Citation Impact
Citing Papers
Anti-Markovnikov alkene oxidation by metal-oxo–mediated enzyme catalysis
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Diversity oriented clicking delivers β-substituted alkenyl sulfonyl fluorides as covalent human neutrophil elastase inhibitors
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Organic Synthesis—Where now?
1990
Playing with organic radicals as building blocks for functional molecular materials
2011
Short-Term Effects of Nose-Only Cigarette Smoke Exposure on Glutathione Redox Homeostasis, Cytochrome P450 1A1/2 and Respiratory Enzyme Activities in Mice Tissues
2013 Standout
[Cu(dap)2Cl] As an Efficient Visible‐Light‐Driven Photoredox Catalyst in Carbon–Carbon Bond‐Forming Reactions
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1999 StandoutNatureNobel
Visible light photoredox catalysis: applications in organic synthesis
2010 Standout
Modular click chemistry libraries for functional screens using a diazotizing reagent
2019 StandoutNatureNobel
Dynamic Covalent Chemistry
2002 StandoutNobel
Reactions of oxyl radicals with DNA
1995
Wet chemical routes to the assembly of organic monolayers on silicon surfaces via the formation of Si–C bonds: surface preparation, passivation and functionalization
2010
Electrografting: a powerful method for surface modification
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Enantioselective α‐Alkylation of Aldehydes by Photoredox Organocatalysis: Rapid Access to Pharmacophore Fragments from β‐Cyanoaldehydes
2015
Eosin Y-catalyzed visible-light-mediated aerobic oxidative cyclization of N,N-dimethylanilines with maleimides
2015
Click Chemistry: Diverse Chemical Function from a Few Good Reactions
2001 StandoutNobel
Dual electrocatalysis enables enantioselective hydrocyanation of conjugated alkenes
2020
On the mechanism of amine oxidations by P450
1995
Sulfonyl fluorides as targets and substrates in the development of new synthetic methods
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Cytochrome P450-Catalyzed Hydroxylation of Hydrocarbons: Kinetic Deuterium Isotope Effects for the Hydroxylation of an Ultrafast Radical Clock
1994
Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution
2011
Fluorescence probes in biochemistry: An examination of the non-fluorescent behavior of dansylamide by photoacoustic calorimetry
1992 StandoutNobel
Multicomponent domino reactions for the synthesis of biologically active natural products and drugs
2000 Standout
Copper‐Catalyzed Radical/Radical CH/PH Cross‐Coupling: α‐Phosphorylation of Aryl Ketone O‐Acetyloximes
2015
Spectroscopic Evidence for Reaction of Prostaglandin H Synthase-1 Tyrosyl Radical with Arachidonic Acid
1995
An overview of N-heterocyclic carbenes
2014 StandoutNature
Mechanistic analysis of oxidative C–H cleavages using inter- and intramolecular kinetic isotope effects
2009
Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds
2012
Cytochrome P450 hydroxylation of hydrocarbons: Variation in the rate of oxygen rebound using cyclopropyl radical clocks including two new ultrafast probes
1993
Photoactive Chiral Metal–Organic Frameworks for Light-Driven Asymmetric α-Alkylation of Aldehydes
2012
An Extremely Long‐Lived Triplet Carbene; Reactivity, Optical Absorption Spectrum, and Kinetics of Highly Congested Diarylcarbenes
1994
Outer Shape of Molecules as Probed by Ground-State Atoms from H to Ar
1997
Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling
2016
The captodative effect
1985 Standout
Catalytic Olefin Hydroamination with Aminium Radical Cations: A Photoredox Method for Direct C–N Bond Formation
2014
Dynamical Contributions to Enzyme Catalysis: Critical Tests of A Popular Hypothesis
2006 StandoutNobel
Enzymatic H-Transfer Requires Vibration-Driven Extreme Tunneling
1999
Solvent-Free Organic Synthesis
2000 StandoutNobel
Mechanistic and synthetic aspects of amine-enone single electron transfer photochemistry
1992
Organic Photoredox Catalysis
