A.L. Spek

Anti-Markovnikov alkene oxidation by metal-oxo–mediated enzyme catalysis

Catalytic Markovnikov and anti‐Markovnikov Functionalization of Alkenes and Alkynes: Recent Developments and Trends

Atomic packing and short-to-medium-range order in metallic glasses

Molecular Tectonics: Porous Cleavable Networks Constructed by Dipole‐Directed Stacking of Hydrogen‐Bonded Sheets

DNA-based asymmetric catalysis

Porous Coordination Polymer with π Lewis Acidic Pore Surfaces, {[Cu₃(CN)₃{hat(CN)₃(OEt)₃}]⋅3 THF}_n

A Kinetic and Structural Investigation of DNA‐Based Asymmetric Catalysis Using First‐Generation Ligands

Strategies and Tactics for the Metal‐Directed Synthesis of Rotaxanes, Knots, Catenanes, and Higher Order Links

DNA‐Based Asymmetric Catalysis

Palladium‐Catalyzed anti‐Markovnikov Oxidation of Terminal Alkenes

SAD phasing by combination of direct methods with theSOLVE/RESOLVEprocedure

Self-assembly of soft nanoparticles with tunable patchiness

Phosphoramidites: Privileged Ligands in Asymmetric Catalysis

Interactions with Aromatic Rings in Chemical and Biological Recognition

Features and development of Coot

Intramolecular C−H Activation by Alkylpalladium(II) Complexes: Insights into the Mechanism of the Palladium-Catalyzed Arylation Reaction

Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts

Molecular Pair Analysis: CH⋅⋅⋅F Interactions in the Crystal Structure of Fluorobenzene? And Related Matters

Electron Delocalization in a Rigid Cofacial Naphthalene‐1,8:4,5‐bis(dicarboximide) Dimer

Multicomponent Reaction Design in the Quest for Molecular Complexity and Diversity

Alternative Metals for Homogeneous Catalyzed Hydroformylation Reactions

Exceptional Thermal Stability in a Supramolecular Organic Framework: Porosity and Gas Storage

Intramolecularly coordinated arylmagnesium compounds: effects on the Schlenk equilibrium

Controlling Switching in Bistable [2]Catenanes by Combining Donor–Acceptor and Radical–Radical Interactions

Bis(imino)pyridines:  Surprisingly Reactive Ligands and a Gateway to New Families of Catalysts

Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles

Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications

Heterogeneous Dinuclear Rhodium(II) Hydroformylation Catalysts—Performance Evaluation and Silsesquioxane-Based Chemical Modeling

Medium-range structure in glasses and low-Q structure in neutron and X-ray scattering data

Large exTTF-Based Dendrimers. Self-Assembly and Peripheral Cooperative Multiencapsulation of C₆₀

One-Component Multifunctional Sequence-Defined Ionizable Amphiphilic Janus Dendrimer Delivery Systems for mRNA

Catalysis for the Valorization of Exhaust Carbon: from CO₂to Chemicals, Materials, and Fuels. Technological Use of CO₂

VersatileN,C,NCoordination Behavior of a Monoanionic Aryldiamine Ligand in Ruthenium(II) Complexes:  Syntheses and Crystal Structures of [Ru^II{C₆H₃(CH₂NMe₂)₂-2,6}X(L)] (L = Norbornadiene, X = Cl, SO₃CF₃; L = PPh₃, X = I) and [Ru^II{C₆H₃(CH₂NMe₂)₂-2,6}(2,2‘:6‘,2‘‘-terpyridine)]Cl

Copper(I)-Assembled [3]Rotaxane Whose Two Rings Act as Flapping Wings

C−H Activation for the Construction of C−B Bonds

Sliding-Ring Catenanes

Synthesis and structure of aryl-substituted phospha-alkenes

Positive Cooperativity in the Template-Directed Synthesis of Monodisperse Macromolecules

Synthesis and Reactivity of Tantalum Alkylidene Complexes Containing the C,N,N‘-Chelating Aryldiamine Ligand [C₆H₄(CH₂N(Me)CH₂CH₂NMe₂)-2]^- (CNN). X-ray Structures of [TaCl₂(CH-t-Bu)(CNN)], [Ta{(CH₂)₃-1,3}(CNN)(O-t-Bu)₂], and [Ta(CNN)(O-t-Bu)₂(H₂CCH₂)]

Formation of Diphosphates. A NMR Study on the Mechanism and Stereochemistry of Diphosphate Formation from Chiral Dioxaphosphorinanes

Novel Aryltitanium(IV) Complexes Containing η³-NCN-Pseudofacial- and η³-NCN-Meridional-Bonded [C₆H₃(CH₂NMe₂)₂-2,6]^- (Abbreviated as NCN) Ligands. The Crystal Structures of [TiCl₂(η³-fac-NCN)(O-i-Pr)], [TiCl(η³-mer-NCN)(O-i-Pr)(OTf)] Containing an η¹-O-Bonded Triflate Anion, and the Seven-Coordinated [Ti(η³-mer-NCN)(O-i-Pr)(OTf)₂] Containing η¹-O- and η²-O,O‘-Bonded Triflate Anions

