Standout Papers
Citation Impact
Citing Papers
Olefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 Enzymes
2012 StandoutScienceNobel
Crippling life support for SARS-CoV-2 and other viruses through synthetic lethality
2020 StandoutNobel
Bioorthogonal Chemistry: Fishing for Selectivity in a Sea of Functionality
2009 StandoutNobel
Short-Term Effects of Nose-Only Cigarette Smoke Exposure on Glutathione Redox Homeostasis, Cytochrome P450 1A1/2 and Respiratory Enzyme Activities in Mice Tissues
2013 Standout
A rapid entry to C-prenylcarbazoles: total synthesis of clausamine C–D, clausevatine D and clausine F
2010
α‐ and β‐Glycosyl Sulfonium Ions: Generation and Reactivity
2009
Alcohols in Isonitrile‐Based Multicomponent Reaction: Passerini Reaction of Alcohols in the Presence of O‐Iodoxybenzoic Acid
2006
Copper-catalyzed decarboxylative C(sp2)–C(sp3) coupling reactions via radical mechanism
2012
New Principles for Glycoside‐Bond Formation
2009
Synthesis of Highly Substituted Tetrahydrofurans by Catalytic Polar‐Radical‐Crossover Cycloadditions of Alkenes and Alkenols
2013
Rethinking amide bond synthesis
2011 StandoutNature
Reactions of oxyl radicals with DNA
1995
Use of Click Chemistry to Define the Substrate Specificity of Leishmania β‐1,2‐Mannosyltransferases
2006
Homogeneous Photocatalytic Reactions with Organometallic and Coordination Compounds—Perspectives for Sustainable Chemistry
2012
A novel neoglycopeptide linkage compatible with native chemical ligation
2006 StandoutNobel
Chemical and chemoenzymatic synthesis of glycosyl-amino acids and glycopeptides related to Trypanosoma cruzi mucins
2007
Indirect Cation‐Flow Method: Flash Generation of Alkoxycarbenium Ions and Studies on the Stability of Glycosyl Cations
2011
2‐Iodoxybenzoic Acid—A Simple Oxidant with a Dazzling Array of Potential Applications
2011
Decarboxylative reduction of free aliphatic carboxylic acids by photogenerated cation radical
2007
IBX‐Mediated Oxidative Ugi‐Type Multicomponent Reactions: Application to the N and C1 Functionalization of Tetrahydroisoquinoline
2007
Oxidative Geminal Functionalization of Organoboron Compounds
2012
Oxidative Cyclization Reactions: Controlling the Course of a Radical Cation‐Derived Reaction with the Use of a Second Nucleophile
2013
Chemoselective Ligation and Modification Strategies for Peptides and Proteins
2008
Thirteen decades of peptide synthesis: key developments in solid phase peptide synthesis and amide bond formation utilized in peptide ligation
2017
Fluorogenic probes using 4-substituted-2-nitrobenzenesulfonyl derivatives as caging groups for the analysis of human glutathione transferase catalyzed reactions
2013
Annonaceous Acetogenins: The Hydroxyl Groups and THF Rings Are Crucial Structural Elements for Targeting the Mitochondria, Demonstration with the Synthesis of Fluorescent Squamocin Analogues
2005
Click Chemistry in Complex Mixtures: Bioorthogonal Bioconjugation
2014
NMR evidence for the participation of triflated ionic liquids in glycosylation reaction mechanisms
2006
Catalysis of Radical Reactions: A Radical Chemistry Perspective
2015
Biaryl Phosphane Ligands in Palladium‐Catalyzed Amination
2008 Standout
Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α‐Oxo Acids
2015
Exploration of the interrupted Fischer indolization reaction
2010
1,n‐Hydrogen‐Atom Transfer (HAT) Reactions in Which n≠5: An Updated Inventory
2014
An overview of N-heterocyclic carbenes
2014 StandoutNature
Intramolecular 1,8‐Hydrogen‐Atom Transfer Reactions in (1→4)‐O‐Disaccharide Systems: Conformational and Stereochemical Requirements
2008
Lysosome-targeting chimaeras for degradation of extracellular proteins
2020 StandoutNatureNobel
Acetone‐Linked Peptides: A Convergent Approach for Peptide Macrocyclization and Labeling
2015
Organic Azides: An Exploding Diversity of a Unique Class of Compounds
2005 Standout
Metal‐Free Cross‐Dehydrogenative Coupling of Heterocycles with Aldehydes
2013
Thiol–Ene Click Chemistry
2010 Standout
A Fluorogenic Aryl Fluorosulfate for Intraorganellar Transthyretin Imaging in Living Cells and in Caenorhabditis elegans
2015 StandoutNobel
A Versatile Method To Prepare RAFT Agent Anchored Substrates and the Preparation of PMMA Grafted Nanoparticles
2006
Electrochemical synthesis of dendritic diarylcarbenium ion pools
2011
Synthesis of Carbazoles by Intramolecular Arylation of Diarylamide Anions
2009
Radical decarboxylative alkylation onto heteroaromatic bases with trivalent iodine compounds
