Standout Papers
Citation Impact
Citing Papers
The highly enantioselective catalytic aza-Morita–Baylis–Hillman reaction
2014
A Highly Regio‐ and Diastereoselective Phosphane‐Catalyzed [3+2] Annulation of Morita–Baylis–Hillman Carbonates with Cyclic N‐Acyl Ketimines
2013
Phosphine‐Catalyzed Asymmetric Umpolung Addition of Trifluoromethyl Ketimines to Morita–Baylis–Hillman Carbonates
2016
Highly Enantioselective Intermolecular Cross Rauhut–Currier Reaction Catalyzed by a Multifunctional Lewis Base Catalyst
2014
Biocatalysis and enzymes in organic synthesis.
2001
Organocatalysis Mediated by (Thio)urea Derivatives
2006
Asymmetric Synthesis of Chiral Aldehydes by Conjugate Additions with Bifunctional Organocatalysis by Cinchona Alkaloids
2006
Dynamic Covalent Chemistry
2002 StandoutNobel
Asymmetric Synthesis of Natural Product Inspired Tricyclic Benzopyrones by an Organocatalyzed Annulation Reaction
2008
The Enantioselective Morita–Baylis–Hillman Reaction and Its Aza Counterpart
2007
Catalytic, Asymmetric Aza‐Baylis–Hillman Reaction of N‐Sulfonated Imines with Activated Olefins by Quinidine‐Derived Chiral Amines
2005
Recent developments in metal catalyzed asymmetric addition of phosphorus nucleophiles
2011
Recent advances in organocatalytic methods for the synthesis of disubstituted 2- and 3-indolinones
2012 Standout
Dynamic imine chemistry
2012 StandoutNobel
An Unexpected Phosphine‐Catalyzed Regio‐ and Diastereoselective [4+1] Annulation Reaction of Modified Allylic Compounds with Activated Enones
2010
Cyclization of ortho-hydroxycinnamates to coumarins under mild conditions: A nucleophilic organocatalysis approach
2012
Computational Design of Enone-Binding Proteins with Catalytic Activity for the Morita–Baylis–Hillman Reaction
2013 StandoutNobel
The road to fully programmable protein catalysis
2022 StandoutNatureNobel
Asymmetric organocatalysis in total synthesis – a trial by fire
2010
Organocatalytic tandem three-component reaction of aldehyde, alkyl vinyl ketone, and amide: one-pot syntheses of highly functional alkenes
2010
Amino Acid Derived Phosphine‐Catalyzed Enantioselective 1,4‐Dipolar Spiroannulation of Cyclobutenones and Isatylidenemalononitrile
2015
Phosphine-catalyzed domino reaction: an efficient method for the synthesis of highly functionalized spirooxazolines
2012
Recent extensions of the Morita–Baylis–Hillman reaction
2009
Asymmetric spiroacetalization catalysed by confined Brønsted acids
2012 StandoutNatureNobel
Bifunctional Polymeric Organocatalysts and Their Application in the Cooperative Catalysis of Morita–Baylis–Hillman Reactions
2006
Highly Enantioselective [3+2] Annulation of Morita–Baylis–Hillman Adducts Mediated by L ‐Threonine‐Derived Phosphines: Synthesis of 3‐Spirocyclopentene‐2‐oxindoles having Two Contiguous Quaternary Centers
2011
Chiral Guanidine Catalyzed Enantioselective Reactions
2008
Construction of Chiral Quaternary Carbon through Morita–Baylis–Hillman Reaction: An Enantioselective Approach to 3‐Substituted 3‐Hydroxyoxindole Derivatives
2010
Chiral Phosphine Catalyzed Asymmetric Michael Addition of Oxindoles
2012
Enantioselective Synthesis of α‐Alkylidene‐γ‐Butyrolactones: Intramolecular Rauhut–Currier Reaction Promoted by Acid/Base Organocatalysts
2012
Phosphine-catalyzed [4 + 2] annulation and vinylogous addition reactions between 1,4-dien-3-ones and 1,1-dicyanoalkenes
2011
Click Chemistry: Diverse Chemical Function from a Few Good Reactions
2001 StandoutNobel
Applications of Chiral Phosphine‐Based Organocatalysts in Catalytic Asymmetric Reactions
2014
Engineering an efficient and enantioselective enzyme for the Morita–Baylis–Hillman reaction
2021 StandoutNobel
Brønsted Acid Catalyzed Morita–Baylis–Hillman Reaction: A New Mechanistic View for Thioureas Revealed by ESI‐MS(/MS) Monitoring and DFT Calculations
2009
Ruthenium catalysed cross metathesis with fluorinated olefins
2001
Reevaluation of the Mechanism of the Baylis–Hillman Reaction: Implications for Asymmetric Catalysis
2005
Multicomponent Domino Processes Based on the Organocatalytic Generation of Conjugated Acetylides: Efficient Synthetic Manifolds for Diversity‐Oriented Molecular Construction
