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2006
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2000
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1998
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1998
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2007 StandoutNobel
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2012
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1996
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2004
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2009
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2013
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1993
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2006
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2015 Standout
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2000
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2005
Weaving Nanoscale Cloth through Electrostatic Templating
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Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
2010 Standout
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2008
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1982
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2008
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1991 StandoutNobel
[γ‐1,2‐H2SiV2W10O40] Immobilized on Surface‐Modified SiO2 as a Heterogeneous Catalyst for Liquid‐Phase Oxidation with H2O2
2006
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1997
Synthesis and spectroscopic characterization of 1,2-divanadium(v)-substituted α-Dawson polyoxotungstate-based 1 ∶ 1-type Cp*Rh2+ complex showing three different supporting sites of the Cp*Rh2+ group
2002
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2013
The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds
2004 Standout
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2002
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2000
Efficacy of heteropolyanions against rabies virus infection in mice
1986
Chemie der Polyoxometallate: Aktuelle Variationen über ein altes Thema mit interdisziplinären Bezügen
1991
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2001
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2007
Electrochemical Properties of Polyoxometalates as Electrocatalysts
1998 Standout
Correlation between structure of polyoxotungstates and their inhibitory activity on polymerases
1983
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2004
Dilacunary Decatungstates Functionalized by Organometallic Ruthenium(II), [{Ru(C6H6)(H2O)}{Ru(C6H6)}(γ-XW10O36)]4- (X = Si, Ge)
2006
Polyoxometalates in Medicine
1998 Standout
Alternative Synthetic Methods through New Developments in Catalysis by Gold
2008 Standout
Octa- and Nonanuclear Nickel(II) Polyoxometalate Clusters: Synthesis and Electrochemical and Magnetic Characterizations
2008
Brønsted Acidity in Metal–Organic Frameworks
2015 StandoutNobel
The Bis-Phenyltin-Substituted, Lone-Pair-Containing Tungstoarsenate [(C6H5Sn)2As2W19O67(H2O)]8-
2004
Theoretical Study of the Relative Stabilities of the α/β3-[XW11O39]m− Lacunary Polyoxometalates (X = P, Si)
2008
Organic/Inorganic Supramolecular Assemblies and Synergy between Physical Properties
1997
Organometallic−Polyoxometalate Hybrid Compounds: Metallosalen Compounds Modified by Keggin Type Polyoxometalates
2003
Activation of C−H Bonds by Metal Complexes
1997 Standout
Remarkable Structure Dependence of Intrinsic Catalytic Activity for Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-Substituted Silicotungstates
1999
Towards Organization of Molecular Machines at Interfaces: Langmuir Films and Langmuir–Blodgett Multilayers of an Acid–Base Switchable Rotaxane
2006 StandoutNobel
Synthesis and Characterization of Copper-, Zinc-, Manganese-, and Cobalt-Substituted Dimeric Heteropolyanions, [(α-XW9O33)2M3(H2O)3]n- (n = 12, X = AsIII, SbIII, M = Cu2+, Zn2+; n = 10, X = SeIV, TeIV, M = Cu2+) and [(α-AsW9O33)2WO(H2O)M2(H2O)2]10- (M = Zn2+, Mn2+, Co2+)
2001
Rate-limiting one-electron transfer in the oxidation of NADH by polyoxometalates
1995
