Standout Papers
- Forty years of hydride reductions (1979)
- Inhibition of the reaction of organoboranes with .alpha.,.beta.-unsaturated carbonyl derivatives by galvinoxyl. Evidence for a free-radical chain mechanism (1970)
- 1,3,2-Benzodioxaborole, a convenient monofunctional hydroborating agent. Simple new synthesis of alkaneboronic esters and acids from olefins via hydroboration (1971)
- Cyclic hydroboration of 1,5-cyclooctadiene. A simple synthesis of 9-borabicyclo[3.3.1]nonane, an unusually stable dialkylborane (1968)
- Hydroboration. III. The Reduction of Organic Compounds by Diborane, an Acid-type Reducing Agent (1960)
- Hydroboration—a powerful synthetic tool (1961)
- Lithium tri-sec-butylborohydride. New reagent for the reduction of cyclic and bicyclic ketones with super stereoselectivity. Remarkably simple and practical procedure for the conversion of ketones to alcohols in exceptionally high stereochemical purity (1972)
- Hydroboration. 50. Hydroboration of representative alkynes with 9-borabicyclo[3.3.1]nonane - a simple synthesis of versatile vinyl bora and gem-dibora intermediates (1979)
- 2,6-DI-BUTYLPYRIDINE—AN UNUSUAL PYRIDINE BASE (1953)
- Selective Reductions. IX. Reaction of Lithium Aluminum Hydride with Selected Organic Compounds Containing Representative Functional Groups1 (1966)
- Solvomercuration-demercuration. I. Oxymercuration-demercuration of representative olefins in an aqueous system. Mild procedure for the Markovnikov hydration of the carbon-carbon double bond (1970)
- A Quantitative Treatment for Electrophilic Reactions of Aromatic Derivatives1-3 (1957)
- Organoborane-carbon monoxide reactions. Synthesis of carbon structures (1969)
- Electrophilic Substituent Constants (1958)
- Stereospecific conversion of alkenylboronic acids into alkenyl bromides with inversion of configuration. Striking differences in the stereochemistry of the replacement of the boronic acid substituent by bromine and iodine and its significance in terms of the reaction mechanism (1973)
- Communications - Hydroboration of Olefins. A Remakably Fast Room-Temperature Addition of Diborane to Olefins (1957)
- Facile reduction of alkyl tosylates with lithium triethylborohydride. An advantageous procedure for the deoxygenation of cyclic and acyclic alcohols (1976)
- Organic Syntheses via Free‐Radical Displacement Reactions of Organoboranes (1972)
- The Preparation of Other Borohydrides by Metathetical Reactions Utilizing the Alkali Metal Borohydrides1 (1953)
- Studies in Stereochemistry. XXII. The Preparation and Reactions of Trimesitylborane. Evidence for the Non-localized Nature of the Odd Electron in Triarylborane Radical Ions and Related Free Radicals1 (1957)
- New, Highly Active Metal Catalysts for the Hydrolysis of Borohydride (1962)
- Chemical effects of steric strains (1956)
- A New Aldehyde Synthesis—The Reducti[UNK]on of Acid Chlorides by Lithium Tri-t-butoxyaluminohydride1 (1958)
- I-Strain as a Factor in the Chemistry of Ring Compounds1,2 (1951)
- The Reaction of Lewis Acids of Boron with Sodium Hydride and Borohydride1, (1958)
- Preparation and Reactions of 2,6-Di-t-butylpyridine and Related Hindered Bases. A Case of Steric Hindrance toward the Proton1,2 (1966)
- A Study of Solvents for Sodium Borohydride and the Effect of Solvent and the Metal Ion on Borohydride Reductions1 (1955)
- Rates of Reaction of Sodium Borohydride with Bicyclic Ketones. Steric Approach Control and Steric Departure Control in the Reactions of Rigid Bicyclic Systems1,2 (1966)
- THE CHROMIC ACID OXIDATION OF ORGANOBORANES—A CONVENIENT PROCEDURE FOR CONVERTING OLEFINS INTO KETONES via HYDROBORATION (1961)
- Organic syntheses via boranes (1975)
- Facile reaction of organoboranes with methyl vinyl ketone. Convenient new ketone synthesis via hydroboration (1967)
- Selective Reductions. V. The Partial Reduction of Tertiary Amides by Lithium Di- and Triethoxyaluminohydrides-A New Aldehyde Synthesis via the Dimethylamides (1964)
- The Reaction of Organoboranes with Chloramine and with Hydroxylamine-O-sulfonic Acid. A Convenient Synthesis of Amines from Olefins via Hydroboration (1964)
- Hydroboration. IX. The Hydroboration of Cyclic and Bicyclic Olefins—Stereochemistry of the Hydroboration Reaction (1961)
- Lithium trisiamylborohydride. A new sterically hindered reagent for the reduction of cyclic ketones with exceptional stereoselectivity (1976)
- An Interpretation of the Chemical Behavior of Five- and Six-membered Ring Compounds1 (1954)
- Hydroboration. XVIII. The Reaction of Diisopinocampheylborane with Representative cis-Acyclic, Cyclic, and Bicyclic Olefins. A Convenient Systhesis of Optically Active Alcohols and Olefins of High Optical Purity and Established Configuration (1964)
- The Oxymercuration-Demercuration of Representative Olefins. A Convenient, Mild Procedure for the Markovnikov Hydration of the Carbon-Carbon Double Bond (1967)
- Selective reductions. XII. Explorations in some representative applications of aluminum hydride for selective reductions (1968)
- Hydroboration of Terpenes. II. The Hydroboration of α- and β-Pinene-The Absolute Configuration of the Dialkylborane from the Hydroboration of α-Pinene (1964)
- Additions to bicyclic olefins. III. Stereochemistry of the epoxidation of norbornene, 7,7-dimethylnorbornene, and related bicyclic olefins. Steric effects in the 7,7-dimethylnorbornyl system (1970)
- New Developments in the Chemistry of Diborane and the Borohydrides. I. General Summary1 (1953)
- Hydroboration. II. A Remarkably Fast Addition of Diborane to Olefins—Scope and Stoichiometry of the Reaction (1959)
- Sodium Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen1 (1953)
- Boranes in Organic Chemistry (1972)
- The Reaction of Sodium Borohydride with Nickel Acetate in Ethanol Solution--A Highly Selective Nickel Hydrogenation Catalyst (1963)
- The Reaction of Lithium Aluminum Hybride with Alcohols. Lithium Tri-t-butoxyaluminohydride as a New Selective Reducing Agent1,2 (1958)
- Diborane as a Mild Reducing Agent for the Conversion of Primary, Secondary, and Tertiary Amides into the Corresponding Amines (1964)
- Hydroboration. XI. The Hydroboration of Acetylenes—A Convenient Conversion of Internal Acetylenes into cis-Olefins and of Terminal Acetylenes into Aldehydes (1961)
- HYDROBORATION AS A CONVENIENT PROCEDURE FOR THE ASYMMETRIC SYNTHESIS OF ALCOHOLS OF HIGH OPTICAL PURITY (1961)
- Uranium(IV) Borohydride1 (1953)
- A New Powerful Reducing Agent—Sodium Borohydride in the Presence of Aluminum Chloride and Other Polyvalent Metal Halides1,2 (1956)
- Solubility of Hydrogen Chloride at Low Temperatures. A Measure of the Basic Properties of Aromatic Nuclei; π- and σ-Complexes and Their Role in Aromatic Substitution1,2 (1952)
- Organoboranes (1977)
- Hydroboration. XXVII. The hydroboration of 1-butenyl and related vinyl derivatives containing representative substituents. An unusually powerful directive influence of the ethoxy substituent (1968)
- The Heats of Reaction of Pyridine and Nitrobenzene with Boron Trifluoride, Trichloride and Tribromide; the Relative Acceptor Properties of the Boron Halides1,2 (1956)
- Convenient and general synthesis of acetylenes via the reaction of iodine with lithium l-alkynyltriorganoborates (1973)
- Reaction of alkenylboronic acids with iodine under the influence of base. Simple procedure for the stereospecific conversion of terminal alkynes into trans-1-alkenyl iodides via hydroboration (1973)
- Hydroboration. V. A Study of Convenient New Preparative Procedures for the Hydroboration of Olefins (1960)
- A STEREOSPECIFIC CIS HYDRATION OF THE DOUBLE BOND IN CYCLIC DERIVATIVES (1959)
- Lithium triethylborohydride. Exceptionally powerful nucleophile in displacement reactions with organic halides (1973)
- The Effect of Ring Size on the Rate of Solvolysis of the 1-Chloro-1-methylcycloalkanes1,2 (1952)
- Substituent Constants for Aromatic Substitution1-3 (1957)
- A SIMPLE PROCEDURE FOR THE CHROMIC ACID OXIDATION OF ALCOHOLS TO KETONES OF HIGH PURITY (1961)
- The Preparation of Sodium Borohydride by the High Temperature Reaction of Sodium Hydride with Borate Esters1 (1953)
- Chemical effects of steric strains—XIV (1957)
- Hydroboration. VII. Directive Effects in the Hydroboration of Olefins (1960)
- The Nonclassical Ion Problem (1967)
- A NEW TECHNIQUE FOR THE CONVERSION OF OLEFINS INTO ORGANOBORANES AND RELATED ALCOHOLS (1956)
- Selective reductions. XVIII. Fast reaction of primary, secondary, and tertiary amides with diborane. Simple, convenient procedure for the conversion of amides to the corresponding amines (1973)
- Selective Reductions. X. Reaction of Aluminum Hydride with Selected Organic Compounds Containing Representative Functional Groups. Comparison of the Reducing Characteristics of Lithium Aluminum Hydride and Its Derivatives (1966)
- Selective reductions. XV. Reaction of diborane in tetrahydrofuran with selected organic compounds containing representative functional groups (1970)
- Hydroboration. XXXIX. 1,3,2-Benzodioxaborole (catecholborane) as a new hydroboration reagent for alkenes and alkynes. General synthesis of alkane- and alkeneboronic acids and esters via hydroboration. Directive effects in the hydroboration of alkenes and alkynes with catecholborane (1975)
- Catecholborane (1,3,2-benzodioxaorole) as a new, general monohydroboration reagent for alkynes. Convenient synthesis of alkeneboronic esters and acids from alkynes via hydroboration (1972)
- Reactions of Diborane with Alkali Metal Hydrides and Their Addition Compounds. New Syntheses of Borohydrides. Sodium and Potassium Borohydrides1 (1953)
- An Extended Table of Hammett Substitutent Constants Based on the Ionization of Substituted Benzoic Acids (1958)
- Hydroboration. XXXVI. Direct route to 9-borabicyclo[3.3.1]nonane via the cyclic hydroboration of 1,5-cyclooctadiene. 9-Borabicyclo[3.3.1]nonane as a uniquely selective reagent for the hydroboration of olefins (1974)
