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Chemistry and insulin-like properties of vanadium(IV) and vanadium(V) compounds1This manuscript summarizes the presentation given at the symposium ‘Biological Aspects of Vanadium Chemistry — Chemistry, Biochemistry and Therapeutic Applications of Vanadium Compounds’ and recently communicated in original research articles. The original research articles describing the experimental details of this work are given in Refs: [1–5].1
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Efficient manganese catalysts for low-temperature bleaching
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1999 StandoutNobel
N,N‘-Ethylenedi-l -cysteine (EC) and Its Metal Complexes: Synthesis, Characterization, Crystal Structures, and Equilibrium Constants
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Synthesis, Characterization, and Crystal Structure of a (μ-Oxo)bis(μ-acetato)diiron(III) Complex with a Dinucleating Hexapyridine Ligand, 1,2-Bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane. The First Example of a Discrete (μ-Oxo)bis(μ-acetato)diiron(III) Complex with a Dinucleating Ligand
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2005
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Manganese Clusters with Relevance to Photosystem II
2004
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1996
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1996
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1997 StandoutNobel
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1997
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Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates
2004 Standout
Where Plants Make Oxygen: a Structural Model for the Photosynthetic Oxygen-Evolving Manganese Cluster
1993 Science
Enzymatic construction of highly strained carbocycles
2018 StandoutScienceNobel
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1993
H3O2 Bridging Ligand in a Metal–Organic Framework. Insight into the Aqua-Hydroxo↔Hydroxyl Equilibrium: A Combined Experimental and Theoretical Study
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1998
Manganese Cluster in Photosynthesis: Where Plants Oxidize Water to Dioxygen
1996
A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density
2001 StandoutNobel
Vanadium metabolism in tunicates: The coordination chemistry of V(III), V(IV), and V(V) with models for the tunichromes
1991
[Fe3(HCOO)6]: A Permanent Porous Diamond Framework Displaying H2/N2 Adsorption, Guest Inclusion, and Guest‐Dependent Magnetism
2007
Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal–Organic Framework
2019 StandoutNobel
Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology
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The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds
2004 Standout
Polynuclear Complexes of the Pendent-Arm Ligand 1,4,7-Tris(acetophenoneoxime)-1,4,7-triazacyclononane
2002
Novel iron(III) complexes with imidazole containing tripodal ligands as model systems for catechol dioxygenases
1999
C−H Bond Activation by a Ferric Methoxide Complex: A Model for the Rate-Determining Step in the Mechanism of Lipoxygenase
1997
Hexadentate Bispidine Derivatives as Versatile Bifunctional Chelate Agents for Copper(II) Radioisotopes
2009
Three-Membered-Ring-Based Molecular Architectures
2006
Preparation and Structure of Oxo-bridged Dinuclear Vanadium(III) Complex [VIII2(l -his)4(μ-O)]·2H2O
1993
Spectroscopic and Electronic Structural Studies of the Cu(III)2Bis-μ-oxo Core and Its Relation to the Side-On Peroxo-Bridged Dimer
1999
Highly efficient immobilization of Cinchona alkaloid derivatives to silica gel via click chemistry
2006
New VIVO2+ complexes containing biologically relevant ligands as synthetic models for the vanadium(IV) transferrins
2001
Characterization of Novel Vanadium(III)/Acetate Clusters Formed in Aqueous Solution
2005
Bleach and oxidation catalysis by manganese–1,4,7-triazacylononane complexes and hydrogen peroxide
2006
Brønsted Acidity in Metal–Organic Frameworks
2015 StandoutNobel
