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Nickel: An Element with Wide Application in Industrial Homogeneous Catalysis
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2000 Standout
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Accessing the Synthetic Chemistry of Radical Ions
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1999 StandoutNobel
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2002 StandoutNobel
Preparation of Sterically Protected 3,4-Bis(phosphinidene)cyclobutenes and Their Isomerism
1990
Preparation, Methylation, and Coupling Reaction of 1,2-Dithienyl-3,4-bis[(2,4,6-tri-t-butylphenyl)phosphinidene]cyclobutenes
2004
Cobalt-Catalyzed Addition of Azoles to Alkynes
2010
Reaktive EC (pp) π‐Systeme, XIV. Synthese und Struktur von Phosphaalkenen des Typs F3CPC(F)NR2
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C2-Alkylation and Alkenylation of Indoles Catalyzed by a Low-Valent Cobalt Complex in the Absence of Reductant
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A Carbene•Phosphinidene Adduct: “Phosphaalkene”
1997
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Artificial Molecular Machines
2000 StandoutNobel
An Operational Supramolecular Nanovalve
2004 StandoutNobel
Photocatalysis for the Formation of the C−C Bond
2007
The First Distibabutadiene: Synthesis and Structure of trans‐1,4‐Bis(trimethylsiloxy)‐1,4‐bis(2,4,6‐tri‐tert‐butylphenyl)‐2,3‐distibabutadiene
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Mesoporous Graphitic Carbon Nitride as a Heterogeneous Visible Light Photoinitiator for Radical Polymerization
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Oligocatenanes Made to Order1
1998 StandoutNobel
Peculiarities of pπpπ conjugation in aminosubstituted phosphaalkenes
1991
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2006
Carbene−Pnictinidene Adducts
1997
Cycloaddition Reactions Initiated by Photochemically Excited Pyrylium Salts
1993
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Cobalt-Catalyzed, Room-Temperature Addition of Aromatic Imines to Alkynes via Directed C–H Bond Activation
2011
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2000 StandoutNobel
MOLECULAR AND CRYSTAL STRUCTURE AND ELECTRON DENSITY DISTRIBUTION IN P-BIS(TRIMETHYLSILYL)AMINO-C,C-DICHLOROMETHYLENEPHOSPHINE
1993
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2016
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2017
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2005 StandoutNobel
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2017
Synthesis, crystal structure and rearrangement of a methylene(ylene)- phosphorane containing a CH2-moiety at an sp2-hybridized phosphorus(v) centre
1997
STRUCTURES OF PHOSPHAETHYLENES AND A 1-PHOSPHAALLENE CONTAINING PHOSPHORUS IN LOWER COORDINATION STATE
1985
Selbstorganisation in natürlichen und in nichtnatürlichen Systemen
1996 StandoutNobel
Synthesis and Structure of a Diphospha[4]radialene
1993
The Mechanism of the Slippage Approach to Rotaxanes. Origin of the “All-or-Nothing” Substituent Effect
1998 StandoutNobel
Acyl‐ und Alkylidenphosphane. XXIX. Molekül‐ und Kristallstruktur des Orthorhombischen (Diphenylmethyliden)mesitylphosphans
1986
Molybdenum Triamidoamine Complexes that Contain Hexa-tert-butylterphenyl, Hexamethylterphenyl, or p-Bromohexaisopropylterphenyl Substituents. An Examination of Some Catalyst Variations for the Catalytic Reduction of Dinitrogen
2004 StandoutNobel
Self‐Assembly in Natural and Unnatural Systems
1996 StandoutNobel
Synthesis and Characterization of 1,3-Diphosphapropene and Alkali-Metal 1,3-Diphosphaallyl Complexes and Unexpected 1,3-Rearrangement of a Cesium 1,3-Diphosphaallyl Complex to a Cesium Secondary Phosphanide
2004
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