1993
Anodic Coupling Reactions: The Use of N,O-Ketene Acetal Coupling Partners
2004
Resolution of Diols via Catalytic Asymmetric Acetalization
2015 StandoutNobel
The propensity for covalent organic frameworks to template polymer entanglement
2024 StandoutScienceNobel
A Highly Selective Tandem Cross-Coupling ofgem-Dihaloolefins for a Modular, Efficient Synthesis of Highly Functionalized Indoles
2007
Tetraarylphosphonium Salts as Soluble Supports for Oxidative Catalysts and Reagents
2009
Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation
2012 StandoutNobel
Acyclic stereochemical control in free-radical reactions
1991
Reductive Addition of Alkyl Radical to Phenyl Vinyl Sulfone
1992
Quantum Chemical Studies of Radical-Containing Enzymes
2003
Polyvalent iodine in organic chemistry: Recent developments, 2002–2005
2006
Silver-Catalyzed Radical Tandem Cyclization: An Approach to Direct Synthesis of 3-Acyl-4-arylquinolin-2(1H)-ones
2014
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
2011 Standout
Studies of the Mechanism and Origins of Enantioselectivity for the Chiral Phosphoric Acid-Catalyzed Stereoselective Spiroketalization Reactions
2015
Oligosaccharide Synthesis Based on a One-pot Electrochemical Glycosylation–Fmoc Deprotection Sequence
2008
First total synthesis of (±)-epocarbazolin A and epocarbazolin B, and asymmetric synthesis of (−)-epocarbazolin A via Shi epoxidation
2006
Highly diastereoselective synthesis of pyrido[2,1-b][1,3]oxazin-4(6H)-one by intramolecular anodic oxidation
2009
A mild oxidative decarboxylation of carbohydrate acids
1997
Gold-Catalyzed Direct Arylation
2012 Science
Electrochemical O-glycosylation using thioglycosides as glycosyl donors in the presence of a catalytic amount of sodium trifluoromethanesulfonate as a supporting electrolyte
2007
Fine Feathers Make Fine Birds: The Heck Reaction in Modern Garb
1995
Chemical Glycobiology
2001 StandoutScienceNobel
Oxidations of Secondary Alcohols to Ketones Using Easily Recyclable Bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF3(CF2)n-1I(OCOCF3)2
2006
A Flexible Route to Mannose 6-Phosphonate Functionalized Derivatives
2002
Enantioselective Synthesis of Pyrroloindolines via Noncovalent Stabilization of Indole Radical Cations and Applications to the Synthesis of Alkaloid Natural Products
2018
An easily accessed class of recyclable hypervalent iodide reagents for functional group oxidations: bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)n–1I(OCOCF3)2
2005
Multistep Solid-State Organic Synthesis of Carbamate-Linked Covalent Organic Frameworks
2019 StandoutNobel
Carbon−Carbon Bond Forming Reactions Mediated by Silicon Lewis Acids
2003 Standout
Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor
2008
Room Temperature Palladium-Catalyzed Decarboxylative ortho-Acylation of Acetanilides with α-Oxocarboxylic Acids
2010
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
2001 Standout
Fluorous phase chemistry: a new industrial technology
2002
A synthetic approach to carbazoles using electrochemically generated hypervalent iodine oxidant
2010
Carbodiimide-Mediated Preparation of the Tricyclic Pyrido[3‘,2‘:4,5]pyrrolo[1,2-c]pyrimidine Ring System and Its Application to the Synthesis of the Potent Antitumoral Marine Alkaloid Variolin B and Analog
2002
Recent developments in indole ring synthesis—methodology and applications
2000 Standout
Electrochemical glycosylation in the presence of a catalytic chemical mediator
2008
Precision Polymer Synthesis by Degenerative Transfer Controlled/Living Radical Polymerization Using Organotellurium, Organostibine, and Organobismuthine Chain-Transfer Agents
2009
Catalytic, Asymmetric Transannular Aldolizations: Total Synthesis of (+)-Hirsutene
2008 StandoutNobel
Occurrence, Biogenesis, and Synthesis of Biologically Active Carbazole Alkaloids
2012 Standout
1-Fluoropyridinium triflates: versatile reagents for transformation of thioglycoside into O-glycoside, glycosyl azide and sulfoxide
2003
Functionalization of Coordination Nanochannels for Controlling Tacticity in Radical Vinyl Polymerization
2010 StandoutNobel
Chemical Approaches to Glycobiology
2010
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Perfluoroalkyl-Functionalized Covalent Organic Frameworks with Superhydrophobicity for Anhydrous Proton Conduction
2020 StandoutNobel