Structures of Metal–Organic Frameworks with Rod Secondary Building Units
2016 StandoutNobel
Gallium and Indium Complexes of Bis(amino thiol) (N2S2) Ligands
1996
“Let's Twist Again”Double-Stranded, Triple-Stranded, and Circular Helicates
2001
The Cinchona Primary Amine-Catalyzed Asymmetric Epoxidation and Hydroperoxidation of α,β-Unsaturated Carbonyl Compounds with Hydrogen Peroxide
2013 StandoutNobel
Hydrogen Atom Abstraction by Metal−Oxo Complexes: Understanding the Analogy with Organic Radical Reactions
1998
Organocatalytic and Highly Enantioselective Direct α-Amination of Aromatic Ketones
2007
Iron(II ) Formate [Fe(O2CH)2]·1/3HCO2H: A Mesoporous Magnet − Solvothermal Syntheses and Crystal Structures of the Isomorphous Framework Metal(II ) Formates [M(O2CH)2]·n(Solvent) (M = Fe, Co, Ni, Zn, Mg)
2005
Bioinspired Metal–Organic Framework Catalysts for Selective Methane Oxidation to Methanol
2018 StandoutNobel
Theoretical investigation on chiral cinchona alkaloid salts‐catalyzed asymmetric epoxidation of cyclic enones
2010
Coordination chemistry of vanadium in biological systems
1991
Catalytic Asymmetric Epoxidation of α-Branched Enals
2010 StandoutNobel
Anionic metal–organic and cationic organic layer alternation in the coordination polymers [{M(BTEC)(OH2)4}·{C4H12N2}·4H2O]n (M = Co, Ni, and Zn; BTEC = 1,2,4,5-benzenetetracarboxylate)
2001
π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium
2010 Standout
Spectroscopic, magnetic and structural studies on the mixed-valence cuboidal clusters [Mo4E4(edta)2]3–(E = S or Se; H4edta = ethylenediaminetetraacetic acid) and [Mo4S4(H2O)12]5+
1996
The Tri‐μ‐amidobis[triamminecobalt(III )] Cation: The First Triply Amido‐bridged Complex
1990
Biomimetic oxo-, dioxo- and oxo-peroxo-hydrazonato-vanadium(iv/v) complexes
2002
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
2011 StandoutNobel
A novel enantiopure proline-derived triazacyclononane: synthesis, structure and application of its manganese complex
2000
The Chemistry and Applications of Metal-Organic Frameworks
2013 StandoutScienceNobel
Catalytic epoxidation of unfunctionalized alkenes by dinuclear nickel(II) complexes
1996 StandoutNobel
Structural, Spectroscopic, and Theoretical Characterization of Bis(μ-oxo)dicopper Complexes, Novel Intermediates in Copper-Mediated Dioxygen Activation
1996
C−H Bond Activation by a Ferric Methoxide Complex: Modeling the Rate-Determining Step in the Mechanism of Lipoxygenase
2001
Recent advances in asymmetric catalysis with cinchona alkaloid-based primary amines
2011
Synthesis, spectra and electrochemistry of non-oxovanadium(IV) bischelates of tridentate schiff base ligands. Magnetism of bis[N-(2-hydroxyphenyl)-5-methylsalicylideniminato]vanadium(IV)
1992
Synthesis, mechanism of formation and characterization of a new class of octanuclear mixed-metal clusters Na2M′2[M3O4(O2CEt)8]2(M′= Cr or V; M = Mo or W)
1994
Photolysis ofcis- andtrans-[FeIII(cyclam)(N3)2]+Complexes: Spectroscopic Characterization of a Nitridoiron(V) Species
1999
Magneto−Structural Correlation Studies of A Ferromagnetically Coupled Dinuclear Vanadium(IV) Complex. Single-Crystal EPR Study
1998
Syntheses, Structures, and Physicochemical Properties of Diruthenium Compounds of Tetrachlorocatecholate with Metal−Metal Bonded Ru3+(μ-OR)2Ru3+ and Ru3.5+(μ-OR)2Ru3.5+ Cores (R = CH3 and C2H5)
2001 StandoutNobel
Synthesis, structure and electrochemical characterization of a new non-oxo vanadium(IV) complex
1992
Organorhenium Oxides
1997
Raman Evidence for a Weakened O−O Bond in Mononuclear Low-Spin Iron(III)−Hydroperoxides
1998 StandoutNobel
Mechanistic Studies on Synthetic Fe−S-Based Clusters and Their Relevance to the Action of Nitrogenases
2005 StandoutNobel
Mixed-Valent {FeIV(μ-O)(μ-carboxylato)2FeIII}3+ Core
2003
Cu-Catalyzed Azide−Alkyne Cycloaddition
2008 StandoutNobel
NaV(3)(OH)(6)(SO(4))(2): A Kagomé-Type Vanadium(III) Compound with Strong Intralayer Ferromagnetic Interactions Financial support for this work was provided by the National Science Foundation (DMR-9311597) and by the Center for Materials Science and Engineering Research at MIT (DMR-9808941).