- Oxidation of secondary alcohols in diethyl ether with aqueous chromic acid. Convenient procedure for the preparation of ketones in high epimeric purity (1971)
- The Reaction of Sodium Borohydride with Nickel Acetate in Aqueous Solution--A Convenient Synthesis of an Active Nickel Hydrogenation Catalyst of Low Isomerizing Tendency (1963)
- Steric Effects in Displacement Reactions. III. The Base Strengths of Pyridine, 2,6-Lutidine and the Monoalkylpyridines (1955)
- Reaction of 2-alkenyl-1,3,2-benzodioxaboroles with mercuric acetate. Convenient stereospecific procedure for the conversion of alkynes into alkenylmercuric salts (1972)
- Organoboranes. 22. Light-induced reaction of bromine with alkylboronate esters. A convenient synthesis of .alpha.-bromoalkylboronate esters (1977)
- Facile double migration in the protonation of lithium alkynyltrialkylborates with acid (1975)
- Addition Compounds of Alkali Metal Hydrides. Sodium Trimethoxyborohydride and Related Compounds1 (1953)
- Reaction of representative alkynes with monochloroborane diethyl etherate. Simple convenient synthesis of dialkenylchloroboranes via hydroboration (1973)
- Organoboranes. X. Fast reaction of organoboranes with mercuric acetate. Convenient procedure for the conversion of terminal olefins into alkylmercuric salts via hydroboration-mercuration (1970)
- Strained Homomorphs.1 14. General Summary. (1953)
- Rates and Isomer Distribution in the Mercuration of Benzene and Toluene. A Proposed Extension of the Quantitative Relationship Governing Isomer Distribution in Aromatic Substitution1 (1955)
- Solvomercuration-demercuration of representative olefins in the presence of acetonitrile. Convenient procedure for the synthesis of amines (1969)
- Organoboranes (1974)
- Organoboranes (1977)
- Organoboranes (1979)
- New four-carbon-atom homologation involving the free-radical chain reaction of 1,3-butadiene monoxide with organoboranes. Synthesis of 4-alkyl-2-buten-1-ols from olefins via hydroboration (1971)
- Notes - Generalization Dealing with Chemical Behavior or 5- and 6- Membered Ring Compounds (1957)
- Conjugate addition of B-1-alkynyl-9-borabicyclo[3.3.1]-nonanes to .alpha.,.beta.-unsaturated ketones. A convenient synthesis of .gamma.,.delta.-acetylenic ketones (1977)
- Hydroboration. VIII. Bis-3-methyl-2-butylborane as a Selective Reagent for the Hydroboration of Alkenes and Dienes (1961)
- Hydroboration. 51. Hydroboration of representative allenes with 9-borabicyclo[3.3.1]nonane. An exceptional directive effect providing a direct synthesis of B-allyl-9-borabicyclo[3.3.1]nonane derivatives (1979)
- Organoboranes. 23. Reaction of organolithium and Grignard reagents with .alpha.-bromoalkylboronate esters. A convenient, essentially quantitative procedure for the synthesis of tertiary alkyl-, benzyl-, propargyl-, and stereospecific allylboranes (1977)
- Steric Effects in Displacement Reactions. XI. The Heats of Reaction of Diborane with Pyridine Bases. Steric Strains in Homomorphs of o-t-Butyltoluene and Hemimellitene1 (1956)
- Selective Reductions. VIII. The Stereochemistry of Reduction of Cyclic and Bicyclic Ketones by the Alkoxy-Substituted Lithium Aluminum Hydrides1 (1965)
- Structural effects in solvolytic reactions. 26. A critical study of the effect of solvent on the exo:endo rate ratio in the solvolysis of 2-norbornyl derivatives. Evidence that the exo:endo rate ratio is not the result of K.DELTA./Ks processes (1978)
- Oxygen-induced reaction of trialkylboranes with alkyl iodides. Facile coupling of benzylic and allylic iodides via triethylborane (1971)
- Stoichiometrically controlled reaction of organoboranes with oxygen under very mild conditions to achieve essentially quantitative conversion into alcohols (1971)
- Solvolysis of 9-aryl-9-pentacyclo[4.3.0.02,4.03,8.05,7]nonyl p-nitrobenzoates. Unambiguous evidence for the presence of carbon participation by the application of the tool of increasing electron demand (1977)
- The Action of the Catalyst Couple Aluminum Chloride—Hydrogen Chloride on Toluene at Low Temperatures; the Nature of Friedel—Crafts Complexes1,2 (1952)
- Reaction of lithium ethynyl- and ethenyltrialkylborates with acid. Valuable route to the Markovnikov alkenyl- and alkylboranes (1975)
- An Interpretation of Meta Orientation in the Alkylation of Toluene. The Relative Reactivity and Isomer Distribution in the Chloromethylation and Mercuration of Benzene and Toluene1,2 (1953)
- Oxygen-induced reactions of organoboranes with acetylacetylene. Convenient new synthesis of .alpha.,.beta.-unsaturated ketones via hydroboration (1970)
- THE REACTION OF TRIETHYLBORANE WITH OXIDES OF SILVER, GOLD AND PLATINUM—A NEW CONVENIENT ROUTE TO NOBLE METAL ALKYLS AND TO FREE RADICAL CHEMISTRY (1961)
- Solvolysis of 2-aryl-2-bicyclo[2.1.1]hexyl p-nitrobenzoates. Evidence for the absence of .sigma.-participation by the application of the tool of increasing electron demand (1977)
- Conjugate addition of B-alkenyl-9-borabicyclo[3.3.1]nonanes to methyl vinyl ketone. A convenient synthesis of .gamma.,.delta.-unsaturated ketones (1976)
- Organoboranes (1971)
- Convenient stereospecific synthesis of terminal acetylenes via the treatment of lithium ethynyltrialkylborates with iodine (1974)
- A Stereospecific Synthesis of Alicyclic and Bicyclic Amines via Hydroboration (1966)
- LITHIUM DIETHOXYALUMINOHYDRIDE AS A SELECTIVE REDUCING AGENT—THE REDUCTION OF DIMETHYLAMIDES TO ALDEHYDES (1959)
- Question of .sigma. bridging in the solvolysis of 2-norbornyl derivatives (1973)
- Base-induced reaction of organoboranes with bromine. Convenient procedure for the anti-Markovnikov hydrobromination of terminal olefins via hydroboration-bromination (1970)
- THE REACTION OF TRIALKYLBORANES WITH ALKALINE SILVER NITRATE—A NEW GENERAL COUPLING REACTION (1961)
- A Grignard-like addition of B-alkenyl-9-borabicyclo[3.3.1]nonanes to aldehydes. A novel synthesis of allylic alcohols with defined stereochemistry (1977)
- Solvolysis of the 2-[3,5-bis(trifluoromethyl)phenyl]-2-norbornyl p-nitrobenzoates and the 1-arylcyclopentyl p-nitrobenzoates. Failure of a further increase in electron demand to alter the exo:endo rate ratio (1975)
- Chemical effects of steric strains—XIII (1957)
- Dissociation of the Addition Compounds of Trimethylboron with Branched-Chain Primary Amines; the Effects of Chain-Branching1,2 (1953)
- Reaction of organoboranes with bromoacetone under the influence of potassium 2,6-Di-tert-butylphenoxide. A convenient procedure for the conversion of olefins into methyl ketones via hydroboration (1969)
- Thexylborane as a convenient reagent for the cyclic hydroboration of dienes. Stereospecific syntheses via cyclic hydroboration (1967)
- Formation of alkyl bromides in the dark reaction of bromine with organoboranes. Evidence for an unusual pathway involving the prior bromination of the organoborane (1970)
- Structural effects in solvolytic reactions. 27. Solvolysis of the exo- and endo-1,2-diphenyl-2-norbornyl and -1,2-dimethyl-2-norbornyl p-nitrobenzoates and chlorides. Evidence for the classical nature of 1,2-disubstituted tertiary 2-norbonyl cations and structure of the parent 2-norbornyl cation (1978)
- 9-Borabicyclo[3.3.1]nonane as a highly selective reducing agent for the facile conversion of .alpha.,.beta.-unsaturated aldehydes and ketones to the corresponding allylic alcohols in the presence of other functional groups (1975)
- Acyl peroxide and photochemical induced reactions of organoboranes with the inert .alpha.,.beta.-unsaturated carbonyl derivatives (1970)
- Lithium .beta.-isopinocamphenyl-9-borabicyclo[3.3.1]nonyl hydride. A new reagent for the asymmetric reduction of ketones with remarkable consistency (1977)
- Mono- and dialkylation of ethyl dihaloacetates by reaction with organoboranes under the influence of potassium tert-butoxide. Convenient procedures for the conversion of olefins into the .alpha.-halo alkanoic or dialkylacetic acid esters via hydroboration (1968)
- Selective Reductions. I. The Partial Reduction of Tertiary Amides with Lithium Aluminum Hydride. A New Aldehyde Synthesis via the 1-Acylaziridines1,2 (1961)
- New addition compounds of dialkylboranes and aluminum methoxide. New practical synthesis of dialkylboranes and of mixed trialkylboranes containing functional groups (1971)
- Hydroboration. XXVIII. The hydroboration of 3-cyclopentenyl derivatives containing representative substituents. Directive effects and the elimination reaction in a cyclic system (1968)
- Synthesis of secondary alkyl bromides in the dark reaction of bromine with B-sec-alkyl-9-borabicyclo[3.3.1]nonanes. A convenient procedure for the anti-Markovnikov hydrobromination of internal olefins (1971)
- Stereochemistry of the carbonylation, carbethoxymethylation, and .gamma.-propanalation reactions of organoboranes. Substitution reactions at carbon that proceed with retention of configuration (1969)
- A Quantitative Approach to the Ortho Effects of Halogen Substituents in Aromatic Systems1,2 (1955)
- The Rates of Mercuration of the Monoalkyl- and the Polymethylbenzenes. Calculation of Relative Reactivities for the Mercuration Reaction1,2 (1955)
- Organoboranes (1972)
- Light-induced reaction of bromine with trialkylboranes in the presence of water. A remarkably simple procedure for the union of two or three alkyl groups to produce highly substituted alcohols (1971)
- A fast reaction of organoboranes with iodine under the influence of base. A convenient procedure for the conversion of terminal olefins into primary iodides via hydroboration-iodination (1968)
- Organoboranes (1972)
- Solvomercuration-demercuration. IV. Monohydration of representative dienes via oxymercuration-demercuration (1972)
- Rates and products of solvolysis of 2-methyl-2-norbornenyl and 2,5-dimethyl-2-norbornenyl p-nitrobenzoates. Evidence for increasing .pi.-participation with increasing electron demand (1975)