Copper-mediated Coupling Reaction of Kinetically Stabilized 1-Methyl-2-phosphaethenyllithiums Involving an Isomerization to a 3-Phospha-2-propenyllithium Derivative
2002
Valence Isomerism between Sterically Protected Methylenephosphine P-Sulfide and 1,2-Thiaphosphirane
1996
Understanding Reactivity Patterns of Radical Cations
1997
Bioinspired Metal–Organic Framework Catalysts for Selective Methane Oxidation to Methanol
2018 StandoutNobel
Synthesis, Structure, and Reactivity of Novel 3,4-Diphosphacyclobutenes Bearing Silyl Groups
2005
Donor‐Functionalised N‐Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions
2008
Preparation and X-ray analyses of siloxane-bridged acyclic and 8-membered cyclic phosphaethenes
2006
π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium
2010 Standout
Isolation and Characterization of the Molybdenum Alkylidyne Complex [(F3C)Me2CO]2Mo(C-t-Bu)[N(Ar)PC(H)(CMe2Ph)] and Its Conversion to a Phosphamolybdacyclobutene
1996
Cobalt(iii )-catalyzed synthesis of pyrroles from enamides and alkynes
2016
Synthesis of 2-(2-Pyridyl)phosphaalkenes [Mes*PC(R)Py] (R = H, SiMe3) and Their Complexes η1,η1-[Mes*PC(R)Py]XPdCl (X = Cl, Me, Ac)
1997
Radical cation Diels–Alder reaction between indoles and exocyclic 1,3-dienes with incorporated intentional cleaving points
1999
π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
1999 Standout
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
2003 StandoutScienceNobel
Acid−Base Controllable Molecular Shuttles
1998 StandoutNobel
Low-valent cobalt-catalyzed C–H allylation
2016
Cationic Nickel(II) Complexes of Chelating N-Heterocyclic Carbenes
1999
Main Chain Polyrotaxanes by Threading Crown Ethers onto A Preformed Polyurethane: Preparation and Properties
1998
Cobalt‐Catalyzed Annulation Reactions via C−H Bond Activation
2017
Topochemical [2+2] Dimerization of Kinetically Stabilized 1‐Phosphaallenes in the Solid State
2003
Scope and Limitations of the Base-Catalyzed Phospha-Peterson PC Bond-Forming Reaction
2006
The Nitrogenase FeMo-Cofactor and P-Cluster pair: 2.2 Å Resolution Structures
1993 Science
Phosphaalkene derivatives of furane and thiophene: Synthesis, crystal structure, electrochemistry and EPR study of their radical anions
1997
Heterocycles in asymmetric synthesis. Part 1. Construction of the chiral building blocks for enantioselective alkaloid synthesis via an asymmetric intramolecular Michael reaction
1992
Cobalt mediated C–H bond functionalization: emerging tools for organic synthesis
2014
Efficient Templated Synthesis of Donor−Acceptor Rotaxanes Using Click Chemistry
2006 StandoutNobel
Donor-Functionalized Heterocyclic Carbene Complexes of Palladium(II): Efficient Catalysts for C−C Coupling Reactions
2000
Photoinduced Electron Transfer in a Triad That Can Be Assembled/Disassembled by Two Different External Inputs. Toward Molecular-Level Electrical Extension Cables
2002 StandoutNobel
A Simple Route to the 1‐Aza‐3‐Phosphaallyl System: Structure of a Dimeric Lithium Complex and Protonation to Give the First NH2‐Substituted Phosphaalkene
1995
Aromatic 1H-[1,2]Diphosphole with a Planar Tricoordinated Phosphorus, Plus η2-Coordination Mode between Ruthenium(0) and a Phosphaalkene
2007
The First Example of a Formal Scandium(I) Complex: Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring
1996
Cobalt-Catalyzed C–H Activation
2015
Catalytic Methods for CH Bond Functionalization: Application in Organic Synthesis
2003
Mechanistic Studies on Synthetic Fe−S-Based Clusters and Their Relevance to the Action of Nitrogenases
2005 StandoutNobel
Cobalt(III)-Catalyzed Synthesis of Indazoles and Furans by C–H Bond Functionalization/Addition/Cyclization Cascades
2014
A Titanium–Organic Framework as an Exemplar of Combining the Chemistry of Metal– and Covalent–Organic Frameworks
2016 StandoutNobel
Operating Molecular Elevators
2006 StandoutNobel
Synthesis of new chelating agents: Association of a phosphaalkene moiety with a pyridine.