2001
Metalloenzymes, Structural Motifs, and Inorganic Models
1993 Science
Synthesis, Structure, and Catalase‐Type Activity of a Novel Oxo‐Bridged Tetranuclear Manganese Aggregate Exhibiting Short OċO Interactions
1990
Tetranuclear and Pentanuclear Vanadium(IV/V) Carboxylate Complexes: [V4O8(NO3)(O2CR)4]2- and [V5O9X(O2CR)4]2- (X = Cl-, Br-) Salts
1996
Macrocyclic dimeric vanadium(IV ) and heterodinuclear vanadium(IV )–nickel(II ) complexes. Structure, magnetic, electronic and redox properties
1996
Synthesis and structure of a novel dinuclear copper(II) complex containing 1,4,7-triazacyclododecane [Cu2(HO) (MeCO2) (tacd)2](Cl04)2
1997
Asymmetric Enamine Catalysis
2007 StandoutNobel
Aldehyde Selective Wacker Oxidations of Phthalimide Protected Allylic Amines: A New Catalytic Route to β3-Amino Acids
2009 StandoutNobel
Reactivity of Surface Species in Heterogeneous Catalysts Probed by In Situ X-ray Absorption Techniques
2013
Amavadin, an Example for Selective Binding of Vanadium in Nature: Studies of Its Complexation Chemistry and a New Structural Proposal
1987
Substitution of manganese for iron in ribonucleotide reductase from Escherichia coli. Spectroscopic and crystallographic characterization.
1992
Synthesis and Characterization of Novel V/O/SO4Chains Incorporating 2,2‘-Bipyridine Ligands: Crystal Structure of [V2O2(OH)2(SO4)(2,2‘-bpy)2]
1998
Synthesis, Crystal Structure, and Properties of a 3-D Network Assembled by Nickel(II) Macrocyclic Complex and Terephthalato Bridge
1999
1,2-Bis(pyridine-2-carboxamido)benzenate(2−), (bpb)2-: A Noninnocent Ligand. Syntheses, Structures, and Mechanisms of Formation of [(n-Bu)4N][FeIV2(μ-N)(bpb)2(X)2] (X = CN-, N3-) and the Electronic Structures of [MIII(bpbox1)(CN)2] (M = Co, Fe)
2000
The first evidence for activation of exogenous O2 on a vanadium(IV) center: synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate
1999
Expanded Prussian Blue Analogues Incorporating [Re6Se8(CN)6]3-/4- Clusters: Adjusting Porosity via Charge Balance
2001
Monomeric InC6H3-2,6-Trip2 (Trip = -C6H2-2,4,6-i-Pr3) and Its Manganese Complex (η5-C5H5)(CO)2MnInC6H3-2,6-Trip2: One-Coordinate Indium in the Solid State
1998
Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)FeIII(N3)]+ and Ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in Water/Acetone Mixtures
2000
The coordination chemistry of the binuclear iron site in hemerythrin
1987
The Library of Cinchona Alkaloids-1,2,3-triazole Derivatives: Structure and Facile Access by “Click Chemistry”
2005
Works of Bernhard Nuber being referenced
The reactivity of the {Mn2(μ-O)(μ-CH3CO2)2}2+ core. The crystal structures of [LMn(N3)3] and [L′Mn(S4)(H2O)] (L = 1,4,7-triazacyclononane, L′= N,N′,N″-trimethyl-1,4,7-triazacyclononane)
1987
Structural Rearrangements in Triple-Decker-Like Complexes with Mixed Group 15/16 Ligands: Synthesis and Characterization of the Redox Couple [Cp2*Fe2As2Se2]/[Cp2*Fe2As2Se2]+ (Cp*=C5Me5)
