Standout Papers
Citation Impact
Citing Papers
Olefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 Enzymes
2012 StandoutScienceNobel
Palladium-Catalyzed C(sp3)–H Bond Functionalization of Aliphatic Amines
2019
Computational Stabilization of a Non‐Heme Iron Enzyme Enables Efficient Evolution of New Function
2024 StandoutNobel
Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis
2014
Postsynthetic Modification of Peptides: Chemoselective C‐Arylation of Tryptophan Residues
2009
Mechanisms of C–H bond activation: rich synergy between computation and experiment
2009
Copper‐Mediated CH/CH Biaryl Coupling of Benzoic Acid Derivatives and 1,3‐Azoles
2013
Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups
2013 Standout
Room Temperature CH Activation and Cross‐Coupling of Aryl Ureas in Water
2009
An improved catalyst architecture for rhodium(iii) catalyzed C–H activation and its application to pyridone synthesis
2011
Metal-free catalytic C-H bond activation and borylation of heteroarenes
2015 Science
Rhodium-Catalyzed C–H Bond Arylation of Arenes
2009
Enantioselective Intramolecular CH Amination Catalyzed by Engineered Cytochrome P450 Enzymes In Vitro and In Vivo
2013 StandoutNobel
Towards mild metal-catalyzed C–H bond activation
2011 Standout
Direct multiple C–H bond arylation reaction of heteroarenes catalyzed by cationic palladium complex bearing 1,10-phenanthroline
2010
Late-stage C–H functionalization of complex alkaloids and drug molecules via intermolecular rhodium-carbenoid insertion
2015
Dehydrative Direct CH Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis
2015
Aerobic Oxidative Coupling of o‐Xylene: Discovery of 2‐Fluoropyridine as a Ligand to Support Selective Pd‐Catalyzed CH Functionalization
2010
Palladium‐Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates
2008
Palladium‐Catalyzed Domino CH/NH Functionalization: An Efficient Approach to Nitrogen‐Bridged Heteroacenes
2015
Copper as a Powerful Catalyst in the Direct Alkynylation of Azoles
2009
C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation
2012 Standout
Hydroarylation of alkynes catalyzed by nickel
2011
Selective Rhodium(III)‐Catalyzed Cross‐Dehydrogenative Coupling of Furan and Thiophene Derivatives
2012
Indoles from Simple Anilines and Alkynes: Palladium‐Catalyzed CH Activation Using Dioxygen as the Oxidant
2009
Copper-mediated oxidative direct C–C (hetero)aromatic cross-coupling
2012
Ruthenium(II)‐Catalyzed CH Activation/Alkyne Annulation by Weak Coordination with O2 as the Sole Oxidant
2015
Pd(ii)-catalyzed direct C5-arylation of azole-4-carboxylates through double C–H bond cleavage
2012
Recent advances in homogeneous nickel catalysis
2014 StandoutNature
Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands
2011
CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals
2012 Standout
Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides
2010
Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
2018
Catalytic Arylation of a CH Bond in Pyridine and Related Six‐Membered N‐Heteroarenes Using Organozinc Reagents
2012
Palladium‐ and Nickel‐Catalyzed Direct Alkylation of Azoles with Unactivated Alkyl Bromides and Chlorides
2010
A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene
2012
The road to fully programmable protein catalysis
2022 StandoutNatureNobel
Palladium‐Catalyzed Selective Dehydrogenative Cross‐Couplings of Heteroarenes
2011
Palladium‐Catalyzed β‐Selective Direct Arylation of Porphyrins
2011
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
How Can Theory Predict the Selectivity of Palladium‐Catalyzed Cross‐Coupling of Pristine Aromatic Molecules?
2011
A Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading
2010
Regioselective syntheses of fully-substituted 1,2,3-triazoles: the CuAAC/C–H bond functionalization nexus
2010
Isolation, Structure, and Reactivity of an Arylnickel(II) Pivalate Complex in Catalytic C–H/C–O Biaryl Coupling
2013
Direct CH Arene Homocoupling over Gold Nanoparticles Supported on Metal Oxides
2015
Palladium‐Catalyzed Direct Arylation of Cyclic Enamides with Aryl Silanes by sp2 CH Activation
2009
A steric tethering approach enables palladium-catalysed C–H activation of primary amino alcohols
2015
Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation
2011 Standout
Computational study of ethene hydroarylation at [Ir(κ2-OAc)(PMe3)Cp]+
2010
Cyclometallation of arylimines and nitrogen-containing heterocycles via room-temperature C–H bond activation with arene ruthenium(ii) acetate complexes
2012
Synthesis of Extended π‐Systems through C–H Activation
2014 Standout
Ruthenium(II)/N‐Heterocyclic Carbene Catalyzed [3+2] Carbocyclization with Aromatic NH Ketimines and Internal Alkynes
2013
Enzymatic assembly of carbon–carbon bonds via iron-catalysed sp3 C–H functionalization
2018 StandoutNatureNobel
Microwave-assisted direct biaryl coupling: first application to the synthesis of aporphines