2005
Cascade Reactions in Total Synthesis
2006 Standout
A Novel Selective Aza‐Morita–Baylis–Hillman (aza‐MBH) Domino Reaction and Aza‐MBH Reaction of N‐Sulfonated Imines with Acrolein Catalyzed by a Bifunctional Phosphine Organocatalyst
2008
Phosphine-catalyzed annulation of ethyl (arylimino)acetates: synthesis of highly functionalized oxoimidazolidines
2008
Phosphine‐Catalyzed Enantioselective γ‐Addition of 3‐Substituted Oxindoles to 2,3‐Butadienoates and 2‐Butynoates: Use of Prochiral Nucleophiles
2014
Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons
2014
Enantioselective catalysis and complexity generation from allenoates
2009
Phosphine‐Catalyzed Annulations of 4,4‐Dicyano‐2‐Methylenebut‐3‐enoates with Maleimides and Maleic Anhydride
2014
Essential role of phosphines in organocatalytic β-boration reaction
2012
PPh3‐Catalyzed Reactions of Alkyl Propiolates with N‐Tosylimines: A Facile Synthesis of Alkyl 2‐[aryl(tosylimino)methyl]acrylate and an Insight into the Reaction Mechanism
2009
Advances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs
2013
An efficient stereoselective synthesis of 3-spirocyclopentene- and 3-spiropyrazole-2-oxindoles via 1,3-dipolar cycloaddition reaction
2010
Morita–Baylis–Hillman adduct derivatives (MBHADs): versatile reactivity in Lewis base-promoted annulation
2015
An overview of N-heterocyclic carbenes
2014 StandoutNature
N-heterocyclic carbene-catalyzed reactions of C–C unsaturated bonds
2013
An atom-efficient and practical synthesis of new pyridinium ionic liquids and application in Morita–Baylis–Hillman reaction
2008
Regio‐ and Stereoselective Construction of γ‐Butenolides through Phosphine‐Catalyzed Substitution of Morita–Baylis–Hillman Acetates: An Organocatalytic Allylic Alkylation
2004
PPh3-catalyzed synthesis of dicyano-2-methylenebut-3-enoates as efficient dienes in catalytic asymmetric inverse-electron-demand Diels–Alder reaction
2011
Equilibrium between a vinylogous ylide and a phosphonium dienolate zwitterion: vinylogous Wittig olefination versus vinylogous aldol-type reaction
2010
In the Golden Age of Organocatalysis
2004 Standout
Baylis–Hillman reactions of N-tosyl aldimines and aryl aldehydes with 3-methylpenta-3,4-dien-2-one
2005
Intramolecular Organocatalytic [3+2] Dipolar Cycloaddition: Stereospecific Cycloaddition and the Total Synthesis of (±)‐Hirsutene
2003
Lewis Base Catalysis in Organic Synthesis
2008
Olefin Metathesis Involving Ruthenium Enoic Carbene Complexes
2001 StandoutNobel
Enantioselective allylic substitution of Morita–Baylis–Hillman adducts catalyzed by planar chiral [2.2]paracyclophane monophosphines
2007
Nucleophilic‐Bisphosphine‐Catalysed One‐Pot Sequential [4+2]/[4+2] Annulation of an Allenoate with Benzylidenepyrazolones
2015
Ultrasound in Baylis–Hillman reactions with aliphatic and aromatic aldehydes: scope and limitations
2002
A highly active ionic liquid catalyst for Morita–Baylis–Hillman reaction
2005
NaNO2–Ceric ammonium nitrate mediated conversion of acrylic esters and Baylis–Hillman derived acrylic esters into corresponding β-nitro acrylic esters
2003
Highly Enantioselective Regiodivergent Allylic Alkylations of MBH Carbonates with Phthalides
2012
Catalytic Asymmetric Dearomatizing Redox Cross Coupling of Ketones with Aryl Hydrazines Giving 1,4-Diketones
2015 StandoutNobel
Diastereo- and Enantioselective [3 + 2] Cycloaddition Reaction of Morita–Baylis–Hillman Carbonates of Isatins with N-Phenylmaleimide Catalyzed by Me-DuPhos
2012
Resolution of Diols via Catalytic Asymmetric Acetalization
2015 StandoutNobel
Development of Chiral Nucleophilic Pyridine Catalysts: Applications in Asymmetric Quaternary Carbon Synthesis
2003
Novel application of phosphonium salts as co-catalysts for the Baylis–Hillman reaction
2004
Phosphine catalyzed δ-carbon addition and isomerization of alkynones to ketimines: the preparation of 1,3-diene substituted dihydroquinazolinones and 3-aminooxindoles
2017
Enzyme promiscuity: first protein-catalyzed Morita–Baylis–Hillman reaction
2007
Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation
2012 StandoutNobel
Sulfide–BF3·OEt2 mediated Baylis–Hillman reactions