2001
Mono- and dinuclear titanium(III)/titanium(IV) complexes with 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structures of a compositionally disordered green and a blue form of [LTiCl3]. Structures of [LTi(O)(NCS)2], [LTi(OCH3)Br2](ClO4), and [L2Ti2(O)2F2(.mu.-F)](PF6)
1992
Novel cofacial bioctahedral complexes of ruthenium: syntheses and properties of the mixed-valence species [LRu2.5(.mu.-X)3Ru2.5L]2+ (X = Cl, Br, I, OH). Crystal structures of [LRu2.5(.mu.-OH)3Ru2.5L](PF6)2.cntdot.H2O and [LRuIV(.mu.-O)3RuIVL](PF6)2.cntdot.H2O (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
1990
Ruthenium Complexes Containing “Noninnocent” o-Benzoquinone Diimine/o-Phenylenediamide(2−) Ligands. Synthesis and Crystal Structure of the Nitrido-Bridged Complex [{LRu(o-C6H4(NH)2)}2(μ-N)](PF6)2·3CH3CN·C6H5CH3
1998
Syntheses and characterization of stable pseudo-octahedral tris-phenolato complexes of vanadium-(III), -(IV), and -(V)
1990
A new N,O-donor hexadentate ligand and its first vanadium(III) complex
1991
The missing link in the series [L2MIII2(µ-O)(µ-MeCO2)2]2+(M = Ti, V, Cr, Mn, Fe). Synthesis, crystal structure and magnetism of [L2CrIII2(µ-O)(µ-MeCO2)2][BPh4]2
1990
[L2Mn2(.mu.-O)2(.mu.-O2)](ClO4)2. The first binuclear (.mu.-peroxo)dimanganese(IV) complex (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). A model for the S4 .fwdarw. S0 transformation in the oxygen-evolving complex in photosynthesis
1990
[(η5‐C5Me5)AlFe(CO)4]—Synthesis, Structure, and Bonding
1997
Syntheses and crystal structures of complexes [L′O(H2O)V(µ-O)WO2L]Cl(ClO4) and [L′(acac)MoIII(µ-O)MoVIO2L′][BPh4]2(L,L′= 1,4,7-triazacyclononane and its 1,4,7-trimethyl derivative; acac = pentane-2,4-dionate)
1991
The Molecular and Electronic Structure of Symmetrically and Asymmetrically Coordinated, Non-Heme Iron Complexes Containing [FeIII(μ-N)FeIV]4+ (S=3/2) and [FeIV(μ-N)FeIV]5+ (S=0) Cores
1999
Mono- and dinuclear zinc(II) complexes of biological relevance. Crystal structures of [L2Zn](PF6)2, [L'Zn(O2CPh)2(H2O)], [L'2Zn2(.mu.-OH)2](ClO4)2, and [L'2Zn2(.mu.-OH)(.mu.-CH3CO2)2](ClO4).cntdot.H2O (L = 1,4,7-triazacyclononane, L' = 1,4,7-trimethyl-1,4,7-triazacyclononane)
1992
Bioanorganische Modellkomplexe für Metalloproteine des Eisen(III) und Mangan(III): Synthese, Magnetismus und Kristallstrukturen von [L2Fe2(acac)2(μ-O)](ClO4)2, [L'Mn(acac)(OC2H5)]BPh4 und [L'Mn(acac)(OH2)](ClO4)2 (L = 1,4,7-Triazacyclononan, L' = N,N',N"-Trimethyl-1,4,7-triazacyclononan)
1988
Synthesis, crystal structures, reactivity, and magnetochemistry of a series of binuclear complexes of manganese(II), -(III), and -(IV) of biological relevance. The crystal structure of [L'MnIV(.mu.-O)3MnIVL'](PF6)2.H2O containing an unprecedented short Mn.cntdot..cntdot..cntdot.Mn distance of 2.296 .ANG.