2009
Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation
2009
Chiral Cp‐Rhodium(III)‐Catalyzed Asymmetric Hydroarylations of 1,1‐Disubstituted Alkenes
2013
Palladium-catalysed direct arylation of a tris-cyclometallated Ir(iii ) complex bearing 2,2′-thienylpyridine ligands: a powerful tool for the tuning of luminescence properties
2011
Chiral Monodentate Phosphines and Bulky Carboxylic Acids: Cooperative Effects in Palladium‐Catalyzed Enantioselective C(sp3)–H Functionalization
2012
Mechanistic Understanding of the Unexpected Meta Selectivity in Copper-Catalyzed Anilide C–H Bond Arylation
2011
Copper‐Mediated C6‐Selective Dehydrogenative Heteroarylation of 2‐Pyridones with 1,3‐Azoles
2014
Synthesis of 5‐Alkyl[3,4‐c]thienopyrrole‐4,6‐dione‐Based Polymers by Direct Heteroarylation
2011
Anilide activation of adjacent C–H bonds in the palladium-catalysed Fujiwara–Moritani reaction
2010
Recent advances in aryl–aryl bond formation by direct arylation
2009
The Nickel/Copper‐Catalyzed Direct Alkylation of Heterocyclic CH Bonds
2010
Phosphine‐Free, Palladium‐Catalyzed Arylation of Heterocycles through CH Bond Activation with Pivalic Acid as a Cocatalyst
2008
DFT study of the mechanism of benzocyclobutene formation by palladium-catalysed C(sp3)–H activation: role of the nature of the base and the phosphine
2010
Copper‐Mediated and Copper‐Catalyzed Cross‐Coupling of Indoles and 1,3‐Azoles: Double CH Activation
2012
Efficient synthesis of biazoles by aerobic oxidative homocoupling of azoles catalyzed by a copper(i)/2-pyridonate catalytic system
2011
Computational and synthetic studies on the cyclometallation reaction of dimethylbenzylamine with [IrCl2Cp*]2: role of the chelating base
2009
The imidazo[1,2-a]pyridine ring system as a scaffold for potent dual phosphoinositide-3-kinase (PI3K)/mammalian target of rapamycin (mTOR) inhibitors
2015
Pyridine synthesis from oximes and alkynesviarhodium(iii ) catalysis: Cp* and Cptprovide complementary selectivity
2011
Carbonates: Ecofriendly Solvents for Palladium‐Catalyzed Direct 2‐Arylation of Oxazole Derivatives
2009
A General Catalyst for the β‐Selective C–H Bond Arylation of Thiophenes with Iodoarenes
2010
Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus
2009
Pd-catalysed regioselective C–H functionalisation of 2-pyrones
2010
Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds
2011
Importance of palladium–carbon bond energies in direct arylation of polyfluorinated benzenes
2010
Oxidative Biaryl Coupling of Thiophenes and Thiazoles with Arylboronic Acids through Palladium Catalysis: Otherwise Difficult C4‐Selective CH Arylation Enabled by Boronic Acids
2011
Transition‐Metal‐Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage
2009 Standout
PdII‐Catalysed CH Functionalisation of Indoles and Pyrroles Assisted by the Removable N‐(2‐Pyridyl)sulfonyl Group: C2‐Alkenylation and Dehydrogenative Homocoupling
2010
Access to β‐Lactams by Enantioselective Palladium(0)‐Catalyzed C(sp3)H Alkylation
2014
Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation
2011 Standout
Copper-catalyzed CuAAC/intramolecular C–H arylation sequence: Synthesis of annulated 1,2,3-triazoles
2012
Palladium‐Catalyzed C(sp3)H Activation: A Facile Method for the Synthesis of 3,4‐Dihydroquinolinone Derivatives
2014
CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems
2010
Manganese‐Catalyzed Synthesis of cis‐β‐Amino Acid Esters through Organometallic CH Activation of Ketimines
2015
Decarboxylative CH Cross‐Coupling of Azoles
2010
Insights into the intramolecular acetate-mediated formation of ruthenium vinylidene complexes: a ligand-assisted proton shuttle (LAPS) mechanism
2010
Direct palladium-catalysed C–H arylation of BODIPY dyes at the 3- and 3,5-positions
2012
Beyond Directing Groups: Transition‐Metal‐Catalyzed CH Activation of Simple Arenes
2012 Standout
Copper(II)‐Catalyzed meta‐Selective Direct Arylation of α‐Aryl Carbonyl Compounds
2010
Investigating N-methoxy-N′-aryl ureas in oxidative C–H olefination reactions: an unexpected oxidation behaviour
2011
Mild Rhodium(III)‐Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates
2013
Palladium(0)‐Catalyzed Enantioselective CH Arylation of Cyclopropanes: Efficient Access to Functionalized Tetrahydroquinolines
2012
Versatile Access to Chiral Indolines by Catalytic Asymmetric Fischer Indolization
2013 StandoutNobel
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
2010
C–H bond functionalisation with [RuH(codyl)2]BF4 catalyst precursor
2011
Programmed synthesis of arylthiazoles through sequential C–H couplings
2013
Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions
2015
Copper-Mediated Intermolecular Direct Biaryl Coupling
2011
Direct Arylation of Simple Azoles Catalyzed by 1,10-Phenanthroline Containing Palladium Complexes: An Investigation of C4 Arylation of Azoles and the Synthesis of Triarylated Azoles by Sequential Arylation