2016 Standout
Photodissociation of 1,2-chloroiodoethane at 248 and 266 nm: The enthalpy of formation of CH2ClCH2I
1984 StandoutNobel
Preparative trapping of tert-butoxy radicals by captodative olefins
1984
Solute Solvent Dynamics and Energetics in Enzyme Catalysis: The SN2 Reaction of Dehalogenase as a General Benchmark
2004 StandoutNobel
Electronic and Molecular Structure of Room-Temperature Stable Triplet Carbene as Studied by ESR Spectroscopy
1996
Complete Resonance Assignment of a Natural Abundance Solid Peptide by Through-Bond Heteronuclear Correlation Solid-State NMR
2000
Substituenteneffekte auf die CC‐Bindungsstärke, 5. Kinetik und Thermochemie der homolytischen Dissoziation von meso‐ und D ,L ‐2,3‐Dimethoxy‐2,3‐diphenylbernsteinsäuredinitril
1983
Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts
2001 StandoutNobel
Branch-Selective Hydroarylation: Iodoarene–Olefin Cross-Coupling
2016
A new paradigm for electrostatic catalysis of radical reactions in vitamin B 12 enzymes
2007 StandoutNobel
The beginnings of modern carbene chemistry triplets and singlets
1985
Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis
2009
Visible-Light-Mediated Synthesis of Amidyl Radicals: Transition-Metal-Free Hydroamination and N-Arylation Reactions
2016
Functionally Diverse Nucleophilic Trapping of Iminium Intermediates Generated Utilizing Visible Light
2011
Catalytic iron-carbene intermediate revealed in a cytochrome c carbene transferase
2018 StandoutNobel
Stepwise and Concerted Pathways in Photoinduced and Thermal Electron-Transfer/Bond-Breaking Reactions. Experimental Illustration of Similarities and Contrasts
2001
Stable Carbenes
1999 Standout
PhSeSiR3-Catalyzed Group Transfer Radical Reactions
2000
Free Radical Functionalization of Organic Compounds Catalyzed by N-Hydroxyphthalimide
2007
Competition Methods and Scales for Alkyl Radical Reaction Kinetics
1993
Catalytic Enantioselective Conversion of Epoxides to Thiiranes
2016 StandoutNobel
N‐Heterocyclic Carbenes
1997 Standout
The Standard Redox Potential of the Phenyl Radical/Anion Couple
2003
Synthesis and Characterization of (Me3ECH2)2Ta(CHEMe3)Si(SiMe3)3 (E = C, Si). Kinetic and Mechanistic Studies of the Formation of a Silyl Alkylidene Complex through Preferential Silane Elimination
1996
An ab initio molecular orbital study of the potential energy surface of the N2H → N2 + H system
1984 StandoutNobel
Mechanisms of Coenzyme B 12 -Dependent Rearrangements
1985 Science
Functionalization of Coordination Nanochannels for Controlling Tacticity in Radical Vinyl Polymerization
2010 StandoutNobel
Organometallic Chemistry on Silicon and Germanium Surfaces
2002
Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds
2021 StandoutNobel
Reactions and Kinetics of (2,4,6-Tri-tert-butylphenyl)phenylcarbene
1994
From equilibrium acidites to radical stabilization energies
1993
The synthesis and structure of a stabilized nitrilium ylide
1984
Stability of chemical species
1983
Regio- and stereo-selectivity of alkenyl radical ring closure: A theoretical study
1985
Enantioselective Organocatalytic Alkylation of Aldehydes and Enals Driven by the Direct Photoexcitation of Enamines
2015
Active participation of amine-derived radicals in photoredox catalysis as exemplified by a reductive cyclization
2013
Control of Carbene Reactivity by Crystals. A Highly Selective 1,2-H Shift in the Solid-to-Solid Reaction of 1-(4‘-Biphenylyl)-2-phenyldiazopropane to (Z)-1-(4‘-Biphenylyl)-2-phenylpropene
1997
Biologically active Phytophthora mating hormone prepared by catalytic asymmetric total synthesis
2008 StandoutNobel
Proton-transfer reactions of photogenerated radical ion pairs
1986
Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis
2010
Anti-Markovnikov Oxidation of β-Alkyl Styrenes with H2O as the Terminal Oxidant
2016
Metal-Mediated Reductive Hydrodehalogenation of Organic Halides
2002
How Important Are Quantum Mechanical Nuclear Motions in Enzyme Catalysis?
