Standout Papers
Citation Impact
Citing Papers
SuFEx-enabled, agnostic discovery of covalent inhibitors of human neutrophil elastase
2019 StandoutNobel
Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life
2016 StandoutScienceNobel
The Catalytic Cross-Coupling of Unactivated Arenes
2007 Science
Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis
2005 Standout
Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
2021
Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
2020
An efficient and convenient Cu(OAc)2/air mediated oxidative coupling of azoles via C–H activation
2009
Platinum-catalyzed hydrofunctionalization of unactivated alkenes with carbon, nitrogen and oxygen nucleophiles
2007
Knipholone and related 4-phenylanthraquinones: structurally, pharmacologically, and biosynthetically remarkable natural products
2008
Copper‐Mediated CH/CH Biaryl Coupling of Benzoic Acid Derivatives and 1,3‐Azoles
2013
Copper catalyzed oxidation of organozinc halides
2006
Metal-free catalytic C-H bond activation and borylation of heteroarenes
2015 Science
Chiral Metal–Organic Assemblies—A New Approach to Immobilizing Homogeneous Asymmetric Catalysts
2004
Two novel series of allocolchicinoids with modified seven membered B-rings: design, synthesis, inhibition of tubulin assembly and cytotoxicity
2005
Intermolecular oxidative cross-coupling of arenes
2009
Intramolecular hydroamination/cyclisation of aminoallenes mediated by a cationic zirconocene catalyst: a computational mechanistic study
2006
Enamide Synthesis by Copper‐Catalyzed Cross‐Coupling of Amides and Potassium Alkenyltrifluoroborate Salts
2008
Nickel-catalyzed sp2 C–H bonds arylation of N-aromatic heterocycles with Grignard reagents at room temperature
2011
Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides
2010
Pd‐PEPPSI‐IPent: An Active, Sterically Demanding Cross‐Coupling Catalyst and Its Application in the Synthesis of Tetra‐Ortho‐Substituted Biaryls
2009
A Cationic Gold(I) Complex as a General Catalyst for the Intermolecular Hydroamination of Alkynes: Application to the One‐Pot Synthesis of Allenes from Two Alkynes and a Sacrificial Amine
2009
Intermolecular hydroamination of oxygen-substituted allenes. New routes for the synthesis of N,O-chelated zirconium and titanium amido complexes
2011
Chiral Neutral Zirconium Amidate Complexes for the Asymmetric Hydroamination of Alkenes
2006
Fluorescent Diarylindoles by Palladium‐Catalyzed Direct and Decarboxylative Arylations of Carboxyindoles
2009
Highly Efficient Cross‐Dehydrogenative‐Coupling between Ethers and Active Methylene Compounds
2006
π-Acidic alkene ligand effects in Pd-catalysed cross-coupling processes: exploiting the interaction of dibenzylidene acetone (dba) and related ligands with Pd(0) and Pd(ii)
2008
Copper-mediated domino synthesis of pyrimido[4,5-b]carbazolones via Ullmann N-arylation and aerobic oxidative C–H amidation
2012
Intramolecular Hydroamination/Cyclisation of Aminoallenes Mediated by a Neutral Zirconocene Catalyst: A Computational Mechanistic Study
2007
Cross‐Coupling of Aryllithiums with Aryl and Vinyl Halides in Flow Microreactors
2012
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
Catalytic asymmetric hydroamination of non-activated olefins
2005
Copper‐Catalyzed One‐Pot Synthesis of Imidazo/Benzoimidazoquinazolinones by Sequential Ullmann‐Type Coupling and Intramolecular CH Amidation
2011
Gold(i)-catalyzed intramolecular hydroamination of unactivated CC bonds with alkyl ammonium salts
2008
A Highly Para‐Selective Copper(II)‐Catalyzed Direct Arylation of Aniline and Phenol Derivatives
2010
Asymmetric spiroacetalization catalysed by confined Brønsted acids
2012 StandoutNatureNobel
Manganese‐Catalyzed Oxidative Cross‐Coupling of Grignard Reagents with Oxygen as an Oxidant
2009
Arylation of unactivated arenes
2010
Synthesis of Extended π‐Systems through C–H Activation
2014 Standout
Palladium‐Catalyzed Cross‐Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize
2012 Standout
Gold(i)-catalyzed intramolecular hydroamination of unactivated alkenes with carboxamides
2006
Enzymatic assembly of carbon–carbon bonds via iron-catalysed sp3 C–H functionalization
2018 StandoutNatureNobel
Asymmetric additions to dienes catalysed by a dithiophosphoric acid
2011 Nature
Recent advances in organothorium and organouranium catalysis
2007
The Palladium‐Catalyzed C–H Activation of Benzylic gem‐Dialkyl Groups
2003
Copper(I)‐Mediated Oxidative Cross‐Coupling between Functionalized Alkynyl Lithium and Aryl Magnesium Reagents
2007
Copper‐ or Iron‐Catalyzed Arylation of Phenols from respectively Aryl Chlorides and Aryl Iodides
2008
Heterogeneous Pd/C‐Catalyzed Ligand‐Free, Room‐Temperature Suzuki–Miyaura Coupling Reactions in Aqueous Media
2007
Catalytic Functionalization of Indoles in a New Dimension
2009 Standout
Cobalt-catalyzed cross-coupling reactions
2008
Atroposelective Synthesis of Axially Chiral Biaryl Compounds
2005 Standout
Phosphine-free chiral metal catalysts for highly effective asymmetric catalytic hydrogenation
2010
A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes
2004
Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
2003 Standout
Synthesis of 5‐Alkyl[3,4‐c]thienopyrrole‐4,6‐dione‐Based Polymers by Direct Heteroarylation
2011
Comparison of Oxidative Aromatic Coupling and the Scholl Reaction
2013
Asymmetric Hydroalkoxylation of Non‐Activated Alkenes: Titanium‐Catalyzed Cycloisomerization of Allylphenols at High Temperatures
2015
Oxovanadium(v)-catalyzed oxidative biaryl synthesis from organoborate under O2
2006
Organosulfur Compounds: Electrophilic Reagents in Transition‐Metal‐Catalyzed Carbon–Carbon Bond‐Forming Reactions
2005
The Mechanisms of the Stille Reaction
2004
Recent advances in aryl–aryl bond formation by direct arylation
2009
Applications of and alternatives to π-electron-deficient azine organometallics in metal catalyzed cross-coupling reactions
2007
Anilide ortho‐Arylation by Using CH Activation Methodology
2005
Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation
2010
Palladium‐Catalyzed Oxidative Cyclization of N‐Aryl Enamines: From Anilines to Indoles
2008
Palladium‐Catalyzed Dehydrogenative Cross‐Couplings of Benzazoles with Azoles
2011
Oxidative Cross‐Coupling of Arenes Induced by Single‐Electron Transfer Leading to Biaryls by Use of Organoiodine(III) Oxidants
2007
2-Pyridinyl β-ketones as new ligands for room-temperature CuI-catalysed C–N coupling reactions
2009
Synthesis of bifunctional Au–Sn organic–inorganic catalysts for acid-free hydroamination reactions
2008
Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
2010 StandoutNobel
Aryl–aryl coupling via directed lithiation and oxidation
2005
Palladium catalyzed arylation for the synthesis of polyarenes
2007
