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1967
Diverse Mechanistic Pathways and Selectivities in Organo-f-Element-Catalyzed Hydroamination. Intermolecular Organolanthanide-Catalyzed Alkyne and Alkene Hydroamination
1996
Photochemical Generation of Six- and Five-Membered Cyclic Vinyl Cations
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Stable compounds of the heavier group 14 and 15 elements involving pπpπ multiple bonding: an overview of the first decade
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Organic Reactions in Aqueous Media with a Focus on Carbon−Carbon Bond Formations: A Decade Update
2005 Standout
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1984
High Oxidation State Multiple Metal−Carbon Bonds
2001 StandoutNobel
Reaction d'aminomercuration—VIII
1972
A Stable Stannaethene
1987
Reaction of acyl chlorides with organometallic reagents: A banquet table of metals for ketone synthesis
1999
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Aromatic Trifluoromethylation with Metal Complexes
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π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
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2000
Position-specific alkylation of lithio-1-trimethylsilylpropyne, a useful new route to acetylenes and 1, 5-dienes
1968 StandoutNobel
Multiple bonds to silicon: 20 years later
2002
Anisotropy of the Induced Current Density (ACID), a General Method To Quantify and Visualize Electronic Delocalization
2005 Standout
From aminosilane to iminosilane
1994
Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes
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Chemistry and Biology Of Multicomponent Reactions
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1999
Novel Stable Silenes via a Sila-Peterson-type Reaction. Molecular Structure and Reactivity
1996
On the nature of carbenoids generated from bicyclo[1.1.0]butanes and transition metal complexes
1973 StandoutNobel
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
2009 Standout
A Surprisingly Stable 1‐(Chlorosilyl)‐2‐phosphaethenyllithium Compound, RCl2SiC(Li)=PMes*
2005
Asymmetric Enamine Catalysis
2007 StandoutNobel
Some Typical Advances in the Synthetic Applications of Allenes
2005 Standout
Ru3(CO)12- and Rh4(CO)12-Catalyzed Reactions of Pyridylolefins or N-(2-Pyridyl)enamines with CO and Olefins. Carbonylation at Olefinic C−H Bonds
1998
Ru-, Rh-, and Pd-Catalyzed C−C Bond Formation Involving C−H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic Aspects
2002 Standout
The equilibrium structure of silene H2C=SiH2 from millimeter wave spectra and from ab initio calculations
1997
A Chemical Trick: How To Make a Digermene from a Disilene, Formation of 3Δ-1,2,3,4-Disiladigermetene
2003
A "Green" Route to Adipic Acid: Direct Oxidation of Cyclohexenes with 30 Percent Hydrogen Peroxide
1998 StandoutScienceNobel
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
2000 Standout
The isomers of silacyclopropane
1980 Standout
Indium- and zinc-mediated allylation of difluoroacetyltrialkylsilanes in aqueous media
2003
Heavy Ketones, the Heavier Element Congeners of a Ketone
2000
Synthesis and Properties of an Overcrowded Silabenzene Stable at Ambient Temperature
2000
Applied Hydroformylation
2012 Standout
Stronger Brønsted Acids
2007 Standout
Phenyl Silaisocyanide: The First Organosilicon Compound with a Formal SiN Triple Bond
1985
Recent Developments in the Synthesis and Structure of Organosilanols
2004
Reaction Pathway of the Conjugate Addition of Lithium Organocuprate Clusters to Acrolein
1997
Disilenyl Anions Derived from Reduction of Tetrakis(di-tert-butylmethylsilyl)disilene with Metal Naphthalenide through a Disilene Dianion Intermediate: Synthesis and Characterization
2005
Works of A. G. Brook being referenced
Displacements at Asymmetric Germanium. Methyl-α-naphthylphenylgermyllithium and its Derivatives
1963
Triphenylsilyl Phenyl Ketone
1957
Stable silene geometric isomers
1992
Cycloaddition reactions of stable silenes with acylsilanes
1993
Reactions of Silenes: A New Silene to Silene Thermal Rearrangement
1995
The Alkaline Cleavage of Tetrasubstituted Silanes
1953
1-Sila-3-azacyclobutanes: the insertion of isocyanides into silaaziridines
1989
Silaaziridines from the reaction of isonitriles with stable silenes
1988
Synthesis, resolution, and absolute configuration of 1-phenyl-1-methyl-1-silacyclohexanone-2
1970
1,4-Silyl rearrangements of siloxyalkenes to siloxyketones during peroxidation
1974
Stable solid silaethylenes
1982
Siloxycarbenes from the thermolysis of acylsilanes
1975
Photolysis of Acyl Group IV Metalloids: the Formation of Silyl Radicals
1971
PMR studies of silycarbinols and related compounds
1967
Reactions of stable silenes with dienes and alkenes: [2 + 2], [2 + 4] and ene reactions
1987
Photochemical rearrangements of stable silenes
1989
Attempted stabilization of silaethylenes with aryl or trifluoromethyl groups
1982
1,2-Siloxetanes: formation, structure, and rearrangements.