- Selective reductions. XIV. Fast reaction of aryl bromides and iodides with lithium aluminum hydride in tetrahydrofuran. Simple convenient procedure for the hydrogenolysis of aryl bromides and iodides (1969)
- Organoboranes. II. The Preparation and Properties of Alkyldiboranes Containing Bulky Alkyl Substituents (1962)
- Reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with carbon monoxide in the presence of lithium trimethoxyaluminohydride. A convenient procedure for the conversion of olefins into aldehydes via hydroboration (1969)
- Reaction of organoboranes with methoxycarbene, and reaction of dichloromethyl methyl ether with at-complex obtained from organoboranes and methyl lithium (1969)
- Carbonylation of thexyldialkylboranes. New general synthesis of ketones (1967)
- Stereochemistry of .beta. elimination in 2-norbornyl and 7,7-dimethyl-2-norbornyl tosylates. Evidence for the preferential attack by base on the exo-3-hydrogen in both systems (1970)
- Molecular addition compounds. 3. Redistribution of borane-methyl sulfide with boron trichloride-methyl sulfide and boron tribromide-methyl sulfide as convenient routes to the corresponding haloborane-methyl sulfides (1977)
- Additions to bicyclic olefins. VII. Electrophilic additions of hydrogen chloride and deuterium chloride to norbornene, 2-methylenenorbornane, and related bicyclic olefins. Evidence for a carbonium ion process and the capture of unsymmetrical (classical) 2-norbornyl cations (1975)
- Rates of Solvolysis of the p-Nitrobenzoates of exo-endo Tertiary Norborneols. A Critical Examination of the exo-endo Rate Ratio as a Basis for the Postulated Nonclassical Structure of the Norbornyl Cation (1964)
- Hydroboration. VI. A Convenient Synthesis of the Alkane and Cycloalkane Boronic and Borinic Esters and Acids (1960)
- Reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with .alpha.-bromo ketones under the influence of potassium tert-butoxide. A convenient procedure for the .alpha.-alkylation of ketones (1969)
- Fast base-induced reaction of .alpha.,.alpha.-dichloromethyl ether with organoboranes. New general route from organoboranes to the corresponding carbon structures (1973)
- The Reaction of Methyl Iodide with o-Phenylenediamine; Homomorphs of o-Di-t-butylbenzene1,2 (1953)
- Explorations in the nonclassical ion area (1976)
- A Simple Preparation of Highly Active Platinum Metal Catalysts for Catalytic Hydrogenation (1962)
- Solvomercuration-demercuration of representative olefins in the presence of alcohols. Convenient procedures for the synthesis of ethers (1969)
- Synthesis of both cis- and trans-vinyl bromides from 1-alkynes via hydroboration (1967)
- Selective Reductions. III. Further Studies of the Reaction of Alcohols with Lithium Aluminum Hydride as a Route to the Lithium Alkoxyaluminohydrides (1964)
- Hydroboration of Terpenes. III. Isomerization of (+)-3-Carene to (+)-2-Carene. Hydroboration of (+)-2-Carene ([UNK]4-Carene). Nuclear Magnetic Resonance Spectra with Absolute Configurational and Conformational Assignments for the 2-Caranols and 2-Caranones (1967)
- Carbonylation of mixed trialkylboranes containing substituents as a synthetic route to unsymmetrical ketones with such functional substituents. Route for the conversion of olefins, RCH:CH2, into the corresponding carboxylic acids, RCH2CH2CO2H (1967)
- Reaction of organoboranes with ethyl bromoacetate under the influence of potassium tert-butoxide. A convenient procedure for the conversion of olefins into esters via hydroboration (1968)
- Additions to bicyclic olefins. V. Effect of 7,7-dimethyl substituents on the stereochemistry and rates of cyclic additions to norbornenes (1973)
- Improved Arc Process for the Preparation of Diborane. Purification of Diborane1 (1953)
- The Effect of Perchloric Acid on the Reactivity Ratio and Isomer Distribution in the Mercuration of Benzene and Toluene. Modification of the Activity and Selectivity of an Electrophilic Substituting Agent1,2 (1955)
- Steric Effects in Elimination Reactions. II. The Effect of the Steric Requirements of Alkyl Substituents upon the Extent and Direction of Unimolecular Elimination in the Solvolysis of Tertiary Alkyl Bromides (1955)
- Organoboranes. VII. The Displacement Reaction with Organoboranes Derived from the Hydroboration of Cyclic and Bicyclic Olefins. Conversion of Endocyclic to Exocyclic Double Bonds (1967)
- Facile redistribution of trialkylboranes with trimethylene borate. A simple, general synthesis of alkaneboronic esters and acids from olefins via hydroboration (1970)
- Reaction of organoboranes with .alpha.-bromo ketones under the influence of potassium tert-butoxide in tetrahydrofuran. A new technique for the .alpha.-alkylation of ketones (1968)
- Solvomercuration-demercuration. V. Additions to bicyclic olefins. VI. Stereochemistry of the oxymercuration-demercuration of norbornene, 7,7-dimethylnorbornene, and related olefins (1973)
- The Oxygen-Induced Reactions of Organoboranes with 3,4-Epoxy-1-butynes. A New Route to Functionalized Allenes (1973)
- Reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with carbon monoxide in the presence of lithium tri-t-butoxyaluminohydride. The conversion of functionally substituted olefins into aldehydes via hydroboration (1969)
- Reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with ethyl mono- and dihaloacetates under the influence of potassium tert-butoxide. A convenient procedure for the conversion of olefins into esters or .alpha.-halo esters via hydroboration (1969)
- Facile reaction of alkyl- and aryldichloroboranes with organic azides. General stereospecific synthesis of secondary amines (1973)
- Additions to bicyclic olefins. VIII. Electrophilic addition of trifluoroacetic acid and deuteriotrifluoroacetic acid to norbornene and related bicyclic olefins. Evidence for the capture of the the unsymmetrical (classical) 2-norbornyl cation (1975)
- Reaction of carbon monoxide at atmospheric pressure with trialkylboranes in the presence of water. Synthesis of dialkyl ketones via hydroboration (1967)
- Rates of Solvolysis of the Alkylphenyldimethylcarbinyl Chlorides. Evidence for the Importance of Carbon-to-Carbon Hyperconjugative Contributions in Alkyl Groups1,2 (1957)
- Reaction of B-methoxydialkylboranes with lithium aluminum hydride in the presence of olefins. A new and general synthesis of acyclic and cyclic mixed trialkylboranes and their conversion into the corresponding trialkylcarbinols via carbonylation-oxidation (1970)
- Hydroboration. XXI. The Reaction of Unsaturated Alkyl Chlorides and p-Toluenesulfonates with Diborane and Disiamylborane (1964)
- Unusually high exo-endo rate ratio in the solvolysis of the 2,2,6-trimethyl-2-norbornyl p-nitrobenzoates. Evidence for steric effects as a major factor in the exo-endo rate ratios of norbornyl derivatives (1968)
- Organoboranes. 20. The facile allylboration of representative carbonyl compounds with B-allyl derivatives of 9-borabicyclo[3.3.1]nonane (1977)
- Hydroboration of Terpenes. IV. Hydroboration of (+)-3-Carene ([UNK]3-Carene). Configuration Assignments for the 4-Caranols and 4-Caranones. An Unusual Stability of 4-Isocaranone with a cis Relationship of the Methyl and gem-Dimethyl Groups (1967)
- Oxygen-induced reactions of organoboranes with the inert .alpha.,.beta.-unsaturated carbonyl derivatives. Convenient new aldehyde and ketone synthesis via hydroboration (1970)
- Hydroboration. XVII. An Examination of Several Representative Dialkylboranes as Selective Hydroborating Agents (1963)
- Solvomercuration-demercuration. III. Relative rates of oxymercuration of representative olefins in an aqueous tetrahydrofuran system (1972)
- The Reaction of 7-Norbornadienyl and 7-Dehydronorbornyl Derivatives with Borohydride under Solvolytic Conditions--Evidence for the Tricyclic Nature of the Corresponding Cations (1963)
- A General Multi-Carbon Homologation of OlefinsviaHydroboration-Carbonylation (1972)
- 9-Borabicyclo[3.3.1]nonane as a convenient selective hydroborating agent (1968)
- Reaction of ethyl haloacetates and .alpha.-bromo ketones with B-aryl-9-borabicyclo(3.3.1)nonanes under the influence of potassium tert-butoxide. A new convenient procedure for the .alpha.-arylation of ketones and esters (1969)
- Facile reaction of B-alkylboracyclanes with .alpha.,.beta.-unsaturated carbonyl derivatives. Extension of the 1,4-addition reaction via organoboranes to highly branched secondary and tertiary alkyl groups (1971)
- Selective reductions. 24. Acyloxyboranes in the controlled reaction of carboxylic acids with borane-tetrahydrofuran. Acyloxyboranes as intermediates in the fast reduction of carboxylic acids by borane-tetrahydrofuran (1977)
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- Reaction of representative organic azides with triethylborane. New route to secondary amines (1971)
- Steric Effects in Elimination Reactions. V. The Importance of Steric Strains in the Extent and Direction of Unimolecular Elimination. The Role of Steric Strains in the Reactions of Highly Branched Carbonium Ions (1955)
- Facile reaction of dialkylchloroboranes with organic azides. Remarkable enhancement of reactivity relative to trialkylboranes (1972)
- Product-rate correlation in acetolysis of threo-3-aryl-2-butyl brosylates. Supporting evidence for the existence of two discrete pathways (1970)
- Homomorphs of 2,6-Dimethyl-t-butylbenzene1,2 (1953)
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Stereocontrolled Total Synthesis of (+)-Altohyrtin A/Spongistatin 1 Financial support was provided by the EPSRC (GR/L41646), Cambridge Commonwealth Trust (Scholarship to M.J.C.), EC (Marie Curie Postdoctoral Fellowship to J.L.A.), DFG (Postdoctoral Fellowship to T.T.), NSERC-Canada (Postdoctoral Fellowship to R.M.O.), Churchill College (Research Fellowship to D.J.W.), Kingapos;s College and Sims Fund, Cambridge (Scholarship to D.Y.K.C.). We also thank Merck and AstraZeneca Pharmaceuticals for generous support, and Dr. Anne Butlin (AZ) and Dr. Nick Bampos (Cambridge) for valuable assistance.