Catalytic alkene cyclohydroamination via an imido mechanism
2008
A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes
2006
tBuLi‐Mediated One‐Pot Direct Highly Selective Cross‐Coupling of Two Distinct Aryl Bromides
2015 StandoutNobel
Palladium‐Catalyzed Desulfitative Mizoroki–Heck Couplings of Sulfonyl Chlorides with Mono‐ and Disubstituted Olefins: Rhodium‐Catalyzed Desulfitative Heck‐Type Reactions under Phosphine‐ and Base‐Free Conditions
2004
Organopalladium(iv) chemistry
2009
Biaryl synthesis with control of axial chirality
2006
Copper‐Catalyzed CC Bond Formation through CH Functionalization: Synthesis of Multisubstituted Indoles from N‐Aryl Enaminones
2009
Nickel catalyzed alkylation of N-aromatic heterocycles with Grignard reagents through direct C–H bond functionalization
2012
Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction
2010
Heterocycle synthesis by copper facilitated addition of heteroatoms to alkenes, alkynes and arenes
2007
Copper-catalyzed arene C–H bond cross-coupling
2009
A new heterogeneous catalyst for epoxidation of alkenes via one-step post-functionalization of IRMOF-3 with a manganese(ii) acetylacetonate complex
2011
A Simple and Efficient Iron‐Catalyzed Intramolecular Hydroamination of Unactivated Olefins
2006
Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling
2009 Standout
A general gold-catalyzed direct oxidative coupling of non-activated arenes
2007
Homogeneous Catalytic Hydroamination of Alkynes and Allenes with Ammonia
2008
Palladium-catalyzed direct arylation of simple arenes in synthesis of biaryl molecules
2006
Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents
2010
Ligand-free copper(i)-catalysed intramolecular direct C–H functionalization of azoles
2009
Intramolecular Hydroamination with Homogeneous Zinc Catalysts: Evaluation of Substituent Effects in N,N′‐Disubstituted Aminotroponiminate Zinc Complexes
2007
Homogeneous and heterogenized Au(iii ) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids
2005
Computed CH Acidity of Biaryl Compounds and Their Deprotonative Metalation by Using a Mixed Lithium/Zinc‐TMP Base
2013
Transition‐Metal‐Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage
2009 Standout
Cross‐Coupling in a Flow Microreactor: Space Integration of Lithiation and Murahashi Coupling
2010
Palladium‐Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids
2008
The enantioselective intramolecular aminative functionalization of unactivated alkenes, dienes, allenes and alkynes for the synthesis of chiral nitrogen heterocycles
2009
Direct arylation of aromatic C–H bonds catalyzed by Cp*Ir complexes
2004
Catalytic CC, CN, and CO Ullmann‐Type Coupling Reactions
2009 Standout
Base-catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a dimeric chiral diamidobinaphthyl dilithium salt
2006
Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes
2015
Iron‐Mediated Direct Arylation of Unactivated Arenes
2008
Catalytic Hydroaminoalkylation
2009
An Extremely Simple Dibenzopentalene Synthesis from 2‐Bromo‐1‐ethynylbenzenes Using Nickel(0) Complexes: Construction of Its Derivatives with Various Functionalities
2009
Rational Ligand Design in Constructing Efficient Catalyst Systems for Suzuki–Miyaura Coupling
2004
Versatile tools in the construction of substituted 2,2′-bipyridines—cross-coupling reactions with tin, zinc and boron compounds
2008
Synthesis of Medium‐Ring and Iodinated Biaryl Compounds by Organocuprate Oxidation
2005
The Suzuki homocoupling reaction under high-intensity ultrasound
2004
Palladium‐Catalyzed Cross‐Coupling Reactions of Diazine N‐Oxides with Aryl Chlorides, Bromides, and Iodides
2006
Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)
2007
Copper‐Catalyzed Aerobic Oxidative CH and CC Functionalization of 1‐[2‐(Arylamino)aryl]ethanones Leading to Acridone Derivatives
2013
Atroposelective Synthesis of Axially Chiral Biaryl Compounds
2005
Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products
2010 Standout
Copper-Mediated Intermolecular Direct Biaryl Coupling
2011
Establishment of Broadly Applicable Reaction Conditions for the Palladium-Catalyzed Direct Arylation of Heteroatom-Containing Aromatic Compounds
2009
Platinum‐Catalyzed Intermolecular Hydroamination of Alkenes: Halide‐Anion‐Promoted Catalysis
2007
Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles
2008
Direct C–H bond arylations and alkenylations with phenol-derived fluorine-free electrophiles
2012
Cross-Coupling Reactions of Aromatic and Heteroaromatic Silanolates with Aromatic and Heteroaromatic Halides
2009
Carbon−Carbon Bond Formation through Double sp2 C−H Activations: Synthesis of Ferrocenyl Oxazoline Derivatives
2007
Triazole-Based Monophosphines for Suzuki−Miyaura Coupling and Amination Reactions of Aryl Chlorides
2005
Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis
2008 Standout
Ruthenium‐Catalyzed Oxidative Homo‐Coupling of 2‐Arylpyridines
2009
A Mild and Versatile Method for Palladium‐Catalyzed Cross‐Coupling of Aryl Halides in Water and Surfactants
2003
3d Transition Metals for C–H Activation
2018 Standout
Modulating Reactivity and Diverting Selectivity in Palladium-Catalyzed Heteroaromatic Direct Arylation Through the Use of a Chloride Activating/Blocking Group
2010
Atropodiastereoselective Cleavage of Configurationally Unstable Biaryl Lactones with Amino Acid Esters
2006
New Chiral Rhodium and Iridium Complexes with Chiral Diamine Ligands for Asymmetric Transfer Hydrogenation of Aromatic Ketones
1999 StandoutNobel
A Large Scale Process for the Preparation of Thymitaq
2008
Rhodium/N‐Heterocyclic Carbene‐Catalyzed Cross‐Couplings of Aryl Arenesulfonates with Arylboronic Acids
2008
Synthesis of Benzo[c]phenanthridine Alkaloids Using a Palladium-catalyzed Aryl-Aryl Coupling Reaction
2005
Dinickel(II) Complexes of Bis(N-heterocyclic carbene) Ligands Containing [Ni2(μ-OH)] Cores as Highly Efficient Catalysts for the Coupling of Aryl Chlorides
2008
Cross-Coupling Reactions of Arylsilanols with Substituted Aryl Halides
2003
Iron‐Catalyzed ortho Monoarylation of Benzamide Derivatives
2012
Triazole-Based Monophosphine Ligands for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Chlorides
2006
Total synthesis of the antimalarial naphthylisoquinoline alkaloid 5-epi-4′-O-demethylancistrobertsonine C by asymmetric Suzuki cross-coupling
2008
Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions
2011 Standout
An Adventure in Sustainable Cross-Coupling of Phenols and Derivatives via Carbon–Oxygen Bond Cleavage
2016
The Synthesis and Resolution of 2,2‘-, 4,4‘-, and 6,6‘-Substituted Chiral Biphenyl Derivatives for Application in the Preparation of Chiral Materials
2006
Proton-Abstraction Mechanism in the Palladium-Catalyzed Intramolecular Arylation: Substituent Effects