1996 StandoutNobel
Time-Resolved Photoacoustic Calorimetry: Probing the Energetics and Dynamics of Fast Chemical and Biochemical Reactions
1988 Science
Photoinduced Hydrogen Abstraction from Phenols by Aromatic Ketones. A New Mechanism for Hydrogen Abstraction by Carbonyl n,π* and π,π* Triplets
1996
A Rhodium Catalyst Superior to Iridium Congeners for Enantioselective Radical Amination Activated by Visible Light
2016
Stereoregulation in Living Radical Polymerization
2007
Energetics of Metal−Ligand Multiple Bonds. Thermochemistry of Tantalum(V) Alkylidene Formation
1997
C−H Bond Activation by a Ferric Methoxide Complex: A Model for the Rate-Determining Step in the Mechanism of Lipoxygenase
1997
Click Chemistry: Diverse Chemical Function from a Few Good Reactions
2001 StandoutNobel
Visible Light Photoinitiated Metal-Free Living Cationic Polymerization of 4-Methoxystyrene
2015
Copper‐Catalyzed Radical/Radical CH/PH Cross‐Coupling: α‐Phosphorylation of Aryl Ketone O‐Acetyloximes
2015
A new method in radical chemistry: Generation of radicals by photo-induced electron transfer and fragmentation of the radical cation
1994
On the Mechanism of the Copper-Catalyzed Enantioselective 1,4-Addition of Grignard Reagents to α,β-Unsaturated Carbonyl Compounds
2006 StandoutNobel
A dynamical theory of nonadiabatic proton and hydrogen atom transfer reaction rates in solution
1989
Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents
2008 StandoutNobel
C70: intersystem crossing and singlet oxygen production
1992
Probing the C–O Bond-Formation Step in Metalloporphyrin-Catalyzed C–H Oxygenation Reactions
2017
Bis(trimethylsilyl)selenide in the Selective Synthesis of β‐Hydroxy, β‐Mercapto, and β‐Amino Diorganyl Diselenides and Selenides Through Ring Opening of Strained Heterocycles
2014
A Stable Four-Membered N-Heterocyclic Carbene
2004 StandoutNobel
Room-temperature stable ground-state triplet carbene with perpendicular conformation as models for organic high-spin units with robust π-spin polarization
1997
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
Understanding Reactivity Patterns of Radical Cations
1997
Polymethylated and Poly(tert)butylated Diphenylcarbenes. Generation, Reactions, Kinetics, and Deuterium Isotope Effects of Sterically Congested Triplet Carbenes
1997
Electrostatic Basis for Enzyme Catalysis
2006 StandoutNobel
Pentalenolactone Biosynthesis. Molecular Cloning and Assignment of Biochemical Function to PtlI, a Cytochrome P450 of Streptomyces avermitilis
2006 StandoutNobel
Chemomimetic Biocatalysis: Exploiting the Synthetic Potential of Cofactor-Dependent Enzymes To Create New Catalysts
2015 StandoutNobel
Derivatization of Carbon Surfaces by Anodic Oxidation of Arylacetates. Electrochemical Manipulation of the Grafted Films
1997
Contrastive Photoreduction Pathways of Benzophenones Governed by Regiospecific Deprotonation of Imidazoline Radical Cations and Additive Effects
2005
Mechanical Bonds and Topological Effects in Radical Dimer Stabilization
2014 StandoutNobel
Substituent Effects on the Oxidation and Reduction Potentials of Phenylthiyl Radicals in Acetonitrile
2001
Photosensitized (Electron-Transfer) Deconjugation of 1-Arylcyclohexenes
2000
Nanochannels of Two Distinct Cross-Sections in a Porous Al-Based Coordination Polymer
2008 StandoutNobel
Enantioselective Direct α-Amination of Aldehydes via a Photoredox Mechanism: A Strategy for Asymmetric Amine Fragment Coupling
2013
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
2013 Standout
Oxidative Synthesis of Cyclic Acyl Aminals through Carbon−Carbon σ-Bond Activation
2002
Thermally Persistent Fluorosulfonyl Nitrene and Unexpected Formation of the Fluorosulfonyl Radical
2013
Hydrogen‐Atom Transfer Reactions of Transition‐Metal Hydrides
1991
Simulation of enzyme reactions using valence bond force fields and other hybrid quantum/classical approaches
1993 StandoutNobel
Cascade Cyclizations of Terpenoid Polyalkenes Triggered by Photoelectron Transfer – Biomimetics with Photons
1995
Recent Applications of the (TMS)3SiH Radical-Based Reagent
2012
Regio- and Enantioselective Alkane Hydroxylation with Engineered Cytochromes P450 BM-3
2003 StandoutNobel
Visible‐Light Photocatalysis: Does It Make a Difference in Organic Synthesis?
