Standout Papers
Citation Impact
Citing Papers
Catalytic reduction of dinitrogen to ammonia at well-defined single metal sites
2005 StandoutNobel
Structural basis of biological nitrogen fixation
2005
Formylglycine-generating enzyme binds substrate directly at a mononuclear Cu(I) center to initiate O 2 activation
2019 StandoutNobel
The Evolution and Future of Earth’s Nitrogen Cycle
2010 StandoutScience
Vanadium K-edge X-ray absorption spectrum of the VFe protein of the vanadium nitrogenase of Azotobacter chroococcum
1987 Nature
Legume root nodule nitrogenase
1974
Nitrogenase of Klebsiella pneumoniae : an MgATP hydrolysing energy transduction system with similarities to actomyosin and p21ras
1992
Breaking the N2 triple bond: insights into the nitrogenase mechanism
2006
Circular Dichroism and X-ray Spectroscopies of Azotobacter vinelandii Nitrogenase Iron Protein
1996
Evidence for a Central Role of Lysine 15 of Azotobacter vinelandii Nitrogenase Iron Protein in Nucleotide Binding and Protein Conformational Changes
1995
An All-ferrous State of the Fe Protein of Nitrogenase
1998
Hydrolysis of Nucleoside Triphosphates Other than ATP by Nitrogenase
2000
Homocitrate is a component of the iron-molybdenum cofactor of nitrogenase
1989
The substrate-binding site in Cu nitrite reductase and its similarity to Zn carbonic anhydrase
1995
Dinitrogenase with altered substrate specificity results from the use of homocitrate analogs for in vitro synthesis of the iron-molybdenum cofactor
1988
Perspectives on Non-Heme Iron Protein Chemistry
1991
The Role of Mo Atoms in Nitrogen Fixation: Balancing Substrate Reduction and Dihydrogen Production
2003 StandoutNobel
The structure and mechanism of iron-hydrogenases
1990
The housekeeping gene xanthine oxidoreductase is necessary for milk fat droplet enveloping and secretion: gene sharing in the lactating mammary gland
2002 StandoutNobel
N2 Fixation by Streptomyces thermoautotrophicus Involves a Molybdenum-Dinitrogenase and a Manganese-Superoxide Oxidoreductase That Couple N2Reduction to the Oxidation of Superoxide Produced from O2by a Molybdenum-CO Dehydrogenase
1997
New insights into structure-function relationships in nitrogenase: a 1.6 Å resolution X-ray crystallographic study of Klebsiella pneumoniae MoFe-protein
1999
Catalytic Roles for Two Water Bridged Residues (Asp-98 and His-255) in the Active Site of Copper-containing Nitrite Reductase
2000
Site-directed mutagenesis of conserved cysteine residues within the .beta. subunit of Escherichia coli nitrate reductase. Physiological, biochemical, and EPR characterization of the mutated enzymes
1993
Docking of nitrogenase iron‐and molybdenum‐iron proteins for electron transfer and MgATP hydrolysis: The role of arginine 140 and lysine 143 of the Azotobacter vinelandii iron protein
1994
Enzyme diversity and mosaic gene organization in denitrification
1997
Redox properties and EPR spectroscopy of the P clusters of Azotobacter vinelandii MoFe protein
1993
Nitrogen cycle enzymology
1998
A new method for extraction of iron-molybdenum cofactor (FeMoco) from nitrogenase adsorbed to DEAE-cellulose. 2. Solubilization of FeMoco in a wide range of organic solvents
1989
A Random-sequential Mechanism for Nitrite Binding and Active Site Reduction in Copper-containing Nitrite Reductase
2006
Purification, composition, charge, and molecular weight of the FeMo cofactor from azotobacter vinelandii nitrogenase
1993
Mössbauer spectroscopy applied to the oxidized and semi-reduced states of the iron-molybdenum cofactor of nitrogenase
1989
The nifU, nifS and nifV gene products are required for activity of all three nitrogenases of Azotobacter vinelandii
1992
Removal of the high-potential iron-sulfur [4Fe-4S] center of the .beta.-subunit from Escherichia coli nitrate reductase. Physiological, biochemical, and EPR characterization of site-directed mutated enzymes
1993