2007
Palladium-Catalyzed C−H Homocoupling of Bromothiophene Derivatives and Synthetic Application to Well-Defined Oligothiophenes
2006
Synthesis of Biaryls via Catalytic Decarboxylative Coupling
2006 Science
Rigid-Core Fluorescent Oligothiophene-S,S-dioxide Isothiocyanates. Synthesis, Optical Characterization, and Conjugation to Monoclonal Antibodies
2003
Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation
2012 StandoutNobel
Direct arylation of azine N-oxides with aryl triflates
2009
Palladium-Catalyzed Perarylation of 3-Thiophene- and 3-Furancarboxylic Acids Accompanied by C−H Bond Cleavage and Decarboxylation
2008
Highly efficient and practical phosphoramidite–copper catalysts for amination of aryl iodides and heteroaryl bromides with alkylamines and N(H)-heterocycles
2006
Copper-catalyzed domino synthesis of benzo[b]thiophene/imidazo[1,2-a]pyridines by sequential Ullmann-type coupling and intramolecular C(sp2)–H thiolation
2015
Metal-Catalyzed Intermolecular Hydrofunctionalization of Allenes: Easy Access to Allylic Structures via the Selective Formation of C–N, C–C, and C–O Bonds
2020
Remarkably facile Heck and Suzuki reactions in water using a simple cationic surfactant and ligand-free palladium catalysts
2005
Pd-Catalyzed Cross-Coupling of Aryllithium Reagents with 2-Alkoxy-Substituted Aryl Chlorides: Mild and Efficient Synthesis of 3,3′-Diaryl BINOLs
2014 StandoutNobel
Copper-Catalyzed Homodimerization of Nitronates and Enolates under an Oxygen Atmosphere
2012
Preparation of poly(fluorene)s using trans‐bis(dicyclohexylamine)palladium diacetate as a catalyst: Scope and limitations
2006
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
2011 Standout
Emergence of Copper‐Mediated Formation of C–C Bonds
2016
Direct arylation of imidazo[2,1‐b]thiazoles and thiazoles with aryl iodides via CuCl2/PPh3‐catalyzed C–H bond functionalization
2015
Copper-Catalyzed C−P Bond Construction via Direct Coupling of Phenylboronic Acids with H-Phosphonate Diesters
2011
Iridium-Catalyzed, Intermolecular Hydroetherification of Unactivated Aliphatic Alkenes with Phenols
2013
Copper-Catalyzed Diels−Alder Reactions
2008
Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices
2009 Standout
Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates
2009
Chiral 2-(2-diphenylphosphinophenyl)-5,6,7,8-tetrahydroquinolines: new P–N ligands for asymmetric catalysis
2001
Catalysts for Suzuki−Miyaura Coupling Processes: Scope and Studies of the Effect of Ligand Structure
2005 Standout
Gold-catalyzed direct oxidative coupling reactions of non-activated arenes
2008
Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction
2009
A Concise Update on the Applications of Chiral Ferrocenyl Phosphines in Homogeneous Catalysis Leading to Organic Synthesis
2003
Enantioselective Hydroamination of Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer
2020
Elements of Regiocontrol in Palladium-Catalyzed Oxidative Arene Cross-Coupling
2007 Standout
Practical copper-catalyzed N-arylation of nitrogen heterocycles with aryl halides under ligand and additive free conditions
2006
Active ruthenium-(N-heterocyclic carbene) complexes for hydrogenation of ketones
2006
Palladium-Catalyzed Suzuki Cross-Coupling Reactions in Ambient Temperature Ionic Liquids: Evidence for the Importance of Palladium Imidazolylidene Complexes
2003
A Highly Active Palladium Catalyst for Intermolecular Hydroamination. Factors that Control Reactivity and Additions of Functionalized Anilines to Dienes and Vinylarenes
2006
Methods Utilizing First-Row Transition Metals in Natural Product Total Synthesis
2017
Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation
2009
Cu(OAc)2/Pyrimidines‐Catalyzed Cross‐coupling Reactions of Aryl Iodides and Activated Aryl Bromides with Alkynes under Aerobic, Solvent‐free and Palladium‐free Conditions
2006
Recent Developments in Ruthenium-Catalyzed C–H Arylation: Array of Mechanistic Manifolds
2017
Mild and Efficient Copper-Catalyzed Amination of Aryl Bromides with Primary Alkylamines
2003
Scandium-Catalyzed Intramolecular Hydroamination. Development of a Highly Active Cationic Catalyst
2004
Vanadium(IV) tetrachloride catalyzed oxidative homo-coupling of aryl lithium under mild reaction condition
2012
A highly active palladium-phosphoramidite catalyst for the Suzuki cross-coupling of aryl bromides
2005
Concise synthesis of quinazoline alkaloids, luotonins A and B, and rutaecarpine
2004
Electropolymerized Pd-Containing Thiophene Polymer: A Reusable Supported Catalyst for Cross-Coupling Reactions
2007
Asymmetric Catalytic Hydroamination of Activated Olefins in Ionic Liquids
2007
Synthesis of graphislactones A–D through a palladium-mediated biaryl coupling reaction of phenyl benzoate derivatives
2005
Cobalt-Catalyzed Hydroarylations and Hydroaminations of Alkenes in Tunable Aryl Alkyl Ionic Liquids
2018
Palladium-catalyzed direct arylation of thiazoles with aryl bromides
2003
C–H Arylation Reaction: Atom Efficient and Greener Syntheses of π-Conjugated Small Molecules and Macromolecules for Organic Electronic Materials
2013
Multitechnique Approach to Reveal the Mechanism of Copper(II)-Catalyzed Arylation Reactions
2010
Regioselective Synthesis of 1,5-Diaryl-1H-imidazoles by Palladium-Catalyzed Direct Arylation of 1-Aryl-1H-imidazoles
2005
Iridium catalysts for the asymmetric hydrogenation of olefins with nontraditional functional substituents
2007
Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
2008 Standout
Copper-Catalyzed Aerobic Oxidative Intramolecular C–H Amination Leading to Imidazobenzimidazole Derivatives
2011
Straightforward access to aryl-substituted tetrathiafulvalenes by palladium-catalysed direct C–H arylation and their photophysical and electrochemical properties
2011
Regioselectivity in the Biaryl Coupling Reactions of 1-[(1,3-Benzodioxol-5-yl)methyl]-7-iodo-2,3-dihydroindole Using Palladium Reagent
2006
Robust Ruthenium(II)-Catalyzed C–H Arylations: Carboxylate Assistance for the Efficient Synthesis of Angiotensin-II-Receptor Blockers
2014
Modular N,O‐Chelating Ligands: Group‐4 Amidate Complexes for Catalytic Hydroamination
2007
Iron-Mediated Direct Suzuki−Miyaura Reaction: A New Method for the ortho-Arylation of Pyrrole and Pyridine
2010
Functionalizations of Aryl CH Bonds in 2‐Arylpyridines via Sequential Borylation and Copper Catalysis
2012
The Palladium‐Catalyzed C–H Activation of Benzylic gem‐Dialkyl Groups
2003
The Slow‐Release Strategy in Suzuki–Miyaura Coupling
2010
Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls
2003
Carbon−Carbon Coupling Reactions Catalyzed by Heterogeneous Palladium Catalysts
2006 Standout
Efficient Synthesis of a Variety of New Functionalized Oxacalixarenes by Ullmann Coupling Reactions
2006