1988
Trigonal kristallisierende Metall(II)‐hexacyanoferrate(II)M2II[Fe(CN)6]
1981
Nucleophilic behaviour of monomeric cis-trioxotungsten(VI) complexes LWO3 (L = tridentate N-macrocycle)
1989
General route to .mu.-hydroxo-bis(.mu.-acetato)-bridged heterometal dinuclear complexes. Syntheses, magnetic and redox properties, electronic spectra, and molecular structures of the [Cr(III)-Co(II)] and [Cr(III)-Fe(II)] species
1987
Preparation and magnetism of the binuclear iron(II) complexes [{Fe(C9H21N3)X2}2](X = NCS, NCO, or N3) and their reaction with NO. Crystal structures of [{Fe(C9H21N3)(NCS)2}2] and [Fe(C9H21N3)(NO)(N3)2]
1987
Syntheses, properties and electrochemistry of transition-metal complexes of the macrocycle 1,4,7-tris(2-pyridylmethyl)-1,4,7-triazacyclononane (L). Crystal structures of [NiL](ClO4)2, [MnL](ClO4)2, and [PdL](PF6)2 containing a distorted-square-base-pyramidal PdIIN5 core
1986
Mehrfachbindungen zwischen hauptgruppenelementen und übergangsmetallen XXVIII. Cycloaddition von heterokumulenen an oxorhenium-halbsandwich-komplexe: Synthese neuartiger metallacyclen
1986
[L2Fe(μ‐OH)(μ‐CH3CO2)2](ClO4)·H2O, a Model Compound for the Diiron Centers in Deoxyhemerythrin
1985
Synthesis and co-ordination chemistry of the macrocycle 1,4,7-triisopropyl-1,4,7-triazacyclononane
1993
Co-ordination chemistry of 1,4,7-triazacyclononane (L) and its N-methylated derivative (L′) with silver(I ) and mercury(II ). The crystal structures of [AgL′2]PF6and [AgL′(SCN)]
1991
A Hemerythrin Model Complex with Catalase Activity
1993
A superphane of cyclobutadiene capped by cyclopentadienylcobalt.
1987
First-row transition-metal complexes of mixed ‘pendant-arm’ derivatives of 1,4,7-triazacyclononane containing phenolate and carboxylate functional groups
1996
Syntheses, electrochemistry, and spectroscopic and magnetic properties of new mononuclear and binuclear complexes of vanadium(III), -(IV, and -(V) containing the tridentate macrocycle 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structures of [L2V2(acac)2(.mu.-O)]I2.2H2O, [L2V2O4(.mu.-O)].14H2O, and [L2V2O2(OH)2(.mu.-O)](ClO4)2
1990
Bioinorganic model complexes for the active site in manganese containing catalases. The crystal structures of [L2MnII2(μ-OH)(μ-O2CCH3)2] (PF6)·CH3OH and [L′2MnIII2(μ-O)(μ-O2CCH3)2] (I3)I·H2O
1989
Synthesis and coordination chemistry of the hexadentate ligands 1,4,7-tris(2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L1) and 1,4,7-tris(3-tert-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L2). Crystal structures of [HL1CuII] and [L2FeIII]acacH
1990
Synthesis, magnetism and crystal structure of [V2O2(μ-OH)2(tpen)]I2·4H2O; a binuclear complex containing the syn-{VO(μ-OH)2VO}2+ core (tpen = tetrakis(2-pyridylmethyl)ethylenediamine)
1988
Aqua(dipicolinato)(hydroxylamido-N,O)oxovanadium
1981
Synthesis of novel trimeric µ-oxo-bridged manganese(IV ) complexes: [L3Mn3IV(µ2-O)3(µ3-XO4)]Br3(X = P, As, or VV; L = 1,4,7-triazacyclononane)