Inorganic−Metalorganic Hybrids Based on Copper(II)-Monosubstituted Keggin Polyanions and Dinuclear Copper(II)−Oxalate Complexes. Synthesis, X-ray Structural Characterization, and Magnetic Properties
2005
Inherent Proton Conduction in a 2D Coordination Framework
2012 StandoutNobel
Polyoxoanions Derived from [γ-SiO4W10O32]8--Containing Oxo-Centered Dinuclear Chromium(III) Carboxylato Complexes: Synthesis and Single-Crystal Structural Determination of [γ-SiO4W10O32(OH)Cr2(OOCCH3)2(OH2)2]5-
1996
Polyoxometalate-Based Molecular Materials
1998 Standout
Phenyltin-Substituted 9-Tungstogermanate and Comparison with Its Tungstosilicate Analogue
2008
Lanthanide-Based Luminescent Hybrid Materials
2009 Standout
Trilacunary Heteropolytungstates Functionalized by Organometallic Ruthenium(II), [(RuC6H6)2XW9O34]6- (X = Si, Ge)
2005
Acid–base catalyses by dimeric disilicoicosatungstates and divacant γ-Keggin-type silicodecatungstate parent: Reactivity of the polyoxometalate compounds controlled by step-by-step protonation of lacunary W O sites
2006
Nanocluster crystals of lacunary polyoxometalates as structure-design-flexible, inorganic nonlinear materials
2001
Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives
2008
The Halogen Bond
2016 Standout
Polyoxometalates: Very Large ClustersNanoscale Magnets
1998
Synthesis and Catalysis of Di- and Tetranuclear Metal Sandwich-Type Silicotungstates [(γ-SiW10O36)2M2(μ-OH)2]10−and [(γ-SiW10O36)2M4(μ4-O)(μ-OH)6]8−(M = Zr or Hf)
2008
The True Nature of the Di-iron(III) γ-Keggin Structure in Water: Catalytic Aerobic Oxidation and Chemistry of an Unsymmetrical Trimer
2006
Organic–inorganic hybrids: From magnetic perovskite metal(II) halides to multifunctional metal(II) phosphonates
2014
Lewis Acids: From Conventional Homogeneous to Green Homogeneous and Heterogeneous Catalysis
2003
Sandwich-Type Zinc-Containing Polyoxometalates with a Hexaprismane Core [{Zn2W(O)O3}2]4+Synthesized by Thermally Induced Isomerization of a Metastable Polyoxometalate
2010
Aerobic oxidation of cis-cyclooctene by iron-substituted polyoxotungstates: Evidence for a metal initiated auto-oxidation mechanism
2006
The Effect of Heteropoly Acids on Stability of PFSA PEMs under Fuel Cell Operation
2007
13-Tungstoborate Stabilized by an Organostannoxane Hexamer
2007
Synthesis and Characterization of Zr(IV) Polyoxotungstates as Molecular Analogues of Zirconia-Supported Tungsten Catalysts
2004
Preparation of Monodispersed Nanoparticles by Electrostatic Assembly of Keggin-Type Polyoxometalates and 1,4,7-Triazacyclononane-Based Transition-Metal Complexes
2007
Two Hexanickel‐Substituted Keggin‐Type Germanotungstates
2008
Synthesis and characterization of the highest connected 3D Wells-Dawson POM/TMC hybrid
2008
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
2010 Standout
An All-Inorganic, Polyoxometalate-Based Catechol Dioxygenase That Exhibits >100 000 Catalytic Turnovers
1999
Chemical Structures and Performance of Perovskite Oxides
2001 Standout
Design of Novel Inorganic−Organic Hybrid Materials Based on Iron-Chloranilate Mononuclear Complexes: Characteristics of Hydrogen-Bond-Supported Layers toward the Intercalation of Guests
2002 StandoutNobel
A cyclic voltammetric study of mangano(II)undecatungstosilicate: an illustrative example of the reduction, protonation and disproportionation pathways of transition metal substituted heteropolytungstates in aqueous solution
1997
Optically Active Tripodal Dendritic Polyoxometalates: Synthesis, Characterization and Their Use in Asymmetric Sulfide Oxidation with Hydrogen Peroxide
2011
Synthesis and Reversible Transformation of Cun-Bridged (n= 1, 2, or 4) Silicodecatungstate Dimers
2012
Mechanical Alloying of Metal–Organic Frameworks
2017 StandoutNobel
Effective Dawson type polyoxometallate catalysts for methanol oxidation
2012
Ion Conductivity and Transport by Porous Coordination Polymers and Metal–Organic Frameworks
2013 StandoutNobel
COOH-terminal sequence of the cellular prion protein directs subcellular trafficking and controls conversion into the scrapie isoform
1997 StandoutNobel