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1985
Mesomolecules. Polyaza‐Polyoxa Macropolycyclic Systems
1973
Total Synthesis of (−)-2-epi-Peloruside A
2008
A General, Convergent Strategy for the Construction of Indolizidine Alkaloids: Total Syntheses of (−)-Indolizidine 223AB and Alkaloid (−)-205B
2006
The Reactions of (1-Halo-1-alkenyl)dialkylboranes with Lead(IV) Acetate or (Diacetoxyiodo)benzene. A Stereoselective Synthesis of 1-Halo-1,2-dialkylethylenes
1980 StandoutNobel
π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
1999 Standout
Toward the Total Synthesis of Natural Peloruside A: Stereoselective Synthesis of the Backbone of the Core
2003
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
2003 StandoutScienceNobel
Organoboranes in Organic Syntheses Including Suzuki Coupling Reaction
2009 StandoutNobel
Hammett Studies on Alkene Extrusion from Rhenium(V) Diolates and an MO Description of Metal Alkoxide−Alkyl Metal Oxo Interconversion
1996
An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst
2000
Synthesis of Enantioenriched Homopropargylic Sulfonamides by a Three Component Reaction of Aldehydes, Sulfonamides, and Chiral Allenylsilanes
2009
Reaction of organoboranes with the dianion of phenoxyacetic acid. The first direct synthesis of carboxylic acids from organoboranes
1978 StandoutNobel
Application of basic zeolites in the decomposition reaction of 2-methyl-3-butyn-2-ol and the isomerization of 3-carene
1999
The Reaction of Copper(I) Methyltrialkylborates with Allylic Halides or 2-Propynylic Halides
1977
Development of 10 kW-scale hydrogen generator using chemical hydride
2003
Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications
2011 Standout
Hydridogallium bis(tetrahydroborate), HGa(BH4)2: Synthesis and properties
1995
Influence of the position of the side chain hydroxy group on the biological properties of prostaglandins
1975
Catalytic Asymmetric Ring-Opening Metathesis/Cross Metathesis (AROM/CM) Reactions. Mechanism and Application to Enantioselective Synthesis of Functionalized Cyclopentanes
2001 StandoutNobel
Synthesis of tri-substituted vinyl boronates via ruthenium-catalyzed olefin cross-metathesis
2004 StandoutNobel
Two efficient methods for the cleavage of pinanediol boronate esters yielding the free boronic acids
1994
Rhodium-Catalyzed Conjugate Addition of Aryl- or 1-Alkenylboronic Acids to Enones
1997
Reactions of Organoboranes with Ferric Chloride and Thiocyanate. Convenient Syntheses of Alkyl Chlorides and Thiocyanates from Olefins via Hydroboration
1974 StandoutNobel
Enantioselective Synthesis of (E)-δ-Stannyl Homoallylic Alcohols via Aldehyde Allylboration Using α-Stannylallylboranes Generated by Allene Hydroboration Followed by a Highly Diastereoselective 1,3-Boratropic Shift
2010
The Nature of the Gradual Transition in Sodium Borohydride
1953
Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions
2011 Standout
Base-catalyzed hydroamination of ethylene with diethylamine
2005
LiBH4 a new hydrogen storage material
2003 Standout
Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway
2010 Standout
Stereochemistry of the Core Structure of the Mycolactones
2001
The synthesis of mixed geminal organometallic compounds
1966
The Preparation and Enzymatic Hydrolysis of Reduced and S-Carboxymethylated Proteins
1963 StandoutNobel
B-Allenyl- and B-(γ-Trimethylsilylpropargyl)- 10-phenyl-9-borabicyclo[3.3.2]decanes: Asymmetric Synthesis of Propargyl and α-Allenyl 3°-Carbinols from Ketones
2006
Sterically crowded aryloxide compounds of aluminum
1994
Efficient Total Synthesis of Novel Bioactive Microbial Metabolites
2008 StandoutNobel
Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines
2011
Radical-forming electron-transfer reactions involving main-group organometallics
1985
Optical Purifications via Self‐Disproportionation of Enantiomers by Achiral Chromatography: Case Study of a Series of α‐CF3‐containing Secondary Alcohols
2013
A More Comprehensive and Highly Practical Solution to Enantioselective Aldehyde Crotylation
2011
Reaction d'aminomercuration—VII
1972
Transition metal complexes of boron — synthesis, structure and reactivity
2001
Verbrückte und unverbrückte norbornyl-kationen in der gasphase. Berechnungen zur stabilität isomerer norbornyl-kationen mit hilfe quantenmechanischer verfahren
1979
Stereoselective Synthesis of the C(1)−C(11) Fragment of Peloruside A
2005
Hydrated σ-bonded organometallic cations in organic synthesis
1988
Total synthesis of aphidicolin
1981
Synthesis of 1,4-disubstituted (E,Z)-1,3-dienes from lithium dicyclohexyl(trans-1-alkenyl)(1-alkynyl)borates
1978
Gold(I)-catalyzed asymmetric aldol reaction of methyl isocyanoacetate with fluorinated benzaldehydes
1994
Extended Hückel Theory. IV. Carbonium Ions
1964 StandoutNobel
Use of activation methods for organozinc reagents
1987
Asymmetric Allyl- and Crotylboration with the Robust, Versatile, and Recyclable 10-TMS-9-borabicyclo[3.3.2]decanes
2005
Enantioselective syntheses with titanium carbohydrate complexes. Part 7. Enantioselective allyltitanation of aldehydes with cyclopentadienyldialkoxyallyltitanium complexes
1992
C2-symmetric aziridines as efficient chiral auxiliaries
1991
Transition metal boryl and borylene complexes: substitution and abstraction chemistry
2004
The Vinylogous Aldol Reaction: A Valuable, Yet Understated Carbon−Carbon Bond-Forming Maneuver
2000 Standout
Catalytic Phenylborylation Reaction by Iridium(0) Nanoparticles Produced from Hydridoiridium Carborane
2008
Aldol sensors for the rapid generation of tunable fluorescence by antibody catalysis
1998 StandoutNobel
Accurate Borane Sequential Bond Dissociation Energies by High-Level ab Initio Computational Methods
1996
Cross-Coupling Reaction of Alkyl- or Arylboronic Acid Esters with Organic Halides Induced by Thallium(I) Salts and Palladium-Catalyst
1989 StandoutNobel
Hydrogen storage properties of LiBH4
2003
THE MICHAEL-TYPE REACTION OF LITHIUM 1-ALKYNYLTRIALKYLBORATES WITH METHYL VINYL KETONE IN THE PRESENCE OF TITANIUM TETRACHLORIDE. A NEW SYNTHESIS OF δ-DIKETONES FROM ORGANOBORANES
1980 StandoutNobel
Concise Asymmetric Total Synthesis of Obolactone
2006
Zur “cis-präferenz” bei der addition von butenyl-metallverbindung an ketone und aldehyde
1980
Conversion of 1,3-disubstituted arenes to chiral α,α-diaryl methylammonium chlorides using arene borylation
2008
Gold(I)-catalyzed asymmetric aldol reactions of isocyanoacetic acid derivatives with fluoroaryl aldehydes
1996
Extremely Active Organocatalysts Enable a Highly Enantioselective Addition of Allyltrimethylsilane to Aldehydes
2016 StandoutNobel
Confinement-Controlled, Either syn- or anti-Selective Catalytic Asymmetric Mukaiyama Aldolizations of Propionaldehyde Enolsilanes
2021 StandoutNobel
A Catalytic Enantioselective Route to Hydroxy-Substituted Quaternary Carbon Centers: Resolution of Tertiary Aldols with a Catalytic Antibody
1999 StandoutNobel
(+)-Neomenthyl- and (−)-phenylmenthyl-substituted cyclopentadienyl and indenyl yttrocenes as catalysts in asymmetric hydroamination/cyclization of aminoalkenes (AHA)
2007
Highly Regioselective and Stereoselective Allylation of Aldehydes via Palladium-Catalyzed in Situ Hydrostannylation of Allenes
2000
C13 Nuclear Magnetic Resonance Spectroscopy. IV. Aniline, N,N-Dimethylaniline, and Their Methyl Derivatives: Steric Inhibition of Conjugation
1963 StandoutNobel
Selective transformation of organoboranes to grignard reagents by using pentane-1,5-di(magnesium bromide). Syntheses of the pheromones of southern armyworm moth and Douglas fir tussock moth
1979
The study of redox reactions of bisarenechromium complexes by the rotating disk electrode technique
1981
A simple entry into 1,3-diols from (R)-2,3-cyclohexylideneglyceraldehyde: synthesis of (−)-galantinic acid
2009
Total Syntheses of Amphidinolide X and Y
2006
Synthesis of contiguous cyclopropanes by palladium-catalyzed suzuki-type cross-coupling reactions
1997
Preparation of sodium borohydride by the reaction of MgH2 with dehydrated borax through ball milling at room temperature
2003
Complex Reducing Agents (CRA's)—Versatile, Novel Ways of Using Sodium Hydride in Organic Synthesis
1983
Tetrahedron report number 144
1983
Boron‐Phosphorus Compounds and Multiple Bonding
1990
Chemical Redox Agents for Organometallic Chemistry
1996 Standout
Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of 1-Halo-1-alkenes with 9-Alkyl-9-BBN Derivatives. A Direct Synthesis of α,β-Unsaturated Ketones
1991 StandoutNobel
Catalytic, Enantioselective Addition of Allylsilanes to Aldehydes: Generation of a Novel, Reactive TiIV Complex from TiF4
1996
A versatile synthesis of 9-BBN derivatives from organometallic reagents and 9-(triisopropylsilyl)thio-9-borabicyclo[3.3.1]nonane
2000
An example of the valorization of terpenes: The selective isomerization of 3-carene to 2-carene in the presence of silica supported nickel catalysts modified by tetrabutyl tin
1996
Practical synthesis of bis-homoallylic alcohols from dialdehydes or their acetals
2002
A New and Efficient Synthesis of the HMG‐CoA Reductase Inhibitor Pitavastatin
2007
Rhodium-catalyzed conjugate addition of aryl- and alkenyl-stannanes to α,β-unsaturated carbonyl compounds
2002
Synthesis of Functionalized Vinyl Boronates via Ruthenium-Catalyzed Olefin Cross-Metathesis and Subsequent Conversion to Vinyl Halides
2003 StandoutNobel
Works of Herbert C. Brown being referenced
The Critical Importance of Water in the Asymmetric Allylboration ofN-Trimethylsilylbenzaldimines withB-Allyldiisopinocampheylborane
1999
Hydroboration. XXXIX. 1,3,2-Benzodioxaborole (catecholborane) as a new hydroboration reagent for alkenes and alkynes. General synthesis of alkane- and alkeneboronic acids and esters via hydroboration. Directive effects in the hydroboration of alkenes and alkynes with catecholborane
1975 Standout
Conjugate addition-elimination in the reaction of B-1-alkenyl-9-borabicyclo[3.3.1]nonanes with 4-methoxy-3-buten-2-one. A convenient new route to conjugated dienones
1984
Facile reaction of organoboranes with methyl vinyl ketone. Convenient new ketone synthesis via hydroboration
1967 StandoutNobel
Organoboranes
1972 Standout
Carbonylation of thexyldialkylboranes. New general synthesis of ketones
1967 StandoutNobel
Convenient and general synthesis of acetylenes via the reaction of iodine with lithium l-alkynyltriorganoborates
1973 Standout
Improved procedures for the synthesis of diisopinocampheylborane of high optical purity
1984
The Oxygen-Induced Reactions of Organoboranes with 3,4-Epoxy-1-butynes. A New Route to Functionalized Allenes
1973 StandoutNobel
Reaction of ethyl haloacetates and .alpha.-bromo ketones with B-aryl-9-borabicyclo(3.3.1)nonanes under the influence of potassium tert-butoxide. A new convenient procedure for the .alpha.-arylation of ketones and esters
1969 Standout
Mono- and dialkylation of ethyl dihaloacetates by reaction with organoboranes under the influence of potassium tert-butoxide. Convenient procedures for the conversion of olefins into the .alpha.-halo alkanoic or dialkylacetic acid esters via hydroboration
1968 Standout
Molecular Addition Compounds. 10. Borane Adducts with N,N-Dialkylanilines for Hydroboration
1998
Synthesis of secondary alkyl bromides in the dark reaction of bromine with B-sec-alkyl-9-borabicyclo[3.3.1]nonanes. A convenient procedure for the anti-Markovnikov hydrobromination of internal olefins
1971 Standout
Organoboranes. 32. Homologation of alkylboronic esters with methoxy(phenylthio)methyllithium: regio- and stereocontrolled aldehyde synthesis from olefins via hydroboration
1983
An Exceptionally Rapid and Selective Deoxygenation of Aliphatic Sulfoxides to Sulfides under Mild Conditions with a New Reducing Agent, Dichloroborane
2002
Solvomercuration-demercuration. I. Oxymercuration-demercuration of representative olefins in an aqueous system. Mild procedure for the Markovnikov hydration of the carbon-carbon double bond
1970 Standout
B-(.gamma.-(Trimethylsilyl)propargyl)diisopinocampheylborane: A New, Highly Efficient Reagent for the Enantioselective Propargylboration of Aldehydes. Synthesis of Trimethylsilyl-Substituted and Parent .alpha.-Allenic Alcohols in High Optical Purity
1995
Hydroboration. XXVII. The hydroboration of 1-butenyl and related vinyl derivatives containing representative substituents. An unusually powerful directive influence of the ethoxy substituent
1968 Standout
Synthesis of both cis- and trans-vinyl bromides from 1-alkynes via hydroboration
1967 Standout
Chiral Synthesis via Organoboranes. 39. A Facile Synthesis of .gamma.-Substituted-.gamma.-butyrolactones in Exceptionally High Enantiomeric Purity
1994
Addition compounds of alkali-metal hydrides. 25. Facile reaction of borinic esters with lithium monoethoxyaluminohydride to form lithium dialkylborohydrides
1984
Chemical effects of steric strains
1956 Standout
The Reaction of 7-Norbornadienyl and 7-Dehydronorbornyl Derivatives with Borohydride under Solvolytic Conditions--Evidence for the Tricyclic Nature of the Corresponding Cations