Structural and biochemical implications of single amino acid substitutions in the nucleotide-dependent switch regions of the nitrogenase Fe protein from Azotobacter vinelandii
2004
Studies on Protein-Protein Interaction between Copper-containing Nitrite Reductase and Pseudoazurin from Alcaligenes faecalis S-6
1996
Nitrogenase reduction of carbon-containing compounds
2013
Requirement of Homocitrate for the Transfer of a49V-Labeled Precursor of the Iron-Vanadium Cofactor from VnfX to nif-apodinitrogenase
2001
Biosynthesis of the Iron-Molybdenum Cofactor of Nitrogenase
1994
Nitrogenase and biological nitrogen fixation
1994
SQUID measurement of metalloprotein magnetization. New methods applied to the nitrogenase proteins
1987
The hydrogenase‐like Nar1p is essential for maturation of cytosolic and nuclear iron–sulphur proteins
2004
The inorganic biochemistry of molybdoenzymes
1988
Electron transfer in nitrogenase catalysis
2012
Nucleotide Hydrolysis and Protein Conformational Changes in Azotobacter vinelandii Nitrogenase Iron Protein: Defining the Function of Aspartate 129
1995
Electron‐Transfer Chemistry of the Iron–Molybdenum Cofactor of Nitrogenase: Delocalized and Localized Reduced States of FeMoco which Allow Binding of Carbon Monoxide to Iron and Molybdenum
2002
pH Dependence of Copper Geometry, Reduction Potential, and Nitrite Affinity in Nitrite Reductase
2006
Comparison of redox and EPR properties of the molybdenum iron proteins of Clostridium pasteurianum and Azotobacter vinelandii nitrogenases
1988
Thermodynamics of nucleotide interactions with the Azotobacter vinelandii nitrogenase iron protein
1999
Role for the nitrogenase MoFe protein α-subunit in FeMo-cofactor binding and catalysis
1990 Nature
Demonstration of Proton-coupled Electron Transfer in the Copper-containing Nitrite Reductases
2009
Identification of the V factor needed for synthesis of the iron-molybdenum cofactor of nitrogenase as homocitrate
1987 Nature
The Molybdenum Nitrogenase from Wild‐type Xanthobacter autotrophicus Exhibits Properties Reminiscent of Alternative Nitrogenases
1995
Structural and kinetic evidence for an ordered mechanism of copper nitrite reductase
1999
Resonance Raman studies of the [4Fe‐4S] to [2Fe‐2S] cluster conversion in the iron protein of nitrogenase
1991
Quantitative EPR of an S= 7/2 system in thionine‐oxidized MoFe proteins of nitrogenase
1987
Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigas
1995 StandoutNature
The Structure of Copper-nitrite Reductase from Achromobacter cycloclastes at Five pH Values, with NO-2 Bound and with Type II Copper Depleted
1995
Biochemical characterization and solution structure of nitrous oxide reductase from Alcaligenes xylosoxidans (NCIMB 11015)
1999
EPR and electron nuclear double resonance (ENDOR) studies show nitrite binding to the type 2 copper centers of the dissimilatory nitrite reductase of Alcaligenes xylosoxidans (NCIMB 11015)
1994
Substrate reduction properties of dinitrogenase activated in vitro are dependent upon the presence of homocitrate or its analogs during iron-molybdenum cofactor synthesis
1989
Substitution of histidine for arginine-101 of dinitrogenase reductase disrupts electron transfer to dinitrogenase
1989
Nitrogenase: a general hydrogenator of small molecules
2013
Insights into substrate binding at FeMo-cofactor in nitrogenase from the structure of an α-70Ile MoFe protein variant
2009
Enzymes and associated electron transport systems that catalyse the respiratory reduction of nitrogen oxides and oxyanions
1995
A reinvestigation of the pre‐steady‐state ATPase activity of the nitrogenase from Azotobacter vinelandii
1992
XAFS studies of nitrogenase: the MoFe and VFe proteins and the use of crystallographic coordinates in three-dimensional EXAFS data analysis
2002
Structure of Nitrite Bound to Copper-containing Nitrite Reductase from Alcaligenes faecalis
1997
Vanadium nitrogenase: A two-hit wonder?