2018 Standout
Heme-Containing Oxygenases
1996 Standout
Quantum Mechanical Continuum Solvation Models
2005 Standout
Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis
2015
Electron-Transfer-Photosensitized Conjugate Alkylation
1998
Trapping Silicon Surface-Based Radicals
2006
Synthetic Utilization of α-Aminoalkyl Radicals and Related Species in Visible Light Photoredox Catalysis
2016
Enantioselective α‐Alkylation of Aldehydes by Photoredox Organocatalysis: Rapid Access to Pharmacophore Fragments from β‐Cyanoaldehydes
2015
Homolytic and heterolytic radical cleavage in the Kolbe reaction
2001
Synthesis of a 2H‐Azirine by [1 + 2] Cycloaddition of a Phosphinocarbene with a Nitrile and Its Ring‐Expansion to a 1,2λ5‐Azaphosphete
1995
Alternate Heme Ligation Steers Activity and Selectivity in Engineered Cytochrome P450-Catalyzed Carbene-Transfer Reactions
2018 StandoutNobel
Ruthenium Alkylidene Initiated Living Ring-Opening Metathesis Polymerization (ROMP) of 3-Substituted Cyclobutenes
1997 StandoutNobel
Raman Evidence for a Weakened O−O Bond in Mononuclear Low-Spin Iron(III)−Hydroperoxides
1998 StandoutNobel
Organosilanes as radical-based reducing agents in synthesis
1992
Absorption of CO2 and CS2 into the Hofmann-Type Porous Coordination Polymer: Electrostatic versus Dispersion Interactions
2013 StandoutNobel
Mechanism of the Stereoselective α-Alkylation of Aldehydes Driven by the Photochemical Activity of Enamines
2016
Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents
2012 StandoutNobel
Electron-Transfer Photoredox Catalysis: Development of a Tin-Free Reductive Dehalogenation Reaction
2009
Organische Synthese — wohin?
1990
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications
2010
Visible-Light-Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts
2012
Electron-Transfer Oxidation Properties of Unsaturated Fatty Acids and Mechanistic Insight into Lipoxygenases
2006
Nature and Kinetic Analysis of Carbon−Carbon Bond Fragmentation Reactions of Cation Radicals Derived from SET-Oxidation of Lignin Model Compounds
2010
Redox Control of the Binding Modes of an Organic Receptor
2015 StandoutNobel
Proton-Coupled Electron Transfer in Soybean Lipoxygenase
2004
Quantum-Chemical Predictions of Absolute Standard Redox Potentials of Diverse Organic Molecules and Free Radicals in Acetonitrile
2005
Works of D. Griller being referenced
Studies of the formation and stability of pentadienyl and 3-substituted pentadienyl radicals
1991
Absolute rate constants for the reactions of tert-butoxyl, tert-butylperoxyl, and benzophenone triplet with amines: the importance of a stereoelectronic effect
1981
Structures of dimesitylcarbene and related compounds
1984
Heats of formation of tert-butyl and ethyl radicals
1981
Kinetic applications of electron paramagnetic resonance spectroscopy. XX. 2,4,6-Tri(tert-butyl)benzyl, -anilino, -phenoxy, and -phenylthiyl radicals
1975
Using electron-transfer reactions to propagate radical chain processes
1989
Structure of dimesitylcarbene
1983
A study of transient phenomena in the reactions of alkoxy radicals with triphenylphosphine and triphenylborane
1979
Tris(trimethylsilyl)silane: A catalyst for radical mediated reduction reactions
1989
Thermochemistry of .alpha.-aminoalkyl radicals
1981
Kinetic applications of electron paramagnetic resonance spectroscopy. 26. Quantum-mechanical tunneling in the isomerization of sterically hindered aryl radicals
1976
Heats of formation of some simple alkyl radicals
1982
Bond dissociation energies for common organic compounds