1963 Standout
Selective reductions. XIV. Fast reaction of aryl bromides and iodides with lithium aluminum hydride in tetrahydrofuran. Simple convenient procedure for the hydrogenolysis of aryl bromides and iodides
1969 Standout
A Simple Preparation of Highly Active Platinum Metal Catalysts for Catalytic Hydrogenation
1962 Standout
Steric Effects in Displacement Reactions. III. The Base Strengths of Pyridine, 2,6-Lutidine and the Monoalkylpyridines
1955 Standout
Reactions of Diborane with Alkali Metal Hydrides and Their Addition Compounds. New Syntheses of Borohydrides. Sodium and Potassium Borohydrides1
1953 Standout
Steric Effects in Elimination Reactions. II. The Effect of the Steric Requirements of Alkyl Substituents upon the Extent and Direction of Unimolecular Elimination in the Solvolysis of Tertiary Alkyl Bromides
1955 Standout
Chiral synthesis via organoboranes. 15. Selective reductions. 42. Asymmetric reduction of representative prochiral ketones with potassium 9-O-(1,2:5,6-di-O-isopropylidene-.alpha.-D-glucofuranosyl)-9-boratabicyclo[3.3.1]nonane
1988
Reaction of alkenylboronic acids with iodine under the influence of base. Simple procedure for the stereospecific conversion of terminal alkynes into trans-1-alkenyl iodides via hydroboration
1973 Standout
Selective reductions. 53. Asymmetric reduction of α-fluoromethyl ketones with B-chlorodiisopinocampheylborane and B-isopinocampheyl-9-borabicyclo[3.3.1]nonane. Combined electronic and steric contributions to the enantiocontrol process
1994
Oxygen-induced reactions of organoboranes with acetylacetylene. Convenient new synthesis of .alpha.,.beta.-unsaturated ketones via hydroboration
1970 StandoutNobel
Fast base-induced reaction of .alpha.,.alpha.-dichloromethyl ether with organoboranes. New general route from organoboranes to the corresponding carbon structures
1973 Standout
Vinylic organoboranes. 11. A highly stereospecific and regiospecific synthesis of trisubstituted alkenes via organoboranes
1988
Chiral synthesis via organoboranes. 27. Remarkably rapid and exceptionally enantioselective (approaching 100% ee) allylboration of representative aldehydes at -100.degree. under new, salt-free conditions
1991
Molecular Addition Compounds. 15. Synthesis, Hydroboration, and Reduction Studies of New, Highly Reactive tert-Butyldialkylamine−Borane Adducts
1999
Addition compounds of alkali-metal hydrides. 25. Rapid reaction of boronic esters and acids with lithium aluminum hydride. A novel and quantitative synthesis of lithium monoorganylborohydrides
1984
THE REACTION OF TRIALKYLBORANES WITH ALKALINE SILVER NITRATE—A NEW GENERAL COUPLING REACTION
1961 Standout
Hydroboration. 50. Hydroboration of representative alkynes with 9-borabicyclo[3.3.1]nonane - a simple synthesis of versatile vinyl bora and gem-dibora intermediates
1979 Standout
Selective Reductions. I. The Partial Reduction of Tertiary Amides with Lithium Aluminum Hydride. A New Aldehyde Synthesis via the 1-Acylaziridines1,2
1961 Standout
Rates of Solvolysis of the Alkylphenyldimethylcarbinyl Chlorides. Evidence for the Importance of Carbon-to-Carbon Hyperconjugative Contributions in Alkyl Groups1,2
1957 Standout
Additions to bicyclic olefins. VIII. Electrophilic addition of trifluoroacetic acid and deuteriotrifluoroacetic acid to norbornene and related bicyclic olefins. Evidence for the capture of the the unsymmetrical (classical) 2-norbornyl cation
1975 Standout
Hydroboration Kinetics. 6.1 Hydroboration of Alkenes with 9-Borabicyclo[3.3.1]nonane Dimer and 9-Borabicyclo[3.3.1]nonane-Lewis Base Complexes in Various Solvents: An Interpretation of the Catalytic Effect of Ether Solvents on the Hydroboration Reaction
1982
LITHIUM DIETHOXYALUMINOHYDRIDE AS A SELECTIVE REDUCING AGENT—THE REDUCTION OF DIMETHYLAMIDES TO ALDEHYDES
1959 Standout
Sodium Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen1
1953 Standout
Chiral synthesis via organoboranes. 7. Diastereoselective and enantioselective synthesis of erythro- and threo-.beta.-methylhomoallyl alcohols via enantiomeric (Z)- and (E)-crotylboranes
1986
Organoboranes. 37. Synthesis and properties of (Z)-1-alkenylboronic esters
1984
New, Highly Active Metal Catalysts for the Hydrolysis of Borohydride
1962 Standout
Organoboranes. 31. A simple preparation of boronic esters from organolithium reagents and selected trialkoxyboranes
1983
Molecular addition compounds. 9. Effect of structure on the reactivities of representative borane-amine complexes in typical reactions such as hydrolysis, hydroboration, and reduction
1984
Organoboranes
1977 Standout
Product-rate correlation in acetolysis of threo-3-aryl-2-butyl brosylates. Supporting evidence for the existence of two discrete pathways
1970 Standout
Forty years of hydride reductions
1979 Standout
Organoboranes. 22. Light-induced reaction of bromine with alkylboronate esters. A convenient synthesis of .alpha.-bromoalkylboronate esters
1977 Standout
Hydroboration. 61. Diisopinocampheylborane of high optical purity. Improved preparation and asymmetric hydroboration of representative cis-disubstituted alkenes
1982
Lithium trisiamylborohydride. A new sterically hindered reagent for the reduction of cyclic ketones with exceptional stereoselectivity
1976 Standout
Efficient general asymmetric syntheses of 3-substituted 1(3H)-isobenzofuranones in very high enantiomeric excess
1996
Selective reductions. 37. Asymmetric reduction of prochiral ketones with B-(3-pinanyl)-9-borabicyclo[3.3.1]nonane
1985
ChemInform Abstract: Recent Advances in Asymmetric Reductions with B‐ Chlorodiisopinocampheylborane
1997
Thexylborane as a convenient reagent for the cyclic hydroboration of dienes. Stereospecific syntheses via cyclic hydroboration
1967 Standout
A simple, general synthesis of 1-alkynyldiisopropoxyboranes
1988
Lithium triethylborohydride. Exceptionally powerful nucleophile in displacement reactions with organic halides
1973 Standout
Selective reductions. 30. Effect of cation and solvent on the reactivity of saline borohydrides for reduction of carboxylic esters. Improved procedures for the conversion of esters to alcohols by metal borohydrides
1982
Chemical effects of steric strains—XIII
1957 Standout
Structural effects in solvolytic reactions. 42. Effect of increasing electron demand on the carbon-13 NMR shifts for substituted 9-methyl-9-anthracenium cations. Evidence for the unimportance of steric hindrance to coplanarity in causing anomalous carbon-13 NMR shifts
1982
Electrophilic Substituent Constants
1958 Standout
Selective reductions. 27. Reaction of alkyl halides with representative complex metal hydrides and metal hydrides. Comparison of various hydride reducing agents
1980
A simple conversion of [E]- into the isomeric [Z]-2-(1-substituted-1-alkenyl)-1,3,2-dioxaborinanes, providing a convenient stereospecific synthesis of both [E]- and [Z]-1,2-disubstituted vinyl bromides
1988
Reaction of representative alkynes with monochloroborane diethyl etherate. Simple convenient synthesis of dialkenylchloroboranes via hydroboration
1973 Standout
Catecholborane (1,3,2-benzodioxaorole) as a new, general monohydroboration reagent for alkynes. Convenient synthesis of alkeneboronic esters and acids from alkynes via hydroboration
1972 Standout
Solvomercuration-demercuration. V. Additions to bicyclic olefins. VI. Stereochemistry of the oxymercuration-demercuration of norbornene, 7,7-dimethylnorbornene, and related olefins
1973 Standout
An Interpretation of the Chemical Behavior of Five- and Six-membered Ring Compounds1
1954 Standout
Contrasting steric effects of the ketones and aldehydes in the reactions of the diisopinocampheyl enolborinates of methyl ketones with aldehydes
1996
Critical Role of Catalysts and Boranes for Controlling the Regioselectivity in the Rhodium-Catalyzed Hydroboration of Fluoroolefins
1999
The Reaction of Lithium Aluminum Hybride with Alcohols. Lithium Tri-t-butoxyaluminohydride as a New Selective Reducing Agent1,2
1958 Standout
Stereochemistry of the carbonylation, carbethoxymethylation, and .gamma.-propanalation reactions of organoboranes. Substitution reactions at carbon that proceed with retention of configuration
1969 Standout
Organoboranes
1972 Standout
Chiral synthesis via organoboranes. Part 32. Synthesis of B-(cycloalk-2-enyl)diisopinocampheylboranes of high enantiomeric purity via the asymmetric hydroboration of cycloalka-1,3-dienes. successful asymmetric allylborations of aldehydes with B-(cycloalk-2-enyl)diisopinocampheylboranes
1991
Vinylic organoboranes. 9. A general stereospecific synthesis of (Z)- and (E)-disubstituted alkenes via organoboranes
1988
ChemInform Abstract: Recent Advances in Borane Chemistry
2001
Stereospecific synthesis of 1,4-dienes by cross-coupling of allyl halides with alkenylcopper intermediates from alkenyldialkylboranes
1980
Vinylic organoboranes. 15. Mercuration of 2-alkenyl-1,3,2-benzodioxaboroles and boronic acids. A convenient stereospecific procedure for the conversion of alkynes into (E)-1-halo-1-alkenes via mercuric salts
1989
Asymmetric synthesis of γ-perfluoroalkyl(aryl) butyrolactones via organoboranes
2003
.beta.-Allyldiisopinocampheylborane: a remarkable reagent for the diastereoselective allylboration of .alpha.-substituted chiral aldehydes
1987
Hydroboration. V. A Study of Convenient New Preparative Procedures for the Hydroboration of Olefins
1960 Standout
Steric Effects in Elimination Reactions. V. The Importance of Steric Strains in the Extent and Direction of Unimolecular Elimination. The Role of Steric Strains in the Reactions of Highly Branched Carbonium Ions
1955 Standout
Reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with ethyl mono- and dihaloacetates under the influence of potassium tert-butoxide. A convenient procedure for the conversion of olefins into esters or .alpha.-halo esters via hydroboration
1969 Standout
Organoboranes. II. The Preparation and Properties of Alkyldiboranes Containing Bulky Alkyl Substituents
1962 Standout
Organoboranes for synthesis
1986
Cyclic hydroboration of 1,5-cyclooctadiene. A simple synthesis of 9-borabicyclo[3.3.1]nonane, an unusually stable dialkylborane
1968 Standout
Boranes in Organic Chemistry
1972 Standout
Chiral synthesis via organoboranes. 6. Asymmetric allylboration via chiral allyldialkylboranes. Synthesis of homoallylic alcohols with exceptionally high enantiomeric excess
1986
Chiral synthesis via organoboranes. 4. Synthetic utility of boronic esters of essentially 100% optical purity. Synthesis of homologated boronic acids and esters of very high enantiomeric purities
1985
Selective reductions. 24. Acyloxyboranes in the controlled reaction of carboxylic acids with borane-tetrahydrofuran. Acyloxyboranes as intermediates in the fast reduction of carboxylic acids by borane-tetrahydrofuran
1977 Standout
Highly enantioselective synthesis of alky- and aryl-substituted α-allenic alcohols
1996
Selective reductions. 46. Effect of the steric requirement at the 2-position of apopinene on chiral reductions. B-(iso-2-ethylapopinocampheyl)- and B-(iso-2-n-propylapopinocampheyl)-9-borabicyclo[3.3.1]nonanes as improved reagents for the chiral reduction of .alpha.,.beta.-acetylenic ketones and .alpha.-keto esters
1990
Asymmetric synthesis of 6-(2′,3′,4′,5′,6′-pentafluorophenyl)-δ-lactones via “allyl”boranes: application for the synthesis of fluorinated analog of key pharmacophore of statin drugs
2004
Selective reductions. 26. Lithium triethylborohydride as an exceptionally powerful and selective reducing agent in organic synthesis. Exploration of the reactions with selected organic compounds containing representative functional groups
1980
Organoboranes for Synthesis. 15. B-Allenyl-9-BBN: A Highly Regiospecific and Chemoselective Reagent for Allenylboration of Representative Carbonyl Compounds, Leading to Homopropargylic Alcohols and Amines
1995
Convenient stereospecific synthesis of terminal acetylenes via the treatment of lithium ethynyltrialkylborates with iodine
1974 Standout
The Rates of Mercuration of the Monoalkyl- and the Polymethylbenzenes. Calculation of Relative Reactivities for the Mercuration Reaction1,2
1955 Standout
Reaction of organoboranes with methoxycarbene, and reaction of dichloromethyl methyl ether with at-complex obtained from organoboranes and methyl lithium
1969 Standout
Lithium .beta.-isopinocamphenyl-9-borabicyclo[3.3.1]nonyl hydride. A new reagent for the asymmetric reduction of ketones with remarkable consistency
1977 Standout
Question of .sigma. bridging in the solvolysis of 2-norbornyl derivatives
1973 Standout
Rates and products of solvolysis of 2-methyl-2-norbornenyl and 2,5-dimethyl-2-norbornenyl p-nitrobenzoates. Evidence for increasing .pi.-participation with increasing electron demand
1975 Standout
Hydroboration. XI. The Hydroboration of Acetylenes—A Convenient Conversion of Internal Acetylenes into cis-Olefins and of Terminal Acetylenes into Aldehydes
1961 Standout
Strained Homomorphs.1 14. General Summary.
