Standout Papers
- Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes (1986)
- Metal-promoted cyclization. 19. Novel bicyclization of enynes and diynes promoted by zirconocene derivatives and conversion of zirconabicycles into bicyclic enones via carbonylation (1989)
- A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols (1986)
- Zirconium-promoted bicyclization of enynes. Effects of enyne structure (1987)
Citation Impact
Citing Papers
Total Synthesis of Nominal Diazonamides-Part 1: Convergent Preparation of the Structure Proposed for (−)-Diazonamide A
2001
Highly Diastereoselective Tandem Reduction–Allylation Reactions of 1,4‐Diketones with Zirconocene–Olefin Complexes
2003
Reaction of Alkene–Zirconocene Complexes and Cyclic Enol Ethers through New Reaction Pathways
2004
Iron catalysed direct alkylation of amines with alcohols
2014 StandoutNobel
Zirconocene-Mediated, High-Yielding Macrocyclizations of Silyl-Terminated Diynes
2002
Stereoselective Synthesis of the Side Chains of Mycolactones A and B Featuring Stepwise Double Substitutions of 1,1‐Dibromo‐1‐alkenes
2006 StandoutNobel
Biaryl Phosphane Ligands in Palladium‐Catalyzed Amination
2008 Standout
A quarter of a century of explorations in organozirconium chemistry
2005 StandoutNobel
Stoichiometric reactions of nonconjugated dienes with zirconocene derivatives. Further delineation of the scope of bicyclization and observation of novel multipositional alkene regioisomerization
1995 StandoutNobel
Copper(I)-Catalyzed Synthesis of Azoles. DFT Study Predicts Unprecedented Reactivity and Intermediates
2004 StandoutNobel
Preparation and reactions of allenic zirconium species from propargylic ether derivatives
1992
Palladium-Catalyzed Cyclization of 1-Iodo-Substituted 1,4-, 1,5-, and 1,6-Dienes as Well as of 5-Iodo-1,5-dienes in the Presence of Carbon Monoxide
1996 StandoutNobel
Factors Affecting the Unusual Reactivity Order in the β-Hydrogen Abstraction of Dialkylzirconocenes
1992 StandoutNobel
Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization
1987 StandoutNobel
Zirconocene-Mediated Route to Enantiopure 9-Oxabicyclononanes Functionalized on Both Carbon Bridges
2002
Diastereoselectivity Control in the Zirconocene-Mediated Ring Contraction of 4-Vinylfuranosides to Enantiopure Multiply Functionalized Cyclobutanes
2002
Reaction of 3-zircona-1-cyclopentenes and zirconacyclopentanes with aldehydes. A selective and convenient synthesis of 4-penten-1-ols, (Z)-5-iodo-4-penten-1-ols, and related alkanols
1994 StandoutNobel
Allylzirconation of alkynes by the reactions of zirconocene-alkyne complexes with allylic ethers
1993
Novel and selective α-substitution of ketones and other carbonyl compounds based on Pd-catalyzed cross coupling of α,β-unsaturated carbonyl derivatives containing α-halogen or α-metal groups
1999 StandoutNobel
Transformation of Zirconocene−Olefin Complexes into Zirconocene Allyl Hydride and Their Use as Dual Nucleophilic Reagents: Reactions with Acid Chloride and 1,4-Diketone
2004
Highly Chemo-, Regio-, and Stereoselective Carbon−Carbon Bond Formation via Migratory Insertion Reaction of Zirconacyclopentene Derivatives and Alkynyl Metals Containing Li and Mg. Novel Synthesis of 1,5-Dienes and 1,5-Enynes
1999 StandoutNobel
Zirconium Catalyzed or Mediated Regioselective C–C Bond Formation Reactions of α,β-Unsaturated Acetals
1994
Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and Related Complexes of Synthetic Interest
1994 StandoutNobel
Direct Preparation of Allylic Zirconium Reagents from Zirconocene−Olefin Complexes and Alkenes