1988
Synthesis and Characterization of Six-Coordinate Nitrido Complexes of Vanadium(V), Chromium(V), and Manganese(V). Isolation of a Dinuclear, Mixed-Valent μ-Nitrido Chromium(III)/Chromium(V) Species
1996
Intramolecular, base-induced formation of a metal-metal bond in [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2]3+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). Crystal structures of [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2](ClO4)3.cntdot.H2O and [L2MoIII2(.mu.-O)(.mu.-CH3CO2)2](ClO4)(BF4).cntdot.H2O and of the mixed-valence complex [L2MoIIIMoIV(.mu.-O)(.mu.-CH3CO2)2](ClO43.cntdot.H2O
1989
Dipicolinato(hydroxylamido‐O,N)(nitrosyl)aquavanadat — ein Nitrosylkomplex des Vanadiums mit „side on” koordiniertem Hydroxylamin
1978
Complexes of thallium(I) and -(III) containing 1,4,7-triazacyclononane (L) ligands. Kinetics and mechanism of the reduction of [L2TlIII]3+. Crystal structure of (N,N',N"-trimethyl-1,4,7-triazacyclononane)thallium(I) hexafluorophosphate
1986
Macrocyclic complexes of indium(III): novel .mu.-hydroxo- and .mu.-oxo-bridged complexes. Crystal structures of [L4In4(.mu.-OH)6](S2O6)3.4H2O and [L2In2(CH3CO2)4(.mu.-O)].2NaClO4 (L = 1,4,7-triazacyclononane)
1986
The Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane and Its Complexes with Zinc(II), Cadmium(II), and Mercury(II) in Solution and in the Solid State
1995
Synthesis, magnetic properties, redox behaviour, and crystal structure of the bridged binuclear nickel(II ) complex [Ni2(µ-OH)(µ-CH3CO2)2L2]ClO4·H2O
1988
Crown Thioether Complexes of AgI and CuI: The Crystal Structures of [{Ag3L3}AgL{AgL2}](ClO4)4 and [LCuI] (L = 1, 4, 7‐Trithiacyclononane)
1987
Neue μ‐Hydroxo‐Übergangsmetallkomplexe, I. Darstellung und Struktur des trans‐Diaqua‐di‐μ‐hydroxo‐bis[(1,4,7‐triazacyclononan)cobalt(III)]‐Kations; Kinetik und Mechanismus seiner Bildung
1979
Inter- versus intramolecular cyclobutadiene complex formation in the reaction of 1,6-cyclodecadiyne derivatives with (.eta.5-Me5C5)Co(C2H4)2
1993
Synthesis and structural and spectroscopic studies of manganese complexes of pendant-arm macrocycles based on 1,4,7-triazacyclononane: crystal structures of the manganese(II) complex [MnLH3][MnCl4] and of the mixed-valence manganese(II)-manganese(IV) hydrogen-bridged dimer [MnLH3LMn][PF6]3 (LH3 = N,N',N''-tris[(2S)-2-hydroxypropyl]-1,4,7-triazacyclononane) and of the manganese(IV) monomer [MnL'][ClO4] (L'H3 = N,N',N''-tris(2-hydroxyethyl)-1,4,7-triazacyclononane)
1991
Syntheses of [LRe(CO)3]+ and [LRe(NO)(CO)2]2+ and their oxidative decarbonylation product [LReO3]+. Crystal structure of [LReO3]Cl (L = 1,4,7-triazacyclononane)
1986
Schwingungsspektrum und Kristallstruktur des fünffach-koordinierten cis-Dioxo-dipicolinato-vanadat(V)-Anions / Vibrational Spectrum and Crystal Structure of the cis-Dioxo-dipicolinato-vanadium(V) Anion
1978
1,3λ3-Thiaphosphole
1987
The design of a new type of very rigid tetradentate ligand