Towards a facile synthesis of triarylethanones: palladium-catalyzed arylation of ketone enolates under homogeneous and heterogeneous conditions
2004
Facile Synthesis and Isolation of Secondary Amines via a Sequential Titanium(IV)‐Catalyzed Hydroamination and Palladium‐Catalyzed Hydrogenation
2016
Nickel−NHC-Catalyzed α-Arylation of Acyclic Ketones and Amination of Haloarenes and Unexpected Preferential N-Arylation of 4-Aminopropiophenone
2007
CuI catalyzed C–N bond forming reactions between aryl/heteroaryl bromides and imidazoles in [Bmim]BF4
2006
Iron‐Mediated Direct Arylation of Unactivated Arenes
2008
Synthesis of Benzocyclobutenes by Palladium-Catalyzed C−H Activation of Methyl Groups: Method and Mechanistic Study
2008
Palladium charcoal-catalyzed, ligandless Suzuki reaction by using tetraarylborates in water
2005
Cobalt-promoted selective arylation of benzamides and acrylamides with arylboronic acids
2016
Cross-coupling of organoboronic acids and sulfinate salts using catalytic copper(II) acetate and 1,10-phenanthroline: synthesis of aryl and alkenylsulfones
2007
Palladium-catalysed synthesis of nonsymmetrically disubstituted-1,1′-biphenyls from o-substituted aryl iodides through aryl coupling and delayed hydrogenolysis
2005
Novel CuO Nanoparticle Catalyzed C−N Cross Coupling of Amines with Iodobenzene
2007
Pd-catalyzed ortho-arylation of phenylacetamides, benzamides, and anilides with simple arenes using sodium persulfate
2010
Direct C–H Arylation of Heteroarenes with Copper Impregnated on Magnetite as a Reusable Catalyst: Evidence for CuO Nanoparticle Catalysis in Solution
2016
Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic and Mechanistic Investigations
2006
α-Fluorinated Ethers, Thioethers, and Amines: Anomerically Biased Species
2005
Rhodium-Catalyzed Arylation Using Arylboron Compounds: Efficient Coupling with Aryl Halides and Unexpected Multiple Arylation of Benzonitrile
2005
Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination
2020
Base-free anaerobic Cu(II) catalysed aryl-nitrogen bond formations
2004
Palladium-Catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C−H Activation
2009
Nickel- and Palladium-Catalyzed Coupling of Aryl Fluorosulfonates with Aryl Boronic Acids Enabled by Sulfuryl Fluoride
2015
First-Row Late Transition Metals for Catalytic Alkene Hydrofunctionalisation: Recent Advances in C-N, C-O and C-P Bond Formation
2017
Palladium-Catalyzed Inter- and Intramolecular Coupling Reactions of Aryl and Vinyl Halides Mediated by Indium
2004
Palladium‐Catalyzed Monoselective Halogenation of CH Bonds: Efficient Access to Halogenated Arylpyrimidines using Calcium Halides
2010
Copper-Catalyzed Aerobic Oxidative Intramolecular Alkene C–H Amination Leading to N-Heterocycles
2011
Chiral Neutral Zirconium Amidate Complexes for the Asymmetric Hydroamination of Alkenes
2006
Pd‐PEPPSI‐IPent: An Active, Sterically Demanding Cross‐Coupling Catalyst and Its Application in the Synthesis of Tetra‐Ortho‐Substituted Biaryls
2009
New calcineurin inhibiting 3-dimethylaminopropyl substituted diarylheterocycles by sonogashira reactions and catalytic hydrogenation
2005
Enantioselective Hydrogenation of β‐Keto Esters using Chiral Diphosphine‐Ruthenium Complexes: Optimization for Academic and Industrial Purposes and Synthetic Applications
2003
Palladium‐ and Copper‐Mediated Direct C‐2 Arylation of Azoles — Including Free (NH)‐Imidazole, ‐Benzimidazole and ‐Indole — Under Base‐Free and Ligandless Conditions
2006
Anilide ortho‐Arylation by Using CH Activation Methodology
2005
Copper-Mediated Formally Dehydrative Biaryl Coupling of Azine N-Oxides and Oxazoles
2015
Highly efficient, base-catalysed, intramolecular hydroamination of non-activated olefins
2007
Development and Applications of Disulfonimides in Enantioselective Organocatalysis
2015 StandoutNobel
Intramolecular 5-endo-Trig Aminomercuration of β-Hydroxy-γ-alkenylamines: Efficient Route to a Pyrrolidine Ring and Its Application for the Synthesis of (+)-Castanospermine and Analogues
2006
Palladium‐Catalyzed Cross‐Coupling Reactions of Diazine N‐Oxides with Aryl Chlorides, Bromides, and Iodides
2006
Palladium-Catalyzed Direct Arylation of Nitro-Substituted Aromatics with Aryl Halides
2008
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Iron-Catalyzed Direct Arylation through an Aryl Radical Transfer Pathway
2010
Suzuki–Miyaura Cross‐Coupling With Quasi‐Heterogeneous Palladium
2003
Tetrabenzyltitanium: An Improved Catalyst for the Activation of sp3 CH Bonds Adjacent to Nitrogen Atoms
2009
Asymmetric Hydroalkoxylation of Non‐Activated Alkenes: Titanium‐Catalyzed Cycloisomerization of Allylphenols at High Temperatures
2015
Chiral Phosphoric Acid‐Catalyzed Asymmetric Oxidation of Aryl Alkyl Sulfides and Aldehyde‐Derived 1,3‐Dithianes: Using Aqueous Hydrogen Peroxide as the Terminal Oxidant
2012
Oxidative C–H/C–H Coupling Reactions between Two (Hetero)arenes
2017
Catalytic Direct Arylation with Aryl Chlorides, Bromides, and Iodides: Intramolecular Studies Leading to New Intermolecular Reactions
2005
Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development
2014
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
2009 Standout
Palladium/Copper‐Catalyzed Decarboxylative Cross‐Coupling of Aryl Chlorides with Potassium Carboxylates
2008
Various P∗-chiral phosphite-type ligands: their synthesis, stereochemistry and use in Pd-catalysed allylation
2007
Homogeneous and supported copper(II) acetate as catalyst for CO coupling reactions
2006
Palladium-Catalyzed Intramolecular Asymmetric Hydroamination, Hydroalkoxylation, and Hydrocarbonation of Alkynes
2006
Copper(I)-catalysed homo-coupling of aryldiazonium salts: synthesis of symmetrical biaryls
2007
Synthesis and Characterization of Alkyllanthanum Biphenolate Complexes as Catalysts for Hydroamination/Cyclization and Hydrosilylation
2004
Copper-catalyzed oxidative decarboxylative C–H arylation of benzoxazoles with 2-nitrobenzoic acids
2015
Efforts Directed toward the Synthesis of Colchicine: Application of Palladium-Catalyzed Siloxane Cross-Coupling Methodology
2005
Intramolecular Pd(II)-Catalyzed Oxidative Biaryl Synthesis Under Air: Reaction Development and Scope
2008
Diastereospecific Intramolecular Ullmann Couplings: Unique Chiral Auxiliary for the Preparation of 3,3‘-Disubstituted MeO-BIPHEP Derivatives
2006
Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines
2016
Mechanistic Study of Chemoselectivity in Ni-Catalyzed Coupling Reactions between Azoles and Aryl Carboxylates
2014
Advances in the Chemistry of Tetrahydroquinolines
2011 Standout
Polycondensation of Dibromofluorene Analogues with Tetrafluorobenzene via Direct Arylation
2011
Palladium‐Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids
2008