2004
New “Cp2Zr”-mediated ring transformations of 2-vinylheterocycles to carbocycles
1997
A Zirconocene-Coupling Route to Substituted Poly(p-phenylenedienylene)s: Band Gap Tuning via Conformational Control
1998
Stereoselective cyclic carbolithiation of alkyne derivatives. A stereoselective synthesis of exocyclic alkenes
1990 StandoutNobel
Synthesis of Hydrazulenes via Zr-Promoted Bicyclization of Enynes and Transition Metal-Catalyzed or Radical Cyclization of Alkenyl Iodides. Efficient Synthesis of (±)-7-epi-β-Bulnesene
1997
Generation of allylic and related organozirconiums through a highly effective zirconium—β-alkoxide elimination reaction
1995
Construction of nitrogen-heterocyclic compounds through zirconium mediated intramolecular alkene-carbonyl coupling reaction of N-(o-alkenylaryl)carbamate derivatives
2003
Transition metal-mediated routes to cyclopentenones
2004
Phosphorescence within benzotellurophenes and color tunable tellurophenes under ambient conditions
2014
Nondissociative mechanism for decomposition of dialkylzirconocenes to produce alkene–zirconocene–phosphine complexes
1990 StandoutNobel
Strictly regio- and stereo-controlled α-alkenylation of bicyclic enone derivatives via palladium-catalyzed cross coupling and its application to a formal synthesis of (±)-carbacyclin
1998 StandoutNobel
On the reversibility of alkene cyclozirconation
1993
Diastereoselective zirconocene-promoted bicyclization-carbonylation of allylically methyl-substituted enynes. Synthesis of (+)-iridomyrmecin
1992 StandoutNobel
Facile and reversible displacement of η-C5H5from Zr by organolithiums; formation of (η5-cyclopentadienyl) trialkylzirconiums and their reactions eith electrophiles and alkenes
1996 StandoutNobel
Synthesis of an enantiomerically pure 2,2,4-trisubstituted cyclobutanone building block by zirconocene-promoted deoxygenative ring contraction of structurally modified 4-vinylfuranosides
2003
Zirconium-Mediated Intramolecular Ester Transfer Reaction: Synthesis of α-Substituted γ-Aminobutyric Acid (GABA) Derivatives
2002
Zirconocene-catalyzed alkylation of aryl alkenes with alkyl tosylates, sulfates and bromides
1998
An efficient and general route to reduced polypropionates via Zr-catalyzed asymmetric C—C bond formation
2004 StandoutNobel
Zirconium Mediated Regioselective Carbon-Carbon Bond Formation Reactions
1992
Aggregation-Induced Emission: Together We Shine, United We Soar!
2015 Standout
Structural and Co-conformational Effects of Alkyne-Derived Subunits in Charged Donor−Acceptor [2]Catenanes
2007 StandoutNobel
Construction of Pyridine Rings by Metal-Mediated [2 + 2 + 2] Cycloaddition
2003
Ni-promoted Cyclopentenone Formation by Intramolecular Cyclocarbonylation of 1-Bromo-1,4-dienes
1993
New Zirconocene-Coupling Route to Large, Functionalized Macrocycles
2000
Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligands [(i-PrN-o-C6H4)2O]2-([i-PrNON]2-) and [(C6H11N-o-C6H4)2O]2-([CyNON]2-)
1999 StandoutNobel
Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope
2011 Standout
Zirconocene–Alkene Complexes. An X-Ray Structure and a Novel Preparative Method
1989 StandoutNobel
Template synthesis of substituted cyclopentanones by zirconocene/olefin/CO systems
1991
Convenient preparative method of α,β-disubstituted cyclopentenone by zirconium promoted intermolecular coupling of an alkyne, EtMgBr (or ethylene) and CO
1997
Multiple Mechanistic Pathways for Zirconium-Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C−H Activation
1996 StandoutNobel
Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation
1988 StandoutNobel
The Atom Economy—A Search for Synthetic Efficiency
1991 StandoutScience
Highly stereoselective and general synthesis of (z)-3-methyl-2-alken-1-ols via palladium-catalyzed cross coupling of (z)-3-iodo-2-buten-1-ol with organozincs and other organometals
1993 StandoutNobel
Palladium-Catalyzed Alkynylation
2003
Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates
2014 StandoutNobel
Brønsted acid-catalyzed stereoselective [4+3] cycloadditions of ortho-hydroxybenzyl alcohols with N,N′-cyclic azomethine imines
2017
One-pot conversion of alkynes and alkenes into one-carbon homologated aldehydes via hydrozirconation-isocyanide insertion-hydrolysis
1988 StandoutNobel
Alkene and Alkyne Complexes of Zirconocene. Their Preparation, Structure, and Novel Transformations
1998 StandoutNobel
Isolation and Structural Characterization of 1-Zirconacyclopent-3-yne, Five-Membered Cyclic Alkynes
2002 Science
Zr-promoted ‘pair’-selective and regioselective synthesis of penta-substituted benzene derivatives
2003 StandoutNobel
Zirconocene Catalyzed Dehalogenation of Aromatic Halides by Alkylmagnesium Reagents
1997
Olefin hydrosilation catalyzed by zirconocene complexes
1991
Catalytic Hydrogenation of Alkenes Using Zirconocene–Alkene Complexes
1991 StandoutNobel
Zirconium-catalyzed and zirconium-promoted cyclization reactions of non-conjugated dienes with alkylmagnesium halides to give cycloalkylmethylmagnesium derivatives
1998 StandoutNobel
Preparation and regio- and diastereoselective reactions of allylic zirconium reagents from allylic ether derivatives
1992
Cationic Hafnium Alkyl Complexes that Are Stable toward β-Hydride Elimination below 10 °C and Active as Initiators for the Living Polymerization of 1-Hexene
2001 StandoutNobel
Synthesis and X-ray crystal structures of tricyclic ketone containing trans-fused bicyclo[3.3.0]octane unit
1995
Reaction pathways of zirconocene-catalyzed silylation of alkenes with chlorosilanes
2003
Zirconocene-Mediated Cyclization of 2-Bromo α,ω-Dienes
1997
Convenient synthesis of diene–zirconocenes and regioselective partial reduction of the more highly substituted double bonds of conjugated dienes via complexation with zirconocenes and protonolysis
1993 Nobel
Palladium-catalyzed cycloisomerizations of enynes and related reactions
1990
Reaction of Dimethylzirconocene with Alkylmagnesium Halides as a Potentially General Method for Preparing Zirconocene-Alkene Complexes
1990 StandoutNobel
Strictly regio-controlled method for α-alkenylation of cyclic ketones via palladium-catalyzed cross coupling
1991 StandoutNobel
Cp2Zr(C2H4)(PMe3), der erste stabile Ethylenkomplex des Zirkoniums
1988
Intramolecular Cyclization of Ene-Imine Using Dibutylzirconocene
2004
Novel type of carbozirconation reaction of alkynes
1995
Organocatalytic Asymmetric Inverse-Electron-Demand 1,3-Dipolar Cycloaddition of N,N′-Cyclic Azomethine Imines
2014
(1‐Alken)(trimethylphosphan)zirconocen‐Komplexe: Darstellung, Charakterisierung und Reaktivität
1989
Synthesis of [5.5.5.5]fenestranes by pd-catalyzed carbonylation-cyclisation
1992
Complexation of Vinylcyclopropanes with Zirconocene−1-butene Complex: Application to the Stereocontrolled Synthesis of Steroidal Side Chains
1997
Transformation of the First Zirconocene Alkyne Complex without an Additional Phosphane Ligand into a Dinuclear σ‐Alkenyl Complex by Hydrogen Transfer from η5‐C5H5 to the Alkyne Ligand
1993
Chiral Allenes via Alkynylogous Mukaiyama Aldol Reaction
2016 StandoutNobel
Nickel(0)-promoted cyclization of enynes with isocyanides: a new route to polycyclic cyclopentenone skeletons