1997
Dinuclear Manganese(II,III,IV ) Model Complexes for the Active Center of the Metalloprotein Photosystem II: Synthesis, Magnetism, and Crystal Structure of [LMnIII (μ‐O)(μ‐CH3CO2)2MnIV L][ClO4]3(L = N,N′N″‐Trimethyl‐1,4,7‐triazacyclononane)
1986
Synthesis and characterization of (.mu.-hydroxo)bis(.mu.-acetato)diiron(II) and (.mu.-oxo)bis(.mu.-acetato)diiron(III) 1,4,7-trimethyl-1,4,7-triazacyclononane complexes as models for binuclear iron centers in biology; properties of the mixed valence diiron(II,III) species
1987
Kinetics and mechanism of the outer-sphere electron-transfer-induced formation of cis-dioxovanadium(V) species from vanadyl(IV) complexes. Crystal structures of [VO(TCDA)].cntdot.H2O and [VO2(TCDAH)].cntdot.2H2O (TCDA = 1,4,7-triazacyclononane-N,N'-diacetate)
1988
The redox chemistry of LMO3·3H2O (MMo(VI), W(VI); L=1,4,7-triazacyclononane). The crystal structures of anti-[L2W2Cl2(μ-O)(μ-OH)]ZnCl4·2H2O and [L3Mo3O4] [Zn(Cl,Br)4]2·H2O
1993
Moderately strong intramolecular magnetic exchange interaction between the copper(II) ions separated by 11.25 .ANG. in [L2Cu2(OH2)2(.eta.-terephthalato)](ClO4)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
1988
Syntheses, redox behavior, and magnetic and spectroscopic properties of copper(II)copper(II)copper(II), copper(II)nickel(II)copper(II), and copper(II)palladium(II)copper(II) species. Crystal structure of [L2Cu2Cu(dmg)2Br]ClO4.cntdot.CH3OH (L = 1,4,7-trimethyl-1,4,7-triazacyclononane; dmg = dimethylglyoximato(2-))
1991
Spontaneous self assembly of the {M2(µ-O)(µ-MeCO2)2}2+core. Synthesis, structure, and properties of the binuclear vanadium(III ) complex
1986
The monofunctionalized 1,4,7-triazacyclononane derivatives 1,4,7-triazacyclononane-N-acetate (L1) and N-(2-hydroxybenzyl-1,4,7-triazacyclononane (HL2) and their complexes with vanadium(IV)/(V). Localized and delocalized electronic structures in compounds containing the mixed valent [OVIVOVVO]3+ core
1995
Dipicolinato(hydroxylamido‐O,N)(nitrosyl)aquavanadate—A Nitrosyl Complex of Vanadium with “side on” Coordinated Hydroxylamine
1978
A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration
1992
Synthesis, properties and crystal structures of [RuIII2(tacn)2(µ-OH)2(µ-CO3)]Br2·3.75H2O and [Ru3.52(dtne)(µ-O)2(µ-CO3)]PF6·5H2O [tacn = 1,4,7-triazacyclononane, dtne = 1,2-bis(1,4,7-triazacyclononan-1-yl)ethane]
1994
Coordination chemistry of rhenium(V), -(IV), and -(III) with the macrocyclic ligands 1,4,7-triazacyclononane (L) and its N-methylated derivative (L'). Crystal structures of [LReCl3]Cl, [L2Re2Cl2(.mu.-Cl)(.mu.-OH)]I2.cntdot.2H2O, [L2Re2I2(.mu.-O)2]I2.cntdot.2H2O, and [L'2Re2Cl4(.mu.-O)]ZnCl4. Effect of .pi.-donors on the Re-Re bond distance
1991
Mononuclear and dinuclear ruthenium complexes containing the LRu(acac) fragment. Crystal structures of [LRuIII(acac)(OH)]PF6.cntdot.H2O, [{LRuIII(acac)}2(.mu.-O2H3)](PF6)3, and [{LRuIII(acac)}2(.mu.-O)](PF6)2. Characterization of the mixed-valence species [{LRu(acac)}2(.mu.-O)](PF6)3 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