Palladium‐katalysierte oxidative Cyclisierung von N‐Aryl‐Enaminen: von Anilinen zu Indolen
2008
Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals
2015
The First Suzuki Cross-Couplings of Aryltrimethylammonium Salts
2003
Copper-Catalyzed Domino Annulation Approaches to the Synthesis of Benzoxazoles under Microwave-Accelerated and Conventional Thermal Conditions
2008
Nickel-catalyzed ortho-halogenation of unactivated (hetero)aryl C–H bonds with lithium halides using a removable auxiliary
2016
Synthesis, Structural Characterization, and Reactivity of Organolanthanides Derived from a New Chiral Ligand, (R)-Bis(pyrrol-2-ylmethyleneamino)-1,1‘-binaphthyl
2007
Gold‐Catalyzed Hydroamination of C–C Multiple Bonds
2006
Selected Patented Cross-Coupling Reaction Technologies
2006 Standout
Manganese(III) acetate-mediated synthesis of biaryls under microwave irradiation
2009
Air-Stable and Phosphine-Free Iridium Catalysts for Highly Enantioselective Hydrogenation of Quinoline Derivatives
2008
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation
2007 Standout
A Solution to the 2-Pyridyl Organometallic Cross-Coupling Problem: Regioselective Catalytic Direct Arylation of Pyridine N-Oxides
2005
Fluorine in Pharmaceuticals: Looking Beyond Intuition
2007 StandoutScience
Pyrrolidine and Piperidine Formation via Copper(II) Carboxylate-Promoted Intramolecular Carboamination of Unactivated Olefins: Diastereoselectivity and Mechanism
2007
Homocoupling reactions of alkynes, alkenes and alkyl compounds
2010
Hydrogen Autotransfer in the N-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles
2009 Standout
Copper‐Mediated Thiolation of Unactivated Heteroaryl C−H Bonds with Disulfides under Ligand‐ and Metal‐Oxidant‐Free Conditions
2017
Intramolecular Hydroamination of Unactived Olefins with Ti(NMe2)4 as a Precatalyst
2005
Direct coupling of arenes and iodoarenes catalyzed by a rhodium complex with a strongly π-accepting phosphite ligand
2008 Nobel
Non-conventional methodologies for transition-metal catalysed carbon–carbon coupling: a critical overview. Part 2: The Suzuki reaction
2007
Sulfuration of the C(sp2)–H bond of enaminones: a protocol for the synthesis of thioether using elemental sulfur as a sulfurating reagent
2016
Iron-Catalyzed Homocoupling of Aryl Halides and Derivatives in the Presence of Alkyllithiums
2013
Catalytic Sequential Reactions Involving Palladacycle-Directed Aryl Coupling Steps
2008
Mono-cyclopentadienyl complexes of lanthanum: synthesis and characterization of anilido derivatives
2004
A Scaleable Synthesis of Dutasteride: A Selective 5α-Reductase Inhibitor
2007
Oxidative Coupling of Arylboronic Acids with Arenes via Rh-Catalyzed Direct C−H Arylation
2007
Nickel-Catalyzed Direct Thiolation of C(sp3)–H Bonds in Aliphatic Amides
2015
Self-supported chiral catalysts for heterogeneous enantioselective reactions
2007
Synthesis of 2,5-diaryloxazoles through van Leusen reaction and copper-mediated direct arylation
2009
Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene)
2010
Highly efficient copper-catalyzed N-arylation of alkylamines with aryl iodides using phosphoramidite as ligand
2005
Facile Access to Optically Active Ferrocenyl Derivatives with Direct Substitution of the Hydroxy Group Catalyzed by Indium Tribromide
2007
Direct Transition-Metal-Free Intramolecular Arylation of Phenols
2008
Transition metal catalyzed oxidative functionalization of carbon–hydrogen bonds
2006
Copper-Catalyzed Coupling of Arylboronic Acids and Amines
2001
Amination Reactions of Aryl Halides with Nitrogen‐Containing Reagents Catalyzed by CuI in Ionic Liquid
2008
Asymmetric hetero-Diels–Alder reactions of carbonyl compounds
2009
Cu(II)-mediated oxidative dimerization of 2-phenylpyridine derivatives
2008
The Asymmetric Suzuki Coupling Route to Axially Chiral Biaryls
2005
Neutral Group‐IV Metal Catalysts for the Intramolecular Hydroamination of Alkenes
2008
Nickel‐Catalyzed C−H Heteroarylation of Chiral Oxazolines
2017
Copper in cross-coupling reactions
2004 Standout
Intermolecular hydroamination and hydroarylation reactions of alkenes in ionic liquids
2006
Intermolecular Cross-Coupling of Simple Arenes via C−H Activation by Tuning Concentrations of Arenes and TFA
2006
Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates
2009
Mild and efficient copper-catalyzed N-arylation of alkylamines and N–H heterocycles using an oxime-phosphine oxide ligand
2005
Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate
2010
Cu-nanoparticle catalyzed O-arylation of phenols with aryl halides via Ullmann coupling
2007
Effect of oxygen substituents on the regioselectivity of the Pd-assisted biaryl coupling reaction of benzanilides
2005
Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction
2008
Concise Synthesis of 11H-Indolizino- [1,2-b]quinolin-9-one by an Aryl-Aryl Coupling Reaction Using Pd Reagent
2004
Palladiumkatalysierte Kreuzkupplungen in der Totalsynthese
2005
Active catalytic centers in silica-supported Cu(II) and Mn(II) biomimetic complexes: Correlation between catalytic and EPR data
2006
Chiral 5-(diphenylphosphanyl)-1,2,3,4-tetrahydroacridines: new N,P-ligands for asymmetric catalysis
2005
Aerobic Copper-Catalyzed Organic Reactions
2013 Standout
Chemical and catalytic activity of copper nanoparticles prepared via metal vapor synthesis
2004
Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds
2010
Sidearm Effect: Improvement of the Enantiomeric Excess in the Asymmetric Michael Addition of Indoles to Alkylidene Malonates
2002
Room Temperature Hydroamination ofN-Alkenyl Ureas Catalyzed by a Gold(I)N-Heterocyclic Carbene Complex
2006
Enantioselective Intramolecular Alkene Hydroaminations Catalyzed by Yttrium Complexes of Axially Chiral Bis(thiolate) Ligands
2005
The Versatile Thiophene: An Overview of Recent Research on Thiophene‐Based Materials
2005
Nickel-Catalyzed Direct Alkynylation of Azoles with Alkynyl Bromides
2009
An efficient BINAM–copper(II) catalyzed Ullmann-type synthesis of diaryl ethers
2007
Synthesis of 5‐Alkyl[3,4‐c]thienopyrrole‐4,6‐dione‐Based Polymers by Direct Heteroarylation
2011
Synthesis of Novel Chelating Benzimidazole-Based Carbenes and Their Nickel(II) Complexes: Activity in the Kumada Coupling Reaction
2009
Total Synthesis of (±)-Rhazinal Using Novel Palladium-Catalyzed Cyclizations
2009
Mechanisms and Origins of Switchable Chemoselectivity of Ni-Catalyzed C(aryl)–O and C(acyl)–O Activation of Aryl Esters with Phosphine Ligands
2014
Organoschwefelverbindungen: elektrophile Reagentien für übergangsmetallkatalysierte C‐C‐Verknüpfungen
2005
Copper‐Promoted Thiolation of C(sp2)–H Bonds Using a 2‐Amino Alkylbenzimidazole Directing Group
2017
C–H functionalization by high-valent Cp*Co(iii ) catalysis
2017