1987
Relatively stable silaethylenes. Photolysis of acylpolysilanes
1979
The Reaction of Triphenylsilylpotassium with Organic Halides, a Case of Halogen-Metal Interconversion1
1957
Alkoxycarbenes from the thermolysis of silyl ketals
1969
The mechanism of the β-ketosilane to siloxyalkene thermal rearrangement
1975
Stereochemistry at asymmetric carbon in the silylcarbinol to alkoxysilane rearrangement
1971
The Spectral and Chemical Properties of α-Silyl Ketones
1960
A silathiirane and a silaselenirane from a stable silene
1994
Silicon-carbon double bonds: new route, new substituents, new behavior
1976
REACTIONS OF THE STILBENE-DISODIUM AND -DILITHIUM ADDUCTS
1953
Reaction of a silene with a silacyclopropane to yield a disilacyclopropane
1985
Preparation and X-ray crystal structure of a carbamylsilane
1991
Silyl-substituted α,β-Unsaturated Ketones from the Reaction of Silylvinylmetallic Reagents with Acid Anhydrides
1973
Tris(trimethylsilyl)silyllithium · 3 THF: a stable crystalline silyllithium reagent
1982
Carbon-13 and silicon-29 chemical shifts and coupling constants involving tris(trimethylsilyl)silyl systems
1982
The configurations of the diastereomeric 1-chloromercuri-2-methoxycyclo-hexanes
1951
Cycloaddition Reactions of Silyldiazoalkanes Involving Rearrangements from Carbon to Nitrogen
1974
Photoisomerization of a highly substituted silene
1985
Synthesis of α,β-Unsaturated Acylsilanes and an Unusual Thermal Reaction Involving a Siladiene
1996
Synthesis of some tris(trimethylsilyl)germyl compounds
1986
Optically active silyl- and germylmethyllithium reagents and the stereochemistry of carbene insertions into the silicon-hydrogen and germanium-hydrogen bonds
1970
Reactions of silyl and germyl ketones with alkylidenephosphoranes
1967
Synthesis of Silyl and Germyl Ketones
1967
Reactions of silenes with .alpha.,.beta.-unsaturated aldehydes and ketones
1991
Structure of 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsily)-1-silaethylene
1985
Cleavage of Hexaphenyldisilane by Sodium and Lithium
1954
Photolysis of acylpolysilanes containing .alpha.-hydrogens. Formation of linear head-to-head silene dimers
1987
Silicon-29 NMR studies of relatively stable silaethylenes
1979
Preparation and reactions of sulfoxides and phosphine oxides containing silicon and germanium
1968
One thing leads to another - from silylcarbinols to silaethylenes
1986
A solid silaethene: isolation and characterization
1981
Isomerism of Some α-Hydroxysilanes to Silyl Ethers
1958