2002
Tandem Three-Component Reactions of Aldehyde, Alkyl Acrylate, and Dialkylmalonate Catalyzed by Ethyl Diphenylphosphine
2012
β-Isocupreidine–hexafluoroisopropyl acrylate method for asymmetric Baylis–Hillman reactions
2005
Remarkable Rate Acceleration of Imidazole-Promoted Baylis−Hillman Reaction Involving Cyclic Enones in Basic Water Solution
2003
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
2011 Standout
An Efficient Conjugate Addition of Dialkyl Phosphite to Electron-Deficient Olefins: The Use of a Nucleophilic Organocatalyst to Form a Strong Base
2013
Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
2003
A General Model for Selectivity in Olefin Cross Metathesis
2003 StandoutNobel
Lewis Base Effects in the Baylis−Hillman Reaction of Imines with Methyl Vinyl Ketone
2002
New Approaches to Olefin Cross-Metathesis
1999 StandoutNobel
Phosphine-catalyzed addition of P(O)–H compounds to ethyl phenylpropiolate
2015
Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands
2016
Nucleophilic Lewis Base Dependent Addition Reactions of Allenoates with Trifluoromethylated Cyclic Ketimines
2014
Use of Protease from Bacillus licheniformis as Promiscuous Catalyst for Organic Synthesis: Applications in CC and CN Bond Formation Reactions
2011
Dual-reagent organocatalysis with a phosphine and electron-deficient alkene: application to the Henry reaction
2008
Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts
2001 StandoutNobel
Lewis‐Base‐Catalyzed Annulations of Nitroallylic Acetates as C3 Synthons with Electron‐Deficient Alkenes
2014
Synthesis of Functionalized Olefins by Cross and Ring-Closing Metatheses
2000 StandoutNobel
Crystal structures of proline-derived enamines
2010 StandoutNobel
Highly Enantioselective Aza‐Baylis–Hillman Reactions Catalyzed by Chiral Thiourea Derivatives
2005
Dual Catalyst Control in the Amino Acid-Peptide-Catalyzed Enantioselective Baylis−Hillman Reaction
2003
Mitsunobu and Related Reactions: Advances and Applications
2009
New Strategies for the Development of an Asymmetric Version of the Baylis–Hillman Reaction
2000
Conformational lock in a Brønsted acid–Lewis base organocatalyst for the aza-Morita–Baylis–Hillman reaction
2006
Catalytic Asymmetric [4+2]-Cycloaddition of Dienes with Aldehydes
2017 StandoutNobel
Phosphine‐Catalyzed [3+2] Annulation of Electron‐Deficient Alkynes with N‐Hydroxyphthalimide: Synthesis of 3a‐Hydroxyisoxazolo[3,2‐a]isoindol‐8(3aH)‐ones
2013
Lewis base and l-proline co-catalyzed Baylis–Hillman reaction of arylaldehydes with methyl vinyl ketone
2002
Phosphine Organocatalysis
2018 Standout
Cu-catalyzed cross-dehydrogenative coupling: A versatile strategy for C–C bond formations via the oxidative activation of sp 3 C–H bonds
2006
A Highly Nucleophilic Multifunctional Chiral Phosphane‐Catalyzed Asymmetric Intramolecular Rauhut–Currier Reaction
2012
Enantioselective Synthesis of β2-Amino Acids via Rh-Catalyzed Asymmetric Hydrogenation with BoPhoz-Type Ligands: Important Influence of an N−H Proton in the Ligand on the Enantioselectivity
2008
Phosphine-Catalyzed Domino Benzannulation: An Efficient Method to Construct Biaryl Skeletons
2013
Hydroxyl ionic liquid (HIL)-immobilized quinuclidine for Baylis–Hillman catalysis: synergistic effect of ionic liquids as organocatalyst supports
2006
Baylis–Hillman reaction in [bdmim][PF 6 ] ionic liquid
2004
Synthesis of monoene pheromone components having a double bond in positions 6–11 using cometathesis of cycloolefins with α-olefins
1994
Enantioselective hydrogenation of α-aminomethylacrylates containing a free NH group for the synthesis of β-amino acid derivatives
2007
Amine-Catalyzed Coupling of Allenic Esters to α,β-Unsaturated Carbonyls
2003
The Contribution Made by Triphenylphosphane in the Putative Catalysis by Ruthenium Species in Conjugate Additions of β-Dicarbonyl Compounds
2001
Catalytic Enantioselective Synthesis of Prostaglandin E1 Methyl Ester Using a Tandem 1,4-Addition-Aldol Reaction to a Cyclopenten-3,5-dione Monoacetal
2001 StandoutNobel
Development and Applications of Disulfonimides in Enantioselective Organocatalysis
2015 StandoutNobel