Hydrodecarboxylation of Carboxylic and Malonic Acid Derivatives via Organic Photoredox Catalysis: Substrate Scope and Mechanistic Insight
2015
Automated Electrochemical Assembly of the Protected Potential TMG-chitotriomycin Precursor Based on Rational Optimization of the Carbohydrate Building Block
2015
Tandem Radical Decarboxylation−Oxidation of Amino Acids: A Mild and Efficient Method for the Generation of N-Acyliminium Ions and Their Nucleophilic Trapping
2000
Organocatalyzed Anodic Oxidation of Aldehydes to Thioesters
2014
Recent developments in oligosaccharide synthesis
2000
Metal-Catalyzed Decarboxylative C–H Functionalization
2017 Standout
Homogeneous Catalysis in Supercritical Fluids
1999 StandoutNobel
Photo‐Organocatalytic Enantioselective Radical Cascade Reactions of Unactivated Olefins
2018
A chemoenzymatic synthesis of the linear triquinane (−)-hirsutene and identification of possible precursors to the naturally occurring (+)-enantiomer
2003
Folding of a donor–acceptor polyrotaxane by using noncovalent bonding interactions
2008 StandoutNobel
Enantioselective Imidation of Sulfides via Enzyme-Catalyzed Intermolecular Nitrogen-Atom Transfer
2014 StandoutNobel
Stereoselective Cyclopropanation Reactions
2003 Standout
Stereoselective intramolecular cyclopropanations: Enantioselective syntheses of 1α,25-dihydroxyvitamin D3 A-ring precursors
1995
De novo design of covalently constrained mesosize protein scaffolds with unique tertiary structures
2017 StandoutNobel
One-pot selective oxidation/olefination of primary alcohols using TEMPO–BAIB system and stabilized phosphorus ylides
2005
Hypervalent iodine in synthesis. Part 54: One-step conversion of aryl aldehydes to aroyl azides using a combined reagent of (diacetoxyiodo)benzene with sodium azide
2000
A Pictet-Spengler ligation for protein chemical modification
2012 StandoutNobel
Direct Catalytic Anti-Markovnikov Hydroetherification of Alkenols
2012
IBS-Catalyzed Regioselective Oxidation of Phenols to 1,2-Quinones with Oxone®
2012
Automated Solution-Phase Synthesis of Oligosaccharides via Iterative Electrochemical Assembly of Thioglycosides
2013
Investigating the Reactivity of Radical Cations: Experimental and Computational Insights into the Reactions of Radical Cations with Alcohol and p-Toluene Sulfonamide Nucleophiles
2012
Reductive addition to electron-deficient olefins with trivalent iodine compounds
1993
Metal–Organic Polyhedral Core as a Versatile Scaffold for Divergent and Convergent Star Polymer Synthesis
2016 StandoutNobel
Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance
2017 Standout
The reaction of acetic acid 2‐selenoxo‐2H‐pyridin‐1‐yl esters with benzynes: A convenient route to Benzo[b]seleno[2,3‐b]pyridines
2004
Understanding the Chemistry and Biology of Glycosylation with Glycan Synthesis
2016
Distannane mediated reaction of N-acyliminium ion pools with alkyl halides. A chain mechanism involving radical addition followed by electron transfer
2006
Chemically tunable mucin chimeras assembled on living cells
2015 StandoutNobel
Radical Addition to “Cation Pool”. Reverse Process of Radical Cation Fragmentation
2005
Glycosyl Sulfonium Ions as Storable Intermediates for Glycosylations
2011
An Air- and Water-Stable Iodonium Salt Promoter for Facile Thioglycoside Activation
2014
When Phosphosugars Meet Gold: Synthesis and Catalytic Activities of Phostones and Polyhydroxylated Phosphonite Au(I) Complexes
2015
Modern Strategies in Electroorganic Synthesis
2008
Quantum Chemical Studies of Radical-Containing Enzymes
2003
Generation of Alkoxycarbenium Ion Pools from Thioacetals and Applications to Glycosylation Chemistry
2004
Photochemical Reactions as Key Steps in Organic Synthesis
2008
Dual Catalysis Strategies in Photochemical Synthesis
2016 Standout
Understanding Reactivity Patterns of Radical Cations
1997
Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals
2011 Standout
Electrostatic Basis for Enzyme Catalysis
2006 StandoutNobel
Adventures in Carbohydrate Chemistry: New Synthetic Technologies, Chemical Synthesis, Molecular Design, and Chemical Biology
2001
Mechanical Susceptibility of a Rotaxane
2019
Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System
2013
Adventures in Carbohydrate Chemistry: New Synthetic Technologies, Chemical Synthesis, Molecular Design, and Chemical Biology A list of abbreviations can be found at the end of this article. Telemachos Charalambous was an inspiring teacher at the Pancyprian Gymnasium, Nicosia, Cyprus.