2011
Cyanamide: a new substrate for nitrogenase
1988
Directing the mode of nitrite binding to a copper‐containing nitrite reductase from Alcaligenes faecalis S‐6: Characterization of an active site isoleucine
2003
Vanadium nitrogenase
2000
Nitrite, a new substrate for nitrogenase
1989
Hydrogen-1 nuclear magnetic resonance of the nitrogenase iron protein (Cp2) from Clostridium pasteurianum
1988
Evidence for Two Distinct Azurins in Alcaligenes xylosoxidans (NCIMB 11015): Potential Electron Donors to Nitrite Reductase
1995
Iron-molybdenum cofactor of nitrogenase: Electrochemical determination of the electron stoichiometry of the oxidized/semi-reduced couple
1988
A method for preparing analytically pure sodium dithionite. Dithionite quality and observed nitrogenase-specific activities
1991
The Copper-containing Dissimilatory Nitrite Reductase Involved in the Denitrifying System of the Fungus Fusarium oxysporum
1995
Biogenesis of Molybdenum Cofactors
1990
Why R-Homocitrate Is Essential to the Reactivity of FeMo-Cofactor of Nitrogenase: Studies on NifV--Extracted FeMo-Cofactor
1998 StandoutNobel
Klebsiella pneumoniae nitrogenase. Mechanism of acetylene reduction and its inhibition by carbon monoxide
1990
Cell biology and molecular basis of denitrification
1997 Standout
Role of magnesium adenosine 5'-triphosphate in the hydrogen evolution reaction catalyzed by nitrogenase from Azotobacter vinelandii
1980
3d Transition Metals for C–H Activation
2018 Standout
Nickel and iron-sulphur centres in Desulfovibrio gigas hydrogenase: ESR spectra, redox properties and interactions
1987
Hydrazine complexes of vanadium(II and III)
1993
Plausible structure of the iron-molybdenum cofactor of nitrogenase.
1992
The Mechanism of Dinitrogen Reduction by Molybdenum Nitrogenases
1995
Reactions with the oxidized iron protein of Azotobacter vinelandii nitrogenase: formation of a 2Fe center
1984
X-ray absorption spectroscopic studies of the binding of ligands to FeMoco of nitrogenase from Klebsiella pneumoniae
1998
Isolation of an iron-molybdenum cofactor from nitrogenase
1977
Evidence for the inorganic nature of the cyanolyzable sulfur of molybdenum hydroxylases.
1982
Structural, Spectroscopic, and Redox Consequences of a Central Ligand in the FeMoco of Nitrogenase: A Density Functional Theoretical Study
2003
Effects of homocitrate, homocitrate lactone, and fluorohomocitrate on nitrogenase in NifV- mutants of Azotobacter vinelandii
1991
Cyanide and Methylisocyanide Binding to the Isolated Iron-Molybdenum Cofactor of Nitrogenase
1989
The isolated iron–molybdenum cofactor of nitrogenase binds carbon monoxide upon electrochemically accessing reduced states
1999
EPR and Mössbauer studies of nucleotide-bound nitrogenase iron protein from Azotobacter vinelandii.
1987
X-ray-absorption-spectroscopic evidence for a novel iron cluster in hydrogenase II from Clostridium pasteurianum
1989
Molecular Basis of the Biological Function of Molybdenum
1974
Single- and Double-Cubane Clusters in the Multiple Oxidation States [VFe3S4]3+,2+,1+
2002
A methyldiazene (HNNCH 3 )-derived species bound to the nitrogenase active-site FeMo cofactor: Implications for mechanism
2006
Nanozymes: Classification, Catalytic Mechanisms, Activity Regulation, and Applications
2019 Standout
Beyond fossil fuel–driven nitrogen transformations
2018 StandoutScienceNobel
The unusual metal clusters of nitrogenase: structural features revealed by x-ray anomalous diffraction studies of the MoFe protein from Clostridium pasteurianum.
1993
Crystallization of the Azotobacter vinelandii nitrogenase iron protein.
1983
Structure and Spectroscopy of Copper−Dioxygen Complexes
2004 Standout
Oxidative Titration of the Nitrogenase VFe Protein from Azotobacter vinelandii: An Example of Redox-Gated Electron Flow
1996
Evidence for a dynamic role for homocitrate during nitrogen fixation: the effect of substitution at the α-Lys426 position in MoFe-protein of Azotobacter vinelandii
2006
Copper Active Sites in Biology
2014 Standout
Binding Sites of Nitrogenase: Kinetic and Theoretical Studies of Cyanide Binding to Extracted FeMo-Cofactor Derivatives
2003 StandoutNobel
The Bioinorganic Chemistry of Vanadium
1991
Possible binding modes for dinitrogen activation by the FeMo-cofactor in nitrogenase
1997
The alternative nitrogenase of Azotobacter chroococcum is a vanadium enzyme
1986 Nature
Purification and characterization of the assimilatory nitrate reductase of Azotobacter vinelandii
1993
Crystallographic structure and functional implications of the nitrogenase molybdenum–iron protein from Azotobacter vinelandii
1992 Nature
Structural Models for the Metal Centers in the Nitrogenase Molybdenum-Iron Protein
1992 Science
Understanding and exploiting C–H bond activation
2002 StandoutNature
A new approach to identifying substrate binding sites on isolated FeMo-cofactor of nitrogenase
1997 StandoutNobel
Altered nitrogenase MoFe proteins from Azotobacter vinelandii. Analysis of MoFe proteins having amino acid substitutions for the conserved cysteine residues within the β-subunit
1991
NITROGENASE STRUCTURE AND FUNCTION: A Biochemical-Genetic Perspective
1995
Temperature-Dependent Regulation by Molybdenum and Vanadium of Expression of the Structural Genes Encoding Three Nitrogenases in Azotobacter vinelandii
1991
Structural and Functional Aspects of Metal Sites in Biology
1996 Standout
Nitrogenase of klebsiella pneumoniae: A pre‐steady state burst of ATP hydrolysis is coupled to electron transfer between the component proteins
1978
Canonical ordered cosmid library of the symbiotic plasmid of Rhizobium species NGR234.