1988
Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design
2021 StandoutNobel
Catalytic Asymmetric Intramolecular [4+2] Cycloaddition of In Situ Generated ortho‐Quinone Methides
2017 StandoutNobel
Highly stereoselective synthesis of exocyclic alkenes via cyclialkylation
1987 StandoutNobel
Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes
2011 Standout
A genealogy of Pd-catalyzed cross-coupling
2002 StandoutNobel
Facile cleavage of the CβCβ′ bond of zirconacyclopentenes. Convenient method for selectively coupling alkynes with alkynes, nitriles, and aldehydes
1993 StandoutNobel
Synthesis of Heterocycles Using Zirconium-Catalyzed Asymmetric Diene Cyclization
1997
Nickel(II)-Promoted Homocoupling Reaction of 2-(Phosphininyl)halogenozirconocene Complexes: A New and Efficient Synthesis of 2,2‘-Biphosphinines
1998
Zirconocene-promoted stereoselective bicyclization of 1,6- and 1,7-dienes to produce trans-zirconabicyclo[3.3.0]octanes and cis-zirconabicyclo[4.3.0]nonanes
1989 StandoutNobel
Pair-Selective Coupling of Alkynes with Alkenes on Zirconocene Complex
1993
A Simple, Efficient Route to Cage Compounds via Zirconocene Coupling
1998
Chemistry and Biology Of Multicomponent Reactions
2012 Standout
Conversion of non-conjugated dienes into conjugated diene-zirconocenes via multipositional regioisomerization
1993 StandoutNobel
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
2009 Standout
On the regiochemistry of cyclialkylation of regiodefined 4-halo-1-alkenylmetals producing cyclobutenes
1997 StandoutNobel
Synthesis of α-iodo-α,β-unsaturated ketones by the reaction of α-silyl-α,β-unsaturated ketones with ICl or IClAlCl3
1999 StandoutNobel
Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones
2019 StandoutNobel
Zirconacyclopropanes and Zirconacyclopropenes. Their Synthesis, Characterization, and Reactions
1987 StandoutNobel
Preparation and reactions of γ,γ-dialkoxyallylic zirconium species: α,β-Unsaturated acyl anion equivalent
1997
Transition metal catalyzed reactions of organozinc reagents
1992
Aryl−Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction
2002 Standout
Copper-Catalyzed Electrophilic Carbofunctionalization of Alkynes to Highly Functionalized Tetrasubstituted Alkenes
2013
Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds
1996 StandoutNobel
Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes
1996 StandoutNobel
Convergent Synthetic Routes to Orthogonally Fused Conjugated Oligomers Directed toward Molecular Scale Electronic Device Applications
1996
Zirconocene mediated cyclization and isomerization of 1,3,6-heptatriene
2002
Efficient Zirconocene-Coupling of Silicon-Substituted Diynes to Polymers and Macrocycles
1998
An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes
1996 StandoutNobel
Works of Fredrik Cederbaum being referenced
Multicomponent reactions in fungicide research: The discovery of mandipropamid
2007
Aryldiones incorporating a [1,4,5]oxadiazepane ring. Part I: Discovery of the novel cereal herbicide pinoxaden
2009
Metal-promoted cyclization. 19. Novel bicyclization of enynes and diynes promoted by zirconocene derivatives and conversion of zirconabicycles into bicyclic enones via carbonylation
1989 StandoutNobel
Zirconium-promoted bicyclization of enynes. Effects of enyne structure
1987 StandoutNobel
A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols
1986 StandoutNobel
Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes
1986 StandoutNobel
Total synthesis of (±)-rocaglamide and some aryl analogues
2001