyquinoxaline
1997
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
2002 StandoutScienceNobel
Docking in Metal-Organic Frameworks
2009 StandoutScienceNobel
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2013 StandoutScienceNobel
A Diferric Peroxo Complex with an Unprecedented Spin Configuration: AnS=2 System Arising from anS=5/2, 1/2 Pair
2002
Synthesis, Structure, and H2O2-Dependent Catalytic Functions of Disulfide-Bridged Dicopper(I) and Related Thioether−Copper(I) and Thioether−Copper(II) Complexes
2000
A homochiral metal–organic porous material for enantioselective separation and catalysis
2000 StandoutNature
Novel Intercalation Host System Based on Transition Metal (Fe2+, Co2+, Mn2+)−Chloranilate Coordination Polymers. Single Crystal Structures and Properties
1998 StandoutNobel
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2005 StandoutScienceNobel
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2002 StandoutNobel
Synthesis and crystal structures of novel one-dimensional polymers, [{M(bpen)X}∞][M = CuI, X = PF6–; M = AgI, X = ClO4–; bpen =trans-1,2-bis(2-pyridyl)ethylene] and [{Cu(bpen)(CO)(CH3CN)(PF6)}∞]
1991 StandoutNobel
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1997 Standout
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
1999 StandoutNatureNobel
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2001
Construction of Various Supramolecules by π−π Interactions: Self-Assembly of Nickel(II) Macrocyclic Complexes Containing Pyridine Pendant Arms with Bidentate Ligands
2001
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
2011 StandoutNobel
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2013 StandoutScienceNobel
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1999
Protein Radicals in Enzyme Catalysis
1998 Standout
Dynamic Aspects of Lattice Inclusion Complexation Involving a Phase Change. Equilibrium, Kinetics, and Energetics of Guest-Binding to a Hydrogen-Bonded Flexible Organic Network
1998
Porous Metal−Organic Framework with Coordinatively Unsaturated MnII Sites:Sorption Properties for Various Gases
2006
Dioxygen Cleavage and Methane Activation on Diiron Enzyme Models: A Theoretical Study
1997 Nobel
[N-Alkyl-(2-pyridyl)methanimine]copper(I) Complexes: Characterisation and Application as Catalysts for Atom-Transfer Polymerisation
1998
Atom Transfer Radical Polymerization
2001 Standout
Metric Engineering of Soft Molecular Host Frameworks
2000
Synthesis, structure, and catalytic function of a disulfide-bridged dicopper(I) complex
2000
Iron-Catalyzed Olefin cis-Dihydroxylation by H2O2: Electrophilic versus Nucleophilic Mechanisms
2003
Raman Evidence for a Weakened O−O Bond in Mononuclear Low-Spin Iron(III)−Hydroperoxides
1998 StandoutNobel
Design and control of gas diffusion process in a nanoporous soft crystal
2019 StandoutScienceNobel
Synthesis, Characterization, and Activation of Thermally Stable μ-1,2-Peroxodiiron(III) Complex
2001
Functional Mimic of Dioxygen-Activating Centers in Non-Heme Diiron Enzymes: Mechanistic Implications of Paramagnetic Intermediates in the Reactions between Diiron(II) Complexes and Dioxygen
2002
Gold−Gold Interactions as Crystal Engineering Design Elements in Heterobimetallic Coordination Polymers
2001
Synthesis, Crystal Structure, and Properties of a 3-D Network Assembled by Nickel(II) Macrocyclic Complex and Terephthalato Bridge
1999
Engineering coordination polymers towards applications
2003 Standout
New Zinc Phosphates Decorated by Imidazole-Containing Ligands