2011
Direct C−H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids
2010
Mechanistic Insights into the Palladium-Catalyzed Aziridination of Aliphatic Amines by C–H Activation
2015
3d Transition Metals for C–H Activation
2018 Standout
SuFEx Click Chemistry Enabled Late-Stage Drug Functionalization
2018 StandoutNobel
Modulating Reactivity and Diverting Selectivity in Palladium-Catalyzed Heteroaromatic Direct Arylation Through the Use of a Chloride Activating/Blocking Group
2010
Unveiling Secrets of Overcoming the “Heteroatom Problem” in Palladium-Catalyzed Aerobic C–H Functionalization of Heterocycles: A DFT Mechanistic Study
2016
Palladiumkatalysierte oxidative Kupplung von Thiophenen und Thiazolen mit Arylboronsäuren: ungewöhnliche C4‐selektive C‐H‐Arylierung durch den Einsatz von Boronsäuren
2011
Expedient C–H Amidations of Heteroaryl Arenes Catalyzed by Versatile Ruthenium(II) Catalysts
2013
Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)2(TFA)2: Evidence for Ligand-Controlled Chemoselectivity
2013
Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis
2016 Standout
Mechanism of the Palladium-Catalyzed Arene C–H Acetoxylation: A Comparison of Catalysts and Ligand Effects
2015
Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes
2014
Arene–Metal π-Complexation as a Traceless Reactivity Enhancer for C–H Arylation
2013
Palladiumkatalysierte direkte Arylierungen von Heteroarenen mit Tosylaten und Mesylaten
2008
Palladium-Catalyzed Direct Arylations, Alkenylations, and Benzylations through C−H Bond Cleavages with Sulfamates or Phosphates as Electrophiles
2010
Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines
2011
Key Mechanistic Features of Enantioselective C–H Bond Activation Reactions Catalyzed by [(Chiral Mono-N-Protected Amino Acid)–Pd(II)] Complexes
2011
Cu-Catalyzed Oxidative C(sp2)–H Cycloetherification ofo-Arylphenols for the Preparation of Dibenzofurans
2012
Use of Molecular Oxygen as a Reoxidant in the Synthesis of 2‐Substituted Benzothiazoles via Palladium‐Catalyzed CH Functionalization/Intramolecular CS Bond Formation
2010
Sequential Allylic C–H Amination/Vinylic C–H Arylation: A Strategy for Unnatural Amino Acid Synthesis from α-Olefins
2012
Palladium(0)-catalyzed cyclopropane C–H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives
2011
Palladium‐Catalyzed β‐Selective Direct Arylation of Porphyrins
2011
Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates
2009
Palladium-Catalyzed Decarboxylative Arylation of C−H Bonds by Aryl Acylperoxides
2009
Copper‐Catalyzed Direct CH Arylation of Thieno[3,4‐c]pyrrole‐4,6‐dione (TPD): Toward Efficient and Low‐Cost Synthesis of π‐Functional Small Molecules
2014
Organic Photoredox Catalysis
2016 Standout
Copper-Mediated Oxidative Coupling of Benzamides with Maleimides via Directed C–H Cleavage
2015
Palladium-Catalyzed Annulation of Arynes byo-Halobenzamides: Synthesis of Phenanthridinones
2012
Palladium-Catalyzed Alkylation of ortho-C(sp2)–H Bonds of Benzylamide Substrates with Alkyl Halides
2011
Sterically Controlled, Palladium-Catalyzed Intermolecular Amination of Arenes
2013
Oxidative coupling reactions for the functionalisation of C–H bonds using oxygen
2014
Synthesis of Condensed Pyrroloindoles via Pd-Catalyzed Intramolecular C−H Bond Functionalization of Pyrroles
2008
Computational Studies of Carboxylate-Assisted C–H Activation and Functionalization at Group 8–10 Transition Metal Centers
2017
Recent Advances in Copper-mediated Direct Biaryl Coupling
2015
A Cp*CoI2-dimer as a precursor for cationic Co(iii )-catalysis: application to C–H phosphoramidation of indoles
2015
Stereoselective Synthesis of Tetrasubstituted Alkenes via a Cp*CoIII‐Catalyzed C−H Alkenylation/Directing Group Migration Sequence
2017
Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C–H Activation
2012 Science
Ruthenium(II)-Catalyzed Regio- and Stereoselective Hydroarylation of Alkynes via Directed C–H Functionalization
2012
Chirale einzähnige Phosphine und sperrige Carbonsäuren: kooperative Effekte in Pd‐katalysierten enantioselektiven C(sp3)‐H‐Funktionalisierungen
2012
C–H Arylation Reaction: Atom Efficient and Greener Syntheses of π-Conjugated Small Molecules and Macromolecules for Organic Electronic Materials
2013
Site-Selective Azaindole Arylation at the Azine and Azole Rings via N-Oxide Activation
2009
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
2018 Standout
Straightforward access to aryl-substituted tetrathiafulvalenes by palladium-catalysed direct C–H arylation and their photophysical and electrochemical properties
2011
Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams
2015
Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles
2010
Palladium-Catalyzed Acylation of sp2 C−H bond: Direct Access to Ketones from Aldehydes
2009
Strong and Confined Acids Catalyze Asymmetric Intramolecular Hydroarylations of Unactivated Olefins with Indoles