Stereoselective Cascade Double-Annulations Provide Diversely Ring-Fused Tetracyclic Benzopyrones
2012
A novel approach to Morita–Baylis–Hillman (MBH) lactones via the Lewis acid-promoted couplings of α,β-unsaturated lactone with aldehydes
2003
Nucleophilic Phosphine Organocatalysis
2004 Standout
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Unexpected Inversions in Asymmetric Reactions: Reactions with Chiral Metal Complexes, Chiral Organocatalysts, and Heterogeneous Chiral Catalysts
2009
Michael additions catalyzed by phosphines. An overlooked synthetic method
2005
Enantioselective Morita−Baylis−Hillman Reaction of Isatins with Acrylates: Facile Creation of 3-Hydroxy-2-oxindoles
2010
Intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions. A catalytic and atom economic route for carbocycles and heterocycles
2015
Recent developments in the asymmetric organocatalytic Morita−Baylis−Hillman reaction
2017
PPh3-Catalyzed (3 + 3) Annulations of 5-Acetoxypenta-2,3-dienoate with 1C,3O-Bisnucleophiles: Facile Entry to Stable Monocyclic 2H-Pyrans
2012
Conjugate Additions of Nitroalkanes to Electron-Poor Alkenes: Recent Results
2005
Organocatalytic Asymmetric Synthesis of Substituted 3-Hydroxy-2-oxindoles via Morita−Baylis−Hillman Reaction
2010
Development of bis-thiourea-type organocatalyst for asymmetric Baylis–Hillman reaction
2004
Im Goldenen Zeitalter der Organokatalyse
2004
Multifunctional Chiral Phosphine Organocatalysts in Catalytic Asymmetric Morita−Baylis−Hillman and Related Reactions
2010
Quantum chemical investigation on the reaction mechanism of tertiary phosphines with unsaturated carboxylic acids: An insight into kinetic data
2012
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
2-Phospha[3]ferrocenophanes with Planar Chirality: Synthesis and Use in Enantioselective Organocatalytic [3 + 2] Cyclizations
2008
Recent Advances in Organocatalytic Asymmetric Morita–Baylis–Hillman/aza-Morita–Baylis–Hillman Reactions
2013
Quantum Mechanical Investigations of Organocatalysis: Mechanisms, Reactivities, and Selectivities
2011
Powerful Amino Acid Derived Bifunctional Phosphine Catalysts Bearing a Hydrogen Bond Donor in Asymmetric Synthesis
2013
Heck reaction of β-substituted acrylates in ionic liquids catalyzed by a Pd-benzothiazole carbene complex
2001
Regiodivergent Enantioselective γ-Additions of Oxazolones to 2,3-Butadienoates Catalyzed by Phosphines: Synthesis of α,α-Disubstituted α-Amino Acids and N,O-Acetal Derivatives
2015
Tributylphosphine-catalyzed Stetter reaction of N,N-dimethylacrylamide: synthesis of N,N-dimethyl-3-aroylpropionamides
2002
Stable Tetravalent Phosphonium Enolate Zwitterions
2007
Phosphine-Catalyzed [4 + 2] Annulation of γ-Substituent Allenoates: Facile Access to Functionalized Spirocyclic Skeletons
2013
Tertiary Amine-Catalyzed Chemoselective and Asymmetric [3 + 2] Annulation of Morita–Baylis–Hillman Carbonates of Isatins with Propargyl Sulfones
2011
An imidazolinium salt as ionic liquid for medium and strong bases
2005
Mechanisms and stereoselectivities of phosphine-catalyzed Rauhut-Currier reaction between N-phenylmaleimide and 2-benzoyl acrylate: A computational investigation
2017
Core-Structure-Motivated Design of a Phosphine-Catalyzed [3 + 2] Cycloaddition Reaction: Enantioselective Syntheses of Spirocyclopenteneoxindoles
2011
Efficient organocatalysts derived from simple chiral acyclic amino acids in asymmetric catalysis
2011
The DABCO-catalysed Baylis–Hillman reactions in the chloroaluminate room temperature ionic liquids: rate promoting and recyclable media
2003
Dienamine Catalysis: Organocatalytic Asymmetric γ-Amination of α,β-Unsaturated Aldehydes
2006
Enantioselective Conjugate Additions
2000
The osmium-catalyzed aminohydroxylation of Baylis-Hillman olefins
1999 StandoutNobel
Kinetic Resolution of Homoaldols via Catalytic Asymmetric Transacetalization
2010 StandoutNobel
Stereoselective epoxidation of hydroxyenones. The synthesis of the sidechain of clerocidin
1990
Click Chemistry: Diverse Chemical Function from a Few Good Reactions
2001 StandoutNobel
An exploration of asymmetric Baylis–Hillman reactions catalyzed by quinidine-derived chiral amines