2001
Advances in Synthetic Applications of Hypervalent Iodine Compounds
2016 Standout
Chemoselektive Ligations‐ und Modifikationsstrategien für Peptide und Proteine
2008
[C−H···O] Interactions as a Control Element in Supramolecular Complexes: Experimental and Theoretical Evaluation of Receptor Affinities for the Binding of Bipyridinium-Based Guests by Catenated Hosts1
1999 StandoutNobel
Amine Functionalization via Oxidative Photoredox Catalysis: Methodology Development and Complex Molecule Synthesis
2015
Hydrogen atom transfer experiments provide chemical evidence for the conformational differences between C- and O-glycosides
2007
Recent advances in enantioselective copper-catalyzed 1,4-addition
2009 StandoutNobel
Regioselective Csp2–H dual functionalization of indoles using hypervalent iodine(iii ): bromo-amination via 1,3-migration of imides on indolyl(phenyl)iodonium imides
2014
A simple and efficient approach to realize difunctionalization of arylketones with malonate esters via electrochemical oxidation
2014
Competition studies and the relative reactivity of enol ether and allylsilane coupling partners toward ketene dithioacetal derived radical cations
2015
Asymmetric Catalysis via Cyclic, Aliphatic Oxocarbenium Ions
2017 StandoutNobel
Diastereoselective photosensitised radical addition to fumaric acid derivatives bearing oxazolidine chiral auxiliaries
2000
Pd-Catalyzed Asymmetric Intermolecular Hydroalkoxylation of Allene: An Entry to Cyclic Acetals with Activating Group-Free and Flexible Anomeric Control
2014
Extending Pummerer Reaction Chemistry. Application to the Oxidative Cyclization of Indole Derivatives
2004
Chemoenzymatic elaboration of monosaccharides using engineered cytochrome P450 BM3 demethylases
2009 StandoutNobel
Electro-reductive cyclization of aryl halides promoted by fluorene derivatives
2012
Electrochemically Generated ArS(ArSSAr)+B(C6F5)4− as an Activator of Thioglycosides for Glycosylation
2011
De Novo Asymmetric Bio- and Chemocatalytic Synthesis of Saccharides − Stereoselective Formal O-Glycoside Bond Formation Using Palladium Catalysis
2003 StandoutNobel
Activation of olefins via asymmetric Brønsted acid catalysis
2018 StandoutScienceNobel
Reactions of conjugated haloenoates with nucleophilic reagents
2001
Conformationally restricted amino acids: Diastereoselective substitution at the β-position of L-tryptophan
1992
Toward an enhanced understanding and implementation of photopolymerization reactions
2008
Catalytic Asymmetric Transacetalization
2010 StandoutNobel
Indirect Cation Pool Method. Rapid Generation of Alkoxycarbenium Ion Pools from Thioacetals
2006
Regioselective synthesis of 1-hydroxycarbazoles via anionic [4+2] cycloaddition of furoindolones: a short synthesis of murrayafoline-A
2005
The Catalytic Asymmetric Fischer Indolization
2011 StandoutNobel
Cu-Catalyzed Azide−Alkyne Cycloaddition
2008 StandoutNobel
Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides
2003
Total Synthesis of 5-N-Acetylardeemin and Amauromine: Practical Routes to Potential MDR Reversal Agents
1999
Self‐Regeneration of Stereocenters (SRS)—Applications, Limitations, and Abandonment of a Synthetic Principle
1996
Scavenging Byproducts in the Sulfoxide Glycosylation Reaction: Application to the Synthesis of Ciclamycin 0
1999
1,1′-(azodicarbonyl)dipiperidine-tributylphosphine, a new reagent system for mitsunobu reaction
1993
CalFluors: A Universal Motif for Fluorogenic Azide Probes across the Visible Spectrum
2015 StandoutNobel
Stereochemische Eigenschaften als Diversitätselement: Festphasensynthese cyclischer RGD-Peptidderivate via asymmetrische Katalyse
1998
Photoredox Mediated Nickel Catalyzed Cross-Coupling of Thiols With Aryl and Heteroaryl Iodides via Thiyl Radicals
2016
Iodine(V) Reagents in Organic Synthesis. Part 4. o-Iodoxybenzoic Acid as a Chemospecific Tool for Single Electron Transfer-Based Oxidation Processes
2002
Palladium-Catalyzed Method for the Synthesis of Carbazoles via Tandem C−H Functionalization and C−N Bond Formation
2008
Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes
1996 StandoutNobel
Chemical Glycoproteomics
2016 StandoutNobel
Intramolecular 1,8-Hydrogen Abstraction Between Glucopyranose Units in a Disaccharide Model Promoted by Alkoxy Radicals
2002