2005
Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)FeIII(N3)]+ and Ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in Water/Acetone Mixtures
2000
Variable Pore Size, Variable Chemical Functionality, and an Example of Reactivity within Porous Phenylacetylene Silver Salts
1999
Large-Pore Apertures in a Series of Metal-Organic Frameworks
2012 StandoutScienceNobel
Spectroscopic Properties and Electronic Structure of Low-Spin Fe(III)−Alkylperoxo Complexes: Homolytic Cleavage of the O−O Bond
2001
Structure and 1H NMR study of copper(I) complex with ethylene and tetramethylethylenediamine
1997
Self-Accelerating CO Sorption in a Soft Nanoporous Crystal
2013 StandoutScienceNobel
Chiral Three-Dimensional Microporous Nickel Aspartate with Extended Ni−O−Ni Bonding
2006
Adsorption Dynamics of Gases and Vapors on the Nanoporous Metal Organic Framework Material Ni2(4,4‘-Bipyridine)3(NO3)4: Guest Modification of Host Sorption Behavior
2001
Extended X-ray Absorption Fine Structure Analysis of the Bipyridine Copper Complexes in Atom Transfer Radical Polymerization
2000
Ultrahigh Porosity in Metal-Organic Frameworks
2010 StandoutScienceNobel
Works of Hideki Masuda being referenced
Synthesis, Structure, and Spectroscopic Properties of [Feiii(tnpa)(OH)(PhCOO)]ClO4: A Model Complex for an Active Form of Soybean Lipoxygenase-1
1998
Structural and Spectroscopic Characterization of a Mononuclear Hydroperoxo-Copper(II) Complex with Tripodal Pyridylamine Ligands
1998
„Programmierte” Selbstorganisation von Kupfer(II)‐L ‐ und ‐D ‐Arginin‐Komplexen mit aromatischen Dicarboxylaten unter Bildung von chiralen Doppelhelices
1996
Synthesis and Characterization of Novel Alkylperoxo Mononuclear Iron(III) Complexes with a Tripodal Pyridylamine Ligand: A Model for Peroxo Intermediates in Reactions Catalyzed by Non-Heme Iron Enzymes
1999
Guest-Binding Properties of Organic Crystals Having an Extensive Hydrogen-Bonded Network: An Orthogonal Anthracene-Bis(resorcinol) Derivative as a Functional Organic Analog of Zeolites
1995
Catalysis by Organic Solids. Stereoselective Diels−Alder Reactions Promoted by Microporous Molecular Crystals Having an Extensive Hydrogen-Bonded Network
1997
Structure–Activity Relationship Study on Isothiocyanates: Comparison of TRPA1-Activating Ability between Allyl Isothiocyanate and Specific Flavor Components of Wasabi, Horseradish, and White Mustard
2015
A Unique Copper(II)-Hydroxide Complex Derived from Copper(II)-Superoxide
1996
cis-μ-1,2-Peroxo Diiron Complex: Structure and Reversible Oxygenation
1996
Kinetic Resolution of rac-Phenylalanine by Stereoselective Complexation to a Chiral Cobalt Complex through π−π Stacking Interaction
2003
Crystal Structure of Bis(2,2′-bipyridine)copper(I) Perchlorate
1987 StandoutNobel
Structural studies of copper(I) complexes with ethylene. Crystal structures of [Cu(2,2′-bipyridine)(ethylene)]ClO4 and [Cu(1,10-phenanthroline)(ethylene)]ClO4
1987 StandoutNobel
Structural and Spectroscopic Features of a cis (Hydroxo)-FeIII-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases
2002
Structure of bis(2,6-dimethylpyridine)copper(I) perchlorate. The relationship between the CuN(pyridine) distance and Cu···CH3(methyl group) contacts
1989 StandoutNobel
Interligand CH · · · π interaction in binary cobalt(III) complexes of N-pyridoxy-L-amino acids. Biological significance of the pyridoxal 2-methyl group
1997
Reactivity of Hydroperoxide Bound to a Mononuclear Non-Heme Iron Site
2002