2002
Recent advances in stoichiometric phosphine-mediated organic synthetic reactions
2013
Intramolecular Organocatalytic [3+2] Dipolar Cycloaddition: Stereospecific Cycloaddition and the Total Synthesis of (±)‐Hirsutene
2003
Bifunctional Organocatalysts for Enantioselective aza-Morita−Baylis−Hillman Reaction
2005
Synthesis of Trisubstituted Alkenes via Olefin Cross-Metathesis
1999 StandoutNobel
Highly regio- and diastereoselective construction of spirocyclopenteneoxindole phosphonates through a phosphine-catalyzed [3 + 2] annulation reaction
2014
Phosphine Catalyst-Controlled Cycloaddition or Dienylation Reactions of Trifluoromethyl Aryl Ketones with Bis-Substituted Allenoates
2013
Phosphine-Catalyzed Diastereo- and Enantioselective Michael Addition of β-Carbonyl Esters to β-Trifluoromethyl and β-Ester Enones: Enhanced Reactivity by Inorganic Base
2017
Enamine Catalysis Is a Powerful Strategy for the Catalytic Generation and Use of Carbanion Equivalents
2004 StandoutNobel
Probing Phosphane‐Mediated [2+1] Annulation Reactions
2010
Phosphine-Catalyzed Annulation Reactions of 2-Butynoate and α-Keto Esters: Synthesis of Cyclopentene Derivatives
2014
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
Lewis base-catalyzed divergent isomerizations of 5-hydroxyl-2,3-dienoate
2013
Small-Molecule H-Bond Donors in Asymmetric Catalysis
2007 Standout
Aza-Baylis−Hillman Reactions of N-Tosylated Aldimines with Activated Allenes and Alkynes in the Presence of Various Lewis Base Promoters
2005
Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings
2015
Efficient Baylis–Hillman reactions promoted by mild cooperative catalysts and their application to catalytic asymmetric synthesis
2000
Alkyne Elementometalation−Pd-Catalyzed Cross-Coupling. Toward Synthesis of All Conceivable Types of Acyclic Alkenes in High Yields, Efficiently, Selectively, Economically, and Safely: “Green” Way
2010 StandoutNobel
Organic Reactions in Aqueous Media with a Focus on Carbon−Carbon Bond Formations: A Decade Update
2005 Standout
aza-Baylis−Hillman Reaction
2009
Enantioselective, Organocatalytic Morita-Baylis-Hillman and Aza-Morita-Baylis-Hillman Reactions: Stereochemical Issues
2010
First application of chiral ionic liquids in asymmetric Baylis–Hillman reaction
2004
Phosphine-Catalyzed Cascade [3 + 2] Cyclization−Allylic Alkylation, [2 + 2 + 1] Annulation, and [3 + 2] Cyclization Reactions between Allylic Carbonates and Enones
2011
1,3,5‐Triaza‐7‐phosphaadamantane (PTA): A Practical and Versatile Nucleophilic Phosphine Organocatalyst
2007
Asymmetric Organocatalytic Cyclization and Cycloaddition Reactions
2011
Phosphine-mediated enantioselective synthesis of carbocycles and heterocycles
2016
Three-Component Coupling Catalyzed by Phosphine: Preparation of α-Amino γ-Oxo Acid Derivatives
2012
Enantioselective Synthesis of Isatin‐Derived α‐(Trifluoromethyl)imine Derivatives: Phosphine‐Catalyzed γ‐Addition of α‐(Trifluoromethyl)imines and Allenoates
2017
Acceleration of the Baylis–Hillman Reaction in the Presence of Ionic Liquids
2003
Synthesis, Structure, and Activity of Enhanced Initiators for Olefin Metathesis
2003 StandoutNobel
Organocatalytic asymmetric aldol reaction of ketones with isatins: straightforward stereoselective synthesis of 3-alkyl-3-hydroxyindolin-2-ones
2007
Catalysis in Ionic Liquids
2007 Standout
A nucleophile-catalyzed cycloisomerization permits a concise synthesis of (+)-harziphilone
2004
Disulfonimide-Catalyzed Asymmetric Synthesis of β3-Amino Esters Directly from N-Boc-Amino Sulfones
2013 StandoutNobel
Organocatalytic Asymmetric Transferhydrogenation of β-Nitroacrylates: Accessing β2-Amino Acids
2008 StandoutNobel
Pyridinium ionic liquids-accelerated amine-catalyzed Morita–Baylis–Hillman reaction
2006
Protein self-assembly induces promiscuous nucleophilic biocatalysis in Morita–Baylis–Hillman (MBH) reaction
2015
Organocatalytic Asymmetric Transfer Hydrogenation of Nitroolefins
2007 StandoutNobel
Advances in the Baylis–Hillman reaction-assisted synthesis of cyclic frameworks
2008 Standout
Ionic liquids as a recyclable reaction medium for the Baylis–Hillman reaction