1991 StandoutNobel
Structure of the Mo‐Fe protein component of Azotobacter vinelandii nitrogenase
1983
Nitrogenase of Azotobacter chroococcum: A new electronparamagnetic‐resonance signal associated with a transient species of the MoFe protein during catalysis
1976
Biosynthesis of the Iron-Molybdenum Cofactor of Nitrogenase
2008
Electron Paramagnetic Resonance Analysis of Different Azotobacter vinelandii Nitrogenase MoFe-Protein Conformations Generated during Enzyme Turnover: Evidence for S = 3/2 Spin States from Reduced MoFe-Protein Intermediates
2001
Nitrous oxide as a substrate and as a competitive inhibitor of nitrogenase
1986
Nitrogenase of Klebsiella pneumoniae. Hydrazine is a product of azide reduction
1981
Spectroscopic Evidence for Changes in the Redox State of the Nitrogenase P-Cluster during Turnover
1999
Formation and Insertion of the Nitrogenase Iron−Molybdenum Cofactor
2003
Effects of oxidation state, solvent acidity and thiophenol on the electrochemical properties of iron-molybdenum cofactor from nitrogenase
1990
Azotobacter vinelandii Nitrogenases with Substitutions in the FeMo-Cofactor Environment of the MoFe Protein: Effects of Acetylene or Ethylene on Interactions with H+, HCN, and CN-
2000
Homocitrate cures the NifV- phenotype in Klebsiella pneumoniae
1988
Occurrence, Classification, and Biological Function of Hydrogenases: An Overview
2007 Standout
Catalysis by Enzymes: The Biological Ammonia Synthesis
2006
Selenol binds to iron in nitrogenase iron-molybdenumcofactor: an extended x-ray absorption fine structure study.
1994
Uncoupling Nitrogenase: Catalytic Reduction of Hydrazine to Ammonia by a MoFe Protein in the Absence of Fe Protein-ATP
2010
Systematic synthesis, structural characterization, and reactivity studies of vanadium(V)–citrate anions [VO2(C6H6O7)]22−, isolated from aqueous solutions in the presence of different cations
2001
The Effect of the Redox Potential on the Activity of the Nitrogenase and on the Fe-Protein of Azotobacter vinelandi
1982
Refinement of a Model for the Nitrogenase MoFe Cluster Using Single‐Crystal Mo and Fe EXAFS
1993
Evidence for Electron Transfer from the Nitrogenase Iron Protein to the Molybdenum−Iron Protein without MgATP Hydrolysis: Characterization of a Tight Protein−Protein Complex
1996
Genetic and biochemical analysis of mutants induced by bacteriophage Mu DNA integration into Klebsiella pneumoniae nitrogen fixation genes
1978
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
2005 StandoutNobel
Effect of magnesium adenosine 5'-triphosphate on the accessibility of the iron of clostridial azoferredoxin, a component of nitrogenase
1974
Mössbauer, EPR, and magnetization studies of the Azotobacter vinelandii Fe protein. Evidence for a [4Fe-4S]1+ cluster with spin S = 3/2.
1985
Probing Single Biomolecules in Solution Using the Anti-Brownian Electrokinetic (ABEL) Trap
2012 StandoutNobel
Differential Effects on N2 Binding and Reduction, HD Formation, and Azide Reduction with α-195His- and α-191Gln-Substituted MoFe Proteins of Azotobacter vinelandii Nitrogenase
2000
Mapping the site(s) of MgATP and MgADP interaction with the nitrogenase of Azotobacter vinelandii. Lysine 15 of the iron protein plays a major role in MgATP interaction.