1992
Asymmetric Enamine Catalysis
2007 StandoutNobel
Cobalt-Catalyzed Hydroarylation of Alkynes through Chelation-Assisted C−H Bond Activation
2010
Palladium(0) mediated coupling of bromophosphaalkenes with Grignard reagents
1997
From the New Arsaalkene ArAsC(Br)SiMe3 to the First Stable Arsaallene, ArAsCCR2 (Ar = 2,4,6-Tri-tert-butylphenyl, CR2 = Fluorenylidene)
2002
Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization
2014
Co(III)-Catalyzed C–H Activation/Formal SN-Type Reactions: Selective and Efficient Cyanation, Halogenation, and Allylation
2014
Reactions of small molecules at transition metal sites: studies relevant to nitrogenase, an organometallic enzyme
1996
Efficient photochemical electron transfer sensitization of homogeneous organic reactions
2008
Synthesis of Group 4 Complexes that Contain the Diamidoamine Ligands, [(2,4,6-Me3C6H2NCH2CH2)2NR]2- ([Mes2N2NR]2-; R = H or CH3), and Polymerization of 1-Hexene by Activated [Mes2N2NR]ZrMe2 Complexes
1999 StandoutNobel
Spontane Bildung eines Schiff-Basen-Tetramakrocyclus
2000
A novel pattern of dimerization for 1, 4‐diphospha‐1,3‐butadienes
2003
Thermal Reactions of 5‐Alkylidene‐4,5‐dihydro‐3H‐1,2,4(λ3)‐diazaphospholes (4‐Phosphapyrazolines) – A Route to Various PHeterocycles and to 2‐Phosphabutadienes
1997
Molecular structure of 1-(2,4,6-tri-tert-butylphenyl)-4,4-bis(dimethylamino)-1-aza-2,3λ3-phosphabutadiene-1,3
2001
Molecular and electronic structure of halogen-substituted phosphaalkenes
1997
A Metal−Organic Framework with Covalently Bound Organometallic Complexes
2010 StandoutNobel
Cobalt(II)-Catalyzed Oxidative C–H Alkenylations: Regio- and Site-Selective Access to Isoindolin-1-one
2015
Molecular structure of 1-phenyl-1-dimethylamino-4,4-bis(trimethylsilyl)-2-aza-3λ3-phosphabutadiene-1,3
1999
Reduction of Dinitrogen to Ammonia at a Well-Protected Reaction Site in a Molybdenum Triamidoamine Complex
2002 StandoutNobel
Works of Falk Knoch being referenced
The First Organodithioxophosphorane
1983
Synthese des ersten Triphosphabutadiens
1986
Photochemically induced radical-cation Diels-Alder reaction of indole and electron-rich dienes
1991
Niederkoordinierte Phosphorverbindungen, 30. 1‐Chlor‐2‐phenyl‐2‐(trimethylsilyl)‐1‐phosphaethen als Synthese‐baustein neuer Phosphaalkene
1985
Niederkoordinierte Phosphorverbindungen, 55 Zur Cope‐Umlagerung an 1,3‐Diphospha‐1,5‐hexadienen
1987
A Square Pyramidal Coordination Cap: The Co(III) Complex of a Novel Tetrapodal Pentadentate Ligand with an NN4 Donor Set
1996
Niederkoordinierte Phosphor‐Verbindungen, 281). Monophosphabutadiene
1984
Asymmetric Michael additions via SAMP-/RAMP-hydrazones anti-diastereo- and enantioselective synthesis of 3,4-disubstituted 5-oxo-alkanoates
1986
Niederkoordinierte Phosphorverbindungen, 37. Zum Mechanismus der [2 + 4]‐Cycloaddition an Phosphaalkene
1985
Niederkoordinierte Phosphor‐Verbindungen, 18. Synthese und Molekülstruktur von zwei 1,3‐Diphosphapropenen
1983
The First Stable Methyleneoxophosphorane
1984
Transformation of η1‐Nitrosyl to η2‐Hydroxylaminyl Ligands in the Reduction of [Mo(NO)2(‘S4’)] to [Mo(η2‐NH2O)(NO)(‘S4’)]: A Model Reaction for a Partial Step in the Enzymatic NO→NH3 Conversion
