Carsten Menke

Self-Driving Laboratories for Chemistry and Materials Science

Ultrafiltration separation of Am(VI)-polyoxometalate from lanthanides

[Mo₁₅₄(NO)₁₄O₄₂₀(OH)₂₈(H₂O)₇₀]^{(25 ± 5)−}: A Water‐Soluble Big Wheel with More than 700 Atoms and a Relative Molecular Mass of About 24000

New Perspectives in Polyoxometalate Chemistry by isolation of compounds containing very large moieties as transferable building blocks: (NMe₄)₅[As₂Mo₈V₄AsO₄₀] · 3H₂O, (NH₄)₂₁[H₃Mo₅₇V₆(NO)₆O₁₈₃(H₂O)₁₈] · 65 H₂O, (NH₂Me₂)₁₈(NH₄)₆[Mo₅₇V₆(NO)₆O₁₈₃(H₂O)₁₈] · 14 H₂O, and (NH₄)₁₂[Mo₃₆(NO)₄O₁₀₈(H₂O)₁₆] · 33 H₂O