1992
Mechanism of Molybdenum Nitrogenase
1996 Standout
Roles of Water for Chemical Reactions in High-Temperature Water
2002 Standout
Synthesis and Characterization of Sulfur-Voided Cubanes. Structural Analogues for the MoFe3S3 Subunit in the Nitrogenase Cofactor
2001
Nitrogenase reactivity: effects of component ratio on electron flow and distribution during nitrogen fixation
1981
Solubilization of the iron molybdenum cofactor of Azotobacter vinelandii nitrogenase in dimethylformamide and acetonitrile
1986
Nitrogenase: the reaction between iron protein and bathophenanthrolinedisulfonate as a probe for interactions with MgATP
1978
The Clusters of Nitrogenase: Synthetic Methodology in the Construction of Weak-Field Clusters
2003
Hydrogenases
2014 Standout
Use of preassembled iron/sulfur and iron/molybdenum/sulfur clusters in the stepwise synthesis of potential analogs for the Fe/Mo/S site in nitrogenase
1991
Nitrogenase XII. Mössbauer studies of the MoFe protein from Clostridium pasteurianum W5
1980
Nitrogenase X: Mössbauer and EPR studies on reversibly oxidized MoFe protein from Azotobacter vinelandii OP Nature of the iron centers
1978
Atomic resolution structures of resting-state, substrate- and product-complexed Cu-nitrite reductase provide insight into catalytic mechanism
2005
A novel S = 3/2 EPR signal associated with native Fe‐proteins of nitrogenase
1985
Directed transposon Tn5 mutagenesis and complementation analysis of rhizobium meliloti symbiotic nitrogen fixation genes
1982 StandoutNobel
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
2014 Standout
Crystal structure of the soluble domain of the major anaerobically induced outer membrane protein (AniA) from pathogenic Neisseria: a new class of copper-containing nitrite reductases
2002
Substrate Interactions with Nitrogenase: Fe versus Mo
2004
Protonation and substitution reactions of Fe–S ‘basket’ clusters including extracted FeMo-cofactor of nitrogenase
1999 StandoutNobel
“Fixation” of Dinitrogen by Molybdenum and the Formation of a Trigonal Planar Iron−Tris[molybdenum(dinitrogen)] Complex
1997 StandoutNobel
Involvement of the P Cluster in Intramolecular Electron Transfer within the Nitrogenase MoFe Protein
1995
Hydrazine is a product of dinitrogen reduction by the vanadium-nitrogenase from Azotobacter chroococcum
1991
Oxidation of nitrogenase iron protein by dioxygen without inactivation could contribute to high respiration rates of Azotobacter species and facilitate nitrogen fixation in other aerobic environments
1989
Identification of a nitrogenase protein-protein interaction site defined by residues 59 through 67 within the Azotobacter vinelandii Fe protein.
1994
Unconventional Methods for Fabricating and Patterning Nanostructures
1999 Standout
The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds
2004 Standout
Studies by electron paramagnetic resonance on the catalytic mechanism of nitrogenase of Klebsiella pneumoniae
1973
Structure of the FeFe-cofactor of the iron-only nitrogenase and possible mechanism for dinitrogen reduction
2004
Electron-paramagnetic-resonance studies on nitrogenase of Klebsiella pneumoniae. Evidence for acetylene- and ethylene-nitrogenase transient complexes
1978
Polarity of mutations induced by insertion of transposons Tn5, Tn7 and Tn10 into the nif gene cluster of Klebsiella pneumoniae
1978
Thiol reactivity of the nitrogenase Fe-protein from Azotobacter vinelandii.
1983
Alternate Substrate Binding Modes to Two Mutant (D98N and H255N) Forms of Nitrite Reductase from Alcaligenes faecalis S-6: Structural Model of a Transient Catalytic Intermediate,
2001
Nitrogenase of Klebsiella pneumoniae
1974
On the prosthetic group(s) of component II from nitrogenase
1985
Role of Nucleotides in Nitrogenase Catalysis
1997
Azotobacter vinelandiiVanadium Nitrogenase: Formaldehyde Is a Product of Catalyzed HCN Reduction, and Excess Ammonia Arises Directly from Catalyzed Azide Reduction
2006
Unique features of the nitrogenase VFe protein from Azotobacter vinelandii
2009
Elicitation of thiomolybdates from the iron‐molybdenum cofactor of nitrogenase
1986
A general method for site-directed mutagenesis in prokaryotes
1981 StandoutNatureNobel
The Mononuclear Molybdenum Enzymes
1996 Standout
Interspecies homology of nitrogenase genes.