Copper-Catalyzed Iminoiodane-Mediated Aminolactonization of Olefins: Application to the Synthesis of 5,5-Disubstituted Butyrolactones
2011
Works of David Crich being referenced
1-ベンゼンスルフィニルピペリジン/トリフルオロメタンスルホン酸無水物 チオグリコシドのグリコシルトリフラートへの低温変換及び種々の異なるグリコシド結合生成用の貯蔵安定性のある試薬の強力な組合せ
2001
Triblock Peptide and Peptide Thioester Synthesis With Reactivity‐Differentiated Sulfonamides and Peptidyl Thioacids
2009
Dissecting the mechanisms of a class of chemical glycosylation using primary 13C kinetic isotope effects
2012
NO Bond as a Glycosidic‐Bond Surrogate: Synthetic Studies Toward Polyhydroxylated N‐Alkoxypiperidines
2012
On the nitrile effect in l-rhamnopyranosylation
2006
Synthesis of a β-(1→3)-d -Rhamnotetraose by a One-Pot, Multiple Radical Fragmentation
2006
CD1c Presentation of Synthetic Glycolipid Antigens with Foreign Alkyl Branching Motifs
2007 StandoutNobel
A propos of glycosyl cations and the mechanism of chemical glycosylation; the current state of the art
2014
Epimerization‐Free Block Synthesis of Peptides from Thioacids and Amines with the Sanger and Mukaiyama Reagents
2009
Improved Synthesis of 1‐Benzenesulfinyl Piperidine and Analogs for the Activation of Thioglycosides in Conjunction with Trifluoromethanesulfonic Anhydride*
2005
Mechanism of 4,6‐O‐Benzylidene‐Directed β‐Mannosylation as Determined by α‐Deuterium Kinetic Isotope Effects
2004
Direct Formation of β-Mannopyranosides and Other Hindered Glycosides from Thioglycosides
1998
Nucleotide C3‘,4‘-Radical Cations and the Effect of a 2‘-Oxygen Substituent. The DNA/RNA Paradox
1997
Revisiting the Armed−Disarmed Concept: The Importance of Anomeric Configuration in the Activation of S-Benzoxazolyl Glycosides
2007
On the Role of Neighboring Group Participation and Ortho Esters in β-Xylosylation: 13C NMR Observation of a Bridging 2-Phenyl-1,3-dioxalenium Ion
1999
Synthesis of Tetrahydrofurans by a Tandem Hydrogen Atom Abstraction/Radical Nucleophilic Displacement Sequence
1999
Mechanism of a Chemical Glycosylation Reaction
2010
Generation and trapping of benzyl radicals from benzyl iodides by cobaloximemediated iodine atom abstractions
1993
Direct synthesis of β-mannosides. Synthesis of β-D-xyl-(1→2)-β-D-man-(1→4)-α-D-Glc-OMe: A trisaccharide component of the Hyriopsis schlegelii glycosphingolipid. Formation of an orthoester from a xylopyranosyl sulfoxide
1999
Photoinitiated Glycosylation at 350 nm
2011
Synthesis of carbazomycin B by radical arylation of benzene
2004
The β-nitroxyalkyl and β-sulfonatoxyalkyl radical rearrangements
1993
Direct Synthesis of β-Mannans. A Hexameric [→3)-β-d -Man-(1→4)-β-d -Man-(1]3 Subunit of the Antigenic Polysaccharides from Leptospira biflexa and the Octameric (1→2)-Linked β-d -Mannan of the Candida albicans Phospholipomannan. X-ray Crystal Structure of a Protected Tetramer
2001
Facile Amide Bond Formation from Carboxylic Acids and Isocyanates
2011
Catalytic Allylic Oxidation with a Recyclable, Fluorous Seleninic Acid
2004
Inter- and Intramolecular Pathways for the Formation of Tetrahydrofurans from β-(Phosphatoxy)alkyl Radicals. Evidence for a Dissociative Mechanism
1999
Efficient Glycosidation of a Phenyl Thiosialoside Donor with Diphenyl Sulfoxide and Triflic Anhydride in Dichloromethane
2006
A short synthesis of the trisaccharide building block of the N-linked glycans
2003
The 3,4-O-Carbonate Protecting Group as a β-Directing Group in Rhamnopyranosylation in Both Homogeneous and Heterogeneous Glycosylations As Compared to the Chameleon-like 2,3-O-Carbonates
2003
Synthesis of the Salmonella Type E1 Core Trisaccharide as a Probe for the Generality of 1-(Benzenesulfinyl)piperidine/Triflic Anhydride Combination for Glycosidic Bond Formation from Thioglycosides
2002
Stereoselective sulfoxidation of α-mannopyranosyl thioglycosides: the exo-anomeric effect in action
1998
S-(4-Methoxyphenyl) Benzenethiosulfinate (MPBT)/Trifluoromethanesulfonic Anhydride: A Convenient System for the Generation of Glycosyl Triflates from Thioglycosides
2000
The chemistry of acyl tellurides: generation and trapping of acyl radicals, including aryltellurium group transfer
1992
ChemInform Abstract: 1‐Benzenesulfinyl Piperidine/Trifluoromethanesulfonic Anhydride: A Potent Combination of Shelf‐Stable Reagents for the Low‐Temperature Conversion of Thioglycosides to Glycosyl Triflates and for the Formation of Diverse Glycosidic Linkages.