1988
Rate constants for the reactions of tris(trimethylsilyl)silyl radicals with organic halides
1989
Dimesitylcarbene: the distinct chemistries of its singlet and triplet states
1983
An electron spin resonance study of pentadienyl and related radicals: homolytic fission of cyclobut-2-enylmethyl radicals
1981
A critical examination of transient assignments in the laser flash photolysis of 9-diazofluorene
1982
Structures of diarylcarbenes and their effect on the energy separation between singlet and triplet states
1985
Amino- and alkoxysulfonyl radicals
1989
Sulfur–chlorine bond dissociation enthalpies in methane- and benzene-sulfonyl chlorides
1994
Heats of formation and ionization potentials of some .alpha.-aminoalkyl radicals
1983
Experimental and theoretical approaches to the optical absorption spectra of sulfonyl radicals
1987
Reduction of silicon-hydrogen bond strengths
1987
Kinetic applications of electron paramagnetic resonance spectroscopy. 32. Further studies of quantum-mechanical tunneling in the isomerization of sterically hindered aryl radicals
1978
Design of modified pyrroline N-oxide derivatives as spin traps specific for hydroxyl radical
1992
Flash photolysis studies of carbenes and their impact on the skell-woodworth rules
1985
Electron paramagnetic resonance and the art of physical-organic chemistry
1980
Singlet and triplet dimesitylcarbene
1984
Allylcarbinyl-cyclopropylcarbinyl rearrangement
1980
The mechanism of the radical chain transformation of nitroalkanes to alkanes using triaryl- or trialkyltin hydrides
1990
Persistent carbon-centered radicals
1976
Heats of formation of radicals and molecules by a photoacoustic technique
1986
The germanium-hydrogen bond dissociation energies of organogermanes. A laser-induced photoacoustic study
1991
A study on the reducing abilities of tris(alkylthio)silanes
1992
The structure of amidyl radicals. Evidence for the .pi.-electronic ground state and for twist about the acyl-nitrogen bond by electron paramagnetic resonance spectroscopy
1981
Tris(trimethylsilyl)silane (TTMSS): formation of carbon-centered radicals from 1,3-dithiolanes and 1,3-dithianes
1990
Oxidation and reduction potentials of transient free radicals
1988
Fluorenylidene: kinetics and mechanisms
1984
Triphenylsilane: a useful radical-based reducing agent
1990
Solvent effects on the thermochemistry of free-radical reactions
1989
A kinetic study of the reactions of tert-butoxyl with alkenes: hydrogen abstraction vs. addition
1982
Oxidation potentials of α-aminoalkyl radicals: bond dissociation energies for related radical cations
1986
Oxidation and reduction potentials of transient free radicals
1985
The free radical reaction between alkanes and carbon tetrachloride
1985
Tris(trimethylsilyl)silane. A new reducing agent
1988
The structure of amidyl radicals. An investigation by variable-temperature electron paramagnetic resonance spectroscopy
1980
Unifying the solution thermochemistry of molecules, radicals, and ions
1989
Thermodynamic significance of .rho.+ and .rho.- from substituent effects on the redox potentials of arylmethyl radicals
1990
Reduction potentials for substituted benzyl radicals: pKa values for the corresponding toluenes
1989
Free-radical clocks
1980
Tris(trimethylsilyl)silane as a radical-based reducing agent in synthesis
1991
Digital simulation of photomodulation voltammograms: reactivity of the diphenylmethyl carbanion and carbocation in acetonitrile
1991
Ring-inversion barriers for the 3- and 4-cyclohexenyl radicals in solution
1987