1980 StandoutNobel
Metal Substitution in the Active Site of Nitrogenase MFe7S9 (M = Mo4+, V3+, Fe3+)
2002
Isolated iron-molybdenum cofactor of nitrogenase exists in multiple forms in its oxidized and semi-reduced states
1989
Molybdenum Triamidoamine Complexes that Contain Hexa-tert-butylterphenyl, Hexamethylterphenyl, or p-Bromohexaisopropylterphenyl Substituents. An Examination of Some Catalyst Variations for the Catalytic Reduction of Dinitrogen
2004 StandoutNobel
Atomic Resolution Structures of Native Copper Nitrite Reductase from Alcaligenes xylosoxidans and the Active Site Mutant Asp92Glu
2003
Electron allocation to alternative substrates of Azotobacter nitrogenase is controlled by the electron flux through dinitrogenase
1980
Metal-Ion Valencies of the FeMo Cofactor in CO-Inhibited and Resting State Nitrogenase by 57Fe Q-Band ENDOR
1997
Iron-Sulfur Clusters: Nature's Modular, Multipurpose Structures
1997 StandoutScience
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation
2013 Standout
Spectroscopic and Computational Studies of Nitrite Reductase: Proton Induced Electron Transfer and Backbonding Contributions to Reactivity
2008
Identification of possible adenine nucleotide‐binding sites in nitrogenase Fe‐ and MoFe‐proteins by amino acid sequence comparison
1984
Electron Paramagnetic Resonance of Nitrogenase and Nitrogenase Components from Clostridium pasteurianum W5 and Azotobacter vinelandii OP
1972
Chemistry of Biologically Important Synthetic Organoselenium Compounds
2001 Standout
Comparative Assessment of the Composition and Charge State of Nitrogenase FeMo-Cofactor
2011
Small-angle x-ray scattering studies of the iron-molybdenum cofactor from Azotobacter vinelandii nitrogenase.
1993
Nitrogenase metalloclusters: structures, organization, and synthesis
1993
Electron‐Paramagnetic‐Resonance Studies on Nitrogenase
1974
Characterization of a Tungsten-Substituted Nitrogenase Isolated from Rhodobacter capsulatus,
2003
Biological nitrogen fixation by way of an enzyme-bound dinitrogen-hydride intermediate
1978 Nature
Noble metal-free hydrogen evolution catalysts for water splitting
2015 Standout
Purification of the Azotobacter vinelandii nifV-encoded homocitrate synthase
1997
Molybdenum and vanadium nitrogenases of Azotobacter chroococcum. Low temperature favours N2 reduction by vanadium nitrogenase
1988
N2O reduction and HD formation by nitrogenase from a nifV mutant of Klebsiella pneumoniae
1989
Structural Basis of Biological Nitrogen Fixation
1996
Structure−Function Relationships of Alternative Nitrogenases
1996
N coordination of FeMo cofactor requires His-195 of the MoFe protein alpha subunit and is essential for biological nitrogen fixation.
1991
The Mononuclear Molybdenum Enzymes
2014 Standout
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
2003 StandoutScienceNobel
Redox cycling and kinetic analysis of single molecules of solution-phase nitrite reductase
2011 StandoutNobel
Complementary functioning of the component proteins of nitrogenase from several bacteria
1978
Ionic interactions in the nitrogenase complex. Properties of Fe-protein containing substitutions for Arg-100.
1992
Hydrogen burst associated with nitrogenase-catalyzed reactions.
1988
Theoretical Studies of Biological Nitrogen Fixation. I. Density Functional Modeling of the Mo-Site of the FeMo-Cofactor
2001
Effect of high pN2 and high pD2 on ammonia production, hydrogen evolution, and hydrogen deuteride formation by nitrogenases
1985
Kinetics of nitrogenase of Klebsiella pneumoniae. Heterotropic interactions between magnesium-adenosine 5′-diphosphate and magnesium-adenosine 5′-triphosphate
1977
Binding of MgATP to the Nitrogenase Proteins from Azotobactor vinelandii
1983
The continuing story of dinitrogen activation
2000
Diastereomer-dependent substrate reduction properties of a dinitrogenase containing 1-fluorohomocitrate in the iron-molybdenum cofactor.