1988
Niederkoordinierte phosphorverbindungen
1985
Niederkoordinierte phosphorverbindungen
1987
Ein neuer 1,3-Diphosphaallylnickel-Komplex für die Ethen-Polymerisation
1987
Niederkoordinierte Phosphorverbindungen, 45. Gemischt substituierte Bismethylenphosphorane durch Einwirkung von Carbenoiden auf Phosphaalkene
1986
Ionenpaarbildung und Cyclisierungsreaktionen an koordinierten Oxalamidinen
1995
Type B Semiconductor Photocatalysis: The Synthesis of Homoallyl Amines by Cadmium Sulfide‐Catalyzed Linear Photoaddition of Olefins and Enol/allyl Ethers to N‐Phenylbenzophenone Imine
1997
1,3-Diphospha-1,3-butadiene
1986
Semiconductor‐Catalysed Photoaddition: γ,δ‐Unsaturated Amines from Cyclopentene and Schiff Bases
1996
Niederkoordinierte Phosphorverbindungen, 54 Phosphaalkene durch Cope‐Umlagerung
1987
Niederkoordinierte Phosphor‐Verbindungen. 42. Trennung und röntgenographische Strukturbestimmung der E,Z‐Isomeren des 2,4,6‐Tri(tert.butyl)phenyl‐phenylmethylenphosphans
1986
Niederkoordinierte Phosphorverbindungen, 44. Zur Kenntnis silylierter Bismethylenphosphorane RP[C(SiMe3)2]2
1986
Transition-metal complexes with sulfur ligands. 94. Synthesis and reactivity of nickel, palladium, and platinum complexes with the thiolate carbene ligand 'S2C'2-. X-ray structure determinations of [Ni(PMe3)('S2C')], [Ni(PPh3)('S2C')], [Ni('SC')2], [Pt(PMe3)('S2C')], and ('S2CO')2
1993
First Evidence for the Existence of a Phosphathioketene
1984
Phosphaallenes
1984
Anodic oxidation of N-acyl and N-alkoxycarbonyl dipeptide esters as a key step for the formation of chiral heterocyclic synthetic building blocks
1991
Tricarbonyl(1,3‐diphosphaallyl)cobalt, a Phosphorus Analogue of (η3‐Allyl)tricarbonylcobalt
1985
Niederkoordinierte Phosphorverbindungen
1988
Niederkoordinierte Phosphorverbindungen, 46. 2,4‐Diphospha‐1‐butene
1986
Syntheses, Structures and Properties of Copper(I) and Copper(II) Complexes of the Ligand N,N′-Bis[2′-(dimethylamino)ethyl]-N,N′-dimethylethane1,2-diamine (Me6trien)
2000
Niederkoordinierte Phosphor‐Verbindungen, 17. Diphosphabutadiene
1983
Niederkoordinierte Phosphorverbindungen. 59. 2,4,6‐Tri‐tert‐butylphenylphosphaketen, ein Baustein gemischt substituierter Phospha‐carba‐polyene
1988
Functionalization of Aromatic Azo Compounds by the Cobalt‐Catalyzed, Regioselective Double Addition of Tolane: 2,6‐Distilbenylazobenzenes and 2,3‐Dihydrocinnolines
1994
Transition Metal Complexes with Sulfur Ligands, Part 119. Synthesis of Water Soluble Fe and Ru Complexes with Novel Multidentate Thioether Thiolate Ligands Containing Carboxylate Substituents
1996
Nitrogenase Model Compounds: [μ‐N2H2{Fe(“NHS4”)}2], the Prototype for the Coordination of Diazene to Iron Sulfur Centers and Its Stabilization through Strong NH S Hydrogen Bonds
1989
Über niederkoordinierte phosphorverbindungen
1985
Transition metal complexes with sulfur ligands CIV. Protonation and alkylation of thiolate donors of [Fe(CO)2(‘S4’)] and [Fe(CO)(‘S5’)]: syntheses and properties of Fe(II) complexes with open-chain thioether ligands (‘S4’2−=1,2-bis(2-mercaptophenylthio)ethane(2−); ‘S5’2−=2,2′-bis(2-mercapto-phenylthio)diethylsulfide(2−))