1953 Standout
Base-induced reaction of organoboranes with bromine. Convenient procedure for the anti-Markovnikov hydrobromination of terminal olefins via hydroboration-bromination
1970 Standout
Chiral synthesis via organoboranes. 35. Simple procedures for the efficient recycling of the terpenyl chiral auxiliaries and convenient isolation of the homoallylic alcohols in asymmetric allyl- and crotylboration of aldehydes
1992
The development of a simple general procedure for synthesis of pure enantiomers via chiral organoboranes
1988
Additions to bicyclic olefins. VII. Electrophilic additions of hydrogen chloride and deuterium chloride to norbornene, 2-methylenenorbornane, and related bicyclic olefins. Evidence for a carbonium ion process and the capture of unsymmetrical (classical) 2-norbornyl cations
1975 Standout
Selective Reductions. III. Further Studies of the Reaction of Alcohols with Lithium Aluminum Hydride as a Route to the Lithium Alkoxyaluminohydrides
1964 Standout
The Effect of Perchloric Acid on the Reactivity Ratio and Isomer Distribution in the Mercuration of Benzene and Toluene. Modification of the Activity and Selectivity of an Electrophilic Substituting Agent1,2
1955 Standout
Chiral synthesis via organoboranes. 12. Conversion of boronic esters of essentially 100% optical purity into monoalkylthexylboranes providing convenient synthetic routes to trans-olefins, cis-olefins, alkynes, and ketones of very high enantiomeric purities
1988
Organoboranes. 43. A more convenient, practical route to achieve the homologation of boronic esters
1986
Solvomercuration-demercuration. 8. Oxymercuration-demercuration of methoxy-, hydroxy-. and acetoxy-substituted alkenes
1981
Chiral synthesis via organoboranes. 21. Allyl- and crotylboration of .alpha.-chiral aldehydes with diisopinocampheylboron as the chiral auxiliary
1989
Rates and Isomer Distribution in the Mercuration of Benzene and Toluene. A Proposed Extension of the Quantitative Relationship Governing Isomer Distribution in Aromatic Substitution1
1955 Standout
Acyl peroxide and photochemical induced reactions of organoboranes with the inert .alpha.,.beta.-unsaturated carbonyl derivatives
1970 Standout
Facile reaction of B-alkylboracyclanes with .alpha.,.beta.-unsaturated carbonyl derivatives. Extension of the 1,4-addition reaction via organoboranes to highly branched secondary and tertiary alkyl groups
1971 StandoutNobel
Inhibition of the reaction of organoboranes with .alpha.,.beta.-unsaturated carbonyl derivatives by galvinoxyl. Evidence for a free-radical chain mechanism
1970 StandoutNobel
Organoboranes. 20. The facile allylboration of representative carbonyl compounds with B-allyl derivatives of 9-borabicyclo[3.3.1]nonane
1977 Standout
Hydroboration of mono-substituted allenes: A general synthetic route to the higher crotylboranes and anti-3-alkyl/aryl-4-hydroxy-1-alkenes
1997
Chiral synthesis via organoboranes. 25. B-(Z and E)-crotylbis-(2-isocaranyl)boranes as valuable reagents for the asymmetric crotylboration of aldehydes
1990
The Action of the Catalyst Couple Aluminum Chloride—Hydrogen Chloride on Toluene at Low Temperatures; the Nature of Friedel—Crafts Complexes1,2
1952 Standout
Solubility of Hydrogen Chloride at Low Temperatures. A Measure of the Basic Properties of Aromatic Nuclei; π- and σ-Complexes and Their Role in Aromatic Substitution1,2
1952 Standout
Oxygen-induced reaction of trialkylboranes with alkyl iodides. Facile coupling of benzylic and allylic iodides via triethylborane
1971 Standout
The Reaction of Methyl Iodide with o-Phenylenediamine; Homomorphs of o-Di-t-butylbenzene1,2
1953 Standout
Chiral synthesis via organoboranes. 36. Exceptionally enantioselective allylborations of representative heterocyclic aldehydes at -100 .degree.C under salt-free conditions
1992
Structural effects in solvolytic reactions. 26. A critical study of the effect of solvent on the exo:endo rate ratio in the solvolysis of 2-norbornyl derivatives. Evidence that the exo:endo rate ratio is not the result of K.DELTA./Ks processes
1978 Standout
Stereospecific conversion of alkenylboronic acids into alkenyl bromides with inversion of configuration. Striking differences in the stereochemistry of the replacement of the boronic acid substituent by bromine and iodine and its significance in terms of the reaction mechanism
1973 Standout
Hydroboration. XXXVI. Direct route to 9-borabicyclo[3.3.1]nonane via the cyclic hydroboration of 1,5-cyclooctadiene. 9-Borabicyclo[3.3.1]nonane as a uniquely selective reagent for the hydroboration of olefins
1974 Standout
Hydroboration of Terpenes. III. Isomerization of (+)-3-Carene to (+)-2-Carene. Hydroboration of (+)-2-Carene ([UNK]4-Carene). Nuclear Magnetic Resonance Spectra with Absolute Configurational and Conformational Assignments for the 2-Caranols and 2-Caranones
1967 Standout
Stereospecific synthesis of symmetrical conjugated dienes with alkenylcopper intermediates from alkenyldialkylboranes
1980
Asymmetric synthesis of goniothalamin, hexadecanolide, massoia lactone, and parasorbic acid via sequential allylboration–esterification ring-closing metathesis reactions
2000
Organoborane-carbon monoxide reactions. Synthesis of carbon structures
1969 Standout
Improved Procedures for the Generation of Diborane from Sodium Borohydride and Boron Trifluoride
2000
Organic syntheses via boranes
1975 Standout
Chiral synthesis via organoboranes. 2. Rapid reaction of boronic esters of very high optical purity with lithium aluminum hydride. Facile reaction of essentially optically pure borinic esters with lithium monoethoxyaluminohydride. A novel and quantitative synthesis of lithium monoalkyl- and dialkylborohydrides of essentially 100% optical purity
1985
Enantiomeric Z- and E-crotyldiisopinocampheylboranes. Synthesis in high optical purity of all four possible stereoisomers of .beta.-methylhomoallyl alcohols
1986
Highly enantioselective synthesis of (+)- and (−)-perfluoroalkyl(aryl) homoallyl alcohols
2000
Major effect of the leaving group in dialkylboron chlorides and triflates in controlling the stereospecific conversion of ketones into either [E]- or [Z]-enol borinates
1989
Rates of Solvolysis of the p-Nitrobenzoates of exo-endo Tertiary Norborneols. A Critical Examination of the exo-endo Rate Ratio as a Basis for the Postulated Nonclassical Structure of the Norbornyl Cation
1964 Standout
Pheromones via organoboranes. 3. Vinylic organoboranes. 10. Stereospecific synthesis of (Z)- and (E)-6- and -7-alken-1-ols via boracyclanes
1988
Structural effects in solvolytic reactions. 40. Carbon-13 nuclear magnetic resonance studies of carbocations. 8. Anomalous carbon-13 chemical shifts with increasing electron demand in the 2-aryl-2-norbornyl cations and related systems. Evidence that these anomalous shifts are not diagnostic for the onset of nonclassical .sigma. bridging
1982
Organoboranes
1977 Standout
Enolboration. 4. An examination of the effect of the leaving group (X) on the stereoselective enolboration of ketones with various R2BX/triethylamine. New reagents for the selective generation of either Z or E enol borinates from representative ketones
1993
Improved procedure for the asymmetric reduction of prochiral ketones by B-3-pinanyl-9-borabicyclo[3.3.1]nonane
1982
Reaction of carbon monoxide at atmospheric pressure with trialkylboranes in the presence of water. Synthesis of dialkyl ketones via hydroboration
1967 Standout
An asymmetric synthesis of the diastereomeric 1-(2-cyclohexenyl)-1-alkanols in high optical purity via a stereochemically stable allylic borane, B-2-cyclohexen-1-yldiisopinocampheylborane
1985
Dissociation of the Addition Compounds of Trimethylboron with Branched-Chain Primary Amines; the Effects of Chain-Branching1,2
1953 Standout
Chiral Oxazaborolidines as Catalysts for the Enantioselective Addition of Diethylzinc to Aldehydes
1989
Facile redistribution of trialkylboranes with trimethylene borate. A simple, general synthesis of alkaneboronic esters and acids from olefins via hydroboration
1970 Standout
Selective reductions. XII. Explorations in some representative applications of aluminum hydride for selective reductions
1968 Standout
Asymmetric reduction with chiral organoboranes based on .alpha.-pinene
1992
I-Strain as a Factor in the Chemistry of Ring Compounds1,2
1951 Standout
New Developments in the Chemistry of Diborane and the Borohydrides. I. General Summary1
1953 Standout
Homomorphs of 2,6-Dimethyl-t-butylbenzene1,2
1953 Standout
Reaction of organoboranes with ethyl bromoacetate under the influence of potassium tert-butoxide. A convenient procedure for the conversion of olefins into esters via hydroboration
1968 Standout
The boron approach to asymmetric synthesis
1991
Solvomercuration-demercuration of representative olefins in the presence of acetonitrile. Convenient procedure for the synthesis of amines
1969 Standout
Improved Procedure for Borane-Dimethyl Sulfide Reduction of Tertiary and Secondary Amides in the Presence of Boron Trifluoride Etherate
1981
Reaction of organoboranes with .alpha.-bromo ketones under the influence of potassium tert-butoxide in tetrahydrofuran. A new technique for the .alpha.-alkylation of ketones
1968 Standout
Reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with carbon monoxide in the presence of lithium trimethoxyaluminohydride. A convenient procedure for the conversion of olefins into aldehydes via hydroboration
1969 Standout
Chiral synthesis via organoboranes. 8. Synthetic utility of boronic esters of essentially 100% optical purity. Synthesis of primary amines of very high enantiomeric purities
1986
New Economical, Convenient Procedures for the Synthesis of Catecholborane
2000
Preparation and Reactions of 2,6-Di-t-butylpyridine and Related Hindered Bases. A Case of Steric Hindrance toward the Proton1,2
1966 Standout
Chiral Synthesis via Organoboranes. 46. An Efficient Preparation of Chiral Pyridino- and Thiopheno-18-crown-6 Ligands from Enantiomerically PureC2-Symmetric Pyridine- and Thiophenediols1
1999
Uranium(IV) Borohydride1
1953 Standout
3,3-Dimethylallyldiisopinocampheylborane: A novel reagent for chiral isoprenylation of aldehydes. Synthesis of (+)- and (−)-artemisia alcohol in exceptionally high enantiomeric purity
1984
THE REACTION OF TRIETHYLBORANE WITH OXIDES OF SILVER, GOLD AND PLATINUM—A NEW CONVENIENT ROUTE TO NOBLE METAL ALKYLS AND TO FREE RADICAL CHEMISTRY
1961 Standout
Solvomercuration-demercuration. IV. Monohydration of representative dienes via oxymercuration-demercuration
1972 Standout
Reaction of sodium aluminum hydride with selected organic compounds containing representative functional groups. Comparison of the reducing characteristics of lithium and sodium aluminum hydrides
1993
Hydroboration. VI. A Convenient Synthesis of the Alkane and Cycloalkane Boronic and Borinic Esters and Acids
1960 Standout
Steric Effects in Displacement Reactions. XI. The Heats of Reaction of Diborane with Pyridine Bases. Steric Strains in Homomorphs of o-t-Butyltoluene and Hemimellitene1
1956 Standout
Asymmetric allylboration for the synthesis of β-hydroxy-δ-lactone unit of statin drug analogs
2001
Homologation of representative boronic esters using in situ generated (halomethyl)lithiums: A comparative study
1994
Conjugate addition of B-alkenyl-9-borabicyclo[3.3.1]nonanes to methyl vinyl ketone. A convenient synthesis of .gamma.,.delta.-unsaturated ketones
1976 Standout
Carbonylation of mixed trialkylboranes containing substituents as a synthetic route to unsymmetrical ketones with such functional substituents. Route for the conversion of olefins, RCH:CH2, into the corresponding carboxylic acids, RCH2CH2CO2H
1967 Standout
Structural effects in solvolytic reactions. 24. Solvolysis of 1-cycloalkyl-1-aryl-1-ethyl p-nitrobenzoates. Effect of .alpha.-cycloalkyl groups in stabilizing an electron-deficient center as revealed by the tool of increasing electron demand
1978
Structural effects in solvolytic reactions. 27. Solvolysis of the exo- and endo-1,2-diphenyl-2-norbornyl and -1,2-dimethyl-2-norbornyl p-nitrobenzoates and chlorides. Evidence for the classical nature of 1,2-disubstituted tertiary 2-norbonyl cations and structure of the parent 2-norbornyl cation
1978 Standout
Addition compounds of alkali metal hydrides. 22. Convenient procedures for the preparation of lithium borohydride from sodium borohydride and borane-dimethyl sulfide in simple ether solvents
1982
Chiral synthesis via organoboranes. 13. A highly diastereoselective and enantioselective addition of [(Z)-.gamma.-alkoxyallyl]diisopinocampheylboranes to aldehydes
1988
The Reaction of Organoboranes with Chloramine and with Hydroxylamine-O-sulfonic Acid. A Convenient Synthesis of Amines from Olefins via Hydroboration
1964 Standout
New addition compounds of dialkylboranes and aluminum methoxide. New practical synthesis of dialkylboranes and of mixed trialkylboranes containing functional groups
1971 Standout
Solvomercuration-demercuration. 11. Alkoxymercuration-demercuration of representative alkenes in alcohol solvents with the mercuric salts acetate, trifluoroacetate, nitrate, and methanesulfonate
1984
1,3,2-Benzodioxaborole, a convenient monofunctional hydroborating agent. Simple new synthesis of alkaneboronic esters and acids from olefins via hydroboration
1971 Standout
Synthesis of methylenecycloalkanes from cycloalkenes via borane chemistry
1981
Preparative-scale synthesis of both antipodes of B-γ,γ-dimethylallyldiisopinocampheylborane: application for the synthesis of C1–C6 subunit of epothilone
2003
9-Borabicyclo[3.3.1]nonane as a highly selective reducing agent for the facile conversion of .alpha.,.beta.-unsaturated aldehydes and ketones to the corresponding allylic alcohols in the presence of other functional groups
1975 Standout
Solvomercuration-demercuration. III. Relative rates of oxymercuration of representative olefins in an aqueous tetrahydrofuran system
1972 Standout
Organoboranes
1988
Molecular addition compounds. 8. Carbon-13 and boron-11 NMR examination of .beta.-substituted derivatives of 9-borabicyclo[3.3.1]nonane and their pyridine complexes
1980
Substituent Constants for Aromatic Substitution1-3
1957 Standout
Stereochemistry of .beta. elimination in 2-norbornyl and 7,7-dimethyl-2-norbornyl tosylates. Evidence for the preferential attack by base on the exo-3-hydrogen in both systems
1970 Standout
Organoboranes. 23. Reaction of organolithium and Grignard reagents with .alpha.-bromoalkylboronate esters. A convenient, essentially quantitative procedure for the synthesis of tertiary alkyl-, benzyl-, propargyl-, and stereospecific allylboranes
1977 Standout
A new catalytic enantioselective reducing reagent system from (−)-α,α-diphenylpyrrolidinemethanol and 9-borabicyclo[3.3.1]nonane, especially effective for hindered and substituted aralkylketones
2002
Chiral synthesis via organoboranes. 30. Facile synthesis, by the Matteson asymmetric homologation procedure, of .alpha.-methyl boronic acids not available from asymmetric hydroboration and their conversion into the corresponding aldehydes, ketones, carboxylic acids, and amines of high enantiomeric purity
1991
A general and stereospecific synthesis of cis alkenes via stepwise hydroboration: a simple synthesis of muscalure, the sex pheromone of house fly (Musca domestica)
1982
Enolboration. 1. Dicyclohexylchloroborane/triethylamine as a convenient reagent for enolboration of ketones and other carbonyl derivatives
1992
Additions to bicyclic olefins. V. Effect of 7,7-dimethyl substituents on the stereochemistry and rates of cyclic additions to norbornenes
1973 Standout
A Quantitative Approach to the Ortho Effects of Halogen Substituents in Aromatic Systems1,2
1955 Standout
Organoboranes
1971 Standout
Studies in Stereochemistry. XXII. The Preparation and Reactions of Trimesitylborane. Evidence for the Non-localized Nature of the Odd Electron in Triarylborane Radical Ions and Related Free Radicals1
1957 Standout
Chiral synthesis via organoboranes. 14. Selective reductions. 41. Diisopinocampheylchloroborane, an exceptionally efficient chiral reducing agent
1988
Hydroboration. 57. Hydroboration with 9-borabicyclo[3.3.1]nonane of alkenes containing representative functional groups
1981
Facile reaction of dialkylchloroboranes with organic azides. Remarkable enhancement of reactivity relative to trialkylboranes
1972 Standout
An Interpretation of Meta Orientation in the Alkylation of Toluene. The Relative Reactivity and Isomer Distribution in the Chloromethylation and Mercuration of Benzene and Toluene1,2
1953 Standout
Ring enlargement of boracyclanes via sequential one carbon homologation. The first synthesis of boracyclanes in the strained medium ring range
1988
The Preparation of Other Borohydrides by Metathetical Reactions Utilizing the Alkali Metal Borohydrides1
1953 Standout
Organoboranes for synthesis - substitution with retention
1987
Hydroboration. 75. Directive effects in the hydroboration of vinyl and propenyl heterocycles with representative hydroborating agents
1986
Solvolysis of 9-aryl-9-pentacyclo[4.3.0.02,4.03,8.05,7]nonyl p-nitrobenzoates. Unambiguous evidence for the presence of carbon participation by the application of the tool of increasing electron demand
1977 Standout
Oxygen-induced reactions of organoboranes with the inert .alpha.,.beta.-unsaturated carbonyl derivatives. Convenient new aldehyde and ketone synthesis via hydroboration
1970 Standout
Reaction of organoboranes with bromoacetone under the influence of potassium 2,6-Di-tert-butylphenoxide. A convenient procedure for the conversion of olefins into methyl ketones via hydroboration
1969 Standout
Relationship between the structure and enantioselectivity in the asymmetric reduction of 2′,6′-disubstituted acetophenones with DIP-ChlorideTM. An ab initio study
2004
The dimesitylboron group in organic chemistry. 6 Hydroborations with dimesitylborane.
1983
Chiral synthesis via organoboranes. 24. B-allylbis(2-isocaranyl)borane as a superior reagent for the asymmetric allylboration of aldehydes
1990
An Efficient Synthesis of N-Unsubstituted Imines as Organoborane Adducts Stable at Room Temperature: New Promising Intermediates for Synthesis
2000
Potassium 9-O-(1,2:5,6-di-O-isopropylidene-.alpha.-D-glucofuranose)-9-boratabicyclo[3.3.1]nonane. A new, effective chiral borohydride reagent
1986
The energy of the transition states and the intermediate cation in the ionization of 2-norbornyl derivatives. Where is the nonclassical stabilization energy?