2021 StandoutNobel
Engineered Biosynthesis of β‐Alkyl Tryptophan Analogues
2018 StandoutNobel
Iron-Catalyzed Heterocycle and Arene Deprotonative Alkylation
2010
Synthesis of Pyridine and Dihydropyridine Derivatives by Regio- and Stereoselective Addition toN-Activated Pyridines
2012 Standout
One-pot Sequential Direct C–H Bond Arylation of Azoles Catalyzed by [Pd(phen)2](PF6)2: Synthetic Methods for Triarylated Azoles
2012
Direct Synthesis of Pyrazolo[5,1‐a]isoindoles via Intramolecular Palladium‐Catalyzed CH Bond Activation
2010
Synthesis of Quinoline N‐Oxides by Cobalt‐Catalyzed Annulation of Arylnitrones and Alkynes
2017
Tuning Reactivity and Site Selectivity of Simple Arenes in C–H Activation: Ortho-Arylation of Anisoles via Arene–Metal π-Complexation
2014
Direct Arylation as a Synthetic Tool for the Synthesis of Thiophene-Based Organic Electronic Materials
2011
Palladium-Catalyzed Synthesis of 2-Substituted Benzothiazoles via a C−H Functionalization/Intramolecular C−S Bond Formation Process
2008
Synthesis of Benzocyclobutenes by Palladium-Catalyzed C−H Activation of Methyl Groups: Method and Mechanistic Study
2008
Pd(OAc)2-Catalyzed Oxidative C−H/C−H Cross-Coupling of Electron-Deficient Polyfluoroarenes with Simple Arenes
2010
Highly Efficient Catalytic System for C–H Activation: A Practical Approach to Angiotensin II Receptor Blockers
2011
Mild metal-catalyzed C–H activation: examples and concepts
2016 Standout
Modular Approach to Tricyclic Heterocycles through Copper Catalysis and Functionalization by Palladium‐Catalyzed C–H Arylation
2017
2-Aminobiphenyl Palladacycles: The “Most Powerful” Precatalysts in C–C and C–Heteroatom Cross-Couplings
2015
Rhodium-Catalyzed Oxidative 1:1, 1:2, and 1:4 Coupling Reactions of Phenylazoles with Internal Alkynes through the Regioselective Cleavages of Multiple C−H Bonds
2010
One-Pot Cross-Coupling/C–H Functionalization Reactions: Quinoline as a Substrate and Ligand through N–Pd Interaction
2020
Nickel-Catalyzed Alkynylation of a C(sp2)–H Bond Directed by an 8-Aminoquinoline Moiety
2015
Palladium-catalyzed trifluoroacetate-promoted mono-arylation of the β-methyl group of alanine at room temperature: synthesis of β-arylated α-amino acids through sequential C–H functionalization
2014
Palladium-Catalyzed Ortho-Arylation of O-Phenylcarbamates with Simple Arenes and Sodium Persulfate
2010
C4–H indole functionalisation: precedent and prospects
2018
Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners
2011 Standout
Dual role of carboxylic acid additive: mechanistic studies and implication for the asymmetric C–H amidation
2015
Mechanistic Details of Pd(II)-Catalyzed C–H Iodination with Molecular I2: Oxidative Addition vs Electrophilic Cleavage
2015
Palladium‐katalysierte selektive dehydrierende Kreuzkupplung von Heteroarenen
2011
Copper-Mediated Amination of Aryl C–H Bonds with the Direct Use of Aqueous Ammonia via a Disproportionation Pathway
2018
A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation
2013
Homologation of the Fischer Indolization: A Quinoline Synthesis via Homo‐Diaza‐Cope Rearrangement
2020 StandoutNobel
Palladium-Catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C−H Activation
2009
Synthesis of Indolines by Copper-Mediated Intramolecular Aromatic C–H Amination
2015
Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities
2016
Palladium-Catalyzed Selective β-Arylation of Aliphatic Amides Using a Removable N,O-Bidentate Auxiliary
2015
Programmed Synthesis of Tetraarylthiophenes through Sequential C−H Arylation
2009
C—H Bond Activation in Transition Metal Species from a Computational Perspective
2010
Copper-Mediated Formally Dehydrative Biaryl Coupling of Azine N-Oxides and Oxazoles
2015
Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C–H bond functionalization
2014
Pd‐Catalyzed CH Activation: Expanding the Portfolio of Metal‐Catalyzed Functionalization of Unreactive CH Bonds by Arene–Chromium π‐Complexation
2015
Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope
2011 Standout
Palladium-Catalyzed Direct Arylation of Nitro-Substituted Aromatics with Aryl Halides
2008
Ni-Catalyzed Alkenylation of Triazolopyridines: Synthesis of 2,6-Disubstituted Pyridines
2012
Synthesis of 2-Substituted Pyrazolo[1,5-a]pyridines through Cascade Direct Alkenylation/Cyclization Reactions
2010
Palladium-Catalyzed Transformations of Alkyl C–H Bonds
2016 Standout
Regioselective Palladium-Catalyzed Arylation of 4-Chloropyrazoles
2010
Rhodium(iii )-catalyzed C–H/C–C activation sequence: vinylcyclopropanes as versatile synthons in direct C–H allylation reactions
2014
Controlling Site Selectivity in Pd-Catalyzed Oxidative Cross-Coupling Reactions
2011
Carbonates: eco-friendly solvents for palladium-catalysed direct arylation of heteroaromatics
2010
Iridium(III)‐Catalyzed Direct CH Sulfonamidation of 2‐Aryl‐1,2,3‐triazole N‐Oxides with Sulfonyl Azides
2016
Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization
2012
Hydrofluoroarylation of Alkynes with Ni Catalysts. C–H Activation via Ligand-to-Ligand Hydrogen Transfer, an Alternative to Oxidative Addition
2011
Palladium-Catalyzed Direct Synthesis of Carbazoles via One-Pot N-Arylation and Oxidative Biaryl Coupling: Synthesis and Mechanistic Study
2009
Oxidative C–H/C–H Coupling Reactions between Two (Hetero)arenes
2017
Mechanistic Studies of the Rhodium-Catalyzed Direct C–H Amination Reaction Using Azides as the Nitrogen Source
2014
Full Selectivity Control in Cobalt(III)‐Catalyzed C−H Alkylations by Switching of the C−H Activation Mechanism
2017
Ring Construction by Palladium(0)-Catalyzed C(sp3)–H Activation
2017
The Complementary Competitors: Palladium and Copper in C–N Cross-Coupling Reactions
2012
Copper-Catalyzed Intramolecular Benzylic C–H Amination for the Synthesis of Isoindolinones
2016
Iridium(III)‐Catalyzed Benzylic Amine Directed CH Sulfonamidation of Arenes with Sulfonyl Azides
2015
Copper-Mediated Dehydrogenative Biaryl Coupling of Naphthylamines and 1,3-Azoles
2013
Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C–H Oxidation
2013
Cp*CoIII-catalyzed directed C–H trifluoromethylthiolation of 2-phenylpyridines and 6-arylpurines
2017
Mechanistic Study of Chemoselectivity in Ni-Catalyzed Coupling Reactions between Azoles and Aryl Carboxylates
2014
The medicinal chemist's toolbox for late stage functionalization of drug-like molecules
2015
Polycondensation of Dibromofluorene Analogues with Tetrafluorobenzene via Direct Arylation
2011
Copper Catalyzed N-Arylation of Amidines with Aryl Boronic Acids and One-Pot Synthesis of Benzimidazoles by a Chan–Lam–Evans N-Arylation and C–H Activation/C–N Bond Forming Process
2012
Oxidative Alkenylation of Aromatic Esters by Ruthenium-Catalyzed Twofold C–H Bond Cleavages
2012
Ligand-promoted intramolecular dehydrogenative cross-coupling using a Cu catalyst: direct access to polycyclic heteroarenes
2015
Cp*CoIII-Catalyzed C–H Alkenylation/Annulation Reactions of Indoles with Alkynes: A DFT Study
2017
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
2011 Standout
Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds
2015
C–H Bond Arylations and Benzylations on Oxazol(in)es with a Palladium Catalyst of a Secondary Phosphine Oxide
2011
Cu-Catalyzed Mild C(sp2)–H Functionalization Assisted by Carboxylic Acids en Route to Hydroxylated Arenes
2013
Cp*CoIII-Catalyzed Dehydrative C–H Allylation of 6-Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols
2016
RuCl3-Catalyzed Alkenylation of Aromatic C−H Bonds with Terminal Alkynes
2008
Ruthenium(II) Acetate Catalyst for Direct Functionalisation of sp2‐CH Bonds with Aryl Chlorides and Access to Tris‐ Heterocyclic Molecules
2009
Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides
2010
Direct arylation of dithienylperfluorocyclopentenes via palladium-catalysed C–H bond activation: a simpler access to photoswitches
2012
Air‐Stable Carbonyl(pentamethylcyclopentadienyl)cobalt Diiodide Complex as a Precursor for Cationic (Pentamethylcyclopentadienyl)cobalt(III) Catalysis: Application for Directed C‐2 Selective CH Amidation of Indoles
2014
Azine Activation via Silylium Catalysis
2021 StandoutNobel
Experimental and theoretical investigation of the oxidative carbonylation of toluene to toluic acid catalyzed by palladium(II) in the presence of vanadium and molecular oxygen
2012
Evaluation of Electron‐Deficient Phosphine Ligands for Direct Arylation of Heterocycles
2010
Cobalt-Catalyzed Addition of Azoles to Alkynes
2010
Transition‐Metal‐Mediated Routes to 3,3‐Disubstituted Oxindoles through Anilide Cyclisation
2011
Synthesis of Angiotensin II Receptor Blockers by Means of a Catalytic System for C–H Activation
2011
Pd-Catalyzed Direct Arylation of Polyfluoroarenes on Water under Mild Conditions Using PPh3 Ligand
2012
A Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C–H Amidation Using Azidoformates
2016
Highly Regioselective Palladium-Catalyzed Direct Arylation of Oxazole at C-2 or C-5 with Aryl Bromides, Chlorides, and Triflates
2010
Ruthenium(II)-Catalyzed C–H Arylation of Azoarenes by Carboxylate Assistance
2015
Palladium‐Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation
2009
Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups
2015
Heterocycle Formation via Palladium-Catalyzed Intramolecular Oxidative C−H Bond Functionalization: An Efficient Strategy for the Synthesis of 2-Aminobenzothiazoles
2009
Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations
2013 Standout
Origins of regioselectivity of the palladium-catalyzed (aromatic)CH bond metalation–deprotonation
2012
A Mild and Direct Site-Selective sp2 C–H Silylation of (Poly)Azines
2018
Weakly Coordinating, Ketone-Directed Cp*Co(III)-Catalyzed C–H Allylation on Arenes and Indoles
2017
Isolation of Cp*CoIII–Alkenyl Intermediate in Efficient Cobalt‐Catalyzed C−H Alkenylation with Alkynes