C–H arylation of unactivated arenes with aryl halides catalyzed by cobalt porphyrin
2010
Highly Active Au(I) Catalyst for the Intramolecularexo-Hydrofunctionalization of Allenes with Carbon, Nitrogen, and Oxygen Nucleophiles
2006
A General Method for Copper-Catalyzed Arene Cross-Dimerization
2011
Asymmetric Transformations under Iridium/Chiral Diene Catalysis
2016
Copper-catalyzed cross-coupling of amides and potassium alkenyltrifluoroborate salts: a general approach to the synthesis of enamides
2010
Identification of simple arylfluorosulfates as potent agents against resistant bacteria
2021 StandoutNobel
Aminotroponiminate zinc complexes as catalysts for the intramolecular hydroamination
2010
Palladium-Mediated Intramolecular Biaryl Coupling Reaction for Natural Product Synthesis
2008
Carbon−Nitrogen Bond Formation Involving Well-Defined Aryl−Copper(III) Complexes
2008
Enantioselective Hydroamination/Cyclization Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)-2′-(dimethylamino)-1,1′-binaphthyl
2008
Recyclable Copper Catalyst for meta‐Selective CH Bond Arylation
2011
Confined acids catalyze asymmetric single aldolizations of acetaldehyde enolates
2018 StandoutScienceNobel
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
Copper-catalyzed amination of aryl halides with nitrogen-containing heterocycle using hippuric acid as the new ligand
2007
Stepwise Construction of Head-to-Tail-Type Oligothiophenes via Iterative Palladium-Catalyzed CH Arylation and Halogen Exchange
2009
Iron(III) Chloride Catalyzed Oxidative Coupling of Aromatic Nuclei
2008
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
Functional Oligothiophenes: Molecular Design for Multidimensional Nanoarchitectures and Their Applications
2009 Standout
The first total synthesis and structural determination of TMC-66
2007
Oxidative Nickel–Air Catalysis in CH Arylation: Direct Cross‐Coupling of Azoles with Arylboronic Acids using Air as Sole Oxidant
2010
A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds
2008
Rhodium‐Catalyzed Oxidative Homocoupling of Boronic Acids
2008
Amino Acid Promoted CuI-Catalyzed C−N Bond Formation between Aryl Halides and Amines or N-Containing Heterocycles
2005
Palladium(II)-Catalyzed Oxidative C−H/C−H Cross-Coupling of Heteroarenes
2010
Palladium‐Catalyzed, tert‐Butyllithium‐Mediated Dimerization of Aryl Halides and Its Application in the Atropselective Total Synthesis of Mastigophorene A
2016 StandoutNobel
Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals
2011 Standout
Regioselective Functionalization of the Imidazole Ring via Transition Metal‐Catalyzed CN and CC Bond Forming Reactions
2010
Toward Safer Methodologies for the Synthesis of Polyheterocyclic Systems: Intramolecular Arylation of Arenes under Mizoroki−Heck Reaction Conditions
2003
Radical Ions of α,α‘-Bis(diphenylamino)-capped Oligothiophenes: A Combined Spectroelectrochemical and Theoretical Study
2006
A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes
2004
Copper‐Mediated C–H Activation of 1,3,4‐Oxadiazoles with 1,1‐Dibromo‐1‐alkenes Using PEG‐400 as a Solvent Medium: Distinct Approach for the Alkynylation of 1,3,4‐Oxadiazoles
2011
Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis
2004
An Efficient Approach to 3-Bromo-6-chloro-phenanthrene-9,10-dione
2008
Synthesis, Optical, and Electrochemical Properties of a New Family of Dendritic Oligothiophenes
2006
The ‘lactone method’: enantioselective preparation of novel P,N-biaryl ligands and their use in the synthesis of the biarylic alkaloids, ancistrotanzanine B and ancistroealaine A
2004
Copper-Mediated C−H Bond Arylation of Arenes with Arylboronic Acids
2008
Mild and General Conditions for the Cross-Coupling of Aryl Halides with Pentafluorobenzene and Other Perfluoroaromatics
2006
Copper‐Catalyzed Aerobic Oxidative Synthesis of 5‐Substituted Imidazo/Benzimidazoquinazolinones through Intramolecular CH Amination
2012
Übergangsmetallkatalysierte direkte Arylierungen von (Hetero)Arenen durch C‐H‐Bindungsbruch
2009
Synthesis and Catalytic Properties of Phenylene-Bridged Binuclear Organolanthanide Complexes
2008
Planar‐Chiral [2.2]Paracyclophane‐Based Amides as Proligands for Titanium‐ and Zirconium‐Catalyzed Hydroamination
2017
ZnBr2‐Catalyzed Efficient Oxidative Homo Coupling of Aryl Magnesium Bromides
2006
Efficient catalysis of Ullmann-type arylation reactions by a novel trinuclear copper(I) complex with a chelating tricarbene ligand
2008
A Route to Annulated Indoles via a Palladium-Catalyzed Tandem Alkylation/Direct Arylation Reaction
2005
Copper-mediated direct arylation of benzoazoles with aryl iodides
2008
Copper-catalyzed N-arylation of diazoles with aryl bromides using KF/Al2O3: an improved protocol
2006
Weak O‐Assistance Outcompeting Strong N,N‐Bidentate Directing Groups in Copper‐Catalyzed C−H Chalcogenation
2016
3,3‘-Bis(trisarylsilyl)-Substituted Binaphtholate Rare Earth Metal Catalysts for Asymmetric Hydroamination
2006
Gold (I) and (III) catalyze Suzuki cross-coupling and homocoupling, respectively
2006
Effect of microwave heating on Ullmann-type heterocycle-aryl ether synthesis using chloro-heterocycles
2006
Catalytic Asymmetric Oxidation of Cyclic Dithioacetals: Highly Diastereo- and Enantioselective Synthesis of the S-Oxides by a Chiral Aluminum(salalen) Complex
2010
Application of a catalytic palladium biaryl synthesis reaction, via C–H functionalization, to the total synthesis of Amaryllidaceae alkaloids
2004
Die Mechanismen der Stille‐Reaktion
2004
IDPi Catalysis
2019 StandoutNobel
Palladium-Catalyzed Direct C-2 Arylation of Indoles with Potassium Aryltrifluoroborate Salts
2008
Rhodium-catalyzed regioselective arylation of phenylazoles and related compounds with arylboron reagents via C–H bond cleavage
2008
Oxidative aromatische Kupplung und Scholl‐Reaktion im Vergleich
2013
Copper(ii )-mediated regioselective N-arylation of pyrroles, indoles, pyrazoles and carbazole via dehydrogenative coupling
2016
Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions
2011
CuI/L (L=pyridine-functionalized 1,3-diketones) catalyzed C–N coupling reactions of aryl halides with NH-containing heterocycles
2008
Blue Emitting Polymers as Host Materials of Phosphorescent Dopant and Their Electroluminescent Properties
2005
Copper-catalyzed ortho-halogenation of arenes and heteroarenes directed by a removable auxiliary
2015
Palladium-Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air
2008
Non-conventional methodologies for transition-metal catalysed carbon–carbon coupling: a critical overview. Part 1: The Heck reaction
2005
Preparation and catalytic applications of partially fluorinated binaphthol ligands
2004
An efficient phosphine-free palladium coupling for the synthesis of new 2-arylbenzo[b]thiophenes
2004