1D‐Polyoxometalate‐Based Composite Compounds − Design, Synthesis, Crystal Structures, and Properties of [{Ln(NMP)6}(PMo12O40)]n (Ln = La, Ce, Pr; NMP = N‐methyl‐2‐pyrrolidone)
2003
Investigation of the Pronounced Medium Effects Observed in the Voltammetry of the Highly Charged Lacunary Anions [α-SiW11O39]8-and [α-PW11O39]7-
2006
{Ta12}/{Ta16} Cluster-Containing Polytantalotungstates with Remarkable Photocatalytic H2Evolution Activity
2012
Reversible Deprotonation and Protonation Behaviors of a Tetra-Protonated γ-Keggin Silicodecatungstate
2012
Investigation of the manganese-substituted α-Keggin-heteropolyanion K6SiW11O39Mn(H2O) by cyclic voltammetry and its application as oxidation catalyst
1996
Coordination chemistry of soluble metal oxides of molybdenum and vanadium
1992
Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates
2005
Metal–Organic Frameworks for Heterogeneous Basic Catalysis
2017 Standout
Stabilization and immobilization of polyoxometalates in porous coordination polymers through host–guest interactions
2009
The antiviral compound HPA-23 can prevent scrapie when administered at the time of infection
1983
Polyoxometalate-based homogeneous catalysis of electrode reactions: Recent achievements
2006
Organic−Inorganic Hybrids Based on Polyoxometalates. 5.1Synthesis and Structural Characterization of Bis(organophosphoryl)decatungstosilicates [γ-SiW10O36((RPO)2]4-
1999
Photooxidation in Water by New Hybrid Molecular Photocatalysts Integrating an Organic Sensitizer with a Polyoxometalate Core
2004
Proton-Coupled Electron Transfer
2012 Standout
High-Valent Manganese in Polyoxotungstates. 3. Dimanganese Complexes of γ-Keggin Anions
1996
Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers
2007 StandoutNobel
Organophosphoryl derivatives of trivacant tungstophosphates of general formula α-A-[PW9O34(RPO)2]5−: synthesis and structure determination by multinuclear magnetic resonance spectroscopy (31P, 183W) ‡
1998
Spontaneous Neurodegeneration in Transgenic Mice with Mutant Prion Protein
1990 StandoutScienceNobel
Structure and Magnetic Properties of Pyridine Coordinated Sandwich‐type Heteropolyanion {[Na(H2O)2]3[Ni(C5H5N)]3(AsW9O33)2}9−
2005
Advances in the synthesis of polyoxometalates and in the study of heteropolyacids
1995
Combination of Lacunary Polyoxometalates and High-Nuclear Transition Metal Clusters under Hydrothermal Conditions. 3. Structure and Characterization of [Cu(enMe)2]2{[Cu(enMe)2(H2O)]2[Cu6(enMe)2(B-a-SiW9O34)2]}·4H2O
2007
Methoxide of an Anderson-Type Polyoxometalate and Its Conversion to a New Type of Species, [IMo9O32(OH)(OH2)3]4-
2005
Modification of Tetranuclear Zirconium‐Substituted Polyoxometalates – Syntheses, Structures, and Peroxidase‐Like Catalytic Activities
2012
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
2010 Standout
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
2016 Standout
Ultra-low-? polyimide hybrid films via copolymerization of polyimide and polyoxometalates
2007
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
2011 Standout
Works of Gilbert Hervé being referenced
Dinuclear vanadium and tetranuclear iron complexes obtained with the open Wells–Dawson [Si2W18O66]16– tungstosilicate
2006
Modification of the structural and redox properties of cytochrome c by heteropolytungstate binding
1987
The Heteropolytungstate Core {BW13O46}11− Derived as Monomer, Dimer, and Trimer
2007
Dawson Type Heteropolyanions. 3. Syntheses and31P,51V, and183W NMR Structural Investigation of Octadeca(molybdo−tungsto−vanado)diphosphates Related to the [H2P2W12O48]12-Anion
2004
Synthesis, structure, and phosphorus-31 and tungsten-183 NMR spectra of tungstophosphate, P4W14O5812-
1988
Synthesis and structure of the novel anion [AsMo6O15(OH)3(SO4)3]6–, first example of a reduced molybdo-sulphate cluster
2000
Cation-Directed Synthesis of Tungstosilicates. 1. Syntheses and Structures of K10A-α-[SiW9O34]·24H2O, of the Sandwich-Type Complex K10.75[Co(H2O)6]0.5[Co(H2O)4Cl]0.25A-α-[K2{Co(H2O)2}3(SiW9O34)2]·32H2O and of Cs15[K(SiW11O39)2]·39H2O
2003
Synthesis, molecular structure and chemical properties of a new tungstosilicate with an open Wells-Dawson structure, alpha-[Si2W18O66]16-.