1994
Protonation and Alkylation of the Thiolato Donors in [Fe(CO)(“NHS4”)]: Effects on the Structural, Electronic, and Redox Properties of Metal–Sulfur Complexes
1996
Niederkoordinierte Phosphor‐Verbindungen, 27. Synthese und Reaktionen von Ethinylphosphaalkenen
1984
Transition-metal complexes with sulfur ligands. 89. Unexpected formation of the highly stable binuclear nickel carbene complex [Ni(S2C)]2 from nickel(II) salts, diamine-dithiolate ligands, and C1 components [S2C2- = 1,3-imidazolidine-1,3-diylbis(2-benzenethiolate)(2-)]
1992
Übergangsmetallkomplexe mit Schwefelliganden CXXIV. Koordination von C- und S-Liganden an Metall—Carben—Thiolat-Fragmente [M(‘S2C’)] [M = NiII, PdII, PtII; ‘S2C’2− = 1,3-Imidazolidinyl-N,N′-bis(2-benzolthiolat)(2 −)]. [M(L)(‘S2C’)]-Komplexe mit L = CN−, CH3−, COCH3−, CNBu, CR2, SH− und SR− (R = Et, Ph, o-C6H4NH2)
1997
A Convenient Way to Novel FeIV Complexes with Mixed N/S/P Coordination Spheres and “Innocent” Ligands
1997
Niederkoordinierte Phosphor‐Verbindungen, 49. Zur Kenntnis der 1,3,4,6‐Tetraphospha‐1,5‐hexadiene
1986
Übergangsmetallkomplexe von Diazenen XXXIV. 2,6-di-(trans-stilbenyl) azobenzole und 2,3-dihydrocinnoline durch cobaltkatalysierte, zweifache addition von tolan an azobenzolderivate
1995
Niederkoordinierte Phosphorverbindungen, 29. Diels‐Alder‐Reaktion von 2,3‐Dimethylbutadien mit stabilen Phosphaalkenen als Dienophilen
1985
Niederkoordinierte Phosphor‐Verbindungen, 10. Synthese eines 1,3‐Azaphosphetidins mit exocyclischer (PC)‐Doppelbindung
1982
Semiconductor‐Catalysed Photoaddition of Olefins and Enol Ethers to 1,2‐Diazenes: A New Route to Allylhydrazines
1995
Nitrogenase‐Modellverbindungen: [μ‐N2H2{Fe(„NHS4”)}2], der Prototyp für die Koordination von Diazen an Eisen‐Schwefel‐Zentren und seine Stabilisierung durch starke N–H … S‐Wasserstoffbrücken
1989
Das erste Organodithioxophosphoran
1983
Einfache Synthese von Phosphaalkenen durch phosphoranaloge Isocyanid‐Reaktion und atypische Kristallstruktur eines Tetracarbonylphosphaalkeneisen‐Komplexes
1984
Funktionalisierung aromatischer Azoverbindungen durch cobaltkatalysierte, regioselektive Doppeladdition von Tolan: 2,6‐Distilbenylazobenzole und 2,3‐Dihydrocinnoline
1994
Synthesis of the First Triphosphabutadiene
1986
Phosphaallene
1984
Easy Synthesis of Phosphaalkenes by a Phosphorus‐Analogous Isocyanide Reaction and an Atypical Crystal Structure of a Tetracarbonyl(phosphaalkene)iron Complex
1984
Niederkoordinierte Phosphorverbindungen, 56 Valenzisomerisierung eines 3,4‐Diphospha‐1,5‐hexadiins zu einem 3,4‐Bis(phosphamethylen)‐1‐cyclobuten
1987
2,4‐Di‐tert‐butyl‐1λ3,3λ3‐diphosphinines: Targeted Synthesis at Iron(0) Centers and Oxidative Release
1995
Niederkoordinierte Phosphor‐Verbindungen, 48. Synthese von 1‐Phosphaallenen
1986
A New 1,3‐Diphosphaallylnickel Complex for the Polymerization of Ethene
1987
Syntheses, Structures and Properties of Copper(I) and Copper(II) Complexes of the LigandN,N′-Bis[2′-(dimethylamino)ethyl]-N,N′-dimethylethane1,2-diamine (Me6trien)
2000