Tetrathiafulvalene Hetero Radical Cation Dimerization in a Redox-Active [2]Catenane

Intramolecularly Stabilized 1,4-Phenylene-Bridged Homo- and Heterodinuclear Palladium and Platinum Organometallic Complexes Containing N,C,N-Coordination Motifs; η¹-SO₂ Coordination and Formation of an Organometallic Arenium Ion Complex with Two Pt−C σ-Bonds

Synthesis and Characterization of β‐Phosphaenones An Investigation on the Conjugative Properties of the PC Bond

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

Synthesis of Chelate-Supported Dialkyl and Alkylidene Complexes of Molybdenum(VI)

Two Dimensional Chiral Networks Emerging from the Aryl−F···H Hydrogen-Bond-Driven Self-Assembly of Partially Fluorinated Rigid Molecular Structures

Stabilization and reaction behaviour of a terminal phosphido unit on a mononuclear Pt(II) centre. Synthesis and X-ray structure of a cationic diphenylphosphine complex [Pt{C6H3(CH2NMe2)2-2,6}(PHPh2)][OSO2CF3] and a diphenylphosphido-bridged Pt(II)/Pd(II) complex [Pt{C6H3(CH2NMe2)2-2,6}(μ-PPh2)Pd(C6H4CH2NMe2-2)-(H2O)][BF4]·CH2Cl2

Supramolecular Polymers

Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation

Fluorine in Pharmaceuticals: Looking Beyond Intuition

Phosphane Coordination to Magnesium: Synthesis and Structure of Bis[ortho, ortho′‐bis{(dimethylphosphino)‐methyl}phenyl]magnesium

Stereoselective oxidative-addition reactions of dihalogens and copper(II) halides to square-planar organoplatinum(II) complexes containing hard N and C donor atoms. Molecular structures of [bc,de-bis(8-dimethylamino-1-naphthyl)]-af-diiodoplatinum(IV) and ab-dibromo[cf,de-bis(8-dimethylamino-1-naphthyl)]platinum(IV)

Hypercoordinate Aryltrialkylsilanes and -stannanes and Their Use in the Synthesis of Homodinuclear Organometallic Complexes with a 1,4-Phenylene Bridge

New Ruthenium(II) Complexes of Functionalized Monoanionic Aryldiamine N,C,N'‐Terdentate Ligands: Syntheses of [Ru^II{2,6‐(Me₂NCH₂)₂‐4‐R‐C₆H₂}‐(terpy)]⁺Cl^‐; X‐ray Structure of a Dimeric Organolithium Compound, [Li{2,6‐(Me₂NCH₂)₂‐4‐Ph‐C₆H₂}]₂

Monodentate Phosphoramidites: A Breakthrough in Rhodium‐Catalysed Asymmetric Hydrogenation of Olefins

Metal–Organic Polyhedral Core as a Versatile Scaffold for Divergent and Convergent Star Polymer Synthesis

Acyl‐ und Alkylidenphosphane. XXIX. Molekül‐ und Kristallstruktur des Orthorhombischen (Diphenylmethyliden)mesitylphosphans

High Oxidation State Multiple Metal−Carbon Bonds

DNA-Based Asymmetric Catalysis: Sequence-Dependent Rate Acceleration and Enantioselectivity

Katalytische Markownikow‐ und Anti‐Markownikow‐Funktionalisierung von Alkenen und Alkinen

Framework Engineering by Anions and Porous Functionalities of Cu(II)/4,4‘-bpy Coordination Polymers

Mechanical Bonds and Topological Effects in Radical Dimer Stabilization

IDPi Catalysis

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

Synthesis of 2-(2-Pyridyl)phosphaalkenes [Mes*PC(R)Py] (R = H, SiMe₃) and Their Complexes η¹,η¹-[Mes*PC(R)Py]XPdCl (X = Cl, Me, Ac)

Strong Dimerization of Ureidopyrimidones via Quadruple Hydrogen Bonding

The Halogen Bond

Coordination Networks of 3,3‘-Dicyanodiphenylacetylene and Silver(I) Salts:  Structural Diversity through Changes in Ligand Conformation and Counterion

Dinuclear Palladium, Nickel, and Rhodium Complexes Based on 1,3-Bis[(2-(diphenylphosphino)benzylidene)amino]propan-2-ol

Charge Transport in Organic Semiconductors

The title compound 4 was synthesized from dipotassium 1,8‐anthracenedisulfonate (9) and potassium diphenylphosphide (Ph₂PK). On reaction of 4 with nickel(II) chloride and bis‐(benzonitrile)palladium(II) chloride, cyclometallation of the C – H bond in anthracene 9‐position led to the square‐planar chelate complexes 11 and 13, respectively. In the case of the palladium complex 13, the cyclometallated structure was proved by X‐ray structure analysis. Treatment with aqueous potassium cyanide did not remove nickel from 11, but converted 11 into 12 by substitution of chloride with cyanide, demonstrating the high stability of these cyclometallated chelate complexes.