Catalytic C−C Bond Formation Accomplished by Selective C−F Activation of Perfluorinated Arenes
2006
Oxidation of sulfides to sulfoxides and sulfones with 30% hydrogen peroxide under organic solvent- and halogen-free conditions
2001 StandoutNobel
Copper-Mediated Remote C–H Bond Chalcogenation of Quinolines on the C5 Position
2015
Transition Metal‐Catalyzed Asymmetric Hydroamination of Alkenes (AHA)
2005
The Chemistry and Applications of Metal-Organic Frameworks
2013 StandoutScienceNobel
Cu(I)-catalyzed intramolecular cyclization of ene-carbamates: synthesis of indoles and pyrrolo[2,3-c]pyridines
2005
Atroposelective Biaryl Coupling with Chiral Catalysts: Total Synthesis of the Antileishmanial Naphthylisoquinoline Alkaloids Ancistrotanzanine B and Ancistroealaine A
2003
Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination
2006
Nickel-catalyzed intramolecular C–H arylation using aryl pivalates as electrophiles
2013
Copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones
2004 StandoutNobel
Activation of olefins via asymmetric Brønsted acid catalysis
2018 StandoutScienceNobel
Copper-Mediated Annulative Direct Coupling of o-Alkynylphenols with Oxadiazoles: A Dehydrogenative Cascade Construction of Biheteroaryls
2011
Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling
2011
Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents
2010
Iron-Catalyzed Oxidative Homo-Coupling of Aryl Grignard Reagents
2005
Catalytic Intermolecular Direct Arylation of Perfluorobenzenes
2006
Generation of Aryl Radicals from Arylboronic Acids by Manganese(III) Acetate: Synthesis of Biaryls and Heterobiaryls
2002
Transition metal catalyzed cross-coupling of aryl Grignard reagents with aryl fluorides via Pd- or Ni-activation of the C–F bond: an efficient synthesis of unsymmetrical biaryls – application of microwave technology in ligand and catalyst screening
2004
Synthesis and Characterization of Blue-Light-Emitting Alternating Copolymers of 9,9-Dihexylfluorene and 9-Arylcarbazole
2005
Synthesis and structural chemistry of arene-ruthenium half-sandwich complexes bearing an oxazolinyl–carbene ligand
2006
Enantioselective addition of alkynes to imines in ionic liquids
2004
Direct C−H Transformation via Iron Catalysis
2010 Standout
A Meta-Selective Copper-Catalyzed C–H Bond Arylation
2009 Science
Copper(II)-Catalyzed Ether Synthesis from Aliphatic Alcohols and Potassium Organotrifluoroborate Salts
2003
Enantioselective Synthesis of Sulfoxides: 2000−2009
2010
Organophosphine Oxide/Sulfide-Substituted Lanthanide Binaphtholate Catalysts for Enantioselective Hydroamination/Cyclization
2006
Katalytische C‐C‐, C‐N‐ und C‐O‐Ullmann‐Kupplungen
2009
Cu-Catalyzed Azide−Alkyne Cycloaddition
2008 StandoutNobel
Modified BINAP: The How and the Why
2005
Palladium‐Iminodiacetic Acid Immobilized on pH‐Responsive Polymeric Microspheres: Efficient Quasi‐Homogeneous Catalyst for Suzuki and Heck Reactions in Aqueous Solution
2008
Highly enantioselective hydrogenation of quinolines under solvent-free or highly concentrated conditions
2009
Iron‐Catalyzed Mizoroki–Heck Cross‐Coupling Reaction with Styrenes
2008
Palladium/2,2′-bipyridyl/Ag2CO3 catalyst for C–H bond arylation of heteroarenes with haloarenes
2011
Enantioselective Direct-Addition of Terminal Alkynes to Imines Catalyzed by Copper(I)pybox Complex in Water and in Toluene
2002
An Efficient Copper‐Catalyzed Amination of Aryl Halides by Aqueous Ammonia
2009
Functionalized Aminotroponiminate Zinc Complexes as Catalysts for the Intramolecular Hydroamination of Alkenes
2010
N-Hydroxyimides as Efficient Ligands for the Copper-Catalyzed N-Arylation of Pyrrole, Imidazole, and Indole
2007
Internal Alkene Hydroaminations Catalyzed by Zirconium(IV ) Complexes and Asymmetric Alkene Hydroaminations Catalyzed by Yttrium(III ) Complexes
2006
Synthesis of 5,5′-diarylated 2,2′-bithiophenes via palladium-catalyzed arylation reactions
2004
Electrogenerated poly(thiophenes) derivatized by bipyridine ligands and metal complexes
2004
Suzuki route to regioregular polyalkylthiophenes using Ir-catalysed borylation to make the monomer, and Pd complexes of bulky phosphanes as coupling catalysts for polymerisation
2006
Efficient Anti‐Markovnikov‐Selective Catalysts for Intermolecular Alkyne Hydroamination: Recent Advances and Synthetic Applications
2014
Homocoupling of Arylboronic Acids Catalyzed by 1,10‐Phenanthroline‐Ligated Copper Complexes in Air
2009
Rhodium-Catalyzed Carbon−Carbon Bond Forming Reactions of Organometallic Compounds
2002
ortho-Arylation of Benzamides
2006
Atropselektive Synthese axial‐chiraler Biaryle
2005
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
2000 Standout
Cu‐Catalyzed Intramolecular Amidation of Unactivated C(sp3)−H Bonds To Synthesize N‐Substituted Indolines
2016
A General and Mild Ullmann-Type Synthesis of Diaryl Ethers
2004
Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism
2008
Chiral Oxazoline‐NHC Ligands with and without CR2 Bridges: A Comparative Study in Rhodium Hydrosilylation Catalysis
2009
Development of an Open-Air and Robust Method for Large-Scale Palladium-Catalyzed Cyanation of Aryl Halides: The Use of i-PrOH to Prevent Catalyst Poisoning by Oxygen
2009
Copper‐Mediated ortho‐Arylation of Benzamides with Arylboronic Acid
2016
Direct C−H Arylation of (Hetero)arenes with Aryl Iodides via Rhodium Catalysis
2006 Nobel
Poly(α-vinyl-ω-alkyloligothiophene) Side-Chain Polymers. Synthesis, Fluorescence, and Morphology
2004
Catalytic and Highly Regioselective Cross-Coupling of Aromatic C−H Substrates
2007
Dual C–H activations of electron-deficient heteroarenes: palladium-catalyzed oxidative cross coupling of thiazoles with azine N-oxides
2012
Asymmetric hydrofunctionalization of minimally functionalized alkenesviaearth abundant transition metal catalysis
2017
Cross‐Coupling in a Flow Microreactor: Space Integration of Lithiation and Murahashi Coupling
2010
Moderne Synthesemethoden: Kupfer‐vermittelte C(Aryl)‐O‐, C(Aryl)‐N‐ und C(Aryl)‐S‐Verknüpfungen
2003
(+)-Neomenthyl- and (−)-phenylmenthyl-substituted cyclopentadienyl and indenyl yttrocenes as catalysts in asymmetric hydroamination/cyclization of aminoalkenes (AHA)
2007
Biaryl Synthesis via Direct Arylation: Establishment of an Efficient Catalyst for Intramolecular Processes
2004
Chiral 2-(2-phenylthiophenyl)-5,6,7,8-tetrahydroquinolines: new N–S ligands for asymmetric catalysis Palladium-catalyzed allylic alkylation and copper-catalyzed cyclopropanation reactions
2002
Non-metallocene rare earth metal catalysts for the diastereoselective and enantioselective hydroamination of aminoalkenes
2005
Mechanism of Benzoquinone-Promoted Palladium-Catalyzed Oxidative Cross-Coupling Reactions
2009
Nickel-Catalyzed Direct Arylation of Azoles with Aryl Bromides