2003
Study of ammonium, mixed ammonium–cesium and cesium salts derived from (NH4)5[PMo11VIVO40] as isobutyric acid oxidation catalysts
2000
A Novel Dimeric Ni-Substituted β-Keggin Silicotungstate: Structure and Magnetic Properties of K12[{β-SiNi2W10O36(OH)2(H2O)}2]·20H2O
1999
[Ag6(PMo10V2O40)](CH3COO)·8H2O: A 3D Macrocationic Polyoxometallic Keggin Complex
2004
Polyoxometalates catalyst materials: X-ray thermal stability study of phosphorus-containing heteropolyacids H3 +xPM12 –xVxO40·13–14H2O (M = Mo,W; x= 0–1)
1992
Structural Characterization and Magnetic Properties of Sandwich-Type Tungstoarsenate Complexes. Study of a Mixed-Valent VIV2/VV Heteropolyanion
2000
About the Keggin Isomers: Crystal Structure of [N(C4H9)4]4-γ-[SiW12O40], the γ-Isomer of the Keggin Ion. Synthesis and183W NMR Characterization of the Mixed γ-[SiMo2W10O40]n-(n= 4 or 6)
2001
In Vivo Inhibition of Murine Leukemia and Sarcoma Viruses by the Heteropolyanion 5-Tungsto-2-antimoniate2
1974
Cation-Directed Synthesis of Tungstosilicates. 2. Synthesis, Structure, and Characterization of the Open Wells−Dawson Anion α-[{K(H2O)2}(Si2W18O66)]15-and Its Transiton-Metal Derivatives [{M(H2O)}(μ-H2O)2K(Si2W18O66)]13-and [{M(H2O)}(μ-H2O)2K{M(H2O)4}(Si2W18O66)]11-
2005
Synthesis and structure of potassium octatungstodiarsenate(III)
1985
Synthesis, Structural Characterization, and Oxidation−Reduction Behavior of the γ-Isomer of the Dodecatungstosilicate Anion
1996
Electrochemical Properties and ESR Characterization of Mixed Valence α-[XMo3-xVxW9O40]n- Heteropolyanions with X = PV and SiIV, x = 1, 2, or 3
1996
Syntheses and multinuclear NMR characterizations of .alpha.-[SiMo2W9O39]8- and .alpha.-[SiMo3-xVxW9O40](4+x)- (x = 1, 2) heteropolyoxometalates
1992
Relationship between structures and properties of undecatungstosilicate isomers and of some derived compounds
1977
Square pyramidal complexes of divalent cations of the first transition row with the 20-tungsto-2-arsenate(III): synthesis, visible and E.S.R. spectra
1983
Synthesis and Structure of the Polyoxoanion [Si2W23O77(OH)]9-
1997
Disubstituted tungstosilicates. 1. Synthesis, stability, and structure of the lacunary precursor polyanion of a tungstosilicate .gamma.-SiW10O368-
1986
Study of .alpha.- and .beta.-enneatungstosilicates and -germanates
1977
Syntheses and Structures of the Tungstoborate Anions
1997
Disubstituted tungstosilicates. 2. .gamma.- and .beta.-isomers of tungstovanadosilicate, [SiV2W10O40]6-: syntheses and structure determinations by tungsten-183, vanadium-51 and silicon-29 NMR spectroscopy
1991
Mixed valence and magnetically coupled vanadate domains in heteropoly tungstate anions
1980
Formation et isomerisation des undeca et dodeca tungstosilicates et germanates isomeres
1977
Synthesis and X-ray characterization of nickel(II) arsenatotungstate complexes: isolation of an intermediate leading to the formation of a sandwich-type polyoxometalate
2002
Synthesis, molecular structure and chemical properties of a new tungstosilicate with an open Wells–Dawson structure, α-[Si2W18O66]16−
2003
Dawson type heteropolyanions. 1. Multinuclear (phosphorus-31, vanadium-51, tungsten-183) NMR structural investigations of octadeca(molybdotungstovanado)diphosphates .alpha.-1,2,3-[P2MM'2W15O62]n- (M, M' = Mo, V, W): syntheses of new related compounds
1991
Mixed-valence bis(ethylenedithio)tetrathiafulvalenium (BEDT-TTF) monolayers sandwiched between extended close-packed Keggin-type molecular metal oxide cluster arrays: synthesis, unprecedented acentric structure, and preliminary conducting and e.s.r. properties of (BEDT-TTF)8SiW12O40
1989
Synthesis and chemical behavior of the inorganic cryptates (MSb9W21O86)(19−n)− Mn+ Na+, K+, NH4+, Ca2+, Sr2+
1980
Step‐by‐Step Assembly of Trivacant Tungstosilicates: Synthesis and Characterization of Tetrameric Anions
2005
A Cubane-Substituted Polyoxoanion: Structure and Magnetic Properties of Cs2[H2PW9Ni4O34(OH)3(H2O)6]·5H2O
1999