2017
Mechanistic Study of Acetate-Assisted C−H Activation of 2-Substituted Pyridines with [MCl2Cp*]2(M = Rh, Ir) and [RuCl2(p-cymene)]2
2008
Recent Developments in C–H Activation for Materials Science in the Center for Selective C–H Activation
2018
Direct and Regioselective C−H Alkenylation of Tetrahydropyrido[1,2-a]pyrimidines
2009
Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates
2009
The broadening reach of frustrated Lewis pair chemistry
2016 StandoutScience
Palladium–Silver Cooperativity in an Aryl Amination Reaction through C–H Functionalization
2015
Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization
2012
Pd/Cu‐Catalyzed Direct Alkenylation of Azole Heterocycles with Alkenyl Halides
2010
Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies
2011
Total Synthesis of Diptoindonesin G via a Highly Efficient Domino Cyclodehydration/Intramolecular Friedel−Crafts Acylation/Regioselective Demethylation Sequence
2010
Regioselective Ruthenium-Catalyzed Direct Benzylations of Arenes through C−H Bond Cleavages
2009
User‐Friendly [(Diglyme)NiBr2]‐Catalyzed Direct Alkylations of Heteroarenes with Unactivated Alkyl Halides through CH Bond Cleavages
2011
Highly Efficient and Versatile Pd-Catalyzed Direct Alkynylation of Both Azoles and Azolines
2010
Mechanisms of Nucleophilic Organocopper(I) Reactions
2011
(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed C–H Bond Functionalization: From Discovery to Unique Reactivity and Selectivity
2017
Assessment of the Intermediacy of Arylpalladium Carboxylate Complexes in the Direct Arylation of Benzene: Evidence for C−H Bond Cleavage by “Ligandless” Species
2011
Experimental and Theoretical Studies on Rhodium-Catalyzed Coupling of Benzamides with 2,2-Difluorovinyl Tosylate: Diverse Synthesis of Fluorinated Heterocycles
2017
Synthesis of 5‐Alkyl[3,4‐c]thienopyrrole‐4,6‐dione‐Based Polymers by Direct Heteroarylation
2011
Mechanisms and Origins of Switchable Chemoselectivity of Ni-Catalyzed C(aryl)–O and C(acyl)–O Activation of Aryl Esters with Phosphine Ligands
2014
Mechanistic Investigation of Palladium-Catalyzed Allylic C–H Activation
2013
Mechanism and Regioselectivity of Rh(III)-Catalyzed Intermolecular Annulation of Aryl-Substituted Diazenecarboxylates and Alkenes: DFT Insights
2016
Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization
2012 Standout
Pd-Catalyzed Intermolecular ortho-C−H Amidation of Anilides by N-Nosyloxycarbamate
2010
Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation
2010
Metal and Metal Oxide Nanoparticles: A Lever for C–H Functionalization
2016
Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates
2014
Mechanistic Study of the Direct Intramolecular Allylic Amination Reaction Catalyzed by Palladium(II)
2016
Stereoselective Intermolecular Allylic C–H Trifluoroacetoxylation of Functionalized Alkenes
2012
A Highly Efficient Ruthenium(II) Catalyst with (1,2-Diarylvinyl)phosphine Ligands for Direct Ortho Arylation of 2-Arylpyridine with Aryl Chlorides
2010
Copper-Catalyzed Dehydrogenative Cross-Coupling of Benzothiazoles with Thiazoles and Polyfluoroarene
2012
Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes
2009
Oxidative C–H/C–H Coupling of Azine and Indole/Pyrrole Nuclei: Palladium Catalysis and Synthesis of Eudistomin U
2011
Ruthenium-catalyzed coupling reaction of 2,3,5-trisubstituted furans with aryl halides through C–H bond cleavages
2011
Mild Cobalt(III)‐Catalyzed Allylative C−F/C−H Functionalizations at Room Temperature
2017
“On Water” Direct and Site‐Selective Pd‐Catalysed CH Arylation of (NH)‐Indoles
2010
Palladium(II)-Catalyzed Oxidative C−H/C−H Cross-Coupling of Heteroarenes
2010
Selective Synthesis of 3-Aryl Quinolin-2(1H)-ones and 3-(1-Arylmethylene)oxindoles Involving a 2-Fold Arene C−H Activation Process
2009
Cobalt-Catalyzed Selective Synthesis of Isoquinolines Using Picolinamide as a Traceless Directing Group
2017
Palladium-catalyzed Direct C–H Bond Arylation of Simple Arenes with Aryltrimethylsilanes
2011
Key Mechanistic Features of Ni-Catalyzed C–H/C–O Biaryl Coupling of Azoles and Naphthalen-2-yl Pivalates
2014
Intramolecular Oxidative C−H Coupling for Medium-Ring Synthesis
2010
Ohne dirigierende Gruppen: übergangsmetallkatalysierte C‐H‐Aktivierung einfacher Arene
2012
Intermolecular Dehydrogenative Heck Reactions
2011
Chemomimetic Biocatalysis: Exploiting the Synthetic Potential of Cofactor-Dependent Enzymes To Create New Catalysts
2015 StandoutNobel
Synthesis of 3-Haloindolizines by Copper(II) Halide Mediated Direct Functionalization of Indolizines
2009
Gold(I)-Mediated C−H Activation of Arenes
2010
Übergangsmetallkatalysierte direkte Arylierungen von (Hetero)Arenen durch C‐H‐Bindungsbruch
2009
Ruthenium-catalyzed direct arylations with aryl chlorides
2016
A Detailed Study of Acetate-Assisted C–H Activation at Palladium(IV) Centers
2013
Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups
2018
Copper-Mediated sp 2 C–H Chlorination with Trichloroacetamide Using a Removable Directing Group
2017
Regioselective Oxidative Coupling Reactions of 3-Substituted Thiophenes with Arylboronic Acids
2011
Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
2016 Standout
Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H Functionalization
2011
A General Catalyst for the β‐Selective C–H Bond Arylation of Thiophenes with Iodoarenes
2010
Cationic Palladium(II) Catalysis: C−H Activation/Suzuki−Miyaura Couplings at Room Temperature
2010
Facile Benzo-Ring Construction via Palladium-Catalyzed Functionalization of Unactivated sp3 C−H Bonds under Mild Reaction Conditions
2010
Pyridine N-Oxide vs Pyridine Substrates for Rh(III)-Catalyzed Oxidative C–H Bond Functionalization
2015
Intramolecular Palladium-Catalyzed Alkane C−H Arylation from Aryl Chlorides
2010
High-Valent Co(III)- and Ni(II)-Catalyzed C–H Activation
2014
Functionalization of a Simple Dithienylethene via Palladium-Catalyzed Regioselective Direct Arylation
2011
Pd-Catalyzed Cascade Crossover Annulation of o-Alkynylarylhalides and Diarylacetylenes Leading to Dibenzo[a,e]pentalenes
2013
C–H arylations of 1,2,3-triazoles by reusable heterogeneous palladium catalysts in biomass-derived γ-valerolactone
2016
A potential role of a substrate as a base for the deprotonation pathway in Rh-catalysed C–H amination of heteroarenes: DFT insights
2016
Low-valent cobalt-catalyzed C–H allylation
2016
Improving the Catalytic Performance of an Artificial Metalloenzyme by Computational Design
2015 StandoutNobel
Catalytic Enantioselective Transformations Involving C–H Bond Cleavage by Transition-Metal Complexes
2017
Rh(III)-Catalyzed Cyclopropanation Initiated by C–H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes
2014
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Nickel-catalyzed intramolecular C–H arylation using aryl pivalates as electrophiles
2013
Stereoselective Synthesis of β-Alkylated α-Amino Acids via Palladium-Catalyzed Alkylation of Unactivated Methylene C(sp3)–H Bonds with Primary Alkyl Halides
2013
Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 Carbon−Hydrogen Bonds
2010
Copper‐Catalyzed Direct Sulfoximination of Heteroaromatic N‐Oxides by Dual C−H/N−H Dehydrogenative Cross‐Coupling
2015
Palladium-Catalyzed Picolinamide-Directed Alkylation of Unactivated C(sp3)–H Bonds with Alkyl Iodides
2013
Highly Regioselective Palladium-Catalyzed Oxidative Coupling of Indolizines and Vinylarenes via C−H Bond Cleavage
2009
Iridium-Catalyzed Direct C–H Amination with Alkylamines: Facile Oxidative Insertion of Amino Group into Iridacycle
2015
Copper-Catalyzed Direct Benzylation or Allylation of 1,3-Azoles with N-Tosylhydrazones
2011
Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications
2017 Standout
Towards applications of metal–organic frameworks in catalysis: C–H direct activation of benzoxazole with aryl boronic acids using Ni2(BDC)2(DABCO) as an efficient heterogeneous catalyst
2013
Copper(II)‐Catalyzed meta‐Selective Direct Arylation of α‐Aryl Carbonyl Compounds
2010
Cationic Cobalt(III) Catalyzed Indole Synthesis: The Regioselective Intermolecular Cyclization of N‐Nitrosoanilines and Alkynes
2016
Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism
2010
Cobalt-Catalyzed C–H Activation
2015
Site- and Regioselective Monoalkenylation of Pyrroles with Alkynes via Cp*CoIII Catalysis
2016
Direct C−H Transformation via Iron Catalysis
2010 Standout
Room-Temperature Direct Arylation of Polyfluorinated Arenes under Biphasic Conditions
2010
Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C–H Bond Cleavage
2012
Catalyst and base controlled site-selective sp2 and sp3 direct arylation of azine N-oxides
2008
Weakly Coordinating Directing Groups for Ruthenium(II)‐ Catalyzed CH Activation
2014
Cobalt(III)-Catalyzed [5 + 1] Annulation for 2H-Chromenes Synthesis via Vinylic C–H Activation and Intramolecular Nucleophilic Addition
2016
Pd(ii)-catalyzed alkoxylation of unactivated C(sp3)–H and C(sp2)–H bonds using a removable directing group: efficient synthesis of alkyl ethers
2013
Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of the meta-Regioselectivity
2011
Direct Arylations of 2H-Indazoles On Water
2009
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
2009 Standout
A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides
2013
Palladium-Catalyzed Alkenylation and Alkynylation of ortho-C(sp2)–H Bonds of Benzylamine Picolinamides
2012
Funktionalisierung von C‐H‐Bindungen: neue Synthesemethoden für Naturstoffe und Pharmazeutika
2012
Ru-catalysed C–H functionalisations as a tool for selective organic synthesis
2016
Recent development of direct asymmetric functionalization of inert C–H bonds
2013
Site-selective C–H arylation of primary aliphatic amines enabled by a catalytic transient directing group
2016