(Catecholato)iron(III) complexes with tetradentate tripodal ligands containing substituted phenol and pyridine units as structural and functional model complexes for the catechol-bound intermediate of intradiol-cleaving catechol dioxygenases
2000
Creation of a Type 1 Blue Copper Site within a de Novo Coiled-Coil Protein Scaffold
2010
Pteridine-containing ternary and quaternary complexes as models for metalloenzyme-pterin cofactor-substrate association. Structure of ternary copper(II)-2,2'-bipyridine-lumazine complex and successful equilibrium study of a quaternary copper(II) system
1992
Aromatic carboxylate-controlled self-organization of copper(II)–l-arginine complexes
1999
An infinite chiral single-helical structure formed in Cu(II)-l-/d-glutamic acid system
1998
Programmed Self‐Assembly of Copper(II )‐L ‐ and ‐D ‐Arginine Complexes with Aromatic Dicarboxylates to Form Chiral Double‐Helical Structures
1996
Structure and1H n.m.r. spectrum of a binuclear copper(I ) complex with non-bridging and bridging 2-vinylpyridine ligands (vpy), [Cu2(µ-vpy)2(vpy)2](ClO4)2
1987 StandoutNobel
Nucleobase Stacking Evidenced on Ternary Metal (Palladium(II), Copper(II)) Complexes with Nucleobase Amino Acids and Aromatic Diimines
1999
Synthesis and Structure of a New Tripodal Polypyridine Copper(II) Complex That Enables to Recognize a Small Molecule
1995
Strukturelle und spektroskopische Charakterisierung eines einkernigen Hydroperoxo-Kupfer(II)-Komplexes mit tripodalem Pyridylaminliganden
1998
Preparations, Structures, and Properties of Cu(II) Complexes with Tripodal Tetradentate Ligand, Tris(6-pivaloylamino-2-pyridylmethyl)amine (Htppa), and Reaction of Its Cu(I) Complex with Dioxygen
1998
Functional Self-Assembly of Hydrogen-Bonded Networks. Construction of Aromatic Stacks and Columns and Cavity-Size Control via Flexible Intercalation of 1D Chains Having Orthogonal Aromatic Substituents
1997
Crystal Engineering of Stacked Aromatic Columns. Three-Dimensional Control of the Alignment of Orthogonal Aromatic Triads and Guest Quinones via Self-Assembly of Hydrogen-Bonded Networks
1996
Epoxidation activities of mononuclear ruthenium–oxo complexes with a square planar 6,6′-bis(benzoylamino)-2,2′-bipyridine and axial ligands
2002
Hydrogen-bonded network formation in organic crystals as effected by perpendicular and divergent hydroxyl groups: The crystal structure of a bisresorcinol derivative of anthracene
1993
Synthesis and structures of (2,9-dimethyl-1,10-phenanthroline)(acetonitrile)copper(I) perchlorate and hexafluorophosphate. A correlation between bond angles and bond distances in T- and Y-shaped three-coordinate copper(I) complexes
1989 StandoutNobel
Efficient Electron Transfer Ruthenium Sensitizers for Dye-Sensitized Solar Cells
2009
A Structurally Characterized Mononuclear Copper(II)-Superoxo Complex
1994
Self-Assembly of Porphyrin Arrays by Hydrogen Bonding in the Solid State: An Orthogonal Porphyrin-Bisresorcinol System
1998
Crystal structure of an infinite stair-type chain compound [{Cu2(tc)2(ClO4)2} n ](tc = thiochrome)
1991 StandoutNobel
Synthesis, properties and crystal structures of dicopper(I) and disilver(I) complexes with 1,8-naphthyridine (napy): [Cu2(napy)2](ClO4)2 and [Ag2(napy)2](ClO4)2
1990 StandoutNobel
Structure and properties of a pterin-containing ternary copper(II) complex, [Cu(bpy)(PC)(H2O)].cntdot.3H2O (bpy = 2,2'-bipyridine; PC = pterin-6-carboxylate). Implications for the active-site copper-cofactor bonding in Chromobacterium violaceum phenylalanine hydroxylase
1989