1983
Hydroboration. XXVIII. The hydroboration of 3-cyclopentenyl derivatives containing representative substituents. Directive effects and the elimination reaction in a cyclic system
1968 Standout
Hydroboration. 86. Convenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple synthesis of either (Z)- or (E)-alkenes
1991
Hydroboration. 83. Asymmetric hydroboration of representative cis disubstituted and heterocyclic olefins with dicaranylboranes of high enantiomeric purity
1988
A Stereospecific Synthesis of Alicyclic and Bicyclic Amines via Hydroboration
1966 Standout
Organoboranes. 30. Convenient procedures for the synthesis of alkyl- and alkenylboronic acids and esters
1983
Selective Reductions. VIII. The Stereochemistry of Reduction of Cyclic and Bicyclic Ketones by the Alkoxy-Substituted Lithium Aluminum Hydrides1
1965 Standout
Notes - Generalization Dealing with Chemical Behavior or 5- and 6- Membered Ring Compounds
1957 Standout
Conjugate addition of B-1-alkynyl-9-borabicyclo[3.3.1]-nonanes to .alpha.,.beta.-unsaturated ketones. A convenient synthesis of .gamma.,.delta.-acetylenic ketones
1977 Standout
Solvolysis of 2-aryl-2-bicyclo[2.1.1]hexyl p-nitrobenzoates. Evidence for the absence of .sigma.-participation by the application of the tool of increasing electron demand
1977 Standout
Selective reductions. 52. Efficient asymmetric reduction of α-acetylenic α′-fluoroalkyl ketones with either B-chlorodiisopinocampheylborane or B-isopinocampheyl-9-borabicyclo[3.3.1]nonane in high enantiomeric purity. The influence of fluoro groups in such reductions
1994
Lithium tri-sec-butylborohydride. New reagent for the reduction of cyclic and bicyclic ketones with super stereoselectivity. Remarkably simple and practical procedure for the conversion of ketones to alcohols in exceptionally high stereochemical purity
1972 Standout
Light-induced reaction of bromine with trialkylboranes in the presence of water. A remarkably simple procedure for the union of two or three alkyl groups to produce highly substituted alcohols
1971 Standout
Organoboranes. 46. New procedures for the homologation of boronic esters. A critical examination of the available procedures to achieve convenient homologation of boronic esters
1986
A new convenient approach to the preparation of Z-1-alkenylboronates by the cis-Hydrogenation of 1-Alkynyldiisopropoxyboranes
1988
A facile synthesis of chiral ω-allyl- and ω-n-propyllactones via asymmetric allylboration of formyl esters with B-allyldiisopinocampheylborane
1999
A Study of Solvents for Sodium Borohydride and the Effect of Solvent and the Metal Ion on Borohydride Reductions1
1955 Standout
Structural effects in solvolytic reactions; carbon-13 NMR studies of carbocations † : Effect of increasing electron demand on the carbon-13 NMR shifts in substituted tert -cumyl and 1-aryl-1-cyclopentyl carbocations—correlation of the data by a new set of substituent constants, σ C+
1980
9-Allenyl-9-BBN: A new reagent for the efficient allenylboration of carbonyl compounds producing the homopropargylic alcohols in high purity and yield
1993
New four-carbon-atom homologation involving the free-radical chain reaction of 1,3-butadiene monoxide with organoboranes. Synthesis of 4-alkyl-2-buten-1-ols from olefins via hydroboration
1971 StandoutNobel
Reaction of aluminum hydride-triethylamine complex with selected organic compounds containing representative functional groups
1993
Facile reaction of alkyl- and aryldichloroboranes with organic azides. General stereospecific synthesis of secondary amines
1973 Standout
Reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with carbon monoxide in the presence of lithium tri-t-butoxyaluminohydride. The conversion of functionally substituted olefins into aldehydes via hydroboration
1969 Standout
Reaction of B-methoxydialkylboranes with lithium aluminum hydride in the presence of olefins. A new and general synthesis of acyclic and cyclic mixed trialkylboranes and their conversion into the corresponding trialkylcarbinols via carbonylation-oxidation
1970 StandoutNobel
The Effect of Ring Size on the Rate of Solvolysis of the 1-Chloro-1-methylcycloalkanes1,2
1952 Standout
An Extended Table of Hammett Substitutent Constants Based on the Ionization of Substituted Benzoic Acids
1958 Standout
Chiral synthesis via organoboranes. 38. Selective reductions. 48. Asymmetric reduction of trifluoromethyl ketones by B-chlorodiisopinocampheylborane in high enantiomeric purity
1993
Hydroboration of Terpenes. IV. Hydroboration of (+)-3-Carene ([UNK]3-Carene). Configuration Assignments for the 4-Caranols and 4-Caranones. An Unusual Stability of 4-Isocaranone with a cis Relationship of the Methyl and gem-Dimethyl Groups
1967 Standout
Organoboranes for synthesis. 6.
1987
Organoboranes
1979 Standout
Stereospecific synthesis of conjugated enynes from alkenyldialkylboranes via alkenylcopper intermediates
1981
2,6-DI-BUTYLPYRIDINE—AN UNUSUAL PYRIDINE BASE
1953 Standout
Addition Compounds of Alkali Metal Hydrides. Sodium Trimethoxyborohydride and Related Compounds1
1953 Standout
Unusually high exo-endo rate ratio in the solvolysis of the 2,2,6-trimethyl-2-norbornyl p-nitrobenzoates. Evidence for steric effects as a major factor in the exo-endo rate ratios of norbornyl derivatives
1968 Standout
9-Borabicyclo[3.3.1]nonane as a convenient selective hydroborating agent
1968 Standout
Organoboranes. 53. A high-field variable-temperature proton and boron-11 NMR study of the effects of solvent and structure on reactivity in allylboration
1990
Vinylic organoboranes. 7. Stereoselective synthesis of (E)-(1-substituted-1-alkenyl)boronic esters by the nucleophilic substitution of (Z)-(1-bromo-1-alkenyl)boronic esters with organolithium or Grignard reagents. Isolation and oxidation to ketones
1986
Organoboranes. X. Fast reaction of organoboranes with mercuric acetate. Convenient procedure for the conversion of terminal olefins into alkylmercuric salts via hydroboration-mercuration
1970 Standout
Organoboranes
1974 Standout
A General Multi-Carbon Homologation of OlefinsviaHydroboration-Carbonylation
1972 StandoutNobel
Diborane as a Mild Reducing Agent for the Conversion of Primary, Secondary, and Tertiary Amides into the Corresponding Amines
1964 Standout
Selective reductions. 28. The fast reaction of lithium aluminum hydride with alkyl halides in tetrahydrofuran. A reappraisal of the scope of the reaction
1982
Improved Arc Process for the Preparation of Diborane. Purification of Diborane1
1953 Standout
Hydroboration. XVII. An Examination of Several Representative Dialkylboranes as Selective Hydroborating Agents
1963 Standout
An efficient preparation of optically pure C2-symmetric aromatic diols by the asymmetric reduction of diacylaromatic compounds with B-chlorodiisopinocampheylborane
1996
Reaction of representative organic azides with triethylborane. New route to secondary amines
1971 Standout
An efficient enantioselective total synthesis of a trifluoromethyl analog of blastmycinolactol
2004
Organoboranes for synthesis. 1
1986
A Grignard-like addition of B-alkenyl-9-borabicyclo[3.3.1]nonanes to aldehydes. A novel synthesis of allylic alcohols with defined stereochemistry
1977 Standout
Hydroboration. XXI. The Reaction of Unsaturated Alkyl Chlorides and p-Toluenesulfonates with Diborane and Disiamylborane
1964 Standout
Facile double migration in the protonation of lithium alkynyltrialkylborates with acid
1975 Standout
Conjugate addition-elimination in the reaction of .beta.-1-alkynyl-9-borabicyclo[3.3.1]nonanes with 4-methoxy-3-buten-2-one and related derivatives. A convenient new route to conjugated enynones
1977 Standout
Selective reductions. XVIII. Fast reaction of primary, secondary, and tertiary amides with diborane. Simple, convenient procedure for the conversion of amides to the corresponding amines
1973 Standout
Explorations in the nonclassical ion area
1976 Standout
The Nonclassical Ion Problem
1967 Standout
[(E)-.gamma.-(1,3,2-Dioxaborinanyl)allyl]diisopinocampheylborane, an Exceptional Reagent for the Stereo- and Enantioselective Synthesis of anti- 1-Alkene-3,4-diols via a Masked .alpha.-Hydroxyallylboration
1995
Reaction of 2-alkenyl-1,3,2-benzodioxaboroles with mercuric acetate. Convenient stereospecific procedure for the conversion of alkynes into alkenylmercuric salts
1972 Standout
A fast reaction of organoboranes with iodine under the influence of base. A convenient procedure for the conversion of terminal olefins into primary iodides via hydroboration-iodination
1968 Standout
Chiral Synthesis via Organoboranes. 40. Selective Reductions. 55. A Simple One-Pot Synthesis of the Enantiomers of Trifluoromethyloxirane. A General Synthesis in High Optical Purities of .alpha.-Trifluoromethyl Secondary Alcohols via the Ring-Cleavage Reactions of the Epoxide
1995
Formation of alkyl bromides in the dark reaction of bromine with organoboranes. Evidence for an unusual pathway involving the prior bromination of the organoborane
1970 Standout
Solvomercuration-demercuration of representative olefins in the presence of alcohols. Convenient procedures for the synthesis of ethers
1969 Standout
Organoboranes. 49. An examination of convenient procedures for the generation of borane and monoalkyl- and dialkylboranes from lithium borohydride and monoalkyl- and dialkylborohydrides
1986
Stoichiometrically controlled reaction of organoboranes with oxygen under very mild conditions to achieve essentially quantitative conversion into alcohols
1971 Standout
Reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with .alpha.-bromo ketones under the influence of potassium tert-butoxide. A convenient procedure for the .alpha.-alkylation of ketones
1969 Standout
A novel route to 1,3-dienyl-2-boronic esters providing simple syntheses of conjugated [E,E]-dienes and conjugated [E]-alkenones.
1991
Versatile α-pinene-based borane reagents for asymmetric syntheses
1995
Reaction of the cyclic organoboranes from dienes with methyl vinyl ketone. A convenient synthesis of ω-hydroxy-ketones from dienes via hydroboration
1969 Nobel
Molecular addition compounds. 3. Redistribution of borane-methyl sulfide with boron trichloride-methyl sulfide and boron tribromide-methyl sulfide as convenient routes to the corresponding haloborane-methyl sulfides
1977 Standout
Hydroboration. 51. Hydroboration of representative allenes with 9-borabicyclo[3.3.1]nonane. An exceptional directive effect providing a direct synthesis of B-allyl-9-borabicyclo[3.3.1]nonane derivatives
1979 Standout
Organoboranes. VII. The Displacement Reaction with Organoboranes Derived from the Hydroboration of Cyclic and Bicyclic Olefins. Conversion of Endocyclic to Exocyclic Double Bonds
1967 Standout
B-Allyldiisocaranylborane: a new, remarkable enantioselective allylborating agent for prochiral aldehydes. Synthesis of homoallylic alcohols approaching 100% enantiomeric purities
1984
Organic Syntheses via Free‐Radical Displacement Reactions of Organoboranes
1972 Standout
Solvomercuration-demercuration. 9. Oxymercuration-demercuration of chloro-, epoxy-, and thiomethyl-substituted alkenes
1981
Asymmetric carbon-carbon bond formation via .beta.-allyldiisopinocampheylborane. Simple synthesis of secondary homoallylic alcohols with excellent enantiomeric purities
1983
The Preparation of Sodium Borohydride by the High Temperature Reaction of Sodium Hydride with Borate Esters1
1953 Standout
Molecular Addition Compounds. 16. New, Highly Reactive Borane Adducts with N,N-Dialkyl-tert-alkylamines for Hydroboration
2000
Chiral synthesis via organoboranes. 34. Selective reductions. 47. Asymmetric reduction of hindered .alpha.,.beta.-acetylenic ketones with B-chlorodiisopinocampheylborane to propargylic alcohols of very high enantiomeric excess. Improved workup procedure for the isolation of product alcohols
1992
Convenient Procedure for the Synthesis of (E)-1-Bromo-1-alkenes and (Z)-1-Iodo-1-alkenes
1984
Hydroboration. VIII. Bis-3-methyl-2-butylborane as a Selective Reagent for the Hydroboration of Alkenes and Dienes
1961 Standout
Reaction of lithium ethynyl- and ethenyltrialkylborates with acid. Valuable route to the Markovnikov alkenyl- and alkylboranes
1975 Standout
The Reaction of Sodium Borohydride with Nickel Acetate in Aqueous Solution--A Convenient Synthesis of an Active Nickel Hydrogenation Catalyst of Low Isomerizing Tendency
1963 Standout
Solvolysis of the 2-[3,5-bis(trifluoromethyl)phenyl]-2-norbornyl p-nitrobenzoates and the 1-arylcyclopentyl p-nitrobenzoates. Failure of a further increase in electron demand to alter the exo:endo rate ratio
1975 Standout
Facile reduction of alkyl tosylates with lithium triethylborohydride. An advantageous procedure for the deoxygenation of cyclic and acyclic alcohols
1976 Standout
A New Powerful Reducing Agent—Sodium Borohydride in the Presence of Aluminum Chloride and Other Polyvalent Metal Halides1,2
1956 Standout