2002
Alternative Synthesis of P-Chiral Phosphonite-Borane Complexes: Application to the Synthesis of Phostone–Phostone Dimers
2013
Heterobivalent Library Expansion by “Living Radical” Processes: Thiocarbonyl Addition/Elimination, and Nitroxide-Based Reactions with Fluorous Deconvolution
2007
Are Glycosyl Triflates Intermediates in the Sulfoxide Glycosylation Method? A Chemical and 1H, 13C, and 19F NMR Spectroscopic Investigation
1997
Reaction of Thioacids with Isocyanates and Isothiocyanates: A Convenient Amide Ligation Process
2009
Cyclic Tautomers of Tryptophan: Enantio- and Diastereoselective Synthesis of .beta.-Substituted and .alpha.,.beta.-Disubstituted Derivatives of Tryptophan
1994
The free radical chemistry of carboxylic esters of 2-selenopyridine--oxide: a convenient synthesis of (L)-vinylglycine
1985
4,6-O-[1-Cyano-2-(2-iodophenyl)ethylidene] Acetals. Improved Second-Generation Acetals for the Stereoselective Formation of β-d -Mannopyranosides and Regioselective Reductive Radical Fragmentation to β-d -Rhamnopyranosides. Scope and Limitations
2006
Amino Acid and Peptide Synthesis and Functionalization by the Reaction of Thioacids with 2,4-Dinitrobenzenesulfonamides
2007
4,6-O-Benzylidene-Directed β-Mannopyranosylation and α-Glucopyranosylation: The 2-Deoxy-2-fluoro and 3-Deoxy-3-fluoro Series of Donors and the Importance of the O2−C2−C3−O3 Interaction
2007
Convergent, stereoselective synthesis of the caloporoside disaccharide
1998
Direct Synthesis of β-Mannopyranosides by the Sulfoxide Method
1997
Stereocontrolled Formation of Quaternary Carbon Centers by Conjugate Addition of Lithium Enolates of Dioxanones to .beta.-Bromoacrylates and .beta.-Bromovinyl Sulfones: Dependence of Stereoselectivity on Alkene Geometry
1994
Asymmetric Synthesis of Polyhydroxylated N-Alkoxypiperidines by Ring-Closing Double Reductive Amination: Facile Preparation of Isofagomine and Analogues
2011
Benzylidene Acetal Fragmentation Route to 6-Deoxy Sugars: Direct Reductive Cleavage in the Presence of Ether Protecting Groups, Permitting the Efficient, Highly Stereocontrolled Synthesis of β-d -Rhamnosides from d -Mannosyl Glycosyl Donors. Total Synthesis of α-d -Gal-(1→3)-α-d -Rha-(1→3)- β-d -Rha-(1→4)-β-d -Glu-OMe, the Repeating Unit of the Antigenic Lipopolysaccharide from Escherichia hermannii ATCC 33650 and 33652
2004
2,4,6-Tri-tert-butylpyrimidine (TTBP): A Cost Effective, Readily Available Alternative to the Hindered Base 2,6-Di-tert-butylpyridine and its 4-Substituted Derivatives in Glycosylation and Other Reactions
2001
Direct Synthesis of the β-l -Rhamnopyranosides
2003
Disarming, non-participating 2-O-protecting groups in manno- and rhamnopyranosylation: scope and limitations of sulfonates, vinylogous esters, phosphates, cyanates, and nitrates
2005
Synthesis of the Antigenic Tetrasaccharide Side Chain from the Major Glycoprotein of Bacillus anthracis Exosporium
2007
Cation Clock Permits Distinction Between the Mechanisms of α- and β-O- and β-C-Glycosylation in the Mannopyranose Series: Evidence for the Existence of a Mannopyranosyl Oxocarbenium Ion
2012
Mechanism of 4,6‐O‐Benzylidene‐Directed β‐Mannosylation as Determined by α‐Deuterium Kinetic Isotope Effects
2004
ChemInform Abstract: Synthesis of β‐Hydroxy O‐Alkyl Hydroxylamines from Epoxides Using a Convenient and Versatile Two‐Step Procedure.