2001
A multi-pronged mechanistic study of the phosphine-mediated conjugate addition of an alcohol to an acetylenic ester
2014
Isatin derivatives are reactive electrophilic components for the Baylis–Hillman reaction
2002
Enantioselective Synthesis of Functionalized 4-Aryl Hydrocoumarins and 4-Aryl Hydroquinolin-2-ones via Intramolecular Vinylogous Rauhut–Currier Reaction of para-Quinone Methides
2017
Advances in Annulation Reactions Initiated by Phosphorus Ylides Generated in situ
2016
[4 + 3] Cycloadditions with Bromo-Substituted Morita–Baylis–Hillman Adducts of Isatins and N-(ortho-Chloromethyl)aryl Amides
2015
Aza‐Baylis–Hillman Reactions and Their Synthetic Applications
2007
Copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones
2004 StandoutNobel
Phosphines catalyzed nucleophilic addition of azoles to allenes: synthesis of allylazoles and indolizines
2006
New Insights into the Mechanism of Ruthenium-Catalyzed Olefin Metathesis Reactions
2001 StandoutNobel
Phosphine-Catalyzed Asymmetric Intermolecular Cross-Vinylogous Rauhut–Currier Reactions of Vinyl Ketones with para-Quinone Methides
2017
TiCl4-Mediated Baylis–Hillman and aldol reactions without the direct use of a Lewis base
2000
Neue Strategien zur Entwicklung einer asymmetrischen Variante der Baylis-Hillman-Reaktion
2000
Claisen Rearrangement over the Past Nine Decades
2004
Remarkable Phosphine-Effect on the Intramolecular Aldol Reactions of Unsaturated 1,5-Diketones: Highly Regioselective Synthesis of Cross-Conjugated Dienones
2005
Catalytic Asymmetric Transacetalization
2010 StandoutNobel
Chiral phosphine-catalyzed regio- and enantioselective allylic amination of Morita–Baylis–Hillman acetates
2009
Highly selective synthesis of 1‐phenylpentane‐1, 4‐diones, and (E)‐5‐hydroxy‐5‐phenylpent‐3‐en‐2‐ones catalyzed by organophosphorus compounds
2009
The Development of the Asymmetric Morita—Baylis—Hillman Reaction Catalyzed by Chiral Brønsted Acids
2004
Aza‐Baylis–Hillman Reactions of N‐(Arylmethylene)diphenylphosphinamides with Activated Olefins in the Presence of Various Lewis Bases
2004
Domino Cyclization Initiated by Cross‐Rauhut–Currier Reactions
2013
The Catalytic Asymmetric Fischer Indolization
2011 StandoutNobel
Highly Regio- and Diastereoselective Construction of Spirocyclopenteneoxindoles through Phosphine-Catalyzed [3 + 2] Annulation of Morita–Baylis–Hillman Carbonates with Isatylidene Malononitriles
2011
Facile synthesis of α-methylidene-γ-butyrolactones: intramolecular Rauhut–Currier reaction promoted by chiral acid–base organocatalysts
2012
Dynamic Control of Chiral Space in a Catalytic Asymmetric Reaction Using a Molecular Motor
2011 StandoutScienceNobel
Organocatalytic domino reaction of salicyl N-thiophosphoryl imines and methyl vinyl ketone initiated by an aza-MBH reaction with bifunctional phosphine catalysts
2012
Tandem three-component reaction of aldehyde, alkyl acrylate, and amide using ethyl diphenylphosphine as organocatalyst
2010
Correlation between pKa and Reactivity of Quinuclidine-Based Catalysts in the Baylis−Hillman Reaction: Discovery of Quinuclidine as Optimum Catalyst Leading to Substantial Enhancement of Scope
2003
Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications
2016 Standout
Asymmetric Enamine Catalysis
2007 StandoutNobel
Asymmetric Morita–Baylis–Hillman reactions of 2-cyclohexen-1-one catalyzed by chiral biaryl-based bis(thiourea) organocatalysts
2011
Catalytic asymmetric synthesis of 3-hydroxyl-2-oxindoles via enantioselective Morita–Baylis–Hillman reaction of isatins
2011
The Rauhut–Currier reaction: a history and its synthetic application
2009
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
2000 Standout
Chiral Binaphthyl-Derived Amine-Thiourea Organocatalyst-Promoted Asymmetric Morita−Baylis−Hillman Reaction
2005
Direct Catalytic Asymmetric Synthesis of Cyclic Aminals from Aldehydes
2008 StandoutNobel
Privileged chiral catalysts in asymmetric Morita-Baylis-Hillman/aza-Morita-Baylis-Hillman reaction
2010
Enantioselective Synthesis of Chromanones via a Peptidic Phosphane Catalyzed Rauhut–Currier Reaction
2015