New palladium, patinum and nickel complexes based on rigid phosphorus and nitrogen containing ligands

Inter-ligand reactions: in situ formation of new polydentate ligands

Alternative Metalle für die homogen katalysierte Hydroformylierung

Scope and Limitations of the Base-Catalyzed Phospha-Peterson PC Bond-Forming Reaction

The Directed Lithiation of Benzenoid Aromatic Systems

Lanthanide Single-Molecule Magnets

Activation of olefins via asymmetric Brønsted acid catalysis

Hydroformylation of 1-octene using rhodium-1,3-R2-3,4,5,6-tetrahydropyrimidin-2-ylidenes (R=2-Pr, mesityl)

Phosphan‐Koordination an Magnesium: Synthese und Struktur von Bis[ortho, ortho′‐bis‐{(dimethylphosphano)methyl}phenyl]magnesium

The Effect of the Trimethylsilyl Group on Electrophilic Cyclopalladation; A Study of Caryl-Si versus Caryl-H Selective Bond Activation with 2,6-(Me2NCH2)2C6H3R (R=H or SiMe3)

Chemistry and Biology Of Multicomponent Reactions

Mechanical Bond-Induced Radical Stabilization

The crystal structure, spectroscopy and EPR of tetragonal bis(2-(aminomethyl)pyridine)Cu(II) compounds. Rare cases of the absence of Cu(II) plasticity

Which organic crystal structures are predictable by lattice energy minimisation?

Redox Control of the Binding Modes of an Organic Receptor

Sequential C−H and C−Ru Bond Formation and Cleavage during the Thermally Induced Rearrangement of Aryl Ruthenium(II) Complexes with [C₆H₃(CH₂NMe₂)₂-2,6]^-as a Bidentate η²-C,NCoordinated Ligand. The Crystal Structures of the Isomeric Pairs [RuCl{η⁶-C₁₀H₁₄}{η²-C,N-C₆H₃(CH₂NMe₂)₂-2,n}] (n= 4 or 6) and [Ru(η⁵-C₅H₅){η²-C,N-C₆H₃(CH₂NMe₂)₂-2,n}(PPh₃)] (n= 4 or 6)

Self-Assembly of a [2]Pseudorota[3]catenane in Water

Wechselwirkungen mit aromatischen Ringen in chemischen und biologischen Erkennungsprozessen

Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations

Structural Elucidation of Dendritic Host–Guest Complexes by X‐ray Crystallography and Molecular Dynamics Simulations

A Multicomponent Reaction Towards N‐(Cyanomethyl)amides

Structure of (E)-[(2-isopropylphenyl)(phenyl)methylene](mesityl)phosphine

Bis(2-aminomethylpyridine-N,N')bis(nitrato-O)copper(II)

Structure of {2,3,5,6-tetrakis[(dimethylamino)methyl]phenyl-C,N,N'}lithium dimer

Direct phase determination of triple products from Bijvoet inequalities. II. A probabilistic approach

Hypothetical Crystal Structures of Benzene at 0 and 30 kbar

[2,6-Bis(N-tert-butyliminomethyl)pyridine-κ³N](phenolato-κO)rhodium(I)

Reaction of (1,8-Naphthalenediyl)magnesium with Group 5 and 6 Metallocene Dichlorides. Formation and X-ray Crystal Structure of (.eta.5-Cp)Mo(PMe3)2(.eta.3-6b-H-7,9a-dihydrocyclopent[a]acenaphthylen-7-yl)

ChemInform Abstract: TRANS‐2,6‐BIS((DIMETHYLAMINO)METHYL)PHENYL‐N,N′,C COMPLEXES OF PALLADIUM(II) AND PLATINUM(II). CRYSTAL STRUCTURE OF (PTI(MEC6H3(CH2NME2)2‐O,O′))BF4: A CYCLOHEXADIENYL CARBONIUM ION WITH A Σ‐BONDED METAL SUBSTITUENT

Structure of KLiSi₂O₅ and the hygroscopicity of glassy mixed alkali disilicates

The crystal and molecular structure of N-mesitylbenzophenoneimine [N-(diphenylmethylene)mesitylamine]

In Quest of the Double Rotaxane Formation of the Bis(coronand) (1,5),(2,4)‐Durenetetrayl‐bis(18‐crown‐5) with Organomagnesium Compounds

Ein stabiler, umweltfreundlicher Katalysator für die hochselektive Hydroformylierung

LEPAGE– an MS-DOS program for the determination of the metrical symmetry of a translation lattice

Structure of a second monoclinic polymorph of triphenylphosphine oxide