1993
Zweikernige Mangan(II,III,IV)-Modelkomplexe für das aktive Zentrum des Metalloproteins Photosystem II: Darstellung, Magnetismus und Kristallstruktur von [LMnIII(-O)(-CH3CO2)2 MnIVL][ClO4]3 (L=N,N′,N″-Trimethyl-1,4,7-triazacyclononan
1986
[L2FeII2(μ‐OH)(μ‐CH3CO2)2](CIO4)·H2O, eine Modellverbindung der Dieisenzentren in Desoxyhämerythrin
1985
A new tetranuclear oxohydroxoiron(III) cluster: crystal structure, magnetic properties, and EXAFS investigation of [L4Fe4(.mu.-O)2(.mu.-OH)4]I4.cntdot.3H2O (L = 1,4,7-triazacyclononane)
1989
New triply hydroxo-bridged complexes of chromium(III), cobalt(III), and rhodium(III): crystal structure of tris(.mu.-hydroxo)bis[(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)] triiodide trihydrate
1982
Enantioselective catalysis. Part 119: New chiral 2-(2-pyridinyl)oxazoline ligands containing an additional optically active substituent in the pyridine system
1998
Enantioselective catalysis 98. Preparation of 9-amino(9-deoxy)cinchona alkaloids
1995
(.mu.-Hydroxo)bis(.mu.-carboxylato)diruthenium and (.mu.-oxo)bis(.mu.-carboxylato)diruthenium Complexes Containing Weatk Intramolecular Ru.cntdot..cntdot..cntdot.Ru interactions
1989
Crystal structure of bis[bis(1,4,7-triazacyclononane)nickel(III)] dithionate heptahydrate and its single-crystal EPR spectrum
1986
Synthesis and x-ray and neutron structures of anti-dihydridodi-.mu.-hydridobis(1,4,7-trimethyl-1,4,7-triazacyclononane)dirhodium(2+) hexafluorophosphate and a related species containing a syn-[Rh2(H)2(.mu.-H)2]2+ core. Isolation of tri-.mu.-hydridobis(1,4,7-trimethyl-1,4,7-triazacyclononane)diiron(1+) tetraphenylborate
1993
Pendent arm macrocyclic complexes: crystal structures of AI(TCTA) and In(TS-TACN)
1993
New mono- and dinuclear titanium(III) complexes. The crystal structure of and exchange coupling in [{LTiIII(NCO)2}2(.mu.-O)] (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
1994
Struktur‐Magnetismus‐Beziehung in [TiIII‐O‐TiIII]4⊕‐Komplexen
1990
Syntheses and spectroscopic and magnetic properties of novel binuclear vanadium(III)/(IV) complexes. Crystal structures of [L2V2(.mu.-O)(.mu.-CH3CO2)2]I2.cntdot.2H2O and [L2V2O2(.mu.-CH3CO2)2]I2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
1988
Die Re‐Re‐Bindung in zweikernigen Di‐μ‐oxorheniumkomplexen mit dem Liganden 1,4,7‐Triazacyclononan
1990
Synthesis and Characterization of Mononuclear Octahedral Titanium(IV) Complexes Containing Ti:O, Ti(O2), and Ti(OCH3)x (x = 1-3) Structural Units
1994
Darstellung und Charakterisierung des Zwitterions S2C—C(NMe2)2; eine übergangsmetallinduzierte C—C-Kopplung. Komplexchemie der Zwitterionen S2C—C(NR2)2 / Synthesis and Characterization of the Zwitter Ion S2C —C(NMe2)2; a Transition Metal Induced C —C Coupling. Complex Chemistry of the Zwitter Ions S2C —C(NR2)2
1987