Phosphine‐Catalyzed Annulations between Modified Allylic Derivatives and Polar Dienes and Substituent Effect on the Annulation Mode
2013
Chiral Bifunctional Thiourea–Phosphane Organocatalysts in Asymmetric Allylic Amination of Morita–Baylis–Hillman Acetates
2011
Phosphine-Catalyzed Regiospecific Allylic Amination and Dynamic Kinetic Resolution of Morita−Baylis−Hillman Acetates
2004
Application of non-imidazolium-based ionic liquid in the Baylis–Hillman reactions: Rate and yield promoted
2006
Stronger Brønsted Acids
2007 Standout
Arylation of Allylic Alcohols in Ionic Liquids Catalysed by a Pd‐Benzothiazole Carbene Complex
2003
Synthesis of 3-Hydroxy-2-Methylene Carbonyl Compounds - Effect of Catalyst and Substrate on Reaction Rate
1988
Synthesis and metathesis reactions of a phosphine-free dihydroimidazole carbene ruthenium complex
2000
A novel ionic liquid supported organocatalyst of pyrrolidine amide: Synthesis and catalyzed Claisen–Schmidt reaction
2006
Selenonium ionic liquid as efficient catalyst for the Baylis–Hillman reaction
2009
Synthesis of Functionalized Vinyl Boronates via Ruthenium-Catalyzed Olefin Cross-Metathesis and Subsequent Conversion to Vinyl Halides
2003 StandoutNobel
Works of Deevi Basavaiah being referenced
A novel, tandem construction of C–N and C–C bonds: facile and one-pot transformation of the Baylis–Hillman adducts into 2-benzazepines
2003
Baylis–Hillman Bromides as a Source of 1,3‐Dipoles: Sterically Directed Synthesis of Oxindole‐Fused Spirooxirane and Spirodihydrofuran Frameworks
2013
The Baylis–Hillman reaction: a novel concept for creativity in chemistry
2011
The Baylis–Hillman reaction: a novel source of attraction, opportunities, and challenges in synthetic chemistry
2007
An efficient and rapid chalcogenide-Morita–Baylis–Hillman process promoted by TBDMSOTf and a thiolane
2006
Applications of Baylis–Hillman acetates: one-pot, facile and convenient synthesis of substituted γ-lactams
2004
A simple synthesis of α-methylene-β-hydroxyalkanones
1986
Terminal Hydroxyalkyl Acrylates as Substrates for Baylis-Hillman Reaction
1990
Simple and One-Pot Protocol for Synthesis of Indene-spiro-oxindoles Involving Tandem Prins and Friedel−Crafts Reactions
2006
The Acrylamide Moiety as an Activated Alkene Component in the Intramolecular Baylis–Hillman Reaction: Facile Synthesis of Functionalized α‐Methylene Lactam and Spirolactam Frameworks
2014
Chiral acrylates as substrates in baylis-hillman reaction
1990
Applications of Baylis–Hillman adducts: a simple, convenient, and one-pot synthesis of 3-benzoylquinolines
2005
Synthetic applications of the baylis-hillman reaction: Simple synthesis of [2E]-2-butyloct-2-enal and [2E]-2-tridecylheptadec-2-enal
1996
The Baylis–Hillman acetates as a source of ambiphilic molecules: a simple synthesis of 1,3-thiazinane-2-thione frameworks
2015
Recent Contributions from the Baylis−Hillman Reaction to Organic Chemistry
2010
The First Intramolecular Friedel-Crafts Reaction of Baylis-Hillman Adducts: Synthesis of Functionalized Indene and Indane Derivatives
2001
Stereoselective Transformation of Baylis-Hillman Adducts into (3E)-3-(Alkoxymethyl)alk-3-en-2-ones
2000
Methanolic trimethylamine mediated Baylis-Hillman reaction
2002
The Aqueous Trimethylamine Mediated Baylis-Hillman Reaction
2000
A facile tandem construction of C–O and C–C bonds: a novel one-pot transformation of Baylis–Hillman adducts into 2-benzoxepines
2004
α-Keto Esters as Electrophiles for the Chalcogeno-Baylis-Hillman Reaction
1999
Less reactive ketones as electrophiles and acrylamides as activated alkenes in intramolecular Baylis–Hillman reaction: facile synthesis of functionalized γ-lactam frameworks
2014
A Simple Synthesis of 2-(1-Hydroxyalkyl)acrylonitriles
1987
Applications of Baylis–Hillman chemistry: one-pot convenient synthesis of functionalized (1H)-quinol-2-ones and quinolines
2002
A Facile One-Pot Conversion of Acetates of the Baylis−Hillman Adducts to [E]-α-Methylcinnamic Acids
1999
Bovine liver acetone powder (BLAP) catalyzed synthesis of chiral C-8 allyl alcohols: An application of substrate specificity approach
1994
Baylis–Hillman chemistry: a novel synthesis of functionalized 1,4-pentadienes