2009
Efficient Negishi Coupling Reactions of Aryl Chlorides Catalyzed by Binuclear and Mononuclear Nickel−N-Heterocyclic Carbene Complexes
2008
Manganese Complexes for (De)Hydrogenation Catalysis: A Comparison to Cobalt and Iron Catalysts
2017
Deproto-metallation using mixed lithium–zinc and lithium–copper bases and computed CH acidity of 2-substituted quinolines
2014
Novel Method of Aromatic Coupling between N-Aryl Methanesulfonamide and Thiophene Derivatives
2007
A Chiral-Bridged Aminotroponiminate Complex of Lutetium as Catalyst for the Asymmetric Hydroamination
2006
Cobalt‐Catalyzed C−H Thiolation through Dehydrogenative Cross‐Coupling
2016
Novel palladium imidazole catalysts for Suzuki cross-coupling reactions
2003
Mild Conditions for Copper‐Catalyzed Coupling Reaction of Phenols and Aryl Iodides and Bromides
2006
Copper-Catalyzed Suzuki Cross-Coupling Using Mixed Nanocluster Catalysts
2002
Efficient Access to 2-Aryl-3-Substituted Benzo[b]thiophenes
2005
Structure−Activity Relationships for Group 4 Biaryl Amidate Complexes in Catalytic Hydroamination/Cyclization of Aminoalkenes
2007
Biaryl Synthesis via Pd-Catalyzed Decarboxylative Coupling of Aromatic Carboxylates with Aryl Halides
2007
Direct (Hetero)Arylation: A New Tool for Polymer Chemists
2013
Palladium-Catalyzed Benzene Arylation: Incorporation of Catalytic Pivalic Acid as a Proton Shuttle and a Key Element in Catalyst Design
2006
Efficient copper-catalyzed amination of aryl halides with amines and NH heterocycles using rac-BINOL as ligand
2006
An Unsaturated Nickel(0) NHC Catalyst: Facile Preparation and Structure of Ni(0)(NHC)2, Featuring a Reduction Process from Ni(II)(NHC)(acac)2
2008
Cu(OAc)2 catalyzed Sonogashira cross-coupling reaction in amines
2007
Asymmetric Intramolecular Hydroalkoxylation of Unactivated Alkenes Catalyzed by Chiral N‐Triflyl Phosphoramide and TiCl4 †
2020
Direct (Hetero)arylation Polymerization: Simplicity for Conjugated Polymer Synthesis
2016
Catalytic Direct Arylation of Heteroaromatic Compounds
2006
Versatile Synthesis of Pentalene Derivatives via the Pd-Catalyzed Homocoupling of Haloenynes
2009
Chiral oxazoline route to enantiomerically pure biphenyls: magnesio and copper mediated asymmetric hetero- and homo-coupling reactions
2004
Proton Abstraction Mechanism for the Palladium-Catalyzed Intramolecular Arylation
2006
Works of Emmanuelle Schulz being referenced
Convenient method for the rapid generation of highly active and enantioselective yttrium catalysts for asymmetric hydroamination
2008
New Chiral Lanthanide Amide Ate Complexes for the Catalysed Synthesis of Scalemic Nitrogen‐Containing Heterocycles
2007
Asymmetric hydroamination of non-activated carbon–carbon multiple bonds
2007
Lanthanide complexes derived from (R)-1,1′-binaphthyl-2,2′-bis(neopentylamine) – {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) – novel catalysts for enantioselective intramolecular hydroamination
2003
Lanthanide Complexes Coordinated by N‐Substituted (R)‐1,1′‐Binaphthyl‐2,2′‐diamido Ligands in the Catalysis of Enantioselective Intramolecular Hydroamination
2005
Well-defined and easily accessible yttrium complexes for enantioselective cyclisation of amines tethered to 1,2-di-substituted alkenes
2010
Asymmetric Hydroamination: A Survey of the Most Recent Developments
2013
An efficient synthesis of pure 4,6-dimethyldibenzothiophene
1996
Recent developments in alkene hydro-functionalisation promoted by homogeneous catalysts based on earth abundant elements: formation of C–N, C–O and C–P bond
2015
Simple Chiral Diaminobinaphthyl Dilithium Salts for Intramolecular Catalytic Asymmetric Hydroamination of Amino‐1,3‐dienes
2010
Towards the preparation of modified chiral electrodes for heterogeneous asymmetric catalysis: synthesis and electrochemical properties of (S,S)-5,5′-bis-[3-(3-methyl-pentyl)-thiophen-2-yl]-[2,2′]-bipyridine
1998
New axially chiral atropos and tropos secondary diamines as ligands for enantioselective intramolecular hydroamination
2008
Group 3 metal complexes based on a chiral tetradentate diamine-diamide ligand: Synthesis and use in polymerization of (d,l)-lactide and intramolecular alkene hydroamination catalysis
2006
Anti‐Markovnikov Hydroamination of Aromatic Alkenes with Secondary Amines Catalyzed by Easily Accessible Yttrium Complexes
2014
Lanthanide Complexes Coordinated by N‐Substituted (R)‐1,1′‐Binaphthyl‐2,2′‐diamido Ligands in the Catalysis of Enantioselective Intramolecular Hydroamination.
2006
Chromium‐Thiophene‐salen‐Based Polymers for Heterogeneous Asymmetric Hetero‐Diels–Alder Reactions
2008
Lithium‐Catalyzed anti‐Markovnikov Intermolecular Hydroamination Reactions of Vinylarenes and Simple Secondary Amines
2017
Heterogeneous catalytic hydrogenation of olefinic substrates by poly-NAP
2000
‘Diam-BINAP’; a highly efficient monomer for the synthesis of heterogeneous enantioselective catalysts
2000
Catalytic, Enantioselective Intramolecular Hydroamination of Primary Amines Tethered to Di- and Trisubstituted Alkenes
2011
Electropolymerized Cr–salen complexes for the heterogeneous asymmetric hetero Diels-Alder reaction
2007
Hydroamination and Hydroaminoalkylation of Alkenes by Group 3–5 Elements: Recent Developments and Comparison with Late Transition Metals
2018
Neutral Yttrium Tris(amide) and Ate Complexes Coordinated by an (R)‐N,N′‐Diisopropyl‐1,1′‐binaphthyl‐2,2′‐diamido Ligand as Enantioselective Catalysts for Intramolecular Hydroamination
2007
Enantioselective Intramolecular Hydroamination Catalyzed by Lanthanide Ate Complexes Coordinated by N-Substituted (R)-1,1‘-Binaphthyl-2,2‘-diamido Ligands
2006
Chiral Amido Alkyl Rare Earth Complexes: A New Family of Asymmetric Intramolecular Hydroamination Catalysts
2008
Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes
2015
Chiral nitrogen-metal complexes for the asymmetric reduction of ketones
1997
Chiral Sulfur Ligands for Asymmetric Catalysis
2007
Enantioselective Intramolecular Hydroamination of Secondary Amines Catalyzed by Easily Accessible Ate and Neutral Rare‐Earth Complexes
2010
Palladium-catalyzed synthesis of oligo(alkylthiophenes)
2003
New synthetic method for the polymerization of alkylthiophenes
1999
Recent progress in asymmetric heterogeneous catalysis: use of polymer-supported catalysts
2000
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis
2000
A New Method for Recycling Asymmetric Catalysts via Formation of Charge Transfer Complexes
2006
Palladium-catalyzed coupling reactions towards the synthesis of well-defined thiophene-oligomers
2003
Aryl−Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction
2002 Standout
Dibenzothiophene-bis(oxazolines): new sulfur-containing ligands tested in asymmetric palladium-catalyzed allylic substitutions
2002