2013
Direct chemical synthesis of β-mannopyranosides and other glycosides via glycosyl triflates
1998
Enhanced Diastereoselectivity in β-Mannopyranosylation through the Use of Sterically Minimal Propargyl Ether Protecting Groups
2006
Enantiospecific synthesis of amino acids: preparation of (R)- and (S)-α-methylaspartic acid from (S)-tryptophan
1992
The 4,6-O-[α-(2-(2- Iodophenyl)ethylthiocarbonyl)benzylidene] Protecting Group: Stereoselective Glycosylation, Reductive Radical Fragmentation, and Synthesis of β-d -Rhamnopyranosides and Other Deoxy Sugars
2003
1-Naphthylpropargyl Ether Group: A Readily Cleaved and Sterically Minimal Protecting System for Stereoselective Glycosylation
2006
Chemistry of 1-Alkoxy-1-glycosyl Radicals: The Manno- and Rhamnopyranosyl Series. Inversion of α- to β-Pyranosides and the Fragmentation of Anomeric Radicals
1996
Direct Chemical Synthesis of the β-Mannans: Linear and Block Syntheses of the Alternating β-(1→3)-β-(1→4)-Mannan Common to Rhodotorula glutinis, Rhodotorula mucilaginosa, and Leptospira biflexa
2004
Preparation, isolation and X-ray crystallographic structure determination of a stable, crystalline carbonic anhydride of an N-protected α-amino acid
1992
Catalysis of Stannane-Mediated Radical Chain Reactions by Benzeneselenol
2007
On the Use of 3,5-O-Benzylidene and 3,5-O-(Di-tert-butylsilylene)-2-O-benzylarabinothiofuranosides and Their Sulfoxides as Glycosyl Donors for the Synthesis of β-Arabinofuranosides: Importance of the Activation Method
2007
On the Reaction of Tryptophan Derivatives with N-Phenylselenyl Phthalimide: The Nature of the Kinetic and Thermodynamic Hexahydropyrrolo[2,3-b]indole Products. Alkylation of Tryptophan with Inversion of Configuration
1999
Direct Stereocontrolled Synthesis of 3-Amino-3-deoxy-β-Mannopyranosides: Importance of the Nitrogen Protecting Group on Stereoselectivity
2007
Free-Radical Ring Contraction of Six-, Seven-, and Eight-Membered Lactones by a 1,2-Shift Mechanism. A Kinetic and 17O NMR Spectroscopic Study
1999
One Pot Selective 5′-Oxidation/Olefination of 2′-Deoxynucleosides
1999
Native Chemical Ligation at Phenylalanine
2007
Synthesis, Characterization, and Coupling Reactions of Six-Membered Cyclic P-Chiral Ammonium Phosphonite–Boranes; Reactive H-Phosphinate Equivalents for the Stereoselective Synthesis of Glycomimetics
2012
Characterization and Noncovalent Inhibition of the Deubiquitinase and deISGylase Activity of SARS-CoV-2 Papain-Like Protease
2020
Chemistry of the Hexahydropyrrolo[2,3-b]indoles: Configuration, Conformation, Reactivity, and Applications in Synthesis
2007
The fluorous Swern and Corey–Kim reactions: scope and mechanism
2002
Chemistry of Cyclic Tautomers of Tryptophan: Formation of a Quaternary Center at C3a and Total Synthesis of the Marine Alkaloid (+)-ent-Debromoflustramine B
1994
New and improved methods for the radical decarboxylation of acids
1983
Enantioselective alkene radical cations reactions
2006
A new method for the radical deoxygenation of tertiary alcohols
1984
Synthesis of 2-deoxy-β-C-pyranosides by diastereoselective hydrogen atom transfer
1990
Formation of β-Mannopyranosides of Primary Alcohols Using the Sulfoxide Method
1996
Influence of the O3 Protecting Group on Stereoselectivity in the Preparation ofC-Mannopyranosides with 4,6-O-Benzylidene Protected Donors
2010
.beta.-(Phosphatoxy)alkyl and .beta.-(Acyloxy)alkyl Radical Rearrangements: Evidence for Nondissociative Mechanisms
1994
Design, synthesis, application and recovery of a minimally fluorous diaryl diselenide for the catalysis of stannane-mediated radical chain reactions
1999
Chemistry of 4,6-O-Benzylidene-d -glycopyranosyl Triflates: Contrasting Behavior between the Gluco and Manno Series
1999
Tandem Polar/Radical Crossover Sequences for the Formation of Fused and Bridged Bicyclic Nitrogen Heterocycles Involving Radical Ionic Chain Reactions, and Alkene Radical Cation Intermediates, Performed under Reducing Conditions: Scope and Limitations
2003
Some observations on the mechanism of the Mitsunobu reaction
1989
Electrochemical Generation of Glycosyl Triflate Pools
2007
Chemistry of Acyl Radicals
1999
Synthesis of the mannosyl erythritol lipid MEL A; confirmation of the configuration of the meso-erythritol moiety
2002
Allylic Disulfide Rearrangement and Desulfurization: Mild, Electrophile-Free Thioether Formation from Thiols
2006
Intramolecular hydrogen atom abstraction in carbohydrates and nucleosides: Inversion of an α- to β-mannopyranoside and generation of thymidine C-4′ radicals