1990
Purification and Characterization of the Molybdenum-Iron Protein Component of Nitrogenase from Soybean Nodule Bacteroids
1974
Reduction of Thiocyanate, Cyanate, and Carbon Disulfide by Nitrogenase: Kinetic Characterization and EPR Spectroscopic Analysis
1997
Novel metal cluster in the iron-molybdenum cofactor of nitrogenase. Spectroscopic evidence
1978
Klebsiella pneumoniae nitrogenase. Inhibition of hydrogen evolution by ethylene and the reduction of ethylene to ethane
1987
Klebsiella pneumoniae nitrogenase. The pre-steady-state kinetics of MoFe-protein reduction and hydrogen evolution under conditions of limiting electron flux show that the rates of association with the Fe-protein and electron transfer are independent of the oxidation level of the MoFe-protein
1991
Molecular Basis of the Biological Function of Molybdenum
1974
Mechanistic Studies on Synthetic Fe−S-Based Clusters and Their Relevance to the Action of Nitrogenases
2005 StandoutNobel
Time-Resolved Binding of Carbon Monoxide to Nitrogenase Monitored by Stopped-Flow Infrared Spectroscopy
1997
Legume root nodule nitrogenase. Purification, properties, and studies on its genetic control.
1974
Nucleotide-Iron-Sulfur Cluster Signal Transduction in the Nitrogenase Iron-Protein: the Role of Asp 125
1992 Science
Transition Metal Complexes That Contain a Triamidoamine Ligand
1997 StandoutNobel
The rates of binding protons and substrates to [Fe4S4Cl4]2−
2002 StandoutNobel
Broad host range DNA cloning system for gram-negative bacteria: construction of a gene bank of Rhizobium meliloti.
1980 Standout
Reactions of small molecules at transition metal sites: studies relevant to nitrogenase, an organometallic enzyme
1996
Bioelectrochemical Haber–Bosch Process: An Ammonia‐Producing H2/N2 Fuel Cell
2017
Structure–function relationships of copper-containing nitrite reductases
1999
Diazene (HNNH) Is a Substrate for Nitrogenase: Insights into the Pathway of N2 Reduction
2007
Nitrogenase of Klebsiella pneumoniae: reductant‐independent ATP hydrolysis and the effect of pH on the efficiency of coupling of ATP hydrolysis to substrate reduction
1980
Catalytic Reduction of Hydrazine to Ammonia with MoFe3S4−Polycarboxylate Clusters. Possible Relevance Regarding the Function of the Molybdenum-Coordinated Homocitrate in Nitrogenase
1996
Cross-linking site in Azotobacter vinelandii complex.
1990
Electron nuclear double resonance (ENDOR) of metalloenzymes
1991
Overlapping sequences of Klebsiella pneumoniae nif DNA cloned and characterised
1979
The molybdenum and vanadium nitrogenases of Azotobacter chroococcum: effect of elevated temperature on N2 reduction
1993
Structural investigation of nitrogenase components from Clostridium pasteurianum and comparison with similar components of other organisms
1973
Proton-Coupled Electron Transfer
2012 Standout
Current status of structure function relationships of vanadium nitrogenase
2003
Proton-Coupled Electron Transfer in the Catalytic Cycle of Alcaligenes xylosoxidans Copper-Dependent Nitrite Reductase
2011
Mechanism of Mo-Dependent Nitrogenase
2009
Kinetics of MgATP-dependent Iron Chelation from the Fe-protein of the Azotobacter vinelandii Nitrogenase Complex
1989
Nitrogenase-catalyzed ethane production and CO-sensitive hydrogen evolution from MoFe proteins having amino acid substitutions in an alpha-subunit FeMo cofactor-binding domain.
1992
Effects on Substrate Reduction of Substitution of Histidine-195 by Glutamine in the α-Subunit of the MoFe Protein of Azotobacter vinelandii Nitrogenase
1998
Reduction of Dinitrogen to Ammonia at a Well-Protected Reaction Site in a Molybdenum Triamidoamine Complex
2002 StandoutNobel
The mechanism of Klebsiella pneumoniae nitrogenase action. The determination of rate constants required for the simulation of the kinetics of N2 reduction and H2 evolution
1984
Iron-sulfur clusters in the molybdenum-iron protein component of nitrogenase. Electron paramagnetic resonance of the carbon monoxide inhibited state
1979
Works of B. E. Smith being referenced
S=7/2 EPR of the P-clusters in thionine oxidized MoFe-proteins of nitrogenase.