Highly Efficient and Versatile Synthesis of Polyarylfluorenes via Pd-Catalyzed C−H Bond Activation
2009
Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence
2014
Cu‐Catalyzed Intramolecular Amidation of Unactivated C(sp3)−H Bonds To Synthesize N‐Substituted Indolines
2016
Cp∗Co(III)-catalyzed oxidative C–H alkenylation of benzamides with ethyl acrylate
2015
Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes
2011
Palladium-Catalyzed Arylation of Cyclopropanes via Directing Group-Mediated C(sp3)–H Bond Activation To Construct Quaternary Carbon Centers: Synthesis of cis- and trans-1,1,2-Trisubstituted Chiral Cyclopropanes
2013
Catalytic C–C coupling through C–H arylation of arenes or heteroarenes
2009
Dehydrative Direct Arylations of Arenes with Phenols via Ruthenium-Catalyzed C−H and C−OH Bond Functionalizations
2008
Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents
2012 StandoutNobel
Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)
2012
TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines
2009
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
2010 Standout
Copper‐Mediated CH/CH Biaryl Coupling of Benzoic Acid Derivatives and 1,3‐Azoles
2013
A Catalytic, Brønsted Base Strategy for Intermolecular Allylic C−H Amination
2009
TADDOL-based phosphorus(iii )-ligands in enantioselective Pd(0)-catalysed C–H functionalisations
2015
Transition‐Metal‐Catalyzed Direct C–H Alkenylation, Alkynylation, Benzylation, and Alkylation of (Hetero)arenes
2010
Mechanism of Benzoquinone-Promoted Palladium-Catalyzed Oxidative Cross-Coupling Reactions
2009
Regioselective Oxidative Arylation of Indoles Bearing N-Alkyl Protecting Groups: Dual C−H Functionalization via a Concerted Metalation−Deprotonation Mechanism
2010
Cp*CoIII Catalyzed Site‐Selective CH Activation of Unsymmetrical O‐Acyl Oximes: Synthesis of Multisubstituted Isoquinolines from Terminal and Internal Alkynes
2015
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition‐Metal‐Catalyzed CH Functionalization
2013
Proton-Coupled Electron Transfer
2012 Standout
Auxiliary-assisted palladium-catalyzed halogenation of unactivated C(sp3)–H bonds at room temperature
2016
Synthesis of Complex Allylic Esters via C−H Oxidation vs C−C Bond Formation
2010
Amine directed Pd(ii )-catalyzed C–H bond functionalization under ambient conditions
2010
Organometallic Approaches for Direct Modification of Peripheral CH Bonds in Porphyrin Cores
2013
Cobalt(II)-Catalyzed Oxidative C–H Alkenylations: Regio- and Site-Selective Access to Isoindolin-1-one
2015
Direct (Hetero)Arylation: A New Tool for Polymer Chemists
2013
Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate
2012
Palladium-Catalyzed C−H Activation/C−N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates
2010
Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity
2015 Standout
Palladium-Catalyzed Asymmetric Arylation of C(sp3)–H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids
2015
Mechanistic Analysis of Azine N-Oxide Direct Arylation: Evidence for a Critical Role of Acetate in the Pd(OAc)2 Precatalyst
2010
CuI-Mediated Sequential Iodination/Cycloetherification ofo-Arylphenols: Synthesis of 2- or 4-Iododibenzofurans and Mechanistic Studies
2012
Synthesis of Functionalized Spiroindolines via Palladium-Catalyzed Methine C–H Arylation
2013
Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C–H Functionalization
2012 Science
Synthesis of Carbazoles by Copper-Catalyzed Intramolecular C–H/N–H Coupling
2014
Direct (Hetero)arylation Polymerization: Simplicity for Conjugated Polymer Synthesis
2016
Palladium-Catalyzed Direct ortho-Alkynylation of Aromatic Carboxylic Acid Derivatives
2011
Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme
2017 StandoutNobel
Switching the Regioselectivity of Direct C–H Arylation of 1,3‐Dimethyluracil
2009
Understanding Ni(II)-Mediated C(sp3)–H Activation: Tertiary Ureas as Model Substrates
2018
Cp*Co(III)-Catalyzed C–H Functionalization Cascade of N-Methoxyamides with Alkynedione for the Synthesis of Indolizidines
2017
Works of David Lapointe being referenced
Gallium(III)‐Catalyzed Cycloisomerization Approach to the Diterpenoid Alkaloids: Construction of the Core Structure for the Hetidines and Hetisines
2013
Establishment of Broadly Applicable Reaction Conditions for the Palladium-Catalyzed Direct Arylation of Heteroatom-Containing Aromatic Compounds
2009
Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates
2008 Standout
Mild and efficient palladium-catalyzed intramolecular direct arylation reactions
2008
Domino Palladium-Catalyzed Heck-Intermolecular Direct Arylation Reactions
2009
Predictable and Site-Selective Functionalization of Poly(hetero)arene Compounds by Palladium Catalysis
2010
Palladium-Catalyzed Benzylation of Heterocyclic Aromatic Compounds
2009
Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes
2011
Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway
2010 Standout