1994
Photoinduced Free Radical Chemistry of the Acyl Tellurides: Generation, Inter- and Intramolecular Trapping, and ESR Spectroscopic Identification of Acyl Radicals
1994
Stereocontrolled Synthesis of the d - and l -glycero-β-d -manno-Heptopyranosides and Their 6-Deoxy Analogues. Synthesis of Methyl α-l -Rhamno-pyranosyl-(1→3)-d -glycero-β-d -manno-heptopyranosyl- (1→3)-6-deoxy-glycero-β-d -manno-heptopyranosyl-(1→4)-α-l - rhamno-pyranoside, a Tetrasaccharide Subunit of the Lipopolysaccharide from Plesimonas shigelloides
2006
6-O-Benzyl- and 6-O-Silyl-N-acetyl-2-amino-2-N,3-O-carbonyl-2-deoxyglucosides: Effective Glycosyl Acceptors in the Glucosamine 4-OH Series. Effect of Anomeric Stereochemistry on the Removal of the Oxazolidinone Group
2005
Direct synthesis of β-d-Xyl-(1→2)-β-d-Man-(1→4)-α-d-Glc-OME: a trisaccharide component of the Hyriopsis schlegelii glycosphingolipid
1998
Oxazolidinone Protection of N-Acetylglucosamine Confers High Reactivity on the 4-Hydroxy Group in Glycosylation
2003
Chemistry of β-(Acyloxy)alkyl and β-(Phosphatoxy)alkyl Radicals and Related Species: Radical and Radical Ionic Migrations and Fragmentations of Carbon−Oxygen Bonds
1997
Diastereoselective Cyclizations of 1,3-Dioxan-2-yl Radicals: Chiral Acyl Radical Equivalents
1996
Stereoselectivity in free radical reactions
1987
The invention of new radical chain reactions. Part 12. Improved methods for the addition of carbon radicals to substituted allylic groups
1986
Fluorous Swern Reaction
2001
Conformational analysis of substituted hexahydropyrrolo [2,3-b]indoles and related systems. An unusual example of hindered rotation about sulfonamide SN bonds. An X-ray crystallographic and NMR study
1995
Radical chemistry associated with the thiocarbonyl group
1989
Allylic Selenosulfide Rearrangement: A Method for Chemical Ligation to Cysteine and Other Thiols
2006
CHEMISTRY OF GLYCOSYL TRIFLATES: SYNTHESIS OFβ-MANNOPYRANOSIDES
2002
Stereocontrolled Formation of β-Glucosides and Related Linkages in the Absence of Neighboring Group Participation: Influence of a trans-Fused 2,3-O-Carbonate Group
2005
A New Method for the Synthesis oftert-Alkyl Chlorides fromtert-Alcohols
1987
Dynamics of Alkene Radical Cation/Phosphate Anion Pair Formation from Nucleotide C4‘ Radicals. The DNA/RNA Paradox Revisited
2001
1-Benzenesulfinyl Piperidine/Trifluoromethanesulfonic Anhydride: A Potent Combination of Shelf-Stable Reagents for the Low-Temperature Conversion of Thioglycosides to Glycosyl Triflates and for the Formation of Diverse Glycosidic Linkages
2001
On the Influence of the C2−O2 and C3−O3 Bonds in 4,6-O-Benzylidene-Directed β-Mannopyranosylation and α-Glucopyranosylation
2006
Diastereoselectivity in the Cyclization of Alkene Radical Cations Generated under Non-Oxidizing Conditions: Contact Ion Pairs and Memory Effects
2002
Stereochemical Memory Effects in Alkene Radical Cation/Anion Contact Ion Pairs: Effect of Substituents, and Models for Diastereoselectivity
2005
α-Selective Sialylations at −78 °C in Nitrile Solvents with a 1-Adamantanyl Thiosialoside
2007
Solid-Phase Synthesis of β-Mannosides
2002
The Intramolecular Asymmetric Pauson−Khand Cyclization as a Novel and General Stereoselective Route to Benzindene Prostacyclins: Synthesis of UT-15 (Treprostinil)
2004
An asymmetric synthesis of a 1α,25-dihydroxyvitamin D3 A-ring synthon
1992
Enantiospecific synthesis with amino acids. Part 1. Tryptophan as a chiron for the synthesis of α-substituted tryptophan derivatives
1991
Enantioselective Cyclization of Alkene Radical Cations
2003
Methodology Development and Physical Organic Chemistry: A Powerful Combination for the Advancement of Glycochemistry
2011
The .beta.-(phosphonooxy)alkyl radical rearrangement
1993
Synthesis and Stereoselective Glycosylation of d - and l -glycero-β-d -manno-Heptopyranoses
2005
Synthesis of the 3a-(3-Indolyl)-1,2,3,3a,8,8a-hexahydropyrrolo-[2,3-b]indole Core of Leptosins D-F
1998
Catalytic Oxidation Adjacent to Carbonyl Groups and at Benzylic Positions with a Fluorous Seleninic Acid in the Presence of Iodoxybenzene
2005
Highly diastereoselective radical cyclization of a glucose-derived enol ether radical cation/phosphate anion pair
2003
Reaction of tryptophan derivatives with phenylsulphenyl chloride and phenylselenenyl bromide
1989
The cyclization route to the calcitriol A-ring: a formal synthesis of (+)-1α,25-dihydroxyvitamin D3
1993