2001
DABCO catalyzed coupling of α-keto esters with acrylonitrile and methyl acrylate
1987
Diethyl Ketomalonate: A Fast Reacting Substrate for Baylis-Hillman Reaction
1989
A Novel and Facile Synthesis of Functionalized [4.4.3] and [4.4.4]Propellano-bislactones Using Acetates of the Baylis−Hillman Adducts
2001
Pheromones via organoboranes. 3. Vinylic organoboranes. 10. Stereospecific synthesis of (Z)- and (E)-6- and -7-alken-1-ols via boracyclanes
1988 Nobel
A general and stereospecific synthesis of trans-alkenes and regiospecific synthesis of ketones via stepwise hydroboration
1982 Nobel
Simple, Facile, and One-Pot Conversion of the Baylis−Hillman Adducts into Functionalized 1,2,3,4-Tetrahydroacridines and Cyclopenta[b]quinolines
2004
The Baylis–Hillman chemistry in aqueous media: a convenient synthesis of 2-methylenealkanoates and alkanenitriles
2001
Dimethyl Sulfide Induced [3 + 2] Annulation Strategy: An Efficient Synthesis of Functionalized Dihydropyrazole Derivatives Using the Baylis−Hillman Bromides
2008
The Baylis−Hillman Reaction: One-Pot Facile Synthesis of 2,4-Functionalized 1,4-Pentadienes
2002
The Baylis−Hillman Acetates as a Valuable Source for One-Pot Multistep Synthesis: A Facile Synthesis of Functionalized Tri-/Tetracyclic Frameworks Containing Azocine Moiety
2007
The Friedel-Crafts Chemistry: Acetates of the Baylis-Hillman Adducts as Novel Stereodefined β-Electrophiles
1996
ChemInform Abstract: The Baylis‐Hillman Reaction: A Novel Carbon‐Carbon Bond Forming Reaction
1996
A novel Baylis–Hillman protocol for the synthesis of functionalized fused furans
2001
DABCO catalyzed dimerization of α,β-unsaturated ketones and nitriles
1987
First example of electrophile induced Baylis-Hillman reaction: a novel facile one-pot synthesis of indolizine derivatives.
2003
Toward understanding the scope of Baylis–Hillman reaction: synthesis of 3-(2- hydroxyphenyl)indolin-2-ones and polycyclic fused furans
2010
One-pot inter- and intramolecular Friedel–Crafts reactions in Baylis–Hillman chemistry: a novel facile synthesis of ( E )-2-arylideneindan-1-ones
2001
The Baylis-Hillman reaction: A novel carbon-carbon bond forming reaction
1996 Standout
Applications of Baylis–Hillman chemistry: enantioselective synthesis of (−)-methyl 3-aryl-2-methylene-3-(prop-2-yn-1-yloxy)propanoates via chiral leaving group strategy
2001
A new protocol for the syntheses of (E)-3-benzylidenechroman-4-ones: a simple synthesis of the methyl ether of bonducellin
1998
(5S)-1,3-Diaza-2-imino-3-phenylbicyclo[3.3.0]octane: first example of guanidine based in situ recyclable chiral catalytic source for borane-mediated asymmetric reduction of prochiral ketones
2006
1-Benzopyran-4(4H)-ones as novel activated alkenes in the Baylis–Hillman reaction: a simple and facile synthesis of indolizine-fused-chromones
2003
Steric Factors Direct Baylis−Hillman and Aldol Reactions in Titanium Tetrachloride Mediated Coupling between α-Keto Esters and Cyclohex-2-enone Derivatives
2003
The Johnson-Claisen rearrangement of 3-hydroxy-2-methylenealkanenitriles: Stereoselective synthesis of functionalized trisubstituted alkenes
1995
THE BAYLIS—HILLMAN REACTION: TiCl4MEDIATED COUPLING OF ALKYL VINYL KETONES WITH α-KETO ESTERS AND ALDEHYDES
2001
Synthetic Applications of the Baylis–Hillman Adducts: A Simple Stereoselective Synthesis of (E)-3-(Nitroxymethyl)alk-3-en-2-ones
2000
Arylation of the Baylis-Hillman adducts
1998
The Baylis-Hillman reaction: An expedient synthesis of (Z)-keto allyl bromides and chlorides
1999
First example of electrophile induced Baylis–Hillman reaction: a novel facile one-pot synthesis of indolizine derivativesElectronic supplementary information (ESI) available: Experimental procedures, analytical and spectral data for all the compounds 2a–i. See http://www.rsc.org/suppdata/cc/b2/b211349j/
2003
The Friedel-Crafts reaction of the Baylis-Hillman adducts
1997
Recent Advances in the Baylis−Hillman Reaction and Applications
2003 Standout
Unprecedented Stereochemical Reversal from Alkyl to Aryl Substituents in the Johnson-Claisen Rearrangement of Methyl 3-Hydroxy-2-methylenealkanoates
1996