1987
Biochemistry of nitrogenase and the physiology of related metabolism
1987
Analysis of site‐directed mutations in the α‐and β‐subunits of Klebsiella pneumoniae nitrogenase
1990
Structures of a Blue-Copper Nitrite Reductase and its Substrate-Bound Complex
1997
Crystallization and preliminary X-ray studies of nitrogenase component 1 (the MoFe protein) from Klebsiella pneumoniae
1997
Structure of a new azurin from the denitrifying bacteriumAlcaligenes xylosoxidansat high resolution
1995
Nitrogenase from Klebsiella pneumoniae. An e.p.r. signal observed during enzyme turnover under ethylene is associated with the iron-molybdenum cofactor
1983
Nitrogenases from Klebsiella pneumoniae and Clostridium pasteurianum. Kinetic investigations of cross-reactions as a probe of the enzyme mechanism
1976
Circular dichroism and magnetic circular dichroism of nitrogenase proteins
1979
Electron-paramagnetic-resonance and magnetic-circular-dichroism studies of the binding of cyanide and thiols to the iron-molybdenum cofactor from Klebsiella pneumoniae nitrogenase
1994
The vanadium-iron protein of vanadium nitrogenase from Azotobacter chroococcum contains an iron-vanadium cofactor
1988
Nitrogenase from nifV mutants of Klebsiella pneumoniae contains an altered form of the iron-molybdenum cofactor
1984
Electron-paramagnetic-resonance spectroscopy and related techniques in the study of nitrogenase
1985
Site-directed mutagenesis of the Klebsiella pneumoniae nitrogenase. Effects of modifying conserved cysteine residues in the α- and β-subunits
1989
Energy transduction by nitrogenase: binding of MgADP to the MoFe protein is dependent on the oxidation state of the iron-sulphur ‘P’ clusters
1993
Vanadium K-edge X-ray-absorption spectroscopy of the functioning and thionine-oxidized forms of the VFe-protein of the vanadium nitrogenase from Azotobacter chroococcum
1989
Iron K-edge X-ray-absorption spectroscopy of the iron-vanadium cofactor of the vanadium nitrogenase from Azotobacter chroococcum.
1990
A Mössbauer spectroscopic investigation of the redox behaviour of the molybdenum-iron protein from Klebsiella pneumoniae nitrogenase. Mechanistic and structural implications
1980
The inactive MoFe protein (NifB−Kp1) of the nitrogenase from nif B mutants of Klebsiella pneumoniae. Its interaction with FeMo-cofactor and the properties of the active MoFe protein formed
1984
Difference EXAFS Studies of Nitrogenase and Nitrite Reductase Enzymes of the Nitrogen Cycle
1997
Nitrogenase of Klebsiella pneumoniae. Purification and properties of the component proteins
1972
EXAFS of Klebsiella pneumoniae nitrogenase MoFe protein from wild-type and nif V mutant strains
1986
Reduction of cyclopropene by NifV- and wild-type nitrogenases from Klebsiella pneumoniae
1989
Nitrogenase of Klebsiella pneumoniae nifV mutants. Investigation of the novel carbon monoxide-sensitivity of hydrogen evolution by the mutant enzyme
1983
Low-temperature magnetic-circular-dichroism spectroscopy of the iron-molybdenum cofactor and the complementary cofactor-less MoFe protein of Klebsiella pneumoniae nitrogenase
1984
Nitrogenase of Klebsiella pneumoniae: electron-paramagnetic-resonance studies on the catalytic mechanism
1972
Evidence on intramolecular electron transfer in the MoFe protein of nitrogenase from Klebsiella pneumoniae from rapid-freeze electron-paramagnetic-resonance studies of its oxidation by ferricyanide
1983
Purification and characterization of the inactive MoFe protein (NifB-Kp1) of the nitrogenase from nifB mutants of Klebsiella pneumoniae
1983
Exploring the reactivity of the isolated iron-molybdenum cofactor of nitrogenase
1999 StandoutNobel
Electron-paramagnetic-resonance studies on the redox properties of the molybdenum-iron protein of nitrogenase between +50 and −450 mV
1978
X-RAY ABSORPTION SPECTROSCOPY OF Cu-Mo-S AND Fe-Mo-S SYSTEMS OF BIOLOGICAL RELEVANCE
1986
Purification and characterization of the dissimilatory nitrite reductase from Alcaligenes xylosoxidans subsp. xylosoxidans (N.C.I.M.B. 11015): evidence for the presence of both type 1 and type 2 copper centres
1993
Iron K-edge X-ray absorption spectroscopy of the iron-molybdenum cofactor of nitrogenase from Klebsiella pneumoniae
1988